An antibiotic wastewater photo-reaction treatment device and treatment method
The photoreaction treatment equipment, which employs a combination of synergistic methods including flocculation sedimentation, photolysis plate cleaning, ozone aeration, and ultrasonic vibration, has solved the problems of low efficiency and high energy consumption in antibiotic wastewater treatment, achieving efficient and energy-saving antibiotic degradation.
Patent Information
- Application Number
- CN202411826453.X
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-12-12
- Publication Date
- 2025-11-21
- Estimated Expiration
- 2044-12-12
AI Technical Summary
Existing photolysis equipment for antibiotic wastewater relies on weather or artificial light sources, resulting in low efficiency and high energy consumption. Furthermore, the equipment is prone to contamination, leading to poor treatment efficiency for antibiotic wastewater.
The photochemical reaction treatment equipment employs multiple synergistic methods, including wastewater coagulation, photolysis, ozone oxidation, and ultrasonic vibration. Through flocculation sedimentation, photolysis plate cleaning, light-transmitting cover to enhance ultraviolet intensity, ozone aeration, and ultrasonic cavitation effect, the photolysis efficiency is improved.
It improved the photolysis efficiency of antibiotic wastewater, reduced energy consumption, and enhanced the light transmittance and antibiotic degradation effect of the photolysis device.
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Figure CN119683794B_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The present application relates to the technical field of wastewater treatment, in particular to an antibiotic wastewater photo-reaction treatment equipment and method. BACKGROUND
[0002] Antibiotic wastewater refers to the wastewater containing high concentration of antibiotics generated during the production of antibiotics. The treatment of this kind of wastewater is an important environmental challenge because the widespread use of antibiotics has led to the problem of antibiotic pollution in water bodies. The characteristics of antibiotic wastewater include high concentration of organic matter, many toxic and harmful substances, and high salt content, which makes it difficult for traditional wastewater treatment methods to effectively treat antibiotic wastewater.
[0003] Antibiotic photolysis is a method of using photocatalytic technology to treat antibiotic wastewater. The main principle of this technology is to generate strong oxidants such as hydroxyl radicals or superoxide radicals through photocatalysts under light conditions, which can break the chemical bonds in antibiotic molecules and achieve the degradation of antibiotics.
[0004] The existing wastewater photolysis equipment has the following problems: relying on solar energy as the light source, the photolysis of wastewater is more dependent on the weather, and the photolysis efficiency decreases linearly in bad weather. The use of artificial light sources for photolysis consumes a lot of energy, and the lampshade in the water body is easily contaminated, affecting the light transmittance and leading to a decrease in photolysis efficiency. Therefore, a multi-way collaborative photo-reaction treatment equipment is needed to degrade antibiotics in antibiotic wastewater to achieve the purpose of energy saving and efficiency improvement. SUMMARY
[0005] To solve the above technical problems, the present application provides an antibiotic wastewater photo-reaction treatment equipment and method.
[0006] The technical solution of the present application is: an antibiotic wastewater photo-reaction treatment equipment, comprising a wastewater coagulation device, a water inlet pipe is fixedly connected to the left side of the wastewater coagulation device, a sedimentation mechanism is connected to the right side of the wastewater coagulation device, and a photolysis device is fixedly connected to the right side of the sedimentation mechanism.
[0007] The photolysis device comprises a left collecting tank, the left collecting tank is in communication with the sedimentation mechanism, a photolysis tank is arranged on the right side of the left collecting tank, a support frame is fixedly connected to the bottom of the photolysis tank, a plurality of photolysis plates are fixedly connected in the photolysis tank, a right collecting tank is connected to the right side of the photolysis tank, a drain pipe is connected to the front end of the right collecting tank, the photolysis plate comprises a photolysis lamp shell, a filter one is attached to the inner wall of the photolysis lamp shell, and a plurality of xenon lamps are fixedly connected in the photolysis lamp shell.
