Preparation method of environment-friendly ceramic colored stone capable of being used for coiled material wallpaper

Abstract

The invention provides a preparation method of an environment-friendly ceramic colored stone for coiled material wallpaper, which comprises the following steps: S1, mixing ceramic particles and a flax core mixture, and uniformly stirring to obtain a mixture A; s2, dropwise adding an environment-friendly emulsion and an additive into the mixture A obtained in the step S1, uniformly stirring, grinding, and screening with a screen to obtain a mixture B; s3, mixing plant essential oil with the mixture B obtained in the step S2, and uniformly stirring at the temperature of 40-60 DEG C to obtain a mixture C; s4, environment-friendly colored sand and the mixture C in the step S3 are mixed, stirred to be uniform and left to stand, and a mixture D is obtained; s5, mixing microbial enzyme catalysis liquid with the mixture D obtained in the step S4, uniformly stirring at the temperature of 20-30 DEG C, and standing to obtain a mixture E; s6, a chemical flocculant and the mixture E obtained in the step S5 are mixed, centrifugal separation is conducted under the condition that the rotating speed ranges from 3000 rpm to 4000 rpm, curing is conducted, and the environment-friendly ceramic colored stone is obtained. In the preparation process, the flax core mixture, the environment-friendly emulsion, the environment-friendly colored sand and the environment-friendly plant essential oil are used as raw materials, are non-toxic and harmless and meet the environment-friendly requirement. The environment-friendly raw material is used for preparing the ceramic colored stone, the environment-friendly performance of a product can be remarkably improved, and harm to a human body and the environment is reduced. The microbial enzyme catalysis liquid is added in the preparation process to decompose toxic volatile organic compounds in the mixed liquid in the preparation process, the toxic volatile organic compounds are decomposed into harmless or low-toxicity small molecular substances through enzymolysis, and the environmental protection performance of the product is improved.

Description

Technical Field

[0001] The invention relates to the technical field of ceramic colored stone processing, and in particular to a method for preparing environmentally friendly ceramic colored stone that can be used for coiled wallpaper. Background Art

[0002] Roll wallpaper is a material widely used in interior decoration. Roll wallpaper is usually made of different types of plastics, rubber, fiber and other materials. The manufacturing process is to shape the raw materials through hot pressing or extrusion, and then roll them up.

[0003] With the development of the interior decoration field, some roll wallpapers are combined with super-flexible ceramic colored stones. This kind of wallpaper has excellent flexibility and can adapt to various wall curves and irregular shapes, making the decoration more natural. The surface presents the unique texture and color of ceramic colored stones, adding a natural and simple beauty to the interior space.

[0004] At present, most of the ceramic colored stone products on the market use raw materials that may contain harmful substances or volatile organic compounds in the production process, which causes some traditional roll wallpapers to seriously affect the surrounding air environment after laying. Therefore, there is an urgent need for a preparation method of environmentally friendly ceramic colored stone that can be used for roll wallpaper. Summary of the invention

[0005] In view of the above-mentioned deficiencies in the prior art, the present invention provides a method for preparing an environmentally friendly ceramic colored stone that can be used for roll wallpaper.

[0006] The object of the present invention is to provide a method for preparing an environmentally friendly ceramic colored stone that can be used for coiled wallpaper, comprising the following steps:

[0007] S1. Mix the ceramic particles and the flax core mixture and stir evenly to obtain a mixture A;

[0008] S2. Add the environmentally friendly emulsion and additives to the mixture A in step S1, stir evenly, grind, and sieve through a sieve to obtain a mixture B;

[0009] S3. The plant essential oil and the mixture B in step S2 are mixed and stirred at a temperature of 40-60 ° C to obtain a mixture C;

[0010] S4. The environmentally friendly colored sand, the mixture C in step S3, mixed, stirred, and allowed to stand to obtain a mixture D;

[0011] S5. The microbial enzyme catalytic liquid and the mixture D in step S4 are mixed, stirred evenly at a temperature of 20-30 ° C, and allowed to stand to obtain a mixture E;

[0012] S6. Mix the chemical flocculant and the mixture E in step S5, centrifuge at a rotation speed of 3000-4000 rpm, and solidify to obtain an environmentally friendly ceramic colored stone.

[0013] The invention adopts flax core mixed material, environmentally friendly emulsion, environmentally friendly colored sand and environmentally friendly plant essential oil as raw materials in the preparation process, which are non-toxic and harmless and meet environmental protection requirements. The environmentally friendly raw materials are used in the preparation of pottery colored stone, which can significantly improve the environmental performance of the product and reduce the harm to human body and environment.

