A hair fermentation oil, a hair conditioner and a preparation method and application thereof

Abstract

The present application relates to the daily chemical technical field, especially to a hair fermented oil, a hair care agent and a preparation method and application thereof. The hair fermented oil is prepared from the following raw materials: sweet almond, macadamia nut seed, radix anemarrhena, citrus medica fruit. The hair care agent is added with the fermented oil, so that the hair care effect and nutrients are increased, the texture is light and easy to spread, the hair is given gloss, and the hair is nourished and cared while being light and comfortable. Meanwhile, the hair fermented oil has the function of maintaining the hair dyeing effect.

Description

TECHNICAL FIELD

[0001] The present application relates to the field of daily chemical technology, and in particular to a hair fermentation oil, a hair conditioner and a preparation method and application thereof. BACKGROUND

[0002] The hair conditioner has basic hair moisturizing and nourishing effects. In the market, the hair conditioner is mainly used for achieving softening care through silicone film forming, and adding single oil care, which has a sticky film forming feeling or is relatively moist. At present, the hair conditioner on the market is mainly used for hair moisturizing and repairing. In daily life, hair is often subjected to various tests, such as hot blow drying, dyeing and perming, ultraviolet damage and the like, so that the hair of people is easily damaged, has dandruff, splits, is dry, is difficult to comb, has large friction, and has dull luster. The existing hair conditioner cannot well meet the hair care needs of people.

[0003] In order to solve the above problems, the present application provides a hair fermentation oil, a hair conditioner and a preparation method and application thereof. SUMMARY

[0004] To solve the above technical problems, the present application provides a hair fermentation oil, and the preparation raw materials thereof comprise: sweet almond, macadamia nut seed, radix anemarrhena, citrus medica fruit.

[0005] As an embodiment of the present application, the mass ratio of the sweet almond, the macadamia nut seed, the radix anemarrhena and the citrus medica fruit is 1:1:1:1.

[0006] A hair conditioner for hair, comprising the hair fermentation oil.

[0007] As an embodiment of the present application, the preparation raw materials of the hair conditioner for hair comprise: hair conditioner, moisturizing agent, fragrance, hair conditioner, moisturizing agent and antioxidant.

[0008] As an embodiment of the present application, the preparation raw materials of the hair conditioner for hair comprise, according to mass fraction:

[0009] Cyclopentasiloxane 50-60

[0010] Dimethicone, dimethiconol 35-45

[0011] Isocetyl 4-5

[0012] Essence 0.8-1

[0013] Caprylic / capric triglyceride 0.1-1

[0014] Hair fermentation oil 0.1-1

[0015] Mauritia flexuosa fruit oil 0.1-1

[0016] Macadamia ternifolia seed oil 0.1-1

[0017] Prunus amygdalus dulcis oil 0.1-1

[0018] Simmondsia chinensis seed oil 0.1-1

[0019] Tocopheryl acetate 0.02-0.06.

[0020] As an embodiment of the present application, the raw material for preparation contains, by mass:

[0021] Cyclopentasiloxane 53

[0022] Dimethicone, dimethiconol 42

[0023] Isocetyl alcohol 4

[0024] Fragrance 0.9

[0025] Caprylic / capric triglyceride 0.7

[0026] Fermented oil for hair 1

[0027] Mauritia flexuosa fruit oil 0.3

[0028] Macadamia ternifolia seed oil 0.2

[0029] Prunus amygdalus dulcis oil 0.5

[0030] Simmondsia chinensis seed oil 0.5

[0031] Tocopheryl acetate 0.05.

[0032] A method for preparing the hair conditioner for hair, comprising the steps of:

[0033] (1) A stirring emulsifying pan is charged with cyclopentasiloxane, dimethicone, dimethiconol, and stirring is started. The mixture is stirred until uniform and transparent;

[0034] (2) Isocetyl alcohol, fragrance, and caprylic / capric triglyceride are added to the emulsifying pan, and stirring is maintained;

[0035] (3) Add fermented oil, Mauritius flexuosa fruit oil, Macadamia ternifolia seed oil, sweet almond (Prunus amygdalus dulcis) oil, jojoba (Simmondsia chinensis) seed oil, tocopheryl acetate, stir evenly until completely stirred evenly, and discharge.

[0036] As an embodiment of the present application, the hair conditioner is applied in the field of daily chemicals.

[0037] By adopting the technical scheme, the present application has the following beneficial effects:

[0038] The fermented oil added in the hair conditioner increases the hair care effect and nutrient substances, has light texture and is easy to apply, gives hair gloss, and brings light and comfortable feeling while moisturizing and protecting hair. Meanwhile, the hair conditioner has the function of maintaining hair dyeing effect. BRIEF DESCRIPTION OF DRAWINGS

[0039] In order to more clearly illustrate the specific embodiments of the present application or the technical solutions in the prior art, the drawings needed in the following description of the specific embodiments or the prior art will be briefly introduced. Obviously, the drawings in the following description are some embodiments of the present application, and for those skilled in the art, other drawings can be obtained without creative labor on the basis of these drawings.

[0040] Figure 1 Morphology of hair scales (Example 1);

[0041] Figure 2 Morphology of hair scales (control group). DETAILED DESCRIPTION

[0042] The technical solutions of the present application will be described clearly and completely below. Obviously, the described embodiments are part of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in the present application, all other embodiments obtained by those skilled in the art without creative labor fall within the protection scope of the present application.

