Carbon fibers, ceramic matrix composites, and methods and apparatus for making same
Through layer-by-layer deposition systems and equipment, multi-layer coating is used to utilize the opposite polarity of ion charges of nanoparticles, which solves the problems of coating inhomogeneity and high manufacturing cost, and achieves efficient and uniform nanoparticle coating production. Improves strength consistency of composite materials.
Patent Information
- Application Number
- CN202410553218.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2023-06-13
- Filing Date
- 2024-05-07
- Publication Date
- 2024-12-13
AI Technical Summary
The prior art When manufacturing coated fiber materials, the coating is uneven and manufacturing costs are high, especially the pyrolytic carbon (pyC) coating cannot be applied continuously, limiting the fiber length and strength variability of the composite material.
Using layer by layer (LBL) deposition system and equipment, fiber material is coated layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer by layer Coating reduces manufacturing costs and achieves continuous coating.
The uniformity and efficient production of multi-layer fiber materials coated with nanoparticles are achieved, reducing manufacturing costs, avoiding the demand for special equipment and controlled conditions, and improving the strength consistency of composite materials.
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Figure CN119114399A_ABST
Abstract
Description
Technical Field
[0001] The present disclosure relates generally to coated materials, and more particularly to methods and apparatus for making multi-layered nanoparticle-coated fiber materials. Background Art
[0002] Materials comprising one or more coating layers, such as coated fibers, manufactured by known manufacturing methods are susceptible to one or more coating layer non-uniformities.
[0003] For example, pyrolytic carbon (pyC) coatings on fibers are prone to one or more coating non-uniformities, resulting in variable composite strength when the coated fibers are combined with a ceramic matrix to make a ceramic matrix composite (CMC). The purpose of the pyC coating in a CMC is to create a weak interface between the matrix and the fibers to allow the fibers to move relative to the matrix under certain loads, thereby allowing the composite to deform and carry more loads than would be possible with a strong fiber-matrix interface.
[0004] Furthermore, the pyC coating needs to be applied using chemical vapor deposition (CVD), which requires specialized equipment and controlled temperature and pressure.
[0005] However, another disadvantage of pyC coatings is that these coatings cannot be applied continuously. Batch processing must be used, which means that the length of the fiber that can be coated is limited by the size of the CVD chamber.
[0006] The result is higher manufacturing costs and the inability to continuously coat fibers when CVD is used to apply the pyC coating on fibers that are subsequently combined with a ceramic matrix to make a CMC.
[0007]
[0006] Despite the progress that has been made, those skilled in the art continue to conduct research and development work in the field of making coated materials, such as coated fiber materials used in making CMCs. Summary of the invention
[0008] A method for making multi-layered nanoparticle-coated fibers is disclosed.
[0009] In one example, the disclosed manufacturing method includes: coating a fiber substrate with a first type of nanoparticles to provide a first coating layer of a multi-layered fiber material coated with nanoparticles. The manufacturing also includes: coating the first coating layer with a second type of nanoparticles to provide a second coating layer of a multi-layered fiber material coated with nanoparticles.
[0010] In another example, the disclosed manufacturing method includes treating the surface of each of the plurality of fibers to impart an ionic charge polarity to the surface. Manufacturing also includes: coating the surface of each of the plurality of fibers with nanoparticles having an ionic charge polarity opposite to the ionic charge polarity of the surface of each of the plurality of fibers to provide a first layer of a plurality of fibers coated with nanoparticles in multiple layers. Manufacturing also includes: coating the first layer with nanoparticles having an ionic charge polarity opposite to the ionic charge polarity of the first layer to provide a second layer of a plurality of fibers coated with nanoparticles in multiple layers.
[0011] Also disclosed is a carbon fiber and ceramic matrix composite material prepared according to the manufacturing method.
[0012] Also disclosed is a manufacturing apparatus for multi-layer, nanoparticle-coated fiber materials.
