Semiconductor structure and manufacturing method thereof

By designing the isolation layer-insulated fin structure and stacked structure in semiconductor memory devices, combined with the low dielectric constant dielectric layer, the problem of insufficient integration density and control capabilities in the prior art is solved, and a higher storage density is achieved and stability and reduce parasitic capacitance.

CN119173029AActive Publication Date: 2024-12-20CHANGXIN MEMORY TECH INC

Patent Information

Application Number
CN202310706540.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-06-13
Publication Date
2024-12-20
Estimated Expiration
2043-06-13

AI Technical Summary

Technical Problem

In existing semiconductor memory devices, the transistor's integration density and control capabilities are limited, resulting in insufficient storage density and stability, and the parasitic capacitance problems are more prominent.

Method used

A semiconductor structure is designed in which fins extending in the first direction on the substrate are arranged at intervals, insulated by an isolation layer, and a stacked structure is formed on the fins, each stacked structure includes a plurality of active layers and covered by word lines. On the side of the channel region of the stacked structure, the dielectric layer covers the word line away from the surface of the stacked structure, and the parasitic capacitance is reduced using a low dielectric constant material.

Benefits of technology

The integrated density of the semiconductor structure and the control ability of transistors are improved, the parasitic capacitance between word lines and between word lines and stacked structures is reduced, and the stability and performance of the structure are enhanced.

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Abstract

The embodiment of the invention relates to the field of semiconductors, and provides a semiconductor structure and a manufacturing method thereof, and the structure comprises a substrate which comprises a plurality of fin parts which extend in a first direction and are arranged at intervals in a second direction; the isolation layers are located between the adjacent fin parts, and the top surfaces of the isolation layers are not higher than the top surfaces of the fin parts; the laminated structures are in one-to-one correspondence with the fin parts, each laminated structure is located on the corresponding fin part, each laminated structure comprises a plurality of active layers which are laminated on the fin parts in the third direction and are spaced, and the active layers extend in the first direction and comprise source regions, channel regions and drain regions which are sequentially arranged in the first direction; the word lines are in one-to-one correspondence with the laminated structures, the word lines extend in the third direction and cover at least one side face of the channel region in the corresponding laminated structure, and the bottom faces of the word lines make contact with the top face of the isolation layer; the dielectric layer at least covers the side face, away from the laminated structure, of the word line, and the dielectric layer is made of a low-dielectric-constant material.
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Description

Technical Field

[0001] The embodiments of the present disclosure relate to the semiconductor field, and in particular to a semiconductor structure and a method for manufacturing the same. Background Art

[0002] Memory is a memory component used to store programs and various data information. The random access memory (RAM) used in general computer systems can be divided into two types: dynamic random access memory (DRAM) and static random access memory (SRAM). Dynamic random access memory is a commonly used semiconductor memory device in computers, consisting of many repeated storage units.

[0003] A memory cell generally includes a capacitor and a transistor, wherein one of the source, drain or drain of the transistor is connected to a bit line structure, and the other of the source, drain or drain is connected to a capacitor, and the capacitor includes a capacitor contact structure and a capacitor. The word line structure of the memory cell can control the opening or closing of the channel region of the transistor, thereby reading the data information stored in the capacitor through the bit line structure, or writing the data information into the capacitor for storage through the bit line structure. Summary of the invention

[0004] The embodiments of the present disclosure provide a semiconductor structure and a method for manufacturing the same, which are at least beneficial to improving the performance of the semiconductor structure.

[0005] According to some embodiments of the present disclosure, on the one hand, an embodiment of the present disclosure provides a semiconductor structure, including: a substrate, the substrate including a plurality of fins extending along a first direction and arranged at intervals along a second direction; an isolation layer, the isolation layer is located between adjacent fins, and the top surface of the isolation layer is not higher than the top surface of the fins; a plurality of stacked structures, the stacked structures correspond one-to-one to the fins, each stacked structure is located on a corresponding fin, the stacked structures include a plurality of active layers stacked and spaced apart along a third direction on the fins, the active layers extend along the first direction and include source regions, channel regions and drain regions arranged in sequence along the first direction; a plurality of word lines, the word lines correspond one-to-one to the stacked structures, the word lines extend along the third direction and cover at least one side of the channel region in the corresponding stacked structure, and the bottom surface of the word lines contacts the top surface of the isolation layer; a dielectric layer, the dielectric layer at least covers the side of the word line away from the stacked structure, wherein the material of the dielectric layer is a low dielectric constant material.

[0006] In some embodiments, a top surface of the fin protrudes from a top surface of the isolation layer along a third direction, and the word line further covers a side surface of the fin protruding from a top surface of the isolation layer.

[0007] In some embodiments, a height difference between a top surface of the fin and a top surface of the isolation layer is less than half of a height of the fin.

[0008] In some embodiments, the dielectric layer also extends to a position between adjacent stacked structures that is opposite to the source region along the second direction and to a position opposite to the drain region along the second direction; the semiconductor structure also includes an insulating layer, which is located at least between the fin and the corresponding stacked structure, between adjacent active layers in the stacked structure, between the dielectric layer and the source region, and between the dielectric layer and the drain region.

[0009] In some embodiments, the semiconductor structure further includes: an air gap extending along a third direction, the air gap being located at least between adjacent word lines and located on a side of the dielectric layer away from the word lines.