[0043] A hair conditioner, according to mass fraction, is prepared from the following raw materials:

[0044] Cyclopentasiloxane 53

[0045] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0046] Isocetyl 4

[0047] Fragrance 0.9

[0048] Caprylic / capric triglyceride 0.7

[0049] Fermented oil for hair 1

[0050] Mauritia flexuosa fruit oil 0.3

[0051] Macadamia ternifolia seed oil 0.2

[0052] Prunus amygdalus dulcis oil 0.5

[0053] Simmondsia chinensis seed oil 0.5

[0054] Tocopheryl acetate 0.05.

[0055] A preparation method of the hair conditioner for hair, steps are as follows:

[0056] (1) the emulsification kettle is stirred to add cyclopentasiloxane, dimethicone, dimethiconol, and stirring is started, and stirring is uniformly mixed until transparent;

[0057] (2) iso-hexadecane, essence, caprylic / capric triglyceride are added to the emulsification kettle, and stirring is maintained;

[0058] (3) fermented oil for hair, mauritia flexuosa fruit oil, macadamia ternifolia seed oil, prunus amygdalus dulcis oil, simmondsia chinensis seed oil, tocopheryl acetate are added, and stirring is uniformly mixed until stirring is completely uniform, and the material is discharged.

[0059] Wherein, the preparation raw material of the fermented oil for hair comprises: sweet almond, macadamia seed, anemarrhena asphodeloides root and citrus medica fruit.

[0060] In the application, the preparation method of the fermented oil for hair is as follows:

[0061] (1) freshly picked preparation raw materials are stored at 0-5 DEG C for 72 hours, then taken out, mixed and chopped, placed in a culture solution, and inoculated with strain A for culture;The fermentation temperature is 30 DEG C, and the time is 72 hours.

[0062] (2) after step (1) fermentation is completed, inoculate new strain B, continue to ferment, centrifuge, remove the upper clear liquid, and add the same volume of methyl tert-butyl ether;

[0063] (3) After operating at 30℃ and 300r / min for 40min, then continue to centrifugal separation of solvent phase at normal temperature for 10000r / min, 3min, then add equal volume of 0.1wt% NaCl solution to wash the solvent phase, dry over anhydrous sodium sulfate, then remove methyl tert-butyl ether by rotary evaporation, and finally dry the oil to obtain the product.

[0064] In step (1), the composition of the culture solution is as follows: casein peptone (pancreatic digestion) 10.0 g, beef infusion powder 10.0 g, yeast infusion powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0065] The strain A is Bacillus polyfermenticus (China Industrial Microbial Culture Collection Center, CICC 23909) and Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), and the inoculation amount is 5vol%, and the inoculation amount ratio is 3:2.

[0066] The strain B is Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5vol%. The fermentation temperature is 37℃, and the time is 48h.

[0067] The application will be further explained in combination with specific embodiments.

[0068] Example 1

[0069] The present embodiment provides a hair conditioner for hair, and the preparation raw materials thereof comprise, according to mass fraction:

[0070] Cyclopentasiloxane 53

[0071] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0072] Isocetyl 4

[0073] Fragrance 0.9

[0074] Caprylic / capric triglyceride 0.7

[0075] Fermented oil for hair 1

[0076] Mauritia flexuosa fruit oil 0.3

[0077] Macadamia ternifolia seed oil 0.2

[0078] sweet almond (Prunus amygdalus dulcis) oil 0.5

[0079] jojoba (Simmondsia chinensis) seed oil 0.5

[0080] tocopheryl acetate 0.05.

[0081] A preparation method of the hair conditioner for hair, steps are as follows:

[0082] (1) the emulsification kettle is stirred to add cyclopentasiloxane, dimethicone, dimethiconol, and stirring is started, and stirring is uniformly mixed until transparent;

[0083] (2) iso-hexadecane, essence, caprylic / capric triglyceride are added to the emulsification kettle, and stirring is maintained;

[0084] (3) fermented oil, mauritia flexuosa fruit oil, macadamia ternifolia seed oil, prunus amygdalus dulcis oil, simmondsia chinensis seed oil, tocopheryl acetate are added, and stirring is uniformly mixed until stirring is completely uniform, and the material is discharged.

[0085] The preparation raw materials of the fermented oil for hair include sweet almond, macadamia seed, anemarrhena asphodeloides root, and citrus medica fruit, and the mass ratio is 1:1:1:1.

[0086] The preparation method of the fermented oil for hair is as follows:

[0087] (1) the freshly picked preparation raw materials are stored at 0-5 DEG C for 72 h, then mixed and chopped, placed in a culture solution, and inoculated with strain A for culture; the fermentation temperature is 30 DEG C, and the time is 72 h.

[0088] (2) after the fermentation in step (1) is completed, new strain B is inoculated, and the fermentation is continued; centrifugation is performed, the supernatant is removed, and the same volume of methyl tert-butyl ether is added;

[0089] (3) after 40 min of operation at a temperature of 30 DEG C and a speed of 300 r / min, the solvent phase is separated by centrifugation at room temperature at 10,000 r / min for 3 min, then the same volume of 0.1wt% NaCl solution is added to wash the solvent phase, and the methyl tert-butyl ether is removed by rotary evaporation after drying over anhydrous sodium sulfate, and the oil is dried to obtain the fermented oil.