[0013] In one example, the manufacturing apparatus includes a first coating container containing a first nanoparticle-based solution through which a substrate can pass to impart a first coating of nanoparticles to the substrate. The manufacturing apparatus also includes a second coating container containing a second nanoparticle-based solution through which a substrate having a first coating of nanoparticles can pass to impart a second coating of nanoparticles to the substrate coated with the first coating of nanoparticles and thereby provide a multilayered fiber material coated with nanoparticles.
[0014] Other examples of the disclosed manufacturing methods and apparatus will become apparent from the following detailed description, the accompanying drawings, and the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS
[0015] Figure 1 is a schematic block diagram of a layer-by-layer (LBL) deposition system including a manufacturing apparatus for multi-layered nanoparticle-coated fiber materials.
[0016] Figure 2A is constructed according to an exemplary implementation Figure 1 Schematic diagram of the manufacturing equipment.
[0017] Figure 2B It is shown Figure 2A Schematic diagram of an exemplary relationship between a coating container and a cleaning container of a manufacturing apparatus.
[0018] Figure 2C yes Figure 2A Schematic diagram of an exemplary minimum size production line apparatus for manufacturing equipment.
[0019] Figure 2D is available in Figure 2A An exemplary post-processing device for use after manufacturing equipment.
[0020] Figure 3A is a schematic elevation view of different layers of a fabricated multi-layer nanoparticle-coated fiber material.
[0021] Figure 3B is a schematic elevation view of different layers of another fabricated multi-layer nanoparticle-coated fiber material.
[0022] Figure 4 is a flow chart depicting a manufacturing method according to an exemplary implementation.
[0023] Figure 5 is a flow chart depicting a manufacturing method according to another exemplary implementation.
[0024] Figure 6 It is a block diagram of the aircraft production and maintenance methods.
[0025] Figure 7 It is a schematic diagram of the aircraft. DETAILED DESCRIPTION
[0026] The present application relates to manufacturing apparatus and methods using layer-by-layer (LBL) deposition systems. Therefore, the specific structure of the apparatus and methods and the industry in which the apparatus and methods are implemented can vary. It should be understood that the following disclosure provides multiple embodiments or examples for implementing the different features of various embodiments. Specific examples of components and arrangements are described to simplify the present disclosure. These are merely examples and are not restrictive.
[0027] By way of example, the following disclosure describes a multilayer nanoparticle coated fiber material manufacturing apparatus and method for use in manufacturing aerospace components. The apparatus and method may be implemented by original equipment manufacturers (OEMs) in accordance with military and space regulations. It is contemplated that the disclosed apparatus and method may be implemented in many other industries.
[0028] refer to Figure 1 , a schematic block diagram of a layer-by-layer deposition system 10 is shown. The layer-by-layer deposition system 10 includes an apparatus 100 for manufacturing multiple layers of nanoparticle-coated fiber materials and constructed according to an exemplary implementation. Exemplary fiber materials include carbon fiber materials. Other types of fiber materials are also possible.
[0029] refer to Figure 2A, a schematic diagram of a manufacturing apparatus 100 is shown. The manufacturing apparatus 100 includes a first coating container 110 containing a first nanoparticle-based solution 112, through which a fiber substrate 102 (e.g., a carbon fiber material) can be passed along a path 104 (e.g., a fiber production line or a fiber handling path using roll-to-roll processing) to apply a first coating 114 of nanoparticles to the fiber substrate 102, thereby providing a first coated substrate 116. In other words, the fiber substrate 102 is imparted with a first coating 114 of nanoparticles to form a monolayer of the first coating 114 of nanoparticles. The fiber substrate 102 has an ionic charge polarity (i.e., a cationic charge or an anionic charge) and can be treated (e.g., acid or alkaline washing, or plasma) to impart such an ionic charge. The nanoparticles contained in the first coating container 110 have an ionic charge polarity opposite to the ionic charge polarity of the fiber substrate 102. The nanoparticles contained in the first coating container 110 can be selected from graphene, BN, SiN, TiC, TiO2, and combinations and mixtures thereof. Other types of nanoparticle materials are also possible. The first nanoparticle-based solution 112 includes a polymer that acts as a carrier for the nanoparticles contained in the first coating container 110 .
