Sulfonamide compound and noxious arthropod control composition containing same

Abstract

The present invention provides a compound having an excellent controlling efficacy against harmful arthropods. In formula (I) (in the formula, Q (# represents a bonding site with a sulfur atom and a bonding site with Het) represents a group represented by formula Q1 or the like, R2a and R2b are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms or the like, R3a, R3b and R3d are the same or different from each other and represent a hydrogen atom or the like, Het represents a group represented by formula Het1 or the like, A2 represents a nitrogen atom or CR4a, and Re represents a hydrogen atom or the like. W1 represents an oxygen atom or a sulfur atom, R4a represents a C1-C6 chain hydrocarbon group or the like, a combination of B1, B2, B3 and B4 represents a combination of B1 being a nitrogen atom or CR6a, B2 being CR6e, B3 being a nitrogen atom or CR6c, B4 being a nitrogen atom or CR6d or the like, R6a, R6c and R6d are the same or different from each other and represent a hydrogen atom or the like, and R6e represents a C1-C6 chain hydrocarbon group or the like substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. ) The compound or N-oxide thereof has an excellent controlling effect on harmful arthropods. # imgabs0 #

Description

Technical Field

[0001] This application claims priority and the benefits thereof from Japanese Patent Application No. 2022-164661 filed on October 13, 2022, the entire content of which is incorporated herein by reference.

[0002] The present invention relates to a sulfonamide compound and a pest arthropod control composition containing the sulfonamide compound. Background Art

[0003] Hitherto, various compounds have been studied for the purpose of controlling pest arthropods. For example, Patent Document 1 describes that a certain compound has a pest control effect.

[0004] Prior Art Documents

[0005] Patent Documents

[0006] Patent Document 1: WO 2019 / 131575 Summary of the Invention

[0007] Problems to be Solved by the Invention

[0008] An object of the present invention is to provide a compound having excellent control efficacy against pest arthropods.

[0009] Means for Solving the Problems

[0010] The present invention is as follows.

[0011] 〔1〕A compound represented by formula (I) (hereinafter referred to as Compound N of the present invention) or its N-oxide (hereinafter, the compound represented by formula (I) or its N-oxide is referred to as the compound of the present invention).

[0012] [Chemical Formula 1]

[0013]

[0014] 〔In the formula,

[0015] Q represented by the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents the bonding site to the sulfur atom, ● represents the bonding site to Het),

[0016] [Chemical Formula 2]

[0017]

[0018] [Chemical Formula 3]

[0019]

[0020] A 1a represents NR 5a , an oxygen atom or a sulfur atom,

[0021] A 1b represents an oxygen atom or a sulfur atom,

[0022] G 1 , G 2 , G 3 and G 4 in combination represent:

[0023] G 1 is a nitrogen atom or CR 3a , G 2 is CR 3b , G 3 is CR 3d , G 4 is CR 3c in combination;

[0024] G 1 is CR 3a , G 2 is a nitrogen atom, G 3 is CR 3d , G 4 is CR 3c in combination;

[0025] G 1 is CR 3a , G 2 is CR 3b , G 3 is a nitrogen atom, G 4 is CR 3c or

[0026] G 1 is CR 3a , G 2 is CR 3b , G 3 is CR 3d , G 4 is a nitrogen atom in combination,

[0027] R 2a and R 2b are the same or different from each other and represent a C1-C6 alkyl group that can be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group that can be substituted by one or more halogen atoms, or a hydrogen atom; or

[0028] R 2a and R 2bThey can together with the nitrogen atoms to which they are bonded form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group,

[0029] R 3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3g 、R 3i and R 3k are the same as or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group E, a phenyl group which may be substituted by one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H, OR 12 、NR 11 R 12 、NR 11a R 12a 、NR 24 NR 11 R 12 、NR 24 OR 11 、NR 11 C(O)R 13 、NR 24 NR 11 C(O)R 13 、NR 11 C(O)OR 14 、NR 24 NR 11 C(O)OR 14 、NR 11 C(O)NR 31 R 32 、NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 、CR 30 =NOR 17 、NR 11 CR 24 =NOR 17, S(O) q R 23 , a cyano group, a nitro group, a hydrogen atom or a halogen atom,

[0030] R 3e and R 3h , which are the same as or different from each other, represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a phenyl group which may be substituted by one or more substituents selected from the group H,

[0031] When Q is a group represented by the formula Q1, R 3a and R 3b or R 3b and R 3d may together with the two carbon atoms to which they are bonded form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring may be substituted by one or more substituents selected from the group H}, or a triazole ring which may be substituted by one or more substituents selected from the group I,

[0032] p represents 0 or 1,

[0033] q represents 0, 1 or 2,

[0034] R 30 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom, OR 35 , NR 36 R 37 , or a hydrogen atom,

[0035] R 17 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from the group D, or a hydrogen atom,

[0036] R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from the group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from the group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from the group J, a phenyl group which may be substituted by one or more substituents selected from the group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from the group D, a hydrogen atom, or S(O)2R 23 ,

[0037] R 23represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D,

[0038] R 11a and R 12a together with the nitrogen atom to which they are bonded form a 3-7 membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E,

[0039] R 13 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom,

[0040] R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenylC1-C3 alkyl group {the phenyl moiety in the phenylC1-C3 alkyl group may be substituted with one or more substituents selected from Group D},

[0041] R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms,

[0042] R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom,

[0043] R 32 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from Group J, or a hydrogen atom,

[0044] Het represents a group represented by Formula Het1, a group represented by Formula Het2, a group represented by Formula Het3, or a group represented by Formula Het4,

[0045] [Chemical Formula 4]

[0046]

[0047] A 2 represents a nitrogen atom or CR 4a ,

[0048] A 3 represents NR5b 、 an oxygen atom, a sulfur atom or CHR 4b ,

[0049] A 4 represents NR 5c 、 an oxygen atom or a sulfur atom,

[0050] W 1 represents an oxygen atom or a sulfur atom,

[0051] When Het is the group represented by formula Het3, Q represents the group represented by formula Q2, the group represented by formula Q5, the group represented by formula Q6, or the group represented by formula Q7,

[0052] When Het is the group represented by formula Het4, Q represents the group represented by formula Q2, the group represented by formula Q3, the group represented by formula Q4, the group represented by formula Q5, the group represented by formula Q6, or the group represented by formula Q7,

[0053] B 1 、 B 2 、 B 3 and B 4 The combination of represents:

[0054] B 1 is a nitrogen atom or CR 6a , B 2 is CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d of the combination; or

[0055] B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 is CR 6e , B 4 is a nitrogen atom or CR 6d of the combination,

[0056] R 4a 、 R 4b 、 R 6a 、 R 6b 、 R 6c and R 6d are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a nitro group, OR 18 、 NR 18 R 19 、 a cyano group, an amino group, a halogen atom or a hydrogen atom,

[0057] R 6e represents a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , a halogen atom or OS(O)2R 7 ,

[0058] R 5a represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C6 alkoxy group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom,

[0059] R 5b and R 5c are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C6 alkoxy group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, or a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms,

[0060] R 7 represents a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms,

[0061] m represents 0, 1 or 2,

[0062] R 18 and R 35 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms,

[0063] R 11 , R 19 , R 24 , R 36 and R 37 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms or a hydrogen atom.

[0064] Group B: a group consisting of a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a C1-C6 alkylthio group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a cyano group, a hydroxyl group and a halogen atom.

[0065] Group C: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom.

[0066] Group D: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a hydroxyl group, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a thio group, a C1-C6 alkylthio group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, an amino group, NHR 21 、NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 、a cyano group, a nitro group and a halogen atom.

[0067] R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms.

[0068] Group E: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a halogen atom, an oxo group, a hydroxyl group, a cyano group and a nitro group.

[0069] Group F: consisting of a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a 3-7 membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from Group C, an amino group, NHR 21 、NR 21 R 22 、a halogen atom and a cyano group.

[0070] Group H: consisting of a C1-C6 alkyl group which may be substituted by one or more halogen atoms, OR 10 、NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 、NR 10 C(O)R 9 、NR 10 C(O)OR 9 、C(O)OR 10 、a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group.

[0071] R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms,

[0072] R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0073] Group I: consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group and a bis(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms.

[0074] Group J: consisting of a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a halogen atom and a cyano group. ]]

[0075] 〔2〕The compound or its N-oxide as described in 〔1〕, wherein Q is a group represented by formula Q1 or a group represented by formula Q5.

[0076] 〔3〕The compound or its N-oxide as described in 〔1〕, wherein Q is a group represented by formula Q5.

[0077] 〔4〕The compound or its N-oxide as described in any one of 〔1〕 to 〔3〕, wherein Het is a group represented by formula Het1, A 2 is a nitrogen atom, B 1 is CR 6a , B 2 is CR 6e , B 3 is CR 6c , B 4 is CR 6d .

[0078] 〔5〕The compound or its N-oxide as described in any one of 〔1〕 to 〔3〕, wherein Het is a group represented by formula Het3, B 1 is CR 6a , B 2 is CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d .

[0079] 〔6〕A pest arthropod control composition comprising an inert carrier and the compound or its N-oxide as described in any one of 〔1〕 to 〔5〕.

[0080] 〔7〕A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c) and group (d), and the compound or its N-oxide as described in any one of 〔1〕 to 〔5〕,

[0081] Group (a): The group consisting of an insecticidal active ingredient, a miticidal active ingredient and a nematicidal active ingredient;

[0082] Group (b): A bactericidal active ingredient;

[0083] Group (c): A plant growth regulating ingredient;

[0084] Group (d): A repellent ingredient.

[0085] 〔8〕A method for controlling pest arthropods, wherein an effective amount of the compound or its N-oxide as described in any one of 〔1〕 to 〔5〕 or an effective amount of the composition as described in 〔7〕 is applied to the pest arthropods or their habitats.

[0086] 〔9〕A seed or vegetative propagating organ that retains an effective amount of the compound or its N-oxide according to any one of 〔1〕 to 〔5〕 or an effective amount of the composition according to 〔7〕.

[0087] Advantages of the Invention

[0088] According to the present invention, harmful arthropods can be controlled. Detailed Description of the Invention

[0089] The substituents in the present invention will be described.

[0090] The term "halogen atom" means a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.

[0091] When the substituent is substituted with two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different from each other.

[0092] In this specification, the expression "CX-CY" means that the number of carbon atoms is from X to Y. For example, the expression "C1-C6" means that the number of carbon atoms is from 1 to 6.

[0093] The term "chain hydrocarbon group" means an alkyl group, an alkenyl group or an alkynyl group.

[0094] Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group and a hexyl group.

[0095] Examples of the alkenyl group include a vinyl group, a 1-propenyl group, a 2-propenyl group, a 1-methyl-1-propenyl group, a 1-methyl-2-propenyl group, a 1,2-dimethyl-1-propenyl group, a 1-ethyl-2-propenyl group, a 3-butenyl group, a 4-pentenyl group and a 5-hexenyl group.

[0096] Examples of the alkynyl group include an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-methyl-2-propynyl group, a 1,1-dimethyl-2-propynyl group, a 1-ethyl-2-propynyl group, a 2-butynyl group, a 4-pentynyl group and a 5-hexynyl group.

[0097] Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a tert-butoxy group, a pentyloxy group and a hexyloxy group.

[0098] Examples of the alkenyloxy group include a 2-propenyloxy group, a 2-butenyloxy group and a 5-hexenyloxy group.

[0099] Examples of the alkynyloxy group include a 2-propynyloxy group, a 2-butynyloxy group and a 5-hexynyloxy group.

[0100] Examples of the cycloalkyl group include, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl.

[0101] Examples of the cycloalkenyl group include, for example, cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclohexenyl, and cycloheptenyl.

[0102] Examples of the 3- to 7-membered non-aromatic heterocyclic group include, for example, aziridinyl, oxiranyl, thiiranyl, azetidinyl, oxetanyl, thietanyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydrothienyl, piperidinyl, pyranyl, dihydropyranyl, tetrahydropyranyl, tetrahydrothiopyranyl, azepanyl, oxepanyl, thiepanyl, pyrazolinyl, pyrazolidinyl, imidazolinyl, imidazolidinyl, oxazolinyl, thiazolinyl, oxazolidinyl, thiazolidinyl, isoxazolinyl, isoxazolidinyl, isothiazolinyl, isothiazolidinyl, dioxolanyl, dioxolyl, dioxanyl, morpholinyl, thiomorpholinyl, and piperazinyl.

[0103] Examples of the 5- or 6-membered aromatic heterocyclic group include, for example, pyrrolyl, furyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, and tetrazinyl.

[0104] Examples of the 6-membered aromatic heterocyclic group include, for example, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, and tetrazinyl.

[0105] Examples of the (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms include, for example, cyclopropylmethyl, (2-fluorocyclopropyl)methyl, cyclopropyl(fluoro)methyl, and (2-fluorocyclopropyl)(fluoro)methyl.

[0106] The (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms means a group in which the (C3-C7 cycloalkyl) and / or (C1-C6 alkyl) may be substituted with one or more halogen atoms, and examples thereof include (2,2-difluorocyclopropyl)methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl, (2,2-difluorocyclopropyl)propyl, (2,2-difluorocyclopropyl)butyl, (2,2-difluorocyclopropyl)pentyl, and (2,2-difluorocyclopropyl)hexyl.

[0107] Examples of the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D} include, for example, benzyl, 2-fluorobenzyl, 4-chlorobenzyl, 4-(trifluoromethyl)benzyl, and 2-[4-(trifluoromethyl)phenyl]ethyl.

[0108] Examples of the alkylthio group include a methylthio group, an ethylthio group, a propylthio group, and an isopropylthio group.

[0109] Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.

[0110] Examples of the alkylsulfonyl group include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

[0111] Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, a 2-methylpropionyl group, and a hexanoyl group.

[0112] Examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, and a pentyloxycarbonyl group.

[0113] Examples of the (C1-C6 alkyl)aminocarbonyl group include a methylaminocarbonyl group, an ethylaminocarbonyl group, a propylaminocarbonyl group, and an isopropylaminocarbonyl group.

[0114] Examples of the bis(C1-C4 alkyl)aminocarbonyl group include a dimethylaminocarbonyl group, a diethylaminocarbonyl group, and an ethylmethylaminocarbonyl group.

[0115] Examples of the N-oxide of the compound represented by the formula (I) include the compounds represented by the following formula.

[0116] [Chemical formula 5]

[0117]

[0118] [In the formula, the symbol represents the same meaning as described above.]

[0119] The compounds of the present invention may have one or more stereoisomers. Examples of the stereoisomers include enantiomers, diastereomers, and geometric isomers. The compounds of the present invention include each stereoisomer and a mixture of stereoisomers in any ratio.

[0120] The compounds of the present invention may form acid addition salts. Examples of the acid for forming the acid addition salt include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. The acid addition salt can be obtained by mixing the compound of the present invention with an acid.

[0121] Examples of the form of the compound N of the present invention include the following compounds.

[0122] [Mode 1] Among the compounds of the present invention N, a compound in which Q is a group represented by the formula Q1 or a group represented by the formula Q5.

[0123] [Mode 2] In Mode 1, G 1is a nitrogen atom or CR 3a , G 2 is CR 3b , G 3 is CR 3d , G 4 is CR 3c ,

[0124] R 3a , R 3b , R 3c and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group E, a phenyl group which may be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group H, OR 12 , CR 30 =NOR 17 , a hydrogen atom or a halogen atom,

[0125] R 17 and R 30 are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0126] R 12 is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, or a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D.

[0127] 〔Mode 3〕In Mode 2, R 3a and R 3c are hydrogen atoms,

[0128] R 3b and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more halogen atoms, OR 12 , a hydrogen atom or a halogen atom,

[0129] R 12 is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms.

[0130] 〔Mode 4〕In Mode 3, R 3b and R 3dA compound that is the same as or different from each other and is a C1-C6 chain hydrocarbon group, a hydrogen atom, or a halogen atom that can be substituted by one or more halogen atoms.

[0131] 〔Mode 5〕Among the compounds of the present invention N, a compound in which Q is a group represented by formula Q1.

[0132] 〔Mode 6〕In Mode 5, R 3a , R 3b and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from Group B, a C3-C7 cycloalkyl group that can be substituted by one or more substituents selected from Group E, a phenyl group that can be substituted by one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group that can be substituted by one or more substituents selected from Group H, OR 12 , CR 30 =NOR 17 , a hydrogen atom, or a halogen atom,

[0133] R 17 and R 30 are the same as or different from each other and are a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms,

[0134] R 12 is a C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group that can be substituted by one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group that can be substituted by one or more substituents selected from Group D.

[0135] 〔Mode 7〕In Mode 6, R 3a is a hydrogen atom,

[0136] R 3b and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted by one or more halogen atoms, a phenyl group that can be substituted by one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group that can be substituted by one or more halogen atoms, OR 12 , a hydrogen atom, or a halogen atom,

[0137] R 12 is a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms.

[0138] 〔Mode 8〕In Mode 7, R 3b and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, a hydrogen atom, or a halogen atom.

[0139] 〔Mode 9〕Among the compounds of the present invention N, a compound in which Q is a group represented by formula Q5.

[0140] 〔Mode 10〕In Mode 9, G 1 is a nitrogen atom or CR 3a , G 2 is CR 3b , G 3 is CR 3d , G 4 is CR 3c ,

[0141] R 3a , R 3b , R 3c and R 3d are the same as or different from each other, and are a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group E, a phenyl group which may be substituted by one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H, OR 12 , CR 30 =NOR 17 , a hydrogen atom or a halogen atom,

[0142] R 17 and R 30 are the same as or different from each other, and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0143] R 12 is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D.

[0144] 〔Mode 11〕In Mode 10, R 3a and R 3c are hydrogen atoms,

[0145] R 3b and R 3d are the same as or different from each other, and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more halogen atoms, OR 12 , a hydrogen atom or a halogen atom,

[0146] R 12 is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms.

[0147] [Mode 12] In Mode 11, R 3b and R 3d are the same as or different from each other and are a C1-C6 chain hydrocarbon group, a hydrogen atom, or a halogen atom that may be substituted with one or more halogen atoms.

[0148] [Mode 13] In the compound N of the present invention, R 2a and R 2b are the same as or different from each other and are a C1-C6 alkyl group that may be substituted with one or more halogen atoms, or a hydrogen atom.

[0149] [Mode 14] In the compound N of the present invention, R 2a and R 2b are the same as or different from each other and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom.

[0150] [Mode 15] In Mode 1, R 2a and R 2b are the same as or different from each other and are a C1-C6 alkyl group that may be substituted with one or more halogen atoms, or a hydrogen atom.

[0151] [Mode 16] In Mode 1, R 2a and R 2b are the same as or different from each other and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom.

[0152] [Mode 17] In Mode 2, R 2a and R 2b are the same as or different from each other and are a C1-C6 alkyl group that may be substituted with one or more halogen atoms, or a hydrogen atom.

[0153] [Mode 18] In Mode 2, R 2a and R 2b are the same as or different from each other and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom.

[0154] [Mode 19] In Mode 3, R 2a and R 2b are the same as or different from each other and are a C1-C6 alkyl group that may be substituted with one or more halogen atoms, or a hydrogen atom.

[0155] [Mode 20] In Mode 3, R 2a and R 2b are the same as or different from each other and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom.

[0156] [Mode 21] In Mode 4, R 2a and R 2bA compound which is the same as or different from each other and is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0157] 〔Mode 22〕In Mode 4, R 2a and R 2b A compound which is the same as or different from each other and is a methyl group, an ethyl group, a cyclopropyl group or a hydrogen atom.

[0158] 〔Mode 23〕In Mode 5, R 2a and R 2b A compound which is the same as or different from each other and is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0159] 〔Mode 24〕In Mode 5, R 2a and R 2b A compound which is the same as or different from each other and is a methyl group, an ethyl group, a cyclopropyl group or a hydrogen atom.

