A method, medium, and apparatus for seawater electrolysis

By constructing modified transition metal electrodes and optimizing catalyst reaction conditions, combined with high-entropy alloys and pH gradient electrolysis cells, the problem of high energy consumption and low efficiency in seawater electrolysis was solved, and low-energy, high-efficiency preparation of hypochlorous acid solution was achieved.

CN119287389BActive Publication Date: 2025-11-18FUJIAN HADA INTELLIGENCE TECH CO LTD
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Patent Information

Application Number
CN202411322684.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-09-23
Publication Date
2025-11-18
Estimated Expiration
2044-09-23

AI Technical Summary

Technical Problem

In the existing technology for preparing hypochlorous acid by seawater electrolysis, there are problems of high energy consumption and low efficiency. In particular, when titanium plates are used as cathode materials, the activity is low and is greatly affected by electrode surface parameters and pH gradient.

Method used

By constructing a transition metal electrode and modifying its surface, the reaction conditions of the catalyst were optimized using a neural network model. Combined with a high-entropy alloy and a pH gradient acid-base asymmetric electrolysis cell, the optimal catalyst was prepared to electrolyze seawater to produce hypochlorous acid solution.

Benefits of technology

This improved the efficiency of seawater electrolysis, effectively saved power consumption, and enabled the efficient preparation of hypochlorous acid solution with low energy consumption.

✦ Generated by Eureka AI based on patent content.

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Abstract

The application provides a seawater electrolysis method, medium and device, reaction conditions of a catalyst, component content and distribution state of different surfaces of an electrode are analyzed by introducing a neural network model, the relationship between morphology, structure and catalytic activity and the influence of electrocatalytic selectivity are further investigated, and the correlation between the total combined component conditions and electrocatalytic activity is established. Through the scheme of the application, the influence law of the component content and distribution state of the electrode on the performance of the catalyst can be summarized, and the targeted synthesis of different component catalysts is studied, and the optimal catalytic composition and structure are established. Then the optimal catalyst is added to the electrolysis device, and a hypochlorous acid solution is prepared by electrolyzing seawater. Compared with the prior art, the seawater electrolysis efficiency can be improved, and the power consumption can be effectively saved.
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Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of water source desalination, in particular to a seawater electrolysis method, medium and device. BACKGROUND

[0002] At present, in the industry, the titanium plate is generally used as the cathode material for electrolyzing seawater to prepare hypochlorous acid, which has the problem of low activity, and the electrolysis efficiency is affected by the electrode surface related parameters and the pH gradient of the electrolyte. Different pH gradients have different effects on the hydrogen production efficiency, hypochlorous acid production efficiency, reaction voltage and energy consumption. How to realize low-energy-consumption electrolysis of seawater to prepare hydrogen and high-value-added chemical products such as hypochlorous acid has been a research topic in the field. SUMMARY

[0003] Therefore, it is necessary to provide a seawater electrolysis technical scheme to solve the problems of high energy consumption and low seawater electrolysis efficiency in the prior art.

[0004] To solve the above problems, in a first aspect, the present application provides a seawater electrolysis method, which comprises the following steps:

[0005] Constructing a transition metal electrode and modifying the surface of the transition metal electrode to obtain a modified transition metal electrode;

[0006] Inputting the initial catalyst reaction conditions and the initial experimental result data into a first neural network model for iterative updating to obtain improved catalyst reaction conditions, and under the conditions of the improved catalyst reaction conditions, preparing catalysts on different surfaces of the transition metal electrode;

[0007] Inputting the component content and distribution state of different surfaces of the sample electrode into the trained second neural network model to analyze the influence of the component content and distribution state of different surfaces of the sample electrode on the correlation of the catalyst activity, and obtaining the mapping relationship between the component content and distribution state and the catalyst related parameters, including the catalyst components and structure;

[0008] Obtaining the component content and distribution state of different surfaces of the transition metal electrode, obtaining the optimal related parameters of the catalyst on different surfaces according to the mapping relationship, and preparing the optimal catalyst according to the optimal related parameters;

[0009] Adding the optimal catalyst to the electrolysis device to electrolyze seawater to prepare a hypochlorous acid solution.

