Multi-effect coupling algae-removing and fish-repelling device and method driven by renewable electric energy
The multi-effect coupling algae removal and fish repellent device driven by renewable electric energy uses multiple physical and chemical effects to remove algae blooms and drive away fish, solving the problems of low algae removal efficiency and difficulty in repelling fish in the existing technology, achieving high efficiency and environmental protection Water body repair effect.
Patent Information
- Application Number
- CN202411492981.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-10-24
- Publication Date
- 2025-01-24
- Estimated Expiration
- 2044-10-24
AI Technical Summary
Existing algae removal methods are inefficient and difficult to achieve algae removal and fish repellency at the same time. Especially in the restoration of aquatic ecosystems, fish eating dominant plants has become a problem.
A multi-effect coupling algae and fish repellent device driven by renewable electric energy. The device includes a curved cavity structure, a metal electrode assembly and an underwater monitoring device. It releases pulsed electric fields, strong light, strong oxidizing substances, pressure waves and sound waves in the water. , combined with catalytic functional coating and control system, to achieve the generation of multiple physical and chemical effects.
It achieves efficient removal of harmful algal blooms, while driving away fish in the water and preventing them from eating aquatic plants. The equipment is simple, easy to operate, and has no secondary pollution, overcoming the limitations of traditional technology.
Smart Images

Figure CN119344290A_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of ecological restoration technology research, and in particular to a multi-effect coupling algae removal and fish driving device and method driven by renewable electric energy. Background Art
[0003] The current algae removal methods are mainly divided into physical, chemical or biological methods. However, it is difficult to achieve efficient algae removal with a single effect. At the same time, the dominant plants used in aquatic ecological restoration are often easily eaten by large aquatic animals such as fish, which brings great difficulties to the restoration of aquatic ecosystems. In view of the above problems, it is urgent to develop a method of underwater efficient inducing multiple physical and chemical effects to achieve the purpose of simultaneous algae removal and fish repelling. Summary of the invention
[0004] The present invention provides a multi-effect coupling algae removal and fish driving device and method driven by renewable electric energy to overcome the above technical problems.
[0005] In order to achieve the above object, the technical solution of the present invention is:
[0006] A multi-effect coupling algae removal and fish driving device driven by renewable electric energy, comprising a shore-based device, a multi-effect coupling algae removal and fish driving device connected to the shore-based device, and a control system; and the shore-based device comprises a hoisting structure for hoisting the multi-effect coupling algae removal and fish driving device and a renewable electric power system for providing power to the multi-effect coupling algae removal and fish driving device and the control system;
[0007] The multi-effect coupling algae removal and fish driving device comprises a curved cavity structure, a metal electrode assembly, and an underwater monitoring device, wherein the curved cavity structure is a hollow cavity structure, a pressure wave emission port is provided at one end of the hollow cavity structure, and a main body driving device is installed at the other end;
[0008] The underwater monitoring device is arranged at one end of the curved cavity structure and is adjacent to the pressure wave emission port, and is used to monitor and obtain image data of underwater fish and algae;
[0009] The metal electrode assembly is connected to the top of the curved cavity structure, and the metal electrode assembly includes a first electrode and a second electrode with adjustable spacing; the first electrode and the second electrode are connected to a renewable power system, and are used to release a pulse electric field in water through the first electrode and the second electrode to produce a variety of products that can have algae removal and fish repelling effects under multiple physical and chemical effects;
[0010] The products include strong light, strong oxidizing substances, pressure waves and sound waves;
[0011] The inner wall of the hollow cavity structure is provided with a catalytic functional coating for obtaining free radicals under strong photocatalysis to promote the generation of strong oxidizing substances;
[0012] The control system is used to drive the multi-effect coupling algae removal and fish driving device to adjust its position in the water, and to obtain image data of underwater fish and algae at the current position in real time during the adjustment process.