[0160] 〔Mode 25〕In Mode 6, R 2a and R 2b A compound which is the same as or different from each other and is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0161] 〔Mode 26〕In Mode 6, R 2a and R 2b A compound which is the same as or different from each other and is a methyl group, an ethyl group, a cyclopropyl group or a hydrogen atom.

[0162] 〔Mode 27〕In Mode 7, R 2a and R 2b A compound which is the same as or different from each other and is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0163] 〔Mode 28〕In Mode 7, R 2a and R 2b A compound which is the same as or different from each other and is a methyl group, an ethyl group, a cyclopropyl group or a hydrogen atom.

[0164] 〔Mode 29〕In Mode 8, R 2a and R 2b A compound which is the same as or different from each other and is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0165] 〔Mode 30〕In Mode 8, R 2a and R 2b A compound which is the same as or different from each other and is a methyl group, an ethyl group, a cyclopropyl group or a hydrogen atom.

[0166] 〔Mode 31〕In Mode 9, R 2a and R 2bCompounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or hydrogen atoms.

[0167] 〔Mode 32〕In Mode 9, R 2a and R 2b Compounds that are the same as or different from each other and are methyl, ethyl, cyclopropyl, or hydrogen atoms.

[0168] 〔Mode 33〕In Mode 10, R 2a and R 2b Compounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or hydrogen atoms.

[0169] 〔Mode 34〕In Mode 10, R 2a and R 2b Compounds that are the same as or different from each other and are methyl, ethyl, cyclopropyl, or hydrogen atoms.

[0170] 〔Mode 35〕In Mode 11, R 2a and R 2b Compounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or hydrogen atoms.

[0171] 〔Mode 36〕In Mode 11, R 2a and R 2b Compounds that are the same as or different from each other and are methyl, ethyl, cyclopropyl, or hydrogen atoms.

[0172] 〔Mode 37〕In Mode 12, R 2a and R 2b Compounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or hydrogen atoms.

[0173] 〔Mode 38〕In Mode 12, R 2a and R 2b Compounds that are the same as or different from each other and are methyl, ethyl, cyclopropyl, or hydrogen atoms.

[0174] 〔Mode 39〕Among any one of Modes 1 to 38 or Compound N of the present invention, compounds in which Het is a group represented by Formula Het1, a group represented by Formula Het2, or a group represented by Formula Het3.

[0175] 〔Mode 40〕Among any one of Modes 1 to 38 or Compound N of the present invention, compounds in which Het is a group represented by Formula Het1 or a group represented by Formula Het2.

[0176] 〔Mode 41〕Among any one of Modes 1 to 38 or Compound N of the present invention, compounds in which Het is a group represented by Formula Het1 or a group represented by Formula Het3.

[0177] 〔Embodiment 42〕Among any one of Embodiments 1 to 38 or Compound N of the present invention, a compound in which Het is a group represented by Formula Het1.

[0178] 〔Embodiment 43〕Among any one of Embodiments 1 to 38 or Compound N of the present invention, a compound in which Het is a group represented by Formula Het2.

[0179] 〔Embodiment 44〕Among any one of Embodiments 1 to 38 or Compound N of the present invention, a compound in which Het is a group represented by Formula Het3.

[0180] 〔Embodiment 45〕Among any one of Embodiments 1 to 38 or Compound N of the present invention, a compound in which Het is a group represented by Formula Het4.

[0181] 〔Embodiment 46〕In Embodiment 39, A 3 is NR 5b , A 4 is NR 5c or an oxygen atom, B 1 is CR 6a , B 2 is CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d ,

[0182] R 4a , R 6a , R 6c and R 6d are the same or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom.

[0183] R 6e is a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 or a halogen atom.

[0184] 〔Embodiment 47〕In Embodiment 39, A 3 is NR 5b , A 4 is NR 5c or an oxygen atom, B 1 is CR 6a , B 2 is CR 6b , B 3 is CR 6e , B 4 is a nitrogen atom or CR6d ,

[0185] R 4a 、R 6a 、R 6b and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom or a hydrogen atom.

[0186] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 、OR 7 or a halogen atom.

[0187] 〔Mode 48〕In Mode 40, A 3 is NR 5b , R 4a is a hydrogen atom, R 5b is a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms.

[0188] B 1 is CR 6a , B 2 is CR 6e , B 3 is CR 6c , B 4 is a nitrogen atom or CR 6d .

[0189] R 6a 、R 6c and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom or a hydrogen atom.

[0190] R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom.

[0191] 〔Mode 49〕In Mode 41, A 4 is NR 5c or an oxygen atom, R 4a is a hydrogen atom, R 5c is a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms.

[0192] B 1 is CR 6a , B 2 is CR 6e , B 3is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d ,

[0193] R 6a , R 6c and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom.

[0194] R 6e is a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 or a halogen atom.

[0195] 〔Mode 50〕In Mode 42, R 4a is a hydrogen atom, B 1 is CR 6a , B 2 is CR 6e , B 3 is CR 6c , B 4 is a nitrogen atom or CR 6d , R 6a , R 6c and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom.

[0196] R 6e is a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom.

[0197] 〔Mode 51〕In Mode 43, A 3 is NR 5b , R 5b is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms.

[0198] B 1 is CR 6a , B 2 is CR 6e , B 3 is CR 6c , B 4 is a nitrogen atom or CR 6d ,

[0199] R 6a , R 6c and R6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group, a halogen atom or a hydrogen atom which may be substituted by one or more halogen atoms,

[0200] R 6e is a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a compound of a halogen atom.

[0201] 〔Mode 52〕In Mode 44, A 4 is NR 5c or an oxygen atom, and R 5c is a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0202] B 1 is CR 6a B 2 is CR 6e B 3 is a nitrogen atom or CR 6c B 4 is a nitrogen atom or CR 6d R 6a R 6c and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 OR 7 or a compound of a halogen atom.

[0203] 〔Mode 53〕In Mode 45, A 2 is CR 4a and R 4a is a hydrogen atom,

[0204] B 1 is CR 6a B 2 is CR 6e B 3 is a nitrogen atom or CR 6c B 4 is CR 6d R 6a R 6c and R 6d are the same as or different from each other and are a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom,

[0205] R 6eA C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 or a halogen atom compound.

[0206] [Mode 54] In Mode 46, R 4a , R 6a , R 6c and R 6d are hydrogen atoms, and R 5b is a methyl group compound.

[0207] [Mode 55] In Mode 47, R 4a , R 6a , R 6b and R 6d are hydrogen atoms, and R 5b is a methyl group compound.

[0208] [Mode 56] In Mode 48, R 6a , R 6c and R 6d are hydrogen atoms, and R 5b is a methyl group compound.

[0209] [Mode 57] In Mode 49, R 6a , R 6c and R 6d are hydrogen atoms, and R 5c is a methyl group compound.

[0210] [Mode 58] In Mode 50, R 6a , R 6c and R 6d are hydrogen atom compounds.

[0211] [Mode 59] In Mode 51, R 6a , R 6c and R 6d are hydrogen atoms, and R 5b is a methyl group compound.

[0212] [Mode 60] In Mode 52, R 6a , R 6c and R 6d are hydrogen atoms, and R 5c is a methyl group compound.

[0213] [Mode 61] In Mode 53, R 4a , R 6a , R 6c and R 6d are hydrogen atom compounds.

[0214] 〔Embodiment 62〕In any one of Embodiments 1 to 38 or the compound N of the present invention, W 1 is a compound in which W is an oxygen atom.

[0215] 〔Embodiment 63〕In Embodiment 39, W 1 is a compound in which W is an oxygen atom.

[0216] 〔Embodiment 64〕In Embodiment 40, W 1 is a compound in which W is an oxygen atom.

[0217] 〔Embodiment 65〕In Embodiment 41, W 1 is a compound in which W is an oxygen atom.

[0218] 〔Embodiment 66〕In Embodiment 42, W 1 is a compound in which W is an oxygen atom.

[0219] 〔Embodiment 67〕In Embodiment 43, W 1 is a compound in which W is an oxygen atom.

[0220] 〔Embodiment 68〕In Embodiment 46, W 1 is a compound in which W is an oxygen atom.

[0221] 〔Embodiment 69〕In Embodiment 47, W 1 is a compound in which W is an oxygen atom.

[0222] 〔Embodiment 70〕In Embodiment 48, W 1 is a compound in which W is an oxygen atom.

[0223] 〔Embodiment 71〕In Embodiment 49, W 1 is a compound in which W is an oxygen atom.

[0224] 〔Embodiment 72〕In Embodiment 50, W 1 is a compound in which W is an oxygen atom.

[0225] 〔Embodiment 73〕In Embodiment 51, W 1 is a compound in which W is an oxygen atom.

[0226] 〔Embodiment 74〕In Embodiment 54, W 1 is a compound in which W is an oxygen atom.

[0227] 〔Embodiment 75〕In Embodiment 55, W 1 is a compound in which W is an oxygen atom.

[0228] 〔Embodiment 76〕In Embodiment 56, W 1 is a compound in which W is an oxygen atom.

[0229] 〔Embodiment 77〕In Embodiment 57, W 1 is a compound in which W is an oxygen atom.

[0230] [Method 78] In Method 58, W 1 is a compound with an oxygen atom.

[0231] [Method 79] In Method 59, W 1 is a compound with an oxygen atom.

[0232] Next, the method for manufacturing the compound of the present invention will be described.

[0233] Manufacturing Method 1

[0234] The compound represented by formula (I) (the compound N of the present invention) can be manufactured by reacting the compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with the compound represented by formula (M-2) (hereinafter referred to as compound (M-2)).

[0235] [Chemical formula 6]

[0236]

[0237] [In the formula, the symbols have the same meanings as described above.]

[0238] The reaction is usually carried out in a solvent. Examples of the solvent include ethers such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane (hereinafter referred to as DME), methyl tert-butyl ether (hereinafter referred to as MTBE), and diethyl ether (hereinafter referred to as ethers); halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons); aromatic hydrocarbons such as toluene and xylene (hereinafter referred to as aromatic hydrocarbons); nitriles such as acetonitrile (hereinafter referred to as nitriles); water, and mixtures of two or more of them.

[0239] In the reaction, relative to 1 mole of compound (M-1), compound (M-2) is usually used in a proportion of 0.8 to 10 moles.

[0240] The reaction can be carried out by mixing compound (M-1) and compound (M-2). This reaction can also be carried out in the presence of a base as needed. Examples of the base include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, relative to 1 mole of compound (M-1), the base is usually used in a proportion of 1 to 3 moles.

[0241] The reaction temperature is usually in the range of -20 to 200°C. The reaction time is usually in the range of 0.1 to 24 hours.

[0242] After the reaction is completed, water can be injected into the reaction mixture, and then extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the organic layer are performed to obtain the compound N of the present invention.

[0243] Compound (M-2) is a commercially available compound or can be produced by known methods.

[0244] Production Method 2

[0245] The compound represented by formula (I-a) (hereinafter referred to as compound (I-a)) can be produced by reacting the compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with the compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) in the presence of a base.

[0246] [Chemical formula 7]

[0247]

[0248] [In the formula, Het A represents the group represented by formula Het1 or the group represented by formula Het2, and other symbols have the same meanings as described above.

[0249] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents such as dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), and dimethyl sulfoxide (hereinafter referred to as DMSO) (hereinafter referred to as aprotic polar solvents); water, and mixtures of two or more of them.

[0250] Examples of the base include alkali metal carbonates; and alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides).

[0251] In the reaction, relative to 1 mole of compound (M-3), compound (M-4) is usually used in a ratio of 0.8 to 1.2 moles, and the base is usually used in a ratio of 1 to 3 moles.

[0252] The reaction temperature is usually in the range of -20 to 200 °C. The reaction time is usually in the range of 0.5 to 24 hours.

[0253] After the reaction is completed, water can be added to the reaction mixture, and then extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the obtained organic layer are performed to obtain compound (I-a).

[0254] Compound (M-3) is known or can be produced according to the methods described in, for example, International Publication No. 2018 / 008727, International Publication No. 2019 / 131575, or International Publication No. 2019 / 131587.

[0255] Production method 3

[0256] Compound (I-a) can also be produced by reacting compound (M-3) with a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) in the presence of a metal catalyst.

[0257] [Chemical formula 8]

[0258]

[0259] [In the formula, X a represents a chlorine atom, a bromine atom or an iodine atom, and the other symbols have the same meanings as described above.]

[0260] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents and mixtures of two or more thereof.

[0261] Examples of the metal catalyst include copper catalysts such as copper(I) iodide, copper(I) bromide, copper(I) chloride, copper(I) oxide, copper(I) trifluoromethanesulfonate benzene complex, copper(I) tetraethylacetonitrile hexafluorophosphate, copper(I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel(0), nickel(II) chloride; palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(II), etc.

[0262] In the reaction, relative to 1 mole of compound (M-3), compound (M-5) is usually used in a ratio of 0.8 to 1.2 moles, and the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles.

[0263] In the reaction, a ligand can be used as needed. Examples of the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthalene, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, N,N'-dimethylethylenediamine, etc. When a ligand is used in the reaction, relative to 1 mole of compound (M-3), the ligand is usually used in a ratio of 0.01 to 0.5 moles.

[0264] In the reaction, a base can be used as needed. Examples of the base include organic bases such as tertiary amines and nitrogen-containing aromatic compounds (hereinafter referred to as organic bases); alkali metal carbonates and alkali metal hydrides.

[0265] When a base is used in the reaction, the base is usually used in a proportion of 1 to 3 moles relative to 1 mole of the compound (M-3).

[0266] The reaction temperature is usually in the range of -20°C to 150°C. The reaction time is usually in the range of 0.5 to 24 hours.

[0267] After the reaction is completed, water can be added to the reaction mixture, and extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the organic layer are carried out to obtain the compound (I-a).

[0268] Production Method 4

[0269] The compound represented by the formula (I-b) (hereinafter referred to as the compound (I-b)) can be produced by reacting the compound represented by the formula (M-6) (hereinafter referred to as the compound (M-6)) with the compound (M-5) in the presence of a metal catalyst.

[0270] [Chemical Formula 9]

[0271]

[0272] [In the formula, Het B represents the group represented by the formula Het1, the group represented by the formula Het2, or the group represented by the formula Het4, M represents 9-borabicyclo[3.3.1]nonan-9-yl, dihydroxyboron group, 4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl, tributylstannyl group, or ZnCl, and other symbols have the same meanings as described above.]

[0273] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; aprotic polar solvents; water, and mixtures of two or more of them.

[0274] Examples of the metal catalyst include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocene dichloropalladium(II), tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetonate; and copper catalysts such as copper(I) iodide and copper(I) chloride.

[0275] In the reaction, a ligand, a base, and / or an inorganic halide can be used as needed.

[0276] Examples of the ligand include triphenylphosphine, Xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthalene, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, and the like.

[0277] Examples of the base include, for example, alkali metal hydrides; alkali metal carbonates; and organic bases.

[0278] Examples of the inorganic halide include alkali metal fluorides such as potassium fluoride and sodium fluoride; and alkali metal chlorides such as lithium chloride and sodium chloride.

[0279] In the reaction, relative to 1 mole of the compound (M-6), the compound (M-5) is usually used in a ratio of 1 to 10 moles, and the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles. When a ligand is used in the reaction, relative to 1 mole of the compound (M-6), the ligand is usually used in a ratio of 0.01 to 1 mole. When a base is used in the reaction, relative to 1 mole of the compound (M-6), the base is usually used in a ratio of 0.1 to 5 moles. When an inorganic halide is used in the reaction, relative to 1 mole of the compound (M-6), the inorganic halide is usually used in a ratio of 0.1 to 5 moles.

[0280] The reaction temperature is usually in the range of -20°C to 200°C. The reaction time is usually in the range of 0.1 to 24 hours.

[0281] After the reaction is completed, water can be added to the reaction mixture, and extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the organic layer are then carried out to obtain the compound (I-b).

[0282] The compound (M-6) is known or can be produced according to, for example, the method described in International Publication No. 2018 / 221720.

[0283] Reference Production Method 1

[0284] The compound (M-1) can be produced by reacting the compound represented by the formula (M-7) (hereinafter referred to as the compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0285] [Chemical Formula 10]

[0286]

[0287] [In the formula, the symbols represent the same meanings as described above. ]

[0288] The reaction can be carried out in a solvent as required. Examples of the solvent used in the reaction include ethers; aromatic hydrocarbons and mixtures of two or more of them.

[0289] Examples of the chlorinating agent include phosphoryl chloride and thionyl chloride.

[0290] In the reaction, relative to 1 mole of the compound (M-7), chlorosulfonic acid is usually used in a ratio of 1 to 10 moles, and the chlorinating agent is usually used in a ratio of 1 to 10 moles.

[0291] The reaction temperature is usually in the range of -20°C to 200°C. The reaction time is usually in the range of 0.1 to 24 hours.

[0292] After the reaction is completed, water can be added to the reaction mixture, and extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the organic layer are carried out to obtain the compound (M-1).

[0293] The compound (M-7) is known or can be prepared according to the methods described in, for example, International Publication No. 2018 / 008727, International Publication No. 2018 / 221720, International Publication No. 2019 / 131575, or International Publication No. 2019 / 131587.

[0294] Reference Production Method 2

[0295] The compound represented by the formula (M-9) (hereinafter referred to as the compound (M-9)) can be prepared by reacting the compound represented by the formula (M-8) (hereinafter referred to as the compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0296] [Chemical Formula 11]

[0297]

[0298] [In the formula, the symbols represent the same meanings as described above.]

[0299] The reaction can be carried out using the compound (M-8) instead of the compound (M-7) according to the method described in Reference Production Method 1.

[0300] The compound (M-8) is a commercially available compound or can be prepared using known methods.

[0301] Reference Production Method 3

[0302] The compound (M-5) can be prepared by reacting the compound (M-9) with the compound (M-2).

[0303] [Chemical Formula 12]

[0304]

[0305] [In the formula, the symbols represent the same meanings as described above.]

[0306] The reaction can be carried out using compound (M-9) instead of compound (M-1) according to the method described in Production Method 1.

[0307] Reference Production Method 4

[0308] Compound (M-4) can be produced by reacting compound (M-5) with a fluorinating agent.

[0309] [Chemical Formula 13]

[0310]

[0311] [In the formula, the symbols represent the same meanings as described above.]

[0312] The reaction is usually carried out in a solvent. Examples of the solvent include aromatic hydrocarbons; aprotic polar solvents; and mixtures of two or more of them.

[0313] Examples of the fluorinating agent include cesium fluoride and potassium fluoride.

[0314] In the reaction, the fluorinating agent is usually used in a ratio of 1 to 10 moles relative to 1 mole of compound (M-5).

[0315] The reaction temperature is usually in the range of 20°C to 300°C. The reaction time is usually in the range of 0.1 to 24 hours.

[0316] After completion of the reaction, water can be added to the reaction mixture, and extraction can be carried out using an organic solvent. Post-treatment operations such as drying and concentrating the organic layer are carried out to obtain compound (M-4).

[0317] The compound of the present invention can be mixed or used in combination with one or more components (hereinafter referred to as this component) selected from the group consisting of the following group (a), group (b), group (c), and group (d).

[0318] The aforementioned mixing or combination means that the compound of the present invention and this component are used simultaneously, separately, or at intervals of time.

[0319] When the compound of the present invention and this component are used simultaneously, the compound of the present invention and this component can be contained in separate preparations, or can be contained in the same preparation.

[0320] One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) (i.e., the present component) and a compound of the present invention.

[0321] Group (a) is a group consisting of acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphorus insecticides), GABA-gated chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), allosteric modulators of nicotinic acetylcholine receptors, allosteric modulators of glutamate-gated chloride channels (e.g., macrolide insecticides), juvenile hormone mimetics, multi-site inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, insect midgut epithelial disruptors derived from microorganisms, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport chain complexes I, II, III, and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ modulators, microbial insecticides, and other insecticidal active ingredients, acaricidal active ingredients, and nematicidal active ingredients. These components are listed according to the classification of the mode of action based on IRAC.