[0010] Further, the constructing a transition metal electrode and modifying the surface of the transition metal electrode comprises:

[0011] A multi-element high-entropy alloy transition metal electrode is constructed by combining electrolysis and electrodeposition with high-temperature atmosphere calcination method, and the surface of the transition metal electrode is modified by phosphating and sulfidizing methods.

[0012] Further, the method further comprises:

[0013] The cocktail effect of high-entropy alloys is utilized to alloyize multi-element non-noble metals, and the specific surface area of the transition metal electrode is improved by local low-dimensional nanocrystallization.

[0014] Further, the initial catalyst reaction conditions include a reaction solvent, a reaction ligand, and reaction basic parameters including reaction time, temperature, and concentration.

[0015] Further, the influence of the composition content and distribution state of different surfaces of the analysis sample electrode on the correlation of catalyst activity includes:

[0016] The characterization technology is used to highlight the surface structure and element valence difference of the transition metal electrode, and the influence of the composition content and distribution state of different surfaces on the correlation of catalyst activity is obtained by correlating the improved catalyst reaction conditions.

[0017] Further, the method comprises:

[0018] When electrolyzing seawater, a pH gradient asymmetric electrolytic cell is constructed, specifically including:

[0019] Acidic seawater is used as the cathode, and alkaline seawater is used as the anode, and corresponding pH gradients are provided for the cathode and anode reactions.

[0020] Further, the electrolysis device comprises a reaction barrel (1), a fourth connecting pipe (48) is fixedly connected to the top right side of the reaction barrel (1), a dustproof pipe is fixedly connected to the front end of the fourth connecting pipe (48), a compensation assembly is arranged at the left top end of the dustproof pipe, a third connecting pipe (46) is fixedly connected to the left bottom end of the dustproof pipe, a first control valve is fixedly connected to the bottom end of the third connecting pipe (46), a jet (44) is fixedly connected to the bottom end of the first control valve, a delivery pump (43) is fixedly connected to the right side of the jet (44), a second connecting pipe (42) is fixedly connected to the top end of the delivery pump (43), a three-way valve (41) is fixedly connected to the top end of the second connecting pipe (42), a communication pipe (5) is fixedly connected to the right side of the three-way valve (41), a first connecting pipe (4) is fixedly connected to the left side of the three-way valve (41), the first connecting pipe (4) is fixedly connected with the reaction barrel (1), and a refinement assembly is arranged at the bottom end of the reaction barrel (1).

[0021] Further, the refining assembly comprises a second connecting rod, a support ring is fixedly connected to the inner side of the bottom end of the reaction barrel (1), a first air inlet pipe is fixedly connected to the inner side of the middle end of the support ring, and a spiral pipe is fixedly connected to the right side of the first air inlet pipe.

[0022] In a second aspect, the present application provides a computer readable storage medium, which stores a computer program, and the program is executed by a processor to realize the seawater electrolysis method of the first aspect of the present application.

[0023] In a third aspect, the present application provides an electronic device, which stores a computer program, and comprises a processor and a storage medium, and the storage medium stores a computer program, and the computer program is executed by the processor to realize the seawater electrolysis method of the first aspect of the present application.

[0024] Compared with the prior art, the seawater electrolysis method, medium and device of the present application analyze the reaction conditions of the catalyst, the component content and distribution state of different surfaces of the electrode, further investigate the relationship between the morphology, structure and catalytic activity and the influence of the electrocatalytic selectivity, and establish the correlation between the total combination conditions and the electrocatalytic activity. Through the scheme of the present application, the influence of the component content and distribution state of the electrode on the performance of the catalyst can be summarized, and the targeted synthesis of different component catalysts can be researched, and the optimal catalytic composition and structure can be established. Then the optimal catalyst is added to the electrolysis device, and the hypochlorous acid solution is prepared by electrolyzing seawater. Compared with the prior art, the seawater electrolysis efficiency can be improved, and the power consumption can be effectively saved. BRIEF DESCRIPTION OF DRAWINGS

[0025] In order to more clearly illustrate the technical solutions in the embodiments of the present application, the drawings needed in the embodiment description will be briefly introduced. Obviously, the drawings in the following description are only some embodiments of the present application, and other drawings can be obtained by those skilled in the art without creative labor.

