Preparation process and product of anti-noise ear hook for ear clip-on headphones

By injecting rubber and vulcanizing the silicone layer on the outside of the headphone wire, combined with polishing and oil spraying, the problem of abnormal noise during wearing of ear clip headphones is solved, and the durability and sound quality of the headphones are improved.

CN119603625BActive Publication Date: 2025-09-05DONGGUAN XINGSHENGDA INTELLIGENT TECH CO LTD
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Patent Information

Application Number
CN202411729914.1
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-11-29
Publication Date
2025-09-05
Estimated Expiration
2044-11-29

AI Technical Summary

Technical Problem

Existing clip-on earphones are prone to producing unusual noises when frequently bent during wearing, which affects the sound quality and performance.

Method used

The first silicone agent is first used to injection-mold the outside of the headphone cable and shape it, and then the second silicone agent is used to injection-mold the cable and vulcanize it. Combined with polishing and oil spraying, a stable silicone layer structure is formed to improve the flexibility and wear resistance of the headphone cable and reduce abnormal noise.

Benefits of technology

It effectively reduces abnormal noise and sound quality damage caused by frequent bending of ear clip headphones during long-term use, and improves the stability and sound quality of the headphones.

✦ Generated by Eureka AI based on patent content.

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Patent Text Reader

Abstract

The present application relates to the field of earphone processing, and discloses a preparation process and product of an anti-abnormal-noise earhook for ear-clip earphones. A preparation process of an anti-abnormal-noise earhook for ear-clip earphones, comprising the following steps: S1, using a first silicone agent to perform a first injection molding and gluing on the assembled earphone wire and shaping it to obtain a shaped earphone wire; S2, using a second silicone agent to perform injection molding and gluing on the shaped earphone wire and vulcanizing it to obtain a preliminary earhook; S3, polishing and oil-spraying the preliminary earhook, and then vulcanizing it to obtain an anti-abnormal-noise earhook. The anti-abnormal-noise earhook prepared by the preparation process of the present application has good flexibility and wear resistance, and is applied to ear-clip earphones. It will not produce abnormal noise or unstable sound quality after multiple bendings, and has good stability in use.
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Description

Technical Field

[0001] The present application relates to the field of earphone processing, and more specifically, to a preparation process and product of an anti-noise ear hook for an ear clip-on earphone. Background Art

[0002] With the continuous development of wireless communication technology, Bluetooth headsets are becoming increasingly popular. In particular, clip-on Bluetooth headsets are increasingly popular among consumers due to their portability and comfort. Clip-on earphones primarily consist of a sound chamber, an earhook, and a headphone cable. The sound chamber produces sound, the earhook clips onto the ear to secure the earphones, and the headphone cable runs through the earhook to transmit audio signals.

[0003] During the production process of ear clip headphones, the assembled headphone wire needs to be placed in an injection mold for injection molding. However, the assembled headphone wire is not easy to fix its shape in the injection mold and is prone to deformation, thereby reducing the yield of the finished product. Therefore, it is necessary to first use quick-drying glue to shape the headphone wire, and then add a layer of UV glue on the surface of the headphone wire and cure it to prevent the headphone wire from deforming in the injection mold and maintain a good bending shape.

[0004] However, this processing technology makes the various parts of the assembled headphone wire completely fixed. When the ear clip-on headphones need to be bent frequently during wear, the cured quick-drying glue and UV glue will wrinkle or even break, causing the ear clip-on headphones to produce abnormal noises, affecting the sound quality and other performance of the ear clip-on headphones. Summary of the Invention

[0005] In order to solve the problem that the ear clip-on earphones produced by the existing preparation process are prone to abnormal noise when they need to be frequently bent during wearing, thereby reducing the sound quality and performance of the ear clip-on earphones, the present application provides a preparation process and product of an anti-abnormal noise ear hook for ear clip-on earphones.