[0010] In some embodiments, the air gap also extends along the first direction, and the air gap is located between adjacent stacked structures; the isolation layer includes a first isolation portion located below the air gap and a second isolation portion located on both sides of the air gap along the second direction, and the top surface of the first isolation portion is lower than the top surface of the second isolation portion.

[0011] In some embodiments, the air gap includes a first gap portion and a second gap portion connected along a third direction, the first gap portion is located between the dielectric layers, the second gap portion is located below the dielectric layer, and the width of the second gap portion along the second direction is greater than the width of the first gap portion along the second direction.

[0012] In some embodiments, the isolation layer includes: a first isolation layer, the first isolation layer is located on the substrate surface between adjacent fins; and a second isolation layer, the second isolation layer is located on the surface of the first isolation layer, and a material of the second isolation layer is different from that of the first isolation layer.

[0013] According to some embodiments of the present disclosure, on the other hand, the embodiments of the present disclosure further provide a method for manufacturing a semiconductor structure, comprising: providing an initial substrate and forming a stacking structure on the surface of the initial substrate, the stacking structure comprising alternatingly stacked sacrificial layers and semiconductor layers; patterning the stacking structure and part of the initial substrate, the remaining initial substrate serving as a substrate, the substrate comprising a plurality of fins extending along a first direction and arranged along a second direction, the remaining semiconductor layer serving as an active layer, the active layer extending along the first direction and comprising a source region, a channel region and a drain region arranged in sequence along the first direction, a plurality of active layers stacked along a third direction on the top surface of the fin constitute a stacking structure; forming an isolation layer, the isolation layer being located between adjacent fins, and the top surface of the isolation layer being not higher than the top surface of the fin; forming a word line, the word line corresponding to the stacking structure one by one, and the word line extending along the third direction and covering at least one side of the channel region in the corresponding stacking structure, and the bottom surface of the word line being in contact with the top surface of the isolation layer; forming a dielectric layer, the dielectric layer at least covering the side of the word line away from the stacking structure, wherein the dielectric layer is a material with a low dielectric constant.

[0014] In some embodiments, before forming the dielectric layer, it also includes: forming a filling layer, the filling layer is located on the surface of the isolation layer and fills the gap between the stacked structures; forming a dielectric layer, including: patterning the filling layer to form a dielectric groove; forming a dielectric layer at least on the side wall of the dielectric groove, and the air gap is sandwiched between the dielectric layers located on the side wall of the dielectric groove.

[0015] The technical solution provided by the embodiments of the present disclosure has at least the following advantages:

[0016] In the semiconductor structure provided by the embodiment of the present disclosure, the substrate includes a plurality of fins, and adjacent fins are insulated by an isolation layer. The stacked structure on the fin can be used to form a transistor structure, and each stacked structure has a plurality of active layers, that is, each stacked structure can form a plurality of transistors stacked along a third direction, thereby improving the integration density of the semiconductor structure. The word line covers at least one side of the channel region of the active layer in the stacked structure to achieve control of the transistor, wherein the bottom surface of the word line contacts the top surface of the isolation layer, and the top surface of the isolation layer is not higher than the top surface of the fin, so that the word line can fully cover the side of the channel region of the active layer closest to the fin in the stacked structure, thereby facilitating the word line to control the transistor closest to the fin in the stacked structure. In addition, the surface of the word line away from the stacked structure is covered with a dielectric layer, so that adjacent word lines can be insulated by the dielectric layer, and at the same time, it is beneficial to reduce the parasitic capacitance between adjacent word lines or the parasitic capacitance between the word line and other stacked structures. BRIEF DESCRIPTION OF THE DRAWINGS

[0017] One or more embodiments are exemplarily illustrated by pictures in the corresponding drawings, and these exemplified descriptions do not constitute a limitation on the embodiments. Unless otherwise specified, the pictures in the drawings do not constitute a scale limitation. In order to more clearly illustrate the embodiments of the present disclosure or the technical solutions in the traditional technology, the drawings required for use in the embodiments are briefly introduced below. Obviously, the drawings described below are only some embodiments of the present disclosure. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.

[0018] Figures 1 to 10 Schematic diagram of various semiconductor structures provided by an embodiment of the present disclosure;

[0019] Figures 11 to 21 A schematic structural diagram corresponding to each step of a method for manufacturing a semiconductor structure provided in another embodiment of the present disclosure. DETAILED DESCRIPTION

[0020] According to some embodiments of the present disclosure, an embodiment of the present disclosure provides a semiconductor structure, which is at least beneficial to improving the performance of the semiconductor structure.

[0021] The following will describe the various embodiments of the present disclosure in detail with reference to the accompanying drawings. However, it will be appreciated by those skilled in the art that in the various embodiments of the present disclosure, many technical details are provided in order to enable the reader to better understand the present disclosure. However, even without these technical details and various changes and modifications based on the following embodiments, the technical solutions claimed in the present disclosure can be implemented.