[0322] Group (b) is a group consisting of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acyl amino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-site contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These components are listed according to the classification of the mode of action based on FRAC.

[0323] Group (c) is a group of plant growth regulating components (including mycorrhizal fungi and rhizobia).

[0324] Group (d) is a group of repellent components.

[0325] Examples of the combination of the present component and the compound of the present invention are described below. For example, alanycarb + SX means the combination of alanycarb and SX.

[0326] It should be noted that the abbreviation SX refers to any one of the compounds of the present invention selected from the compound groups SX1 to SX540. In addition, the components described below are all known components, which can be obtained from commercially available preparations or manufactured by known methods. When the component is a microorganism, it can also be obtained from a microorganism preservation institution. It should be noted that the numbers in parentheses represent CAS RN (registered trademark).

[0327] The combination of the component of the above group (a) and the compound of the present invention:

[0328] Abamectin + SX, Acephate + SX, Acequinocyl + SX, Acetamiprid + SX, Acetoprole + SX, Acrinathrin + SX, Acynonapyr + SX, Afidopyropen + SX, Afoxolaner + SX, Alanycarb + SX, Aldicarb + SX, Allethrin + SX, Alpha - Cypermethrin + SX, Alpha - Endosulfan + SX, Aluminium Phosphide + SX, Amitraz + SX, Azadirachtin + SX, Azamethiphos + SX, Azinphos - ethyl + SX, Azinphos - methyl + SX, Azocyclotin + SX, Bark of Celastrus angulatus + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta - Cyfluthrin + SX, Beta - Cypermethrin + SX, Bifenazate + SX, Bifenthrin + SX, Bioallethrin + SX, Bioresmethrin + SX, Bistrifluron + SX, Borax + SX, Boric Acid + SX, Broflanilide + SX, Bromopropylate + SX, Buprofezin + SX, Butocarboxim + SX, Butoxycarboxim + SX, Cadusafos + SX, Calcium Phosphidephosphide)+SX, carbaryl+SX, carbofuran+SX, carbosulfan+SX, cartap hydrochloride+SX, cartap+SX, chinomethionat+SX, chlorantraniliprole+SX, chlordane+SX, chlorethoxyfos+SX, chlorfenapyr+SX, chlorfenvinphos+SX, chlorfluazuron+SX, chlormephos+SX, chloropicrin+SX, chlorpyrifos+SX, chlorpyrifos-methyl+SX, chromafenozide+SX, clofentezine+SX, clothianidin+SX, concanamycinA) +SX, coumaphos+SX, cryolite+SX, cyanophos+SX, cyantraniliprole+SX, cyclaniliprole+SX, cyclobutrifluram+SX, cycloprothrin+SX, cycloxaprid+SX, cyenopyrafen+SX, cyetpyrafen+SX, cyflumetofen+SX, cyfluthrin+SX, cyhalodiamide+SX, cyhalothrin+SX, cyhexatin+SX, cypermethrin+SX, cyphenothrin+SX, cyproflanilide+SX, cyromazine+SX, dazomet+SX, deltamethrin+SX, demeton-S-methyl+SX, diafenthiuron+SX, diazinon+SX, dichlorvos+SX, dicloromezotiaz+SX, dicofol+SX, dicrotophos+SX, diflovidazin+SX, diflubenzuron+SX, dimefluthrin+SX, dimethoate+SX, dimethylvinphos+SX, dimpropyridaz+SX, dinotefuran+SX, disodium octaborate+SX, disulfoton+SX, DNOC (2-methyl-4,6-dinitrophenol+SX, doramectin+SX, dried leaves of Dryopterisfilix-mas)+SX, emamectin-benzoate)+SX, empenthrin)+SX, endosulfan)+SX, EPN (O-ethyl O-(4-nitrophenyl)phenylphosphonothioate)+SX, epsilon-metofluthrin)+SX, epsilon-momfluorothrin+SX, esfenvalerate)+SX, ethiofencarb)+SX, ethion)+SX, ethiprole)+SX, ethoprophos)+SX, etofenprox)+SX, etoxazole)+SX, extract of Artemisia absinthium)+SX, extract of Azadirachta indica)+SX, extract of Cassia nigricans)+SX, extract of clitoria ternatea)+SX, extract of Symphytum officinale)+SX, extract of Chenopodium ambrosioides)+SX, extract of Tanacetum vulgare)+SX, extract of Urtica dioica)+SX, extract of Viscum album)+SX, famphur)+SX, fenamiphos)+SX, fenazaquin)+SX, fenbutatinoxide)+SX, fenitrothion+SX, fenmezoditiaz+SX, fenobucarb+SX, fenoxycarb+SX, fenpropathrin+SX, fenpyroximate+SX, fenthion+SX, fenvalerate+SX, fipronil+SX, flometoquin+SX, flonicamid+SX, fluacrypyrim+SX, fluazaindolizine+SX, fluazuron+SX, flubendiamide+SX, fluchlordiniliprole+SX, flucycloxuron+SX, flucythrinate+SX, fluensulfone+SX, flufenoprox+SX, flufenoxuron+SX, flufiprole+SX, flumethrin+SX, flupentiofenox+SX, flupyradifurone+SX, flupyrimin+SX, flupyroxystrobin+SX, fluralaner+SX, fluvalinate+SX, fluxametamide+SX, formetanate+SX, fosthiazate+SX, furamethrin+SX, furathiocarb+SX, gamma-cyhalothrin+SX, GS-omega / kappa HXTX-Hv1a peptide+SX, halfenprox+SX, halofenozide+SX, heptafluthrin+SX, heptenophos+SX, hexaflumuron+SX, hexythiazox+SX, potassium salt ofhop betaacid)+SX, hydramethylnon)+SX, hydroprene)+SX, imicyafos)+SX, imidacloprid)+SX, imidaclothiz)+SX, imiprothrin)+SX, indazapyroxamet)+SX, indoxacarb)+SX, isocycloseram+SX, isofenphos)+SX, isoprocarb)+SX, isopropyl-O-(methoxyaminothiophosphoryl)salicylate)+SX, isoxathion)+SX, ivermectin)+SX, kadethrin)+SX, kappa-tefluthrin)+SX, kappa-bifenthrin)+SX, kinoprene)+SX, lambda-cyhalothrin)+SX, ledprona+SX, lenoremycin)+SX, lepimectin)+SX, lime sulfur)+SX, lotilaner)+SX, lufenuron)+SX, machine oil)+SX, malathion)+SX, mecarbam)+SX, meperfluthrin)+SX, metaflumizone)+SX, metam)+SX, methamidophos)+SX, methidathion)+SX, methiocarb)+SX, methomyl)+SX, methoprene)+SX, methoxychlor)+SX, methoxyfenozide)+SX, methyl bromide)+SX, metofluthrin)+SX, metolcarb)+SX, metoxadiazone)+SX, mevinphos)+SX, milbemectin)+SX, milbemycinoxime)+SX, mivorilaner+SX, flubendiamide (modoflaner)+SX, momfluorothrin+SX, monocrotophos+SX, moxidectin+SX, naled+SX, nicofluprole+SX, nicotine+SX, nicotine-sulfate+SX, nitenpyram+SX, novaluron+SX, noviflumuron+SX, oil of the seeds of Chenopodium anthelminticum+SX, omethoate+SX, oxamyl+SX, oxazosulfyl+SX, oxydemeton-methyl+SX, parathion+SX, parathion-methyl+SX, permethrin+SX, phenothrin+SX, phenthoate+SX, phorate+SX, phosalone+SX, phosmet+SX, phosphamidon+SX, phosphine+SX, phoxim+SX, pirimicarb+SX, pirimiphos-methyl+SX, prallethrin+SX, profenofos+SX, profluthrin+SX, propargite+SX, propetamphos+SX, propoxur+SX, propylene glycol alginate (propyleneglycolalginate)+SX, prothiofos)+SX, pyflubumide+SX, pymetrozine)+SX, pyraclofos)+SX, pyrethrins)+SX, pyridaben)+SX, pyridalyl)+SX, pyridaphenthion)+SX, pyrifluquinazone)+SX, pyrimidifen)+SX, pyriminostrobin)+SX, pyriprole)+SX, pyriproxyfen)+SX, quinalphos)+SX, resmethrin)+SX, rotenone)+SX, ryanodine)+SX, sarolaner)+SX, selamectin)+SX, sigma-cypermethrin)+SX, silafluofen)+SX, sodium borate)+SX, sodium metaborate)+SX, spidoxamat+SX, spinetoram)+SX, spinosad)+SX, spirobudifen)+SX, spirodiclofen)+SX, spiromesifen)+SX, spiropidion)+SX, spirotetramat)+SX, sulfiflumin)+SX, sulfluramid)+SX, sulfotep)+SX, sulfoxaflor)+SX, sulfur)+SX, sulfurylfluoride)+SX, tartar emetic)+SX, tau-fluvalinate)+SX, tebufenozide)+SX, tebufenpyrad)+SX, tebupirimfos)+SX, teflubenzuron)+SX, tefluthrin)+SX, temephos)+SX, terbufos)+SX, terpene components extracted from Chenopodium ambrosioidesConstituents of the extract of Chenopodium ambrosioides near Ambrosioides)+SX, tetrachlorantraniliprole+SX, tetrachlorvinphos+SX, tetradifon+SX, tetramethrin+SX, tetramethylfluthrin+SX, tetraniliprole+SX, theta-cypermethrin+SX, thiacloprid+SX, thiamethoxam+SX, thiocyclam+SX, thiodicarb+SX, thiofanox+SX, thiometon+SX, thiosultap-disodium+SX, thiosultap-monosodium+SX, tigolaner+SX, tiorantraniliprole+SX, tioxazafen+SX, tolfenpyrad+SX, tralomethrin+SX, transfluthrin+SX, triazamate+SX, triazophos+SX, trichlorfon+SX, trifluenfuronate+SX, triflumezopyrim+SX, triflumuron+SX, trimethacarb+SX, tyclopyrazoflor+SX, umifoxolaner+SX, vamidothion+SX, wood extract of Quassia amara+SX, XMC (3,5-dimethylphenyl N-methylcarbamate, N-methylaminocarbamate of 3,5-dimethylphenyl)+SX, xylylcarb+SX, zeta-cypermethrin+SX, zinc phosphide(zincphosphide) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}inden-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methylsulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methylsulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methylsulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylthio)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methylsulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, BT crop protein Cry1Ab + SX, BT crop protein Cry1Ac + SX, BT crop protein Cry1Fa + SX, BT cropprotein Cry1Fa)+SX, BT crop protein Cry1A.105)+SX, BT crop protein Cry2Ab)+SX, BT crop protein Vip3A)+SX, BT crop protein mCry3A)+SX, BT crop protein Cry3Ab)+SX, BT crop protein Cry3Bb)+SX, BT crop protein Cry34Ab1 / Cry35Ab1)+SX, Adoxophyes orana GV (granulovirus) strain BV-0001)+SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus))+SX, Autographa californica MNPV)+SX, Cydia pomonella GV strain V15)+SX, Cydia pomonella GV strain V22)+SX, Cryptophlebia leucotreta GV)+SX, Dendrolimus punctatus cypovirus)+SX, Helicoverpa armigera NPV (nucleopolyhedrovirus) strain BV-0003)+SX, Helicoverpa zea NPV)+SX, Lymantria dispar NPV)+SX, Mamestra brassicae NPV)+SX, Mamestra configurata NPV)+SX, Neodiprion abietisNPV) + SX, Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Nosema locustae + SX, Orgyia pseudotsugata NPV + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Spodoptera exigua MNPV + SX, Spodoptera littoralis MNPV + SX, Spodoptera litura NPV + SX, Arthrobotrys dactyloides + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus megaterium + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX,CR-371)+SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857)+SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52)+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91)+SX, Bacillus thuringiensis subsp. Aizawaistrain NB200)+SX, Bacillus thuringiensis subsp. Aizawai Serotype strain H-7)+SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351)+SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123)+SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306)+SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348)+SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841)+SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19)+SX, Bacillus thuringiensis subsp. Kurstaki strain F810)+SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1strain HD-1)+SX, Bacillus thuringiensis subsp. Kurstaki strain PB54)+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11)+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12)+SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176)+SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002)+SX, Bacillus thuringiensis subsp. morrisoni)+SX, Bacillus thuringiensis var. colmeri)+SX, Bacillus thuringiensis var. darmstadiensis strain 24-91)+SX, Bacillus thuringiensis var. dendrolimus)+SX, Bacillus thuringiensis var. galleriae)+SX, Bacillus thuringiensis var. israelensis strain BMP144)+SX, Bacillus thuringiensis var. israelensis serotype strain H-14)+SX, Bacillus thuringiensis var. japonensis strain buibui)+SX, Bacillus thuringiensis var. sandiego strain M-7)+SXM-7)+SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. aegypti + SX, Bacillus thuringiensis var. T36 + SX, Beauveria bassiana strain ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain GHA + SX, Beauveria brongniartii + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Dactyllela ellipsospora + SX, Dectylaria thaumasia + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Lagenidium giganteum + SX, Lecanicillium lecanii strain KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX, Lecanicillium muscarium strain Ve6 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae var. acridum + SX, Metarhizium anisopliae var. anisopliae microspora BIPESCO5 / F52 strain (Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52) + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawa strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae + SX, Pasteuria thornei + SX, Serratia entomophila + SX, Verticillium chlamydosporium + SX, Verticillium lecanii strain NCIM1312 + SX, Wolbachia pipientis + SX.

[0329] The combination of the component of the above group (b) and the compound of the present invention:

[0330] Acibenzolar-S-methyl + SX, Aldimorph + SX, Ametoctradin + SX, Aminopyrifen + SX, Amisulbrom + SX, Anilazine + SX, Azaconazole + SX, Azoxystrobin + SX, Basic copper sulfate + SX, Benalaxyl + SX, Benalaxyl-M + SX, Benodanil + SX, Benomyl + SX, Benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, Benzovindiflupyr + SX, Binapacryl + SX, Biphenyl + SX, Bitertanol + SX, Bixafen + SX, Blasticidin-S + SX, Bordeaux mixture + SX, Boscalid + SX, Bromothalonil + SX, Bromuconazole + SX, Bupirimate + SX, Captafol + SX, Captan + SX, Carbendazim + SX, Carboxin + SX, Carpropamid + SX, Chinomethionat + SX, Chitin + SX, Chloroinconazide + SX, Chloroneb + SX, Chlorothalonil + SX, Chlozolinate + SX, Colletochlorin B + SX, Copper(II)acetate + SX, Copper(II)hydroxide + SX, Copperoxychloride + SX, Copper(II)sulfate + SX, Coumoxystrobin + SX, Cyazofamid + SX, Cyflufenamid + SX,Cymoxanil + SX, Cyproconazole + SX, Cyprodinil + SX, Dichlobentiazox + SX, Dichlofluanid + SX, Diclocymet + SX, Diclomezine + SX, Dicloran + SX, Diethofencarb + SX, Difenoconazole + SX, Diflumetorim + SX, Dimethachlone + SX, Dimethirimol + SX, Dimethomorph + SX, Dimoxystrobin + SX, Diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogenphosphite + SX, Dipymetitrone + SX, Dithianon + SX, Dodecylbenzenesulphonic acid bisethylenediamine copper(II)salt + SX, Dodemorph + SX, Dodine + SX, Edifenphos + SX, Enoxastrobin + SX, Epoxiconazole + SX, Etaconazole + SX, Ethaboxam + SX, Ethirimol + SX, Etridiazole + SX, Extract of Allium sativum + SX, Extract of the cotyledons of lupine plantlets (“BLAD”) + SX, Extract of Equisetum arvense + SX, Extract of Melaleuca alternifolia + SX, Extract of Reynoutria sachalinensis + SX, Extract of Tropaeolum majus + SXFamoxadone + SX, Fenamidone + SX, Fenaminstrobin + SX, Fenarimol + SX, Fenbuconazole + SX, Fenfuram + SX, Fenhexamid + SX, Fenoxanil + SX, Fenpiclonil + SX, Fenpicoxamid + SX, Fenpropidin + SX, Fenpropimorph + SX, Fenpyrazamine + SX, Fentin acetate, Fentinchloride, Fentin hydroxide, Ferbam, Ferimzone, Florylpicoxamid, Fluazinam, Flubeneteram, Fludioxonil, Flufenoxadiazam, Flufenoxystrobin, Fluindapyr, Flumetylsulforim, Flumorph, Fluopicolide, Fluopyram, Fluopimomide, Fluoroimide, Fluoxapiprolin, Fluoxastrobin, Fluoxytioconazole, Fluquinconazole, Flusilazole, Flusulfamide, Flutianil, Flutolanil, Flutriafol, Fluxapyroxad, Folpet, Fosetyl, Fosetyl - aluminium, Fuberidazole, Furalaxyl, Furametpyr, GuazatineHexaconazole + SX, Hymexazole + SX, Imazalil + SX, Imibenconazole + SX, Iminoctadine + SX, Iminoctadine triacetate + SX, Inpyrfluxam + SX, Iodocarb + SX, Ipconazole + SX, Ipflentrifluconazole + SX, Ipflufenoquin + SX, Iprobenfos + SX, Iprodione + SX, Iprovalicarb + SX, Isofetamid + SX, Isoflucypram + SX, Isoprothiolane + SX, Isopyrazam + SX, Isotianil + SX, Kasugamycin + SX, Kresoxim-methyl + SX, Laminarin + SX, Leaves and bark of Quercus + SX, Mancozeb + SX, Mandestrobin + SX, Mandipropamid + SX, Maneb + SX, Mefentrifluconazole + SX, Mepanipyrim + SX, Mepronil + SX, Meptyldinocap + SX, Metalaxyl + SX, Metalaxyl-M + SX, Metarylpicoxamid + SX, Metconazole + SX, Methasulfocarb + SX, Metiram + SX, Metominostrobin + SX, Metrafenone + SX, Metyltetraprole + SX, Myclobutanil + SX, Naftifine + SX, Nuarimol + SX, Octhilinone + SX, Ofurace + SX, Orysastrobin + SX, Oxadixyl + SX,Oxathiapiprolin + SX, Oxine - copper + SX, Oxolinic acid + SX, Oxpoconazole + SX, Oxpoconazole fumarate + SX, Oxycarboxin + SX, Oxytetracycline + SX, Pefurazoate + SX, Penconazole + SX, Pencycuron + SX, Penflufen + SX, Penthiopyrad + SX, Phenamacril + SX, Phosphorous acid + SX, Phthalide + SX, Picarbutrazox + SX, Picoxystrobin + SX, Piperalin + SX, Polyoxins + SX, Potassium hydrogencarbonate + SX, Potassium dihydrogenphosphite + SX, Probenazole + SX, Prochloraz + SX, Procymidone + SX, Propamidine + SX, Propamocarb + SX, Propiconazole + SX, Propineb + SX, Proquinazid + SX, Prothiocarb + SX, Prothioconazole + SX, Pydiflumetofen + SX, Pyraclostrobin + SX, Pyrametostrobin + SX, Pyraoxystrobin + SX, Pyrapropoyne + SX, Pyraziflumid + SX, Pyrazophos + SX, Pyribencarb + SX, Pyributicarb + SX, Pyridachlometyl + SX, Pyrifenox + SX, Pyrimethanil + SX, Pyrimorph + SX,Pyriofenone + SX, Pyrisoxazole + SX, Pyroquilon + SX, Quillaja extract + SX, Quinconazole + SX, Quinofumelin + SX, Quinoxyfen + SX, Quintozene + SX, Saponins of Chenopodium quinoa + SX, Seboctylamine + SX, Sedaxane + SX, Silthiofam + SX, Simeconazole + SX, Sodium hydrogencarbonate + SX, Spiroxamine + SX, Streptomycin + SX, Sulfur + SX, Tebuconazole + SX, Tebufloquin + SX, Teclofthalam + SX, Tecnazene + SX, Terbinafine + SX, Tetraconazole + SX, Thiabendazole + SX, Thifluzamide + SX, Thiophanate + SX, Thiophanate-methyl + SX, Thiram + SX, Thymol + SX, Tiadinil + SX, Tolclofos-methyl + SX, Tolfenpyrad + SX, Tolprocarb + SX, Tolylfluanid + SX, Triadimefon + SX, Triadimenol + SX, Triazoxide + SX, Triclopyricarb + SX, Tricyclazole + SX, Tridemorph + SX, Trifloxystrobin + SX, Triflumizole + SX, Triforine + SX, Triticonazole + SX, Validamycin + SX, Valifenalate + SX,Vinclozolin + SX, Yellow mustard powder + SX, Zinc thiazole + SX, Zineb + SX, Ziram + SX, Zoxamide + SX, N’-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylformamidine (1202781-91-6) + SX, N’-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylformamidine (929908-57-6) + SX, N’-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylformamidine (1052688-31-9) + SX, N’-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylformamidine (2055589-28-9) + SX, N’-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylformamidine (2055756-21-1) + SX, N’-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylformamidine (2062599-39-5) + SX, N’-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylformamidine (2101814-55-3) + SX, N’-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylformamidine (1817828-69-5) + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, (2Z)-Ethyl 3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX,(1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX,2-(Difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(Difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethylsulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SXN-[(3-Hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(4-bromo-7-fluoro-1H-indol-1-yl)butan-2-yl ester + SX, N-[(3-Hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-1H-indol-1-yl)butan-2-yl ester + SX, N-[(3-Hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-4-fluoro-1H-indol-1-yl)butan-2-yl ester + SX, N-[(3-Hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(3,5-dichloropyridin-2-yl)butan-2-yl ester + SX, N-{[3-(Acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine 3-(3,5-dichloropyridin-2-yl)butan-2-yl ester + SX, N-[(3-Hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate) + SX, N-[(3-Acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate) + SX, N-{[3-(Acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate) + SX, N-({4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-Allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-Allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(Trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX3,3,3-Trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N’-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N’-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N’-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylic acid ethyl ester + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SXN-Methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + SX, methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate + SX, ethyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate + SX, methyl 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX, 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX2-[Cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[Cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[Acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-Methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-Methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-Difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxolane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(Oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(Difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX3-[3-(3-Cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-Cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-Chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-Chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-Chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-Chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-Fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-Fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-Fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-Methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-Fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX({5-[1-(2,6-Difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)methyl carbamate + SX, ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)methyl carbamate + SX, ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)methyl carbamate + SX, (Z)-Methyl 2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyacrylate + SX, (Z)-Methyl 2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyacrylate + SX, (Z)-Methyl 2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyacrylate + SX, 1-(4,5-Dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-Dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(Pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-Dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, (2Z)-Methyl 3-methoxy-2-[(4-methyl[1,1'-biphenyl]-3-yl)oxy]acrylate + SX, Agrobacterium radiobactor strain K1026, Agrobacterium radiobactor strain K84, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (trademark) EZ Nematicide), Bacillus amyloliquefaciens strain AT332, Bacillus amyloliquefaciens strain B3, Bacillus amyloliquefaciens strain D747, Bacillus amyloliquefaciens strain DB101Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus simplex strain CGF2856 + SXBacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus subtilis strain Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin strain J82 + SXBurkholderia cepacia type Wisconsin strain M54 + SX, biocontrol yeast Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-8 + SX, Cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Fusarium oxysporum strain Fo47 + SX, Gliocladium catenulatum strain J1446 + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Pantoea agglomerans strain E325 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SXPseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain MA-4 + SX, Pseudozyma flocculosa PF-A22UL strain + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum SKT-1 + SX, Trichoderma asperellum strain T25 + SXTrichoderma asperellum strain T34 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harzianum strain 21 + SX, Trichoderma harzianum strain DB104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain kd + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain SF + SXTrichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma polysporum strain IMI206039 + SX, Trichoderma stromaticum + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus strain CGF4526 + SX, Harpin protein + SX.