[0026] Figure 1 The flow chart of the seawater electrolysis method described in an exemplary embodiment of the present application;

[0027] Figure 2 The principle diagram of electrolyzing seawater described in an exemplary embodiment of the present application;

[0028] Figure 3 The technical route diagram of reducing the energy consumption of electrolyzing seawater described in an exemplary embodiment of the present application;

[0029] Figure 4 The structural schematic diagram of the electrolysis device described in an exemplary embodiment of the present application;

[0030] Figure 5 A module schematic diagram of the electronic device described in an exemplary embodiment of the present application;

[0031] Explanation of reference numerals:

[0032] 1. Reaction barrel

[0033] 11. Support leg

[0034] 2. Motor

[0035] 4. First connecting pipe

[0036] 41. Three-way valve

[0037] 42. Second connecting pipe

[0038] 43. Delivery pump

[0039] 44. Jetting device

[0040] 46. Third connecting pipe

[0041] 48. Fourth connecting pipe

[0042] 5. Communication pipe

[0043] 51. Compensation bottle

[0044] 10. Electronic device

[0045] 101. Processor

[0046] 102. Storage medium DETAILED DESCRIPTION

[0047] In order to describe the technical content, structural features, purposes and effects of the technical scheme in detail, the following will be described in detail in combination with specific embodiments and the accompanying drawings.

[0048] The embodiments of the technical scheme of the present application will be described in detail below in combination with the accompanying drawings. The following embodiments are only used to more clearly illustrate the technical scheme of the present application, and therefore only serve as examples, and cannot limit the protection scope of the present application.

[0049] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present application belongs; the terms used herein are only for the purpose of describing specific embodiments of the present application, and are not intended to limit the present application; the terms "include" and "have" and any variations thereof in the specification and claims of the present application and the above description of drawings are intended to cover not exclusive inclusion.

[0050] In the description of the embodiments of this application, technical terms such as "first" and "second" are used only to distinguish different objects and should not be construed as indicating or implying relative importance or implicitly specifying the number, specific order, or primary and secondary relationship of the indicated technical features. In the description of the embodiments of this application, "multiple" means two or more, unless otherwise explicitly defined.

[0051] In this document, the term "embodiment" means that a particular feature, structure, or characteristic described in connection with an embodiment may be included in at least one embodiment of this application. The appearance of this phrase in various places throughout the specification does not necessarily refer to the same embodiment, nor is it a separate or alternative embodiment mutually exclusive with other embodiments. It will be explicitly and implicitly understood by those skilled in the art that the embodiments described herein can be combined with other embodiments.

[0052] In the description of the embodiments in this application, the term "and / or" is merely a description of the relationship between related objects, indicating that three relationships can exist. For example, A and / or B can represent: A existing alone, A and B existing simultaneously, and B existing alone. Additionally, the character " / " in this document generally indicates that the preceding and following related objects have an "or" relationship.

[0053] In the description of the embodiments of this application, the term "multiple" refers to two or more (including two), similarly, "multiple sets" refers to two or more (including two sets), and "multiple pieces" refers to two or more (including two pieces).

[0054] In the description of the embodiments of this application, the technical terms "center," "longitudinal," "lateral," "length," "width," "thickness," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," "clockwise," "counterclockwise," "axial," "radial," and "circumferential" indicate the orientation or positional relationship based on the orientation or positional relationship shown in the accompanying drawings. They are only for the convenience of describing the embodiments of this application and simplifying the description, and are not intended to indicate or imply that the device or element referred to must have a specific orientation, or be constructed and operated in a specific orientation. Therefore, they should not be construed as limitations on the embodiments of this application.

[0055] In the description of the embodiments of this application, unless otherwise expressly specified and limited, the technical terms such as "installation," "connection," "joining," and "fixing" should be interpreted broadly. For example, they can refer to a fixed connection, a detachable connection, or an integral part; they can refer to a mechanical connection or an electrical connection; they can refer to a direct connection or an indirect connection through an intermediate medium; they can refer to the internal communication of two components or the interaction between two components. Those skilled in the art can understand the specific meaning of the above terms in the embodiments of this application according to the specific circumstances.

[0056] In the first aspect, such asFigure 1 As shown, this application provides a seawater electrolysis method, the method comprising the following steps:

[0057] First, proceed to step S101 to construct a transition metal electrode, and then modify the surface of the transition metal electrode to obtain a modified transition metal electrode.