[0006] In a first aspect, the present application provides a process for preparing an anti-noise ear hook for an ear clip-on headphone, which adopts the following technical solution:

[0007] A process for preparing an anti-noise ear hook for an ear clip-on headphone comprises the following steps:

[0008] S1. Injection-molding the assembled earphone cable with a first silicone agent and shaping it to obtain a shaped earphone cable;

[0009] S2. Injection-molding the shaped earphone wire with a second silicone agent and vulcanizing it to produce a primary earhook product;

[0010] S3. The ear hook is polished and oil-sprayed, and then vulcanized to obtain an anti-sounding ear hook.

[0011] By adopting the above technical solution, the first silicone agent is firstly used to perform injection molding and gluing on the outer side of the assembled earphone wire and to shape it, so that the outer surface of the earphone wire is covered with a layer of silicone layer. Under the action of the silicone layer, the earphone wire can maintain a bent state while not easily deformed. The silicone layer has good flexibility, thereby enhancing the structural stability of the earphone wire, making it difficult for the earphone wire to break or crack during the bending process; then the second silicone agent is used to perform injection molding and gluing and vulcanization treatment, so that the second silicone agent stably covers and adheres to the surface of the silicone layer formed with the first silicone agent, and the silicone of the earphone wire is formed. The outer side of the layer is covered with a silicone outer layer, which improves the durability and fatigue resistance of the earphone wire. When it is bent, the earphone wire is not easily damaged under the joint buffering effect of the silicone layer and the silicone outer layer. The prepared ear hook will not crack after long-term use, reducing the problems of abnormal noise and sound quality damage in ear-clip earphones and improving the stability of ear-clip earphones. The prepared ear hook is then polished and sprayed with oil and vulcanized again. Polishing can remove burrs and uneven parts on the surface of the ear hook, and spraying with oil can further improve the flatness of the ear hook, giving the ear hook a smooth feel and wear resistance.

[0012] Preferably, the upper mold temperature of the injection molding process in step S1 is 120±5°C, the lower mold temperature is 130±5°C, and the molding pressure is 90±20kg / cm 2 , the setting time is 180±10s.

[0013] By adopting the above technical solution, the better injection molding parameters and shaping parameters can improve the shaping accuracy and stability of the headphone wire, form a silicone layer on the outer surface of the headphone wire that stably covers the headphone wire, and stably bend and shape the headphone wire.

[0014] Preferably, the injection pressure of the first silicone agent in step S1 is 35-55 kg / cm 2 , the injection speed is 20-40%.

[0015] By adopting the above technical solution, the better injection pressure and injection rate can enable the first silicone agent to be stably injected into the mold, thereby improving the injection stability of the first silicone agent and forming a uniform and stable silicone layer on the surface of the earphone wire.

[0016] Preferably, the vulcanization temperature in step S2 is 140±5° C., and the vulcanization time is 120±10 min.

[0017] By adopting the above technical solution, the better second vulcanization conditions can enable the second silicone agent to be fully vulcanized and stably adhere to the surface of the silicone layer formed by the first silicone agent, thereby improving the flexibility and durability of the ear hook, further reducing the abnormal noise problem caused by frequent bending of the ear clip earphones during use, and improving the overall quality of the ear clip earphones.

[0018] Preferably, the vulcanization temperature in step S3 is 140±5° C., and the vulcanization time is 120±10 min.

[0019] By adopting the above technical solution, the better third vulcanization conditions can make the ear hook surface have better flatness and smoothness, thereby improving the overall texture and wear resistance of the ear clip earphones.

[0020] Preferably, the first silicone agent is liquid silicone or solid silicone, and the second silicone agent is liquid silicone or solid silicone.

[0021] By adopting the above technical solution, the first silicone agent and the second silicone agent in this application can be either liquid silicone or solid silicone. The two silicones can be used interchangeably and applied to the process of this application, which is easy to operate and saves production energy efficiency.

