Low-temperature-resistant environment-friendly ribbon spray and preparation method thereof

Abstract

The present application relates to the technical field of ribbon spray, and particularly relates to an environment-friendly ribbon spray resistant to low temperature and a preparation method thereof. The environment-friendly ribbon spray resistant to low temperature comprises 20-30 parts of deionized water, 0.2-0.4 parts of preservative, 0-0.3 parts of water-soluble pigment, 0.1-0.2 parts of coconut oil diethanolamide, 0.1-0.2 parts of perfluorooctyl quaternary amine iodide, 0.1-0.2 parts of rhamnolipid, 0.1-0.2 parts of sodium vinyl sulfonate, 4-6 parts of ethanol, 15-25 parts of filling powder, 5-8 parts of acrylic resin, 5-7 parts of ethylene glycol monobutyl ether and 20-30 parts of propellant. The ribbon spray successfully solves the problem of unstable spraying of the existing ribbon spray under low temperature conditions, and still maintains excellent spraying effect in cold environment.

Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of ribbon spray, in particular to a low-temperature-resistant environment-friendly ribbon spray and a preparation method thereof. BACKGROUND

[0002] As a convenient and fun decorative play prop, the ribbon spray plays an indispensable role in various celebrations in today's society, from weddings, birthday parties to holiday celebrations. The ribbon spray has become one of the key props for creating a happy atmosphere.

[0003] With the continuous strengthening of people's environmental awareness, water-based ribbon sprays have gradually replaced traditional oil-based ribbon sprays and become the market mainstream. In order to achieve good spraying effect, most existing water-based ribbon sprays contain a certain proportion of resin compounds as film formers. However, the solubility of resin compounds in water is inherently low, and in low-temperature environments, especially when the temperature drops below freezing point, the compatibility of resin compounds will be severely affected. Specifically, as the temperature drops, the solubility between resin compounds and water decreases, which is prone to precipitation, and even causes the solution to separate or form precipitates. This not only destroys the original uniform dispersion state, but also affects the consistency and continuity of the spray during the spraying process, thereby causing the spray to be not smooth or even clogging the nozzle. This phenomenon greatly limits the application range of the ribbon spray. Once the environmental temperature drops to a low level, especially close to freezing point or lower, or needs to be stored in a cold environment for a long period of time, the existing ribbon spray is difficult to play a stable spraying effect. Therefore, it is necessary to develop a water-based ribbon spray that can maintain stability in low-temperature environments to solve the problem that the existing ribbon spray is difficult to play a stable spraying effect in low-temperature conditions. SUMMARY

[0004] In order to solve the problem that the existing ribbon spray is difficult to play a stable spraying effect in low-temperature conditions, the present application provides a low-temperature-resistant environment-friendly ribbon spray and a preparation method thereof. The ribbon spray of the present application successfully solves the problem of unstable spraying of the existing ribbon spray in low-temperature conditions, provides a wider space for the application of the ribbon spray, and especially in cold environments, the ribbon spray of the present application can still maintain excellent spraying effect and decoration performance, bringing users a more pleasant use experience.

[0005] In the first aspect, the low-temperature-resistant environment-friendly ribbon spray provided by the present application adopts the following technical scheme:

[0006] The low-temperature-resistant environment-friendly color ribbon spray agent comprises the following raw materials in mass fraction: 20-30 parts of deionized water, 0.2-0.4 parts of preservative, 0-0.3 parts of water-soluble pigment, 0.1-0.2 parts of coconut oil diethanolamide, 0.1-0.2 parts of perfluorooctyl quaternary ammonium iodide, 0.1-0.2 parts of rhamnolipid, 0.1-0.2 parts of sodium vinyl sulfonate, 4-6 parts of ethanol, 15-25 parts of filling powder, 5-8 parts of acrylic resin, 5-7 parts of ethylene glycol monobutyl ether and 20-30 parts of propellant.

