Aluminum foil glass fiber adhesive tape and preparation method thereof
By introducing a formula for tearable glass fiber layer and optimized polyurethane adhesive layer into the aluminum foil glass fiber tape, the problem of difficult tape in the prior art is solved, and the tape performance is achieved that easier operation and more durable.
Patent Information
- Application Number
- CN202510147819.9
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-02-11
- Publication Date
- 2025-05-13
AI Technical Summary
When using aluminum foil fiberglass tape, the prior art is difficult to take into account its tearability and physical strength, which makes it difficult to operate during installation and maintenance, and the tape is prone to damage, affecting its application effect in high temperature environments.
By introducing a tearable glass fiber layer into the aluminum foil glass fiber tape, and optimizing the formulation of the polyurethane glue layer, adding acrylic modified alkyd resin and nano-scale reinforcement, the physical strength and toughness of the tape are improved.
It realizes that aluminum foil fiberglass tape is easier to tear off during installation and maintenance, reducing operation difficulty, and not easily damaged when withstand external forces, extending its service life.
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Abstract
Description
Technical Field
[0001] The present application relates to the technical field of aluminum foil glass fiber tape processing, and more specifically, to an aluminum foil glass fiber tape and a preparation method thereof. Background Art
[0002] The automotive wiring harness is the main route connecting the various parts of the vehicle's electrical system, and its quality directly affects the quality and performance of the vehicle. Aluminum foil fiberglass tape has good insulation, anti-interference and shielding properties. At the same time, aluminum foil fiberglass tape can work stably for a long time in a high temperature environment. Its maximum tolerance temperature can reach 150°C or even higher, which enables it to meet the use requirements in high temperature environments such as the engine compartment of the car. Aluminum foil fiberglass tape can effectively isolate the influence of high temperature environment on the wiring harness and protect the wiring harness from high temperature damage. At the same time, aluminum foil fiberglass tape as a wrapping material can effectively improve the insulation performance of the wiring harness and prevent current leakage and short circuit. It effectively shields external electromagnetic interference, protects the signal transmission in the wiring harness from interference, and ensures the stable operation of the automotive electrical system.
[0003] However, during use, the aluminum foil fiberglass tape is not tearable, which greatly increases the difficulty and complexity of the installation and maintenance process. In order to improve the tearability of the aluminum foil fiberglass tape, the strength of the aluminum foil fiberglass tape will be reduced, making the aluminum foil fiberglass tape extremely easy to tear. However, the reduction in the strength of the aluminum foil fiberglass tape will cause the tape to be easily damaged when subjected to external forces, which will seriously affect its actual application effect and durability in wire harness protection. Therefore, while pursuing the tearability of the aluminum foil fiberglass tape, how to take into account and maintain its necessary physical strength and comprehensive performance has become a key issue that needs to be urgently solved in the current field of material research and development and technology improvement. Summary of the invention
[0004] In order to improve the tearability and strength of aluminum foil glass fiber tape, the present application provides an aluminum foil glass fiber tape and a preparation method thereof.
[0005] In the first aspect, the present application provides an aluminum foil glass fiber tape, which adopts the following technical solution: An aluminum foil glass fiber tape comprises an aluminum foil layer, a polyurethane adhesive layer, a tearable glass fiber layer and a silicone layer in sequence, wherein the polyurethane adhesive layer is prepared from the following raw materials in percentage by weight: Polyurethane resin 40-50% Acrylic modified alkyd resin 5-10% Tackifier 10-15% Enhancer 8-12% Adhesive 2-4% Curing agent 1-2% The remaining amount is diluent; The reinforcing agent consists of nano solid filler and cellulose nano fiber.
[0006] By adopting the above technical solution, by introducing a tearable glass fiber layer and optimizing the formula of the polyurethane adhesive layer, the aluminum foil glass fiber tape is easier to tear off during installation and maintenance, reducing the difficulty and complexity of operation. At the same time, the addition of acrylic modified alkyd resin and reinforcing agent and other raw materials to the polyurethane adhesive layer significantly improves the physical strength of the tape. Even when the tape is subjected to external force, it is not easy to be damaged, thus ensuring its practical application effect and durable life in wire harness protection.
