A medium and low temperature waste energy recovery carbon sequestration device

Abstract

The embodiment of the present application provides a kind of low-temperature residual energy recovery carbon fixation device, it is characterized in that, for residual energy recovery and carbon fixation, including energy recovery module, carbon fixation module, reinforcement module and control module;The energy recovery module provides the electric energy required for the carbon fixation module and the control module to work, the carbon fixation module fixes carbon dioxide in chimney as solid carbon material, the reinforcement module is used to slow down chimney corrosion and help the smooth emission of pollutants, the control module is used to the synergistic work of residual energy recovery system, carbon fixation module and reinforcement module;The energy recovery module recovers residual heat and residual energy by temperature difference power generation component, fluidization component, pressure power generation component, and then is converted into the electric energy, the carbon fixation module is used to collect and electrolyze the carbon dioxide as alcohol under low potential, and pyrolyze alcohol as the solid carbon material under low power;The solid carbon material includes at least one of carbon nanotube or graphene.The embodiment of the present application solves the problem of difficult low-quality residual energy recovery and low-cost carbon fixation in prior art.

Description

TECHNICAL FIELD

[0001] The present application relates to the field of waste energy recovery and carbon sequestration, and in particular to a low-temperature waste energy recovery and carbon sequestration device. BACKGROUND

[0002] The current global carbon dioxide emissions amount to 40 billion tons per year, most of which is emitted from chimneys, which poses a threat to human health, pollutes the air, and faces two major core problems of carbon dioxide greenhouse effect and a substantial reduction in the service life of condensate water in the chimney.

[0003] First, for the problem of carbon dioxide emissions, according to the statistics of the U.S. Environmental Protection Agency, the contribution of carbon dioxide to the power supply and heating industry is as high as nearly half. The emission of a large amount of carbon dioxide in the air causes the earth's surface to rise sharply, thereby causing serious extreme weather events, glacier melting, sea level rise, etc. These problems have brought great challenges to the global ecosystem and human society.

[0004] Nowadays, there are many methods to reduce or fix carbon dioxide, which aims to convert carbon dioxide in the atmosphere into solid or liquid, thereby reducing its emissions, such as chemical absorption method, biological absorption method, injection method and carbon capture and storage, etc. However, due to the environmental unfriendliness, low efficiency, high energy consumption and storage difficulty, etc., it is difficult to apply to the more difficult chimney, therefore, changing the inherent thinking, solving the problem of emitting a large amount of carbon dioxide gas with low cost and high added value is of great significance to energy saving and emission reduction.

[0005] Secondly, the widespread application of desulfurization and denitrification equipment (80% have been installed) causes a large amount of water vapor to condense into water droplets on the inner wall of the chimney, and the substantial reduction in the service life of condensate water is also a very important key problem. Since the water vapor condenses into condensate water in the chimney, it contains acidic substances and other corrosive components, which causes serious corrosion to the inner wall of the chimney, seriously damages the structural integrity of the chimney, substantially shortens its service life, and even may cause safety accidents.

[0006] The current means to solve the water vapor is to increase the temperature in the chimney to avoid the condensation of water vapor into water droplets. Moreover, the heating can cause serious waste of energy, therefore, there is an urgent need for a solution that can avoid the formation of condensate water on the inner wall of the chimney and avoid the waste of additional energy.

[0007] In summary, it is necessary and urgent to develop a complete system that can effectively recover and utilize low-quality energy, efficiently fix a large amount of carbon dioxide, and at the same time solve the corrosion of condensate water. SUMMARY

[0008] The embodiment of the present application provides a low-temperature waste energy recovery and carbon fixation device to solve the problem of low-quality waste energy recovery and low-cost carbon fixation in the prior art.

[0009] In order to solve the above technical problems, the application is implemented as follows:

[0010] The embodiment of the present application provides a low-temperature waste energy recovery and carbon fixation device for waste energy recovery and carbon fixation, which comprises at least an energy recovery module, a carbon fixation module and a control module; the energy recovery module is connected with the carbon fixation module.

[0011] The energy recovery module provides the carbon fixation module and the control module with the required electric energy for work.

[0012] The carbon fixation module is used for converting carbon dioxide in the chimney into solid carbon material.

[0013] The chimney comprises at least one of automobile exhaust, ship exhaust and industrial chimney.

[0014] The control module is connected with the energy recovery module and the carbon fixation module respectively, and controls the cooperative work of the energy recovery module and the carbon fixation module.