[0007] In the technical solution, the deionized water is used as the solvent to ensure the environmental protection of the spray agent; the preservative is added to prevent the corrosion of the color ribbon spray agent liquid to the tank body, effectively prolong the shelf life of the color ribbon spray agent, the addition of the water-soluble pigment gives the color ribbon spray agent rich and varied colors and improves the color uniformity of the color ribbon, the combination of the coconut oil diethanolamide, the perfluorooctyl quaternary ammonium iodide, the rhamnolipid and the sodium vinyl sulfonate improves the liquid dispersibility and low-temperature stability of the color ribbon spray agent, ensures the uniformity and continuity of the color ribbon spray agent in the spraying process, especially under low-temperature conditions, the synergistic effect of the coconut oil diethanolamide, the perfluorooctyl quaternary ammonium iodide, the rhamnolipid and the sodium vinyl sulfonate improves the compatibility of the acrylic resin and water, so that the color ribbon spray agent can still be smoothly sprayed into noodles-shaped color ribbon with uniform color and consistent thickness under low-temperature conditions, and the color ribbon spray agent can have a better spraying distance, the ethanol as a cosolvent added to the color ribbon spray agent further improves the compatibility of the resin and water, and the synergistic effect of the filling powder, the acrylic resin and the ethylene glycol monobutyl ether ensures that the color ribbon can be quickly formed into noodles-shaped color ribbon after the liquid is sprayed out.

[0008] Preferably, the preservative is a combination of sodium benzoate and sodium nitrite, and the low-temperature-resistant environment-friendly color ribbon spray agent comprises 0.1-0.2 parts of sodium benzoate and 0.1-0.2 parts of sodium nitrite in mass fraction.

[0009] In the technical solution, the combination of sodium benzoate and sodium nitrite is selected as the preservative, which can not only reduce the corrosion of the color ribbon spray agent liquid to the tank body, but also maintain good corrosion resistance under low-temperature conditions without causing harm to the human body and the environment, meeting the environmental protection requirements.

[0010] Preferably, the propellant is 1,1,1,2-tetrafluoroethane.

[0011] In the technical scheme, the 1,1,1,2-tetrafluoroethane is an environmentally friendly propellant, has good flame retardancy and does not damage the environment and human body, and the use of the 1,1,1,2-tetrafluoroethane and water further improves the flame retardancy and safety of the color belt spray agent.

[0012] Preferably, the filling powder is fluorophlogopite powder and talc powder, and the fluorophlogopite powder and the talc powder account for 5-10 parts and 10-15 parts by mass fraction of the low-temperature-resistant environmentally friendly color belt spray agent.

[0013] In the technical scheme, the fluorophlogopite powder and the talc powder are used as the filling powder, and the synergistic effect of the fluorophlogopite powder and the talc powder improves the film-forming property and gloss of the color belt spray agent, so that the sprayed color belt is more full and has high gloss, and the decoration effect and aesthetic degree of the color belt spray agent are further improved.

[0014] Preferably, the particle size of the fluorophlogopite powder is 5-20 μm, and the particle size of the talc powder is 10-30 μm.

[0015] In the technical scheme, the particle size range of the filling powder is controlled, and the spraying effect and forming property of the color belt spray agent are further optimized, so that the sprayed color belt is more delicate, uniform and continuous, and the use experience and decoration effect of the color belt spray agent are further improved.

[0016] Preferably, the mass ratio of the coconut oil diethanolamide, the perfluorooctyl quaternary amine iodide, the rhamnolipid and the sodium vinyl sulfonate is 0.15:0.15:0.15:0.15.

[0017] In the technical scheme, the mass ratio of the coconut oil diethanolamide, the perfluorooctyl quaternary amine iodide, the rhamnolipid and the sodium vinyl sulfonate is further optimized, so that the coconut oil diethanolamide, the perfluorooctyl quaternary amine iodide, the rhamnolipid and the sodium vinyl sulfonate can exert the best synergistic effect in the color belt spray agent, the spraying stability and continuity of the color belt spray agent under low-temperature conditions are further improved, and the color belt sprayed out of the color belt spray agent has better gloss and delicacy, and the decoration effect and aesthetic degree of the color belt spray agent are further improved.

[0018] In a second aspect, a preparation method of the low-temperature-resistant environmentally friendly color belt spray agent adopts the following technical scheme:

[0019] The preparation method of the low-temperature-resistant environmentally friendly color belt spray agent includes the following steps:

[0020] Step 1: add deionized water into a stirring kettle, start stirring, and add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle under stirring until mixed evenly; Step 2: add ethanol, talc, acrylic resin, and ethylene glycol monobutyl ether into the stirring kettle and stir until mixed evenly;

[0021] Step 3: fill the material obtained in Step 2 into an aerosol can, fill 1,1,1,2-tetrafluoroethane, and obtain an aerosol.