[0007] The polyurethane layer uses polyurethane as a base material to provide basic bonding and strength properties; the flexibility of the tape is improved by introducing acrylic modified alkyd resin, making it easier to tear off while maintaining strength; the tackifier increases the viscosity of the polyurethane adhesive layer to ensure that the aluminum foil layer and the tearable fiberglass cloth layer can be firmly adhered together. The adhesive improves the adhesion between the fiberglass cloth layer and the aluminum foil layer and the fiberglass layer, ensuring a tight bond between the layers of the tape, which helps to improve the overall stability and durability of the tape and prevent delamination or shedding during use. The diluent adjusts the viscosity of the adhesive layer for easy processing and application.
[0008] The reinforcing agent is composed of nano solid fillers and cellulose nanofibers. The nano solid fillers, with their tiny particle size and high specific surface area, effectively improve the strength and hardness of the adhesive layer and enhance the tape's ability to resist external damage. The cellulose nanofibers, with their excellent flexibility and dispersibility, improve the toughness and tear resistance of the adhesive layer, making the tape have good tearability while maintaining high strength. The reinforcing agent content is between 8% and 12%, which effectively balances the tearability and strength of the tape.
[0009] Preferably, the weight ratio of the nano solid filler to the cellulose nanofiber is 5:(8-12).
[0010] By adopting the above technical solution, the dosage of nano solid filler and cellulose nanofiber is optimized, and the physical strength of the adhesive layer is further improved, making the tape tougher and less prone to damage when subjected to external forces, while maintaining good tearability, reducing the operational difficulty during installation and maintenance.
[0011] Preferably, the nano solid filler is a modified nano solid filler, which is prepared by the following method: 1) placing a nano solid filler in an ethanol solution, adding a silane coupling agent, stirring, filtering, and collecting a filter residue to obtain a functionalized nano solid filler; 2) Adding functionalized nano solid filler, alkylene diacrylate, methyl acrylate, azobisisobutyronitrile and benzene into a reactor, raising the temperature of the reactor to 65-75° C., reflux the system, and heat-retaining the reaction for 4-5 hours, and post-treating to obtain modified nano silica.
[0012] By adopting the above technical solution, the dispersion of nano solid fillers in polyurethane resin is significantly improved, reducing the occurrence of agglomeration. The uniform dispersion enables the fillers to more effectively enhance the mechanical properties of the adhesive layer, making the aluminum foil glass fiber tape have higher strength and longer service life while maintaining tearability.
[0013] By treating the nano solid filler with a silane coupling agent to functionalize its surface, the compatibility and interfacial bonding between the filler and the polyurethane resin are enhanced, which helps to improve the overall strength and toughness of the polyurethane adhesive layer, making the tape more resistant to breakage when subjected to force, thereby improving its durability. Secondly, the alkylene diacrylate and methyl acrylate monomers added during the modification process react chemically with the functionalized nano solid filler, allowing the modified nano solid filler to better combine with the polyurethane resin to form a stable composite material, which helps to improve the overall stability and reliability of the tape, making the aluminum foil fiberglass tape tearable while also having good strength during use.
[0014] Preferably, the weight parts of the raw materials used to prepare the modified nano solid filler are as follows: Nano solid filler 12-14 parts Silane coupling agent 1-2 parts Ethanol 10-12 parts 2-3 parts of alkylene diacrylate 1-2 parts of methyl acrylate 0.3-0.5 parts of azobisisobutyronitrile 12-15 parts of benzene.
[0015] By adopting the above technical solution and using the above specific weight portions of raw materials to prepare modified nano solid fillers, the performance of aluminum foil glass fiber tape is significantly improved. The modified nano solid fillers prepared by this formula can significantly improve the strength and toughness of aluminum foil glass fiber tape while maintaining its good tearability, making the tape less likely to break when subjected to external forces, thereby extending the service life in applications such as wire harness protection.
[0016] Preferably, the silane coupling agent includes at least one of γ-(methacryloyloxy)propyltrimethoxysilane, γ-glycidyloxypropyltrimethoxysilane, 3-(2,3-epoxypropyloxy)propyltrimethoxysilane and γ-mercaptopropyltriethoxysilane.
[0017] By adopting the above technical solution, a strong chemical bond can be formed with the nano solid filler, thereby enhancing the compatibility and interfacial bonding strength between the nano solid filler and polyurethane, which not only improves the mechanical properties of the polyurethane adhesive layer, but also makes the tape more resistant to damage when subjected to force, thereby extending its service life.
[0018] Preferably, the diluent includes at least one of dimethyl carbonate, propylene carbonate, ethyl acetate, acryloylmorpholine, tetrahydrofuran acrylate, isobornyl acrylate, lauric acid acrylate and 1,6-hexanediol diacrylate.