[0013] Further, the renewable power system comprises a photovoltaic assembly for converting solar energy into electrical energy, an energy storage device for storing the electrical energy converted by the photovoltaic assembly, and a spark gap switch for controlling the first electrode and the second electrode to release a pulsed electric field, which are connected in sequence;
[0014] A transformer is also provided between the energy storage device and the spark gap switch;
[0015] The transformer is used to adjust the voltage output from the energy storage device so as to transmit it to the first electrode and the second electrode through the spark gap switch.
[0016] Further, it includes an electrode driving device for adjusting the electrode spacing;
[0017] The electrode driving device includes an air compressor and a compression cylinder;
[0018] The air compressor is used to be connected to the compression cylinder through a pipeline;
[0019] A mounting hole structure is provided at the top of the hollow cavity structure;
[0020] The first electrode and the second electrode are respectively arranged at two ends of the insulating member;
[0021] The top of the insulating member is provided with an annular structure, and the top of the annular structure is fixed to the inner wall of the top of the curved cavity structure;
[0022] The compression cylinder is fixedly connected to the outer wall of the hollow cavity structure through the mounting hole structure, and the output end of the compression cylinder piston rod is connected to one end of the second electrode;
[0023] The other end of the second electrode passes through the annular structure and is movably connected to the annular structure;
[0024] The air compressor can drive the piston rod of the compression cylinder to move back and forth through the pipeline, thereby driving the second electrode and the annular structure to move relative to each other.
[0025] Furthermore, it also includes one or more speakers arranged on the outside of the curved cavity structure and connected to the inner wall of the curved cavity structure, and arranged adjacent to the pressure wave emission port.
[0026] Furthermore, the electrode materials of the first electrode and the second electrode are made of metal corrosion-resistant materials;
[0027] The electrode spacing is 2 to 15 mm;
[0028] The electrode spacing is the distance between the top end of the first electrode and the bottom end of the second electrode;
[0029] The curvature radius of the electrode tip of the second electrode is 0.5-5 mm.
[0030] Furthermore, the curved cavity structure is specifically an elliptical hollow cavity structure.
[0031] Furthermore, the control system includes an underwater monitoring control module and a movement control module; and an electrode spacing control module;
[0032] The movement control module is used to control the main body driving device to drive the movement of the multi-effect coupling algae removal and fish driving device;
[0033] The underwater monitoring control module is used to control the underwater monitoring device to collect and identify the image data of underwater fish and algae during the movement of the multi-effect coupling algae removal and fish driving device.
[0034] Furthermore, the control system also includes an electrode spacing control module;
[0035] The electrode spacing control module is used to adjust the electrode spacing by controlling the electrode driving device according to the image data.
[0036] Furthermore, the material of the catalytic functional coating includes at least any one of Ag-modified TiO, Ni-Cu-modified TiO, non-metal-modified TiO, non-metal-modified g-CN, Mo-Cu-modified g-CN or Ni-Ag-modified g-CN.
[0037] A multi-effect coupling algae removal and fish driving method driven by renewable electric energy comprises the following steps:
[0038] S1: Control the main driving device through the mobile control module to realize the underwater movement of the multi-effect coupling algae removal and fish driving device;
[0039] S2: setting a preset sampling period, and controlling the underwater monitoring device through the underwater monitoring control module, periodically collecting underwater image data during the movement of the multi-effect coupling algae removal and fish driving device, and obtaining fish school / algae data in the underwater image data based on image recognition technology;
[0040] And the underwater monitoring device includes an underwater camera, an underwater lighting lamp and an underwater sonar device;
[0041] The fish / algae data at least includes the number and location of the fish / algae;
[0042] S3: Based on the fish / algae data, the electrode distance control module controls the electrode driving device to adjust the electrode distance, and adjusts the voltage output from the energy storage device according to the transformer to be transmitted to the first electrode and the second electrode through the spark gap switch;
[0043] S4: releasing a pulse electric field in water through the first electrode and the second electrode to produce a variety of products capable of removing algae and repelling fish under multiple physical and chemical effects;
[0044] The products include strong light, strong oxidizing substances, pressure waves and sound waves;
[0045] The strong oxidizing substances at least include hydrogen peroxide, ozone and active free radicals;
[0046] S5: Obtain free radicals through the catalytic functional coating under strong photocatalysis to promote the generation of strong oxidizing substances;
[0047] and damage algae cells through oxidation by strong oxidizing substances;
[0048] The pressure waves generated are reflected and enhanced by the inner wall of the curved cavity structure;
[0049] The generated sound waves are amplified by a loudspeaker;
[0050] The processed sound waves are amplified, and the reflected and enhanced pressure waves and strong light released through the pressure wave emission port are used to drive the fish schools in a directional manner.