[0015] The energy recovery module recovers waste heat and energy through a thermoelectric generation assembly, a fluidization assembly and a pressure power generation assembly, and then converts the waste heat and energy into electric energy; the carbon fixation module is used for collecting and electrolyzing carbon dioxide at a low potential to obtain alcohol, and then pyrolyzing the alcohol at a low power to continuously convert the alcohol into the solid carbon material on a moving carrier.

[0016] The carrier comprises at least one of continuous carbon fiber and metal wire.

[0017] The solid carbon material comprises at least one of carbon nanotube and graphene.

[0018] The longitudinal shear force of the product is improved by 53% compared with the carrier, and the carrier is widely applied in strategic and civilian fields such as automobiles and aircrafts, and the characteristics of the carrier are continuous carbon fiber.

[0019] The thermoelectric generation assembly realizes thermoelectric generation based on the thermoelectric effect, especially the Seebeck effect, and realizes the conversion of heat energy into electric energy through a thermocouple or a thermoelectric module. The thermoelectric generation assembly is based on low-temperature waste energy, generates a certain temperature difference through the low-temperature convection heat exchange between the low-quality waste heat contained in the chimney and the ambient air outside the chimney, and then continuously drives the thermoelectric generation assembly to generate power, which is not affected by day and night.

[0020] The temperature of the medium and low temperature residual energy is 120-150 ℃, the temperature of the ambient air is 25-30 ℃, and the temperature difference of the thermoelectric generator assembly is 100-120 ℃.

[0021] The wind power generation is realized by means of a fluidization assembly; the fluidization assembly realizes the conversion of high-speed flow in the chimney into electric energy based on electromagnetic induction and aerodynamic principles.

[0022] The working flow rate of the wind power generation is 2-10 m / s, the flue gas flow rate of the chimney is 8-15 m / s, and the chimney can work.

[0023] The fluidization assembly generates up-and-down reciprocating motion by fluidization effect, and condenses and captures water vapor into condensed water on the inner wall, providing a water source required for the operation of the carbon dioxide electrolytic cell assembly; a pressure relief port is arranged on the side wall of the fluidization assembly, and the fluidization assembly is driven by gas wind energy.

[0024] The fluidization effect and / or the fluidization energy is the energy contained by an object in a balanced state under the action of gravity and the buoyancy of gas, such as the kinetic energy of the object moving up and down during suspension.

[0025] The condensed water is formed by condensation of water vapor.

[0026] The fluidization assembly can also convert mechanical energy, convert the up-and-down reciprocating linear motion of the fluidization assembly into circular motion, provide the mechanical energy for the movement of the carrier, and the unit for converting the mechanical energy is a crank and connecting rod structure; at least two groups of the fluidization assemblies are used to alternately and reciprocally supplement the rotary motion, and then the stable output of the mechanical energy is realized through regulation and control, and the continuous mechanical energy is provided for the preparation of products.

[0027] The pressure power generation assembly cooperates with the fluidization assembly to generate periodic intermittent pressure, realizes the piezoelectric power generation process by positive pressure electric effect; the pressure power generation assembly generates electricity by extruding at least two pieces of piezoelectric ceramic through an impact block, and compared with a single piece, the amplification effect is several times, and the current is larger.

[0028] The periodic intermittent pressure is the force frequently extruded by the fluidization assembly.

[0029] The electric energy recovered by the thermoelectric generator assembly, the fluidization assembly and the pressure power generation assembly is stored in a storage battery, and then is used again.

[0030] The carbon dioxide collection and atomization dissolving device realizes the saturation of the carbon dioxide in the condensed water by gas-liquid separation mixing, and realizes high-ratio adsorption by atomization to increase the unit mass surface area of the droplets; in the carbon dioxide collection and atomization dissolving device, one way of the gas at least including the carbon dioxide in the chimney forms negative pressure through the Venturi tube, thereby driving the condensed water collected by the inner wall of the fluidization assembly to enter the closed container of the gas-liquid separation mixing together, and the gas pressure drives the condensed water to enter the liquid path of the atomization nozzle, and another way of the gas at least including the carbon dioxide enters the gas path of the atomization nozzle to mix with the liquid path of the atomization nozzle to realize the high-ratio dissolution and collection of the carbon dioxide.

[0031] The atomization nozzle is a two-phase flow atomization nozzle, and the gas path and the liquid path are used to perform the atomization process.

[0032] The negative pressure is formed due to the narrowing of the pipeline of the Venturi tube and the sudden increase of the gas flow rate, and the condensed condensed water on the inner wall of the fluidization assembly can be extracted from the side path of the Venturi tube without power consumption.