[0019] By using the above diluent, the viscosity of the polyurethane resin can be effectively reduced, its processing performance can be improved, and the adhesive layer can be more uniform and smooth during the coating process. At the same time, the above diluent also has a certain volatility and can gradually evaporate during the curing process to form a dense and uniform adhesive layer structure, thereby improving the strength and toughness of the tape.
[0020] Preferably, the adhesive is composed of epoxy phosphate and γ-aminopropyltriethoxysilane coupling agent in a weight ratio of (3-5):1.
[0021] By adopting the above technical solution, the type and amount of adhesive are optimized, the adhesion performance between the adhesive layer and the aluminum foil layer and the glass fiber layer is further enhanced, and the stability and mechanical properties of the aluminum foil and glass fiber tape are enhanced. The aluminum foil and glass fiber tape has higher strength and longer service life while maintaining excellent tearability, meeting the needs of a variety of complex application scenarios.
[0022] Preferably, the tackifier is composed of β-terpene resin and rosin resin in a weight ratio of 2:(4-6).
[0023] By adopting the above technical solution and optimizing the type and amount of tackifier, not only the adhesion of the adhesive layer is significantly enhanced, but also the aluminum foil layer and the tearable fiberglass cloth layer can be firmly adhered together and not easy to fall off. As a high-performance natural polysaccharide, β-terpene resin has excellent thickening and stabilizing properties, which helps to improve the uniformity and stability of the polyurethane adhesive layer; while rosin resin, with its unique chemical structure and bonding properties, enhances the interaction between the polyurethane adhesive layer and the aluminum foil layer and the tearable fiberglass cloth layer. Therefore, the application of this tackifier makes the aluminum foil fiberglass tape have a wider range of applicability and a longer service life while maintaining high strength and tearability.
[0024] Preferably, the curing agent is one of hydroquinone dihydroxyethyl ether, resorcinol bishydroxyethyl ether, p-hydroxyethyl bisphenol A, 3,5-dimethylthiotoluenediamine, 3,3'-dichloro-4,4'-diphenylmethanediamine or 3,5-diethyltoluenediamine.
[0025] By adopting the above technical solutions, the polyurethane adhesive layer can reach an ideal curing state in a short time. At the same time, they can also form a strong chemical bond with the polyurethane, enhance the cohesive strength and adhesion of the adhesive layer, and improve the overall strength and durability of the tape.
[0026] In a second aspect, the present application provides a method for preparing an aluminum foil glass fiber tape, using the following technical solution: A method for preparing an aluminum foil glass fiber tape comprises the following steps: S1. According to the weight percentage, the polyurethane resin, acrylic modified alkyd resin, tackifier, reinforcing agent and diluent are stirred, and then the adhesive and curing agent are added and stirred evenly to obtain a polyurethane adhesive; S2. Coat polyurethane glue on the surface of aluminum foil, then spread glass fiber cloth on the surface of polyurethane glue and solidify it. Finally, coat silicone on the side of glass fiber cloth away from polyurethane glue layer and solidify it to obtain aluminum foil glass fiber tape.
[0027] By adopting the above technical solution, a high-performance polyurethane adhesive layer is formed by combining polyurethane resin with acrylic modified alkyd resin, supplemented by tackifiers, reinforcing agents and diluents. This adhesive layer not only has excellent adhesion and can closely adhere to aluminum foil and fiberglass cloth, but also has good flexibility and weather resistance, ensuring that the tape can maintain stable performance in various complex environments.
[0028] In summary, this application has the following beneficial effects: 1. Improve tearability: The introduction of the tearable glass fiber layer makes the tape easier to operate during installation and maintenance, reducing the difficulty and complexity of operation.
[0029] 2. Maintain high strength: By optimizing the formula of the polyurethane adhesive layer and using nano-level reinforcing agents, the tape can maintain the necessary physical strength and comprehensive performance while maintaining high tearability and is not easily damaged by external forces. DETAILED DESCRIPTION Example
[0030] The polyurethane resin was purchased from Jining Fangyu Chemical Co., Ltd. with the brand name ty.
[0031] β-Terpene resin was purchased from Shandong Xinghai Chemical Co., Ltd., model number is XH-022.
[0032] Rosin resin was purchased from Shandong Senya New Materials Co., Ltd. with the brand name SY-Q1.
[0033] Epoxy phosphate was purchased from Guangdong Aona Polymer Co., Ltd., model F-9.
[0034] Acrylic acid modified alkyd resin was purchased from Shandong Guangshen Electronic Technology Co., Ltd., model GS6541.