[0022] Preferably, the first silicone agent and the second silicone agent are both two-component liquid silicone agents, and component A of the two-component liquid silicone agent is prepared from the following raw materials in parts by weight: 40-60 parts of vinyl silicone oil, 15-20 parts of fumed silica, 8-12 parts of crosslinking agent, 5-8 parts of stabilizer, 2-4 parts of silane coupling agent, and 0.5-1.5 parts of color glue; component B of the two-component silicone agent is prepared from the following raw materials in parts by weight: 15-20 parts of hydrogenated silicone oil, 2-4 parts of dimethyl silicone oil, 8-12 parts of fumed silica, and 1-2 parts of catalyst.

[0023] By adopting the above technical solution, the first silicone agent and the second silicone agent of the present application are both two-component liquid silicone agents. The two-component liquid silicone agent has a small shrinkage rate and good fluidity during the curing process. The first silicone agent can be evenly adhered to the surface of the headphone wire to form a silicone layer on the surface of the headphone wire to stabilize the headphone wire. The second silicone agent can evenly form a flexible and wear-resistant silicone outer layer on the outer surface of the silicone layer, while improving the flexibility and wear resistance of the ear hook. Under the joint buffering effect of the first silicone agent and the second silicone agent, it has good bending resistance, which can significantly reduce the abnormal noise problem caused by bending activities during long-term use of ear-clip headphones.

[0024] Among them, component A is mainly composed of vinyl silicone oil, which provides vinyl groups for the reaction; component B is mainly composed of hydrogenated silicone oil, which provides silicon-hydrogen bonds for the reaction. Under the action of the catalyst, a silicon-hydrogen addition reaction is carried out. The fumed silica can enhance the performance of the first silicone agent and the second silicone agent. The cross-linker and the stabilizer can produce a good synergistic effect, further react with the silicone system, and form a network-interwoven macromolecular silicone structure to improve the flexibility and wear resistance of the prepared ear clip. At the same time, it can improve the fitting stability of the first silicone agent and the second silicone agent, and reduce the abnormal noise problem caused by bending activities during long-term use of the ear clip earphones. The silane coupling agent can play a synergistic role with the cross-linker and the stabilizer, improve the dispersion performance of the fumed silica in the silicone system, and further improve the wear resistance and flexibility of the ear clip earphones.

[0025] Preferably, the crosslinking agent is composed of triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester in a weight ratio of 1:1:(1-3).

[0026] By adopting the above technical solution, triallyl isocyanurate is a multifunctional olefin monomer containing a triazine ring, which can produce a good synergistic enhancement effect with diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester, and further undergo a cross-linking reaction with the silicone system; diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester both have long-chain ether structures and active groups, which can cooperate with triallyl isocyanurate and the silicone system to be uniformly interwoven to form a macromolecular network interwoven structure, thereby improving the flexibility and wear resistance of the first silicone agent and the second silicone agent, thereby improving the sound quality damage and abnormal noise problems caused by the inability to withstand bending during long-term use of ear clip-on headphones.

[0027] Preferably, the stabilizer is composed of trimethylolpropane diallyl ether and 2-octenyl succinic anhydride in a weight ratio of (1-2):1.

[0028] By adopting the above technical solution and using trimethylolpropane diallyl ether and 2-octenylsuccinic anhydride in a relatively optimal weight ratio as stabilizers, the reaction stability of the silicone system can be further improved, thereby forming a more stable cross-linked structure of the system, thereby improving the bending resistance of the ear clip-on headphones during repeated bending, thereby improving the abnormal noise problem.

[0029] Preferably, the catalyst is a platinum catalyst.

[0030] By adopting the above technical solution, the use of platinum catalyst can effectively improve the chemical reaction efficiency and stability of the two-component silicone agent during the injection molding and vulcanization process.

[0031] In a second aspect, the present application provides an anti-noise ear hook, which adopts the following technical solution:

[0032] An anti-noise ear hook is made by the above-mentioned preparation process.

[0033] By adopting the above technical solution, the anti-noise ear hook prepared in the present application has good bending resistance and wear resistance, and is applied to ear-clip headphones. During use, it is not easy to crack due to frequent bending, can maintain good sound quality and usage stability, and will not cause abnormal noise problems.