[0090] In step (1), the components of the culture solution are as follows: casein peptone (pancreatic digestion) 10.0 g, beef infusion powder 10.0 g, yeast infusion powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0091] The strain A is Bacillus polyfermenticus (China Industrial Microbial Culture Collection Center, CICC 23909) and Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), with an inoculation amount of 5 vol% and an inoculation amount ratio of 3:2.

[0092] The strain B is Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), with an inoculation amount of 5 vol%. The fermentation temperature is 37°C, and the fermentation time is 48 h.

[0093] Example 2

[0094] The present embodiment provides a hair rinse, and the preparation raw materials thereof comprise, according to mass fraction:

[0095] Cyclopentasiloxane 53

[0096] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0097] Isocetyl 4

[0098] Fragrance 0.9

[0099] Caprylic / capric triglyceride 0.7

[0100] Hair fermentation oil 1

[0101] Mauritia flexuosa fruit oil 0.3

[0102] Macadamia ternifolia seed oil 0.2

[0103] Prunus amygdalus dulcis oil 0.5

[0104] Simmondsia chinensis seed oil 0.5

[0105] Tocopheryl acetate 0.05.

[0106] A preparation method of the hair rinse, comprising the following steps:

[0107] (1) Add cyclopentasiloxane, dimethicone, dimethiconol to the stirring emulsifying pot, turn on the stirring, stir and mix until transparent;

[0108] (2) Add isohexadecane, fragrance, caprylic / capric triglyceride to the emulsifying pot, maintain stirring;

[0109] (3) Add fermented oil, MAURITIA FLEXUOSA fruit oil, MACADAMIA TERNIFOLIA seed oil, PRUNUS AMYGDALUS DULCIS oil, SIMMONDSIA CHINENSIS seed oil, tocopheryl acetate, stir until uniform, and then discharge.

[0110] The preparation raw materials of the fermented oil for hair include PRUNUS AMYGDALUS DULCIS oil, MACADAMIA TERNIFOLIA seed oil, ANEMARRHENA ASPHODELOIDES root extract, and CITRUS MEDICA LIMONUM fruit oil, and the mass ratio is 1:1:1:1.

[0111] The preparation method of the fermented oil for hair is as follows:

[0112] (1) After mixing PRUNUS AMYGDALUS DULCIS oil, MACADAMIA TERNIFOLIA seed oil, ANEMARRHENA ASPHODELOIDES root extract, and CITRUS MEDICA LIMONUM fruit oil, place them in a culture solution, inoculate with strain B, and culture; the fermentation temperature is 30°C, and the time is 72h.

[0113] (2) After the fermentation in step (1) is completed, centrifuge, remove the supernatant, and then add the same volume of methyl tert-butyl ether;

[0114] (3) After operating at a temperature of 30°C and a speed of 300r / min for 40min, then continue to centrifuge the solvent phase at room temperature at 10000r / min for 3min, then add the same volume of 0.1wt% NaCl solution to wash the solvent phase, dry it over anhydrous sodium sulfate, and then remove the methyl tert-butyl ether by rotary evaporation, and then dry the oil to obtain the oil.

[0115] In step (1), the components of the culture solution are as follows: casein peptone (pancreatic digestion) 10.0 g, beef infusion powder 10.0 g, yeast extract powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0116] The strain B is: Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5 vol%. The fermentation temperature is 37°C, and the time is 48 h.

[0117] Example 3

[0118] The present embodiment provides a hair conditioner for hair, and the preparation raw materials thereof comprise, according to mass fraction:

[0119] Cyclopentasiloxane 53

[0120] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0121] Isocetyl 4

[0122] Fragrance 0.9

[0123] Caprylic / capric triglyceride 0.7

[0124] Hair fermented oil 1

[0125] Mauritia flexuosa fruit oil 0.3

[0126] Macadamia ternifolia seed oil 0.2

[0127] Prunus amygdalus dulcis oil 0.5

[0128] Simmondsia chinensis seed oil 0.5

[0129] Tocopheryl acetate 0.05.

[0130] A preparation method of the hair conditioner, and the steps are as follows:

[0131] (1) A stirring emulsifying kettle is added with cyclopentasiloxane, dimethicone, and dimethiconol, and stirring is started until the mixture is uniformly mixed and transparent;

[0132] (2) Isocetyl, fragrance, and caprylic / capric triglyceride are added to the emulsifying kettle, and stirring is maintained;

[0133] (3) Add fermented oil, Mauritius flexuosa fruit oil, Macadamia ternifolia seed oil, sweet almond (Prunus amygdalus dulcis) oil, jojoba (Simmondsia chinensis) seed oil, tocopheryl acetate, and stir until uniform, and then discharge.

[0134] The preparation raw materials of the fermented oil for hair include sweet almond, Macadamia ternifolia seed, Anemarrhena asphodeloides root, and Citrus medica fruit, and the mass ratio is 1:1:1:1.

[0135] The preparation method of the fermented oil for hair is as follows:

[0136] (1) The freshly picked preparation raw materials are stored at 0-5°C for 72 hours, then mixed and cut, and then placed in a culture solution and inoculated with strain B for culture; the fermentation temperature is 30°C, and the fermentation time is 72 hours; after centrifugation, the same volume of methyl tert-butyl ether is added.