[0022] Figures 1 to 10 Schematic diagram of various semiconductor structures provided by an embodiment of the present disclosure, wherein: Figures 2 to 6 for Figure 1 Schematic diagram of various cross-sectional structures along the AA1 direction, Fig. 9 and Fig.10 for Figure 7 Schematic diagrams of various cross-sectional structures along the BB1 ​​direction. The semiconductor structure provided by this embodiment will be described in detail in conjunction with the accompanying drawings, as follows:

[0023] refer to Figures 1 to 10 The semiconductor structure includes: a substrate 100, the substrate 100 includes a plurality of fins 101 extending along a first direction X and arranged at intervals along a second direction Y; an isolation layer 200, the isolation layer 200 is located between adjacent fins 101, and the top surface of the isolation layer 200 is not higher than the top surface of the fin 101; a plurality of stacked structures 300, the stacked structures 300 correspond to the fins 101 one by one, each stacked structure 300 is located on a corresponding fin 101, and the stacked structures 300 include a plurality of active layers 301 stacked and spaced apart along a third direction Z on the fin 101, the active layers 301 extends along a first direction X and includes a source region 311, a channel region 321 and a drain region 331 arranged in sequence along the first direction; a plurality of word lines 400, the word lines 400 correspond to the stacked structures 300 one by one, and the word lines 400 extend along a third direction Z and cover at least one side of the channel region 321 in the corresponding stacked structure 300, and the bottom surface of the word line 400 contacts the top surface of the isolation layer 200; a dielectric layer 500, the dielectric layer 500 at least covers the side of the word line 400 away from the stacked structure 300, wherein the material of the dielectric layer 500 is a low dielectric constant material.

[0024] In the semiconductor structure provided by the embodiment of the present disclosure, the substrate 100 includes a plurality of fins 101, and the adjacent fins 101 are insulated by the isolation layer 200. The stacked structure 300 on the fin 101 can be used to form a transistor structure, and each stacked structure 300 has a plurality of active layers 301, that is, each stacked structure 300 can form a plurality of transistors stacked along the third direction Z, thereby improving the integration density of the semiconductor structure. The word line 400 covers at least one side of the channel region 321 of the active layer 301 in the stacked structure 300 to achieve control of the transistor, wherein the bottom surface of the word line 400 contacts the top surface of the isolation layer 200, and the top surface of the isolation layer 200 is not higher than the top surface of the fin 101, so that the word line 400 can fully cover the side of the channel region 321 of the active layer 301 closest to the fin 101 in the stacked structure 300, thereby facilitating the control of the transistor closest to the fin 101 in the stacked structure 300 by the word line 400. In addition, the surface of the word line 400 away from the stacked structure 300 is covered with a dielectric layer 500, so that adjacent word lines 400 can be insulated by the dielectric layer 500, which is beneficial to reduce the parasitic capacitance between adjacent word lines 400 or the parasitic capacitance between the word line 400 and other stacked structures 300.

[0025] The material of the substrate 100 may include a semiconductor material, such as but not limited to silicon. In some embodiments, the substrate 100 may include: a basic semiconductor, a compound semiconductor, or an alloy semiconductor. For example, the basic semiconductor includes germanium (Ge); the compound semiconductor includes silicon carbide, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide, indium antimonide, and / or III-V semiconductor materials, etc.; the alloy semiconductor includes silicon germanium (SiGe), silicon germanium carbide, germanium tin, silicon germanium tin, gallium arsenic phosphide, gallium indium phosphide, gallium indium arsenide, indium gallium arsenide phosphide, aluminum indium arsenide, and / or aluminum gallium arsenide, etc. In some embodiments, the substrate 100 may also be a silicon-on-insulator structure, a silicon-germanium-on-insulator structure, a germanium-on-insulator structure, or a combination thereof.

[0026] exist Figure 1 In the example, the top surface of the fin 101 protrudes from the top surface of the isolation layer 200 along the third direction Z, and the word line 400 also covers the side of the fin 101 protruding from the top surface of the isolation layer 200. In some embodiments, the top surface of the fin can also be flush with the top surface of the isolation layer. In this way, the word line 400 can fully cover the side of the channel region 321 of the active layer 301 closest to the fin 101 in the stacked structure 300, thereby facilitating the control of the word line 400 on the transistor closest to the fin 101 in the stacked structure 300.

[0027] In some embodiments, the height difference between the top surface of the fin 101 and the top surface of the isolation layer 200 is less than half the height of the fin 101 relative to the surface of the substrate 100 between adjacent fins 101. It is understood that the bottom surface of the word line 400 is in contact with the top surface of the isolation layer 200. In order to avoid leakage between the word line 400 and the substrate 100 due to excessive height difference between the bottom surface of the word line 400 and the top surface of the fin 101, it is necessary to control the height difference between the top surface of the isolation layer 200 and the top surface of the fin 101 within an appropriate range.

[0028] The material of the isolation layer 200 includes silicon oxide, silicon nitride or silicon oxynitride.

[0029] In some embodiments, reference Figure 2 The isolation layer 200 may include: a first isolation layer 201 , the first isolation layer 201 is located on the surface of the substrate 100 between adjacent fins 101 ; a second isolation layer 202 , the second isolation layer 202 is located on the surface of the first isolation layer 201 , and the material of the second isolation layer 202 is different from that of the first isolation layer 201 .

[0030] When forming the isolation layer 200, since the top surface of the isolation layer 200 is not higher than the top surface of the fin 101, in order to control the height difference between the top surface of the isolation layer 200 and the top surface of the fin 101, a first isolation layer 201 and a second isolation layer 202 of different materials can be set, so that when the word line 400 is subsequently formed, the second isolation layer 202 can be used as an etching stop layer for the word line hole to avoid the word line 400 from being too deep, thereby avoiding the bottom surface of the word line 400 from being too much lower than the top surface of the fin 101, thereby causing leakage between the word line 400 and the substrate 100.