[0030] The manufacturing apparatus 100 also includes a first cleaning vessel 120 containing a cleaning solution 122 (e.g., an aqueous solution) that is used to clean the first coated substrate 116 to provide a first cleaned coated substrate 124, and then to dry the first cleaned coated substrate 124. Drying can be performed under ambient conditions or at an elevated temperature. Figure 2B An exemplary relationship between the first coating container 110 and the first cleaning container 120 is shown in FIG. 1 , wherein a plurality of rollers 125 are used to provide a production line type apparatus.
[0031] More specifically, the first cleaning container 120 contains a solution free of nanoparticles through which the fibrous substrate 102 having the first coating 114 of nanoparticles can be passed to remove excess nanoparticles from the first coating 114 of nanoparticles on the fibrous substrate 102, thereby leaving only those nanoparticles adhered to the fibrous substrate 102. The first cleaned coated substrate 124 forms a monolayer of the first coating 114 of nanoparticles. The monolayer of the first coating 114 of nanoparticles has a thickness of about 5 nanometers to about 1000 nanometers, such as a thickness of about 100 nanometers to about 500 nanometers, or a thickness of about 200 nanometers to about 400 nanometers.
[0032] The manufacturing apparatus 100 also includes a second coating container 130 containing a second nanoparticle-based solution 132 through which the first cleaned coated substrate 124 can pass to apply a second coating 134 of nanoparticles to the first cleaned coated substrate 124, thereby providing a second coated substrate 136. The nanoparticles contained in the second coating container 130 have an ionic charge polarity similar to the ionic charge polarity of the fiber substrate 102 (e.g., carbon fiber), and therefore have an ionic charge polarity opposite to the ionic charge polarity of the nanoparticles contained in the first coating container 110. The nanoparticles contained in the second coating container 130 can be selected from at least one of graphene, BN, SiN, TiC, TiO2, and mixtures or combinations thereof. Other types of nanoparticle materials are also possible. The second nanoparticle-based solution 132 includes a polymer that serves as a carrier for the nanoparticles contained in the second coating container 130.
[0033] The manufacturing apparatus 100 also includes a second cleaning vessel 140 containing a cleaning solution 142 (e.g., an aqueous solution) that is used to clean the second coated substrate 136 to provide a second cleaned coated substrate 144, which is then dried (e.g., under ambient conditions or at an elevated temperature).
[0034] More specifically, the second cleaning container 140 contains a solution without second nanoparticles, through which the fibrous substrate 102 having the first coating 114 of nanoparticles and the second coating 134 of nanoparticles can be passed to remove excess particles from the second coating 134 of nanoparticles of the fibrous substrate 102 coated with the first coating 114 of nanoparticles, thereby leaving only the nanoparticles from the second coating adhered to the nanoparticles from the first coating, which adhere to the fibrous substrate 102. The second cleaned coated substrate 144 forms a monolayer of the second coating 134 of nanoparticles. The monolayer of the second coating 134 of nanoparticles has a thickness of about 5 nanometers to about 1000 nanometers, such as a thickness of about 100 nanometers to about 500 nanometers, or a thickness of about 200 nanometers to about 400 nanometers. As described above, after the fiber substrate 102 passes through the first coating container 110, the first cleaning container 120, the second coating container 130 and the second cleaning container 140, the manufactured multi-layered fiber material 150 coated with nanoparticles (i.e., the second cleaned coated substrate 144 after drying) is obtained.
[0035] refer to Figure 3A, shows a schematic elevation view of different layers of a manufactured multi-layer nanoparticle-coated fiber material 150. A single layer of a first coating 114 of nanoparticles is disposed on a fiber substrate 102 and a single layer of a second coating 134 of nanoparticles is disposed on the first coating 114 of nanoparticles. Since the single layer of the first coating 114 of nanoparticles has an ionic charge polarity opposite to that of the fiber substrate 102 and the second coating 134 of nanoparticles, strong bonding with the upper and lower layers is provided.