[0008] Further, the wastewater coagulation device comprises a coagulation bin, a material bin is fixedly connected to the top of the coagulation bin, a discharging motor is fixedly connected to the left side wall of the material bin, a screw rod is in transmission connection with the output shaft of the discharging motor, a discharging pipe is fixedly connected to the right side of the material bin, a blowing shell is fixedly connected to the right side of the material bin, a blower is fixedly connected to the top of the blowing shell, and a bend pipe is arranged on the right side of the blowing shell and used for communicating with the inside of the coagulation bin.
[0009] Description: The flocculating agent in the material bin is discharged into the blowing shell through the screw rod, is blown away by the blower in the blowing shell, and is discharged into the coagulation bin through the bend pipe. Such a structure can make the flocculating agent disperse in the water body.
[0010] Further, a rotating motor is fixedly connected to the top of the coagulation bin, a transmission shaft is in transmission connection with the lower end of the output shaft of the rotating motor, a connecting frame is fixedly connected in the coagulation bin, a rotating shaft is rotatably connected to the middle part of the connecting frame, a universal joint is fixedly connected to the left end of the rotating shaft, a propeller is fixedly connected to the right end of the transmission shaft, and the transmission shaft is hinged to the universal joint.
[0011] Description: The transmission shaft is driven to rotate by the rotating motor, and then the universal joint is driven to rotate. The rotating shaft is driven to rotate by the universal joint, and the propeller is driven to rotate by the rotating shaft. The propeller rotation stirs the water body, so that the flocculating agent and the water body are more easily mixed. Such a stirring mode can effectively reduce the flow resistance of the water body.
[0012] Further, the precipitation mechanism comprises an inclined pipe, the left side of the inclined pipe communicates with the coagulation bin, the right side of the inclined pipe communicates with the left side collecting groove, a plurality of branch pipes are communicated below the inclined pipe, a precipitation pipe is in threaded connection with the lower part of the branch pipe, and a control valve is arranged in the middle part of the branch pipe.
[0013] Description: In the process of upward movement of the water body, the flocculation precipitate is deposited in the precipitation pipe. When cleaning is needed, the control valve is only needed to be closed, the precipitation pipe is only needed to be removed, and the precipitate is only needed to be poured out. Such a structure is convenient to use and does not affect the normal work of the device in the process of cleaning the flocculation precipitate.
[0014] Further, a cleaning mechanism is arranged above the photolysis tank, the cleaning mechanism comprises a front sliding rail mechanism and a rear sliding rail mechanism, the lower parts of the front sliding rail mechanism and the rear sliding rail mechanism are fixedly connected with the support frame through a short rod, a cleaning rod is in sliding connection between the front sliding rail mechanism and the rear sliding rail mechanism, and a plurality of cleaning brushes for cleaning the photolysis plate are arranged below the cleaning rod.
[0015] Description: The cleaning rod is driven to move on the photolysis tank 42 by the front sliding rail mechanism and the rear sliding rail mechanism, and the photolysis plate is cleaned by the cleaning brushes.
[0016] Further, the front slide rail mechanism and the rear slide rail mechanism each comprise a sliding seat, the cleaning rod is fixedly connected with the sliding seat, a lead screw is rotatably connected outside the sliding seat, one end of the sliding seat is fixedly connected with a lead screw motor for driving the lead screw to rotate, and the lead screw is in transmission connection with the cleaning rod.
[0017] Description: The lead screw motor drives the lead screw to rotate, and the lead screw drives the cleaning rod to move on the sliding seat.
[0018] Further, the top of the photolysis tank is fixedly connected with a light-transmitting cover through a support rod, and the bottom of the light-transmitting cover is attached with a filter II.
[0019] Description: The filter II on the light-transmitting cover allows ultraviolet light in the sunlight to pass through and irradiate in the photolysis tank, thereby improving the intensity of the ultraviolet light in the photolysis tank and reducing the energy consumption required for photolysis of the photolysis tank.
[0020] Further, an ozone generator fixedly connected with the support frame is fixedly connected below the photolysis tank, a microporous aeration pipe is fixedly connected to the inner bottom of the photolysis tank, and a gas supply pipe is in communication between the ozone generator and the microporous aeration pipe.
