A gasoline hydrogenation acidic water recovery and utilization system
By designing adjustable fusion institutions and linked air intake and filtering agencies, the problem of low efficiency of fog foam and activated carbon absorbing attachment in the existing systems, achieve efficient acid water recovery and poisoning gas removal effects.
Patent Information
- Application Number
- CN202411723031.X
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-28
- Publication Date
- 2025-01-28
- Estimated Expiration
- 2044-11-28
AI Technical Summary
The existing gasoline hydrogenated acidic water recycling system cannot switch the spacing of the tower plates according to the pollution degree of acidic water, resulting in mist entrainment problems, reducing the efficiency of toxic gas removal in acidic water, and the activated carbon adsorption unit is fixed, so it cannot adapt to the pollution degree. Changes affect recycling efficiency.
A gasoline hydrogen acid water recycling system that includes a fusion mechanism, an intake mechanism and a filtering mechanism is designed. Detecting the pollution of acid water by ORP sensor, regulate the spacing of the secondary scattered plate and the first scattered plate to prevent the foam foam band; Horizontal shaking, improving the recycling efficiency of acidic water.
Effectively prevent the foam foam band, improve the fusion of high -temperature steam and acidic water, improve the efficiency of poisoning gas in acidic water, and use the shaking of the activated carbon filter to improve the recycling efficiency of acid water and achieve full use of resources.
Smart Images

Figure CN119219277B_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of acidic water recovery and treatment, and in particular to a gasoline hydrogenation acidic water recovery and utilization system. Background Art
[0002] Gasoline hydrogenation units usually produce acidic water, i.e., sulfur-containing wastewater, during production. If this part of sulfur-containing wastewater is directly discharged into the factory's sewage treatment unit, it will not only increase the treatment load of the sewage treatment unit, but also fail to recycle the beneficial water in the acidic water.
[0003] The existing recycling system has the following shortcomings:
[0004] 1. It is impossible to switch the spacing of the tower plates according to the degree of contamination of the acidic water, which easily causes the problem of mist entrainment, resulting in the inability of high-temperature steam and acidic water to fully merge, reducing the removal efficiency of toxic gases in the acidic water, thereby reducing the effect of recovery and treatment.
[0005] 2. The activated carbon adsorption unit is generally fixed in position. When encountering acidic water with a high degree of pollution, the filtered impurities adhering to its surface will increase, causing the flow rate of the acidic water passing through to slow down, reducing the recovery efficiency of the acidic water.
[0006] 3. Acidic water is generally not pretreated before recycling, and the acidic water contains a large number of impurities, which seriously affects the recycling rate. Summary of the invention
[0007] The purpose of the present invention is to provide a gasoline hydrogenation acidic water recovery and utilization system.
[0008] To achieve this object, the present invention adopts the following technical solutions:
[0009] Provided is a gasoline hydrogenation acidic water recovery and utilization system, comprising a recovery tank, wherein the recovery tank comprises a top cover and a tank body, wherein the top cover is fixed to the top of the tank body by a plurality of bolts;
[0010] It also includes a controller, a liquid inlet mechanism, a fusion mechanism, an air inlet mechanism and a filtering mechanism;
[0011] The liquid inlet mechanism is arranged on the outer wall of the top cover, and the liquid inlet mechanism includes a liquid inlet pipe, a conical flow guide pipe and a rotating assembly. The top of the top cover is provided with a liquid inlet, the liquid inlet pipe and the conical flow guide pipe are fixedly arranged at the top and bottom of the liquid inlet respectively, and the rotating assembly is arranged at the bottom of the conical flow guide pipe;
[0012] The fusion mechanism is arranged on the recovery tank, and the fusion mechanism includes a first evacuation plate, a second evacuation plate and an adjustment assembly. The first evacuation plate is fixedly arranged on the inner top of the tank body, and the second evacuation plate is slidably arranged below the second evacuation plate through four slide bars. The adjustment assembly is inserted on the outer wall of the top cover, and the second evacuation plate is fixedly connected to the adjustment assembly.
[0013] The air intake mechanism is arranged on the outer wall of the tank body, and the air intake mechanism includes a cover shell, an air intake pipe, a traction assembly, a conveying assembly, a lifting assembly and a plurality of air outlet heads. The air intake pipe is inserted on the tank body, the cover shell and the conveying assembly are respectively fixed on both ends of the air intake pipe, the lifting assembly is inserted on the cover shell, a plurality of air outlet heads are arranged on the conveying assembly at equal intervals, and the traction assembly is arranged between the second evacuation plate and the lifting assembly;
[0014] The filtering mechanism is arranged on the tank body, and the filtering mechanism includes activated carbon, a filter frame, a pressing assembly and a transmission assembly. The filter frame is slidably arranged on the inner bottom of the tank body through two sliding rods, the activated carbon is arranged inside the filter frame, the pressing assembly is arranged between the transmission assembly and one of the sliding rods, the transmission assembly is arranged between the traction assembly and the pressing assembly, and the adjustment assembly is electrically connected to the controller.
[0015] Furthermore, the rotating assembly includes a supporting shell, a discharge pipe, a docking pipe and four liquid outlet pipes. A discharge port is provided at the bottom of the conical guide pipe, the discharge pipe is fixed at the bottom end of the discharge port, the supporting shell is fixed at the bottom of the conical guide pipe, the docking pipe is rotatably arranged on the supporting shell through a bearing, the diameter of the discharge pipe is smaller than the diameter of the docking pipe, the four liquid outlet pipes are arranged at equal intervals, and the docking pipe is connected to the four liquid outlet pipes.
[0016] Furthermore, a water receiving trough is provided on the top of the first evacuation plate and the second evacuation plate, and a conical water receiving hole and a cylindrical air vent are respectively provided on one end of the first evacuation plate and the second evacuation plate away from the water receiving trough, and each conical water receiving hole is connected to a cylindrical air vent.
[0017] Furthermore, the adjustment component includes an electric push rod, a push block and a push rod. A U-shaped plate is fixed on the top of the top cover, a guide rod is fixed on the outer wall of the U-shaped plate, the electric push rod is inserted in the top of the U-shaped plate, the push block is fixed on the output end, the push block is slidably arranged on the outer wall of the guide rod, the push rod is fixed between the push block and the second evacuation plate, the top cover and the first evacuation plate are both slidably connected to the push rod, an ORP sensor is inserted on the outer wall of the liquid inlet pipe, and the electric push rod and the ORP sensor are both electrically connected to the controller.