[0051] Compared with the prior art, the present invention has the following beneficial effects:
[0052] The algae removal and fish driving device of the present invention can remove harmful algae blooms and at the same time drive away fish in the water to prevent them from eating aquatic plants used for water body restoration or rare aquatic plants. The device is simple, easy to operate, and has no secondary pollution to the water body. It overcomes the limitations of traditional algae removal and fish driving technologies, effectively achieves the purposes of algae removal and fish driving, and provides a new choice for the field of water body restoration. BRIEF DESCRIPTION OF THE DRAWINGS
[0053] In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following briefly introduces the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative labor.
[0054] Figure 1 A flow chart of the multi-effect coupling algae removal and fish repelling method driven by renewable electric energy of the present invention;
[0055] Figure 2 A schematic diagram of a multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to the present invention;
[0056] Figure 3 Schematic diagram of the control system in this embodiment;
[0057] Figure 4 FIG. 4 is a schematic diagram of the structure of an electrode driving device for adjusting the electrode spacing in this embodiment.
[0058] In the figure: 1. shore-based device; 11. lifting structure; 2. renewable power system; 21. electric energy photovoltaic module; 22. energy storage device; 23. spark gap switch; 24. transformer; 3. control system; 4. multi-effect coupling algae removal and fish repelling device; 41. curved cavity structure; 411. pressure wave emission port; 412. main body drive device; 413. mounting hole structure; 42. metal electrode assembly; 421. electrode drive device; 4211. air compressor; 4212. compression cylinder; 422. insulating member; 4221. ring structure; 423. first electrode; 424. second electrode; 43. underwater monitoring device; 44. speaker. DETAILED DESCRIPTION
[0059] In order to make the purpose, technical solution and advantages of the embodiments of the present invention clearer, the technical solution in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0060] This embodiment provides a multi-effect coupling algae removal and fish repelling device driven by renewable electric energy, such as Figure 2 As shown, it includes a shore-based device 1 and a multi-effect coupling algae removal and fish driving device 4 and a control system 3 connected to the shore-based device 1; and the shore-based device 1 includes a hoisting structure 11 for hoisting the multi-effect coupling algae removal and fish driving device 4 through a rope and a renewable power system 2 for providing power to the multi-effect coupling algae removal and fish driving device 4 and the control system 3;
[0061] In a specific embodiment, the renewable power system 2 includes a photovoltaic component 21 for converting solar energy into electric energy, an energy storage device 22 for storing the electric energy converted by the photovoltaic component, and a spark gap switch 23 for controlling the first electrode 423 and the second electrode 424 to release a pulse electric field, which are connected in sequence; and the energy storage device 22 is specifically an energy storage capacitor and its size is 20 to 120 μF;
[0062] A transformer is also provided between the energy storage device 22 and the spark gap switch 23;
[0063] The transformer is used to adjust the voltage output from the energy storage device 22 so as to transmit it to the first electrode 423 and the second electrode 424 through the spark gap switch 23; preferably, the electrode material of the first electrode 423 and the second electrode 424 is a metal corrosion-resistant material, such as a tungsten-copper alloy; the electrode spacing is 2 to 15 mm; the electrode spacing is the distance between the top of the first electrode 423 and the bottom of the second electrode 424; the curvature radius of the electrode tip of the second electrode 424 is 0.5 to 5 mm.