[0034] In summary, this application has the following beneficial effects:

[0035] 1. The preparation process of the anti-noise ear hook of the ear clip type earphone of the present application is as follows: first, a first silicone agent is injection molded and coated on the outer surface of the assembled earphone wire and a layer of the first silicone agent is formed; then a second silicone agent is injection molded and coated on the outer surface of the first silicone agent and vulcanized; then, the process is polished and oil-sprayed and vulcanized for the third time; the first silicone agent and the second silicone agent have good fitting stability; under the joint buffering effect of the first silicone agent and the second silicone agent, the earphone wire is not easily damaged, and the prepared ear hook will not crack after long-term use, thereby reducing the problems of abnormal noise and sound quality damage in the ear clip type earphone and improving the stability of the ear clip type earphone.

[0036] 2. By using triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester in an optimal dosage ratio as cross-linking agents, a better synergistic effect is produced, and a cross-linking reaction is carried out with the silicone system to form a macromolecular network interwoven structure, thereby improving the fitting stability, flexibility and wear resistance of the first silicone agent and the second silicone agent, thereby improving the sound quality damage and abnormal noise problems caused by the inability to withstand bending during long-term use of ear clip-on headphones.

[0037] 3. By using trimethylolpropane diallyl ether and 2-octenyl succinic anhydride as stabilizers in a preferred weight ratio, the reaction stability of the silicone system can be further improved, thereby forming a more stable cross-linked structure of the system, thereby improving the bending resistance of the ear clip headphones during repeated bending, thereby reducing the problem of abnormal noise.

[0038] 4. The anti-noise ear hook prepared in this application has good bending resistance and wear resistance. When used in ear-clip headphones, it is not easy to crack due to frequent bending activities during use, can maintain good sound quality and usage stability, and will not cause abnormal noise problems. DETAILED DESCRIPTION

[0039] The present application is further described in detail below with reference to the embodiments.

[0040] The following are the sources and specifications of some raw materials of this application. The raw materials used in the preparation examples and examples of this application can be obtained from commercial sources, including but not limited to the following models and manufacturers. Raw materials with equivalent performance can be used:

[0041] 1. Vinyl silicone oil: vinyl content 1-1.3%, viscosity (cps, 25℃): 1000-2000;

[0042] 2. Methyl hydrogen silicone oil: hydrogen content 1.4-1.6%, viscosity 20-60mm 2 / s;

[0043] 3. Fumed silica: Cabot silica CAB-O-SIL M5;

[0044] 4. Triallyl isocyanurate: purity 99%, CAS number 1025-15-6;

[0045] 5. Cyclohexane-1,2-dicarboxylic acid diglycidyl ester: content 98%, CAS number 5493-45-8;

[0046] 6. Trimethylolpropane diallyl ether: CAS No. 682-09-7, content 99%;

[0047] 7. 2-Octenylsuccinic anhydride: CAS No. 26680-54-6, content 99%;

[0048] 8. Platinum catalyst: platinum content 15000-20000ppm.

[0049] Preparation examples of the first silicone agent and the second silicone agent

[0050] Preparation Example 1

[0051] Preparation Example 1 discloses a first silicone agent and a second silicone agent. Both the first silicone agent and the second silicone agent are two-component liquid silicone agents. The two-component liquid silicone agents are prepared by the following steps:

[0052] Component A: Add 4kg vinyl silicone oil, 1.2kg crosslinker (composed of 0.8kg allyl glycidyl ether and 0.4kg triallyl isocyanurate), 0.5kg trimethylolpropane diallyl ether as a stabilizer, 0.2kg vinyltrimethoxysilane as a silane coupling agent, 1.5kg fumed silica, and 0.05kg color glue into a mixer, mix at 15°C for 1h, mix well, and store. The color glue can be a commercially available special color glue for silicone, and any model is acceptable.

[0053] Component B: Add 1.5 kg hydrogenated silicone oil, 0.2 kg dimethyl silicone oil, 0.8 kg fumed silica and 0.1 kg platinum catalyst into a mixer, mix at 15°C for 30 minutes, mix well and store;

[0054] Preparation Example 2-3

[0055] The difference between Preparation Example 2-3 and Preparation Example 1 is that the amount of raw materials used and the preparation conditions are different. Please refer to Table 1 below for details.