[0058] Then, in step S102, the initial catalyst reaction conditions and initial experimental results data are input into the first neural network model for iterative updates to obtain improved catalyst reaction conditions. Under the improved catalyst reaction conditions, catalysts on different surfaces of the transition metal electrode are prepared.

[0059] Then, in step S103, the component content and distribution state of different surfaces of the sample electrode are input into the trained second neural network model to analyze the influence of the component content and distribution state of different surfaces of the sample electrode on the catalyst activity, and obtain the mapping relationship between component content and distribution state and catalyst-related parameters, including catalyst components and structure.

[0060] Then, in step S104, the composition content and distribution state of different surfaces of the transition metal electrode are obtained, the optimal correlation parameters of the catalysts on different surfaces are obtained according to the mapping relationship, and the optimal catalyst is prepared according to the optimal correlation parameters.

[0061] Then, in step S105, the optimal catalyst is added to the electrolysis device to prepare hypochlorous acid solution by electrolyzing seawater.

[0062] In step S101, a transition metal electrode refers to an electrode that uses transition metals (such as titanium, tungsten, molybdenum, chromium, etc.) as electrode materials. These metals are characterized by having multiple oxidation states and good electrical conductivity, making them very useful in electrochemical reactions. They are widely used in various electrochemical devices and catalysts, such as fuel cells, electrolyzers, and batteries.

[0063] In step S102, the initial catalyst reaction conditions include the reaction solvent, reaction ligands, and basic reaction parameters, including reaction time, temperature, and concentration. Iterative updates using a first neural network model enable controllable catalyst morphology. Specifically, adjusting the heterogeneous elements in the catalyst through pyrolysis under different atmospheres allows the prepared catalyst to possess uniform structure and particle size.

[0064] In step S103, the analysis of the influence of the composition content and distribution state of different surfaces of the sample electrode on the catalyst activity includes: using characterization techniques to highlight the surface structure and element valence state differences of the transition metal electrode, and correlating them with the improved catalyst reaction conditions to obtain the influence of the composition content and distribution state of different surfaces on the catalyst activity.

[0065] Characterization techniques include X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy (XPS), focusing on the surface structure and elemental valence state differences of the electrodes, and relating them to the synthesis and preparation conditions to determine the differences between reaction conditions and material structure.

[0066] The first and second neural network models can be convolutional neural networks (CNNs) or recurrent neural networks (RNNs) and their variants (such as LSTM and GRU).

[0067] In steps S104 and S105, the effects of electrochemical control conditions and temperature control on catalyst morphology regulation are investigated to further examine the relationship between morphology, structure, and catalytic activity, as well as its influence on electrocatalytic selectivity. The correlation between synthesis conditions and electrocatalytic activity is established by summarizing the synthesis conditions. After conducting systematic research, the influence of electrode component content and distribution on catalyst performance (i.e., the mapping relationship) is summarized, thereby enabling targeted synthesis of catalysts with different components and establishing the optimal catalytic composition and structure. Then, the optimal catalyst is added to the electrolysis device to electrolyze seawater to prepare hypochlorous acid solution. Compared with existing technologies, this method can improve seawater electrolysis efficiency and effectively save power consumption.

[0068] In some embodiments, constructing a transition metal electrode and modifying the surface of the transition metal electrode includes: constructing a multi-element high-entropy alloy transition metal electrode by a combination of electrolysis and electrodeposition and high-temperature atmosphere calcination, and modifying the surface of the transition metal electrode by phosphating and sulfidation methods.

[0069] In some embodiments, the method further includes: alloying multiple non-noble metals using the cocktail effect of high-entropy alloys, which can enhance the intrinsic activity and stability of the catalytic material; and increasing the specific surface area of ​​the transition metal electrode through localized low-dimensional nano-sizing. Localized low-dimensional nano-sizing can increase the specific surface area of ​​the seawater electrolysis electrode, expose more active sites, achieve the required current for the electrode, and simultaneously reduce the voltage.

[0070] In some embodiments, the method includes: constructing an electrolytic cell with pH gradient acid-base asymmetry during seawater electrolysis, specifically including: using acidic seawater as the cathode and alkaline seawater as the anode, and providing corresponding pH gradients for the cathode and anode reactions.

