Triazolophenothiazine dioxide compound, photoelectric device and display device

By designing triazole phenothiazine dioxide compounds, the existing phenothiazine dioxide stability and photoelectric properties under ultraviolet light irradiation are solved, and higher stability and photoelectric properties are achieved.

CN119735602APending Publication Date: 2025-04-01TCL TECHNOLOGY GROUP CORPORATION
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Patent Information

Application Number
CN202311291092.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-09-29
Publication Date
2025-04-01

AI Technical Summary

Technical Problem

Existing phenothiazine dioxide and its derivatives are prone to electron transitions under ultraviolet light, resulting in chemical bond rupture and free radicals and ions, affecting their stability and photoelectric properties.

Method used

A triazoleophenothiazine dioxide compound was designed, which forms a benzotriazole structure through the oxidation of sulfur atoms in phenothiazine and the introduction of triazole structures, thereby enhancing the stability of the compound and the ultraviolet absorption capacity.

Benefits of technology

It improves the stability and photoelectric properties of the compound, enhances its tolerance to ultraviolet rays, promotes hole migration, and improves the overall performance of optoelectronic devices.

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Abstract

The invention discloses a triazole phenothiazine dioxide compound, a photoelectric device and a display device, the triazole phenothiazine dioxide compound has a structure as shown in a formula (I): # imgabs0 #. The triazole phenothiazine dioxide compound disclosed by the invention takes triazole phenothiazine dioxide as a core structure, on one hand, the triazole phenothiazine dioxide has a structure as shown in the formula (I), and on the other hand, the triazole phenothiazine dioxide has a structure as shown in the formula (I); through oxidation of sulfur atoms in phenothiazine, lone pair electrons of the sulfur atoms can be effectively passivated, and the stability of the compound is improved; on the other hand, triazole is introduced into a phenothiazine structure, a formed benzotriazole structure can be used as an ultraviolet absorbent to absorb ultraviolet rays entering a compound and reduce damage of the ultraviolet rays to the compound, and on the other hand, the triazole structure can also effectively adjust the electron density on a molecular skeleton of the whole compound, so that the photoelectric conversion efficiency is improved. Therefore, the photoelectric property of the compound is improved.
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