[0031] The materials of the first isolation layer 201 and the second isolation layer 202 may include silicon oxide, silicon nitride, silicon oxynitride or the like.

[0032] In some embodiments, the semiconductor structure may further include an insulating layer 302, and the insulating layer 302 is located between adjacent active layers 301, and is also located between the active layer 301 and the fin 101. In this way, the insulating layer 302 can insulate the transistor structures formed by the adjacent active layers 301, and insulate the transistor structures from the substrate 100, thereby avoiding leakage between adjacent transistor structures or between the transistor structures and the substrate 100, and improving the stability of the semiconductor structure.

[0033] The material of the insulating layer 302 may include silicon oxide, silicon nitride, silicon oxynitride or the like.

[0034] It should be noted that in Figure 1 and Figure 2In the embodiment, the number of active layers 301 stacked in the stacked structure 300 is 2, which does not limit the number of active layers 301 in the stacked structure 300. In some embodiments, the number of active layers in the stacked structure may also be 3, 5 or 8.

[0035] The material of the active layer 301 includes an elemental semiconductor material or a compound semiconductor material. The elemental semiconductor material may be germanium, silicon, selenium, boron, tellurium or antimony; the compound semiconductor material may be gallium arsenide, indium phosphide, indium antimonide, silicon carbide, cadmium sulfide or gallium arsenic silicon, etc. In some embodiments, the material of the active layer 301 may also include an oxide semiconductor, for example, at least one of IGZO (Indium Gallium Zinc Oxide), IWO (Tungsten-doped Indium Oxide) or ITO (Indium Tin Oxide).

[0036] The source region 311 and the drain region 331 are used to form the source and drain of the transistor, respectively. In some embodiments, the source region 311 and the drain region 331 may have doped ions therein. For example, both the source region 311 and the drain region 331 may have N-type ions, including phosphorus ions, arsenic ions, or antimony ions; or, both the source region 311 and the drain region 331 may have P-type ions, including boron ions, indium ions, or gallium ions. The doped ion types of the source region 311 and the drain region 331 and the channel region 321 may be the same to form a junctionless transistor; the doped ion types of the source region 311 and the drain region 331 and the channel region 321 may also be different to form a junction transistor.

[0037] It should be noted that Figure 1 The positions of the source region 311 and the drain region 331 shown in the figure do not constitute a limitation of the source region 311 and the drain region 331. In some embodiments, the positions of the source region 311 and the drain region 331 can be replaced with each other.

[0038] exist Figure 1 In the description, the word line 400 covers two sides of the active layer 301, which does not limit the way in which the word line 400 covers the channel region 321 of the active layer 301. In some embodiments, the word line may also only cover one side of the channel region of the active layer in the stacked structure along the second direction.

[0039] In some embodiments, reference Figure 3The word line 400 may include a first sub-word line 401 and a second sub-word line 402, the first sub-word line 401 and the second sub-word line 402 respectively cover two opposite sides of the stacked structure 300 along the second direction Y, and the first sub-word line 401 and the second sub-word line 402 are insulated from each other. In this way, the first sub-word line 401 and the second sub-word line 402 can respectively control the transistor formed by the active layer 301 in the stacked structure 300, thereby improving the control capability of the semiconductor structure.

[0040] In some embodiments, reference Figure 4 , the word line 400 may further include a third sub-word line 403, which is located on the top surface of the stacked structure 300 and is in electrical contact with the first sub-word line 401 and the second sub-word line 402. In this way, the first sub-word line 401 and the second sub-word line 402 may be electrically connected through the third sub-word line 403, that is, the first sub-word line 401, the second sub-word line 402 and the third sub-word line 403 together constitute the same word line 400, and the word line 400 covers two opposite side surfaces of the active layer 301 in the corresponding stacked structure 300 along the second direction Y, thereby increasing the contact area between the word line 400 and the channel region 321 of the active layer 301, and improving the gate control capability.

[0041] In some embodiments, reference Figure 5 The first sub-word line 401 can also extend to the second sub-word line 402 through the area between the active layers 301, and the second sub-word line 402 can also extend to the first sub-word line 401 through the area between the active layers 301. The first sub-word line 401 and the second sub-word line 402 contact each other through the area between the active layers 301 to facilitate a transistor with a fully surrounding gate structure.

[0042] In some embodiments, the word line 400 may include a gate dielectric layer and a gate conductive layer, wherein the gate dielectric layer covers a surface of a channel region of the active layer, and the gate conductive layer covers a surface of the gate dielectric layer away from the active layer.

[0043] The material of the gate dielectric layer includes silicon oxide, silicon nitride, metal oxide, metal oxynitride, metal silicide, high-K material, ferroelectric material, anti-ferroelectric material or a combination thereof.

[0044] The material of the gate conductive layer includes at least one of polysilicon, titanium nitride, titanium aluminide, tantalum nitride, nickel silicide, cobalt silicide, tantalum, aluminum, lanthanum, titanium or tungsten.

[0045] exist Figures 1 to 5 In the example, the dielectric layer 500 only covers the surface of the word line 400 away from the active layer 300, which does not constitute a limitation on the thickness of the dielectric layer 500 along the second direction Y. In some embodiments, reference Figure 6 , the dielectric layer 500 may also fill the gaps between adjacent word lines 400 .

[0046] refer to Figure 4 and Figure 5 When the word line 400 includes a third sub-word line 403 , the dielectric layer 500 may also cover the side surface of the third sub-word line 403 to avoid parasitic capacitance between adjacent third sub-word lines 403 .