[0071] like Figure 2 The diagram shown is a schematic diagram of the principle of seawater electrolysis according to an exemplary embodiment of this application. Figure 2 This invention relates to an acid-base pH gradient mixed chemical coupling system based on seawater electrolysis for hydrogen production and sodium hypochlorite electrosynthesis. Acidic seawater serves as the cathode, and alkaline seawater as the anode, providing a suitable pH gradient for both reactions. Since the hydrogen evolution reaction is kinetically faster in acidic media, while oxygen or chlorine evolution reactions are more readily carried out in alkaline media, acid / base mixed electrolysis can provide a more suitable pH environment for the anode and cathode. Furthermore, the acidic cathode avoids metal precipitation, improves electrode stability, and regulates the pH gradient effect. This results in a multifunctional, energy-saving acid-base mixed electrolysis device that effectively reduces energy consumption while simultaneously achieving the co-production of hydrogen chlorine and sodium hypochlorite from seawater, thus achieving cost reduction and efficiency improvement.

[0072] like Figure 3 The diagram shown is a schematic representation of a technical route for reducing energy consumption in seawater electrolysis according to an exemplary embodiment of this application. Addressing the technical challenges of high energy consumption, low yield, and low concentration in seawater electrolysis, which are urgent problems for enterprises, this project constructs an acid-base pH gradient mixed chemical coupling seawater electrolysis system. First, laboratory simulations are conducted in modules to select the best electrode materials and optimize operating parameters. Then, intelligent integration and scale-up application experiments are carried out. The technical route adopted is as follows: Figure 3 As shown, it mainly includes:

[0073] (1) Preparation of square meter-level electrodes: Multi-element high-entropy alloy transition metal electrodes are constructed by electrolysis and electrodeposition combined with high-temperature atmosphere calcination. The electrode surface is modified by phosphating and sulfidation. By controlling and optimizing the reaction solvent, ligand, and reaction conditions (time, temperature, concentration, etc.), catalysts with different surfaces are prepared to achieve the purpose of morphology control.

[0074] (2) Characterization of Electrode Physicochemical Properties: Advanced characterization techniques such as X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy (XPS) were used to focus on the surface structure and elemental valence state differences of the electrodes, and to correlate them with the synthesis conditions, revealing the differences between reaction conditions and material structure. Simultaneously, the effects of electrochemical control conditions and temperature control on catalyst morphology were analyzed, further investigating the relationship between morphology, structure, and catalytic activity, as well as its influence on electrocatalytic selectivity. By summarizing the synthesis conditions and establishing their correlation with electrocatalytic activity, the optimal catalytic composition and structure were ultimately determined.

[0075] (3) Construction and performance optimization of a 500W pH gradient seawater electrolyzer

[0076] Based on the optimized electrodes, a novel electrolytic cell was designed, mainly focusing on the effects of different acid-base gradients on reaction voltage and reaction current, as well as the impact of pH changes on energy saving. The stability of the electrolytic cell was tested at different pH levels. Through system optimization, the optimal pH gradient was obtained, achieving the lowest operating energy consumption and the highest reaction current and stability.

[0077] like Figure 4 As shown, the electrolysis device includes a reaction tank (1), a fourth connecting pipe (48) is fixedly connected to the right side of the top of the reaction tank (1), a dustproof pipe is fixedly connected to the front end of the fourth connecting pipe (48), a compensation component is provided at the top left side of the dustproof pipe, a third connecting pipe (46) is fixedly connected to the bottom left side of the dustproof pipe, a first control valve is fixedly connected to the bottom end of the third connecting pipe (46), an ejector (44) is fixedly connected to the bottom end of the first control valve, a delivery pump (43) is fixedly connected to the right side of the ejector (44), a second connecting pipe (42) is fixedly connected to the top of the delivery pump (43), a three-way valve (41) is fixedly connected to the rear side of the top of the second connecting pipe (42), a connecting pipe (5) is fixedly connected to the right side of the three-way valve (41), a first connecting pipe (4) is fixedly connected to the left side of the three-way valve (41), the first connecting pipe (4) is fixedly connected to the reaction tank (1), and a refining component is provided on the inner side of the bottom end of the reaction tank (1).

[0078] Furthermore, the refining component includes a second connecting rod, a support ring is fixedly connected to the inner side of the bottom of the reaction tank (1), a first air inlet pipe is fixedly connected to the middle of the inner side of the support ring, and a spiral tube is fixedly connected to the right side of the first air inlet pipe.