[0014] The present invention adds a microbial enzyme catalytic liquid during the preparation process to decompose toxic volatile organic compounds in the mixed liquid during the preparation process, decomposes them into harmless or low-toxic small molecular substances through enzymatic hydrolysis, and improves the environmental protection performance of the product.

[0015] The invention adds a chemical flocculant during the preparation process, so that the microbial enzyme cells are aggregated into larger particles, and the agglomeration of the particles is prevented by changing the potential on the surface of the particles, thereby optimizing the structure of the pottery colored stone.

[0016] Preferably, the mass ratio of the mixture A, the environmentally friendly emulsion and the additive in step S1 is (8-10):1:(0.08-0.10).

[0017] Preferably, the flax core mixture in step S1 is prepared from flax core and sodium hydroxide solution, and the mass ratio of the flax core to the sodium hydroxide solution is (8-10):1.

[0018] Preferably, in parts by weight, the additive in step S2 is prepared from 4-6 parts of a thickener, 3-5 parts of a dispersant, and 3-5 parts of a defoaming agent.

[0019] Preferably, the amount of the plant essential oil in step S3 is 50-60 parts by weight.

[0020] Preferably, in terms of mass fraction, the mass fraction of the environmentally friendly colored sand in step S4 is 65-75%, and the environmentally friendly colored sand is prepared from 10-30% of 20-30 mesh environmentally friendly colored sand and 70-90% of 40-60 mesh environmentally friendly colored sand.

[0021] Preferably, the mass ratio of the microbial enzyme catalytic liquid to the mixture D in step S5 is (0.4-0.6):1.

[0022] Preferably, the sieve in step S2 has a mesh size of 200-300.

[0023] Preferably, the standing time in step S4 is 24-36 hours.

[0024] Preferably, the standing time in step S5 is 24-36 hours. DETAILED DESCRIPTION

[0025] The following is a further clear and complete description of the technical features in the technical solution provided by the present invention in conjunction with the specific implementation methods. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative work are within the scope of protection of the present invention.

[0026] Example 1

[0027] This embodiment provides a method for preparing an environmentally friendly ceramic colored stone that can be used for coiled wallpaper, comprising the following steps:

[0028] S1. Mix the ceramic particles and the flax core mixture and stir evenly to obtain a mixture A;

[0029] S2. Add the environmentally friendly emulsion and additives to the mixture A in step S1, stir evenly, grind, and sieve through a sieve to obtain a mixture B;

[0030] S3. The plant essential oil and the mixture B in step S2 are mixed and stirred at a temperature of 40 ° C to obtain a mixture C;

[0031] S4. The environmentally friendly colored sand, the mixture C in step S3, mixed, stirred, and allowed to stand to obtain a mixture D;

[0032] S5. The microbial enzyme catalytic liquid and the mixture D in step S4 are mixed, stirred evenly at a temperature of 20°C, and allowed to stand to obtain a mixture E;

[0033] S6. Mix the chemical flocculant and the mixture E described in step S5, centrifuge at a rotation speed of 3000 rpm, and solidify to obtain an environmentally friendly ceramic colored stone.

[0034] Wherein, the mass ratio of the mixture A, the environmentally friendly emulsion and the additive in step S1 is 8:1:0.08.

[0035] Wherein, the flax core mixture in step S1 is prepared from flax core and sodium hydroxide solution, and the mass ratio of the flax core to the sodium hydroxide solution is 8:1.

[0036] Wherein, in terms of weight, the additive in step S2 is prepared from 4 parts of thickener, 3 parts of dispersant and 3 parts of defoamer.

[0037] Wherein, in terms of parts by weight, the amount of the plant essential oil used in step S3 is 50 parts.

[0038] Wherein, in terms of mass fraction, the mass fraction of the environmentally friendly colored sand in step S4 is 65%, and the environmentally friendly colored sand is prepared from 10% of 20-mesh environmentally friendly colored sand and 90% of 40-mesh environmentally friendly colored sand.

[0039] Wherein, the mass ratio of the microbial enzyme catalytic liquid to the mixture D in step S5 is 0.4:1.

[0040] Wherein, the sieve in step S2 is 200 mesh.

[0041] Wherein, the standing time in step S4 is 24 hours.

[0042] Wherein, the standing time in step S5 is 24 hours.