[0033] The carbon dioxide electrolysis cell device electrolyzes the captured carbon dioxide and water vapor into alcohol materials including methanol; the carbon dioxide electrolysis cell device adopts a low potential working technology, and in a solution containing a pyridine catalyst, the atomized two-phase flow of the dissolved carbon dioxide is continuously sent to the negative electrode of the carbon dioxide electrolysis cell device for electrolysis, the positive electrode generates oxygen discharge, the negative electrode generates alcohol, and the alcohol is collected.

[0034] The working voltage of the low potential working technology is several hundred millivolts, and the electric energy is derived from each power generation device.

[0035] The alcohol further includes ethylene glycol.

[0036] The pyridine catalyst does not have material loss and property change in the electrolysis process, and subsequent addition of the catalyst required for electrolysis is not required.

[0037] The carbon nanotube growth device uses the alcohol generated by the electrolysis as raw material, and grows into the solid carbon material on the carrier interface under the action of the electric energy. The solution of the carrier input into the carbon nanotube growth device is connected to the storage battery at both ends of the carrier, the Joule heat generated makes the alcohol decompose and continuously assemble into the solid carbon material on the surface of the carrier to obtain the product; the mechanical energy required by the movement and winding of the carrier is provided by the crank connecting rod.

[0038] The power of the electric energy is in the range of 20-40 W, which belongs to low power.

[0039] The Fe catalyst needs to be supplemented periodically, which belongs to consumables.

[0040] The mechanical energy pulls the carrier at a stable speed, which helps to produce the product with good quality.

[0041] The device also comprises a reinforcement module for slowing down the corrosion of the chimney and facilitating the smooth emission of pollutants; the reinforcement module comprises a reinforced convection component and a turbulent flow consumption component.

[0042] The reinforced convection component generates high flow rate in the chimney based on the "chimney effect" to quickly discharge pollutants. At the same time, the reinforced convection component can generate a large temperature difference, so that the water vapor is quickly condensed and quickly discharged from the chimney, preventing corrosion, and the remaining water vapor in the flue gas is utilized by the carbon dioxide electrolytic cell component; in addition, through the high flow rate of the flue gas, high-frequency oscillation of the fluidization component and improvement of the power generation performance of the pressure power generation component can be realized.

[0043] The "chimney effect" is that the gas pressure is low at the middle and low positions of the chimney, and if the ambient air is connected in communication, the ambient air will be immediately sucked into the chimney due to the effect of density difference, and the mixed gas will quickly diffuse or be discharged from the chimney, so that it flows out of the outlet at a high flow rate.

[0044] The corrosion is due to the high water vapor content in the chimney and the electrochemical reaction formed by the dissolution of acidic gas in the condensed water in the flue gas.

[0045] The turbulent flow consumption component makes the gas experience a series of small-scale turbulent flow generation areas before the outlet of the chimney, so as to disperse and weaken the large turbulent flow, thereby reducing the overall turbulent flow intensity at the outlet and weakening the backflow inhibition of outflow, which helps to smoothly discharge the flue gas.

[0046] The large turbulent flow is formed by the high flow rate, and the large turbulent flow generates backflow at the outlet, thereby further inhibiting the normal flow rate at the outlet and inhibiting the normal emission of pollutants.

[0047] The control module is mainly used for coordinated control and optimization of the low-temperature waste energy recovery and carbon sequestration device. The circuit control component is used to generate, stabilize and collect current; the integrated control component uses a single-chip microcomputer to realize regulation and control of the carbon sequestration module and stable replenishment.

[0048] In the embodiment of the present application, the waste heat in the chimney, fluidization energy and wind energy are recovered by the thermoelectric generation assembly, the pressure generation assembly and the fluidization assembly, which can effectively convert the waste heat and energy into the electric energy independently, differentially and modularly; the wind energy in the chimney is converted into mechanical energy by the crank linkage; the carbon dioxide is collected by the carbon dioxide collection and atomization dissolving device, and the carbon dioxide is dissolved in the collected condensed water by the atomization technology; the alcohol and oxygen are prepared by the low potential electrolysis of the two-phase flow of the above-mentioned condensed water and carbon dioxide; the alcohol is further pyrolyzed at low power by the carbon nanotube growth device, and the solid carbon material is assembled on the carrier interface to finally prepare the product; the pyrolysis process utilizes differential energy to generate a larger temperature near the carrier; the recovered electric energy is more than the total energy of the electrolysis and the pyrolysis, and the entire device can work independently with self-production and self-sale; the entire device is modularly designed, which is convenient to install and replace the modules, and can assemble different modules according to the characteristics of the chimney and realize the functional customization of the product; the embodiment of the present application solves the problems of low-quality energy recovery and low-cost carbon sequestration in the prior art. BRIEF DESCRIPTION OF DRAWINGS

[0049] In order to more clearly illustrate the technical solutions of the embodiments of the present application, the following will briefly introduce the drawings needed to be used in the description of the embodiments of the present application. Obviously, the drawings in the following description are only some embodiments of the present application, and other drawings can be obtained by those skilled in the art without creative labor.