[0021] Description: The ozone generator generates ozone, which is uniformly discharged into the photolysis tank through the microporous aeration pipe, and the antibiotic in the water body is oxidized and degraded by the ozone, thereby improving the degradation efficiency of the antibiotic.
[0022] Further, an ultrasonic oscillator for generating ultrasonic oscillation of the water body in the photolysis tank is fixedly connected to the bottom of the photolysis tank.
[0023] Description: The main function of ultrasonic oscillation is to intensify the decomposition of ozone through ultrasonic cavitation effect, generate a large number of free radicals, and thereby improve the degradation efficiency. The cavitation effect of ultrasonic waves can increase the active sites of the catalyst, improve the utilization rate of the photocatalyst, and also promote the diffusion of the oxidizing agent generated in the photolysis process, so that it is easier to contact and react with the antibiotic molecules.
[0024] Further, the present application also provides an antibiotic wastewater photoreaction treatment method based on the above-mentioned antibiotic wastewater photoreaction treatment device, comprising the following steps:
[0025] S1, introducing the wastewater into the wastewater coagulation device through the water inlet pipe, adding flocculating agent to the wastewater to generate flocculating precipitates, separating the flocculating precipitates from the wastewater in the sedimentation mechanism, and then continuously conveying the wastewater to the photolysis device for photolysis reaction;
[0026] S2, the wastewater enters the left collecting tank, and then enters the photolysis tank, and then passes through the xenon lamp in the photolysis plate to generate light, and then passes through the optical filter to remove stray light, so that the ultraviolet light transmits through the optical filter to irradiate the water body, and then the antibiotics in the wastewater produce photolysis reaction.
[0027] The beneficial effects of the present application are:
[0028] (1) The present application irradiates the water body with ultraviolet light to make the antibiotics in the water body produce photolysis reaction, and at the same time increases the ozone and ultrasonic oscillation, and the ultrasonic oscillation has a synergistic effect on the ozone oxidation of antibiotics and the photolysis reaction of antibiotics, which can improve the efficiency of ozone oxidation degradation of antibiotic wastewater, and also can improve the photolysis efficiency of antibiotics, so the photolysis efficiency of the present application is higher than that of the existing photolysis equipment.
[0029] (2) The present application degrades the antibiotic wastewater by the photolysis plate and the ultraviolet light generated by the sunlight, and the ultraviolet light generated by the sunlight can reduce the energy consumption required by the photolysis of the present application, and the photolysis plate is cleaned by the cleaning mechanism, which enhances the light transmittance of the photolysis plate, and at the same time, the suspended solids in the wastewater are coagulated and precipitated by the wastewater coagulation device before the water body enters the photolysis device, which enhances the light transmittance of the water body, and further improves the degradation efficiency of the photolysis device to the antibiotics. BRIEF DESCRIPTION OF DRAWINGS
[0030] Figure 1 is a structural schematic diagram of the present application.
[0031] Figure 2 is Figure 1 the enlarged view of A in figure 1.
[0032] Figure 3 is Figure 1 the enlarged view of B in figure 1.
[0033] Figure 4 is Figure 1 the enlarged view of C in figure 1.
[0034] Figure 5 is a left view of the connection relationship between the cleaning brush and the photolysis plate of the present application.
[0035] Figure 6 is a top view structural schematic diagram of the photolysis tank of the present application.