[0047] The material of the dielectric layer 500 is a low dielectric constant material, which means that the dielectric constant of the material of the dielectric layer 500 is less than or equal to 4, such as 4, 3.8, 2.7 or 1. The low dielectric constant material can reduce the parasitic capacitance between adjacent word lines 400, or when the word line 400 only covers one side surface of the stacked structure 300, the dielectric layer 500 can reduce the parasitic capacitance between the word line 400 and the stacked structure 300.

[0048] The material of the dielectric layer 500 may be fluorinated polymer, low dielectric constant glass fiber, microporous mass polymer, fluorinated polyurethane, porous low dielectric constant fatty acid methyl ester, etc., such as SiON, SiCN, SiOC or SiOCN.

[0049] In some embodiments, reference Figure 7 The dielectric layer 500 also extends to a position between adjacent stacked structures 300 that is directly opposite to the source region 211 along the second direction Y and to a position that is directly opposite to the drain region 331 along the second direction Y. In this way, the isolation effect of the dielectric layer 500 can be improved, and the possibility of leakage between word lines 400 through the area not directly opposite to the word lines 400 can be further reduced.

[0050] Furthermore, the insulating layer may be located between the dielectric layer and the source region and between the dielectric layer and the drain region to fill the gaps between the semiconductor structures and to insulate adjacent device structures, thereby improving the stability of the semiconductor structure.

[0051] In some embodiments, reference Figures 1 to 5 as well as Figure 7 The semiconductor structure may further include: an air gap 600, the air gap 600 extends along the third direction Z, the air gap 600 is at least located between adjacent word lines 400, and is located on a side of the dielectric layer 500 away from the word lines 400. The air gap 600 has a low dielectric constant, which can further improve the insulation effect between adjacent word lines 400 and avoid parasitic capacitance between adjacent word lines 400.

[0052] refer to Figure 7When the dielectric layer 500 further extends to a position between adjacent stacked structures 300 that is directly opposite to the source region 211 along the second direction Y and to a position that is directly opposite to the drain region 331 along the second direction Y, the air gap 600 may further extend along the first direction X and be located between adjacent stacked structures 300. In this way, non-directly opposite regions between adjacent word lines 400 may also be isolated by the air gap 600, thereby further reducing the possibility of parasitic capacitance between the word lines 400.

[0053] refer to Figure 8 , the isolation layer 200 may include a first isolation portion 210 located below the air gap 600 and second isolation portions 220 located on both sides of the air gap 600 along the second direction Y, and the top surface of the first isolation portion 210 is lower than the top surface of the second isolation portion 220. In other words, the air gap 600 extends into the isolation layer 200 along the third direction Z, so that the bottoms of adjacent word lines 400 can be isolated by the air gap 600, so as to avoid leakage between the bottoms of adjacent word lines 400 and improve the stability of the semiconductor structure.

[0054] exist Figure 8 In the example, the width of the air gap 600 is greater than the width of the dielectric layer 500 along the first direction X, which does not constitute a limitation between the width of the air gap 600 and the width of the dielectric layer 500. In some embodiments, along the first direction, the width of the air gap may be equal to the width of the dielectric layer.

[0055] In some embodiments, reference Fig. 9 The dielectric layer 500 may also cover the side of the second isolation portion 220. That is, the dielectric layer 500 also extends into the isolation layer 200, and the dielectric layer 500 and the air gap 600 in the isolation layer 200 work together to insulate the bottoms of adjacent word lines 400, thereby improving the insulation performance between adjacent word lines 400.

[0056] In some embodiments, reference Fig.10 The air gap 600 includes a first gap portion 601 and a second gap portion 602 connected along the third direction Z, the first gap portion 601 is located between the dielectric layers 500, the second gap portion 602 is located below the dielectric layer 500, and the width of the second gap portion 602 along the second direction Y is greater than the width of the first gap portion 601 along the second direction Y. In other words, the gap width of the air gap 600 in the isolation layer 200 is greater than the gap width of the air gap 600 between the dielectric layers 500, so that the second gap portion 602 in the isolation layer 200 can have better dielectric properties to further avoid the possibility of leakage between the bottoms of adjacent word lines 400.

[0057] In some embodiments, the width of the second gap portion 602 along the second direction Y is less than or equal to the gap width of the adjacent word line 400 along the second direction Y, and is greater than or equal to the gap width of the adjacent dielectric layer 500 along the second direction Y. In this way, the isolation performance of the air gap 600 in the isolation layer 200 can be improved while preventing the second gap portion 602 from exposing the bottom surface of the word line 400.

[0058] In some embodiments, along the second direction, the width of the air gap 600 ranges from 10 to 50 nm, such as 10 nm, 13 nm, 19 nm, 25 nm, 31 nm, 36.5 nm, 42 nm, 46.6 nm or 50 nm. It is understood that the width of the air gap 600 needs to be within an appropriate range so that the air gap 600 can isolate adjacent word lines 400 while avoiding the problem that the width of the air gap 600 is too large and cannot be closed later.

[0059] It can be understood that the above embodiments can be arbitrarily combined without conflict to obtain new embodiments.