[0064] The multi-effect coupling algae removal and fish repelling device 4 comprises a curved cavity structure 41, a metal electrode assembly 42, and an underwater monitoring device 43, wherein the curved cavity structure 41 is a hollow cavity structure, a pressure wave emission port 411 is provided at one end of the hollow cavity structure, and a main body driving device 412 is installed at the other end;
[0065] The underwater monitoring device 43 is disposed at one end of the curved cavity structure 41 and is adjacent to the pressure wave emission port 411 , and is used to monitor and obtain image data of underwater fish and algae;
[0066] The metal electrode assembly 42 is connected to the top of the curved cavity structure 41, and the metal electrode assembly 42 includes a first electrode 423 and a second electrode 424 with adjustable spacing; the first electrode 423 and the second electrode 424 are connected to the renewable power system 2 through a wire, so as to release a pulse electric field in the water through the first electrode 423 and the second electrode 424, so as to produce a variety of products with algae removal and fish repelling effects under multiple physical and chemical effects;
[0067] And the products include strong light, strong oxidizing substances, pressure waves and sound waves;
[0068] The inner wall of the hollow cavity structure is provided with a catalytic functional coating for obtaining free radicals under strong photocatalysis to promote the generation of strong oxidizing substances;
[0069] In this embodiment, after the curved cavity structure 41 is filled with water, the spark gap switch 23 is turned on, the voltage is adjusted to 10-30 kV through the transformer, and the release period is 1-30 s / time. The high-voltage impulse current produces a liquid-electric effect in the water. In this process, multiple physical and chemical effects (pulsed electric field, strong light, strong oxidizing active substances, pressure waves) are simultaneously generated. The inner wall of the water tank is coated with a catalytic functional coating. Due to the photocatalytic effect, more free radicals are stimulated, thereby increasing the generation of strong oxidizing active substances, thereby oxidizing and damaging the algae cell structure, and achieving efficient inactivation of algae; the pressure wave is enhanced due to the energy reflection of the inner wall of the curved cavity structure 41, and is emitted from the pressure wave emission port 411 to the designated fish school. At the same time, the strong light generated overflows from the pressure wave emission port, which has a directional driving effect on the fish school; in addition, sound waves are also generated in the process, and the broadband sound waves are transmitted by the loudspeaker, which can achieve a wide range of fish school driving;
[0070] The control system 3 is used to drive the multi-effect coupling algae removal and fish driving device 4 to adjust the underwater position, and obtain the image data of the underwater fish and algae at the current position in real time during the adjustment process, such as Figure 3 As shown, it includes an underwater monitoring control module, a movement control module and an electrode spacing control module;
[0071] The mobile control module is used to control the main body driving device 412 to realize the movement of the multi-effect coupled algae removal and fish driving device 4; the underwater monitoring control module is used to control the underwater monitoring device 43 to collect and identify the image data of underwater fish and algae during the movement of the multi-effect coupled algae removal and fish driving device 4; the electrode spacing control module is used to adjust the electrode spacing by controlling the electrode driving device 421 according to the image data.
[0072] In a specific embodiment, Figure 4 As shown, it includes an electrode driving device 421 for adjusting the electrode spacing, which includes an air compressor 4211 and a compression cylinder 4212;
[0073] The air compressor 4211 is arranged on the shore and connected to the compression cylinder 4212 through a pipeline;
[0074] A mounting hole structure 413 is provided at the top of the hollow cavity structure;
[0075] The first electrode 423 and the second electrode 424 are respectively disposed at two ends of the insulating member 422;
[0076] The top of the insulating member 422 is provided with an annular structure 4221, and the top of the annular structure 4221 is fixed to the inner wall of the top of the curved cavity structure 41, and the inner diameter of the annular structure 4221 is the same as the diameter of the mounting hole structure 413;
[0077] The compression cylinder 4212 is fixedly connected to the outer wall of the hollow cavity structure through the mounting hole structure 413, and the output end of the piston rod of the compression cylinder 4212 is connected to one end of the second electrode 424;
[0078] The other end of the second electrode 424 passes through the annular structure 4221 and is movably connected to the annular structure 4221;
[0079] The air compressor 4211 can drive the piston rod of the compression cylinder 4212 to move back and forth through a pipeline, thereby driving the second electrode 424 and the annular structure 4221 to move relative to each other.