[0050] Fig. 1 FIG. 1 shows the connection relationship between the carbon sequestration module and the energy recovery module in the low-temperature waste energy recovery and carbon sequestration device provided by the embodiment of the present application;

[0051] Fig. 2 FIG. 2 shows the structural design of the low-temperature waste energy recovery and carbon sequestration device provided by the embodiment of the present application.

[0052] Explanation of reference signs:

[0053] 1, a low-temperature waste energy recovery and carbon sequestration device; 2, a strengthening module; 21, a strengthened convection assembly; 22, a turbulent flow consumption assembly; 3, a carbon sequestration module; 31, a carbon dioxide collection and atomization dissolving assembly; 32, a carbon dioxide electrolytic cell assembly; 33, a carbon nanotube growth assembly; 4, an energy recovery module; 41, a thermoelectric generation assembly; 42, a pressure generation assembly; 43, a fluidization assembly; 5, a control module; 51, a circuit control assembly; 52, an integrated control assembly; 6, a solid carbon material; 7, a carrier; 8, oxygen; 9, a product. DETAILED DESCRIPTION

[0054] The technical solutions in the embodiments of the present application will be described clearly and completely below with reference to the drawings in the embodiments of the present application. Obviously, the described embodiments are only part of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in the present application, all other embodiments obtained by a person of ordinary skill in the art without creative effort belong to the scope of protection of the present application.

[0055] It should be understood that the terms "one embodiment" or "an embodiment" as used throughout this specification mean that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment of the present application. Therefore, the appearance of the phrase "in one embodiment" or "in an embodiment" in various places throughout the specification is not necessarily referring to the same embodiment. Furthermore, the particular features, structures, or characteristics can be combined in any suitable manner in one or more embodiments.

[0056] Referring to Figs. 1-2 The embodiment of the present application provides a low-temperature waste energy recovery and carbon fixation device for waste energy recovery and carbon fixation, which comprises an energy recovery module (4), a carbon fixation module (3), a strengthening module (2) and a control module (5). The energy recovery module (4) provides the carbon fixation module (3) and the control module (5) with the required electric energy and mechanical energy for work. The carbon fixation module (3) fixes the carbon dioxide in the chimney into solid carbon material (6). The strengthening module (2) is used to slow down the corrosion of the chimney and help the smooth emission of pollutants. The control module (5) is used to coordinate the work of the energy recovery module (4), the carbon fixation module (3) and the strengthening module (2).

[0057] The energy recovery module (4) recovers waste heat and energy through a thermoelectric power generation assembly (41), a fluidization assembly (43), a pressure power generation assembly (42) and a crank connecting rod (10), and then converts the waste heat and energy into electric energy. The carbon fixation module (3) is used to collect and electrolyze the carbon dioxide into alcohol at a low potential, and pyrolyze the alcohol into the solid carbon material (6) at a low power. The carrier (7) is used to prepare a product (9). The solid carbon material (6) comprises at least one of carbon nanotubes or graphene. The embodiment of the present application solves the problem of difficult low-quality waste energy recovery and low-cost carbon fixation in the prior art.

[0058] In the embodiment of the present application, the waste heat in the chimney, fluidization energy and wind energy are recovered by the temperature difference power generation assembly, pressure power generation assembly and fluidization assembly, which can effectively convert the waste heat and energy into electric energy; the wind energy in the chimney is recovered by the crank connecting rod, which can effectively convert the wind energy into mechanical energy; the carbon dioxide is collected by the carbon dioxide collection and atomization dissolving device, and the carbon dioxide is dissolved in the collected condensed water by the atomization technology; the alcohol and oxygen are prepared by the low potential electrolysis of the two-phase flow of the above-mentioned condensed water and carbon dioxide; the alcohol is further pyrolyzed at low power by the carbon nanotube growth device, and the solid carbon material is assembled on the carrier interface to finally prepare the product; the pyrolysis process uses differential energy, which can generate a larger temperature near the carrier; the recovered electric energy is more than the total energy of the electrolysis and pyrolysis, and the whole device can work independently; the whole device is modularized, which is easy to install and replace the modules, and different modules can be assembled according to the characteristics of the chimney to realize the functional customization of the product; the embodiment of the present application solves the problems of low-quality energy recovery and low-cost carbon sequestration in the prior art, realizes the full utilization of energy in the chimney, reduces carbon emissions, and achieves benefits.