[0036] Although only two coating and washing cycles are described above, the process can be repeated as many times as necessary to achieve the desired number of deposited layers of fiber material or fiber material fabric, the desired coating density and / or workability. Figure 2A , the manufacturing apparatus 100 may further include a third coating container 160 containing a third nanoparticle-based solution 162, through which the second cleaned coated substrate 144 can pass to apply a third coating 164 of nanoparticles to the second cleaned coated substrate 144, thereby providing a third coated substrate 166. The manufacturing apparatus 100 also includes a third cleaning container 170 containing a cleaning solution 172 (e.g., an aqueous solution), which is used to clean the third coated substrate 166 to provide a third cleaned coated substrate 174, and then dry the third cleaned coated substrate 174. The dried third cleaned coated substrate 174 includes a thicker multi-layered fiber material 152 coated with nanoparticles. As shown in FIG. Figure 3B As shown, the thicker multi-layer nanoparticle-coated fiber material 152 has another single layer of nanoparticles (i.e., a third coating 164 of nanoparticles) on the fiber substrate 102 in addition to the single layer of the first coating 114 of nanoparticles and the single layer of the second coating 134 of nanoparticles.
[0037] While the above description describes a production line apparatus, it is contemplated that the production path and containers may be arranged to allow multiple exposures of the fibers to the same nanoparticle solution or the same cleaning solution to minimize the number of solution containers and cleaning containers required, thereby minimizing the size of the apparatus. Figure 2C An exemplary minimum size production line arrangement is shown in FIG. Figure 2C As shown, the first coating container 110, the first cleaning container 120, the second coating container 130 and the second cleaning container 140 are arranged in a circular production line device, which can be repeated as many times as needed. In addition, excess nanoparticles contained in the cleaning container can be removed and recycled to minimize costs.
[0038] It should be clear that the layer-by-layer deposition system is arranged to apply multiple nanoparticle coating layers to the fiber to produce a desired interfacial coating between the layers. For example, the coating may include a high temperature material (e.g., graphene nanosheets) to produce a desired weak interfacial coating when the fiber is coupled to a ceramic matrix to form a ceramic matrix composite.
[0039] Due to the particle shape and charge, each coating is self-assembled and deposited individually on the previous coating. The number of coating depositions can be repeated as many times as desired or required, such as three or five times. Other numbers of coatings are also possible. Each coating is also substantially uniform throughout the thickness to provide substantially uniform strength with low variability along the length of each layer.
[0040] like Figure 3A and Figure 3B As shown, the multi-layered fiber material coated with nanoparticles manufactured according to the present disclosure can be subjected to post-processing for subsequent use. Post-processing may include exposure to heat, ultraviolet light or other means to modify the coating so as to have more ideal handling properties or more ideal use properties than untreated fiber materials. For example, the manufactured multi-layered fiber material 150, 152 coated with nanoparticles can be placed on a creel to produce a fabric including fibers coated with nanoparticles. For another example, the manufactured multi-layered fiber material 150, 152 coated with nanoparticles can be used as a reinforcing material in a ceramic matrix to manufacture a composite material. The post-processing equipment can be located at the end of a fiber production line, such as Figure 2A as shown, or located away from the fiber production line.
[0041] See also Figure 2D , showing that Figure 2A An exemplary post-processing device 180 for use after manufacturing the apparatus 100. In block 182, Figure 3A or Figure 3B The manufactured multi-layered nanoparticle-coated fiber material 150, 152 is formed into a desired component shape before being subjected to a pyrolysis process in box 184. Then, in box 186, as many cycles of chemical vapor infiltration / chemical vapor deposition (CVI / CVD) processes as desired may be applied before another pyrolysis process as shown in box 188. The process of box 186 and the process of box 188 may also be repeated as many times as desired or required before a fully densified component 190 is provided by the post-processing device 180.
[0042] refer to Figure 4, a flow chart 400 of a method for manufacturing a multi-layer nanoparticle-coated fiber using layer-by-layer nanoparticle deposition according to an exemplary implementation is shown. In block 410, a fiber substrate is coated with a first type of nanoparticles to provide a first coating layer of a multi-layer nanoparticle-coated fiber material. The process proceeds to block 420, where the first coating layer is coated with a second type of nanoparticles to provide a second coating layer of a multi-layer nanoparticle-coated fiber material. The process then ends.