[0018] Furthermore, the traction assembly includes a pull rod, a lifting plate, a connecting rod, two rocker rods and two first plug rods. The pull rod is fixedly arranged on the top of the second evacuation plate, the top cover and the first evacuation plate are both slidably connected to the pull rod, the lifting plate is fixedly arranged at the top of the pull rod, the connecting rod is fixedly arranged at the bottom end of the lifting plate away from the pull rod, the two first plug rods are both fixedly arranged at the bottom end of the connecting rod, two support plates are fixedly arranged on the top of the cover shell, a rotating shaft is rotatably arranged between the two support plates, the two rocker rods are both fixedly arranged on the outer wall of the rotating shaft, each rocker rod is respectively provided with a first slot and a second slot at both ends, and each first plug rod is plugged into a first slot.
[0019] Furthermore, the lifting assembly includes a lifting rod, a conical sealing plug, a circulation ring and two second plug rods. The lifting rod is slidably arranged on the cover shell, the conical sealing plug is fixedly arranged at the bottom end of the lifting rod, the interior of the cover shell is integrally formed with a conveying channel, an input pipe is fixedly arranged at the bottom of the cover shell, the input pipe, the conveying channel and the air intake pipe are connected in sequence, the circulation ring is fixedly arranged on the inner wall of the input pipe, the conical sealing plug is consistent with the axial direction of the circulation ring, the two second plug rods are fixedly arranged at the top end of the lifting rod, and each second plug rod is plugged into a second slot.
[0020] Furthermore, the conveying assembly includes an air supply pipe, a dispersion pipe and several branch pipes. The air supply pipe is fixedly arranged at one end of the air inlet pipe away from the cover shell, the dispersion pipe is fixedly arranged at one end of the air supply pipe away from the air inlet pipe, several branch pipes are evenly spaced on the outer wall of the dispersion pipe, and several air outlet heads are fixedly connected to the several branch pipes respectively.
[0021] Furthermore, the transmission assembly includes a rotating rod, a driving wheel, a driven wheel and a belt. The rotating rod is fixed at one end of the rotating shaft, the driving wheel is fixed at the end of the rotating rod away from the rotating shaft, an L-shaped plate is fixed on the outer wall of the tank body, a hinge shaft is rotatably provided on the L-shaped plate, the driven wheel is fixed on the hinge shaft, the belt is sleeved between the driving wheel and the driven wheel, and the diameter of the driving wheel is larger than the diameter of the driven wheel.
[0022] Furthermore, the pressing assembly includes a wedge-shaped turntable, a ball, a return spring and a baffle. The ball is rotatably arranged on one of the sliding rods close to the driven wheel, the baffle is fixedly arranged on one of the sliding rods close to the driven wheel, the return spring is sleeved on one of the sliding rods close to the driven wheel, a limit plate is fixedly arranged on the outer wall of the L-shaped plate, the baffle and the limit plate respectively abut against two ends of the return spring, the wedge-shaped turntable is fixedly arranged on the hinge shaft, the outer wall of one end of the wedge-shaped turntable is fitted with the outer edge of the ball, a conical guide shell is fixedly arranged on the inner wall of the tank body, and a liquid delivery pipe is fixedly arranged at the bottom of the conical guide shell.
[0023] Furthermore, an exhaust pipe is fixedly provided on the outer wall of the top cover, and a liquid discharge pipe is fixedly provided on the bottom of the tank body.
[0024] Beneficial effects of the present invention:
[0025] 1. The present invention designs a fusion mechanism, namely, a first evacuation plate, a second evacuation plate and an adjustment component, and designs an ORP sensor. When it is detected that the pollution degree of the acidic water entering the liquid inlet pipe becomes larger, the adjustment component is started by the controller, so that the second evacuation plate slides down and the distance with the first evacuation plate is increased to prevent the entrainment of mist and foam, which is beneficial to improve the fusion of high-temperature steam and acidic water and improve the separation effect of toxic gases in acidic water.
[0026] 2. The present invention can make the fusion mechanism and the air intake mechanism operate in conjunction by designing a traction component, that is, while the distance between the first evacuation plate and the second evacuation plate is increased, the delivery amount of high-temperature steam into the tank body is simultaneously increased, thereby ensuring that sufficient high-temperature steam can be fused with the acidic water with greater pollution, reducing the partial pressure in the gas phase, and then promoting the volatile components in the acidic water to enter the gas phase more easily, thereby achieving an effective steam stripping effect.
[0027] 3. The present invention can realize the linkage operation of the air intake mechanism and the filtering mechanism by designing the transmission component, that is, while increasing the delivery amount of high-temperature steam into the tank body, it can simultaneously drive the filter frame to shake horizontally, so that the activated carbon in the filter frame can shake horizontally. On the one hand, the acidic water adhering to the surface of the activated carbon can be thrown off, thereby improving the recovery efficiency of the acidic water and avoiding waste of resources. On the other hand, it can prevent the acidic water with heavy pollution from retaining more impurities on its surface after being filtered by the activated carbon, thereby slowing down the subsequent flow rate of the acidic water, thereby ensuring the stable operation of the recovery and treatment work.
[0028] 4. The present invention degasses, deoils, removes toxic gases and organic matter, heavy metal ions, suspended impurities and pigments from acidic wastewater in sequence by designing a degassing tank, a deoiler, a recovery tank, a liquid inlet mechanism, a fusion mechanism, an air inlet mechanism and a filtering mechanism. Specifically:
[0029] Degassing is used to remove low-carbon hydrocarbons in acidic water to prevent equipment damage or even explosion when processing acidic water in the recovery tank, thereby improving the safety of recovery. The degassed acidic water is input into the deoiler for oil removal to prevent the subsequent acidic water from destroying the gas-liquid balance in the recovery tank due to oil content, resulting in operational disorder and affecting the treatment efficiency. The deoiled acidic water enters the recovery tank, and the separated waste gas is discharged from the exhaust pipe to ensure the recovery of beneficial water in the acidic water. The beneficial water is finally discharged from the drain pipe. By multi-stage treatment of the acidic water, the full recovery and utilization of the beneficial components therein is achieved, greatly improving the practicality of this system.