[0043] Example 2

[0044] This embodiment provides a method for preparing an environmentally friendly ceramic colored stone that can be used for coiled wallpaper, comprising the following steps:

[0045] S1. Mix the ceramic particles and the flax core mixture and stir evenly to obtain a mixture A;

[0046] S2. Add the environmentally friendly emulsion and additives to the mixture A in step S1, stir evenly, grind, and sieve through a sieve to obtain a mixture B;

[0047] S3. The plant essential oil and the mixture B in step S2 are mixed and stirred at a temperature of 50 ° C to obtain a mixture C;

[0048] S4. The environmentally friendly colored sand, the mixture C in step S3, mixed, stirred, and allowed to stand to obtain a mixture D;

[0049] S5. The microbial enzyme catalytic liquid and the mixture D in step S4 are mixed, stirred evenly at a temperature of 25 ° C, and allowed to stand to obtain a mixture E;

[0050] S6. Mix the chemical flocculant and the mixture E in step S5, centrifuge at a rotation speed of 3500 rpm, and solidify to obtain an environmentally friendly ceramic colored stone.

[0051] Wherein, the mass ratio of the mixture A, the environmentally friendly emulsion and the additive in step S1 is 9:1:0.09.

[0052] Wherein, the flax core mixture in step S1 is prepared from flax core and sodium hydroxide solution, and the mass ratio of the flax core to the sodium hydroxide solution is 9:1.

[0053] Wherein, in terms of weight, the additive in step S2 is prepared from 5 parts of thickener, 4 parts of dispersant and 4 parts of defoamer.

[0054] Wherein, in terms of parts by weight, the amount of the plant essential oil used in step S3 is 55 parts.

[0055] Wherein, in terms of mass fraction, the mass fraction of the environmentally friendly colored sand in step S4 is 70%, and the colored sand is prepared from 20% of 25-mesh environmentally friendly colored sand and 80% of 50-mesh environmentally friendly colored sand.

[0056] Wherein, the mass ratio of the microbial enzyme catalytic liquid to the mixture D in step S5 is 0.5:1.

[0057] Wherein, the sieve in step S2 is 250 mesh.

[0058] Wherein, the standing time in step S4 is 30 hours.

[0059] Wherein, the standing time in step S5 is 30 hours.

[0060] Example 3

[0061] This embodiment provides a method for preparing an environmentally friendly ceramic colored stone that can be used for coiled wallpaper, comprising the following steps:

[0062] S1. Mix the ceramic particles and the flax core mixture and stir evenly to obtain a mixture A;

[0063] S2. Add the environmentally friendly emulsion and additives to the mixture A in step S1, stir evenly, grind, and sieve through a sieve to obtain a mixture B;

[0064] S3. The plant essential oil and the mixture B in step S2 are mixed and stirred at a temperature of 60 ° C to obtain a mixture C;

[0065] S4. The environmentally friendly colored sand, the mixture C in step S3, mixed, stirred, and allowed to stand to obtain a mixture D;

[0066] S5. The microbial enzyme catalytic liquid and the mixture D in step S4 are mixed, stirred evenly at a temperature of 30°C, and allowed to stand to obtain a mixture E;

[0067] S6. Mix the chemical flocculant and the mixture E in step S5, centrifuge at a rotation speed of 4000 rpm, and solidify to obtain an environmentally friendly ceramic colored stone.

[0068] Wherein, the mass ratio of the mixture A, the environmentally friendly emulsion and the additive in step S1 is 10:1:0.1.

[0069] Wherein, the flax core mixture in step S1 is prepared from flax core and sodium hydroxide solution, and the mass ratio of the flax core to the sodium hydroxide solution is 10:1.

[0070] Wherein, in terms of weight, the additive in step S2 is prepared from 6 parts of thickener, 5 parts of dispersant and 5 parts of defoamer.

[0071] Wherein, in terms of parts by weight, the amount of plant essential oil used in step S3 is 60 parts.

[0072] Wherein, in terms of mass fraction, the mass fraction of the environmentally friendly colored sand in step S4 is 75%, and the environmentally friendly colored sand is prepared from 30% of 30-mesh environmentally friendly colored sand and 70% of 60-mesh environmentally friendly colored sand.

[0073] Wherein, the mass ratio of the microbial enzyme catalytic liquid to the mixture D in step S5 is 0.6:1.

[0074] Wherein, the sieve in step S2 is 300 mesh.

[0075] Wherein, the standing time in step S4 is 36 hours.

[0076] Wherein, the standing time in step S5 is 36 hours.