[0036] Among them, 1 - wastewater coagulation device, 2 - water inlet pipe, 3 - precipitation mechanism, 4 - photolysis device, 41 - left collecting tank, 42 - photolysis tank, 43 - support frame, 44 - photolysis plate, 441 - photolysis lamp housing, 442 - filter film I, 443 - xenon lamp, 45 - right collecting tank, 46 - drain pipe, 11 - coagulation bin, 12 - material bin, 13 - feeding motor, 14 - spiral rod, 15 - discharge pipe, 16 - blowing shell, 17 - blower, 18 - elbow pipe, 19 - rotating motor, 191 - transmission shaft, 192 - connecting frame, 193 - rotating shaft, 194 - universal joint, 195 - propeller, 31 - inclined pipe, 32 - branch pipe, 33 - precipitation pipe, 34 - control valve, 6 - cleaning mechanism, 61 - front slide rail mechanism, 62 - rear slide rail mechanism, 63 - short rod, 64 - cleaning rod, 65 - cleaning brush, 611 - sliding seat, 612 - screw rod, 613 - screw rod motor, 421 - support rod, 422 - light-transmitting cover, 423 - filter film II, 7 - ozone generator, 71 - microporous aeration pipe, 72 - air supply pipe, 8 - ultrasonic oscillator. Detailed implementation manners
[0037] Example 1:
[0038] As Figure 1 shown, an antibiotic wastewater photoreaction treatment device includes a wastewater coagulation device 1. A water inlet pipe 2 is fixedly connected to the left side of the wastewater coagulation device 1. A precipitation mechanism 3 is connected to the right side of the wastewater coagulation device 1. A photolysis device 4 is fixedly connected to the right side of the precipitation mechanism 3;
[0039] As Figure 5 shown, the photolysis device 4 includes a left collecting tank 41. The left side of the left collecting tank 41 is connected to the precipitation mechanism 3. A photolysis tank 42 is provided on the right side of the left collecting tank 41. A support frame 43 is fixedly connected to the bottom of the photolysis tank 42. A plurality of photolysis plates 44 are fixedly connected in the photolysis tank 42. A right collecting tank 45 is connected to the right side of the photolysis tank 42. A drain pipe 46 is connected to the front end of the right collecting tank 45. The photolysis plate 44 includes a photolysis lamp housing 441. A filter film I 442 is pasted on the inner wall of the photolysis lamp housing 441. A plurality of xenon lamps 443 are fixedly connected in the photolysis lamp housing 441.
[0040] As Figure 2 shown, the wastewater coagulation device 1 includes a coagulation binThe flocculant in the bin 12 is discharged by the screw rod 14 into the blowing shell 16, and is discharged by the elbow pipe 18 into the coagulation bin 11 after being blown by the blower 17, so that the flocculant can be dispersed in the water body, and the flocculant used is the polyaluminum chloride flocculant of Dinghengda Chemical Industry.
[0042] As shown in Figure 3 , the top of the coagulation bin 11 is fixedly connected with a rotating motor 19, the lower end of the output shaft of the rotating motor 19 is drivingly connected with a transmission shaft 191, the coagulation bin 11 is fixedly connected with a connecting frame 192, the middle part of the connecting frame 192 is rotatably connected with a rotating shaft 193, the left end of the rotating shaft 193 is fixedly connected with a universal joint 194, the right end of the transmission shaft 191 is fixedly connected with a propeller 195, and the transmission shaft 191 is hinged to the universal joint 194.
[0043] The rotating motor 19 drives the transmission shaft 191 to rotate, and then drives the universal joint 194 to rotate, and the universal joint 194 drives the rotating shaft 193 to rotate, and the rotating shaft 193 drives the propeller 195 to rotate, so that the water body is stirred, and the flocculant and the water body are more easily mixed, and the stirring mode can effectively reduce the resistance of the water body flow.
[0044] The precipitation mechanism 3 comprises an inclined pipe 31, the left side of the inclined pipe 31 communicates with the coagulation bin 11, the right side of the inclined pipe 31 communicates with the left side collection tank 41, and a plurality of branch pipes 32 are communicated below the inclined pipe 31, the lower end of the branch pipe 32 is threadedly connected with a precipitation pipe 33, and the middle part of the branch pipe 32 is provided with a control valve 34.
[0045] In the process of upward movement of the water body, the flocculation precipitate is deposited in the precipitation pipe 33, when cleaning is needed, only the control valve 34 is closed, the precipitation pipe 33 is removed, and the precipitate is poured out, so that the structure is convenient to use, and the normal work of the device is not affected in the process of cleaning the flocculation precipitate.