[0030] 5. The present invention realizes the sequential linkage of the fusion mechanism, the air intake mechanism and the air intake mechanism through the traction assembly and the transmission assembly, that is, the synchronous operation of the three mechanisms can be realized only through the single driving source of the electric push rod, which greatly reduces the power consumption of the recovery system and saves the cost of recycling acidic water. At the same time, it greatly reduces the overall structure of the system and reduces the construction cost of the system. BRIEF DESCRIPTION OF THE DRAWINGS
[0031] In order to more clearly illustrate the technical solution of the embodiment of the present invention, the drawings in the embodiment of the present invention are briefly introduced below.
[0032] Figure 1 It is a schematic diagram of the three-dimensional structure of the present invention;
[0033] Figure 2 A top view of the present invention;
[0034] Figure 3 for Figure 2 Plane section view along line AA;
[0035] Figure 4 for Figure 3 The enlarged view of point B in the figure;
[0036] Figure 5 The cross-sectional structure of the present invention is shown in FIG. Figure 1 ;
[0037] Figure 6 for Figure 5 The enlarged view of point C in the figure;
[0038] Figure 7 The cross-sectional structure of the present invention is shown in FIG. Figure 2 ;
[0039] Figure 8 for Figure 7 The enlarged view of D in the figure;
[0040] Fig. 9 It is a schematic diagram of the cross-sectional structure of the filter frame of the present invention;
[0041] Fig.10 It is a schematic diagram of the cross-sectional structure of the first evacuation plate and the second evacuation plate of the present invention;
[0042] Fig.11 for Fig.10 The enlarged view of point E in the figure;
[0043] In the figure: top cover 11, tank body 12, liquid inlet pipe 13, conical guide pipe 14, rotating assembly 15, first evacuation plate 16, second evacuation plate 17, adjustment assembly 18, slide bar 19, cover shell 20, air inlet pipe 21, traction assembly 22, conveying assembly 23, lifting assembly 24, air outlet head 25, activated carbon 26, filter frame 27, pressing assembly 28, transmission assembly 29, slide bar 30, support shell 31, discharge pipe 32, butt pipe 33, liquid outlet pipe 34, bearing 35, conical water receiving hole 36, cylindrical vent hole 37, electric push rod 38 , push block 39, push rod 40, ORP sensor 41, pull rod 42, lifting plate 43, connecting rod 44, rocker rod 45, first plug rod 46, rotating shaft 47, lifting rod 48, conical sealing plug 49, circulation ring 50, second plug rod 51, conveying channel 52, input pipe 53, air supply pipe 54, dispersion pipe 55, branch pipe 56, rotating rod 57, driving wheel 58, driven wheel 59, belt 60, wedge-shaped turntable 61, ball 62, return spring 63, baffle 64, conical guide shell 65, liquid supply pipe 66, exhaust pipe 67, discharge pipe 68. DETAILED DESCRIPTION
[0044] The technical solution of the present invention is further described below with reference to the accompanying drawings and through specific implementation methods.
[0045] Among them, the drawings are only used for illustrative purposes and represent only schematic diagrams rather than actual pictures, and should not be understood as limitations on this patent; in order to better illustrate the embodiments of the present invention, some parts of the drawings will be omitted, enlarged or reduced, and do not represent the size of the actual product.
[0046] Reference Figures 1 to 11 As shown, a gasoline hydrogenation acidic water recovery and utilization system includes a recovery tank, wherein the recovery tank includes a top cover 11 and a tank body 12, and the top cover 11 is fixed to the top of the tank body 12 by a plurality of bolts;
[0047] It also includes a controller, a liquid inlet mechanism, a fusion mechanism, an air inlet mechanism and a filtering mechanism;
[0048] The liquid inlet mechanism is arranged on the outer wall of the top cover 11, and the liquid inlet mechanism includes a liquid inlet pipe 13, a conical flow guide pipe 14 and a rotating assembly 15. The top of the top cover 11 is provided with a liquid inlet, the liquid inlet pipe 13 and the conical flow guide pipe 14 are fixedly arranged at the top and bottom of the liquid inlet, respectively, and the rotating assembly 15 is arranged at the bottom of the conical flow guide pipe 14;
[0049] The fusion mechanism is arranged on the recovery tank, and the fusion mechanism includes a first evacuation plate 16, a second evacuation plate 17 and an adjustment assembly 18. The first evacuation plate 16 is fixedly arranged on the inner top of the tank body 12, and the second evacuation plate 17 is slidably arranged below the second evacuation plate 17 through four slide bars 19. The adjustment assembly 18 is inserted on the outer wall of the top cover 11, and the second evacuation plate 17 is fixedly connected to the adjustment assembly 18;
[0050] The air intake mechanism is arranged on the outer wall of the tank body 12, and the air intake mechanism includes a cover 20, an air intake pipe 21, a traction assembly 22, a conveying assembly 23, a lifting assembly 24 and a plurality of air outlet heads 25. The air intake pipe 21 is inserted into the tank body 12, the cover 20 and the conveying assembly 23 are respectively fixed at both ends of the air intake pipe 21, the lifting assembly 24 is inserted into the cover 20, and a plurality of air outlet heads 25 are arranged at equal intervals on the conveying assembly 23, and the traction assembly 22 is arranged between the second evacuation plate 17 and the lifting assembly 24;
[0051] The filtering mechanism is arranged on the tank body 12, and the filtering mechanism includes activated carbon 26, a filter frame 27, a pressing assembly 28 and a transmission assembly 29. The filter frame 27 is slidably arranged on the inner bottom of the tank body 12 through two sliding rods 30. The activated carbon 26 is arranged inside the filter frame 27. The pressing assembly 28 is arranged between the transmission assembly 29 and one of the sliding rods 30. The transmission assembly 29 is arranged between the traction assembly 22 and the pressing assembly 28. The adjustment assembly 18 is electrically connected to the controller.