[0331] The combination of the component of the above group (c) and the compound of the present invention:

[0332] 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, cholinechloride)+SX, cloprop)+SX, cyanamide)+SX, cyclanilide)+SX, daminozide)+SX, decan-1-ol)+SX, dichlorprop)+SX, dikegulac)+SX, dimethipin)+SX, diquat)+SX, ethephon)+SX, ethychlozate)+SX, flumetralin)+SX, flurprimidol)+SX, forchlorfenuron)+SX, formononetin)+SX, Gibberellin A)+SX, GibberellinA3)+SX, inabenfide)+SX, Kinetin)+SX, lipochitooligosaccharide)SP104+SX, maleic hydrazide)+SX, mefluidide)+SX, mepiquat-chloride)+SX, oxidizedglutathione)+SX, paclobutrazol)+SX, pendimethalin)+SX, prohexadione-calcium)+SX, prohydrojasmon)+SX, pyraflufen-ethyl)+SX, sintofen)+SX, sodium 1-naphthaleneacetate)+SX, sodium cyanate)+SX, thidiazuron)+SX, triapenthenol)+SX, tribufos)+SX, trinexapac-ethyl)+SX, uniconazole-P)+SX, 2-(naphthalen-1-yl)acetamide)+SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid+SX, methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate+SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol+SX, Claroideoglomusetunicatum)+SX, Claroideoglomus claroideum)+SX, Funneliformis mosseae)+SX, Gigaspora margarita)+SX, Gigaspora rosea)+SX, Glomus aggregatum)+SX, Glomus deserticola)+SX, Glomusmonosporum)+SX, Paraglomus brasillianum)+SX, Rhizophagusclarus)+SX, Rhizophagus intraradices strain RTI-801+SX, Rhizophagus irregularis strain DAOM 197198+SX, Azorhizobiumcaulinodans)+SX, Azospirillum amazonense)+SX, Azospirillum brasilense strain XOH+SX, Azospirillum brasilense Ab-V5 strain+SX, Azospirillum brasilense Ab-V6 strain+SX, Azospirillum caulinodans+SX, Azospirillumhalopraeferens)+SX, Azospirillum irakense)+SX, Azospirillumlipoferum)+SX, Bradyrhizobium elkanii strain SEMIA 587+SX, Bradyrhizobium SEMIA 5019 strain+SX, Bradyrhizobiumjaponicum strain TA-11+SX, Bradyrhizobium japonicum USDA 110 strain+SX, Bradyrhizobium liaoningense)+SX, Bradyrhizobium lupini)+SX, Delftia acidovorans strain RAY209+SX, Mesorhizobiumciceri)+SX, Mesorhizobium huakuiiHuakii)+SX, Mesorhizobium loti)+SX, Rhizobium etli)+SX, Rhizobium galegae)+SX, Rhizobium leguminosarum bv. Phaseoli)+SX, Rhizobium leguminosarum bv. Trifolii)+SX, Rhizobium leguminosarum bv. Viciae)+SX, Rhizobium trifolii)+SX, Rhizobium tropici)+SX, Sinorhizobium fredii)+SX, Sinorhizobium meliloti)+SX, Zucchini Yellow Mosaik Virus weak strain)+SX.

[0333] The combination of the present component of group (d) and the compound of the present invention:

[0334] Anthraquinone)+SX, Deet)+SX, Icaridin)+SX.

[0335] The ratio of the compound of the present invention to the present component is not particularly limited, and examples thereof include 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, etc. in terms of weight ratio (compound of the present invention: present component).

[0336] The compound of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following animals.

[0337] Hemiptera: Delphacidae such as Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, Peregrinus maidis, Javesella pellucida, Perkinsiella saccharicida, Tagosodes orizicolus, Stenocranus pacificus, etc.; Cicadellidae such as Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Empoasca onukii, Empoasca fabae, Dalbulus maidis, Cofana spectra, Amrasca biguttula biguttula, etc.; Aphrophoridae such as Philaenus spumarius; Cercopidae such as Mahanarva posticata, Mahanarva fimbriolata, etc.Aphididae such as Aphisfabae, Aphis glycines, Aphis gossypii, Aphis pomi, Aphis spiraecola, Myzus persicae, Brachycaudus helichrysi, Brevicoryne brassicae, Dysaphis plantaginea, Lipaphis erysimi, Macrosiphum euphorbiae, Aulacorthum solani, Nasonovia ribisnigri, Rhopalosiphumpadi, Rhopalosiphum maidis, Toxoptera citricida, Hyalopterus pruni, Melanaphis sacchari, Tetraneuranigriabdominalis, Ceratovacuna lanigera, Eriosomalanigerum, Sitobion avenae, etc.; Phylloxeridae such as Daktulosphaira vitifoliae, Phylloxera devastatrix, Phylloxera notabilis, Phylloxera russelae, etc.; Adelgidae such as Adelges tsugae, Adelges piceae, Aphrastasia pectinatae, etc.;Pentatomidae such as Scotinophara lurida, Scotinophara coarctata, Nezara antennata, Eysarcoris aeneus, Eysarcoris lewisi, Eysarcoris ventralis, Eysarcoris annamita, Halyomorpha halys, Nezara viridula, Euschistus heros, Piezodorus guildinii, Oebalus pugnax, Dichelops melacanthus, Piezodorus hybneri, etc.; Cydnidae such as Scaptocoris castanea, etc.; Alydidae such as Riptortus clavatus, Leptocorisa chinensis, Leptocorisa acuta, etc.; Coreidae such as Cletus punctiger, Leptoglossus australis, etc.; Lygaeidae such as Cavelerius saccharivorus, Togohemipterus, Blissus leucopterus, etc.; Miridae such as Trigonotylus caelestialium, Stenotus rubrovittatus, Stenodema calcarata, Lygus lineolaris, etc.; Aleyrodidae such as Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes citri, Aleurocanthus spiniferus, Aleurocanthus camelliae, Pealius euryae, etc.Scale insects of the family Diaspididae such as Abgrallaspis cyanophylli, Aonidiella aurantii, Diaspidiotus perniciosus, Pseudaulacaspis pentagona, Unaspis yanonensis, Unaspis citri, etc.; scale insects of the family Coccidae such as Ceroplastes rubens, etc.; scale insects of the family Margarodidae such as Icerya purchasi, Icerya seychellarum, etc.; scale insects of the family Pseudococcidae such as Phenacoccus solani, Phenacoccus solenopsis, Planococcus kraunhiae, Pseudococcus comstocki, Planococcus citri, Pseudococcus calceolariae, Pseudococcus longispinus, Brevennia rehi, etc.; psyllids of the family Psyllidae such as Diaphorina citri, Trioza erytreae, Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, Cacopsylla pyricola, etc.; lace bugs of the family Tingidae such as Corythucha ciliata, Corythucha marmorata, Stephanitis nashi, Stephanitis pyrioides, etc.; bed bugs of the family Cimicidae such as Cimex lectularius, Cimex hemipterus, etc.; cicadas of the family Cicadidae such as Quesada gigas, etc.Triatomine bugs such as Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, Rhodnius prolixus, etc. (Reduviidae);

[0338] Lepidoptera: Crambidae such as Chilo suppressalis, Chilopolychrysus, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmiapatnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, Ostrinia nubilalis, Hellulaundalis, Herpetogramma luctuosale, Parapediasiateterrellus, Nymphula depunctalis, Diatraea saccharalis, Leucinodes orbonalis, etc.; Pyralidae such as Elasmopalpuslignosellus, Plodia interpunctella, Euzophera batangensis, Cadra cautella, etc.Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestra brassicae, Sesamia inferens, Spodoptera mauritia, Naranga aenescens, Spodoptera frugiperda, Spodoptera exempta, Spodoptera cosmioides, Spodoptera eridania, Agrotis ipsilon, Agrotis segetum, Autographa nigrisigna, Plusia festucae, Chrysodeixis includens, Trichoplusia spp., Heliothis virescens and other Heliothis spp., Helicoverpa armigera, Helicoverpa zea and other Helicoverpa spp., Anticarsia gemmatalis, Alabama argillacea, Hydraecia immanis and other Noctuidae; Pieris rapae and other Pieridae;Tortricidae such as Grapholita molesta, Grapholita dimorpha, Leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes honmai, Homona magnanima, Archips fuscocupreanus, Cydia pomonella, Tetramoera schistaceana, Bean Shoot Borer (Epinotia aporema), Citripestis sagittiferella, Lobesia botrana, etc.; Gracillariidae such as Caloptilia theivora, Phyllonorycter ringoniella, etc.; Carposinidae such as Carposina sasakii, etc.; Lyonetiidae such as Leucoptera coffeella, Lyonetia clerkella, Lyonetia prunifoliella, etc.; Lymantriidae such as Lymantria dispar of Lymantria spp., Euproctis pseudoconspersa of Euproctis spp., etc.; Plutellidae such as Plutella xylostella, etc.; Gelechiidae such as Anarsia lineatella, Helcystogramma triannulella, Pectinophora gossypiella, Phthorimaea operculella, Tuta absoluta, etc.; Arctiidae such as Hyphantria cunea, etc.; Castniidae such as Telchin licus, etc.Cossidae such as Cossus insularis; Geometridae such as Ascotis selenaria; Limacodidae such as Parasalepida; Stathmopodidae such as Stathmopoda masinissa; Sphingidae such as Acherontia lachesis; Sesiidae such as Nokonaferalis, Synanthedon hector, Synanthedon tenuis; Hesperiidae such as Parnara guttata; Tineidae such as Tinea translucens, Tineola bisselliella.

[0339] Thysanoptera: Thripidae such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, Scirtothrips perseae; Phlaeothripidae such as Haplothrips aculeatus.

[0340] Diptera: Anthomyiidae such as Delia platura, Delia antiqua, Pegomya cunicularia, etc.; Ulidiidae such as Tetanops myopaeformis, etc.; Agromyzidae such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, Chromatomyia horticola, etc.; Chloropidae such as Chlorops oryzae, etc.; Tephritidae such as Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera latifrons, Bactrocera oleae, Bactrocera tryoni, Ceratitis capitata, Rhagoletis pomonella, Rhacochlaena japonica, etc.; Ephydridae such as Hydrellia griseola, Hydrellia philippina, Hydrellia sasakii, etc.; Drosophilidae such as Drosophila suzukii, Drosophila melanogaster, etc.; Phoridae such as Megaselia spiracularis, etc.; Psychodidae such as Clogmia albipunctata, etc.; Sciaridae such as Bradysia difformis, Bradysia odoriphaga, etc.; Cecidomyiidae such as Mayetiola destructor, Orseolia oryzae, etc.; Diopsidae such as Diopsis macrophthalma, etc.Glossina palpalis, Glossina morsitans, etc. of the family Glossinidae; Simulium japonicum, Simulium damnosum, etc. of the family Simuliidae; the subfamily Phlebotominae; Tipula aino, Tipula oleracea, Tipula paludosa, etc. of the family Tipulidae; Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles coluzzii, Anopheles albimanus, Anopheles sundai cus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus, etc. of the family Culicidae; Prosimulium yezoensis, Simulium ornatum, etc. of the family Simuliidae; Tabanus trigonus of the family Tabanidae; Musca domestica, Muscina stabulans, Stomoxys calcitrans, Haematobia irritans, etc. of the family Muscidae; the family Calliphoridae; the family Sarcophagidae;Chironomidae such as Chironomus plumosus, Chironomus yoshimatsui, Glyptotendipes tokunagai, etc.; Fannidae.

[0341] Coleoptera: Diabrotica spp. (such as Diabrotica virgifera virgifera, Diabrotica undecimpunctata howardi, Diabrotica barberi, Diabrotica virgifera zeae, Diabrotica balteata, Cucurbit Beetle (Diabrotica speciosa), etc.), Cerotoma trifurcata, Oulema melanopus, Aulacophora femoralis, Phyllotreta striolata, Phyllotreta cruciferae, Phyllotreta pusilla, Psylliodes chrysocephala, Psylliodes punctulata, Leptinotarsa decemlineata, Oulema oryzae, Colaspis brunnea, Chaetocnema pulicaria, Chaetocnema confinis, Epitrix cucumeris, Dicladispa armigera, Myochrous denticollis, Laccoptera quadrimaculata, Epitrix hirtipennis, Phaedon brassicae, Medythia nigrobilineata, etc. (Chrysomelidae); Seedcorn beetle (Stenolophus lecontei), Clivina impressifrons, etc. (Carabidae);Scarabaeidae such as Anomala cuprea, Anomala rufocuprea, Anomala albopilosa, Popillia japonica, Heptophyllapicea, Rhizotrogus majalis, Tomarus gibbosus, Holotrichia spp., Phyllophaga crinita and other Phyllophaga spp., Diloboderus abderus and other Diloboderus spp.; Anthriibidae such as Araecerus coffeae; Aponidae such as Cylas formicarius; Bruchidae such as Zabrotes subfasciatus; Scolytidae such as Tomicus piniperda, Hypothenemus hampei; Curculionidae such as Euscepes postfasciatus, Hypera postica, Sitophilus zeamais, Sitophilus oryzae, Sitophilus granarius, Echinocnemus squameus, Lissorhoptrus oryzophilus, Rhabdoscelus lineaticollis, Anthonomus grandis, Sphenophorus venatus, Sphenophorus callosus, Sternechus subsignatus, Sphenophorus levis, Scepticus griseus, Scepticus uniformis, Aracanthus mourei and other Aracanthus spp., Eutinobothrus brasiliensis and other Curculionidae;Tenebrionidae such as Tribolium castaneum, Tribolium confusum, Alphitobius diaperinus, etc.; Coccinellidae such as Epilachna vigintioctopunctata, etc.; Bostrychidae such as Lyctus brunneus, Rhizopertha dominica, etc.; Ptinidae; Cerambycidae such as Anoplophora malasiaca, Migdolus fryanus, Aromia bungii, etc.; Elateridae such as Melanotus okinawensis, Agriotes fuscicollis, Melanotus legatus, Anchastus spp., Conoderus spp., Ctenicera spp., Limonius spp., Aeolus spp., etc.; Staphylinidae such as Paederus fuscipes, etc.; Dermestidae such as Anthrenus verbasci, Dermestes maculates, Trogoderma granarium, etc.; Anobiidae such as Lasioderma serricorne, Stegobium paniceum, etc.; Laemophloeidae such as Cryptolestes ferrugineus, etc.; Silvanidae such as Oryzaephilus surinamensis, etc., Nitidulidae such as Brassicogethes aeneus, etc.

[0342] Orthoptera: Acrididae such as Locusta migratoria, Dociostaurus maroccanus, Chortoicetes terminifera, Nomadacris septemfasciata, Locustana pardalina, Anacridium melanorhodon, Calliptamus italicus, Melanoplus differentialis, Melanoplus bivittatus, Melanoplus sanguinipes, Melanoplus femurrubrum, Camnula pellucida, Schistocerca gregaria, Gastrimargus musicus, Austracris guttulosa, Oxya yezoensis, Oxya japonica, Patanga succincta, etc.; Gryllotalpidae such as Gryllotalpa orientalis; Gryllidae such as Acheta domestica, Teleogryllus emma; Tettigoniidae such as Anabrus simplex.

[0343] Hymenoptera: Tenthredinidae such as Athalia rosae, Athalia japonica; Solenopsis spp. such as Solenopsis invicta, Solenopsis geminata, Atta spp. such as Brown leaf-cutting ant (Attacapiguara), Acromyrmex spp., Paraponera clavata, Ochetellus glaber, Monomorium pharaonis, Linepithema humile, Formica japonica, Pristomyrmex punctutus, Pheidole noda, Pheidole megacephala, Camponotus japonicus, Camponotus obscuripes and other Camponotus spp., Pogonomyrmex occidentalis and other Pogonomyrmex spp., Wasmania auropunctata and other Wasmania spp., Anoplolepis gracilipes and other Formicidae; Vespidae such as Vespa mandarinia, Vespa simillima, Vespa analis, Vespa velutina, Polistes jokahamae; Siricidae such as Urocerus gigas; Bethylidae.