[0137] (2) After operating at a temperature of 30°C and a rotation speed of 300 r / min for 40 minutes, the solvent phase is then separated by centrifugation at room temperature at 10,000 r / min for 3 minutes; then the same volume of 0.1 wt% NaCl solution is added to wash the solvent phase, and then the methyl tert-butyl ether is removed by rotary evaporation after drying over anhydrous sodium sulfate, and the oil is obtained by drying.

[0138] In step (1), the composition of the culture solution is as follows: casein peptone (pancreatin) 10.0 g, beef extract powder 10.0 g, yeast extract powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0139] Strain B is: Isayama orientalis (China Industrial Microbial Strain Preservation and Management Center, CICC 32866), and the inoculation amount is 5 vol%. The fermentation temperature is 37°C, and the fermentation time is 48 hours.

[0140] Example 4

[0141] The preparation raw materials of the hair conditioner for hair according to the mass fraction include:

[0142] Cyclopentasiloxane 53

[0143] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0144] Isocetyl 4

[0145] Fragrance 0.9

[0146] Caprylic / capric triglyceride 0.7

[0147] Fermented oil for hair 1

[0148] Mauritia flexuosa fruit oil 0.3

[0149] Macadamia ternifolia seed oil 0.2

[0150] Prunus amygdalus dulcis oil 0.5

[0151] Simmondsia chinensis seed oil 0.5

[0152] Tocopheryl acetate 0.05.

[0153] A preparation method of the hair conditioner for hair, comprising the following steps:

[0154] (1) A stirring emulsifying kettle is added with cyclopentasiloxane, dimethicone, and dimethiconol, stirring is started, and stirring and mixing are performed until transparent;

[0155] (2) Isocetyl, fragrance, and caprylic / capric triglyceride are added to the emulsifying kettle, and stirring is maintained;

[0156] (3) Fermented oil for hair, Mauritia flexuosa fruit oil, Macadamia ternifolia seed oil, Prunus amygdalus dulcis oil, Simmondsia chinensis seed oil, and tocopheryl acetate are added, stirring is performed until uniform, and then the mixture is discharged.

[0157] The preparation raw material of the fermented oil for hair comprises Prunus amygdalus dulcis, Macadamia ternifolia seed, Anemarrhena asphodeloides root, and Citrus medica fruit, and the mass ratio is 1:1:1:1.

[0158] The preparation method of the fermented oil for hair is as follows:

[0159] (1) Freshly picked preparation raw materials are stored at 0-5 ℃ for 72 h, then taken out, mixed and chopped, placed in a culture solution, and inoculated with strain A for culture; the fermentation temperature is 30 ℃, and the time is 72 h.

[0160] (2) After the fermentation of step (1) is completed, inoculate new strain B, continue fermentation, centrifuge, remove the supernatant, and then add the same volume of methyl tert-butyl ether;

[0161] (3) After operating at 30°C and 300 r / min for 40 min, then continue to separate the solvent phase by centrifugation at room temperature at 10,000 r / min for 3 min, then add the same volume of 0.1 wt% NaCl solution to wash the solvent phase, dry over anhydrous sodium sulfate, and then remove the methyl tert-butyl ether by rotary evaporation, and then dry the oil to obtain the product.

[0162] In step (1), the composition of the culture solution is as follows: casein peptone (pancreatic digestion) 10.0 g, beef extract 10.0 g, yeast extract 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0163] Strain A is Bacillus polyfermenticus (China Industrial Microbial Culture Collection Center, CICC 23909), and the inoculation amount is 5 vol%.

[0164] Strain B is Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5 vol%. The fermentation temperature is 37°C, and the time is 48 h.

[0165] Example 5

[0166] The present embodiment provides a hair conditioner for hair care, and the preparation raw materials thereof comprise, by mass fraction:

[0167] Cyclopentasiloxane 53

[0168] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0169] Isocetyl 4

[0170] Fragrance 0.9

[0171] Caprylic / capric triglyceride 0.7

[0172] Fermented oil for hair 1

[0173] Mauritia flexuosa fruit oil 0.3

[0174] Macadamia ternifolia seed oil 0.2

[0175] Prunus amygdalus dulcis (sweet almond) oil 0.5

[0176] Simmondsia chinensis (jojoba) seed oil 0.5

[0177] Tocopheryl acetate 0.05.

[0178] A method for preparing the hair conditioner for hair, comprising the following steps:

[0179] (1) Put cyclopentasiloxane, dimethicone, dimethiconol into the stirring emulsifying pot, and stir until transparent;

[0180] (2) Put isohexadecane, fragrance, caprylic / capric triglyceride into the emulsifying pot, and maintain stirring;

[0181] (3) Put fermented oil, Mauritia flexuosa fruit oil, Macadamia ternifolia seed oil, Prunus amygdalus dulcis oil, Simmondsia chinensis seed oil, and tocopheryl acetate into the emulsifying pot, and stir until completely uniform, and then discharge.

[0182] The preparation raw materials of the fermented oil for hair include Prunus amygdalus dulcis, Macadamia ternifolia seed, Anemarrhena asphodeloides root, and Citrus medica fruit, and the mass ratio is 1:1:1:1.

[0183] The preparation method of the fermented oil for hair is as follows:

[0184] (1) Put the freshly picked preparation raw materials into a culture solution after being stored at 0-5℃ for 72 hours, and inoculate strain A for culture; the fermentation temperature is 30℃, and the time is 72 hours.