[0077] Test Case

[0078] 1. Test subjects

[0079] The environmentally friendly pottery colored stones prepared in Examples 1-3 are the common pottery colored stones on the market.

[0080] 2. Test content

[0081] (1) Formaldehyde concentration

[0082] According to the national standard QB T27612006 "Measurement Method for Purification Effect of Indoor Air Purification Products", an experimental device was built to conduct experimental tests. After 24 hours, the formaldehyde concentration (mg / m 3 The initial concentration of formaldehyde in each sample chamber is 0.001 mg / m 3 .

[0083] 3. Test results

[0084] Table 1 Test results of relevant properties of environmentally friendly ceramic colored stone

[0085]

[0086] For the environmentally friendly pottery colored stones prepared in Examples 1-3, the formaldehyde concentration increased over time (from 24 hours to 72 hours), but the increase was very small and remained at an extremely low level (far below the safety limit specified by the national standard). The formaldehyde concentration of common pottery colored stones on the market also tended to increase over time, but the increase was significantly greater than that of Examples 1-3, and the concentration value was significantly higher than that of the example products.

[0087] In summary, the environmentally friendly ceramic colored stones prepared in Examples 1-3 performed well in controlling formaldehyde concentration, which was much lower than the common ceramic colored stones on the market. This was due to the environmentally friendly raw materials (such as flax core mixture, environmentally friendly emulsion, etc.) and scientific preparation processes (such as the addition of microbial enzyme catalytic liquid, centrifugal separation of chemical flocculants, etc.) used in the preparation process. With the combined effect of these measures, the products of the examples achieved lower formaldehyde emissions and higher environmental performance while maintaining excellent performance.

[0088] The above embodiments are only used to illustrate the technical solutions of the present invention rather than to limit the protection scope of the present invention. Although the present invention is described in detail with reference to the above embodiments, ordinary technicians in the relevant field should understand that the technical solutions of the present invention can be modified or equivalently replaced, but these modifications or replacements are all within the protection scope of the present invention.

Claims

1. A method for preparing an environmentally friendly ceramic colored stone that can be used for coiled wallpaper, characterized in that: The following steps are involved: S1. Mix the ceramic particles and the flax core mixture and stir evenly to obtain a mixture A; S2. Add the environmentally friendly emulsion and additives to the mixture A in step S1, stir evenly, grind, and sieve through a sieve to obtain a mixture B; S3. The plant essential oil and the mixture B in step S2 are mixed and stirred at a temperature of 40-60 ° C to obtain a mixture C; S4. The environmentally friendly colored sand, the mixture C in step S3, mixed, stirred, and allowed to stand to obtain a mixture D; S5. The microbial enzyme catalytic liquid and the mixture D in step S4 are mixed, stirred evenly at a temperature of 20-30 ° C, and allowed to stand to obtain a mixture E; S6. Mix the chemical flocculant and the mixture E in step S5, centrifuge at a rotation speed of 3000-4000 rpm, and solidify to obtain an environmentally friendly ceramic colored stone.

2. The preparation method according to claim 1, characterized in that The mass ratio of the mixture A, the environmentally friendly emulsion and the additive in step S1 is (8-10):1:(0.08-0.10).

3. The preparation method according to claim 1, characterized in that: Step S1: The flax core mixture is prepared from flax core and sodium hydroxide solution, and the mass ratio of the flax core to the sodium hydroxide solution is (8-10):

1.

4. The preparation method according to claim 1, characterized in that: In parts by weight, the additive in step S2 is prepared from 4-6 parts of a thickener, 3-5 parts of a dispersant, and 3-5 parts of a defoamer.

5. The preparation method according to claim 1, characterized in that: In parts by weight, the amount of the plant essential oil used in step S3 is 50-60 parts.

6. The preparation method according to claim 1, characterized in that: In terms of mass fraction, the mass fraction of the environmentally friendly colored sand in step S4 is 65-75%, and the environmentally friendly colored sand is prepared from 10-30% of 20-30 mesh environmentally friendly colored sand and 70-90% of 40-60 mesh environmentally friendly colored sand.

7. The preparation method according to claim 1, characterized in that: In step S5, the mass ratio of the microbial enzyme catalytic liquid to the mixture D is (0.4-0.6):

1.

8. The preparation method according to claim 1, characterized in that: The sieve in step S2 is 200-300 mesh.

9. The preparation method according to claim 1, characterized in that: The standing time in step S4 is 24-36 hours.

10. The preparation method according to claim 1, characterized in that: The standing time in step S5 is 24-36 hours.

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