[0059] The atomization technology at least includes two-phase flow atomization.

[0060] It should be noted that the power generation of the energy recovery module is coordinated with the power consumption of the carbon sequestration module and the control module, which can realize the effect of energy self-production and self-sale, independent system operation, without external power, and the power generation of the energy recovery module will be more, and the excess electric energy is used for night lighting in the factory.

[0061] Preferably, the embodiment of the present application realizes temperature difference power generation by the thermoelectric effect of the temperature difference power generation assembly (41), especially the "Seebeck effect", and realizes the conversion of heat energy to electric energy by the thermocouple or thermoelectric module.

[0062] It should be noted that the temperature difference power generation assembly (41) is based on medium and low temperature waste energy, generates a certain temperature difference by the convection heat exchange between the low-quality waste heat in the chimney (1) and the ambient air outside the chimney, and then drives the temperature difference power generation assembly (41) to generate power continuously, which is not affected by day and night.

[0063] It should be noted that the temperature difference power generation assembly (41) can generate 0~5 W of power generation, and the current can be amplified by reasonably connecting multiple thermocouples or thermoelectric modules in series and in parallel, to realize optimal current collection.

[0064] It is to be noted that the thermoelectric power assembly (41) not only includes the outer wall directly attached to the bottom end of the chimney (1) and the heat exchanger for transferring the heat in the chimney (1) to the outer wall and the external environment air to generate temperature difference, but also includes the device for introducing the flue gas into the thermoelectric power assembly (41) for heat exchange.

[0065] Preferably, the wind power generation is realized by means of the fluidization assembly (43).

[0066] It is to be noted that the fluidization assembly (43) realizes the conversion of the high-speed flow in the chimney (1) into the electric energy based on the principle of electromagnetic induction and aerodynamics.

[0067] It is to be noted that the fluidization assembly (43) generates up-and-down reciprocating motion by means of fluidization effect, and condenses and captures the water vapor into condensed water by the inner wall, thereby providing the water source required for the operation of the carbon dioxide electrolytic cell assembly (32).

[0068] It is to be noted that the pressure relief port is arranged on the side wall of the fluidization assembly (43), and the flue gas flows out from the pressure relief port after driving the fluidization assembly (43) to move, and the wind energy is collected by the wind power generation at the position of the pressure relief port.

[0069] It is to be noted that the fluidization assembly (43) can also convert mechanical energy, convert the up-and-down reciprocating linear motion of the fluidization assembly (43) into circular motion, and provide the mechanical energy for the movement of the carrier; the unit for converting the mechanical energy is a crank and connecting rod structure; at least two groups of the fluidization assembly (43) are adopted to realize the alternate reciprocating rotation of the movement, thereby realizing the stable output of the mechanical energy through regulation and control, and providing the continuous mechanical energy for the preparation of the product (9).

[0070] It is to be noted that the inner wall of the fluidization assembly (43) is made of condensation material, which can condense the water vapor into the condensed water on the surface of the condensation material.

[0071] It is to be noted that the shape of the fluidization assembly (43) is a cylinder / rectangular prism with a lower opening, and the lower opening surface is an inclined surface, which is helpful for the fixed-point collection of the condensed water.

[0072] It is to be noted that the fixed-point collection is that the condensed water is collected to the low side of the lower opening surface, and then collected.

[0073] Preferably, the pressure power assembly (42) cooperates with the fluidization assembly (43) to generate periodic intermittent pressure, so as to realize the piezoelectric power generation process by means of the positive pressure electric effect.

[0074] Need to explain, the pressure power generation assembly (42) by the impact block extrusion piezoelectric ceramic power generation, compared to single piece can achieve several times amplification effect, the current is larger.

[0075] Need to explain, the pressure power generation assembly (42) is located on the fluidization assembly (43), the up and down movement energy of the fluidization assembly (43), extrusion the pressure power generation assembly (42) power generation.

[0076] Preferably, the thermoelectric power generation assembly (41), the fluidization assembly (43) and the pressure power generation assembly (42) recycle the electric energy stored in the battery, and then be used.

[0077] Preferably, the carbon dioxide collection and atomization dissolution assembly (31) is realized by gas-liquid separation mixing to dissolve the carbon dioxide in the condensed water, and the atomization increases the unit mass surface area of the droplet to realize high rate adsorption.