[0344] Order Blattodea: Ectobiidae such as Blattella germanica; Blattidae such as Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, Blatta orientalis; Termitidae such as Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes satsumensis, Glyptotermes nakajimai, Glyptotermes fuscus, Hodotermopsis sjostedti, Coptotermes guangzhouensis, Reticulitermes amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, Nasutitermes takasagoensis, Pericapritermes nitobei, Sinocapritermes mushae, Cornitermes cumulans.

[0345] Order Siphonaptera: Pulicidae such as Pulex irritans, Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Echidnophaga gallinacea; Hectopsyllidae such as Tunga penetrans; Ceratophyllidae such as Nosopsyllus fasciatus.

[0346] Psocodea: Pediculidae such as Pediculus humanus capitis; Pthiridae such as Pthirus pubis; Haematopinidae such as Haematopinus eurysternus and Haematopinus suis; Linognathidae such as Linognathus vituli, Linognathus ovillus, and Solenopotes capillatus; Bovicoliidae such as Bovicola bovis, Bovicola ovis, Bovicola breviceps, Damalinia forficula, and Werneckiella spp.; Trichodectidae such as Trichodectes canis and Felicola subrostratus; Menoponidae such as Menopon gallinae, Menacanthus stramineus, and Trinoton spp.; Trimenoponidae such as Cummingsia spp.; Trogiidae such as Trogium pulsatorium; Liposcelidae or Liposcelididae such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.

[0347] Thysanura: Lepismatidae such as Ctenolepisma villosa and Lepisma saccharina.

[0348] Order Acari: Tetranychidae such as Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp.; Eriophyidae such as Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus schlechtendali, Aceria diospyri, Aceria tosichella, Shevtchenkella sp.; Tarsonemidae such as Polyphagotarsonemus latus; Tenuipalpidae such as Brevipalpus phoenicis; Tuckerellidae;Hard ticks of the family Ixodidae such as Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus, Ixodes holocyclus, Ixodes ricinus, Amblyomma americanum, Amblyomma maculatum, Rhipicephalus microplus, Rhipicephalus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus decoloratus, etc.; soft ticks of the family Argasidae such as Argas persicus, Ornithodoros hermsi, Ornithodoros turicata, etc.; flour mites of the family Acaridae such as Tyrophagus putrescentiae, Tyrophagus similis, etc.; house dust mites of the family Pyroglyphidae such as Dermatophagoides farinae, Dermatophagoides pteronyssinus, etc.; predatory mites of the family Cheyletidae such as Cheyletus eruditus, Cheyletus malaccensis, Chelacaropsis moorei, Cheyletiella yasguri, etc.Psoroptidae such as Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, Chorioptes spp.; Sarcoptidae such as Notoedres cati, Notoedres muris, Sarcoptes scabiei; Listrophoridae such as Listrophorus gibbus; Dermanyssidae such as Dermanyssus gallinae; Macronyssidae such as Ornithonyssus sylviarum, Ornithonyssus bacoti; Varroidae such as Varroa jacobsoni; Demodicidae such as Demodex canis, Demodex cati; Trombiculidae such as Leptotrombidium akamushi, Leptotrombidium pallidum, Leptotrombidium scutellare.

[0349] Araneae: Eutichuridae such as Cheiracanthium japonicum; Theridiidae such as Latrodectus hasseltii.

[0350] Polydesmida: Paradoxosomatidae such as Oxidus gracilis, Nedyopus tambanus.

[0351] Isopoda: Armadillidiidae such as Armadillidium vulgare.

[0352] Chilopoda: Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus.

[0353] Gastropoda: Limacidae such as Limax marginatus and Limax flavus; Philomycidae such as Meghimatium bilineatum; Ampullariidae such as Pomacea canaliculata; Lymnaeidae such as Austropeplea ollula.

[0354] Nematoda: Aphelenchoididae such as Aphelenchoides besseyi; Pratylenchidae such as Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, Radopholus similis; Heteroderidae such as Meloidogyne javanica, Meloidogyne incognita, guava root - knot nematodes (Meloidogyne enterolobii), Meloidogyne hapla, Heterodera glycines, Globodera rostochiensis, Globodera pallida, Meloidogyne chitwoodi; Hoplolaimidae such as Rotylenchulus reniformis; Anguinidae such as Nothotylenchus acris, Ditylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoridae such as Xiphinema index; Trichodoridae; Parasitaphelenchidae such as Bursaphelenchus xylophilus.

[0355] Harmful arthropods such as harmful insects and harmful mites, harmful mollusks and harmful nematodes can also be harmful insects, harmful mites and other harmful arthropods, harmful mollusks and harmful nematodes with reduced sensitivity to pesticides, acaricides, molluscicides or nematicides, or with strong drug resistance.

[0356] As a method for controlling harmful arthropods of the present invention, it can be implemented by directly applying an effective amount of the compound or composition A of the present invention to harmful arthropods and / or to the habitats of harmful arthropods (plants, soil, indoors of houses, animals, etc.). As a method for controlling harmful arthropods of the present invention, for example, foliar treatment, soil treatment, root treatment, spraying treatment, fumigation treatment, water surface treatment, and seed treatment can be mentioned.

[0357] For the compound or composition A of the present invention, usually an inert carrier such as a solid carrier, a liquid carrier, a gaseous carrier, etc. and a surfactant, etc. are mixed, and auxiliary agents for formulation such as a binder, a dispersant, a stabilizer, etc. are added as needed, and formulated into an aqueous suspension formulation, an oily suspension formulation, an oil formulation, an emulsion, an emulsion formulation, a microemulsion formulation, a microcapsule formulation, a wettable powder, a water-dispersible granule, a powder, a granule, a tablet, an aerosol, a resin formulation, etc. for use. It is not limited to these formulations, and it can be formulated into the formulations described in Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers - 271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications (Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers - 271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications), 2016, ISSN: 0259 - 2517 for use.

[0358] In these formulations, the compound or composition A of the present invention is usually contained in an amount of 0.0001 to 99% by weight.

[0359] Examples of the solid carrier include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, silica white, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powders and granules of chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0360] As the liquid carrier, examples include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylene ethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0361] As the gaseous carrier, examples include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.

[0362] As the surfactant, examples include nonionic surfactants (polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyethylene glycol fatty acid ester, etc.) and anionic surfactants (alkyl sulfonate, alkyl aryl sulfonate, alkyl sulfate, etc.).

[0363] As other adjuvants for the preparation, binders, dispersants, colorants, stabilizers, etc. can be cited. Specifically, examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), isopropyl acid phosphate, and dibutylhydroxytoluene.

[0364] In addition, as the component for enhancing or assisting the efficacy of the compound of the present invention, adjuvants can be used. Specifically, examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), SundanceII (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark), etc.

[0365] In the present invention, examples of the plant include the whole plant, stems and leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative propagation organs, and seedlings.

[0366] The vegetative propagation organ refers to a part of the root, stem, leaf, etc. of a plant that has the ability to grow when the part is cut off from the main body and placed in the soil. Examples of the vegetative propagation organ include, for example, tuberous root, creeping root, bulb, corm (or solid bulb), tuber, rhizome, stolon, rhizophore, cane cuttings, propagule, and vine cutting. It should be noted that the stolon is sometimes also referred to as a runner, and the propagule is also referred to as a bulbil, which is divided into a broad bud and a bulbil. The vine cutting refers to the slender shoots (a general term for leaves and stems, a shoot without roots) of sweet potato, Dioscorea japonica, etc. The bulb, corm, tuber, rhizome, cane cuttings, rhizophore, or tuberous root are also collectively referred to as a bulb. The cultivation of potatoes starts by implanting tubers into the soil, but the tubers used are usually referred to as seed potatoes.

[0367] As a method for applying an effective amount of the compound or composition A of the present invention to soil to control harmful arthropods, for example, a method of applying an effective amount of the compound or composition A of the present invention to the soil before or after transplanting plants can be cited. More specifically, for example, hole treatment (hole spraying, hole soil mixing), root treatment (root spraying, root soil mixing, root irrigation, late-stage root treatment during seedling raising), furrow treatment (furrow spraying, furrow soil mixing), ridge treatment (ridge spraying, ridge soil mixing, ridge spraying during the growth period), furrow treatment at sowing (furrow spraying at sowing, furrow soil mixing at sowing), overall treatment (whole soil spraying, whole soil mixing), side treatment of ridge cultivation, water surface treatment (water surface application, water surface application after water storage), other soil spraying treatments (granule foliar spraying during the growth period, spraying under the tree crown or around the main trunk, soil surface spraying, soil surface mixing, hole spraying, surface spraying of the ridge part, inter-plant spraying), other irrigation treatments (soil irrigation, irrigation during seedling raising, liquid injection treatment, plant base irrigation, drip irrigation of liquid medicine, chemical solution irrigation), seedling box treatment (seedling box spraying, seedling box irrigation, liquid medicine accumulation in seedling box), seedling tray treatment (seedling tray spraying, seedling tray irrigation, liquid medicine accumulation in seedling tray), seedbed treatment (seedbed spraying, seedbed irrigation, seedbed spraying in paddy field seedbed, seedling dipping), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, spraying before covering soil at sowing, spraying after covering soil at sowing, covering soil mixing), and other treatments (cultivated soil mixing, turning in, topsoil mixing, soil mixing at the rain dripping part, planting position treatment, granule calyx spraying, paste fertilizer mixing).

[0368] As seed treatment, for example, treatment of seeds or vegetative propagation organs with the compound or composition A of the present invention can be cited. Specifically, for example: spraying treatment in which a suspension of the compound or composition A of the present invention is atomized and sprayed onto the surface of seeds or vegetative propagation organs; coating treatment in which the compound or composition A of the present invention is coated on seeds or vegetative propagation organs; immersion treatment in which seeds or vegetative propagation organs are immersed in a liquid medicine of the compound or composition A of the present invention for a certain period of time; a method of coating seeds or vegetative propagation organs with a carrier containing the compound or composition A of the present invention (coating treatment, pellet coating treatment, etc.). As the above-mentioned vegetative propagation organs, seed potatoes can be particularly cited.

[0369] When treating seeds or vegetative propagation organs with Composition A, Composition A can be formulated into a single preparation for treating seeds or vegetative propagation organs, or it can be formulated into different multiple preparations and used to treat seeds or vegetative propagation organs in several times. As a method of formulating Composition A into different multiple preparations and treating in several times, for example, there can be mentioned: treating with a preparation containing only the compound of the present invention as the active ingredient, allowing the seeds or vegetative propagation organs to air-dry, and then treating with a preparation containing this ingredient; and treating with a preparation containing the compound of the present invention and this ingredient as the active ingredients, allowing the seeds or vegetative propagation organs to air-dry, and then treating with a preparation containing this ingredient other than the already treated ingredient.

[0370] The seeds or vegetative propagation organs holding the compound of the present invention or Composition A in the present invention refer to: seeds or vegetative propagation organs in a state where the compound of the present invention or Composition A adheres to the surface of the seeds or vegetative propagation organs. For the above-mentioned seeds or vegetative propagation organs holding the compound of the present invention or Composition A, materials other than the compound of the present invention or Composition A can adhere before and after the compound of the present invention or Composition A adheres to the seeds or vegetative propagation organs.

[0371] In addition, when Composition A forms a layer and adheres to the surface of seeds or vegetative propagation organs, the layer is formed of one layer or multiple layers. In addition, when formed of multiple layers, each layer is a layer containing one or more active ingredients, or is formed of a layer containing one or more active ingredients and a layer not containing active ingredients.

[0372] Seeds or vegetative propagation organs holding the compound of the present invention or Composition A can be obtained, for example, by the following method: applying a preparation containing the compound of the present invention or Composition A to seeds or vegetative propagation organs using the aforementioned seed treatment method.

[0373] When using the compound of the present invention or Composition A for controlling harmful arthropods in the agricultural field, the application rate is usually 1 to 10,000 g based on the amount of the compound of the present invention per 10,000 m 2 In the case of treating seeds or vegetative propagation organs, the amount of the compound of the present invention is usually applied in the range of 0.001 to 100 g relative to 1 Kg of seeds or vegetative propagation organs. When the compound of the present invention or Composition A is formulated into an emulsion, wettable powder, suspension agent, etc., it is usually diluted with water so that the active ingredient concentration becomes 0.01 to 10,000 ppm and then applied, and granule agents, powder agents, etc. are usually applied directly.

[0374] In addition, the compound or composition A of the present invention can also be treated by methods such as winding a resin preparation processed into a sheet or line around a crop, stretching it near the crop, or laying it on the root soil.

[0375] When the compound or composition A of the present invention is used for controlling harmful arthropods inhabiting in a house, for the application amount thereof, in the case of surface treatment, based on the amount of the compound of the present invention per 1 m 2 of the treated area, it is usually 0.01 to 1000 mg, and in the case of space treatment, based on the amount of the compound of the present invention per 1 m 3 of the treated space, it is usually 0.01 to 500 mg. When the compound or composition A of the present invention is formulated into an emulsion, wettable powder, suspension agent, etc., it is usually diluted with water so that the effective ingredient concentration becomes 0.1 to 10000 ppm and applied, and oils, aerosols, fumigants, bait agents, etc. are applied directly.

[0376] When the compound or composition A of the present invention is used for controlling external parasites of livestock such as cattle, horses, pigs, sheep, goats, chickens, and small animals such as dogs, cats, rats, and mice, it can be used for animals by methods known in veterinary medicine. As a specific usage method, in the case of aiming at systemic inhibition, it is administered by, for example, tablets, incorporation into feed, suppositories, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), and in the case of aiming at non-systemic inhibition, it is used by methods such as spraying an oil agent or aqueous liquid agent, pouring treatment or drip treatment, washing the animal with a shampoo preparation, or making a resin preparation into a collar, ear tag and having the animal wear it. The amount of the compound or composition A of the present invention when administered to an animal is usually in the range of 0.1 to 1000 mg relative to 1 kg of the animal's body weight.

[0377] The compound or composition A of the present invention can be used as a control agent for harmful arthropods in agricultural fields such as dry fields, paddy fields, lawns, and orchards. Examples of plants include the following plants.

[0378] Maize (dent corn, flint corn, soft corn, pop corn, waxy corn, sweet corn, nonsweet corn), rice (long-grain rice, short-grain rice, medium-grain rice, japonica rice, tropical japonica rice, indica rice, javanica rice, paddy rice, upland rice, floating rice, direct seeding, transplantation, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat, club wheat, their respective winter wheat types, spring wheat types), barley (two-row barley (= brewing barley), six-row barley, hulless barley, sticky barley, their respective winter barley types, spring barley types), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland cotton, pima cotton), soybean (mature seed harvest variety, edamame variety, green manure variety, their respective indeterminate growth type, determinate growth type, semi-determinate growth type), peanut, buckwheat, sugar beet (for sugar production, for feed, root vegetable, leaf vegetable, for fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflower (for oil extraction, for food, for ornamental use), sugarcane, tobacco, tea plant, mulberry, solanaceous vegetables (eggplant, tomato, green pepper, chili pepper, potato, etc.), cucurbitaceous vegetables (cucumber, pumpkin, zucchini, watermelon, melon, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), asteraceous vegetables (burdock, spring chrysanthemum, artichoke, lettuce, etc.), liliaceous vegetables (scallion, onion, garlic, asparagus, etc.), umbelliferous vegetables (carrot, parsley, celery, parsnip, etc.), chenopodiaceous vegetables (spinach, chard, etc.), labiatae vegetables (perilla, mint, basil, etc.), strawberry, sweet potato, Japanese yam, taro, pome fruits (apple, European pear, Japanese pear, white pear, Chinese quince, quince, etc.), stone fruits (peach, plum, nectarine, greengage, cherry, apricot, prune, etc.), citrus fruits (Satsuma mandarin, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, persimmon, fig, olive, loquat, banana, coffee, date palm, coconut, ornamental plants, forest plants, lawn grasses, forage grasses, etc.

[0379] The above-mentioned plants may be any commonly cultivated varieties without particular limitation. The above-mentioned plants also include plants that can be produced by natural crossing, plants that can be generated by mutation, F1 hybrid plants, and genetically modified crops. Examples of genetically modified crops include plants that have been conferred tolerance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase) inhibitors like isoxaflutole, ALS (acetolactate synthase) inhibitors like imazethapyr and thifensulfuron-methyl, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, and herbicides such as bromoxynil or dicamba; plants that can synthesize selective toxins known in Bacillus species such as Bacillus thuringiensis; and plants that can confer specific insecticidal activity by synthesizing gene fragments partially identical to endogenous genes from harmful insects and inducing gene silencing (RNAi; RNA interference) in the target harmful insects.

[0380] Examples

[0381] Hereinafter, the present invention will be described in more detail with reference to Production Examples, Formulation Examples, and Test Examples, etc., but the present invention is not limited only to these examples.

[0382] In this specification, Me represents methyl, Et represents ethyl, Pr represents propyl, i-Pr represents isopropyl, t-Bu represents tert-butyl, c-Pr represents cyclopropyl, c-Bu represents cyclobutyl, Ph represents phenyl, Py2 represents 2-pyridyl, Py3 represents 3-pyridyl, and Py4 represents 4-pyridyl. When c-Pr, c-Bu, Ph, Py2, Py3, and Py4 are substituted with substituents, the substituents and the substitution positions are described together before the symbol. For example, 1-CN-c-Pr represents 1-cyanocyclopropyl, 3,4-F2-Ph represents 3,4-difluorophenyl, 4-S(O)2CF3-Ph represents 4-(trifluoromethylsulfonyl)phenyl, 3,4-(OCF3)2-Ph represents 3,4-bis(trifluoromethoxy)phenyl, 3-SCF3-4-OCF3-Ph represents 3-[(trifluoromethyl)thio]-4-(trifluoromethoxy)phenyl, and 4-CF3-Py2 represents 4-(trifluoromethyl)-2-pyridyl.

[0383] First, Production Examples of the compounds of the present invention and their production intermediates are shown.

[0384] Reference Production Example 1

[0385] A mixture of 1.48 g of 6-bromo-2-chloroimidazo[1,2-a]pyridine prepared by the method described in International Publication No. 2019 / 124548, 2.4 mL of chlorosulfonic acid, and 13 mL of phosphoryl chloride was stirred at 110 °C for 5 hours. The resulting mixture was concentrated under reduced pressure, 2.7 mL of triethylamine, 13 mL of acetonitrile, and 3 mL of dimethylamine (7% solution in tetrahydrofuran) were added to the resulting residue, and the mixture was stirred at room temperature for 1 hour. Water was added to the resulting mixture, and extraction was performed with ethyl acetate. The obtained organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 1.9 g of Intermediate 1 represented by the following formula.

[0386] [Chemical Formula 14]

[0387]

[0388] Intermediate 1: 1 H-NMR (CDCl3) δ: 9.05 (1H, s), 7.53 - 7.55 (2H, m), 2.93 (6H, s).

[0389] Reference Production Example 2

[0390] A mixture of 0.9 g of Intermediate 1, 1.5 g of cesium fluoride, and 5 mL of DMSO was stirred at 120 °C for 4 hours. After the resulting mixture was brought to room temperature, ethyl acetate and water were successively added thereto, and filtration was performed. The obtained filtrate was separated, the obtained organic layer was dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.3 g of Intermediate 2 represented by the following formula.

[0391] [Chemical Formula 15]

[0392]

[0393] Intermediate 2: 1 H-NMR (CDCl3) δ: 8.95 (1H, s), 7.50 - 7.59 (2H, m), 2.91 (6H, s).