[0080] In this embodiment, the initial distance of the electrode spacing is set and recorded, and the electrode spacing control module controls the air compressor 4211 to drive the piston rod of the compression cylinder 4212 to reciprocate through the gas in the air pipe, and then the movement distance of the piston rod is measured by existing equipment (such as by installing a displacement sensor on the compression cylinder 4212) to adjust the electrode spacing. The compression cylinder 4212 is made of insulating material such as plastic.
[0081] In a specific embodiment, it also includes one or more speakers 44 which are arranged outside the curved cavity structure 41 and connected to the inner wall of the curved cavity structure 41 and are adjacent to the pressure wave emission port 411 .
[0082] In a specific embodiment, the curved cavity structure 41 is specifically an elliptical hollow cavity structure.
[0083] In a specific embodiment, the material of the catalytic functional coating includes at least any one of Ag-modified TiO2, Ni-Cu-modified TiO2, non-metal-modified TiO2, non-metal-modified g-C3N4, Mo-Cu-modified g-C3N4 or Ni-Ag-modified g-C3N4.
[0084] A multi-effect coupling method for removing algae and driving fish driven by renewable electric energy, such as Figure 1 As shown, the following steps are included:
[0085] S1: Control the main body driving device 412 through the mobile control module to realize the multi-effect coupling algae removal and fish driving device 4 to move underwater;
[0086] S2: setting a preset sampling period, and controlling the underwater monitoring device 43 through the underwater monitoring control module, periodically collecting underwater image data during the movement of the multi-effect coupling algae removal and fish driving device 4, and obtaining fish school / algae data in the underwater image data based on the existing image recognition technology;
[0087] The underwater monitoring device 43 includes an underwater camera, an underwater lighting lamp and an underwater sonar device; the fish school / algae data at least includes the type of fish school / algae and the number and position of fish school / algae;
[0088] In order to avoid that the collected underwater image data cannot clearly and accurately identify the fish / algae through the image recognition technology, the method also includes data processing of the periodically collected underwater image data: that is, the underwater image is preliminarily processed by the Gaussian filtering algorithm to blur the high-frequency noise in the underwater image; the guided filtering algorithm is used to perform secondary processing on the low-frequency noise in the underwater image after the Gaussian filtering; the results of the Gaussian filtering and the guided filtering are synthesized to form a bilateral filter, and the noise of the underwater image after the guided filtering is processed by the bilateral filter; the bilateral filtering result is obtained, and a pixel-level analysis is performed to determine whether there is a color deviation; if the pixel-level analysis determines that there is a color deviation, the image parameters are dynamically adjusted by the white balance correction algorithm to generate underwater image data after white balance correction, and then the category of the fish / algae in the underwater image data is obtained according to the image recognition technology, and obtaining the category of the fish / algae in the underwater image data by the image recognition technology is an existing well-known technical means, which will not be repeated here;
[0089] The method for obtaining the number of fish / algae is as follows:
[0090] The underwater sonar equipment is used to collect sonar images within a preset distance range under the water surface. The principle of sonar imaging is to use ultrasonic waves to send out signals, which are reflected back after hitting a moving underwater object. The underwater fish / algae are identified by calculating the time, direction and strength of the signal response.
[0091] A preprocessed image after each sonar image is processed is obtained through image preprocessing, and the image preprocessing includes linear stretching, median filtering and sharpening processing; the area to be divided of the target fish in the preprocessed image is extracted through edge detection technology; a binary division threshold for acoustic calibration of the target fish is set based on an image binarization division threshold algorithm, and the area to be divided is binarized according to the binary division threshold, and the target fish in the binarized image is extracted; the number of fish schools / algae is obtained according to the number of target fish in each sonar image;
[0092] S3: Based on the fish / algae data, the electrode distance control module controls the electrode driving device 421 to adjust the electrode distance, and adjusts the voltage output from the energy storage device 22 according to the transformer 24 to transmit to the first electrode 423 and the second electrode 424 through the spark gap switch 23;
[0093] Specifically, the corresponding fish / algae data is obtained according to a preset sampling period, that is, the electrode spacing and impulse voltage that can achieve the removal effect under the corresponding conditions are set according to the number of fish / algae, and then the electrode spacing sequence table and impulse voltage sequence table corresponding to different numbers of fish / algae are obtained;
[0094] The electrode spacing sequence table and the impulse voltage sequence table are a descending order table of the distances between the first electrode 423 and the second electrode 424 corresponding to the generation of multiple physical and chemical effects of different intensities, and an impulse voltage sequence table corresponding to the descending order table;
[0095] For example, when there are many fish, the electrode spacing can be reduced and the impulse voltage can be increased to generate stronger light, pressure waves and sound waves, as well as more strong oxidizing substances to achieve the effect of driving fish and removing algae; when there are few fish, the electrode spacing can be increased and the impulse voltage can be reduced to generate smaller light, pressure waves and sound waves, as well as less strong oxidizing substances to achieve the effect of driving fish and removing algae, which can effectively reduce energy consumption and energy utilization.