[0046] Example 2:
[0047] The difference between this embodiment and example 1 is that, as shown in Figure 6 , the upper part of the photolysis tank 42 is provided with a cleaning mechanism 6, the cleaning mechanism 6 comprises a front sliding rail mechanism 61 and a rear sliding rail mechanism 62, the lower part of the front sliding rail mechanism 61 and the rear sliding rail mechanism 62 is fixedly connected with the support frame 43 through a short rod 63, a cleaning rod 64 is slidingly connected between the front sliding rail mechanism 61 and the rear sliding rail mechanism 62, and a plurality of cleaning brushes 65 for cleaning the photolysis plate 44 are arranged below the cleaning rod 64.
[0048] Both the front slide rail mechanism 61 and the rear slide rail mechanism 62 include a sliding seat 611. The cleaning rod 64 is fixedly connected to the sliding seat 611. A lead screw 612 is rotatably connected to the outside of the sliding seat 611. A lead screw motor 613 for driving the lead screw 612 to rotate is fixedly connected to one end of the sliding seat 611. The lead screw 612 is connected to the cleaning rod 64 in a transmission connection.
[0049] Compared to Embodiment 1, in this embodiment, the front slide rail mechanism 61 and the rear slide rail mechanism 62 drive the cleaning rod 64 to move on the shopping trough 42, the cleaning brush 65 cleans the photolysis plate 44, the lead screw motor 613 drives the lead screw 612 to rotate, and the lead screw 612 drives the cleaning rod 64 to move on the sliding seat 611. The cleaning mechanism 6 improves the light transmittance of the photolysis plate 44, thereby improving the photolysis efficiency.
[0050] Example 3:
[0051] The difference between this embodiment and embodiment 2 is that, as Figure 4 As shown, in this embodiment, the top of the photolysis cell 42 is fixedly connected to a light-transmitting cover 422 by a support rod 421, and a second filter 423 is attached to the bottom of the light-transmitting cover 422.
[0052] Compared to Example 2, this embodiment allows ultraviolet light from sunlight to pass through the filter 423 on the light-transmitting cover 422 and irradiate the photolysis cell 42, thereby increasing the intensity of ultraviolet light in the photolysis cell 42 and reducing the energy consumption required for photolysis in the photolysis cell 42.
[0053] Example 4:
[0054] The difference between this embodiment and embodiment 3 is that, in this embodiment, an ozone generator 7 is fixedly connected to the bottom of the photolysis tank 42 and fixedly connected to the support frame 43, a microporous aeration pipe 71 is fixedly connected to the bottom of the photolysis tank 42, and an air supply pipe 72 connects the ozone generator 7 and the microporous aeration pipe 71.
[0055] Compared to Example 3, this embodiment generates ozone through ozone generator 7 and evenly discharges it into photolysis tank 42 through microporous aeration pipe 72. The ozone is used to oxidize and degrade antibiotics in the water, thereby improving the degradation efficiency of antibiotics.
[0056] Example 5:
[0057] The difference between this embodiment and embodiment 4 is that, in this embodiment, an ultrasonic oscillator 8 is fixedly connected to the bottom of the photolysis tank 42 to generate ultrasonic vibrations in the water inside the photolysis tank 42.
[0058] Compared with embodiment 4, the role of ultrasonic oscillation in this embodiment is mainly to strengthen the decomposition of ozone through ultrasonic cavitation effect to generate a large number of free radicals, thereby improving the degradation efficiency. The cavitation effect of ultrasonic waves can increase the active sites of the catalyst, improve the utilization rate of the photocatalyst, and also promote the diffusion of the oxidants generated during photolysis, making it easier for them to contact and react with antibiotic molecules, thereby improving the degradation efficiency of antibiotics in water.