[0056] Table 1 Raw material dosage and preparation conditions of Preparation Examples 1-3

[0057]

[0058]

[0059] Preparation Example 4

[0060] The difference between Preparation Example 4 and Preparation Example 1 is that the type of cross-linking agent is different. The cross-linking agent in Preparation Example 4 is composed of triallyl isocyanurate and diethylene glycol divinyl ether. The amount of triallyl isocyanurate is 0.8 kg, and the amount of diethylene glycol divinyl ether is 0.4 kg. The others are the same as Preparation Example 1.

[0061] Preparation Example 5

[0062] The difference between Preparation Example 5 and Preparation Example 1 is that the types of cross-linking agents are different. The cross-linking agent in Preparation Example 5 is composed of triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester. The amount of triallyl isocyanurate is 0.4 kg, the amount of diethylene glycol divinyl ether is 0.4 kg, and the amount of cyclohexane-1,2-dicarboxylic acid diglycidyl ester is 0.4 kg. The rest is the same as Preparation Example 1.

[0063] Preparation Example 6

[0064] The difference between Preparation Example 6 and Preparation Example 1 is that the cross-linking agent consists of triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester, the amount of triallyl isocyanurate used is 0.24 kg, the amount of diethylene glycol divinyl ether used is 0.24 kg, and the amount of cyclohexane-1,2-dicarboxylic acid diglycidyl ester used is 0.72 kg, and the others are the same as Preparation Example 1.

[0065] Preparation Example 7

[0066] The difference between Preparation Example 7 and Preparation Example 6 is that the stabilizer consists of trimethylolpropane diallyl ether and 2-octenyl succinic anhydride, the amount of trimethylolpropane diallyl ether used is 0.25 kg, the amount of 2-octenyl succinic anhydride used is 0.25 kg, and the rest is the same as Preparation Example 6.

[0067] Preparation Example 8

[0068] The difference between Preparation Example 8 and Preparation Example 6 is that the stabilizer consists of trimethylolpropane diallyl ether and 2-octenyl succinic anhydride, the amount of trimethylolpropane diallyl ether used is 0.33 kg, and the amount of 2-octenyl succinic anhydride used is 0.17 kg. The rest is the same as Preparation Example 6.

[0069] Example

[0070] Example 1

[0071] Example 1 discloses a process for preparing an anti-noise earhook for an earhook headphone, comprising the following steps:

[0072] S1. Place the assembled earphone cables one by one on a fixture with four earphone cable clamping positions, then place the fixture in the injection mold of the injection molding machine. Adjust the parameters of the injection molding machine to control the upper mold temperature of the injection molding machine to 115°C and the lower mold temperature to 125°C. Use the commercially available first silicone agent for liquid injection molding, and control the injection pressure of the first silicone agent to 35kg / cm 2 The injection speed is 40%, the injection volume is 15g, and the molding is carried out after injection molding. The molding pressure is controlled at 70kg / cm 2 The shaping time is 170s. After shaping is completed, the mold is opened to obtain the shaped headphone wire.

[0073] S2. Clamp the shaped earphone wire obtained in step S1 on a fixture and place it in the injection mold of an injection molding machine. Control the injection temperature of the injection molding machine to 135°C. Use a commercially available second silicone agent for liquid injection molding. Control the injection pressure of the second silicone agent to 35kg / cm 2 , the injection speed is 40%, the injection volume is 60g, and the curing is carried out at the injection temperature for 110min. After the curing is completed, the mold is opened to obtain the initial ear hook product;

[0074] S3. Polish the outer and inner rings of the ear hook three times using 1200-grit sandpaper, then spray them with hand-feeling oil. After spraying, place them in an oven at 135°C for further vulcanization for 110 minutes to produce the anti-squeak ear hook.

[0075] The first silicone agent and the second silicone agent in this embodiment are both commercially available two-component addition-type liquid silicone rubber from Xin'an Tianyu Silicone, model TYL-6420-60AB, with the ratio of component A to component B being 1:1.