[0079] In some embodiments, a motor (2) is fixedly connected to the top of the reaction vessel (1), the compensation assembly includes a compensation bottle (51), and uniformly distributed support legs (11) are fixedly connected to the outer side of the bottom of the reaction vessel (1).

[0080] In some embodiments, the electrolysis device can also prepare hypochlorous acid solution by separately introducing chlorine gas and sodium hydroxide solution into the anode and cathode. The working principle is as follows: During operation, sodium hydroxide solution is first introduced into the reaction tank through a second control valve. Simultaneously, a motor drives a mixing impeller to rotate, stirring the solution and conveying the solution downwards from the top. Then, chlorine gas is introduced into the spiral tube through a first inlet pipe, and the spiral tube refines the chlorine gas into smaller bubbles. These refined chlorine bubbles are then introduced into the sodium hydroxide solution for reaction. Finally, a delivery pump utilizes a second connecting pipe, a three-way valve, and... The first connecting pipe extracts the solution at the top and transports it back into the reaction vessel via an ejector. During the process, the third and fourth connecting pipes extract the gas at the top of the reaction vessel via the ejector, remix it inside the ejector on the right side, and then spray it out at high speed, allowing the reaction to continue inside the reaction vessel. At the same time, the high-speed ejected gas-liquid mixture forms a vortex inside the reaction vessel, thereby increasing the lateral stress of the bubbles and allowing the bubbles to remain in the same water layer for a longer period of reaction. After mixing is complete, the first connecting pipe and the connecting pipe are connected by turning the three-way valve, allowing cleaning water to be supplied into the reaction vessel for subsequent cleaning.

[0081] In a second aspect, the present invention also provides a computer-readable storage medium having a computer program stored thereon, which, when executed by a processor, implements the intelligent text content segmentation method based on variable vector length as described in the first aspect of the present invention.

[0082] The computer-readable storage medium may be volatile memory or non-volatile memory, or may include both volatile and non-volatile memory.

[0083] The non-volatile memory may be a read-only memory (ROM), a programmable read-only memory (PROM), an erasable programmable read-only memory (EPROM), an electrically erasable programmable read-only memory (EEPROM), a magnetic random access memory (FRAM), a flash memory, a magnetic surface memory, an optical disc, or a compact disc read-only memory (CD ROM); the magnetic surface memory may be a disk storage device or a magnetic tape storage device.

[0084] The volatile memory may be random access memory (RAM), which serves as an external cache. By way of example, but not limitation, many forms of RAM are available, such as static random access memory (SRAM), synchronous static random access memory (SSRAM), dynamic random access memory (DRAM), synchronous dynamic random access memory (SDRAM), double data rate synchronous dynamic random access memory (DDRSDRAM), enhanced synchronous dynamic random access memory (ESDRAM), synclink dynamic random access memory (SLDRAM), and direct memory bus random access memory (DRRAM). The computer-readable storage media described in the embodiments of the present invention are intended to include these and any other suitable types of memory.

[0085] like Figure 5 As shown, in a third aspect, the present invention provides an electronic device 10, including a processor 101 and a storage medium 102, wherein a computer program is stored on the storage medium, and the computer program, when executed by the processor, implements the intelligent text content segmentation method based on variable vector length as described in the first aspect of the present invention.

[0086] In some embodiments, the processor may be implemented by software, hardware, firmware, or a combination thereof, and may use at least one of the following: circuit, single or multiple application-specific integrated circuits (ASICs), digital signal processors (DSPs), digital signal processing devices (DSPDs), programmable logic devices (PLDs), field-programmable gate arrays (FPGAs), central processing units (CPUs), controllers, microcontrollers, and microprocessors, thereby enabling the processor to execute some or all of the steps or any combination of the steps in the text content intelligent segmentation method based on variable vector length described in the various embodiments of this application.

[0087] It should be noted that although the above embodiments have been described herein, this does not limit the scope of patent protection of this application. Therefore, any changes and modifications made to the embodiments based on the innovative concept of this application, or equivalent structural or procedural transformations made using the content of this application's specification and drawings, directly or indirectly applying the above technical solutions to other related technical fields, are all included within the scope of patent protection of this application.