[0052] Reference Figures 1 to 11 As shown, the rotating assembly 15 includes a support shell 31, a discharge pipe 32, a docking pipe 33 and four liquid outlet pipes 34. A discharge port is provided at the bottom of the conical guide pipe 14. The discharge pipe 32 is fixedly arranged at the bottom end of the discharge port. The support shell 31 is fixedly arranged at the bottom of the conical guide pipe 14. The docking pipe 33 is rotatably arranged on the support shell 31 through a bearing 35. The diameter of the discharge pipe 32 is smaller than the diameter of the docking pipe 33. The four liquid outlet pipes 34 are arranged at equal intervals, and the docking pipe 33 is connected to the four liquid outlet pipes 34. When acid water is recovered, the acid water is first degassed through a degassing tank (not shown in the figure) to remove low-carbon hydrocarbons in the acid water, to prevent the recovery tank from treating the acid water and causing equipment damage or even explosion, to improve the safety of recovery, and the degassed acid water is input into a deoiler (not shown in the figure) for deoiling to avoid the subsequent acid water containing oil from destroying the gas-liquid balance in the recovery tank, resulting in The operation is disordered and affects the processing efficiency. The end of the liquid inlet pipe 13 away from the top cover 11 is connected to the output end of the deoiler, so that the acidic water after deoiling enters the interior of the conical guide pipe 14 through the liquid inlet pipe 13 and the liquid inlet. Since the discharge pipe 32 is fixedly connected to the discharge port at the bottom of the conical guide shell 65, the butt joint 33 is rotatably connected to the support shell 31 through the bearing 35, and the support shell 31 is fixedly connected to the conical guide shell 65. The discharge pipe 32 is inserted into the interior of the butt joint 33, and the diameter of the discharge pipe 32 is smaller than the diameter of the butt joint 33. The four liquid outlet pipes 34 are designed with equal intervals, and the butt joint 33 is connected to the four liquid outlet pipes 34. As a result, the acidic water falling from the butt joint 33 to the four liquid outlet pipes 34 will use the inertia of the acidic water flowing out to drive the four liquid outlet pipes 34 to rotate while entering the top of the first evacuation plate 16, thereby realizing the uniform transportation of the acidic water to the first evacuation plate 16.
[0053] Reference Figures 1 to 11 As shown, the tops of the first evacuation plate 16 and the second evacuation plate 17 are both provided with water receiving grooves, and the ends of the first evacuation plate 16 and the second evacuation plate 17 away from the water receiving grooves are respectively provided with conical water receiving holes 36 and cylindrical air vents 37, each of which is connected with a cylindrical air vent 37. When the acidic water is uniformly transported to the water receiving groove at the top of the first evacuation plate 16 by the four rotating liquid outlet pipes 34, the plurality of conical water receiving holes 36 on the first evacuation plate 16 disperse the batch of acidic water in the water receiving groove into a plurality of thin streams, which are transported to the top of the second evacuation plate 17 through the cylindrical air vents 37. At the same time, the high-temperature steam entering from the input pipe 53 enters the conveying channel 52 through the gap between the circulation ring 50 and the conical sealing plug 49, enters the air inlet pipe 21, and then passes through the air inlet pipe 21, the air delivery pipe 54, the dispersion pipe 55, the plurality of branch pipes 56 and A plurality of gas outlets 25 are transported from bottom to top inside the tank body 12 until they pass through a plurality of cylindrical vent holes 37 at the bottom of the second evacuation plate 17, and are discharged through a plurality of conical water receiving holes 36 on the second evacuation plate 17 to contact with the acidic water dripping from the first evacuation plate 16, so as to diffuse the volatile toxic gases in the acidic water into the steam in contact with it, such as toxic gases such as ammonia, hydrogen sulfide and carbon dioxide. It should be noted that the conical water receiving holes 36 and the cylindrical vent holes 37 on the second evacuation plate 17 are designed to be larger than the conical water receiving holes 36 and the cylindrical vent holes 37 on the first evacuation plate 16, so as to facilitate the acidic water to drip in a thin stream, while the high-temperature steam rises in a large stream, so as to achieve the wrapping of the thin stream of acidic water by the high-temperature steam, thereby improving the contact effect of the steam on the acidic water, and quickly extracting the toxic gases in the acidic water, which is beneficial to improving the treatment efficiency.
[0054] Reference Figures 1 to 11As shown, the regulating assembly 18 includes an electric push rod 38, a push block 39 and a push rod 40. A U-shaped plate is fixedly provided on the top of the top cover 11, and a guide rod is fixedly provided on the outer wall of the U-shaped plate. The electric push rod 38 is inserted at the top of the U-shaped plate, and the push block 39 is fixedly provided on the output end. The push block 39 is slidably provided on the outer wall of the guide rod. The push rod 40 is fixedly provided between the push block 39 and the second evacuation plate 17. The top cover 11 and the first evacuation plate 16 are both slidably connected to the push rod 40. An ORP sensor 41 is inserted on the outer wall of the liquid inlet pipe 13. The electric push rod 38 and the ORP sensor 41 are both electrically connected to the controller. When the ORP sensor 41 detects that the pollution degree of the acidic water entering the liquid inlet pipe 13 is relatively large, the amount of high-temperature steam to be delivered increases, thereby ensuring that there is sufficient high-temperature steam to be able to separate the acidic water with relatively large pollution. At this time, it is necessary to adjust the distance between the first evacuation plate 16 and the second evacuation plate 17 to reduce the entrainment of mist and foam and avoid affecting the separation effect. Therefore, when the acidic water pollution degree is detected to be large, the electric push rod 38 is started by the controller, so that its output end extends to the end close to the top cover 11. Since its output end is fixedly connected to the push block 39, the push block 39 is fixedly connected to the second evacuation plate 17 through the push rod 40, the top cover 11 and the first evacuation plate 16 are both slidably connected to the push rod 40, and the second evacuation plate 17 is slidably connected to the inside of the tank body 12, and then the second evacuation plate 17 is driven to drop to a certain height through the push rod 40 to prevent the entrainment of mist and foam, which is beneficial to improve the fusion of high-temperature steam and acidic water and improve the separation effect of toxic gases.
