Environment-friendly antistatic PVC material and preparation method and application thereof

Abstract

The application relates to the technical field of PVC materials, in particular to an environment-friendly antistatic PVC material and a preparation method and application thereof.The environment-friendly antistatic PVC material comprises the following raw materials in parts by weight: 100 parts of PVC resin, 3-6 parts of a stabilizer, 40-60 parts of a plasticizer, 0.5-2 parts of an antioxidant, 10-30 parts of sodium hexanolactone modified lignin sulfonate, 0.5-2 parts of a lubricant and 15-25 parts of conductive filler.The environment-friendly antistatic PVC material prepared by the application has good antistatic performance and can be used for the preparation of Teslin products.

Description

TECHNICAL FIELD

[0001] The application relates to the technical field of PVC materials, in particular to an environment-friendly antistatic PVC material and a preparation method and application thereof. BACKGROUND

[0002] Polyvinyl chloride (PVC) is a thermoplastic plastic with the second largest production after polyethylene, and is formed by polymerization of vinyl chloride monomers. The application fields of PVC are very wide, such as electrical insulation materials in industrial and agricultural industries, frames of buildings, indoor decoration, rainproof films for agriculture, and Teslin products.

[0003] The PVC molecular chain contains chloride ions, and the chloride ions have strong electronegativity, so the PVC molecular chains have strong mutual attraction. In addition, due to the steric hindrance effect, the vinyl chloride has good rigidity, hardness and excellent mechanical properties. At the same time, the existence of the polar group leads to a high resistivity, and static electricity is easily accumulated during processing and use, which causes static hazards and affects normal use. Especially in special places such as micro-device manufacturing workshops, laboratories and operating rooms, the static hazards caused by the devices made of PVC will cause serious losses. Therefore, it is urgent to reduce the static influence of PVC and make the use of PVC products safer. SUMMARY

[0004] In order to reduce the static influence of PVC, the application provides an environment-friendly antistatic PVC material and a preparation method and application thereof.

[0005] In the first aspect, the application provides an environment-friendly antistatic PVC material, which adopts the following technical scheme:

[0006] The environment-friendly antistatic PVC material comprises the following raw materials in parts by weight: 100 parts of PVC resin, 3-6 parts of stabilizer, 40-60 parts of plasticizer, 0.5-2 parts of antioxidant, 10-30 parts of sodium lignosulfonate modified by caprolactone, 0.5-2 parts of lubricant and 15-25 parts of conductive filler.

[0007] By adopting the above technical scheme, the lignosulfonate sodium molecule contains sulfonic acid groups and has water absorption performance. When added to the PVC material, the lignosulfonate sodium can absorb water molecules on the surface of the material and has a moisture absorption and antistatic effect. The lignosulfonate sodium modified by caprolactone has better compatibility with PVC, can be uniformly dispersed in the PVC system, and forms a uniform antistatic network. The conductive filler is dispersed in the PVC resin and cooperates with the lignosulfonate sodium modified by caprolactone to form a three-dimensional antistatic network from the inside to the surface of the PVC material, thereby giving the PVC material excellent antistatic performance. In addition, lignin is a natural polymer with aromatic rings, and is abundant in production and widely sourced, so it is an environment-friendly material.

[0008] Preferably, the sodium caprolactone-modified lignin sulfonate is prepared by reacting caprolactone and sodium lignin sulfonate at a mass ratio of 1:(2-10).

[0009] Preferably, the sodium caprolactone-modified lignin sulfonate is 10-15 parts by weight.

[0010] Preferably, the conductive filler is 20-25 parts by weight.

[0011] Preferably, the conductive filler is one or more of carbon black, graphene, and carbon nanotubes.

[0012] Preferably, the conductive filler is carbon black and / or graphene.

[0013] By adopting the above technical solution, carbon black and graphene synergistically improve the antistatic performance of the PVC material.

[0014] Preferably, the conductive filler is modified graphene, which is prepared by compounding titanate coupling agent and graphene at a mass ratio of 1:(10-18).

[0015] By adopting the above technical solution, graphene modified by the titanate coupling agent has better dispersibility in the PVC material. This helps to form a more uniform antistatic network, further improving the antistatic performance of the PVC material.

[0016] Preferably, the stabilizer is a calcium-zinc composite stabilizer.