[0394] Reference Production Example 3

[0395] 0.05 g of 5-bromo-2-chloro-N,N-dimethyl-3-pyridinesulfonamide prepared by the method described in International Publication No. 2012 / 037108, 0.12 g of cesium fluoride and 0.25 mL of DMSO were added, and the mixture was stirred at room temperature for 22 hours. Ethyl acetate and water were added to the obtained mixture in sequence, and the mixture was filtered. The obtained filtrate was separated, and the obtained organic layer was dried with anhydrous sodium sulfate and concentrated under reduced pressure to obtain 0.03 g of intermediate 3 shown in the following formula.

[0396] [Chemical formula 16]

[0397]

[0398] Intermediate 3: 1 H-NMR(CDCl3)δ:8.44(1H,s),8.40(1H,s),2.93(6H,s).

[0399] Reference Production Example 4

[0400] 0.95 g of 6-(trifluoromethyl)imidazo[1,2-a]pyridine-2-carboxylic acid, prepared by the method described in JP-A-2018-24660, and N 2 -Methyl-5-(trifluoromethyl)-2,3-pyridinediamine 0.79g, N,N-dimethyl-4-aminopyridine 0.10g and pyridine 10mL mixture was added with N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride 1.2g, and stirred at 100°C for 2 hours. After the obtained mixture was cooled to room temperature, water was added, and the precipitated solid was filtered. To the obtained solid was added 10mL of acetic acid, and after stirring for 1.5 hours under reflux, the obtained mixture was concentrated under reduced pressure. Saturated sodium bicarbonate aqueous solution was added to the obtained residue, and extraction was performed with chloroform. The obtained organic layer was dried with anhydrous sodium sulfate and concentrated under reduced pressure to obtain 1.25g of intermediate 4 shown in the following formula.

[0401] [Chemical formula 17]

[0402]

[0403] Intermediate 4: 1 H-NMR(CDCl3)δ:8.69(1H,s),8.61(1H,s),8.55(1H,s),8.27(1H,s),7.82(1H,d),7.44(1H,d),4.47(3H,s).

[0404] Production Example 1

[0405] To a mixture of 0.058 g of 6-(trifluoromethyl)-1,2,4-triazolo[4,3-a]pyridin-3(2H)-one prepared by the method described in International Publication No. 2019 / 131575, 0.08 g of Intermediate 3, and 1 mL of DMF was added 0.18 g of cesium carbonate, and the mixture was stirred at 70 °C for 1 hour. After the resulting mixture was cooled to room temperature, water was added, and extraction was performed with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.084 g of Compound 1 of the present invention represented by the following formula.

[0406] [Chemical Formula 18]

[0407]

[0408] Compound 1 of the present invention: 1 H-NMR(CDCl3)δ: 8.86(1H, s), 8.49(1H, s), 8.20(1H, s), 7.26 - 7.23(2H, m), 2.83(6H, s).

[0409] Production Example 1-2

[0410] The compounds produced according to Production Example 1 and their physical property values are shown below.

[0411] [Chemical Formula 19]

[0412]

[0413] Compound 2 of the present invention: 1 H-NMR(CDCl3)δ: 8.84(1H, s), 8.21(1H, s), 7.70 - 7.62(2H, m), 7.26 - 7.23(2H, m), 2.94(6H, s).

[0414] Production Example 2

[0415] A mixture of 1.25 g of Intermediate 4, 1.2 mL of chlorosulfonic acid, and 16.9 mL of phosphoryl chloride was stirred at 110 °C for 5 hours. The resulting mixture was concentrated under reduced pressure, and to the resulting residue were added 4.5 mL of triethylamine, 6.5 mL of acetonitrile, and 4.9 mL of methylamine (7% tetrahydrofuran solution), and the mixture was stirred at room temperature for 1 hour. Water was added to the resulting mixture, and extraction was performed with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.51 g of Compound 3 of the present invention represented by the following formula.

[0416] [Chemical Formula 20]

[0417]

[0418] Compound 3 of the present invention: 1 1H-NMR(CDCl3)δ: 9.73(1H, s), 8.79(1H, s), 8.59(1H, s), 8.38(1H, s), 7.92(1H, d), 7.67(1H, d), 4.41(3H, s), 2.79(3H, s).

[0419] Next, examples of the compounds of the present invention produced according to any one of the production examples described in the examples and the production methods described in this specification are shown below.

[0420] [Chemical formula 21]

[0421]

[0422] In the compound represented by formula (L-1) (hereinafter referred to as compound (L-1)), R 2a and R 2b are hydrogen atoms, A 2 is CH, B 4 is CH, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX1).

[0423] [Table 1]

[0424]

[0425] In compound (L-1), R 2a and R 2b are hydrogen atoms, A 2 is nitrogen, B 4 is CH, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX2).

[0426] In compound (L-1), R 2a and R 2b are hydrogen atoms, A 2 is CH, B 4 is nitrogen, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX3).

[0427] In compound (L-1), R 2a and R 2b are hydrogen atoms, A 2 is nitrogen, B 4 is nitrogen, and R6e A compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX4).

[0428] In compound (L-1), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is CH, and B 4 is CH, and R 6e is a compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX5).

[0429] In compound (L-1), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and B 4 is CH, and R 6e is a compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX6).

[0430] In compound (L-1), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is CH, and B 4 is a nitrogen atom, and R 6e is a compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX7).

[0431] In compound (L-1), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and B 4 is a nitrogen atom, and R 6e is a compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX8).

[0432] In compound (L-1), R 2a is ethyl, and R 2b is a hydrogen atom, and A 2 is CH, and B 4 is CH, and R 6e is a compound having any of the substituents described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX9).

[0433] In compound (L-1), R 2a is ethyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and B 4 is CH, and R 6eA compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX10).

[0434] In compound (L-1), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, B 4 is a nitrogen atom, R 6e A compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX11).

[0435] In compound (L-1), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, B 4 is a nitrogen atom, R 6e A compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX12).

[0436] In compound (L-1), R 2a and R 2b are methyl, A 2 is CH, B 4 is CH, R 6e A compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX13).

[0437] In compound (L-1), R 2a and R 2b are methyl, A 2 is a nitrogen atom, B 4 is CH, R 6e A compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX14).

[0438] In compound (L-1), R 2a and R 2b are methyl, A 2 is CH, B 4 is a nitrogen atom, R 6e A compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX15).

[0439] In compound (L-1), R 2a and R 2b are methyl, A 2 is a nitrogen atom, B 4 is a nitrogen atom, R 6eA compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX16).

[0440] [Chemical formula 22]

[0441]

[0442] In the compound represented by formula (L-2) (hereinafter referred to as compound (L-2)), R 2a and R 2b are hydrogen atoms, A 3 is NCH3, B 4 is CH, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX17).

[0443] In compound (L-2), R 2a and R 2b are hydrogen atoms, A 3 is an oxygen atom, B 4 is CH, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX18).

[0444] In compound (L-2), R 2a and R 2b are hydrogen atoms, A 3 is NCH3, B 4 is a nitrogen atom, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX19).

[0445] In compound (L-2), R 2a and R 2b are hydrogen atoms, A 3 is an oxygen atom, B 4 is a nitrogen atom, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX20).

[0446] In compound (L-2), R 2a is methyl, R 2b is a hydrogen atom, A 3 is NCH3, B 4 is CH, and R 6e is a compound having any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX21).

[0447] In compound (L-2), R 2a is methyl, R2b is a hydrogen atom, A 3 is NCH3, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX22).

[0448] In compound (L-2), R 2a is methyl, R 2b is a hydrogen atom, A 3 is NCH3, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX23).

[0449] In compound (L-2), R 2a is methyl, R 2b is a hydrogen atom, A 3 is an oxygen atom, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX24).

[0450] In compound (L-2), R 2a is ethyl, R 2b is a hydrogen atom, A 3 is NCH3, B 4 is CH, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX25).

[0451] In compound (L-2), R 2a is ethyl, R 2b is a hydrogen atom, A 3 is NCH3, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX26).

[0452] In compound (L-2), R 2a is ethyl, R 2b is a hydrogen atom, A 3 is NCH3, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX27).

[0453] In compound (L-2), R 2a is ethyl, R2b is a hydrogen atom, A 3 is an oxygen atom, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX28).

[0454] In compound (L-2), R 2a and R 2b are methyl groups, A 3 is NCH3, B 4 is CH, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX29).

[0455] In compound (L-2), R 2a and R 2b are methyl groups, A 3 is an oxygen atom, B 4 is CH, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX30).

[0456] In compound (L-2), R 2a and R 2b are methyl groups, A 3 is NCH3, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX31).

[0457] In compound (L-2), R 2a and R 2b are methyl groups, A 3 is an oxygen atom, B 4 is a nitrogen atom, R 6e is a compound with any substituent described in [Table 1A] or [Table 2A] (hereinafter referred to as compound group SX32).

[0458] [Chemical formula 23]

[0459]

[0460] In the compound represented by formula (L-3) (hereinafter referred to as compound (L-3)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3dIt is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX33).

[0461] [Table 2]

[0462]

[0463] [Table 3]

[0464]

[0465] [Table 4]

[0466]

[0467] In compound (L-3), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX34).

[0468] In compound (L-3), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX35).

[0469] In compound (L-3), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX36).

[0470] In compound (L-3), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX37).

[0471] In compound (L-3), R 2a is methyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX38).

[0472] In compound (L-3), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX39).

[0473] In compound (L-3), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX40).

[0474] In compound (L-3), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX41).

[0475] In compound (L-3), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX42).

[0476] In compound (L-3), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX43).

[0477] In compound (L-3), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX44).

[0478] In compound (L-3), R 2a and R 2b are methyl groups, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX45).

[0479] In compound (L-3), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX46).

[0480] In compound (L-3), R 2a and R 2b are methyl groups, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX47).

[0481] In compound (L-3), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX48).

[0482] [Chemical formula 24]

[0483]

[0484] In the compound represented by formula (L-4) (hereinafter referred to as compound (L-4)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX49).

[0485] In the compound (L-4), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX50).

[0486] In the compound (L-4), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX51).

[0487] In the compound (L-4), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX52).

[0488] In the compound (L-4), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX53).

[0489] In the compound (L-4), R 2a is methyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX54).

[0490] In the compound (L-4), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX55).

[0491] In the compound (L-4), R2a is methyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX56).

[0492] In compound (L-4), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX57).

[0493] In compound (L-4), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX58).

[0494] In compound (L-4), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX59).

[0495] In compound (L-4), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX60).

[0496] In compound (L-4), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX61).

[0497] In compound (L-4), R 2aand R 2b is methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX62).

[0498] In compound (L-4), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX63).

[0499] In compound (L-4), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX64).

[0500] [Chemical formula 25]

[0501]

[0502] In the compound represented by formula (L-5) (hereinafter referred to as compound (L-5)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX65).

[0503] In compound (L-5), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX66).

[0504] In compound (L-5), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3bCompounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX67).

[0505] In compound (L-5), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX68).

[0506] In compound (L-5), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX69).

[0507] In compound (L-5), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX70).

[0508] In compound (L-5), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX71).

[0509] In compound (L-5), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX72).

[0510] In compound (L-5), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3dIt is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX73).

[0511] In compound (L-5), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX74).

[0512] In compound (L-5), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX75).

[0513] In compound (L-5), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX76).

[0514] In compound (L-5), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX77).

[0515] In compound (L-5), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX78).

[0516] In compound (L-5), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3bIt is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX79).

[0517] In compound (L-5), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX80).

[0518] [Chemical formula 26]

[0519]

[0520] In the compound represented by formula (L-6) (hereinafter referred to as compound (L-6)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX81).

[0521] In compound (L-6), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX82).

[0522] In compound (L-6), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX83).

[0523] In compound (L-6), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX84).

[0524] In compound (L-6), R 2a is a methyl group, R2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX85).

[0525] In compound (L-6), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX86).

[0526] In compound (L-6), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX87).

[0527] In compound (L-6), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX88).

[0528] In compound (L-6), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX89).

[0529] In compound (L-6), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX90).

[0530] In compound (L-6), R 2a is ethyl, R2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX91).

[0531] In compound (L-6), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX92).

[0532] In compound (L-6), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX93).

[0533] In compound (L-6), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX94).

[0534] In compound (L-6), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX95).

[0535] In compound (L-6), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX96).

[0536] [Chemical formula 27]

[0537]

[0538] In the compound represented by formula (L-7) (hereinafter referred to as compound (L-7)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX97).

[0539] In compound (L-7), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX98).

[0540] In compound (L-7), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX99).

[0541] In compound (L-7), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX100).

[0542] In compound (L-7), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX101).

[0543] In compound (L-7), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX102).

[0544] In compound (L-7), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX103).

[0545] In compound (L-7), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX104).

[0546] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX105).

[0547] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX106).

[0548] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX107).

[0549] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX108).

[0550] In compound (L-7), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX109).

[0551] In compound (L-7), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX110).

[0552] In compound (L-7), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX111).

[0553] In compound (L-7), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX112).

[0554] [Chemical formula 28]

[0555]

[0556] In the compound represented by formula (L-8) (hereinafter referred to as compound (L-8)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX113).

[0557] In compound (L-8), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX114).

[0558] In compound (L-8), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX115).

[0559] In compound (L-8), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX116).

[0560] In compound (L-8), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX117).

[0561] In compound (L-8), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX118).

[0562] In compound (L-8), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX119).

[0563] In compound (L-8), R 2a is a methyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX120).

[0564] In compound (L-8), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX121).

[0565] In compound (L-8), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX122).

[0566] In compound (L-8), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX123).

[0567] In compound (L-8), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX124).

[0568] In compound (L-8), R 2a and R 2b are methyl groups, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX125).

[0569] In compound (L-8), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX126).

[0570] In compound (L-8), R 2a and R 2b are methyl groups, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX127).

[0571] In compound (L-8), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX128).

[0572] [Chemical formula 29]

[0573]

[0574] In the compound represented by formula (L-9) (hereinafter referred to as compound (L-9)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX129).

[0575] In compound (L-9), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX130).

[0576] In compound (L-9), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX131).

[0577] In compound (L-9), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX132).

[0578] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX133).

[0579] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX134).

[0580] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX135).

[0581] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX136).

[0582] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX137).

[0583] In the compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX138).

[0584] In the compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX139).

[0585] In the compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX140).

[0586] In the compound (L-9), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX141).

[0587] In the compound (L-9), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX142).

[0588] In the compound (L-9), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX143).

[0589] In the compound (L-9), R2a and R 2b is methyl, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX144).

[0590] [Chemical formula 30]

[0591]

[0592] In the compound represented by formula (L-10) (hereinafter referred to as compound (L-10)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX145).

[0593] In compound (L-10), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX146).

[0594] In compound (L-10), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX147).

[0595] In compound (L-10), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX148).

[0596] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3dIt is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX149).

[0597] In compound (L-10), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX150).

[0598] In compound (L-10), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is CH, and R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX151).

[0599] In compound (L-10), R 2a is methyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX152).

[0600] In compound (L-10), R 2a is ethyl, and R 2b is a hydrogen atom, and A 2 is CH, and R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX153).

[0601] In compound (L-10), R 2a is ethyl, and R 2b is a hydrogen atom, and A 2 is a nitrogen atom, and R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX154).

[0602] In compound (L-10), R 2a is ethyl, and R 2b is a hydrogen atom, and A 2 is CH, and R 3d is a hydrogen atom, and R3b A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX155).

[0603] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX156).

[0604] In compound (L-10), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX157).

[0605] In compound (L-10), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX158).

[0606] In compound (L-10), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3b A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX159).

[0607] In compound (L-10), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b A compound having any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX160).

[0608] [Chemical formula 31]

[0609]

[0610] In the compound represented by formula (L-11) (hereinafter referred to as compound (L-11)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, and R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX161).

[0611] In compound (L-11), R 2a and R 2b are hydrogen atoms, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX162).

[0612] In compound (L-11), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX163).

[0613] In compound (L-11), R 2a and R 2b are hydrogen atoms, A 2 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX164).

[0614] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX165).

[0615] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX166).

[0616] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX167).

[0617] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX168).

[0618] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX169).

[0619] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX170).

[0620] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX171).

[0621] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX172).

[0622] In the compound (L-11), R 2a and R 2b are methyl, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX173).

[0623] In the compound (L-11), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX174).

[0624] In the compound (L-11), R 2a and R 2b are methyl, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX175).

[0625] In the compound (L-11), R 2a and R 2b are methyl, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX176).

[0626] [Chemical formula 32]

[0627]

[0628] In the compound represented by formula (L-12) (hereinafter referred to as compound (L-12)), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX177).

[0629] In the compound (L-12), R 2a and R 2b are hydrogen atoms, A 2 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX178).

[0630] In compound (L-12), R 2a and R 2b are hydrogen atoms, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX179).

[0631] In compound (L-12), R 2a and R 2b are hydrogen atoms, A 2 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX180).

[0632] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX181).

[0633] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX182).

[0634] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX183).

[0635] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, A 2 is nitrogen, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX184).

[0636] In compound (L-12), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX185).

[0637] In compound (L-12), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX186).

[0638] In compound (L-12), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX187).

[0639] In compound (L-12), R 2a is an ethyl group, R 2b is a hydrogen atom, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX188).

[0640] In compound (L-12), R 2a and R 2b are methyl groups, A 2 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX89).

[0641] In compound (L-12), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX190).

[0642] In compound (L-12), R 2a and R 2b are methyl groups, A 2 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX191).

[0643] In compound (L-12), R 2a and R 2b are methyl groups, A 2 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX192).

[0644] [Chemical formula 33]

[0645]

[0646] In the compound represented by formula (L-13) (hereinafter referred to as compound (L-13)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX193).

[0647] In compound (L-13), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX194).

[0648] In compound (L-13), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX195).

[0649] In compound (L-13), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX196).

[0650] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX197).

[0651] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX198).

[0652] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX199).

[0653] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX200).

[0654] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX201).

[0655] In the compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX202).

[0656] In the compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX203).

[0657] In the compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX204).

[0658] In the compound (L-13), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX205).

[0659] In the compound (L-13), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX206).

[0660] In the compound (L-13), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX207).

[0661] In the compound (L-13), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX208).

[0662] [Chemical formula 34]

[0663]

[0664] In the compound represented by formula (L-14) (hereinafter referred to as compound (L-14)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX209).

[0665] In compound (L-14), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX210).

[0666] In compound (L-14), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX211).

[0667] In compound (L-14), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX212).

[0668] In compound (L-14), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R3d Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX213).

[0669] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX214).

[0670] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX215).

[0671] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX216).

[0672] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX217).

[0673] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d Compounds with any of the substituents described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX218).

[0674] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX219).

[0675] In compound (L-14), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX220).

[0676] In compound (L-14), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX221).

[0677] In compound (L-14), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX222).

[0678] In compound (L-14), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX223).

[0679] In compound (L-14), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX224).

[0680] [Chemical formula 35]

[0681]

[0682] In the compound represented by formula (L-15) (hereinafter referred to as compound (L-15)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX225).

[0683] In compound (L-15), R 2a and R 2b are hydrogen atoms, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX226).

[0684] In compound (L-15), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX227).

[0685] In compound (L-15), R 2a and R 2b are hydrogen atoms, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX228).

[0686] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX229).

[0687] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX230).

[0688] In the compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX231).

[0689] In the compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX232).

[0690] In the compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX233).

[0691] In the compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX234).

[0692] In the compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX235).

[0693] In the compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX236).

[0694] In the compound (L-15), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX237).

[0695] In the compound (L-15), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX238).

[0696] In the compound (L-15), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX239).

[0697] In the compound (L-15), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX240).

[0698] [Chemical formula 36]

[0699]

[0700] In the compound represented by formula (L-16) (hereinafter referred to as compound (L-16)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX241).

[0701] In the compound (L-16), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX242).

[0702] In compound (L-16), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX243).

[0703] In compound (L-16), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX244).

[0704] In compound (L-16), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX245).