[0043] In some embodiments, one or both of the first type of nanoparticles and the second type of nanoparticles comprise high temperature nanoparticles. In some embodiments, the high temperature nanoparticles comprise graphene nanoparticles.
[0044] In some embodiments, the deposition is performed layer by layer in a manner that deposits the nanoparticles onto the surfaces of the fibers that make up the fabric.
[0045] In some embodiments, the layer-by-layer deposition is performed under ambient or near-ambient conditions.
[0046] In some embodiments, the manufacturing further comprises: cleaning the first coating layer to form a single layer of the first coating layer; and cleaning the second coating layer to form a single layer of the second coating layer.
[0047] In some embodiments, each of the monolayer of the first coating layer and the monolayer of the second coating layer has a thickness of about 5 nanometers to about 100 nanometers.
[0048] In some embodiments, fabricating further comprises coating the second coating layer with a third type of nanoparticles to provide a multi-layer third coating layer of nanoparticle coated material. In some embodiments, the third type of nanoparticles are the same type as the first type of nanoparticles.
[0049] In some embodiments, according to Figure 4 The disclosed manufacturing method forms carbon fibers.
[0050] refer to Figure 5 , a flow chart 500 of a manufacturing method according to another exemplary implementation is shown. In box 510, the surface of each of the plurality of fibers is treated to impart an ionic charge polarity to the surface. The process proceeds to box 520, wherein the surface of each of the plurality of fibers is coated with nanoparticles having an ionic charge polarity opposite to the ionic charge polarity of the surface of each of the plurality of fibers to provide a first layer of a plurality of fibers coated with nanoparticles in a multilayer. Then, in box 530, the first layer is coated with nanoparticles having an ionic charge polarity opposite to the ionic charge polarity of the first layer to provide a second layer of a plurality of fibers coated with nanoparticles in a multilayer. The process then ends.
[0051] In some embodiments, the fabrication further comprises: cleaning the first layer to form a monolayer of the first layer; and cleaning the second layer to form a monolayer of the second layer. Each of the monolayer of the first layer and the monolayer of the second layer has a thickness between about 5 nanometers and about 100 nanometers.
[0052] In some embodiments, manufacturing further comprises spreading the plurality of fibers to maximize the surface area that can be coated with nanoparticles.
[0053] In some embodiments, manufacturing further comprises drying each of the first layer and the second layer to modify a combination of handling and use properties of the multi-layered nanoparticle-coated plurality of fibers.
[0054] In some embodiments, according to Figure 5 The disclosed manufacturing method manufactures a ceramic matrix composite material.
[0055] Many advantages are provided by making multi-layered nanoparticle coated fiber materials as disclosed herein. One advantage is that high temperature nanoparticles can be applied to the fibers under ambient or near ambient conditions.
[0056] Another advantage is that a very dense coating of nanoparticles can be formed on the fibers.
[0057] Another advantage is that specialized (and therefore typically expensive) equipment and highly controlled conditions (eg, temperature and pressure) are not required to make the multi-layered nanoparticle-coated fibers disclosed herein.
[0058] Another advantage is that batch processing is not required, since the amount of multi-layered nanoparticle-coated fiber material can be obtained as needed along the production line device, such as Figure 2A shown.
[0059] You can Figure 6 Aircraft manufacturing and service method 1100 and the like are shown Figure 7 Examples of the present disclosure are described in the context of an aircraft 1102 as shown. During pre-production, aircraft manufacturing and service method 1100 may include specification and design 1104 of aircraft 1102 and material procurement 1106. During production, component / subassembly manufacturing 1108 and system integration 1110 of aircraft 1102 occur. Thereafter, aircraft 1102 may be certified and delivered 1112 for entry into service 1114. When entered into service by a customer, aircraft 1102 is scheduled for routine maintenance and repair 1116, which may also include modification, reconfiguration, refurbishment, etc.