[0055] Reference Figures 1 to 11As shown, the traction assembly 22 includes a pull rod 42, a lifting plate 43, a connecting rod 44, two swing rods 45 and two first plug rods 46. The pull rod 42 is fixedly arranged on the top of the second evacuation plate 17, the top cover 11 and the first evacuation plate 16 are both slidably connected to the pull rod 42, the lifting plate 43 is fixedly arranged on the top of the pull rod 42, the connecting rod 44 is fixedly arranged on the bottom end of the lifting plate 43 away from the pull rod 42, the two first plug rods 46 are fixedly arranged on the bottom end of the connecting rod 44, and two support plates are fixedly arranged on the top of the cover 20, and a rotating shaft 47 is rotatably arranged between the two support plates. , the two swing rods 45 are fixed on the outer wall of the rotating shaft 47, and the two ends of each swing rod 45 are respectively provided with a first slot and a second slot, and each first plug rod 46 is plugged into a first slot. Since the pull rod 42 is fixedly connected to the second evacuation plate 17, the connecting rod 44 is connected to the pull rod 42 through the lifting plate 43, the top cover 11 and the first evacuation plate 16 are slidably connected to the pull rod 42, and the two plug rods are fixedly connected to the bottom end of the connecting rod 44. The two swing rods 45 are rotatably connected to the two support plates through the rotating shaft 47. Each swing rod 45 is designed with a first slot and a second slot at both ends of the rotating shaft 47, and each first plug rod 46 is plugged into a first slot. Therefore, when the second evacuation plate 17 slides down, the downward pressure applied by the two first plug rods 46 in the two first slots forces the two swing rods 45 to rotate counterclockwise with the rotating shaft 47 as the center.
[0056] Reference Figures 1 to 11 As shown, the lifting assembly 24 includes a lifting rod 48, a conical sealing plug 49, a circulation ring 50 and two second plug rods 51. The lifting rod 48 is slidably arranged on the cover 20, and the conical sealing plug 49 is fixedly arranged at the bottom end of the lifting rod 48. The interior of the cover 20 is integrally formed with a delivery channel 52. An input pipe 53 is fixedly arranged at the bottom of the cover 20. The input pipe 53, the delivery channel 52 and the intake pipe 21 are connected in sequence. The circulation ring 50 is fixedly arranged on the inner wall of the input pipe 53. The conical sealing plug 49 is consistent with the axial direction of the circulation ring 50. The two second plug rods 51 are fixedly arranged at the top of the lifting rod 48. Each second plug rod 51 is plugged into a second slot. Since the lifting rod 48 It is slidably connected to the cover shell 20, and the conical sealing plug 49 is fixedly connected to the bottom end of the lifting rod 48. The two second plug rods 51 are fixedly connected to the top of the lifting rod 48, and each second plug rod 51 is plugged into a second slot. Then, when the two rocker arms 45 rotate counterclockwise with the rotating shaft 47 as the center, the conical sealing plug 49 is driven by the lifting rod 48 to rise to the top of the circulation ring 50, so that the circulation ring 50 is no longer blocked, thereby increasing the high-temperature steam delivery rate passing through the circulation ring 50, and then increasing the high-temperature steam delivery rate entering the tank body 12, which can reduce the partial pressure in the gas phase, thereby promoting the volatile components in the acidic water to enter the gas phase more easily, and achieving an effective separation effect of toxic gases.
[0057] Reference Figures 1 to 11 As shown, the conveying assembly 23 includes an air supply pipe 54, a dispersion pipe 55 and a plurality of branch pipes 56. The air supply pipe 54 is fixedly arranged at one end of the air inlet pipe 21 away from the housing 20, and the dispersion pipe 55 is fixedly arranged at one end of the air supply pipe 54 away from the air inlet pipe 21. A plurality of branch pipes 56 are arranged on the outer wall of the dispersion pipe 55 at equal intervals. A plurality of gas outlet heads 25 are respectively fixedly connected to a plurality of branch pipes 56. High-temperature steam enters the conveying channel 52 in the housing 20 from the input pipe 53, and then enters the air inlet pipe 21 from the conveying channel 52. The air inlet pipe 21, the air supply pipe 54, the dispersion pipe 55, the plurality of branch pipes 56 and the plurality of gas outlet heads 25 are connected in sequence, so that the high-temperature steam is discharged from the plurality of gas outlet heads 25 and rises to the inner top of the tank body 12 to facilitate contact with the acidic water. Here, it should be noted that the plurality of gas outlet heads 25 are distributed in a circular array, and the high-temperature steam diffused upward can be in uniform contact with the acidic water dripping from the second evacuation plate 17, which is conducive to improving the fusion of the two, thereby improving the extraction efficiency of the poisonous gas in the acidic water.
[0058] Reference Figures 1 to 11 As shown, the transmission assembly 29 includes a rotating rod 57, a driving wheel 58, a driven wheel 59 and a belt 60. The rotating rod 57 is fixedly arranged at one end of the rotating shaft 47, and the driving wheel 58 is fixedly arranged at the end of the rotating rod 57 away from the rotating shaft 47. An L-shaped plate is fixedly arranged on the outer wall of the tank body 12, and a hinge shaft is rotatably arranged on the L-shaped plate. The driven wheel 59 is fixedly arranged on the hinge shaft. The belt 60 is sleeved between the driving wheel 58 and the driven wheel 59, and the diameter of the driving wheel 58 is larger than the diameter of the driven wheel 59. Each time the rotating shaft 47 drives the two rocking rods 45 to rotate counterclockwise, since the rotating shaft 47 is fixedly connected to one end of the rotating rod 57, the rotating rod 57 is fixedly connected to the driving wheel 58, and the driven wheel 59 is rotationally connected to the L-shaped plate through the hinge shaft. The driving wheel 58 and the driven wheel 59 are sleeved by the belt 60, thereby driving the hinge shaft to rotate.
[0059] Reference Figures 1 to 11As shown, the pressing assembly 28 includes a wedge-shaped turntable 61, a ball 62, a return spring 63 and a baffle 64. The ball 62 is rotatably arranged on one of the slide bars 30 close to the driven wheel 59, the baffle 64 is fixedly arranged on one of the slide bars 30 close to the driven wheel 59, the return spring 63 is sleeved on one of the slide bars 30 close to the driven wheel 59, a limit plate is fixedly arranged on the outer wall of the L-shaped plate, the baffle 64 and the limit plate respectively contact with the two ends of the return spring 63, the wedge-shaped turntable 61 is fixedly arranged on the hinge shaft, the outer wall of one end of the wedge-shaped turntable 61 is in contact with the outer edge of the ball 62, a conical guide shell 65 is fixedly arranged on the inner wall of the tank body 12, and a liquid delivery pipe 66 is fixedly arranged at the bottom of the conical guide shell 65. When the hinge shaft rotates, due to the wedge The wedge-shaped turntable 61 is fixedly connected to the hinge shaft. In the initial state, the outer wall of the narrow section of the wedge-shaped turntable 61 fits with the ball 62, so that the long section and the narrow section of the wedge-shaped turntable 61 are swapped, and the long section is used to resist the ball 62. Since the ball 62 is rotatably connected to one of the slide bars 30 close to the driven wheel 59, the filter frame 27 is slidably connected to the inside of the tank body 12 through two slide bars 30, and then the filter frame 27 is pushed horizontally through one of the slide bars 30 to achieve the shaking of the filter frame 27, which can throw off the acidic water adhering to the surface of the activated carbon 26, improve the recovery efficiency of the acidic water, and avoid waste of resources. When the lifting rod 48 drives the conical sealing plug 49 to reset, the reset spring 63 cooperates with the baffle 64 to drive one of the slide bars close to the driven wheel 59 to reset.