[0035] Cellulose nanofibers were purchased from Hubei Xinyuhong Biopharmaceutical Technology Co., Ltd. with the product number xyh001.
[0036] Example 1 An aluminum foil glass fiber tape is prepared by the following method: S1, 400g of polyurethane resin, 100g of acrylic modified alkyd resin, 150g of tackifier (dimethyl carbonate), 120g of reinforcing agent and 180g of diluent (dimethyl carbonate) were stirred, and then 40g of adhesive (epoxy phosphate) and 10g of curing agent (hydroquinone dihydroxyethyl ether) were added, and stirred evenly to obtain polyurethane glue; S2. Coat polyurethane glue on the surface of aluminum foil, then spread glass fiber cloth on the surface of polyurethane glue and solidify it. Finally, coat silicone on the side of glass fiber cloth away from polyurethane glue layer and solidify it to obtain aluminum foil glass fiber tape.
[0037] The reinforcing agent is composed of nano solid filler (nano silicon dioxide) and cellulose nanofiber in a weight ratio of 5:8.
[0038] The difference between Example 2-3 and Example 1 is that the types, amounts and parameters of raw materials used to prepare the polyurethane adhesive are different. The specific differences are shown in Table 1: In Example 2, the reinforcing agent is composed of nano solid filler (nano silicon dioxide) and cellulose nanofibers in a weight ratio of 5:10.
[0039] In Example 3, the reinforcing agent is composed of nano solid filler (nano silicon dioxide) and cellulose nanofibers in a weight ratio of 5:12.
[0040] Example 4 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that the reinforcing agent is composed of nano solid filler (nano silicon dioxide) and cellulose nanofibers in a weight ratio of 5:5.
[0041] Example 5 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that the nano solid filler is a modified nano solid filler, which is prepared by the following method: 1) placing 120 g of nano solid filler (nano silicon dioxide) in 100 g of ethanol solution, adding 10 g of silane coupling agent (γ-(methacryloyloxy)propyltrimethoxysilane), stirring, filtering, and taking the filter residue to obtain a functionalized nano solid filler; 2) Add functionalized nano solid filler, 20 g of alkylene diacrylate, 10 g of methyl acrylate, 3 g of azobisisobutyronitrile and 120 g of benzene into a reactor, raise the temperature of the reactor to 65° C., reflux the system, keep the temperature for 4 hours, and post-treat to obtain modified nano silica.
[0042] Example 6 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that the nano solid filler is a modified nano solid filler, which is prepared by the following method: 1) placing 140 g of nano solid filler (nano silicon dioxide) in 120 g of ethanol solution, adding 20 g of silane coupling agent (γ-glycidyloxypropyltrimethoxysilane), stirring, filtering, and taking the filter residue to obtain a functionalized nano solid filler; 2) Add functionalized nano solid filler, 30 g of alkylene diacrylate, 20 g of methyl acrylate, 5 g of azobisisobutyronitrile and 150 g of benzene into a reactor, raise the temperature of the reactor to 75° C., reflux the system, keep the temperature for 5 hours, and perform post-treatment to obtain modified nano silica.
[0043] Example 7 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that: the adhesive is composed of epoxy phosphate and γ-aminopropyl triethoxy silane coupling agent in a weight ratio of 3:1.
[0044] Example 8 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 5 is that: the adhesive is composed of epoxy phosphate and γ-aminopropyl triethoxy silane coupling agent in a weight ratio of 5:1.
[0045] Example 9 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 7 is that: the adhesive is composed of epoxy phosphate and γ-aminopropyl triethoxy silane coupling agent in a weight ratio of 3:3.
[0046] Example 10 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that: the tackifier is composed of β-terpene resin and rosin resin in a weight ratio of 2:4.
[0047] Embodiment 11 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 1 is that: the tackifier is composed of β-terpene resin and rosin resin in a weight ratio of 2:6.
[0048] Example 12 An aluminum foil glass fiber tape, the difference between this embodiment and embodiment 10 is that the tackifier is composed of β-terpene resin and rosin resin in a weight ratio of 2:2.
[0049] Comparative Example Comparative Example 1 An aluminum foil glass fiber tape, the difference between this comparative example and Example 1 is that the reinforcing agent is a nano solid filler (nano silicon dioxide).
[0050] Comparative Example 2 An aluminum foil glass fiber tape, the difference between this comparative example and Example 1 is that the reinforcing agent is cellulose nanofiber.