[0078] Need to explain, in the carbon dioxide collection and atomization dissolution assembly (31), the chimney (1) includes the gas including the carbon dioxide through the venturi to form negative pressure, and then drive the condensed water collected on the inner wall to enter the gas-liquid separation closed container together, the gas pressure drives the condensed water to enter the liquid path of the atomization nozzle, and the other way includes the gas including the carbon dioxide enters the gas path of the atomization nozzle and mixes with the liquid path of the atomization nozzle to realize the high rate dissolution of the carbon dioxide.

[0079] Need to explain, the gas-liquid separation closed container can enter the gas including the carbon dioxide and the condensed water together, and use the pressure difference of the gas including the carbon dioxide to only extrude the condensed water out of the gas-liquid separation closed container.

[0080] Need to explain, the structure of the gas-liquid separation closed container is short pipe in and long pipe out.

[0081] Preferably, the carbon dioxide electrolytic cell assembly (32) inputs the captured carbon dioxide and water vapor into the electrolytic cell to electrolyze into the alcohol material including methanol.

[0082] Need to explain, the carbon dioxide electrolytic cell assembly (32) adopts low potential working technology, in the solution containing pyridine catalyst, the atomized two-phase flow of the dissolved carbon dioxide is continuously sent to the negative electrode of the carbon dioxide electrolytic cell assembly (32) by pipeline for electrolysis, the positive electrode produces oxygen discharge, the negative electrode produces alcohol, and the alcohol is collected.

[0083] Preferably, the carbon nanotube growth assembly (33) uses the alcohol produced by electrolysis as raw material, and grows into the solid carbon material (6) on the interface of the carrier (7) under the action of the electric energy.

[0084] It should be noted that the solution of the carrier (7) is input into the carbon nanotube growth assembly (33), and the both ends of the carrier (7) are connected to a storage battery, respectively. The joule heat generated makes the alcohol decompose and continuously assemble into the solid carbon material (6) on the surface of the carrier (7), so as to obtain the product (9).

[0085] It should be noted that the mechanical energy required for the movement of the carrier (7) is provided by the crank linkage, which smoothly pulls the carrier (7) so that the surface of the carrier (7) is uniformly attached with the solid carbon material (6), and the pulled product is timely wound into a roll.

[0086] It should be noted that the mechanical energy is recycled from the crank linkage, and the energy during the movement of the carrier (7) is transmitted by the gear and the conveyor belt.

[0087] It should be noted that the solution contains a Fe catalyst, at least including ferric nitrate, and the solution is the alcohol.

[0088] It should be noted that the alcohol is collected into the carbon nanotube growth assembly (33) through a molecular film, the molecular film selectively permeates substances of different particle sizes, and the particle size of the Fe catalyst is obviously larger than that of the alcohol, so the molecular film can selectively collect alcohol.

[0089] The low-temperature waste heat recovery and carbon sequestration device further comprises a strengthening module (2), which is used for slowing down the corrosion of the chimney and helping the smooth emission of pollutants; the strengthening module (2) comprises a strengthened convection assembly (21) and a turbulent flow consumption assembly (22).

[0090] The strengthened convection assembly (21) generates high flow rate in the chimney (1) based on the "chimney effect" to quickly discharge pollutants.

[0091] It should be noted that the strengthened convection assembly (21) can generate a large temperature difference, so that the water vapor is rapidly condensed and discharged from the chimney (1) quickly, preventing corrosion.

[0092] It should be noted that the remaining water vapor in the flue gas is utilized by the carbon dioxide electrolysis cell assembly (32).

[0093] It should be noted that, by the high flow rate of the flue gas, the high-frequency oscillation of the fluidization assembly (43) and the performance improvement of the pressure power generation assembly (42) can be realized.

[0094] Preferably, the turbulent flow consumption component (22) makes the gas experience a series of small-scale turbulent flow generation areas before the outlet of the chimney (1) to disperse and weaken the large turbulence, thereby reducing the overall turbulence intensity at the outlet and weakening the backflow inhibition outflow, helping the smooth discharge of the flue gas.

[0095] Preferably, the control module (5) is mainly used for coordinated control and optimization of the low-medium temperature waste energy recovery carbon sequestration device, including a circuit control component (51) and an integrated control component (52).

[0096] It should be noted that the circuit control component (51) is used to generate, stabilize and collect current.

[0097] It should be noted that the integrated control component (52) uses a single-chip microcomputer to realize regulation and stable replenishment of the carbon sequestration module (3).