[0060] Reference Figures 1 to 11 As shown, an exhaust pipe 67 is fixedly provided on the outer wall of the top cover 11, and a drain pipe 68 is fixedly provided at the bottom of the tank body 12. The toxic gas separated from the acidic water is discharged from the exhaust pipe 67, and the acidic water after the toxic gas is removed falls into the interior of the conical guide shell 65, and falls into the interior of the frame through the liquid delivery pipe 66 at the bottom center thereof. An opening is provided at the bottom of the filter frame 27, and the activated carbon 26 in the filter frame 27 filters the acidic water after the toxic gas is removed, and absorbs organic matter, heavy metal ions, suspended impurities and pigments in the acidic water. The acidic water treated with the activated carbon 26 falls into the drain pipe 68 at the bottom of the tank body 12 from the opening at the bottom of the filter frame 27, and is discharged from the exhaust pipe 67 after degassing, oil removal, toxic gas removal and filtration, thereby realizing the recycling of beneficial water.
[0061] The working principle of the present invention is as follows: when acidic water is recovered, the acidic water is first degassed through a degassing tank (not shown in the figure) to remove low-carbon hydrocarbons in the acidic water, to prevent the recovery tank from processing acidic water and causing equipment damage or even explosion, and to improve the safety of recovery. The degassed acidic water is input into a deoiler (not shown in the figure) for deoiling to prevent the subsequent acidic water from destroying the gas-liquid balance in the recovery tank due to oil content, resulting in operational disorder and affecting the treatment efficiency. The end of the liquid inlet pipe 13 away from the top cover 11 is connected to the output end of the deoiler, so that the deoiled acidic water enters the interior of the conical guide pipe 14 through the liquid inlet pipe 13 and the liquid inlet port, and the discharge pipe 32 It is fixedly connected to the discharge port at the bottom of the conical guide shell 65, the butt joint pipe 33 is rotatably connected to the support shell 31 through a bearing 35, the support shell 31 is fixedly connected to the conical guide shell 65, the discharge pipe 32 is inserted into the inside of the butt joint pipe 33, and the diameter of the discharge pipe 32 is smaller than the diameter of the butt joint pipe 33, the four liquid outlet pipes 34 are designed with equal intervals, and the butt joint pipe 33 is connected to the four liquid outlet pipes 34, so that the acidic water falling from the butt joint pipe 33 to the four liquid outlet pipes 34 will use the inertia of the outflow of the acidic water to drive the four liquid outlet pipes 34 to rotate when entering the top of the first evacuation plate 16, thereby realizing the uniform transportation of the acidic water to the first evacuation plate 16.
[0062] When the acidic water is uniformly transported from the four rotating liquid outlet pipes 34 to the water receiving trough at the top of the first evacuation plate 16, the conical water receiving holes 36 on the first evacuation plate 16 disperse the batch of acidic water in the water receiving trough into a plurality of thin streams, which are transported to the top of the second evacuation plate 17 through the cylindrical vent holes 37. At the same time, the high-temperature steam entering from the input pipe 53 enters the transport channel 52 through the gap between the circulation ring 50 and the conical sealing plug 49, and enters the air inlet pipe 21, and then passes through the air inlet pipe 21, the air delivery pipe 54, the dispersion pipe 55, the plurality of branch pipes 56 and the plurality of air outlet heads 25 in sequence, and is transported from bottom to top inside the tank body 12 until it passes through the plurality of cylindrical vent holes 37 at the bottom of the second evacuation plate 17. And it is discharged through several conical water receiving holes 36 on the second evacuation plate 17 to contact with the acidic water dripping from the first evacuation plate 16, and the volatile poisonous gas in the acidic water is diffused into the steam in contact with it, such as poisonous gases such as ammonia, hydrogen sulfide and carbon dioxide. It should be noted that the conical water receiving holes 36 and the cylindrical air vents 37 on the second evacuation plate 17 are designed to be larger than the conical water receiving holes 36 and the cylindrical air vents 37 on the first evacuation plate 16, in order to facilitate the acidic water to drip in a thin stream, while the high-temperature steam rises in a large stream, so as to achieve the wrapping of the thin stream of acidic water by the high-temperature steam, thereby improving the contact effect of steam on the acidic water, and quickly extracting the poisonous gas in the acidic water, which is beneficial to improving the treatment efficiency.
[0063] The poisonous gas separated from the acidic water is discharged from the exhaust pipe 67, and the acidic water after the poisonous gas is removed falls into the interior of the conical guide shell 65, and falls into the interior of the frame through the liquid delivery pipe 66 at the bottom center thereof. An opening is provided at the bottom of the filter frame 27, and the activated carbon 26 in the filter frame 27 filters the acidic water after the poisonous gas is removed, and absorbs organic matter, heavy metal ions, suspended impurities and pigments in the acidic water. The acidic water treated with the activated carbon 26 falls into the drain pipe 68 at the bottom of the tank body 12 through the opening at the bottom of the filter frame 27, and is discharged from the exhaust pipe 67 after degassing, oil removal, poisonous gas removal and filtration, thereby realizing the recycling of beneficial water.