[0185] (2) After the fermentation in step (1) is completed, inoculate new strain B for continuous fermentation; centrifuge, remove the supernatant, and then add the same volume of methyl tert-butyl ether;

[0186] (3) After 40 minutes of operation at a temperature of 30℃ and a speed of 300 r / min, then continue to separate the solvent phase by centrifugation at room temperature at a speed of 10,000 r / min for 3 minutes, then wash the solvent phase with the same volume of 0.1wt% NaCl solution, dry over anhydrous sodium sulfate, and then remove the methyl tert-butyl ether by rotary evaporation, and then dry the oil to obtain the fermented oil for hair.

[0187] In step (1), the components of the culture solution are as follows: casein peptone (pancreatic digestion) 10.0 g, beef infusion powder 10.0 g, yeast infusion powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0188] Strain A is Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), and the inoculation amount is 5 vol%.

[0189] Strain B is Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5 vol%. The fermentation temperature is 37°C, and the time is 48 h.

[0190] Example 6

[0191] The present example provides a hair rinse, and the preparation raw materials thereof comprise, according to mass fraction:

[0192] Cyclopentasiloxane 53

[0193] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0194] Isocetyl 4

[0195] Fragrance 0.9

[0196] Caprylic / capric triglyceride 0.7

[0197] Hair fermentation oil 1

[0198] Mauritia flexuosa fruit oil 0.3

[0199] Macadamia ternifolia seed oil 0.2

[0200] Prunus amygdalus dulcis oil 0.5

[0201] Simmondsia chinensis seed oil 0.5

[0202] Tocopheryl acetate 0.05.

[0203] A preparation method of the hair rinse, and the steps are as follows:

[0204] (1) Add cyclopentasiloxane, dimethicone, dimethiconol into the stirring emulsifying pot, start stirring, and stir until uniform and transparent;

[0205] (2) Add isohexadecane, fragrance, caprylic / capric triglyceride into the emulsifying pot, and maintain stirring;

[0206] (3) Add fermented oil, MAURITIA FLEXUOSA fruit oil, MACADAMIA TERNIFOLIA seed oil, PRUNUS AMYGDALUS DULCIS oil, SIMMONDSIA CHINENSIS seed oil, and tocopheryl acetate, and stir until uniform and completely stirred, and then discharge.

[0207] The preparation raw materials of the fermented oil for hair include PRUNUS AMYGDALUS DULCIS, MACADAMIA TERNIFOLIA seed, Anemarrhena asphodeloides root, and Citrus medica fruit, and the mass ratio is 1:1:1:1.

[0208] The preparation method of the fermented oil for hair is as follows:

[0209] (1) After the fresh preparation raw materials are stored at 0-5℃ for 72 hours, the materials are taken out, mixed and chopped, and then placed in a culture solution and inoculated with strain A for culture; the fermentation temperature is 30℃, and the time is 72 hours.

[0210] (2) After the fermentation in step (1) is completed, new strain B is inoculated for further fermentation; after centrifugation and removal of the supernatant, the fermented oil is obtained.

[0211] In step (1), the composition of the culture solution is as follows: casein peptone (trypsin digestion) 10.0 g, beef infusion powder 10.0 g, yeast extract powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0212] Strain A is: Bacillus polyfermenticus (China Industrial Microbial Culture Collection Center, CICC 23909) and Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), and the inoculation amount is 5vol%, and the inoculation amount ratio is 3:2.

[0213] Strain B is: Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5vol%. The fermentation temperature is 37℃, and the time is 48 hours.

[0214] Example 7

[0215] The present embodiment provides a hair conditioner for hair, which is prepared from the following raw materials in the following proportions by mass:

[0216] Isoparaffin 53

[0217] Dimethicone, dimethiconol (1:1 by mass) 42

[0218] Isocetyl 4

[0219] Fragrance 0.9

[0220] Caprylic / capric triglyceride 0.7

[0221] Hair fermentation oil 1

[0222] Mauritia flexuosa fruit oil 0.3

[0223] Macadamia ternifolia seed oil 0.2

[0224] Prunus amygdalus dulcis oil 0.5

[0225] Simmondsia chinensis seed oil 0.5

[0226] Tocopheryl acetate 0.05.

[0227] A method for preparing the hair conditioner, comprising the following steps:

[0228] (1) Add cyclopentasiloxane, dimethicone, and dimethiconol to a stirring emulsifying pot, and stir until uniform and transparent;

[0229] (2) Add isocetyl, fragrance, and caprylic / capric triglyceride to the emulsifying pot, and maintain stirring;

[0230] (3) Add hair fermentation oil, Mauritia flexuosa fruit oil, Macadamia ternifolia seed oil, Prunus amygdalus dulcis oil, Simmondsia chinensis seed oil, and tocopheryl acetate, and stir until uniform and completely stirred, and then discharge.

[0231] The hair fermentation oil is prepared from the following raw materials in the following proportions by mass: Prunus amygdalus dulcis, Macadamia ternifolia seed, Anemarrhena asphodeloides root, and Citrus medica fruit.

[0232] The method for preparing the hair fermentation oil is as follows:

[0233] (1) Freshly picked preparation raw materials are stored at 0-5℃ for 72h, then mixed and cut, and placed in a culture solution and inoculated with strain A for culture; the fermentation temperature is 30℃ and the time is 72h.