[0059] Embodiment 6:
[0060] The embodiment provides an antibiotic wastewater photoreaction treatment method, and is based on the antibiotic wastewater photoreaction treatment equipment in embodiment 5, and comprises the following steps:
[0061] S1, the wastewater is introduced into the wastewater coagulation device 1 through the water inlet pipe 2, the flocculant is added to the wastewater to produce flocculation precipitate, the flocculation precipitate is separated from the wastewater in the sedimentation mechanism 3, and then the wastewater is continuously conveyed into the photolysis device 4 for photolysis reaction; it should be noted that in actual application, the type and addition amount of the flocculant can generally be determined according to the pollution index of the wastewater, for example, when the suspended solids concentration in the wastewater is 500 mg / L, the polyaluminum chloride of Dinghengda Chemical Industry can be used as the flocculant, and the addition amount is 10 mg / L.
[0062] S2, the wastewater enters the left collecting tank 41, and then enters the photolysis tank, and then the light generated by the xenon lamp 443 in the photolysis plate passes through the optical filter 442 to filter out stray light, so that the ultraviolet light transmits through the optical filter 442 to irradiate the water body, and then the antibiotics in the wastewater produce photolysis reaction;
[0063] S3, the cleaning rod 64 is driven by the front sliding rail mechanism 61 and the rear sliding rail mechanism 62 to move on the photolysis tank 42, the photolysis plate 44 is cleaned by the cleaning brush 65, the screw rod motor 613 drives the screw rod 612 to rotate, the screw rod 612 drives the cleaning rod 64 to move on the sliding seat 611, and the light transmittance of the photolysis plate 44 is improved by the cleaning mechanism 6; the ultraviolet light in the sunlight transmits through the optical filter two 423 on the light-transmitting cover 422, irradiates the photolysis tank 42, improves the intensity of the ultraviolet light in the photolysis tank 42, and also reduces the energy consumption required for photolysis of the photolysis tank 42;
[0064] S4, the ozone generator 7 generates ozone which is then conveyed to the microporous aeration pipe 71 through the gas supply pipe 72, the ozone is uniformly distributed in the water body through the microporous aeration pipe 71, the ozone reacts with the antibiotics to generate oxygen to improve the oxygen content of the water body, and at the same time, the ultrasonic oscillator 8 makes the water body produce ultrasonic oscillation, the cavitation effect of ultrasonic waves promotes the oxidation effect of ozone on antibiotics, and also promotes the photolysis efficiency of antibiotics in the water body. It should be noted that the ultrasonic power of the ultrasonic oscillator 8 is 100 W, and the ultrasonic frequency generated is 40 KHz.
[0065] The unloading motor 13, the blower 17, the rotating motor 19, the control valve 34, the screw motor 613, the xenon lamp 443, the ozone generator 7, and the ultrasonic oscillator 8 used in the above embodiments are all commercially available products as long as they can achieve the functions of the present application, and a person skilled in the art can select and use them according to common knowledge, which are not particularly limited herein.