[0060] like Figure 7As shown, aircraft 1102 produced by exemplary method 1100 may include airframe 1118 having plurality of systems 1120 and interior 1122. Examples of plurality of systems 1120 may include one or more of propulsion system 1124, electrical system 1126, hydraulic system 1128, and environmental system 1130. Any number of other systems may be included.
[0061] The disclosed apparatus and methods may be used during any one or more stages of the aircraft manufacturing and service method 1100. As an example, the disclosed apparatus and methods may be used to assemble components or subassemblies corresponding to component / subassembly manufacturing 1108, system integration 1110, and / or maintenance and repair 1116. As another example, airframe 1118 may be constructed using the disclosed apparatus and methods. Furthermore, during component / subassembly manufacturing 1108 and / or system integration 1110, one or more apparatus examples, method examples, or a combination thereof may be utilized, for example, by substantially speeding up assembly of the aircraft 1102 (e.g., airframe 1118 and / or interior 1122) or reducing the cost of the aircraft 1102. Similarly, one or more apparatus examples, method examples, or a combination thereof may be utilized when the aircraft 1102 is in service (e.g., but not limited to, maintenance and repair 1116).
[0062] The different examples of the devices and methods disclosed herein include various components, features, and functions. It should be understood that the various examples of the devices and methods disclosed herein may include any components, features, and functions of any other examples of the devices and methods disclosed herein in any combination, and all of these possibilities are intended to be within the scope of the present disclosure.
[0063] The above apparatus and methods are described in the context of aircraft. However, one of ordinary skill in the art will readily recognize that the disclosed apparatus and methods are applicable to a variety of applications, and the present disclosure is not limited to aircraft manufacturing applications. For example, the disclosed apparatus and methods can be implemented in various types of vehicles, including, for example, reentry aerospace vehicles, high-speed aerospace vehicles, helicopters, passenger ships, automobiles, marine products (boats, motors, etc.), etc. Non-vehicle applications are also contemplated.
[0064] Although the above description describes an apparatus and method for manufacturing multi-layered nanoparticle coated fiber materials in the aerospace industry in accordance with military and space regulations, the apparatus and method can be implemented to facilitate manufacturing multi-layered nanoparticle coated fiber materials in any industry in accordance with applicable industry standards. Specific apparatus and methods can be selected and customized according to specific applications.
[0065] In addition, although various examples of the disclosed embodiments have been shown and described, modifications may occur to those skilled in the art upon reading the specification. The present application includes such modifications and is limited only by the scope of the claims.
Claims
1. A method (400) for producing a multi-layer nanoparticle-coated fiber material (150) using a layer-by-layer nanoparticle deposition system (10), the method (400) comprising: include: coating (410) a fibrous substrate (102) with a first type of nanoparticles (114) to provide a first coating layer (116) of the multi-layer nanoparticle-coated fibrous material (150); and The first coating layer (116) is coated (420) with a second type of nanoparticles (134) to provide a second coating layer (136) of the multi-layer nanoparticle-coated fiber material (150).
2. The manufacturing method (400) according to claim 1, in, One or both of the first type of nanoparticles (114) and the second type of nanoparticles (134) include high temperature nanoparticles.
3. The manufacturing method (400) according to claim 2, in: (i) the high temperature nanoparticles include graphene nanoparticles; and (ii) The fiber substrate (102) comprises a carbon fiber material.
4. The manufacturing method (400) according to claim 1, in, The layer-by-layer nanoparticle deposition is performed in a manner of depositing the nanoparticles onto the surfaces of the fibers constituting the fiber substrate (102).
5. The manufacturing method (400) according to claim 1, in, Layer-by-layer nanoparticle deposition is performed under ambient or near-ambient conditions.
6. The manufacturing method (400) according to claim 1, further comprising: include: cleaning the first coating layer (116) to form a single layer of the first coating layer (116); as well as The second coating layer (136) is cleaned to form a single layer of the second coating layer (136).
7. The manufacturing method (400) according to claim 6, in, Each of the single layer of the first coating layer (116) and the single layer of the second coating layer (136) has a thickness of 5 nanometers to 1000 nanometers.