Claims

1. A method for seawater electrolysis, characterized in that, The method includes the following steps: A multi-element high-entropy alloy transition metal electrode was constructed by a combination of electrolysis and electrodeposition with high-temperature calcination. The surface of the transition metal electrode was then modified by phosphating and sulfidation to obtain a modified transition metal electrode. The initial catalyst reaction conditions and initial experimental results data are input into the first neural network model for iterative updates to obtain improved catalyst reaction conditions. Under the improved catalyst reaction conditions, catalysts on different surfaces of the transition metal electrode are prepared. The composition content and distribution state of different surfaces of the sample electrode are input into the trained second neural network model to analyze the influence of the composition content and distribution state of different surfaces of the sample electrode on the catalyst activity, and obtain the mapping relationship between the composition content and distribution state and the catalyst-related parameters, including catalyst components and structure. The composition content and distribution state of different surfaces of the transition metal electrode are obtained, and the optimal correlation parameters of the catalysts on different surfaces are obtained according to the mapping relationship. The optimal catalyst is prepared according to the optimal correlation parameters. The optimal catalyst is added to the electrolysis device to prepare hypochlorous acid solution by electrolyzing seawater.

2. The seawater electrolysis method as described in claim 1, characterized in that, The method further includes: By utilizing the cocktail effect of high-entropy alloys, multi-component non-noble metals are alloyed, and the specific surface area of ​​transition metal electrodes is increased through localized low-dimensional nano-sizing.

3. The seawater electrolysis method as described in claim 1, characterized in that, The initial catalyst reaction conditions include the reaction solvent, reaction ligand, and basic reaction parameters, including reaction time, temperature, and concentration.

4. The seawater electrolysis method as described in claim 1, characterized in that, The influence of the composition content and distribution state of different surfaces of the analyzed sample electrode on the catalyst activity includes: Characterization techniques were used to highlight the surface structure and elemental valence state differences of the transition metal electrode, and to correlate them with the improved catalyst reaction conditions, thus revealing the influence of the composition content and distribution state of different surfaces on the catalyst activity.

5. The seawater electrolysis method as described in claim 1, characterized in that, The method includes: In the electrolysis of seawater, an electrolytic cell with a pH gradient and acid-base asymmetry is constructed, specifically including: Acidic seawater is used as the cathode, and alkaline seawater is used as the anode, with corresponding pH gradients provided for the cathode and anode reactions.

6. The seawater electrolysis method as described in claim 1, characterized in that, The electrolysis device includes a reaction tank (1), a fourth connecting pipe (48) is fixedly connected to the right side of the top of the reaction tank (1), a dustproof pipe is fixedly connected to the front end of the fourth connecting pipe (48), a compensation component is provided at the top left side of the dustproof pipe, a third connecting pipe (46) is fixedly connected to the bottom left side of the dustproof pipe, a first control valve is fixedly connected to the bottom end of the third connecting pipe (46), an ejector (44) is fixedly connected to the bottom end of the first control valve, a delivery pump (43) is fixedly connected to the right side of the ejector (44), a second connecting pipe (42) is fixedly connected to the top of the delivery pump (43), a three-way valve (41) is fixedly connected to the rear side of the top of the second connecting pipe (42), a connecting pipe (5) is fixedly connected to the right side of the three-way valve (41), a first connecting pipe (4) is fixedly connected to the left side of the three-way valve (41), the first connecting pipe (4) is fixedly connected to the reaction tank (1), and a refining component is provided on the inner side of the bottom end of the reaction tank (1).

7. The seawater electrolysis method as described in claim 6, characterized in that, The refining component includes a second connecting rod, a support ring is fixedly connected to the inner side of the bottom of the reaction tank (1), a first air inlet pipe is fixedly connected to the middle of the inner side of the support ring, and a spiral tube is fixedly connected to the right side of the first air inlet pipe.

8. A computer-readable storage medium having a computer program stored thereon, characterized in that, When the program is executed by the processor, it implements the seawater electrolysis method as described in any one of claims 1 to 7.

9. An electronic device having a computer program stored thereon, characterized in that, It includes a processor and a storage medium, wherein a computer program is stored on the storage medium, and the computer program, when executed by the processor, implements the seawater electrolysis method as described in any one of claims 1 to 7.

Citation Information

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