[0705] In compound (L-16), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX246).

[0706] In compound (L-16), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX247).

[0707] In compound (L-16), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX248).

[0708] In compound (L-16), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX249).

[0709] In compound (L-16), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX250).

[0710] In compound (L-16), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX251).

[0711] In compound (L-16), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX252).

[0712] In compound (L-16), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX253).

[0713] In compound (L-16), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX254).

[0714] In compound (L-16), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX255).

[0715] In compound (L-16), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX256).

[0716] [Chemical formula 37]

[0717]

[0718] In the compound represented by formula (L-17) (hereinafter referred to as compound (L-17)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX257).

[0719] In compound (L-17), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX258).

[0720] In compound (L-17), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX259).

[0721] In compound (L-17), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX260).

[0722] In compound (L-17), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX261).

[0723] In compound (L-17), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX262).

[0724] In compound (L-17), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX263).

[0725] In compound (L-17), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX264).

[0726] In compound (L-17), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX265).

[0727] In the compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX266).

[0728] In the compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX267).

[0729] In the compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX268).

[0730] In the compound (L-17), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX269).

[0731] In the compound (L-17), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX270).

[0732] In the compound (L-17), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX271).

[0733] In the compound (L-17), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX272).

[0734] [Chemical formula 38]

[0735]

[0736] In the compound represented by formula (L-18) (hereinafter referred to as compound (L-18)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX273).

[0737] In compound (L-18), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX274).

[0738] In compound (L-18), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX275).

[0739] In compound (L-18), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX276).

[0740] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX277).

[0741] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX278).

[0742] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX279).

[0743] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX280).

[0744] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX281).

[0745] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX282).

[0746] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX283).

[0747] In compound (L-18), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX284).

[0748] In compound (L-18), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX285).

[0749] In compound (L-18), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX286).

[0750] In compound (L-18), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX287).

[0751] In compound (L-18), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX288).

[0752] [Chemical formula 39]

[0753]

[0754] In the compound represented by formula (L-19) (hereinafter referred to as compound (L-19)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX289).

[0755] In compound (L-19), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX290).

[0756] In compound (L-19), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX291).

[0757] In compound (L-19), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX292).

[0758] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX293).

[0759] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX294).

[0760] In the compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX295).

[0761] In the compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX296).

[0762] In the compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX297).

[0763] In the compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX298).

[0764] In the compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX299).

[0765] In the compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX300).

[0766] In the compound (L-19), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX301).

[0767] In the compound (L-19), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX302).

[0768] In the compound (L-19), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX303).

[0769] In the compound (L-19), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX304).

[0770] [Chemical formula 40]

[0771]

[0772] In the compound represented by formula (L-20) (hereinafter referred to as compound (L-20)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX309).

[0773] In the compound (L-20), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX310).

[0774] In compound (L-20), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX311).

[0775] In compound (L-20), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX312).

[0776] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX313).

[0777] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX314).

[0778] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX315).

[0779] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX316).

[0780] In compound (L-20), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX317).

[0781] In compound (L-20), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX318).

[0782] In compound (L-20), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX319).

[0783] In compound (L-20), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX320).

[0784] In compound (L-20), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX321).

[0785] In compound (L-20), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX322).

[0786] In compound (L-20), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX323).

[0787] In compound (L-20), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX324).

[0788] [Chemical formula 41]

[0789]

[0790] In the compound represented by formula (L-21) (hereinafter referred to as compound (L-21)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX325).

[0791] In compound (L-21), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX326).

[0792] In compound (L-21), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX327).

[0793] In the compound (L-21), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX328).

[0794] In the compound (L-21), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX329).

[0795] In the compound (L-21), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX330).

[0796] In the compound (L-21), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX331).

[0797] In the compound (L-21), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX332).

[0798] In the compound (L-21), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX333).

[0799] In the compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX334).

[0800] In the compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX335).

[0801] In the compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX336).

[0802] In the compound (L-21), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX337).

[0803] In the compound (L-21), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX338).

[0804] In the compound (L-21), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX339).

[0805] In the compound (L-21), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX340).

[0806] [Chemical formula 42]

[0807]

[0808] In the compound represented by formula (L-22) (hereinafter referred to as compound (L-22)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX341).

[0809] In compound (L-22), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX342).

[0810] In compound (L-22), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX343).

[0811] In compound (L-22), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX344).

[0812] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R3d A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX345).

[0813] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX346).

[0814] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX347).

[0815] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX348).

[0816] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX349).

[0817] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d A compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX350).

[0818] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX351).

[0819] In compound (L-22), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX352).

[0820] In compound (L-22), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX353).

[0821] In compound (L-22), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX354).

[0822] In compound (L-22), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX355).

[0823] In compound (L-22), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX356).

[0824] [Chemical formula 43]

[0825]

[0826] In the compound represented by formula (L-23) (hereinafter referred to as compound (L-23)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX357).

[0827] In compound (L-23), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX358).

[0828] In compound (L-23), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX359).

[0829] In compound (L-23), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX360).

[0830] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX361).

[0831] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX362).

[0832] In the compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX363).

[0833] In the compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX364).

[0834] In the compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX365).

[0835] In the compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX366).

[0836] In the compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX367).

[0837] In the compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX368).

[0838] In the compound (L-23), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX369).

[0839] In the compound (L-23), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX370).

[0840] In the compound (L-23), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX371).

[0841] In the compound (L-23), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX372).

[0842] [Chemical formula 44]

[0843]

[0844] In the compound represented by formula (L-24) (hereinafter referred to as compound (L-24)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX373).

[0845] In the compound (L-24), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX374).

[0846] In compound (L-24), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX375).

[0847] In compound (L-24), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX376).

[0848] In compound (L-24), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX377).

[0849] In compound (L-24), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX378).

[0850] In compound (L-24), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX379).

[0851] In compound (L-24), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX380).

[0852] In compound (L-24), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX381).

[0853] In compound (L-24), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX382).

[0854] In compound (L-24), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX383).

[0855] In compound (L-24), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX384).

[0856] In compound (L-24), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX385).

[0857] In compound (L-24), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX386).

[0858] In compound (L-24), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX387).

[0859] In compound (L-24), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX388).

[0860] [Chemical formula 45]

[0861]

[0862] In the compound represented by formula (L-25) (hereinafter referred to as compound (L-25)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX389).

[0863] In compound (L-25), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX390).

[0864] In compound (L-25), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX391).

[0865] In the compound (L-25), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX392).

[0866] In the compound (L-25), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX393).

[0867] In the compound (L-25), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX394).

[0868] In the compound (L-25), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX395).

[0869] In the compound (L-25), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX396).

[0870] In the compound (L-25), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX397).

[0871] In the compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX398).

[0872] In the compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX399).

[0873] In the compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX400).

[0874] In the compound (L-25), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX401).

[0875] In the compound (L-25), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX402).

[0876] In the compound (L-25), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX403).

[0877] In the compound (L-25), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX404).

[0878] [Chemical Formula 46]

[0879]

[0880] In the compound represented by formula (L-26) (hereinafter referred to as compound (L-26)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX409).

[0881] In compound (L-26), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX410).

[0882] In compound (L-26), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX411).

[0883] In compound (L-26), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX412).

[0884] In compound (L-26), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX413).

[0885] In compound (L-26), R 2a is methyl, and R 2b is a hydrogen atom, and B 4 is a nitrogen atom, and R 3b is a hydrogen atom, and R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX414).

[0886] In compound (L-26), R 2a is methyl, and R 2b is a hydrogen atom, and B 4 is CH, and R 3d is a hydrogen atom, and R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX415).

[0887] In compound (L-26), R 2a is methyl, and R 2b is a hydrogen atom, and B 4 is a nitrogen atom, and R 3d is a hydrogen atom, and R 3b It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX416).

[0888] In compound (L-26), R 2a is ethyl, and R 2b is a hydrogen atom, and B 4 is CH, and R 3b is a hydrogen atom, and R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX417).

[0889] In compound (L-26), R 2a is ethyl, and R 2b is a hydrogen atom, and B 4 is a nitrogen atom, and R 3b is a hydrogen atom, and R 3d It is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX418).

[0890] In compound (L-26), R 2a is ethyl, and R 2b is a hydrogen atom, and B 4 is CH, and R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX419).

[0891] In compound (L-26), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX420).

[0892] In compound (L-26), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX421).

[0893] In compound (L-26), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX422).

[0894] In compound (L-26), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX423).

[0895] In compound (L-26), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX424).

[0896] [Chemical formula 47]

[0897]

[0898] In the compound represented by formula (L-27) (hereinafter referred to as compound (L-27)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX425).

[0899] In compound (L-27), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX426).

[0900] In compound (L-27), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX427).

[0901] In compound (L-27), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX428).

[0902] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX429).

[0903] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX430).

[0904] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX431).

[0905] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX432).

[0906] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX433).

[0907] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX434).

[0908] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX435).

[0909] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX436).

[0910] In compound (L-27), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX437).

[0911] In compound (L-27), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX438).

[0912] In compound (L-27), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX439).

[0913] In compound (L-27), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX440).

[0914] [Chemical formula 48]

[0915]

[0916] In the compound represented by formula (L-28) (hereinafter referred to as compound (L-28)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX441).

[0917] In compound (L-28), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX442).

[0918] In compound (L-28), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX443).

[0919] In compound (L-28), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX444).

[0920] In compound (L-28), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX445).

[0921] In compound (L-28), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX446).

[0922] In compound (L-28), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX447).

[0923] In compound (L-28), R 2a is a methyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX448).

[0924] In compound (L-28), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX449).

[0925] In compound (L-28), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX450).

[0926] In compound (L-28), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX451).

[0927] In compound (L-28), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX452).

[0928] In compound (L-28), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX453).

[0929] In compound (L-28), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX454).

[0930] In compound (L-28), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX455).

[0931] In compound (L-28), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX456).

[0932] [Chemical formula 49]

[0933]

[0934] In the compound represented by formula (L-29) (hereinafter referred to as compound (L-29)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX457).

[0935] In compound (L-29), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX458).

[0936] In compound (L-29), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX459).

[0937] In compound (L-29), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX460).

[0938] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX461).

[0939] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX462).

[0940] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX463).

[0941] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX464).

[0942] In compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX465).

[0943] In the compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX466).

[0944] In the compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX467).

[0945] In the compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX468).

[0946] In the compound (L-29), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX469).

[0947] In the compound (L-29), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX470).

[0948] In the compound (L-29), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX471).

[0949] In the compound (L-29), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX472).

[0950] [Chemical formula 50]

[0951]

[0952] In the compound represented by formula (L-30) (hereinafter referred to as compound (L-30)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX473).

[0953] In compound (L-30), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, and R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX474).

[0954] In compound (L-30), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX475).

[0955] In compound (L-30), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX476).

[0956] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R3d Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX477).

[0957] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX478).

[0958] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX479).

[0959] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX480).

[0960] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX481).

[0961] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d Compounds with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX482).

[0962] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX483).

[0963] In compound (L-30), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX484).

[0964] In compound (L-30), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX485).

[0965] In compound (L-30), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX486).

[0966] In compound (L-30), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX487).

[0967] In compound (L-30), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX488).

[0968] [Chemical formula 51]

[0969]

[0970] In the compound represented by formula (L-31) (hereinafter referred to as compound (L-31)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX489).

[0971] In compound (L-31), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX490).

[0972] In compound (L-31), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX491).

[0973] In compound (L-31), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX492).

[0974] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX493).

[0975] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX494).

[0976] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX495).

[0977] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX496).

[0978] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX497).

[0979] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX498).

[0980] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX499).

[0981] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX500).

[0982] In the compound (L-31), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX501).

[0983] In the compound (L-31), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX502).

[0984] In the compound (L-31), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX503).

[0985] In the compound (L-31), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX504).

[0986] [Chemical Formula 52]

[0987]

[0988] In the compound represented by formula (L-32) (hereinafter referred to as compound (L-32)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX509).

[0989] In the compound (L-32), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX510).

[0990] In compound (L-32), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX511).

[0991] In compound (L-32), R 2a and R 2b are hydrogen atoms, B 4 is nitrogen, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX512).

[0992] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX513).

[0993] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX514).

[0994] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX515).

[0995] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, B 4 is nitrogen, R 3dis a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX516).

[0996] In compound (L-32), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX517).

[0997] In compound (L-32), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX518).

[0998] In compound (L-32), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX519).

[0999] In compound (L-32), R 2a is an ethyl group, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX520).

[1000] In compound (L-32), R 2a and R 2b are methyl groups, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX521).

[1001] In compound (L-32), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3bis a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX522).

[1002] In compound (L-32), R 2a and R 2b are methyl groups, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX523).

[1003] In compound (L-32), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX524).

[1004] [Chemical formula 53]

[1005]

[1006] In the compound represented by formula (L-33) (hereinafter referred to as compound (L-33)), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX525).

[1007] In compound (L-33), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX526).

[1008] In compound (L-33), R 2a and R 2b are hydrogen atoms, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX527).

[1009] In compound (L-33), R 2a and R 2b are hydrogen atoms, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX528).

[1010] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX529).

[1011] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX530).

[1012] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX531).

[1013] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX532).

[1014] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX533).

[1015] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX534).

[1016] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX535).

[1017] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, B 4 is a nitrogen atom, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX536).

[1018] In compound (L-33), R 2a and R 2b are methyl, B 4 is CH, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX537).

[1019] In compound (L-33), R 2a and R 2b are methyl, B 4 is a nitrogen atom, R 3b is a hydrogen atom, R 3d is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX538).

[1020] In compound (L-33), R 2a and R 2b are methyl, B 4 is CH, R 3d is a hydrogen atom, R 3b is a compound with any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX539).

[1021] In the compound (L-33), R 2a and R 2b are methyl groups, B 4 is a nitrogen atom, R 3d is a hydrogen atom, and R 3b is a compound having any substituent described in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX540).

[1022] Next, formulation examples of the compounds of the present invention are shown. It should be noted that "parts" means parts by weight. In addition, compound S of the present invention means a compound described in compound groups SX1 to SX540.

[1023] Formulation Example 1

[1024] 35 parts of a mixture of ammonium polyoxyethylene alkyl ether sulfate and silica (weight ratio 1:1), 10 parts of any one of the compounds S of the present invention, and 55 parts of water are mixed and finely pulverized by a wet pulverization method to obtain a formulation.

[1025] Formulation Example 2

[1026] 50 parts of any one of the compounds S of the present invention, 3 parts of calcium lignosulfonate, 2 parts of sodium lauryl sulfate, and 45 parts of silica are pulverized and mixed to obtain a formulation.

[1027] Formulation Example 3

[1028] 5 parts of any one of the compounds S of the present invention, 9 parts of polyoxyethylene styrylphenyl ether, 5 parts of polyoxyethylene decyl ether (ethylene oxide addition number: 5), 6 parts of calcium dodecylbenzenesulfonate, and 75 parts of xylene are mixed to obtain a formulation.

[1029] Formulation Example 4

[1030] 2 parts of any one of the compounds S of the present invention, 1 part of silica, 2 parts of calcium lignosulfonate, 30 parts of bentonite, and 65 parts of kaolin clay are pulverized and mixed, an appropriate amount of water is added, kneaded, granulated by a granulator, and then dried to obtain a formulation.

[1031] Formulation Example 5

[1032] 10 parts of any one of the compounds S of the present invention are mixed into a mixture of 18 parts of benzyl alcohol and 9 parts of DMSO, 6.3 parts of GERONOL (registered trademark) TE250, 2.7 parts of Ethylan (registered trademark) NS-500LQ, and 54 parts of solvent naphtha are added thereto, and the mixture is mixed to obtain a formulation.

[1033] Formulation Example 6

[1034] 0.1 part of any one of the compounds S of the present invention and 39.9 parts of kerosene were mixed and dissolved, filled into an aerosol container, and 60 parts of liquefied petroleum gas (a mixture of propane, butane and isobutane; saturated vapor pressure: 0.47 MPa (25 °C)) were filled to obtain a preparation.

[1035] Formulation Example 7

[1036] 0.2 part of any one of the compounds S of the present invention, 50 parts of pyrethrum extract meal powder, 30 parts of Machilus thunbergii powder and 19.8 parts of wood powder were mixed, an appropriate amount of water was added, kneaded, and then fed to an extruder to form a plate-shaped sheet, which was made into a spiral shape by a punching machine to obtain a preparation.

[1037] Next, the efficacy of the compounds of the present invention against harmful arthropods was shown by test examples. In the following test examples, the tests were carried out at 25 °C.

[1038] Test Method 1

[1039] The test compound was formulated according to the method described in Formulation Example 1, and water containing 0.03% by volume of Shindain (registered trademark) was added thereto to prepare a dilution containing a specified concentration of the test compound.

[1040] About 30 cotton aphids (all stages) were inoculated onto cucumber (Cucumis sativus) seedlings (the stage when the second true leaf unfolds) planted in a container. One day later, the dilution was sprayed onto the seedlings at a ratio of 10 mL / seedling. Furthermore, five days later, the number of surviving insects was investigated, and the control value was calculated from the following formula.

[1041] Control value (%) = {1 - (Cb × Tai) / (Cai × Tb)} × 100

[1042] It should be noted that the letters in the formula represent the following meanings.

[1043] Cb: Number of test insects in the untreated area

[1044] Cai: Number of surviving insects at the time of investigation in the untreated area

[1045] Tb: Number of test insects in the treated area

[1046] Tai: Number of surviving insects at the time of investigation in the treated area

[1047] Here, the untreated area refers to the area where the same operations as the treated area are carried out except that the test compound is not used.

[1048] Test Example 1-1

[1049] The specified concentration was made 500 ppm, and the following compounds of the present invention were used as test compounds, and tests were conducted according to Test Method 1. As a result, all of the following compounds of the present invention showed a control value of 90% or more.

[1050] Compounds of the present invention: 1, 2, 3

[1051] Test Method 2

[1052] The test compounds were formulated according to the method described in Formulation Example 5, and water was added thereto to prepare a dilution containing the test compound at a specified concentration.

[1053] This dilution was root-irrigated at a rate of 5 mL / seedling into cucumber (Cucumis sativus) seedlings (at the stage where the second true leaf had unfolded) planted in containers. After 7 days, approximately 30 cotton aphids (all stages) were inoculated onto the leaves of the seedlings. Further, after 6 days, the number of surviving insects was investigated, and the control value was calculated from the following formula.

[1054] Control value (%) = {1 - (Cb × Tai) / (Cai × Tb)} × 100

[1055] It should be noted that the letters in the formula have the following meanings.

[1056] Cb: Number of test insects in the untreated area

[1057] Cai: Number of surviving insects at the time of investigation in the untreated area

[1058] Tb: Number of test insects in the treated area

[1059] Tai: Number of surviving insects at the time of investigation in the treated area

[1060] Here, the untreated area refers to the area where the same operations as in the treated area are carried out except that the test compound is not used.

[1061] Test Example 2-1

[1062] The specified concentration was made 1000 ppm, and the following compounds of the present invention were used as test compounds, and tests were conducted according to Test Method 2. As a result, the following compounds of the present invention showed a control value of 100%.

[1063] Compounds of the present invention: 2

[1064] Test Example 2-2

[1065] The specified concentration was made 250 ppm, and the following compounds of the present invention were used as test compounds, and tests were conducted according to Test Method 2. As a result, the following compounds of the present invention showed a control value of 100%.

[1066] Compounds of the present invention: 2

[1067] Test method 3

[1068] Prepare a preparation of the test compound according to the method described in Preparation Example 1, add water containing 0.03% by volume of Shindain (registered trademark) thereto, and prepare a dilution containing the test compound at a specified concentration.