[0076] When the first silicone agent and / or the second silicone agent is solid silicone, a molding vulcanizer can be used to vulcanize and encapsulate the earphone wire. The use of a molding vulcanizer is a commonly used vulcanization method in the art and will not be described in detail here.

[0077] The injection molding machine used in this embodiment is an 85T injection molding machine. The hand-feeling oil used in the oil injection process in this embodiment is the commercially available Koshivi SH-05. Actual production includes but is not limited to hand-feeling oils of this manufacturer and model.

[0078] Examples 2-4

[0079] The difference between Example 2-4 and Example 1 is that the first silicone agent and the second silicone agent have different sources and the parameter conditions of the preparation process are different. Please refer to Table 2 below for details.

[0080] Table 2 Parameters of Examples 2-4

[0081]

[0082]

[0083] Examples 5-9

[0084] The difference between Examples 5-9 and Example 1 is that the sources of the first silicone agent and the second silicone agent are different. Please refer to Table 3 below for details.

[0085] Table 3 Sources of the first and second silica gel agents of Examples 5-9

[0086] Example The source of the first silicone agent Source of the second silicone agent Example 5 Preparation Example 4 Preparation Example 4 Example 6 Preparation Example 5 Preparation Example 5 Example 7 Preparation Example 6 Preparation Example 6 Example 8 Preparation Example 7 Preparation Example 7 Example 9 Preparation Example 8 Preparation Example 8

[0087] Comparative Example

[0088] Comparative Example 1

[0089] The difference between the comparative example and Example 1 is that step S1 is not performed, and the assembled earphone wire is directly injection-molded and vulcanized using the second silicone agent. The injection amount of the second silicone agent is 55g, and the rest is the same as Example 1.

[0090] Performance testing

[0091] The anti-noise ear hooks prepared in Examples 1-9 and Comparative Example 1 were tested as follows:

[0092] 1. Elongation at break test:

[0093] Refer to the test method in GB / T528-2009 to test the elongation at break (unit: %) of the anti-squeak ear hook, and test and record the test results.

[0094] 2. Wear resistance test:

[0095] Use a wear tester with a load of 500g, wipe standard artificial sweat with cotton cloth, adjust the test speed to 60r / min, and record the number of frictions when wear marks appear;

[0096] 3. Ear clip headphone abnormal sound test

[0097] Assembling the prepared anti-noise ear hook and other accessories to produce an ear clip-on headset, bending the anti-noise ear hook of the ear clip-on headset to 30 degrees, and performing a 1000-cycle bend. Using an audio analyzer, transmitting a standard audio frequency (1 kHz), the signal-to-noise ratio (in dB) of the ear clip-on headset is tested. A higher signal-to-noise ratio indicates lower noise and better sound quality. The test results are then recorded.

[0098] The following are the performance test data of the anti-noise ear hooks of Examples 1-9 and Comparative Example 1. Please refer to Table 4 below for details.

[0099] Table 4 Data table of Examples 1-9 and Comparative Example 1

[0100]

[0101] Combining Examples 1 and 2-9 with Table 4, it can be concluded that the anti-squeak ear hooks produced using the two-component liquid silicone agent of the present application as the first and second silicone agents exhibit good flexibility and wear resistance, and the resulting ear clip-on headphones have good bending resistance, good sound quality, and no abnormal noise. Compared to Example 1, Examples 2-4, using the first and second silicone agents of the present application, increased the elongation at break by 50%, the number of wear cycles by 125, and the signal-to-noise ratio by 15dB.