[0096] S4: releasing a pulse electric field in the water through the first electrode 423 and the second electrode 424 to produce a variety of products capable of removing algae and repelling fish under multiple physical and chemical effects;
[0097] The products include strong light, strong oxidizing substances, pressure waves and sound waves;
[0098] The strong oxidizing substances at least include hydrogen peroxide, ozone and active free radicals;
[0099] S5: Obtain free radicals through the catalytic functional coating under strong photocatalysis to promote the generation of strong oxidizing substances;
[0100] and damage algae cells through oxidation by strong oxidizing substances;
[0101] The pressure wave is reflected and enhanced by the inner wall of the curved cavity structure 41;
[0102] The generated sound waves are amplified by the speaker 44;
[0103] The amplified sound waves, the reflected and enhanced pressure waves released through the pressure wave emission port 411, and the generated strong light can be used to achieve directional driving of the school of fish.
[0104] This embodiment provides a device and method for multi-effect coupling algae removal and fish driving driven by renewable electric energy. The algae removal and fish driving device overcomes the shortcomings of traditional algae removal technology, such as long processing time, low efficiency, and secondary pollution. Its advantages include: first, the device of the present invention uses solar energy to generate electricity, which is energy-saving and environmentally friendly; second, the system has high processing efficiency and high degree of automation, and the equipment is simple and easy to operate; third, the device is driven by renewable electric energy to induce multiple physical and chemical effects (pulsed electric field, strong light, strong oxidizing active substances, pressure waves) underwater to effectively remove algae blooms and achieve large-scale fish driving to prevent them from eating aquatic plants; fourth, the device does not need to add chemical agents and will not cause secondary pollution to the water body; it is precisely because of the above advantages that the device can quickly and efficiently achieve the effect of algae removal and fish driving.
[0105] The experimental example results in this embodiment are as follows:
[0106] Example 1: Energy storage capacitor 20μF, electrode spacing 4mm, electrode tip curvature radius 5mm, applied peak voltage 14kV, release cycle 30s / time, catalytic functional coating using Ag-modified TiO2, algae solution concentration to be treated 1×10 5 / mL, 4m away from the fish school, the inactivation rate of algae is 80%, and the expulsion rate of fish is 60%.
[0107] Example 2: energy storage capacitor 40μF, electrode spacing 4mm, electrode tip curvature radius 5mm, applied peak voltage 18kV, release cycle 20s / time, catalytic functional coating using Ni-Cu modified TiO2, algae solution concentration to be treated 1×105 cells / mL, 4m away from fish school, algae inactivation rate exceeded 80%, and fish repellent rate reached 80%.
[0108] Example 3: Energy storage capacitor 60μF, electrode spacing 7mm, electrode tip curvature radius 3mm, applied peak voltage 22kV, release cycle 20s / time, catalytic functional coating using non-metal modified TiO2, algae solution concentration to be treated 1×10 5 / mL, 5m away from the fish school, the inactivation rate of algae is 90%, and the expulsion rate of fish is 85%.