[0064] When the ORP sensor 41 detects that the acidic water entering the liquid inlet pipe 13 has a high degree of contamination, the amount of high-temperature steam that needs to be transported increases, so as to ensure that the high-temperature steam is fully integrated with the acidic water with a high degree of contamination, thereby improving the separation efficiency of the toxic gas. At this time, it is necessary to adjust the distance between the first evacuation plate 16 and the second evacuation plate 17 to reduce the entrainment of mist and foam and avoid affecting the separation effect. Therefore, when it is detected that the acidic water has a high degree of contamination, the electric push rod 38 is started by the controller, so that its output end extends to the end close to the top cover 11. Since its output end is fixedly connected to the push block 39, the push block 39 is fixedly connected to the second evacuation plate 17 through the push rod 40, the top cover 11 and the first evacuation plate 16 are both slidably connected to the push rod 40, and the second evacuation plate 17 is slidably connected to the inside of the tank body 12, and then the second evacuation plate 17 is driven to drop to a certain height through the push rod 40 to prevent the entrainment of mist and foam, which is beneficial to improving the fusion of high-temperature steam and acidic water and improving the separation effect of toxic gases.
[0065] Since the pull rod 42 is fixedly connected to the second evacuation plate 17, the connecting rod 44 is connected to the pull rod 42 through the lifting plate 43, the top cover 11 and the first evacuation plate 16 are both slidably connected to the pull rod 42, and the two insertion rods are fixedly connected to the bottom end of the connecting rod 44. The two rocker arms 45 are rotatably connected to the two support plates through the rotating shaft 47. Each rocker arm 45 is respectively designed with a first slot and a second slot at both ends of the rotating shaft 47, and each first insertion rod 46 is plugged into a first slot. Therefore, when the second evacuation plate 17 slides down, the downward pressure applied by the two first insertion rods 46 in the two first slots forces the two rocker arms 45 to rotate counterclockwise around the rotating shaft 47 as the center.
[0066] Since the lifting rod 48 is slidably connected to the cover shell 20, the conical sealing plug 49 is fixedly connected to the bottom end of the lifting rod 48, and the two second plug rods 51 are fixedly connected to the top of the lifting rod 48, and each second plug rod 51 is plugged into a second slot, and then when the two rocker arms 45 rotate counterclockwise with the rotating shaft 47 as the center, the conical sealing plug 49 is driven by the lifting rod 48 to rise to the top of the circulation ring 50, so that the circulation ring 50 is no longer blocked, thereby increasing the high-temperature steam delivery rate passing through the circulation ring 50, and then increasing the high-temperature steam delivery rate entering the tank body 12, which can reduce the partial pressure in the gas phase, and then promote the volatile components in the acidic water to enter the gas phase more easily, thereby achieving an effective steam stripping effect.
[0067] Each time the rotating shaft 47 drives the two rocking arms 45 to rotate counterclockwise, since the rotating shaft 47 is fixedly connected to one end of the rotating rod 57, the rotating rod 57 is fixedly connected to the driving wheel 58, the driven wheel 59 is rotationally connected to the L-shaped plate through the hinge shaft, and the driving wheel 58 and the driven wheel 59 are connected by a belt 60, thereby driving the hinge shaft to rotate.
[0068] When the hinge shaft rotates, since the wedge-shaped turntable 61 is fixedly connected to the hinge shaft, the outer wall of the narrow section of the wedge-shaped turntable 61 is initially in contact with the ball 62, so that the long section and the narrow section of the wedge-shaped turntable 61 are swapped, and the long section is used to resist the ball 62. Since the ball 62 is rotatably connected to one of the sliding rods 30 close to the driven wheel 59, the filter frame 27 is slidably connected to the inside of the tank body 12 through two sliding rods 30, and then the filter frame 27 is pushed laterally through one of the sliding rods 30 to achieve the shaking of the filter frame 27, which can shake off the acidic water adhering to the surface of the activated carbon 26, thereby improving the recovery efficiency of the acidic water and avoiding waste of resources.
Claims
1. A gasoline hydrogenation acidic water recovery and utilization system, comprising a recovery tank, wherein the recovery tank comprises a top cover (11) and a tank body (12), wherein the top cover (11) is fixed to the top of the tank body (12) by a plurality of bolts, and wherein: It also includes a controller, a liquid inlet mechanism, a fusion mechanism, an air inlet mechanism and a filtering mechanism; The liquid inlet mechanism is arranged on the outer wall of the top cover (11), and comprises a liquid inlet pipe (13), a conical flow guide pipe (14) and a rotating assembly (15); a liquid inlet is arranged on the top of the top cover (11); the liquid inlet pipe (13) and the conical flow guide pipe (14) are respectively fixedly arranged on the top and bottom of the liquid inlet; and the rotating assembly (15) is arranged on the bottom of the conical flow guide pipe (14); The fusion mechanism is arranged on the recovery tank, and comprises a first evacuation plate (16), a second evacuation plate (17) and an adjustment assembly (18); the first evacuation plate (16) is fixedly arranged on the inner top of the tank body (12); the second evacuation plate (17) is slidably arranged below the second evacuation plate (17) through four slide bars (19); the adjustment assembly (18) is inserted into the outer wall of the top cover (11); and the second evacuation plate (17) is fixedly connected to the adjustment assembly (18); The air intake mechanism is arranged on the outer wall of the tank body (12), and comprises a cover (20), an air intake pipe (21), a traction assembly (22), a conveying assembly (23), a lifting assembly (24), and a plurality of air outlet heads (25); the air intake pipe (21) is inserted into the tank body (12); the cover (20) and the conveying assembly (23) are respectively fixed at two ends of the air intake pipe (21); the lifting assembly (24) is inserted into the cover (20); the plurality of air outlet heads (25) are arranged at equal intervals on the conveying assembly (23); and the traction assembly (22) is arranged between the second evacuation plate (17) and the lifting assembly (24); The filter mechanism is arranged on the tank body (12), and comprises activated carbon (26), a filter frame (27), a pressing assembly (28) and a transmission assembly (29); the filter frame (27) is slidably arranged on the inner bottom of the tank body (12) via two slide bars (30); the activated carbon (26) is arranged inside the filter frame (27); the pressing assembly (28) is arranged between the transmission assembly (29) and one of the slide bars (30); the transmission assembly (29) is arranged between the traction assembly (22) and the pressing assembly (28); and the adjustment assembly (18) is electrically connected to the controller.
2. A gasoline hydrogenation acidic water recovery and utilization system according to claim 1, characterized in that: The rotating assembly (15) comprises a supporting shell (31), a discharge pipe (32), a butt joint pipe (33) and four liquid outlet pipes (34); a liquid outlet is provided at the bottom of the conical flow guide pipe (14); the discharge pipe (32) is fixedly arranged at the bottom end of the liquid outlet; the supporting shell (31) is fixedly arranged at the bottom of the conical flow guide pipe (14); the butt joint pipe (33) is rotatably arranged on the supporting shell (31) via a bearing (35); the diameter of the discharge pipe (32) is smaller than the diameter of the butt joint pipe (33); the four liquid outlet pipes (34) are arranged at equal intervals, and the butt joint pipe (33) is connected to the four liquid outlet pipes (34).