[0060] In the semiconductor structure provided by the embodiment of the present disclosure, the substrate 100 includes a plurality of fins 101, and the adjacent fins 101 are insulated by an isolation layer 200, and the stacked structure 300 on the fin 101 can be used to form a transistor structure, and each stacked structure 300 has a plurality of active layers 301, that is, each stacked structure 300 can form a plurality of transistors stacked along the third direction Z, thereby improving the integration density of the semiconductor structure. The word line 400 covers at least one side of the channel region 321 of the active layer 301 in the stacked structure 300 to achieve control of the transistor, wherein the bottom surface of the word line 400 contacts the top surface of the isolation layer 200, and the top surface of the isolation layer 200 is not higher than the top surface of the fin 101, so that the word line 400 can fully cover the side of the channel region 321 of the active layer 301 closest to the fin 101 in the stacked structure 300, thereby facilitating the control of the transistor closest to the fin 101 in the stacked structure 300 by the word line 400. In addition, the surface of the word line 400 away from the stacked structure 300 is covered with a dielectric layer 500, so that adjacent word lines 400 can be insulated by the dielectric layer 500, which is beneficial to reduce the parasitic capacitance between adjacent word lines 400 or the parasitic capacitance between the word line 400 and other stacked structures 300.

[0061] According to some embodiments of the present disclosure, another embodiment of the present disclosure provides a method for manufacturing a semiconductor structure, which can be used to form the above-mentioned semiconductor structure to improve the performance of the formed semiconductor structure. It should be noted that the parts that are the same or corresponding to the above-mentioned embodiments can refer to the corresponding description of the above-mentioned embodiments, and will not be described in detail below.

[0062] Figures 11 to 21 A schematic structural diagram corresponding to each step of a method for manufacturing a semiconductor structure provided by another embodiment of the present disclosure, wherein: Figures 13 to 21 for Fig.12 Schematic diagrams of various cross-sectional structures along the CC1 direction. The semiconductor structure manufacturing method provided by this embodiment will be described in detail in conjunction with the accompanying drawings, as follows:

[0063] refer to Fig.11 , providing an initial substrate 110 and forming a stacked structure 310 on a surface of the initial substrate 110 , the stacked structure 310 includes sacrificial layers 312 and semiconductor layers 320 that are alternately stacked.

[0064] The material of the sacrificial layer 312 includes one of silicon, germanium, silicon germanium, silicon carbide and gallium arsenide. The material of the semiconductor layer 320 includes an elemental semiconductor material or a compound semiconductor material. The elemental semiconductor material may be germanium, silicon, selenium, boron, tellurium or antimony; the compound semiconductor material may be gallium arsenide, indium phosphide, indium antimonide, silicon carbide, cadmium sulfide or gallium arsenic silicon, etc. In some embodiments, the material of the semiconductor layer 320 may also include an oxide semiconductor, for example, at least one of IGZO (Indium Gallium Zinc Oxide), IWO (Indium Tungsten Oxide) or ITO (Indium Tin Oxide).

[0065] refer to Fig.12 , a patterned stacked structure 310 and a portion of the initial substrate 110, the remaining initial substrate 110 serves as a substrate 100, the substrate 100 includes a plurality of fins 101 extending along a first direction X and arranged along a second direction Y, the remaining semiconductor layer 320 serves as an active layer 301, the active layer 301 extends along the first direction X and includes a source region 311, a channel region 321 and a drain region 331 arranged in sequence along the first direction X, and a plurality of active layers 301 stacked along a third direction Z on the top surface of the fin 101 constitute a stacked structure 300.

[0066] In some embodiments, patterning the stacked structure and part of the initial substrate includes: forming a mask layer, the mask layer covering the surface of the stacked structure; etching the stacked structure and part of the initial substrate using the mask layer as an etching pattern; and removing the mask layer. The mask layer can serve as a protective layer for the stacked structure to prevent the top surface of the stacked structure from being damaged by the etching process.

[0067] In some embodiments, the mask layer includes a protective layer and a hard mask layer, the protective layer covers the surface of the stacked structure, and the hard mask layer covers the surface of the protective layer. The protective layer can serve as a transition layer between the hard mask layer and the stacked structure to prevent the hard mask layer from being too hard and causing misalignment between the stacked structure.

[0068] The material of the protection layer includes silicon oxide, and the material of the hard mask layer includes silicon nitride.

[0069] refer to Fig.13 , an isolation layer 200 is formed, the isolation layer 200 is located between adjacent fins 101 , and the top surface of the isolation layer 200 is not higher than the top surface of the fin 101 .

[0070] The following example will take the top surface of the isolation layer 200 being lower than the top surface of the fin 101 as an example, which does not constitute a limitation on the height relationship between the top surface of the isolation layer 200 and the top surface of the fin 101. In some embodiments, the top surface of the isolation layer may also be flush with the top surface of the fin.