[0022] In the above technical solution, by using specific preparation steps, the raw materials can be fully mixed and uniform, ensuring the quality stability and spraying effect of the color belt aerosol.

[0023] Preferably, in Step 2, the ethanol, talc, acrylic resin, and ethylene glycol monobutyl ether are pre-mixed and dissolved uniformly.

[0024] In the above technical solution, the present application can further improve the compatibility and dispersibility between these raw materials by selecting to pre-mix and dissolve the ethanol, talc, acrylic resin, and ethylene glycol monobutyl ether uniformly first, and then adding them into the stirring kettle, ensuring that the raw materials can be fully mixed during preparation, thereby improving the quality stability and spraying effect of the color belt aerosol.

[0025] In summary, the present application has at least one of the following beneficial technical effects:

[0026] 1. The coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate in the present application work synergistically to improve the liquid dispersion and low-temperature stability of the color belt aerosol, so that the color belt aerosol can still be smoothly sprayed into a noodle-shaped color belt with uniform color, consistent thickness, and continuity under low-temperature conditions, while ensuring that the color belt aerosol has a good spraying distance.

[0027] 2. The present application selects fluorophlogopite powder and talc as the filler powder, further improving the film-forming property and gloss of the color belt aerosol, making the sprayed color belt more full and glossy, and further improving the decoration effect and aesthetic degree of the color belt aerosol. DETAILED DESCRIPTION

[0028] To better illustrate the purpose, technical solution, and advantages of the present application, the present application will be further described below with reference to specific embodiments.

[0029] Example 1

[0030] A low-temperature-resistant environment-friendly color ribbon spray agent, comprising 28 g of deionized water, 0.15 g of sodium benzoate, 0.15 g of sodium nitrite, 0.3 g of water-soluble pigment, 0.15 g of coconut oil diethanolamide, 0.15 g of perfluorooctyl quaternary amine iodide, 0.15 g of rhamnolipid, 0.15 g of sodium vinyl sulfonate, 5 g of ethanol, 8 g of fluorophlogopite powder, 13 g of talc powder, 7 g of acrylic resin, 6 g of ethylene glycol monobutyl ether and 25.8 g of 1,1,1,2-tetrafluoroethane.

[0031] The coconut oil diethanolamide is purchased from Shandong Suihua Biological Technology Co., Ltd., and the model is CDEA.

[0032] The perfluorooctyl quaternary amine iodide is purchased from Taian Jiangzhou Biological Technology Co., Ltd.

[0033] The rhamnolipid is purchased from Anhui Zhonghong Biological Engineering Co., Ltd.

[0034] The sodium vinyl sulfonate is purchased from Shandong Wanhuaxing Environmental Protection New Material Co., Ltd.

[0035] The fluorophlogopite powder is purchased from Lingshou County Malin Mineral Product Processing Factory, and the particle size is 5 μm-20 μm.

[0036] The talc powder is purchased from Lingshou County Haibin Mineral Product Trade Co., Ltd., and the particle size is 10 μm-30 μm.

[0037] The acrylic resin is purchased from Shandong Huling New Material Co., Ltd., and the model is PT-2095.

[0038] The ethylene glycol monobutyl ether is purchased from Shandong Xuxiang Chemical Co., Ltd.

[0039] The preparation method of the low-temperature-resistant environment-friendly color ribbon spray agent comprises the following steps:

[0040] Step 1: deionized water is added to a stirring kettle, stirring is started, and preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary amine iodide, rhamnolipid and sodium vinyl sulfonate are added to the stirring kettle under stirring until they are uniformly mixed.

[0041] Step 2: ethanol, talc powder, acrylic resin and ethylene glycol monobutyl ether are uniformly mixed and dissolved in advance, and then added to the stirring kettle, mixed with the material obtained in step 1 and stirred uniformly.

[0042] Step 3: the material obtained in step 2 is filled into an aerosol can, 1,1,1,2-tetrafluoroethane is filled, and an aerosol is obtained.