[0102] Furthermore, in Example 5-7, compared with Example 2, in Example 5, triallyl isocyanurate and diethylene glycol divinyl ether are used as cross-linking agents. Compared with Example 2, the elongation at break of the anti-noise ear hook is increased by 15%, the number of wear times is increased by 25 times, and the signal-to-noise ratio is increased by 3dB; while in Examples 6-7, triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester are used as cross-linking agents in a better ratio. Compared with Example 2, the elongation at break of the anti-noise earhook is increased by 62%, the number of wear times is increased by 132 times, and the signal-to-noise ratio is increased by 21dB; it can be seen that the optimal dosage ratio of triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester is used as a cross-linking agent, and the first silicone agent and the second silicone agent prepared have significantly improved the flexibility and wear resistance of the anti-noise earhook of the present application, thereby improving the anti-noise performance of the obtained ear-clip headphones.

[0103] Compared with Example 7, Examples 8-9 further optimize the proportion of the stabilizer, and the elongation at break of the anti-noise ear hook obtained is increased by 26%, the number of wear times is increased by 53 times, and the signal-to-noise ratio is increased by 10dB.

[0104] Compared with Comparative Example 1, Example 1 changes the preparation process of the anti-noise ear clip, and the elongation at break of the anti-noise ear clip is reduced by 20%. Although the reduction is not much, the signal-to-noise ratio is significantly reduced by 34dB. It can be seen that the use of the two-time injection molding and encapsulation preparation process of the present application in combination with the first silicone agent and the second silicone agent of the present application can significantly improve the flexibility and wear resistance of the anti-noise ear clip, solve the abnormal noise problem of ear clip headphones, and improve the sound quality and usage stability of ear clip headphones.

[0105] This specific embodiment is merely an explanation of the present application and is not a limitation of the present application. After reading this specification, those skilled in the art may make non-creative modifications to the present embodiment as needed, but as long as they are within the scope of the claims of the present application, they are protected by the patent law.

Claims

1. A process for preparing an anti-noise ear hook for an ear clip-on headphone, characterized in that: The following steps are involved: S1. Injection-molding the assembled earphone cable with a first silicone agent and shaping it to obtain a shaped earphone cable; S2. Injection-molding the shaped earphone wire with a second silicone agent and vulcanizing it to produce a primary earhook product; S3, polishing and oil-spraying the ear hook, and then vulcanizing the ear hook to obtain the anti-squeak ear hook; The first silicone agent and the second silicone agent are both two-component liquid silicone agents. Component A of the two-component liquid silicone agent is prepared from the following raw materials in parts by weight: 40-60 parts of vinyl silicone oil, 15-20 parts of fumed silica, 8-12 parts of a crosslinking agent, 5-8 parts of a stabilizer, 2-4 parts of a silane coupling agent, and 0.5-1.5 parts of a colorant. Component B of the two-component silicone agent is prepared from the following raw materials in parts by weight: 15-20 parts of hydrogenated silicone oil, 2-4 parts of dimethyl silicone oil, 8-12 parts of fumed silica, and 1-2 parts of a catalyst. The cross-linking agent is composed of triallyl isocyanurate, diethylene glycol divinyl ether and cyclohexane-1,2-dicarboxylic acid diglycidyl ester in a weight ratio of 1:1:(1-3); The stabilizer consists of trimethylolpropane diallyl ether and 2-octenyl succinic anhydride in a weight ratio of (1-2):

1.

2. The process for preparing the anti-noise ear hook for ear clip-on headphones according to claim 1, characterized in that: The upper mold temperature of the injection molding in step S1 is 120±5°C, the lower mold temperature is 130±5°C, the molding pressure is 90±20 kg / cm2, and the molding time is 180±10s.

3. The process for preparing the anti-noise ear hook for ear clip-on headphones according to claim 1, characterized in that: The injection pressure of the first silicone agent in step S1 is 35-55 kg / cm2.

4. The process for preparing the anti-noise ear hook for ear clip-on headphones according to claim 1, characterized in that: The vulcanization temperature in the step S2 is 140±5° C., and the vulcanization time is 120±10 min.

5. The process for preparing the anti-noise ear hook for ear clip-on headphones according to claim 1, characterized in that: The vulcanization temperature in step S3 is 140±5° C., and the vulcanization time is 120±10 min.

6. An anti-noise ear hook, characterized in that: The invention is prepared by the preparation process according to any one of claims 1 to 5.

Citation Information

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