[0234] (2) After the fermentation of step (1) is completed, new strain B is inoculated and the fermentation is continued; after the supernatant is removed by centrifugation, an equal volume of methyl tert-butyl ether is added;

[0235] (3) After 40min of operation at a temperature of 30℃ and a rotation speed of 300r / min, the solvent phase is separated by centrifugation at room temperature at 10000r / min for 3min, then an equal volume of 0.1wt% NaCl solution is added to wash the solvent phase, and the methyl tert-butyl ether is removed by rotary evaporation after the solvent phase is dried over anhydrous sodium sulfate and the oil is dried.

[0236] In step (1), the composition of the culture solution is: casein peptone (pancreatin) 10.0g, beef extract powder 10.0g, yeast extract powder 10.0g, glucose 25.0g, Tween 80 1.0g, sodium acetate 5.0g, triammonium citrate 2.0g, K2HPO4 2.0g, MgSO4·7H2O 0.2g, MnSO4·H2O 0.05g, agar 15.0g, and distilled water 1000.0mL.

[0237] Strain A is: Gluconacetobacter diazotrophicus (China Industrial Microbial Culture Collection Center, CICC 23909) and Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), and the inoculation amount is 5vol%, and the inoculation amount ratio is 3:2.

[0238] Strain B is: Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5vol%. The fermentation temperature is 37℃ and the time is 48h.

[0239] Example 8

[0240] This example provides a hair conditioner for hair, which, according to the mass fraction, contains:

[0241] Cyclopentasiloxane 53

[0242] Dimethicone, dimethiconol (mass ratio 1:1) 42

[0243] Isocetyl 4

[0244] Fragrance 0.9

[0245] Caprylic / capric triglyceride 0.7

[0246] Fermented oil for hair 2.5

[0247] Tocopheryl acetate 0.05.

[0248] A preparation method of the hair conditioner, comprising the following steps:

[0249] (1) Put cyclopentasiloxane, dimethicone, dimethiconol into a stirring emulsifying pot, and stir until transparent;

[0250] (2) Put isohexadecane, fragrance, caprylic / capric triglyceride into the emulsifying pot, and maintain stirring;

[0251] (3) Put fermented oil, MAURITIA FLEXUOSA fruit oil, MACADAMIA TERNIFOLIA seed oil, PRUNUS AMYGDALUS DULCIS oil, SIMMONDSIA CHINENSIS seed oil, and tocopheryl acetate into the emulsifying pot, and stir until completely uniform, and then discharge.

[0252] The fermented oil for hair is prepared from the following raw materials: PRUNUS AMYGDALUS DULCIS, MACADAMIA TERNIFOLIA seed, Anemarrhena asphodeloides root, and Citrus medica fruit, with a mass ratio of 1:1:1:1.

[0253] The preparation method of the fermented oil for hair is as follows:

[0254] (1) Put the freshly picked raw materials into a culture solution after being stored at 0-5℃ for 72 hours, and inoculate with strain A for culture; the fermentation temperature is 30℃, and the fermentation time is 72 hours.

[0255] (2) After the fermentation in step (1) is completed, inoculate with new strain B, and continue to ferment; centrifuge, remove the supernatant, and then add the same volume of methyl tert-butyl ether;

[0256] (3) After 40 minutes of operation at a temperature of 30℃ and a rotation speed of 300 r / min, continue to centrifuge at room temperature at a speed of 10,000 r / min for 3 minutes to separate the solvent phase, then wash the solvent phase with the same volume of 0.1 wt% NaCl solution, dry over anhydrous sodium sulfate, and then remove the methyl tert-butyl ether by rotary evaporation, and finally dry the oil to obtain the fermented oil for hair.

[0257] The components of the culture solution in step (1) are as follows: casein peptone (pancreatic digestion) 10.0 g, beef infusion powder 10.0 g, yeast infusion powder 10.0 g, glucose 25.0 g, Tween 80 1.0 g, sodium acetate 5.0 g, triammonium citrate 2.0 g, K2HPO4 2.0 g, MgSO4·7H2O 0.2 g, MnSO4·H2O 0.05 g, agar 15.0 g, and distilled water 1000.0 mL.

[0258] The strain A is: Bacillus polyfermenticus (China Industrial Microbial Culture Collection Center, CICC 23909) and Pediococcus pentosaceus (China Industrial Microbial Culture Collection Center, CICC 22228), and the inoculation amount is 5 vol%, and the inoculation amount ratio is 3:2.

[0259] The strain B is: Issatchenkia orientalis (China Industrial Microbial Culture Collection Center, CICC 32866), and the inoculation amount is 5 vol%. The fermentation temperature is 37°C, and the time is 48 h.

[0260] Performance test

[0261] Test 1: The method reflects the efficacy of the product in nourishing the hair by measuring the gloss and the improvement in combing property of the hair swatch before and after the sample is used.

[0262] Reagent consumables: cleaning solution; ex vivo human hair strands (length≥10 cm, net weight≥6 g).

[0263] Test object: sample group: examples 1-6.

[0264] Test method:

[0265] (1) Baseline dry hair test: the test hair strand is fully wetted with flowing constant-temperature clean water, and after being treated with the cleaning solution, it is placed in a constant-temperature and constant-humidity box (20-25°C, 40%-60%) for stabilization for more than 4 hours, taken out and fixed at the test position, and subjected to combing cycle test and gloss test.