[0017] In a second aspect, the present application provides a preparation method of the environment-friendly antistatic PVC material, which adopts the following technical solution:

[0018] A preparation method of an environment-friendly antistatic PVC material, comprising the following steps:

[0019] Mixing the components in the raw materials uniformly, extruding and granulating to obtain the environment-friendly antistatic PVC material.

[0020] In a third aspect, the present application provides an application of the environment-friendly antistatic PVC material, which adopts the following technical solution: An application of the environment-friendly antistatic PVC material, which can be used for the preparation of TESLIN products. DETAILED DESCRIPTION

[0021] The present application is further described in detail below in conjunction with examples.

[0022] Unless otherwise specified, the specifications of the raw materials used in the following examples and comparative examples are shown in Table 1.

[0023] Table 1. Raw material specification information

[0024]

[0025]

[0026] Preparation Example of Caprolactone Modified Sodium Lignosulfonate

[0027] Preparation Example 1

[0028] Caprolactone modified sodium lignosulfonate was prepared according to the following steps:

[0029] Caprolactone was added dropwise into sodium lignosulfonate at 80°C (the mass ratio of caprolactone to sodium lignosulfonate was 1:2, and the total mass of the two was 1 kg), and stirred and mixed for 10 min, and then cooled to 25°C to obtain caprolactone modified sodium lignosulfonate.

[0030] Preparation Example 2

[0031] Caprolactone modified sodium lignosulfonate was prepared according to the following steps:

[0032] Caprolactone was added dropwise into sodium lignosulfonate at 80°C (the mass ratio of caprolactone to sodium lignosulfonate was 1:10, and the total mass of the two was 1 kg), and stirred and mixed for 10 min, and then cooled to 25°C to obtain caprolactone modified sodium lignosulfonate.

[0033] Preparation Example 3

[0034] Caprolactone modified sodium lignosulfonate was prepared according to the following steps:

[0035] Caprolactone was added dropwise into sodium lignosulfonate at 80°C (the mass ratio of caprolactone to sodium lignosulfonate was 1:5, and the total mass of the two was 1 kg), and stirred and mixed for 10 min, and then cooled to 25°C to obtain caprolactone modified sodium lignosulfonate.

[0036] Preparation Example of Modified Graphene

[0037] Preparation Example A

[0038] Modified graphene was prepared according to the following steps:

[0039] 100 g of a titanate coupling agent, 1000 g of graphene, and 2 L of water were mixed and ultrasonically dispersed for 20 min, and then dried to obtain modified graphene.

[0040] Preparation Example B

[0041] Modified graphene was prepared according to the following steps:

[0042] 100 g of a titanate coupling agent, 1800 g of graphene, and 2.5 L of water were mixed and ultrasonically dispersed for 20 min, and then dried to obtain modified graphene.

[0043] Preparation Example C

[0044] Modified graphene was prepared according to the following steps:

[0045] 100 g of titanate coupling agent, 1500 g of graphene, and 2 L of water were mixed and ultrasonically dispersed for 20 min, and then dried to obtain modified graphene.

[0046] Example

[0047] Example 1

[0048] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0049] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, sodium caprolactone-modified lignin sulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and conductive filler carbon black 150 g.

[0050] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0051] PVC resin, stabilizer, plasticizer, antioxidant, sodium caprolactone-modified lignin sulfonate, and lubricant, and conductive filler were mixed, stirred at a speed of 900 rpm for 5 min to obtain a mixture, and then the mixture was placed in a hopper and mixed and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder in the direction of material advancement was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. An environmentally friendly antistatic PVC material was prepared.

[0052] Example 2

[0053] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0054] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, sodium caprolactone-modified lignin sulfonate prepared in Preparation Example 2 100 g, lubricant 5 g, and conductive filler carbon black 150 g.

[0055] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0056] PVC resin, stabilizer, plasticizer, antioxidant, hexalactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0057] Example 3

[0058] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0059] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, hexalactone modified sodium lignosulfonate prepared in Preparation Example 3 100 g, lubricant 5 g, and conductive filler carbon black 150 g.

[0060] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0061] PVC resin, stabilizer, plasticizer, antioxidant, hexalactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0062] Example 4

[0063] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0064] PVC resin 1000 g, stabilizer 60 g, plasticizer 600 g, antioxidant 20 g, hexalactone modified sodium lignosulfonate prepared in Preparation Example 1 300 g, lubricant 20 g, and conductive filler carbon black 250 g.