[0043] Example 2

[0044] A low-temperature-resistant environment-friendly color ribbon spray agent, different from Example 1, comprises 25 g of deionized water, 0.2 g of sodium benzoate, 0.1 g of sodium nitrite, 0.3 g of water-soluble pigment, 0.1 g of coconut oil diethanolamide, 0.2 g of perfluorooctyl quaternary ammonium iodide, 0.1 g of rhamnolipid, 0.2 g of sodium vinyl sulfonate, 6 g of ethanol, 5 g of fluorophlogopite powder, 15 g of talc powder, 5 g of acrylic resin, 7 g of ethylene glycol monobutyl ether, and 27.8 g of 1,1,1,2-tetrafluoroethane.

[0045] The preparation method of the low-temperature-resistant environment-friendly color ribbon spray agent comprises the following steps:

[0046] Step 1: Add deionized water into a stirring kettle, and start stirring. Under the stirring condition, add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle, and stir until they are uniformly mixed.

[0047] Step 2: Pre-mix, dissolve and uniformly mix ethanol, talc powder, acrylic resin and ethylene glycol monobutyl ether, and then add them into the stirring kettle to mix with the material obtained in Step 1 and stir until they are uniformly mixed.

[0048] Step 3: Fill the material obtained in Step 2 into an aerosol can, fill 1,1,1,2-tetrafluoroethane, and obtain an aerosol.

[0049] Example 3

[0050] A low-temperature-resistant environment-friendly color ribbon spray agent, different from Example 1, comprises 30 g of deionized water, 0.1 g of sodium benzoate, 0.2 g of sodium nitrite, 0.3 g of water-soluble pigment, 0.2 g of coconut oil diethanolamide, 0.1 g of perfluorooctyl quaternary ammonium iodide, 0.2 g of rhamnolipid, 0.1 g of sodium vinyl sulfonate, 4 g of ethanol, 10 g of fluorophlogopite powder, 10 g of talc powder, 8 g of acrylic resin, 5 g of ethylene glycol monobutyl ether, and 26.8 g of 1,1,1,2-tetrafluoroethane.

[0051] The preparation method of the low-temperature-resistant environment-friendly color ribbon spray agent comprises the following steps:

[0052] Step 1: Add deionized water into a stirring kettle, and start stirring. Under the stirring condition, add preservatives, water-soluble pigments, coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid, and sodium vinyl sulfonate into the stirring kettle, and stir until they are uniformly mixed.

[0053] Step 2: Pre-mix, dissolve and uniformly mix ethanol, talc powder, acrylic resin and ethylene glycol monobutyl ether, and then add them into the stirring kettle to mix with the material obtained in Step 1 and stir until they are uniformly mixed.

[0054] Step 3: The material obtained in Step 2 was filled into an aerosol can, and 1,1,1,2-tetrafluoroethane was filled to obtain an aerosol.

[0055] Comparative Example 1

[0056] An environmentally friendly ribbon spray, which is different from Example 1, is that the perfluorooctyl quaternary amine iodide, rhamnolipid, and sodium vinyl sulfonate are replaced with coconut oil diethanolamide in equal amounts.

[0057] Comparative Example 2

[0058] An environmentally friendly ribbon spray, which is different from Example 1, is that the perfluorooctyl quaternary amine iodide is replaced with coconut oil diethanolamide in equal amounts.

[0059] Comparative Example 3

[0060] An environmentally friendly ribbon spray, which is different from Example 1, is that the rhamnolipid is replaced with coconut oil diethanolamide in equal amounts.

[0061] Comparative Example 4

[0062] An environmentally friendly ribbon spray, which is different from Example 1, is that the sodium vinyl sulfonate is replaced with coconut oil diethanolamide in equal amounts.

[0063] Performance Test

[0064] Test 1

[0065] Test Sample: The environmentally friendly ribbon sprays of the above examples and comparative examples.

[0066] Test Method: Under the conditions of a room temperature of 25°C, a relative humidity of 65%, and no wind, the prepared environmentally friendly ribbon spray was left to stand at a vertical distance of 1 m from the ground for 8 h, and then the ribbon was sprayed horizontally. After the ribbon naturally fell, the far end from the spraying point was taken as the measurement point, the horizontal spraying distance (m) of the ribbon was measured and recorded, and the state of the sprayed ribbon was observed and recorded. Each group was tested in parallel for 10 times.

[0067] Similarly, the room temperature was adjusted to 10°C and 5°C, respectively, and the prepared environmentally friendly ribbon spray was left to stand at the test temperature for 8 h, and then the above test was repeated and the test results were recorded.