[0098] It should be noted that the single-chip microcomputer includes a 51 single-chip microcomputer, a 32 single-chip microcomputer and a terminal capable of running calculations.

[0099] The working process of the device is as follows: first, the waste heat, wind energy and fluidization energy in the chimney are recovered by the thermoelectric generation component (41), the fluidization component (43) and the pressure power generation component (42) to generate the electric energy, which is stored in the battery; in addition, the fluidization component (43) recovers the fluidization energy in the chimney to generate the mechanical energy, and captures the water vapor in the chimney to generate condensed water; further, the carbon dioxide collection and atomization dissolution component (31) captures carbon dioxide; and under the supply of the electric energy, the carbon dioxide and the condensed water are electrolyzed at a low potential in the carbon dioxide electrolysis tank component (32) to generate alcohol and oxygen, the alcohol is filtered through a molecular membrane to the carbon nanotube growth component (33), the alcohol is pyrolyzed at a low power to generate the solid carbon material (6), which is uniformly attached to the interface of the moving carrier (7) through the electric energy, thereby preparing the product (9), and the moving carrier comes from the pulling of the mechanical energy.

[0100] It should be noted that in this document, the terms "comprise", "comprise", or any other variant thereof are intended to cover non-exclusive inclusion, so that processes, methods, articles or devices including a series of elements not only include those elements, but also include other elements not explicitly listed, or include elements inherent to such processes, methods, articles or devices. Without more limitations, the element defined by the statement "comprises a" does not exclude the presence of additional identical elements in the process, method, article or device including the element.

[0101] Those skilled in the art can clearly understand the above-mentioned embodiment method can be realized by means of software and necessary general hardware platform, of course, also can be realized by hardware, but in many cases, the former is a better embodiment. Based on such understanding, the technical solutions of the present application essentially or say the part of prior art contribution can be embodied in the form of software product, the computer software product is stored in a storage medium (such as ROM / RAM, disk, optical disk), including a number of instructions to make a terminal (may be a mobile phone, computer, server, air conditioner, or network equipment, etc.) executes the method described in various embodiments of the present application.

[0102] The embodiments of the present application are described above in conjunction with the drawings, but the present application is not limited to the above-mentioned specific embodiments, the above-mentioned specific embodiments are only illustrative, but not limited, those skilled in the art can make many forms under the inspiration of the present application without departing from the purpose of the present application and the scope protected by the claims, all of which belong to the protection of the present application.

Claims

1. A medium-low temperature waste heat recovery and carbon sequestration device, characterized in that, The chimney waste energy recovery, carbon sequestration, at least including energy recovery module (4), carbon sequestration module (3) and control module (5); the energy recovery module (4) and the carbon sequestration module (3) are connected; The energy recovery module (4) provides the required electric energy for the carbon sequestration module (3) and the control module (5); The carbon sequestration module (3) is used for converting carbon dioxide in the chimney (1) into solid carbon material (6); The control module (5) is connected with the energy recovery module (4) and the carbon sequestration module (3) respectively, and controls the cooperative work of the energy recovery module (4) and the carbon sequestration module (3); The energy recovery module (4) recovers waste heat and energy through the thermoelectric power generation assembly (41), the fluidization assembly (43) and the pressure power generation assembly (42), and then converts into the electric energy; the carbon sequestration module (3) is used to collect and electrolyze the carbon dioxide into alcohol at low potential, and then pyrolyze the alcohol into the solid carbon material (6) on the moving carrier at low power; The carrier at least includes at least one of continuous carbon fiber and metal wire; The solid carbon material (6) includes at least one of carbon nanotube and graphene; The carbon dioxide collection and atomization dissolution assembly (31) realizes the saturation of the carbon dioxide dissolution in the condensed water through gas-liquid separation mixing, realizes high rate adsorption through atomization to increase the unit mass surface area of liquid drops; the carbon dioxide collection and atomization dissolution assembly (31) at least includes two paths; in the carbon dioxide collection and atomization dissolution assembly (31), one path at least includes that the carbon dioxide gas in the chimney (1) forms negative pressure through a venturi tube, and then the condensed water collected on the inner wall of the fluidization assembly (43) is sucked into the closed container of the gas-liquid separation mixing together, the gas pressure drives the condensed water into the liquid path of the atomization nozzle, and the other path at least includes that the carbon dioxide gas enters the gas path of the atomization nozzle and mixes with the liquid path of the atomization nozzle to realize the high rate dissolution collection of the carbon dioxide; The carbon dioxide electrolytic cell assembly (32) inputs the captured carbon dioxide and water vapor into the electrolytic cell to be electrolyzed into alcohol materials including methanol; the carbon dioxide electrolytic cell assembly (32) adopts low potential working technology, and the atomized two-phase flow of the dissolved carbon dioxide is continuously sent to the negative electrode of the carbon dioxide electrolytic cell assembly (32) through a pipeline for electrolysis in a solution containing a pyridine catalyst, oxygen is generated at the positive electrode and discharged, alcohol is generated at the negative electrode, and the alcohol is collected; The carbon nanotube growth assembly (33) uses the alcohol generated by the above electrolysis as raw material to grow into the solid carbon material (6) on the carrier (7) interface under the action of the electric energy; the carrier (7) is input into the carbon nanotube growth assembly (33), the battery is connected to both ends of the carrier (7), the generated Joule heat makes the alcohol decompose and continuously assemble into the solid carbon material (6) on the surface of the carrier (7).