[0065] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0066] PVC resin, stabilizer, plasticizer, antioxidant, hexalactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0067] Example 5

[0068] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0069] PVC resin 1000 g, stabilizer 50 g, plasticizer 500 g, antioxidant 15 g, hexalactone modified sodium lignosulfonate prepared in Preparation Example 1 150 g, lubricant 12 g, and conductive filler carbon black 200 g.

[0070] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0071] PVC resin, stabilizer, plasticizer, antioxidant, hexalactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0072] Example 6

[0073] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0074] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, hexalactone modified sodium lignosulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and conductive filler graphene 150 g.

[0075] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0076] PVC resin, stabilizer, plasticizer, antioxidant, caprolactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and extruded and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0077] Example 7

[0078] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0079] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, caprolactone modified sodium lignosulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and conductive filler 150 g (carbon black and graphene 75 g each).

[0080] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0081] PVC resin, stabilizer, plasticizer, antioxidant, caprolactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and extruded and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0082] Example 8

[0083] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0084] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, caprolactone modified sodium lignosulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and conductive filler 150 g (carbon black and graphene 75 g each).

[0085] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0086] PVC resin, stabilizer, plasticizer, antioxidant, sodium caprolactone modified lignin sulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0087] Example 9

[0088] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0089] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, sodium caprolactone modified lignin sulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and modified graphene prepared in Preparation Example B 150 g.

[0090] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0091] PVC resin, stabilizer, plasticizer, antioxidant, sodium caprolactone modified lignin sulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0092] Example 10

[0093] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0094] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, sodium caprolactone modified lignin sulfonate prepared in Preparation Example 1 100 g, lubricant 5 g, and modified graphene prepared in Preparation Example C 150 g.

[0095] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0096] PVC resin, stabilizer, plasticizer, antioxidant, caprolactone modified sodium lignosulfonate and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The temperature of the barrel of the twin-screw extruder in the direction of material advancement was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0097] Comparative Example

[0098] Comparative Example 1

[0099] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0100] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, sodium lignosulfonate 100 g, lubricant 5 g, and conductive filler carbon black 150 g.

[0101] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0102] PVC resin, stabilizer, plasticizer, antioxidant, sodium lignosulfonate, and lubricant, conductive filler were mixed, stirred at a speed of 900 rpm for 5 minutes to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The temperature of the barrel of the twin-screw extruder in the direction of material advancement was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, an environmentally friendly antistatic PVC material was prepared.

[0103] Comparative Example 2

[0104] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0105] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, lubricant 5 g, and conductive filler carbon black 250 g.

[0106] An environmentally friendly antistatic PVC material was prepared according to the following steps:

[0107] PVC resin, stabilizer, plasticizer, antioxidant, lubricant, conductive filler were mixed, stirred at a speed of 900 r / min for 5 min to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, the environment-friendly antistatic PVC material was prepared.

[0108] Comparative Example 3

[0109] An environment-friendly antistatic PVC material was prepared according to the following steps:

[0110] PVC resin 1000 g, stabilizer 30 g, plasticizer 400 g, antioxidant 5 g, and the sodium caprolactone-modified lignosulfonate prepared in Preparation Example 1 250 g, and lubricant 5 g.

[0111] An environment-friendly antistatic PVC material was prepared according to the following steps:

[0112] PVC resin, stabilizer, plasticizer, antioxidant, sodium caprolactone-modified lignosulfonate, and lubricant, and conductive filler were mixed, stirred at a speed of 900 r / min for 5 min to obtain a mixture, and then the mixture was put into a hopper and granulated by a twin-screw extruder. The barrel temperature of the twin-screw extruder was 145, 145, 155, 155, 160, 160, 170, 170, 180, 180, and 185°C in the direction of material advancement. The rotation speed was 150 r / min, and the cutting speed was 8.5 r / min. Thus, the environment-friendly antistatic PVC material was prepared.

[0113] Detection method

[0114] The environment-friendly antistatic PVC materials prepared in Examples 1-10 and Comparative Examples 1-3 were respectively made into a round piece with a diameter of 100 mm and a thickness of 2 mm, and the surface resistance of the round piece was tested by a surface resistance tester (the sample was placed in an environment with a temperature of 23°C and a humidity of 33%). The specific test results are shown in Table 2.