[0071] In some embodiments, reference Fig.14 , before forming the isolation layer 200, it also includes removing the sacrificial layer 312; forming the isolation layer 200 includes: forming an initial first isolation layer (not shown in the figure), the initial first isolation layer is located on the surface of the substrate 100, and fills the gaps between adjacent stacked structures 300 and the gaps between the active layers 301 in the stacked structures 300; removing part of the initial first isolation layer along the third direction Z, the initial first isolation layer between adjacent fins 101 is used as the first isolation layer 201, and the initial first isolation layer between the active layers 301 is used as the insulating layer 302; forming a second isolation layer 202, the second isolation layer 202 covers the surface of the first isolation layer 201, and the material of the second isolation layer 202 is different from that of the first isolation layer 201. In this way, the insulating layer 302 and the first isolation layer 201 can be formed simultaneously in the same process step, thereby improving the manufacturing efficiency of the semiconductor structure. In addition, the first isolation layer 201 and the second isolation layer 202 are made of different materials, so that the second isolation layer 202 can be used as an etching stop layer when etching the word line hole later, so as to avoid the word line hole being too deep, resulting in the bottom surface of the subsequently formed word line being too deep below the top surface of the fin 101, causing leakage between the word line and the substrate. In one example, after forming the first isolation layer 201, a selective deposition process can be used to form the second isolation layer 202 on the surface of the first isolation layer 201 away from the substrate 100. In other examples, after forming the first isolation layer 201, an initial second isolation material can be deposited to fill the space between the fin 101 and the stacked structure 300, and the initial second isolation material can be planarized and then etched back to form the second isolation layer 202.

[0072] In some embodiments, an isolation layer may be formed first, and then the sacrificial layer may be removed and an insulating layer may be formed.

[0073] The following description will be made by taking the isolation layer 200 including the first isolation layer 201 and the second isolation layer 202 as an example, which does not constitute a limitation on the structure of the isolation layer 200. In some embodiments, the isolation layer may also be a single-layer or three-layer structure.

[0074] refer to Fig.15 , forming a filling layer 700 , the filling layer 700 is located on the top surface of the isolation layer 200 and fills the gaps between adjacent stacked structures 300 .

[0075] The material of the filling layer 700 includes silicon oxide, silicon nitride or silicon oxynitride.

[0076] In one example, a dielectric layer may be formed first, and then the word lines may be formed.

[0077] For example, refer to Fig.16 , patterning the filling layer 700 to form a dielectric trench 510; forming the dielectric layer 500 at least on the sidewall of the dielectric trench 510. In some implementation examples, a dielectric layer may also be formed on the bottom surface and the sidewall of the dielectric trench.

[0078] refer to Fig.17 , forming a spacer layer 520 , and the spacer layer 520 fills the remaining dielectric trench 510 between the dielectric layers 500 .

[0079] The material of the spacer layer 520 includes silicon oxide, silicon nitride or silicon oxynitride.

[0080] refer to Fig.18 , patterning the filling layer 700 to form a word line hole; filling the word line hole to form a word line 400, the word line 400 corresponds to the stacked structure 300 one by one, and the word line 400 extends along the third direction Z and covers at least one side of the channel region 321 in the corresponding stacked structure 300, the bottom surface of the word line 400 contacts the top surface of the isolation layer 200, and the dielectric layer 500 covers at least the side of the word line 400 away from the stacked structure 300, wherein the dielectric layer 500 is a material with a low dielectric constant.

[0081] In some embodiments, reference Fig.19 After forming the word line 400 , the method may further include: removing the spacer layer 520 , and sandwiching the air gap 600 between the dielectric layer 500 and the sidewall of the dielectric trench 510 .

[0082] In another example, the word lines may be formed first and then the dielectric layer may be formed.

[0083] For example, refer to Fig. 20 , patterning the filling layer 700 to form a word line hole; filling the word line hole to form a word line 400, the word line 400 corresponds to the stacked structure 300 one by one, and the word line 400 extends along the third direction Z and covers at least one side of the channel region 321 in the corresponding stacked structure 300, and the bottom surface of the word line 400 contacts the top surface of the isolation layer 200.

[0084] refer to Fig.21, patterning the filling layer 700 to form a dielectric slot 510; forming a dielectric layer 500 at least on the sidewall of the dielectric slot 510, and the air gap 600 is sandwiched between the dielectric layers 500 located on the sidewall of the dielectric slot 510.

[0085] After the air gap is formed, part of the isolation layer may be etched along the third direction to extend the air gap into the isolation layer, thereby preventing leakage between the bottoms of adjacent word lines.

[0086] In some embodiments, the isolation layer exposed by the air gap may be further removed along the second direction, so that the air gap may include a first gap portion and a second gap portion, the first gap portion is located between the dielectric layers, the second gap portion is located below the dielectric layer, and the width of the second gap portion along the second direction is greater than the width of the first gap portion along the second direction. In other words, the gap width of the air gap in the isolation layer is greater than the width of the air gap between the dielectric layers, so that the second gap portion in the isolation layer may have better dielectric properties to further avoid the possibility of leakage between the bottoms of adjacent word lines.

[0087] In some embodiments, a wet etching process may be used to remove the isolation layer partially exposed by the air gap along the second direction.

[0088] In some embodiments, the air gap 600 may be sealed with tetraethylorthosilicate (TEOS). Since TEOS has a poor filling ability, the top of the air gap 600 may be sealed without filling the air gap, thereby forming the air gap 600 into a closed cavity.