[0266] (2) Sample dry hair test: the test hair strand is fully wetted with flowing constant-temperature clean water, and the sample is used on the surface of the hair strand at 0.2 g per gram of hair strand, with a use time of about 30 s. After standing for about 3-5 min, it is placed in a constant-temperature and constant-humidity box (20-25°C, 40%-60%) for stabilization for more than 4 hours, taken out and fixed at the test position, and subjected to combing cycle test and gloss test.

[0267] (3) The combing work value and gloss value before and after the test hair strand is used with the sample are recorded and subjected to data processing.

[0268] Combing work change rate = (A s -A0) / A0*100%.

[0269] A0= Baseline test combing work

[0270] A S Apost = Post-treatment test combing work

[0271] Glossiness change rate = (C s - C0) / C0 * 100%.

[0272] C0= Baseline test glossiness

[0273] C S Cpost = Post-treatment test glossiness

[0274] Table 1 Test results

[0275] Change in combing power / % Gloss test results % Example 1 -28.313 15.235 Example 2 -18.215 8.352 Example 3 -17.021 7.683 Example 4 -19.821 9.783 Example 5 -26.711 13.721 Example 6 -15.211 6.723 Example 7 -21.031 11.283 Example 8 -22.821 12.031

[0276] Performance test 2: breakage resistance efficacy test

[0277] The strength and toughness of hair is determined by tensile properties. Hair that is difficult to stretch or break is more resistant. The tensile force (load), stress, elongation at break point, yield point or specified point, and work done over the entire range are usually used to express the tensile properties. This method is to stretch a single hair at a constant speed until the hair breaks on a CTX texture analyzer instrument. The tensile strength and breaking work are calculated according to the curve. The tensile properties of hair are affected by environmental temperature and humidity, so temperature and humidity control measures are needed during the test process to ensure that the test environment is stable during the test process.

[0278] Reagent consumables: cleaning solution (sodium dodecyl sulfate solution); ex vivo human hair strands (length ≥ 15 cm, net weight ≥ 6 g).

[0279] Sample group: test examples 1-8.

[0280] Test method:

[0281] (1) Pre-test of the sample: the hair strands to be tested are fully wetted with flowing constant temperature water, and after being treated with cleaning solution, they are placed in a constant temperature and humidity chamber [(26±2) ℃, (60±10) %RH] for natural drying for 24 hours. Single tensile test is performed, and each test data is recorded.

[0282] (2) Post-test of the sample: the hair strands to be tested are washed with flowing constant temperature water or exempted from washing according to the sample use method. The sample is used on the surface of the hair strands according to 0.2 g of sample per gram of hair strands or the amount according to the sample use method, and after a certain period of time, the ex vivo hair is placed in a constant temperature and humidity chamber [(26±2) ℃, (60±10) %RH] for natural drying for 24 hours. Single tensile test is performed, and each test data is recorded.

[0283] Tensile strength change rate = (C s - C0) / C0 * 100%.

[0284] Wherein: C0— tensile strength before use of the sample;

[0285] C s — tensile strength after use of the sample.

[0286] Table 2 Tensile strength test results

[0287] Change in tensile strength / % Example 1 23.812 Example 2 18.213 Example 3 17.125 Example 4 20.014 Example 5 22.124 Example 6 15.241 Example 7 21.153 Example 8 21.673

[0288] Performance test 3: color protection performance test

[0289] The hair strands are semi-permanently dyed by the dyeing agent to stabilize the pigments of the hair in the form of care. The hair strand color difference of the hair sample group and the control group is tested by using a precise color difference sensor to measure the effect of the sample on improving the color protection of the hair by reducing the significant degree of the color difference of the hair strands. The color difference calculation formula is as follows:

[0290]

[0291] Wherein, ΔE represents the color difference before and after, L t represents the L value of the color of the hair strands after t time, L0 represents the L value of the color of the hair strands at the initial time, a t represents the a value of the color of the hair strands after t time, a0 represents the a value of the color of the hair strands at the initial time, b t represents the b value of the color of the hair strands after t time, b0 represents the b value of the color of the hair strands at the initial time.

[0292] Materials: light yellow, flat hair strands after bleaching treatment, 15 cm, 3.0 g.

[0293] Environmental requirements: temperature: 21.0℃±1.0℃; humidity: 50%±10%.

[0294] Hair color care test scheme

[0295] Randomly select 27 same flat hair strands (3.0 g, 15 cm, bleached hair strands), and randomly divide them into 9 groups, and equilibrate in a constant temperature and humidity environment [(21±1)℃, (50±10)%RH] for 24 hours;

[0296] Dye the 9 groups of hair strands with equal amounts of dyeing agents, respectively, and stand for 24 hours in a constant temperature and humidity environment [(21±1)℃, (50±10)%RH] after dyeing treatment;

[0297] Test the color values (Before) of the 9 groups of hair strands by colorimeter CL400, respectively;

[0298] 9 groups of hair strands were treated with the products of Examples 1-8 or water (control group) respectively: after washing the hair strands, the excess water was wiped off, 0.1 g / g of each hair strand was sampled and applied evenly to the hair, after 1 min of sample receiving, the hair strands were placed in a constant temperature and humidity [(21±1)℃, (50±10)%RH] environment for natural drying for 24 hours, and the operation was repeated for 50 times; the color values of the 9 groups of hair strands were tested by colorimeter CL400 (After).

[0299] Meanwhile, the anti-breakage of each group of hair strands was tested according to the method of Test 2.