[0051] Comparative Example 3 An aluminum foil glass fiber tape, the difference between this comparative example and Example 1 is that alkyd resin is used instead of acrylic acid modified alkyd resin.
[0052] Alkyd resin was purchased from Shenyang Elex Chemical Co., Ltd., model number 389-9.
[0053] Comparative Example 4 An aluminum foil glass fiber tape, the difference between this comparative example and Example 1 is that polyester polyol is used instead of a reinforcing agent.
[0054] Polyester polyol was purchased from Qikesong New Materials (Foshan) Co., Ltd., model number is QS-45.
[0055] Detection method / test method Tearability test: pinch a corner of the aluminum foil fiberglass tape with your hand, and then tear it in one direction with force, observe the flatness of the tear surface and whether the tape is easy to break. If the tape is easy to tear and the tear line is neat, it means that it is easy to tear; if the tape is difficult to tear, there is a wire drawing phenomenon after tearing, and the tear line is not neat, it is unqualified. Tapes with a smooth tear surface and no burrs are usually of good quality, otherwise they are of poor quality, but they can be used.
[0056] Strength test: The specifications of the aluminum foil glass fiber tape sample are 25±0.5mm in width and about 200mm in length. Prepare an electronic tensile testing machine, install the prepared sample on the fixture of the testing machine, adjust the tensile speed to 300mm / min, the preload to 20N, start the testing machine, and record the maximum force value and elongation at break of the sample. (51.3MPa) Peel strength: refer to the test method specified in GB / T 2792-2014 "Test method for peel strength of adhesive tape". The peel angle is 180° and the peel speed is 150mm / min.
[0057] High temperature resistance: According to the standard GB / T 32368-2015; Determination method: The specifications of the aluminum foil fiberglass tape samples are 25±0.5mm in width, about 200mm in length, and 5 samples. The samples are wound on the wiring harness and tested in an electric constant temperature drying oven at 250℃ for 240h. Cut it open and observe whether the aluminum foil layer and the fiberglass cloth layer are delaminated. The experimental data are shown in Table 2: Table 2 Experimental data of Examples 1-11 and Comparative Examples 1-4 Comparing Example 1 with Comparative Examples 1-2 and 4, the tearability in Example 1 is better than that in Comparative Examples 1-2 and 4. At the same time, the strength and peel strength in Example 1 are higher than those in Comparative Examples 1-2 and 4, indicating that by adding a reinforcing agent prepared by nano-solid fillers and cellulose nanofibers, the aluminum foil glass fiber tape can be torn while having good strength and stability.
[0058] Comparing Example 1 with Comparative Example 3, the tearability of Example 1 is better than that of Comparative Example 3. At the same time, the strength and peel strength of Example 1 are higher than those of Comparative Example 3. After the high temperature test, delamination phenomenon also occurs in Comparative Example 3, indicating that by adding acrylic modified alkyd resin in combination with other raw materials, the tearability of the aluminum foil glass fiber tape can be ensured, and the strength and stability of the aluminum foil glass fiber tape can be improved.
[0059] Comparing Example 1 with Example 5-6, the tearability of Example 5-6 is better than that of Example 1. At the same time, the strength and peel strength of Example 5-6 are higher than those of Example 1, indicating that the modified nano solid filler prepared by the present application can ensure that the aluminum foil glass fiber tape is better torn, and can also improve the strength and stability of the aluminum foil glass fiber tape.
[0060] Comparing Example 1 with Example 7, the tearability in Example 7 is better than that in Example 1, and the strength and peel strength in Example 7 are both higher than those in Example 1; Comparing Example 5 with Example 8, the tearability in Example 8 is better than that in Example 5, and the strength and peel strength in Example 8 are both higher than those in Example 5; Comparing Example 7 with Example 9, the tearability of Example 9 is better than that of Example 7, and the strength and peel strength of Example 9 are both higher than those of Example 7; It can be seen from the experimental data of Examples 1 and 7, Examples 5 and 8, and Examples 7 and 9 that by using epoxy phosphate and γ-aminopropyltriethoxysilane together, the strength and stability of the aluminum foil glass fiber tape can be improved while ensuring that the aluminum foil glass fiber tape is better torn.
[0061] By comparing Example 1 with Example 10, the tearability in Example 10 is better than that in Example 1, and the strength and peel strength in Example 70 are both higher than those in Example 1; Comparing Example 8 with Example 11, the tearability of Example 11 is better than that of Example 8, and the strength and peel strength of Example 11 are both higher than those of Example 8; Comparing Example 10 with Example 12, the tearability of Example 10 is better than that of Example 12, and the strength and peel strength of Example 10 are both higher than those of Example 12; It can be seen from the experimental data of Examples 1 and 10, Examples 8 and 11, and Examples 10 and 12 that by using β-terpene resin and rosin resin together, the aluminum foil glass fiber tape can be torn better while improving the strength and stability of the aluminum foil glass fiber tape.