Claims
1. An apparatus for the photo-reactive treatment of antibiotic wastewater, characterized by, Including wastewater coagulation device (1), the left side of wastewater coagulation device (1) is fixedly connected with water inlet pipe (2), the right side of wastewater coagulation device (1) is connected with sedimentation mechanism (3), the right side of sedimentation mechanism (3) is fixedly connected with photolysis device (4); The photolysis device (4) includes a left side collection tank (41), the left side of the left side collection tank (41) is communicated with the sedimentation mechanism (3), the right side of the left side collection tank (41) is provided with a photolysis tank (42), the bottom of the photolysis tank (42) is fixedly connected with a support frame (43), a plurality of photolysis plates (44) are fixedly connected in the photolysis tank (42), the right side of the photolysis tank (42) is communicated with a right side collection tank (45), the front end of the right side collection tank (45) is connected with a drain pipe (46), the photolysis plate (44) includes a photolysis lamp shell (441), a filter one (442) is attached to the inner wall of the photolysis lamp shell (441), a plurality of xenon lamps (443) are fixedly connected in the photolysis lamp shell (441); The wastewater coagulation device (1) includes a coagulation bin (11), the top of the coagulation bin (11) is fixedly connected with a material bin (12), the left side wall of the material bin (12) is fixedly connected with a discharging motor (13), the output shaft of the discharging motor (13) is drivingly connected with a screw rod (14), the right side of the material bin (12) is fixedly connected with a discharge pipe (15), the right side of the material bin (12) is fixedly connected with a blowing shell (16), the top of the blowing shell (16) is fixedly connected with a blower (17), the right side of the blowing shell (16) is provided with a bend pipe (18) for communicating with the inside of the coagulation bin (11); The top of the coagulation bin (11) is fixedly connected with a rotating motor (19), the lower end of the output shaft of the rotating motor (19) is drivingly connected with a transmission shaft (191), the coagulation bin (11) is fixedly connected with a connecting frame (192), the middle part of the connecting frame (192) is rotatably connected with a rotating shaft (193), the left end of the rotating shaft (193) is fixedly connected with a universal joint (194), the right end of the transmission shaft (191) is fixedly connected with a propeller (195), and the transmission shaft (191) is hinged to the universal joint (194); The sedimentation mechanism (3) includes an inclined pipe (31), the left side of the inclined pipe (31) is communicated with the coagulation bin (11), the right side of the inclined pipe (31) is communicated with the left side collection tank (41), and a plurality of branch pipes (32) are communicated below the inclined pipe (31); the lower part of the branch pipe (32) is threadedly connected with a sedimentation pipe (33), and the middle part of the branch pipe (32) is provided with a control valve (34). The photolysis tank (42) is provided with a cleaning mechanism (6) above it, the cleaning mechanism (6) comprises a front sliding rail mechanism (61) and a rear sliding rail mechanism (62), the front sliding rail mechanism (61) and the rear sliding rail mechanism (62) are fixedly connected with the support frame (43) through a short rod (63) below, and a cleaning rod (64) is slidably connected between the front sliding rail mechanism (61) and the rear sliding rail mechanism (62), a plurality of cleaning brushes (65) for cleaning the photolysis plate (44) are arranged below the cleaning rod (64). The photolysis tank (42) is fixedly connected with an ozone generator (7) fixedly connected with the support frame (43) below, the photolysis tank (42) is fixedly connected with a microporous aeration pipe (71) at the bottom, and the ozone generator (7) and the microporous aeration pipe (71) are in communication with a gas supply pipe (72).
2. An apparatus for the photo-reactive treatment of antibiotic waste water as claimed in claim 1, wherein, The front sliding rail mechanism (61) and the rear sliding rail mechanism (62) each comprise a sliding seat (611), the cleaning rod (64) is fixedly connected with the sliding seat (611), a lead screw (612) is rotatably connected to the outside of the sliding seat (611), one end of the sliding seat (611) is fixedly connected with a lead screw motor (613) for driving the lead screw (612) to rotate, and the lead screw (612) is in transmission connection with the cleaning rod (64).
3. The apparatus for the photo-reactor treatment of antibiotic wastewater according to claim 1, characterized in that, The top of the photolysis tank (42) is fixedly connected with a light-transmitting cover (422) through a support rod (421), and the bottom of the light-transmitting cover (422) is attached with a filter II (423).
4. A method for treating antibiotic wastewater by light reaction, based on the antibiotic wastewater light reaction treatment equipment according to claims 1-3, characterized in that, The method comprises the following steps: S1, introducing wastewater into the wastewater coagulation device (1) through the water inlet pipe (2), adding flocculants to the wastewater to produce flocculation precipitates, separating the flocculation precipitates from the wastewater in the sedimentation mechanism (3), and then continuously conveying the wastewater to the photolysis device (4) for photolysis reaction; S2, the wastewater enters the left collection tank (41), and then enters the photolysis tank, the light generated by the xenon lamp (443) in the photolysis plate is filtered out by the filter I (442), the ultraviolet light transmits through the filter I (442) to irradiate the water body, and then the antibiotics in the wastewater produce photolysis reaction.
Citation Information
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