8. A carbon fiber manufactured according to the manufacturing method (400) of claim 1.
9. A method (500) for manufacturing a multi-layer nanoparticle-coated fiber material (150) using a layer-by-layer nanoparticle deposition system (10), the method (500) comprising: include: treating (510) a surface of each of a plurality of fibers of a fibrous substrate (102) to impart an ionic charge polarity to the surface; coating (520) the surface of each of the plurality of fibers of the fibrous substrate (102) with nanoparticles (114) having an ionic charge polarity opposite to the ionic charge polarity of the surface of each of the plurality of fibers of the fibrous substrate (102) to provide a first layer (116) of the multi-layered nanoparticle-coated fibrous material (150); and The first layer (116) is coated (530) with nanoparticles (134) having an ionic charge polarity opposite to the ionic charge polarity of the first layer (116) to provide a second layer (136) of the multi-layer nanoparticle-coated fiber material (150).
10. The manufacturing method (500) according to claim 9, further comprising: include: cleaning the first layer (116) to form a single layer of the first layer (116); as well as The second layer (136) is cleaned to form a single layer of the second layer (136).
11. The manufacturing method (500) according to claim 10, in, Each of the single layers of the first layer (116) and the single layers of the second layer (136) has a thickness between 5 nanometers and 1000 nanometers.
12. The manufacturing method (500) according to claim 9, further comprising: include: The plurality of fibers of the fibrous substrate (102) are spread out to maximize the surface area that can be coated with nanoparticles.
13. The manufacturing method (500) according to claim 9, further comprising: include: Each of the first layer (116) and the second layer (136) is dried to alter a combination of handling and use properties of the multiple layers of nanoparticle-coated fiber material (150).
14. A ceramic matrix composite material, the ceramic matrix composite material being manufactured according to the manufacturing method (500) according to claim 9.
15. A manufacturing device (100) for a multi-layered fiber material (150) coated with nanoparticles, the manufacturing device (100) include: a first coating vessel (110) comprising a first nanoparticle-based solution (112) through which a fibrous substrate (102) can pass to impart a first coating of nanoparticles (114) to the fibrous substrate (102); and A second coating container (130) comprising a second nanoparticle-based solution (132) through which the fiber substrate (102) having the first coating of the nanoparticles (114) can pass to apply the second coating of the nanoparticles (134) to the fiber substrate (102) coated with the first coating of the nanoparticles (114) and thereby provide the multi-layered nanoparticle-coated fiber material (150).
16. The manufacturing device (100) according to claim 15, in: (i) the fiber substrate (102) has an ionic charge polarity; (ii) the nanoparticles contained in the first coating container (110) have an ionic charge polarity opposite to the ionic charge polarity of the fibrous substrate (102); as well as (iii) the nanoparticles contained in the second coating container (130) have an ionic charge polarity similar to that of the fibrous substrate (102).
17. The manufacturing device (100) according to claim 15, in: (i) the first nanoparticle-based solution (112) includes a polymer that acts as a carrier for the nanoparticles contained in the first coating container (110); and (ii) The second nanoparticle-based solution (132) includes a polymer that acts as a carrier for the nanoparticles contained in the second coating container (130).
18. The manufacturing device (100) according to claim 15, in, The nanoparticles contained in each of the first coating container (110) and the second coating container (130) are selected from graphene, BN, SiN, TiC and TiO 2 combination.
19. The manufacturing apparatus (100) according to claim 15, further comprising: include: a first cleaning container (120) containing a cleaning solution (122), the cleaning solution (122) being used to clean the fiber substrate (102) to which the first coating of the nanoparticles (114) is applied to form a single layer of the first coating of the nanoparticles (114); as well as A second cleaning container (140) containing a cleaning solution (142) for cleaning the fiber substrate (102) coated with the second coating layer of the nanoparticles (134) to form a single layer of the second coating layer of the nanoparticles (134).
20. The manufacturing device (100) according to claim 19, in, Each of the monolayer of the first coating of nanoparticles (114) and the monolayer of the second coating of nanoparticles (134) has a thickness of 5 nanometers to 100 nanometers.