3. A gasoline hydrogenation acidic water recovery and utilization system according to claim 2, characterized in that: The tops of the first evacuation plate (16) and the second evacuation plate (17) are both provided with water receiving grooves, and the ends of the first evacuation plate (16) and the second evacuation plate (17) away from the water receiving grooves are both provided with conical water receiving holes (36) and cylindrical air vents (37), respectively, and each conical water receiving hole (36) is connected to a cylindrical air vent (37).
4. A gasoline hydrogenation acidic water recovery and utilization system according to claim 3, characterized in that: The regulating assembly (18) comprises an electric push rod (38), a push block (39) and a push rod (40); a U-shaped plate is fixedly provided on the top of the top cover (11); a guide rod is fixedly provided on the outer wall of the U-shaped plate; the electric push rod (38) is inserted into the top of the U-shaped plate; the push block (39) is fixedly provided on the output end; the push block (39) is slidably provided on the outer wall of the guide rod; the push rod (40) is fixedly provided between the push block (39) and the second evacuation plate (17); the top cover (11) and the first evacuation plate (16) are both slidably connected to the push rod (40); an ORP sensor (41) is inserted into the outer wall of the liquid inlet pipe (13); and the electric push rod (38) and the ORP sensor (41) are both electrically connected to the controller.
5. A gasoline hydrogenation acidic water recovery and utilization system according to claim 4, characterized in that: The traction assembly (22) comprises a pull rod (42), a lifting plate (43), a connecting rod (44), two swing rods (45) and two first plug rods (46); the pull rod (42) is fixedly arranged on the top of the second evacuation plate (17); the top cover (11) and the first evacuation plate (16) are both slidably connected to the pull rod (42); the lifting plate (43) is fixedly arranged on the top of the pull rod (42); the connecting rod (44) is fixedly arranged on the bottom end of the lifting plate (43) away from the pull rod (42); the two first plug rods (46) are fixedly arranged on the bottom end of the connecting rod (44); two support plates are fixedly arranged on the top of the cover shell (20); a rotating shaft (47) is rotatably arranged between the two support plates; the two swing rods (45) are fixedly arranged on the outer wall of the rotating shaft (47); each swing rod (45) is provided with a first slot and a second slot at both ends, respectively; and each first plug rod (46) is plugged into a first slot.
6. A gasoline hydrogenation acidic water recovery and utilization system according to claim 5, characterized in that: The lifting assembly (24) comprises a lifting rod (48), a conical sealing plug (49), a circulation ring (50) and two second plug rods (51); the lifting rod (48) is slidably mounted on the cover (20); the conical sealing plug (49) is fixedly mounted on the bottom end of the lifting rod (48); the interior of the cover (20) is integrally formed with a delivery channel (52); an input pipe (53) is fixedly mounted on the bottom of the cover (20); the input pipe (53), the delivery channel (52) and the air inlet pipe (21) are sequentially connected; the circulation ring (50) is fixedly mounted on the inner wall of the input pipe (53); the conical sealing plug (49) and the circulation ring (50) are aligned in axial direction; the two second plug rods (51) are fixedly mounted on the top end of the lifting rod (48); and each second plug rod (51) is plugged into a second slot.
7. A gasoline hydrogenation acidic water recovery and utilization system according to claim 6, characterized in that: The conveying assembly (23) comprises an air supply pipe (54), a dispersion pipe (55) and a plurality of branch pipes (56); the air supply pipe (54) is fixedly arranged at one end of the air inlet pipe (21) away from the housing (20); the dispersion pipe (55) is fixedly arranged at one end of the air supply pipe (54) away from the air inlet pipe (21); the plurality of branch pipes (56) are arranged at equal intervals on the outer wall of the dispersion pipe (55); and the plurality of air outlet heads (25) are respectively fixedly connected to the plurality of branch pipes (56).
8. A gasoline hydrogenation acidic water recovery and utilization system according to claim 7, characterized in that: The transmission assembly (29) comprises a rotating rod (57), a driving wheel (58), a driven wheel (59) and a belt (60). The rotating rod (57) is fixedly arranged at one end of the rotating shaft (47), the driving wheel (58) is fixedly arranged at one end of the rotating rod (57) away from the rotating shaft (47), an L-shaped plate is fixedly arranged on the outer wall of the tank body (12), a hinge shaft is rotatably arranged on the L-shaped plate, the driven wheel (59) is fixedly arranged on the hinge shaft, and the belt (60) is sleeved between the driving wheel (58) and the driven wheel (59), and the diameter of the driving wheel (58) is larger than the diameter of the driven wheel (59).
9. A gasoline hydrogenation acidic water recovery and utilization system according to claim 8, characterized in that: The pressing assembly (28) comprises a wedge-shaped turntable (61), a ball (62), a return spring (63) and a baffle (64). The ball (62) is rotatably arranged on one of the slide bars (30) close to the driven wheel (59). The baffle (64) is fixedly arranged on one of the slide bars (30) close to the driven wheel (59). The return spring (63) is sleeved on one of the slide bars (30) close to the driven wheel (59). A limit plate is fixedly arranged on the outer wall of the L-shaped plate. The baffle (64) and the limit plate respectively contact with two ends of the return spring (63). The wedge-shaped turntable (61) is fixedly arranged on the hinge shaft. The outer wall of one end of the wedge-shaped turntable (61) is in contact with the outer edge of the ball (62). A conical guide shell (65) is fixedly arranged on the inner wall of the tank body (12). A liquid delivery pipe (66) is fixedly arranged at the bottom of the conical guide shell (65).
10. A gasoline hydrogenation acidic water recovery and utilization system according to claim 9, characterized in that: An exhaust pipe (67) is fixedly provided on the outer wall of the top cover (11), and a liquid discharge pipe (68) is fixedly provided on the bottom of the tank body (12).
Citation Information
Patent Citations
Plate type rectifying tower
CN115068967A
Energy-saving and consumption-reducing rectifying tower with adjustable tower plate spacing and technological process of energy-saving and consumption-reducing rectifying tower
CN116251373A