[0062] This specific embodiment is merely an explanation of the present application and is not a limitation of the present application. After reading this specification, those skilled in the art may make modifications to the present embodiment without any creative contribution as needed, but such modifications are protected by the patent law as long as they are within the scope of the claims of the present application.
Claims
1. An aluminum foil glass fiber tape, characterized in that: It includes an aluminum foil layer, a polyurethane adhesive layer, a tearable glass fiber layer and a silicone layer in sequence, wherein the polyurethane adhesive layer is prepared from the following raw materials in the following weight percentages: Polyurethane resin 40-50% Acrylic modified alkyd resin 5-10% Tackifier 10-15% Enhancer 8-12% Adhesive 2-4% Curing agent 1-2% The remaining amount is diluent; The reinforcing agent consists of nano solid filler and cellulose nano fiber.
2. The aluminum foil glass fiber tape according to claim 1, characterized in that: The weight ratio of the nano solid filler to the cellulose nanofiber is 5:(8-12).
3. The aluminum foil glass fiber tape according to claim 2, characterized in that: The nano solid filler is a modified nano solid filler, which is prepared by the following method: 1) placing the nano solid filler in an ethanol solution, adding a silane coupling agent, stirring, filtering, and collecting the filter residue to obtain a functionalized nano solid filler; 2) Add functionalized nano solid filler, alkylene diacrylate, methyl acrylate, azobisisobutyronitrile and benzene into a reactor, raise the temperature of the reactor to 65-75° C., reflux the system, keep the temperature for 4-5 hours, and post-treat to obtain modified nano silica.
4. The aluminum foil glass fiber tape according to claim 3, characterized in that: The weight parts of the raw materials used to prepare the modified nano solid filler are as follows: Nano solid filler 12-14 parts Silane coupling agent 1-2 parts Ethanol 10-12 parts 2-3 parts of alkylene diacrylate 1-2 parts of methyl acrylate 0.3-0.5 parts of azobisisobutyronitrile 12-15 parts of benzene.
5. The aluminum foil glass fiber tape according to claim 4, characterized in that: The silane coupling agent includes at least one of γ-(methacryloyloxy)propyl trimethoxysilane, γ-glycidoxypropyl trimethoxysilane, 3-(2,3-epoxypropyloxy)propyl trimethoxysilane and γ-mercaptopropyl triethoxysilane.
6. The aluminum foil glass fiber tape according to claim 1, characterized in that: The diluent includes at least one of dimethyl carbonate, propylene carbonate, ethyl acetate, acryloylmorpholine, tetrahydrofuran acrylate, isobornyl acrylate, lauric acid acrylate and 1,6-hexanediol diacrylate.
7. The aluminum foil glass fiber tape according to claim 1, characterized in that: The adhesive is composed of epoxy phosphate and γ-aminopropyl triethoxy silane coupling agent in a weight ratio of (3-5):
1.
8. The aluminum foil glass fiber tape according to claim 1, characterized in that: The tackifier is composed of beta-terpene resin and rosin resin in a weight ratio of 2: (4-6).
9. The aluminum foil glass fiber tape according to claim 1, characterized in that: The curing agent is one of hydroquinone dihydroxyethyl ether, resorcinol dihydroxyethyl ether, p-hydroxyethyl bisphenol A, 3,5-dimethylthiotoluenediamine, 3,3'-dichloro-4,4'-diphenylmethanediamine or 3,5-diethyltoluenediamine.
10. A method for preparing the aluminum foil glass fiber tape according to any one of claims 1 to 9, characterized in that: The method comprises the following preparation steps: S1. According to the weight percentage, the polyurethane resin, acrylic modified alkyd resin, tackifier, reinforcing agent and diluent are stirred, and then the adhesive and curing agent are added and stirred evenly to obtain a polyurethane adhesive; S2. Coat polyurethane glue on the surface of aluminum foil, then spread glass fiber cloth on the surface of polyurethane glue and solidify it. Finally, coat silicone on the side of glass fiber cloth away from polyurethane glue layer and solidify it to obtain aluminum foil glass fiber tape.
Citation Information
Patent Citations
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CN117343654A
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