[0300] Table 3 Test Results

[0301]

[0302] Performance Test 4: Stability Test

[0303] The products prepared in Examples 1-8 were placed at 0℃ and 45℃ for 90 days to observe the properties, and then were alternately placed at 0℃ and 45℃ for 12 hours, and the alternation was repeated for 6 times to observe the properties of the products.

[0304] Table 4 Test Results

[0305]

[0306]

[0307] Performance Test 5: Hair Scale Test Scheme

[0308] Two flat hair strands (3.0g, 15cm, damaged hair strands) were randomly selected and equilibrated in a constant temperature and humidity [(21±1)℃, (50±10)%RH] environment for 24 hours; after washing the hair strands, the excess water was wiped off, 0.1 g of the product of Example 1 was sampled and evenly applied to the hair of each hair strand in the sample group, after 1 min of sample receiving, the operation was repeated for 1 time, and the control group was treated according to the above steps. The hair strands were placed in a constant temperature and humidity [(21±1)℃, (50±10)%RH] environment for natural drying for 24 hours; after 24 hours, 3 hair strands were randomly selected from each group of hair strands for electron microscope shooting and comparison. The specific results are shown in Figure 1 and Figure 2 . Among them, Figure 1 is the sample group, Figure 2 is the control group.

[0309] Traditional fermented oil is to use yeast to decompose oil into small molecule oil to promote absorption; first, the strain decomposition oil itself has certain energy production limit, and is mixed with macromolecular oil ultimately, and the effect is not ideal. The present application uses two types of strains to ferment, starting from the plant raw material itself, using yeast to decompose the plant oil obtained by the strain, which can control the adjustment of oil to a certain extent.

[0310] However, the inventors found that the yield is low and the cost is high by using the above method; therefore, the fresh plant to be picked is stored at low temperature, and then subjected to enzymatic treatment and two-strain fermentation treatment, which can not only obtain higher yield, but also obtain better hair care effect. At the same time, when matching the hair care product, more macromolecules and siloxanes of the same kind are selected for compounding, and the skin care product with high product stability can be obtained.

[0311] Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present application, and not to limit them; although the present application has been described in detail with reference to the foregoing embodiments, those skilled in the art should understand that: it can still modify the technical solutions recorded in the foregoing embodiments, or make equivalent replacement for part or all of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the scope of the technical solutions of the embodiments of the present application.

Claims

1. A hair conditioner, prepared from the following ingredients by weight: Cyclopentasiloxane 53 Dimethicone, Dimethiconol 42; 1:1 by weight Isocetyl 4 Fragrance 0.9 Caprylic / capric triglyceride 0.7 Hair fermented oil 1 Mauritia flexuosa oil 0.3 Macadamia ternifolia seed oil 0.2 Prunus amygdalus dulcis oil 0.5 Simmondsia chinensis seed oil 0.5 Tocopheryl acetate 0.05 The hair fermented oil is prepared from the following ingredients by weight: Prunus amygdalus dulcis, Macadamia ternifolia seed, Anemarrhena asphodeloides, Citrus medica, 1:1:1:1 The preparation method of the hair fermented oil is as follows: (1) The freshly picked raw materials are stored at 0-5℃ for 72h, then mixed and cut into small pieces, and then placed in a culture solution and inoculated with strain A for culture; the fermentation temperature is 30℃ and the time is 72h; (2) After the fermentation in step (1) is completed, new strain B is inoculated and the fermentation is continued; then centrifugation is performed to remove the supernatant, and then an equal volume of methyl tert-butyl ether is added; wherein (3) After 40min of operation at a temperature of 30℃ and a speed of 300r / min, the solvent phase is then separated by centrifugation at room temperature at a speed of 10000r / min for 3min, then an equal volume of 0.1wt% NaCl solution is added to wash the solvent phase, then the methyl tert-butyl ether is removed by rotary evaporation after drying over anhydrous sodium sulfate, and then the oil is dried to obtain the product; In step (1), the composition of the culture solution is: tryptone, trypsin digestion, 10.0g, beef infusion powder 10.0g, yeast extract powder 10.0g, glucose 25.0g, Tween 80 1.0g, sodium acetate 5.0g, triammonium citrate 2.0g, K2HPO4 2.0g, MgSO4·7H2O 0.2g, MnSO4·H2O 0.05g, agar 15.0g, distilled water 1000.0mL; Strain A is: Gluconacetobacter diazotrophicus, China Industrial Microbial Culture Collection Center, CICC 23909; and Pediococcus pentosaceus, China Industrial Microbial Culture Collection Center, CICC 22228, inoculation amount 5vol%, inoculation amount ratio 3:2; Strain B is: Issatchenkia orientalis, China Industrial Microbial Culture Collection Center, CICC 32866, inoculation amount 5vol%; fermentation temperature 37℃, time 48h.

2. The preparation method of the hair conditioner according to claim 1, the steps are as follows: (1) Add cyclopentasiloxane, dimethicone, dimethiconol to the stirring emulsifying kettle, start stirring, and stir until uniform and transparent; (2) Add isocetyl, fragrance, caprylic / capric triglyceride to the emulsifying kettle and maintain stirring; (3) Add fermented oil, Mauritia flexuosa oil, Macadamia ternifolia seed oil, Prunus amygdalus dulcis oil, Simmondsia chinensis seed oil, and tocopheryl acetate, and stir until uniform and completely, then discharge.

3. The hair conditioner according to claim 1 for use in the field of cosmetics.

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