[0115] Table 2. Performance test of environment-friendly antistatic PVC material

[0116] Item Surface Resistance / Ω Item Surface Resistance / Ω Example 1 8.5 x 10 7 ]]> Example 8 5.2 x 10 7 ]]> Example 2 7.4 x 10 7 ]] Example 9 5.6 x 10 7 ]] Example 3 7.1 x 10 7 ]] Example 10 4.9 x 10 7 ]] Example 4 9.1 x 10 7 ]] Comparative Example 1 9.3 x 10 8 ]] Example 5 7.8 x 10 7 ]] Comparative Example 2 7.6 x 10 9 <!-- 6 -->]]> Example 6 8.3 x 10 7 ]]> Comparative Example 3 2.4 x 10 9 ]]> Example 7 6.2 x 10 7 ]]>

[0117] As can be seen from Table 2, the surface resistance of the environment-friendly antistatic PVC material prepared in the examples is ≤9.1×10 7Ω, the surface resistance is low, and has good antistatic performance. The environment-friendly antistatic PVC material prepared in the application can be used for the preparation of Teslin products, and can solve the problem of easy static electricity in the use process of Teslin products.

[0118] It can be seen from the combination of Example 1 and Comparative Example 1 and Table 2 that the surface resistance of the environment-friendly antistatic PVC material prepared in Example 1 is much lower than that of Comparative Example 1, which may be because: the sodium lignosulfonate modified by caprolactone is selected in Example 1, and the sodium lignosulfonate modified by caprolactone has better compatibility with PVC, can be uniformly dispersed in the PVC system, and form a more uniform antistatic network; while the sodium lignosulfonate in Comparative Example 1 is not modified.

[0119] It can be seen from the combination of Example 1 and Comparative Examples 2-3 and Table 2 that the surface resistance of the environment-friendly antistatic PVC material prepared in Example 1 is much lower than that of Comparative Examples 2-3, which may be because: Comparative Example 2 does not contain sodium lignosulfonate modified by caprolactone, but only contains conductive fillers; Comparative Example 3 does not contain conductive fillers, but only contains sodium lignosulfonate modified by caprolactone; while Example 1 contains both, the conductive fillers are dispersed in the PVC resin, and cooperate with the sodium lignosulfonate modified by caprolactone to form a three-dimensional antistatic network from the inside to the surface of the PVC material, thereby giving the PVC material excellent antistatic performance, and both are indispensable in function and cooperate with each other.

[0120] The specific embodiments are only an explanation of the application, and are not a limitation of the application. Those skilled in the art can make modifications to the embodiments without creative contribution after reading the specification, but as long as the modifications are within the scope of the claims of the application, they are protected by the Patent Law.

Claims

1. An environmentally friendly antistatic PVC material, characterized in that: The raw materials contain the following parts by weight: 100 parts PVC resin, 3-6 parts stabilizer, 40-60 parts plasticizer, 0.5-2 parts antioxidant, 10-30 parts caprolactone-modified sodium lignosulfonate, 0.5-2 parts lubricant, and 15-25 parts conductive filler.

2. The environmentally friendly antistatic PVC material according to claim 1, characterized in that: The caprolactone-modified sodium lignosulfonate is prepared by reacting caprolactone and sodium lignosulfonate in a mass ratio of 1:(2-10).

3. The environmentally friendly antistatic PVC material according to claim 1, characterized in that: The amount of caprolactone-modified sodium lignosulfonate is 10-15 parts by weight.

4. The environmentally friendly antistatic PVC material according to claim 1, characterized in that: The conductive filler is 20-25 parts by weight.

5. The environmentally friendly antistatic PVC material according to claim 1, characterized in that: The conductive filler is one or more of carbon black, graphene, and carbon nanotubes.

6. The environmentally friendly antistatic PVC material according to claim 5, characterized in that: The conductive filler is carbon black and / or graphene.

7. The method for preparing an environmentally friendly antistatic PVC material according to claim 6, characterized in that: The conductive filler is modified graphene, which is prepared by compounding titanate coupling agent and graphene in a mass ratio of 1:(10-18).

8. The environmentally friendly antistatic PVC material according to claim 1, characterized in that: The stabilizer is a calcium-zinc composite stabilizer.

9. A method for preparing an environmentally friendly antistatic PVC material according to any one of claims 1-8, characterized in that: Includes the following steps: The components in the raw materials are mixed evenly and then extruded and granulated to obtain environmentally friendly antistatic PVC material.

10. The application of the environmentally friendly antistatic PVC material according to any one of claims 1-8, characterized in that: The environmentally friendly antistatic PVC material can be used in the preparation of Teslin products.

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