[0068] The above test results are shown in Table 1.

[0069] Table 1:

[0070]

[0071]

[0072] Specifically combining the test results of Examples 1-3, Comparative Examples 1-4 and Table 1, it can be seen that the color band sprays of Examples 1-3 exhibit a smooth spraying state, uniform color and consistent color band morphology at 25℃, 10℃ and 5℃, and the spraying distance is also farther. Therefore, the environmentally friendly color band spray of the present application still has good spraying performance and color band morphology under low temperature conditions, which also proves that the environmentally friendly color band spray of the present application has good solubility and dispersibility under low temperature conditions, and thus can maintain good spraying performance and color band morphology.

[0073] Specifically combining Example 1 and Comparative Examples 1-4, the difference between Comparative Examples 1-4 and Example 1 is that in Comparative Examples 1-4, perfluorooctyl quaternary amine iodide, rhamnolipid, and sodium vinyl sulfonate are replaced by coconut oil diethanolamide in equal or partial equal amounts.

[0074] 1-4, perfluorooctyl quaternary amine iodide, rhamnolipid, and sodium vinyl sulfonate are replaced by coconut oil diethanolamide in equal or partial equal amounts, and further combining the test result analysis of Table 1, Example 1 has good spraying performance and color band morphology under low temperature conditions. Through the above comparison, it can be seen that the synergistic effect of perfluorooctyl quaternary amine iodide, rhamnolipid, and sodium vinyl sulfonate has a significant effect on improving the spraying performance and color band morphology of the color band spray under low temperature conditions.

[0075] Test 2

[0076] According to the test of 4.2 spray combustion in GB / T14449-1993 "Test Methods for Aerosol Products", the combustion of the color band spray was detected, and the test results are shown in Table 2.

[0077] Table 2:

[0078]

[0079] Specifically combining the test results of Examples 1-3, Comparative Examples 1-4 and Table 2, it can be seen that the color band sprays of Examples 1-3 and Comparative Examples 1-4 can all extinguish the candle flame when the spraying distance is 150mm, which indicates that the low-temperature resistant environmentally friendly color band spray of the present application has good spray combustion, meeting the requirements for safe use.

[0080] The present specific embodiment is merely an explanation of the present application, and is not a limitation of the present application. Those skilled in the art can make modifications to the present embodiment without creative contribution after reading the present specification, but as long as the modifications are within the scope of the claims of the present application, they are protected by the patent law.

Claims

1. A low-temperature resistant environmentally friendly ribbon spray, characterized in that: The invention comprises the following raw materials in parts by mass: 20-30 parts of deionized water, 0.2-0.4 parts of preservatives, 0-0.3 parts of water-soluble pigments, 0.1-0.2 parts of coconut oil diethanolamide, 0.1-0.2 parts of perfluorooctyl quaternary ammonium iodide, 0.1-0.2 parts of rhamnolipid, 0.1-0.2 parts of sodium vinyl sulfonate, 4-6 parts of ethanol, 15-25 parts of filling powder, 5-8 parts of acrylic resin, 5-7 parts of ethylene glycol monobutyl ether and 20-30 parts of propellant.

2. The low-temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The preservative is a combination of sodium benzoate and sodium nitrite, and based on the mass parts of the low-temperature resistant environmentally friendly ribbon spray, the preservative comprises 0.1 to 0.2 parts of sodium benzoate and 0.1 to 0.2 parts of sodium nitrite.

3. The low-temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The propellant is 1,1,1,2-tetrafluoroethane.

4. The low-temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The filling powder is fluorphlogopite powder and talc powder, and the filling powder comprises 5 to 10 parts of fluorphlogopite powder and 10 to 15 parts of talc powder based on the mass parts of the low-temperature resistant environmentally friendly ribbon spray.

5. The low-temperature resistant environmentally friendly ribbon spray according to claim 4, characterized in that: The particle size of the fluorphlogopite powder is 5 μm to 20 μm, and the particle size of the talc powder is 10 μm to 30 μm.

6. The low-temperature resistant environmentally friendly ribbon spray according to claim 1, characterized in that: The mass ratio of the coconut oil diethanolamide, perfluorooctyl quaternary ammonium iodide, rhamnolipid and sodium vinyl sulfonate is 0.15:0.15:0.15:0.15.

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