[0089] The semiconductor structure manufacturing method provided by the embodiment of the present disclosure forms a plurality of fins 101 on a substrate 100, and the adjacent fins 101 are insulated by an isolation layer 200, and the stacked structure 300 on the fin 101 can be used to form a transistor structure, and each stacked structure 300 has a plurality of active layers 301, that is, each stacked structure 300 can form a plurality of transistors stacked along a third direction Z, thereby improving the integration density of the semiconductor structure. The word line 400 covers at least one side of the channel region 321 of the active layer 301 in the stacked structure 300 to achieve control of the transistor, wherein the bottom surface of the word line 400 contacts the top surface of the isolation layer 200, and the top surface of the isolation layer 200 is not higher than the top surface of the fin 101, so that the word line 400 can fully cover the side of the channel region 321 of the active layer 301 in the stacked structure 300 closest to the fin 101, thereby facilitating the control of the transistor closest to the fin 101 in the stacked structure 300 by the word line 400. In addition, the surface of the word line 400 away from the stacked structure 300 is covered with a dielectric layer 500, so that adjacent word lines 400 can be insulated by the dielectric layer 500, which is beneficial to reduce the parasitic capacitance between adjacent word lines 400 or the parasitic capacitance between the word line 400 and other stacked structures 300.

[0090] Those skilled in the art will appreciate that the above-mentioned embodiments are specific examples for implementing the present disclosure, and in actual applications, various changes may be made thereto in form and detail without departing from the spirit and scope of the present disclosure.

Claims

1. A semiconductor structure, characterized in that: include: A substrate, the substrate comprising a plurality of fins extending along a first direction and arranged at intervals along a second direction; An isolation layer, wherein the isolation layer is located between adjacent fins, and a top surface of the isolation layer is not higher than a top surface of the fin; a plurality of stacked structures, each of the stacked structures corresponding to the fins one by one, each of the stacked structures being located on the corresponding fin, the stacked structures comprising a plurality of active layers stacked and spaced apart along a third direction on the fins, the active layers extending along the first direction and comprising a source region, a channel region and a drain region sequentially arranged along the first direction; a plurality of word lines, the word lines corresponding to the stacked structures one by one, the word lines extending along the third direction and covering at least one side surface of the channel region in the corresponding stacked structure, the bottom surface of the word line contacting the top surface of the isolation layer; A dielectric layer at least covers the side of the word line away from the stacked structure, wherein the material of the dielectric layer is a low dielectric constant material.

2. The semiconductor structure according to claim 1, characterized in that: The top surface of the fin protrudes from the top surface of the isolation layer along the third direction, and the word line further covers the side surface of the fin protruding from the top surface of the isolation layer.

3. The semiconductor structure according to claim 2, characterized in that: A height difference between a top surface of the fin and a top surface of the isolation layer is less than half of a height of the fin.

4. The semiconductor structure according to claim 1, characterized in that: The dielectric layer also extends to a position between adjacent stacked structures that is directly opposite to the source region along the second direction and a position that is directly opposite to the drain region along the second direction; The semiconductor structure further includes an insulating layer, which is located between the fin and the corresponding stacked structure, between adjacent active layers in the stacked structure, between the dielectric layer and the source region, and between the dielectric layer and the drain region.

5. The semiconductor structure according to any one of claims 1 to 4, characterized in that: Also includes: An air gap extends along the third direction, and the air gap is at least located between adjacent word lines and is located on a side of the dielectric layer away from the word lines.

6. The semiconductor structure according to claim 5, characterized in that: The air gap also extends along the first direction, and the air gap is located between adjacent stacked structures; the isolation layer includes a first isolation portion located below the air gap and a second isolation portion located on both sides of the air gap along the second direction, and the top surface of the first isolation portion is lower than the top surface of the second isolation portion.

7. The semiconductor structure according to claim 6, characterized in that: The air gap includes a first gap portion and a second gap portion connected along the third direction, the first gap portion is located between the dielectric layers, the second gap portion is located below the dielectric layer, and the width of the second gap portion along the second direction is greater than the width of the first gap portion along the second direction.

8. The semiconductor structure according to claim 1, characterized in that: The isolation layer comprises: a first isolation layer, the first isolation layer being located on the surface of the substrate between adjacent fins; A second isolation layer, wherein the second isolation layer is located on the surface of the first isolation layer, and a material of the second isolation layer is different from a material of the first isolation layer.

9. A method for manufacturing a semiconductor structure, characterized in that: include: Providing an initial substrate and forming a stacked structure on the surface of the initial substrate, wherein the stacked structure includes sacrificial layers and semiconductor layers stacked alternately; The stacked structure and part of the initial substrate are patterned, the remaining initial substrate is used as a substrate, the substrate includes a plurality of fins extending along a first direction and arranged along a second direction, the remaining semiconductor layer is used as an active layer, the active layer extends along the first direction and includes a source region, a channel region and a drain region sequentially arranged along the first direction, and the plurality of active layers stacked along a third direction on the top surface of the fin constitute a stacked structure; forming an isolation layer, wherein the isolation layer is located between adjacent fins, and a top surface of the isolation layer is not higher than a top surface of the fin; forming a word line, wherein the word line corresponds to the stacked structure one by one, and the word line extends along the third direction and covers at least one side surface of the channel region in the corresponding stacked structure, and the bottom surface of the word line contacts the top surface of the isolation layer; A dielectric layer is formed, wherein the dielectric layer at least covers the side of the word line away from the stacked structure, wherein the dielectric layer is a material with a low dielectric constant.

10. The method for manufacturing a semiconductor structure according to claim 9, characterized in that: Before forming the dielectric layer, the method further comprises: forming a filling layer, wherein the filling layer is located on the surface of the isolation layer and fills the gaps between the stacked structures; The forming of the dielectric layer comprises: patterning the filling layer to form a dielectric trench; The dielectric layer is formed at least on the sidewall of the dielectric slot, and an air gap is sandwiched between the dielectric layers located on the sidewall of the dielectric slot.

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