[0109] Example 4: energy storage capacitor 80μF, electrode spacing 7mm, electrode tip curvature radius 3mm, applied peak voltage 24kV, release cycle 10s / time, catalytic functional coating using non-metal modified g-C3N4, algae solution concentration to be treated 1×10 5 / mL, 5m away from the fish school, the inactivation rate of algae is over 95%, and the expulsion rate of fish school is over 90%.
[0110] Example 5: Energy storage capacitor 100μF, electrode spacing 10mm, electrode tip curvature radius 1mm, applied peak voltage 26kV, release cycle 5s / time, catalytic functional coating using Mo-Cu modified g-C3N4, algae solution concentration to be treated 1×10 5 / mL, 8m away from the fish school, the inactivation rate of algae is over 99%, and the fish repelling rate is 95%.
[0111] Example 6: Energy storage capacitor 120μF, electrode spacing 15mm, electrode tip curvature radius 1mm, applied peak voltage 30kV, release cycle 1s / time, catalytic functional coating using Ni-Ag modified g-C3N4, algae solution concentration to be treated 1×10 5 / mL, 8m away from the fish school, the inactivation rate of algae is 100%, and the expulsion rate of fish school is 100%.
[0112] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein with equivalents. However, these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the scope of the technical solutions of the embodiments of the present invention.
Claims
1. A multi-effect coupling algae removal and fish repelling device driven by renewable electric energy, characterized in that: The invention comprises a shore-based device (1) and a multi-effect coupled algae removal and fish driving device (4) and a control system (3) connected to the shore-based device (1); and the shore-based device (1) comprises a hoisting structure (11) for hoisting the multi-effect coupled algae removal and fish driving device (4) and a renewable power system (2) for providing power to the multi-effect coupled algae removal and fish driving device (4) and the control system (3); The multi-effect coupling algae removal and fish repelling device (4) comprises a curved cavity structure (41), a metal electrode assembly (42), and an underwater monitoring device (43); the curved cavity structure (41) is a hollow cavity structure, one end of the hollow cavity structure is provided with a pressure wave emission port (411), and the other end is provided with a body drive device (412); The underwater monitoring device (43) is arranged at one end of the curved cavity structure (41) and is adjacent to the pressure wave emission port (411), and the underwater monitoring device (43) is used to monitor and obtain image data of underwater fish and algae; The metal electrode assembly (42) is connected to the top of the curved cavity structure (41), and the metal electrode assembly (42) comprises a first electrode (423) and a second electrode (424) with adjustable spacing; the first electrode (423) and the second electrode (424) are connected to the renewable power system (2) and are used to release a pulse electric field in water through the first electrode (423) and the second electrode (424) to produce a variety of products with algae removal and fish repelling effects under multiple physical and chemical effects; The products include strong light, strong oxidizing substances, pressure waves and sound waves; The inner wall of the hollow cavity structure is provided with a catalytic functional coating for obtaining free radicals under strong photocatalysis to promote the generation of strong oxidizing substances; The control system (3) is used to drive the multi-effect coupling algae removal and fish driving device (4) to adjust the underwater position, and to obtain image data of underwater fish and algae at the current position in real time during the adjustment process.
2. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 1, characterized in that: The renewable power system (2) comprises a photovoltaic component (21) for converting solar energy into electric energy, an energy storage device (22) for storing the electric energy converted by the photovoltaic component, and a spark gap switch (23) for controlling the first electrode (423) and the second electrode (424) to release a pulse electric field, which are connected in sequence; A transformer (24) is also provided between the energy storage device (22) and the spark gap switch (23); The transformer (24) is used to adjust the voltage output from the energy storage device (22) so as to transmit the voltage to the first electrode (423) and the second electrode (424) through the spark gap switch (23).
3. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 2, characterized in that: An electrode driving device (421) is included for adjusting the electrode spacing; The electrode driving device (421) comprises an air compressor (4211) and a compression cylinder (4212); The air compressor (4211) is used to be connected to the compression cylinder (4212) through a pipeline; A mounting hole structure (413) is provided at the top of the hollow cavity structure; The first electrode (423) and the second electrode (424) are respectively arranged at two ends of the insulating component (422); The top end of the insulating component (422) is provided with an annular structure (4221), and the top end of the annular structure (4221) is fixed to the inner wall of the top end of the curved cavity structure (41); The compression cylinder (4212) is fixedly connected to the outer wall of the hollow cavity structure via the mounting hole structure (413), and the output end of the piston rod of the compression cylinder (4212) is connected to one end of the second electrode (424); The other end of the second electrode (424) passes through the annular structure (4221) and is movably connected to the annular structure (4221); The air compressor (4211) can drive the piston rod of the compression cylinder (4212) to move back and forth through a pipeline, thereby driving the second electrode (424) and the annular structure (4221) to move relative to each other.
4. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 1, characterized in that: It also includes one or more loudspeakers (44) arranged outside the curved cavity structure (41) and connected to the inner wall of the curved cavity structure (41), and arranged adjacent to the pressure wave emission port (411).
5. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 3, characterized in that: The electrode materials of the first electrode (423) and the second electrode (424) are made of metal corrosion-resistant materials; The electrode spacing is 2 to 15 mm; The electrode spacing is the distance between the top end of the first electrode (423) and the bottom end of the second electrode (424); The curvature radius of the electrode tip of the second electrode (424) is 0.5 to 5 mm.
6. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 5, characterized in that: The curved cavity structure (41) is specifically an elliptical hollow cavity structure.
7. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 1, characterized in that: The control system (3) includes an underwater monitoring control module and a movement control module; and an electrode spacing control module; The movement control module is used to control the main body driving device (412) to drive the movement of the multi-effect coupling algae removal and fish driving device (4); The underwater monitoring control module is used to control the underwater monitoring device (43) to collect and identify image data of underwater fish and algae during the movement of the multi-effect coupling algae removal and fish driving device (4).
8. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 7, characterized in that: The control system (3) also includes an electrode spacing control module; The electrode spacing control module is used to adjust the electrode spacing by controlling the electrode driving device (421) according to the image data.
9. The multi-effect coupling algae removal and fish repelling device driven by renewable electric energy according to claim 1, characterized in that: The material of the catalytic functional coating includes at least any one of Ag-modified TiO2, Ni-Cu-modified TiO2, non-metal-modified TiO2, non-metal-modified g-C3N4, Mo-Cu-modified g-C3N4 or Ni-Ag-modified g-C3N4.
10. A multi-effect coupling algae removal and fish driving method driven by renewable electric energy, based on the multi-effect coupling algae removal and fish driving device driven by renewable electric energy as claimed in claim 3, characterized in that: The following steps are involved: S1: controlling the main body driving device (412) through the mobile control module to realize the multi-effect coupling algae removal and fish driving device (4) to move underwater; S2: setting a preset sampling period, and controlling the underwater monitoring device (43) through the underwater monitoring control module, periodically collecting underwater image data during the movement of the multi-effect coupling algae removal and fish driving device (4), and obtaining fish school / algae data in the underwater image data based on image recognition technology; The underwater monitoring device (43) includes an underwater camera, an underwater lighting lamp and an underwater sonar device; The fish / algae data at least includes the number and location of the fish / algae; S3: Based on the fish / algae data, the electrode distance control module controls the electrode driving device (421) to adjust the electrode distance, and adjusts the voltage output from the energy storage device (22) according to the transformer to transmit it to the first electrode (423) and the second electrode (424) through the spark gap switch (23); S4: releasing a pulse electric field in water through the first electrode (423) and the second electrode (424) to produce a variety of products capable of removing algae and repelling fish under multiple physical and chemical effects; The products include strong light, strong oxidizing substances, pressure waves and sound waves; The strong oxidizing substances at least include hydrogen peroxide, ozone and active free radicals; S5: Obtain free radicals through the catalytic functional coating under strong photocatalysis to promote the generation of strong oxidizing substances; and damage algae cells through oxidation by strong oxidizing substances; The pressure wave is reflected and enhanced by the inner wall of the curved cavity structure (41); amplifying the generated sound waves through a speaker (44); The amplified sound waves, the reflected and enhanced pressure waves released through the pressure wave emission port (411), and the generated strong light can be used to achieve directional driving of the school of fish.
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