2. The low-medium temperature waste energy recovery and carbon sequestration device according to claim 1, wherein, The thermoelectric power generation assembly (41) realizes thermoelectric power generation based on thermoelectric effect, and realizes the conversion from heat energy to electric energy through thermocouple or thermoelectric module.

3. The low-medium temperature waste energy recovery and carbon sequestration device of claim 1, wherein, The wind power generation is realized by means of the fluidization assembly (43); the fluidization assembly (43) realizes the conversion of high-speed flow in the chimney (1) into electric energy based on electromagnetic induction and aerodynamic principle; The fluidization assembly (43) generates up-and-down reciprocating motion by means of fluidization effect, and condenses and captures water vapor into condensed water by means of inner wall, thereby providing water source required by the carbon dioxide electrolytic cell assembly (32) to work; a pressure relief port is arranged on the side wall of the fluidization assembly (43), and the fluidization assembly (43) is driven by gas wind energy. The fluidization assembly (43) converts mechanical energy, converts the up-and-down reciprocating linear motion of the fluidization assembly (43) into circular motion, and provides the mechanical energy for the movement of the carrier; the unit for converting mechanical energy is a crank connecting rod structure; at least two groups of the movement of the fluidization assembly (43) are adopted to alternately and reciprocally supplement the rotary motion, and then the stable output of the mechanical energy is realized through regulation and control, thereby providing the continuous mechanical energy for the preparation of the product (9).

4. The low-medium temperature waste energy recovery and carbon sequestration device of claim 1, wherein, The pressure power generation assembly (42) cooperates with the fluidization assembly (43) to generate periodic intermittent pressure, and realizes the piezoelectric power generation process by means of positive pressure electric effect; the pressure power generation assembly (42) extrudes at least two pieces of piezoelectric ceramic power generation by means of an impact block. The electric energy recovered by the thermoelectric power generation assembly (41), the fluidization assembly (43) and the pressure power generation assembly (42) is stored in a storage battery, and then is used again.

5. The low-medium temperature waste energy recovery and carbon sequestration device of claim 1, wherein, The device further comprises a strengthening module (2) for slowing down chimney corrosion and helping the smooth emission of pollutants.

6. The low-medium temperature waste energy recovery and carbon sequestration device of claim 5, wherein, The strengthening module (2) comprises a strengthened convection assembly (21) and a turbulent flow consumption assembly (22); The strengthened convection assembly (21) generates high flow rate in the chimney (1) to quickly emit pollutants based on the "chimney effect"; at the same time, the strengthened convection assembly (21) can generate large temperature difference, so that water vapor is rapidly condensed and quickly discharged from the chimney (1), thereby preventing corrosion; the remaining water vapor in the flue gas is utilized by the carbon dioxide electrolytic cell assembly (32); in addition, the high flow rate of the flue gas can realize high-frequency oscillation of the fluidization assembly (43) and improve the power generation performance of the pressure power generation assembly (42); The turbulent flow consumption assembly (22) makes the gas experience a series of small-scale turbulent flow generation areas before the outlet of the chimney (1), so as to disperse and weaken the large turbulent flow, thereby reducing the overall turbulent flow intensity at the outlet and weakening the backflow inhibition flow-out effect, and helping the smooth emission of the flue gas.

7. The low-medium temperature waste energy recovery and carbon sequestration device of claim 1, wherein, The control module (5) is mainly used for coordinated control and optimization of the one kind of low-temperature waste energy recovery carbon fixation device; the circuit control assembly (51) is used for generating, stabilizing and collecting current; the integrated control assembly (52) realizes regulation and control of the carbon fixation module (3) and stable supplement by means of a single-chip microcomputer.

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