[1069] Spray the dilution on the cabbage (Brassicae oleracea) seedlings (at the stage where the second to third true leaves are unfolded) planted in a container at a ratio of 20 mL / seedling. Then, cut off the stem and leaf parts of the seedlings, place them in a container lined with filter paper. Put 5 second-instar larvae of Spodoptera litura into it. After 5 days, count the number of surviving insects, and calculate the mortality rate of dead insects from the following formula.

[1070] Mortality rate (%) = (1 - number of surviving insects / 5) × 100

[1071] Test Example 3-1

[1072] Set the specified concentration to 500 ppm, use the following compounds of the present invention as test compounds, and conduct tests according to Test Method 3. As a result, all of the following compounds of the present invention showed a mortality rate of 80% or more.

[1073] Compounds of the present invention: 2, 3

[1074] Test method 4

[1075] Prepare a preparation of the test compound according to the method described in Preparation Example 1, add water containing 0.03% by volume of Shindain (registered trademark) thereto, and prepare a dilution containing the test compound at a specified concentration.

[1076] Spray the dilution on the cabbage (Brassicae oleracea) seedlings (at the stage where the second to third true leaves are unfolded) planted in a container at a ratio of 20 mL / seedling. Then, cut off the stem and leaf parts of the seedlings, place them in a container lined with filter paper. Put 5 second-instar larvae of Plutella xylostella into it. After 5 days, count the number of surviving insects, and calculate the mortality rate of dead insects from the following formula.

[1077] Mortality rate (%) = (1 - number of surviving insects / 5) × 100

[1078] Test Example 4-1

[1079] Set the specified concentration to 500 ppm, use the following compounds of the present invention as test compounds, and conduct tests according to Test Method 4. As a result, all of the following compounds of the present invention showed a mortality rate of 80% or more.

[1080] Compounds of the present invention: 1, 2, 3

[1081] Test method 5

[1082] Dissolve 1 mg of the test compound in 50 μL of a mixed solution of polyoxyethylene sorbitan monolaurate:acetone = 5:95 (by volume). Add water containing 0.03% by volume of Shindain (registered trademark) thereto to prepare a dilution containing the test compound at a specified concentration.

[1083] Immerse the seedlings of Zea mays in the dilution for 30 seconds. Then, place 2 of the seedlings in a petri dish (90 mm in diameter) and put 10 second-instar larvae of western corn rootworms therein. After 5 days, count the number of dead insects and calculate the mortality rate from the following formula.

[1084] Mortality rate (%) = (number of dead insects / 10) × 100

[1085] Test Example 5-1

[1086] Using the following compound of the present invention as the test compound at a specified concentration of 200 ppm, conduct a test according to Test Method 5. As a result, the following compound of the present invention showed a 100% mortality rate.

[1087] Compound of the present invention: 3

[1088] Test Method 6

[1089] Inject an acetone solution prepared such that the test compound is 800 ppm into a container with an internal volume of 50 mL, and uniformly coat the inner surface of the container such that the test compound is 40 mg / m 2 and then dry it.

[1090] Place 5 male adults of Blattella germanica in the container, close the lid. After a specified time, investigate the state of Blattella germanica and calculate the mortality rate. The mortality rate is calculated from the following formula.

[1091] Mortality rate (%) = (number of dead insects / number of test insects) × 100

[1092] Test Example 6-1

[1093] Using the following compound of the present invention as the test compound and setting the specified time to 3 days, conduct a test according to Test Method 6. As a result, the following compound of the present invention showed a 100% mortality rate.

[1094] Compound of the present invention: 3

[1095] Test Method 7

[1096] Inject an acetone solution prepared such that the test compound is 2000 ppm into a container with an internal volume of 20 mL, and uniformly coat the inner surface of the container such that the test compound is 100 mg / m2 It is uniformly coated on the inner surface of the container in such a manner and then dried.

[1097] Five larvae of Haemaphysalis longicornis are placed into the container and the lid is closed. After a specified period of time, the status of Haemaphysalis longicornis is investigated and the mortality rate is determined. The mortality rate is calculated by the following formula.

[1098] Mortality rate (%) = (number of dead insects / number of test insects) × 100

[1099] Test Example 7-1

[1100] The specified time is set to 2 days, and the following compound of the present invention is used as the test compound. The test is carried out according to Test Method 7, whereby the control effect against Haemaphysalis longicornis can be confirmed.

[1101] Test Method 8

[1102] An acetone solution prepared in such a manner that the test compound becomes 800 ppm is injected into a container with an internal volume of 20 mL, and it is uniformly coated on the inner surface of the container in such a manner that the test compound becomes 40 mg / m 2 It is uniformly coated on the inner surface of the container in such a manner and then dried.

[1103] Five female adult houseflies are placed into the container and the lid is closed. After a specified period of time, the status of the houseflies is investigated and the mortality rate is determined. The mortality rate is calculated by the following formula.

[1104] Mortality rate (%) = (number of dead insects / number of test insects) × 100

[1105] Test Example 8-1

[1106] The specified time is set to 1 day, and the following compound of the present invention is used as the test compound. The test is carried out according to Test Method 8. As a result, the following compound of the present invention shows a mortality rate of 100%.

[1107] Compound of the present invention: 3

[1108] Test Method 9

[1109] The test compound is formulated according to the method described in Formulation Example 5, and water containing 0.03% by volume of Shindain (registered trademark) is added thereto to prepare a dilution containing the test compound at a specified concentration.

[1110] The dilution is sprayed onto cabbage (Brassicae oleracea) seedlings (at the stage where the 3rd to 4th true leaves are unfolded) planted in a container at a ratio of 20 mL / seedling. Then, 10 third-instar larvae of Spodoptera litura are placed in. After 6 days, the number of surviving insects is counted, and the mortality rate is determined by the following formula.

[1111] Mortality rate (%) = (1 - number of surviving insects / 10) × 100

[1112] Test Example 9-1

[1113] Using the compound of the present invention at a specified concentration of 200 ppm as the test compound and conducting tests according to Test Method 9, as a result, all the compounds of the present invention below showed a mortality rate of over 80%.

[1114] Compounds of the present invention: 2, 3

[1115] Test Example 9-2

[1116] Using the compound of the present invention at a specified concentration of 50 ppm as the test compound and conducting tests according to Test Method 9, the control effect against Spodoptera litura can be confirmed thereby.

[1117] Test Method 10

[1118] Prepare a formulation of the test compound according to the method described in Formulation Example 5, add water containing 0.03% by volume of Shindain (registered trademark) thereto, and prepare a dilution containing the test compound at a specified concentration.

[1119] Spray the dilution on the cabbage (Brassicae oleracea) seedlings (at the stage when the 3rd to 4th true leaves are unfolded) planted in containers at a ratio of 20 mL / seedling. Then, place 10 third-instar larvae of Plutella xylostella. After 5 days, count the number of surviving insects and calculate the mortality rate from the following formula.

[1120] Mortality rate (%) = (1 - number of surviving insects / 10) × 100

[1121] Test Example 10-1

[1122] Using the compound of the present invention at a specified concentration of 200 ppm as the test compound and conducting tests according to Test Method 10, as a result, all the compounds of the present invention below showed a mortality rate of over 80%.

[1123] Compounds of the present invention: 1, 2, 3

[1124] Test Example 10-2

[1125] Using the compound of the present invention at a specified concentration of 50 ppm as the test compound and conducting tests according to Test Method 10, as a result, all the compounds of the present invention below showed a mortality rate of over 80%.

[1126] Compounds of the present invention: 2, 3

[1127] Test Method 11

[1128] The test compound was formulated according to the method described in Preparation Example 5, and water containing 0.03% by volume of Shindain (registered trademark) was added thereto to prepare a dilution containing the test compound at a specified concentration.

[1129] Approximately 30 cotton aphids (all stages) were inoculated onto cucumber (Cucumis sativus) seedlings (at the stage when the second true leaf had unfolded) planted in containers. One day later, the dilution was sprayed onto the seedlings at a rate of 10 mL / seedling. Furthermore, five days later, the number of surviving insects was investigated, and the control value was calculated using the following formula.

[1130] Control value (%) = {1 - (Cb × Tai) / (Cai × Tb)} × 100

[1131] It should be noted that the letters in the formula have the following meanings.

[1132] Cb: Number of test insects in the untreated area

[1133] Cai: Number of surviving insects at the time of investigation in the untreated area

[1134] Tb: Number of test insects in the treated area

[1135] Tai: Number of surviving insects at the time of investigation in the treated area

[1136] Here, the untreated area refers to the area where the same operations as in the treated area are carried out except that the test compound is not used.

[1137] Test Example 11-1

[1138] The specified concentration was set at 200 ppm, and the following compounds of the present invention were used as test compounds. Tests were conducted according to Test Method 11. As a result, all of the following compounds of the present invention showed a control value of 90% or more.

[1139] Compounds of the present invention: 1, 2, 3

[1140] Test Example 11-2

[1141] The specified concentration was set at 50 ppm, and the following compounds of the present invention were used as test compounds. Tests were conducted according to Test Method 11. As a result, all of the following compounds of the present invention showed a control value of 90% or more.

[1142] Compounds of the present invention: 1, 2, 3

[1143] Test Method 12

[1144] The test compound was formulated according to the method described in Preparation Example 1, and water was added thereto to prepare a dilution containing the test compound at a specified concentration.

[1145] Put 30 final instar larvae of Culex pipiens pallens into this diluent, investigate the state of the Culex pipiens pallens larvae after 1 day, and calculate the mortality rate. The mortality rate is calculated by the following formula.

[1146] Mortality rate (%) = (Number of dead insects / Number of test insects) × 100

[1147] Test Example 12-1

[1148] Make the specified concentration 3.5 ppm, use the following compound of the present invention as the test compound, and conduct the test according to Test Method 12, whereby the control effect against Culex pipiens pallens larvae can be confirmed.

[1149] Test Method 13

[1150] Dissolve 1 mg of the compound of the present invention in 10 μL of a mixed solution of xylene:DMF:surfactant = 4:4:1 (volume ratio), and dilute it with water containing 0.02% by volume of a spreading agent to prepare Diluent A containing the compound of the present invention at a specified concentration.

[1151] Dissolve 1 mg of this component in 10 μL of a mixed solution of xylene:DMF:surfactant = 4:4:1 (volume ratio), and dilute it with water containing 0.02% by volume of a spreading agent to prepare Diluent B containing this component at a specified concentration.

[1152] Mix Diluent A and Diluent B to obtain Diluent C.

[1153] Place cucumber cotyledon leaves (1.5 cm in length) in each well of a 24-well microplate, put 2 wingless adult cotton aphids and 8 larvae in each well, and disperse 20 μL of Diluent C in each well. This is used as the treatment area.

[1154] It should be noted that the wells where 20 μL of water containing 0.02% by volume of a spreading agent is dispersed instead of Diluent C are used as the untreated area.

[1155] After Diluent C dries, cover the upper part of the microplate with a membrane. After 5 days, investigate the number of surviving insects in each well.

[1156] Calculate the control value by the following formula.

[1157] Control value (%) = {1 - (Tai) / (Cai)} × 100

[1158] It should be noted that the symbols in the formula represent the following meanings.

[1159] Cai: Number of surviving insects at the time of investigation in the untreated area

[1160] Tai: Number of surviving insects at the time of investigation in the treatment area

[1161] Regarding the specific diluent C for which the effect can be confirmed by Test Method 13, it is shown in the following (1) to (5).

[1162] (1) Among the combinations described in List A, diluent C in which the concentration of the compound of the present invention is 200 ppm and the concentration of this component is 2000 ppm. It should be noted that in List A, Comp X refers to any one compound selected from the compound groups SX1 to SX540.

[1163] List A:

[1164] Compound X + clothianidin; Compound X + thiamethoxam; Compound X + imidacloprid; Compound X + thiacloprid; Compound X + flupyradifurone; Compound X + sulfoxaflor; Compound X + triflumezopyrim; Compound X + dichlorothiazopyrim; Compound X + beta-cyfluthrin; Compound X + tefluthrin; Compound X + fipronil; Compound X + chlorantraniliprole; Compound X + cyantraniliprole; Compound X + tetramicarb; Compound X + thiodicarb; Compound X + carbofuran; Compound X + fluxametamide; Compound X + afoxolaner; Compound X + fluralaner; Compound X + broflanilide; Compound X + abamectin; Compound X + fluopyram; Compound X + flumorph; Compound X + triflumizole; Compound X + thifluzamide; Compound X + fluopyrim; Compound X + mycorrhizal fungi; Compound X + Bradyrhizobium japonicum TA-11 strain; Compound X + Bacillus firmus; Compound X + Bacillus firmus I-1582 strain; Compound X + Bacillus amyloliquefaciens; Compound X + Bacillus amyloliquefaciens FZB42 strain; Compound X + Pasteuria; Compound X + Pasteuria Pn1 strain; Compound X + Bacillus badius; Compound X + tebuconazole; Compound X + prothioconazole; Compound X + metconazole; Compound X + ipconazole; Compound X + triadimenol; Compound X + difenoconazole; Compound X + imazalil; Compound X + triadimenol; Compound X + fluconazole; Compound X + difenoconazole; Compound X + mandestrobin; Compound X + azoxystrobin; Compound X + pyraclostrobin; Compound X + tricyclazole; Compound X + fluoxastrobin; Compound X + picoxystrobin; Compound X + fenamidone; Compound X + metalaxyl; Compound X + metalaxyl-M; Compound X + fludioxonil; Compound X + fluxapyroxad; Compound X + sedaxane; Compound X + boscalid; Compound X + pyraclostrobin; Compound X + boscalid; Compound X + captan; Compound X + thiram; Compound X + tolclofos-methyl; Compound X + thiabendazole; Compound X + ethaboxam; Compound X + mancozeb; Compound X + tetraconazole; Compound X + oxathiapiprolin; Compound X + silthiofam; Compound X...

Claims

1. A compound of formula (I) or its N-oxide, [Chemical formula 1] In formula (I), Q represented by the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents the bonding site to the sulfur atom, ● represents the bonding site to Het), [Chemical formula 2] [Chemical formula 3] A 1a represents NR 5a , an oxygen atom or a sulfur atom, A 1b represents an oxygen atom or a sulfur atom, G 1 、G 2 、G 3 and G 4 are represented by the combination of: G 1 is a nitrogen atom or CR 3a , G 2 is CR 3b , G 3 is CR 3d , G 4 is CR 3c ; G 1 is CR 3a ; G 2 is a nitrogen atom; G 3 is CR 3d ; G 4 is CR 3c combination; G 1 is CR 3a ; G 2 is CR 3b ; G 3 is a nitrogen atom; G 4 is CR 3c combination; or G 1 is CR 3a ,G 2 is CR 3b ,G 3 is CR 3d ,G 4 is a combination of nitrogen atoms R 2a and R 2b are the same as or different from each other, and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom; or R 2a and R 2b may together with the nitrogen atom to which they are bonded form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group, R 3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3g 、R 3i and R 3k are the same as or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group E, a phenyl group which may be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group H, OR 12 、NR 11 R 12 、NR 11a R 12a 、NR 24 NR 11 R 12 、NR 24 OR 11 、NR 11 C(O)R 13 、NR 24 NR 11 C(O)R 13 、NR 11 C(O)OR 14 、NR 24 NR 11 C(O)OR 14 、NR 11 C(O)NR 31 R 32 、NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 、CR 30 =NOR 17 、NR 11 CR 24 =NOR 17 、S(O) q R 23 、a cyano group, a nitro group, a hydrogen atom or a halogen atom, R 3e and R 3h which are the same as or different from each other, represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a phenyl group which may be substituted by one or more substituents selected from the group H, When Q is a group represented by formula Q1, R 3a and R 3b or R 3b and R 3d may together with the two carbon atoms to which they are bonded form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring may be substituted with one or more substituents selected from group H}, or a triazole ring which may be substituted with one or more substituents selected from group I p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a halogen atom, OR 35 、NR 36 R 37 、or a hydrogen atom, R 17 represents a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, a phenyl group that can be substituted by one or more substituents selected from Group D, or a hydrogen atom. R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from group J, a phenyl group which may be substituted by one or more substituents selected from group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a hydrogen atom, or S(O)2R 23 , R 23 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, or a phenyl group which may be substituted by one or more substituents selected from Group D R 11a and R 12a together with the nitrogen atom to which they are bonded form a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E, R 13 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, or a hydrogen atom R 14 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted by one or more halogen atoms, or a phenylC1-C3 alkyl group {the phenyl moiety in the phenylC1-C3 alkyl group may be substituted by one or more substituents selected from group D}, R 15 and R 16 which are the same as or different from each other, represent C1-C6 alkyl groups which may be substituted by one or more halogen atoms, R 31 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, or a hydrogen atom Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, or a group represented by formula Het4, [Chemical formula 4] A 2 represents a nitrogen atom or CR 4a , A 3 represents NR 5b , an oxygen atom, a sulfur atom or CHR 4b , A 4 represents NR 5c , an oxygen atom or a sulfur atom, W 1 represents an oxygen atom or a sulfur atom, When Het is a group represented by formula Het3, Q represents a group represented by formula Q2, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7, When Het is a group represented by formula Het4, Q represents a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7, B 1 、 B 2 、 B 3 and B 4 in combination indicate: B 1 is a nitrogen atom or CR 6a ; B 2 is CR 6e ; B 3 is a nitrogen atom or CR 6c ; B 4 is a nitrogen atom or CR 6d ; or B 1 is a nitrogen atom or CR 6a ,B 2 is a nitrogen atom or CR 6b ,B 3 is CR 6e ,B 4 is a nitrogen atom or CR 6d in combination R 4a 、R 4b 、R 6a 、R 6b 、R 6c and R 6d are the same as or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, nitro group, OR 18 、NR 18 R 19 、cyano group, amino group, halogen atom or hydrogen atom, R 6e represents a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , a halogen atom or OS(O)2R 7 , R 5a represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom R 5b and R 5c which are the same as or different from each other, represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, or a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, R 7 represents a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms m represents 0, 1 or 2, R 18 and R 35 which are the same as or different from each other, represent C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, R 11 、R 19 、R 24 、R 36 and R 37 are the same as or different from each other, and represent a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, or a hydrogen atom. Group B: A group consisting of C1-C6 alkoxy which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy which may be substituted by one or more halogen atoms, C1-C6 alkylthio which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, cyano, hydroxyl and halogen atoms, Group C: A group consisting of C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, C1-C6 alkoxy which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy which may be substituted by one or more halogen atoms, and halogen atoms, Group D: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a hydroxyl group, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a thioalkyl group, a C1-C6 alkylthio group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, a C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, an amino group, NHR 21 、NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 、a cyano group, a nitro group and a halogen atom R 21 and R 22 which are the same as or different from each other, represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, Group E: A group consisting of C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, C1-C6 alkoxy which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy which may be substituted by one or more halogen atoms, halogen atoms, oxo group, hydroxyl, cyano and nitro, Group F: C1-C6 alkoxy which may be substituted by one or more halogen atoms, phenyl which may be substituted by one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, C3-C7 cycloalkyl which may be substituted by one or more halogen atoms, 3-7 membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from Group C, amino, NHR 21 , NR 21 R 22 , a group consisting of a halogen atom and a cyano group Group H: consisting of a C1-C6 alkyl group that can be substituted by one or more halogen atoms, OR 10 、NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 、NR 10 C(O)R 9 、NR 10 C(O)OR 9 、C(O)OR 10 、a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group, R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group I: A group consisting of C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, phenyl which may be substituted by one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, C2-C6 alkylcarbonyl which may be substituted by one or more halogen atoms, C2-C6 alkoxycarbonyl which may be substituted by one or more halogen atoms, aminocarbonyl, (C1-C6 alkyl)aminocarbonyl which may be substituted by one or more halogen atoms, methyl and di(C1-C4 alkyl)aminocarbonyl which may be substituted by one or more halogen atoms, Group J: A group consisting of a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a halogen atom, and a cyano group.

2. The compound or its N-oxide according to claim 1, wherein, Q is a group represented by formula Q1 or a group represented by formula Q5.

3. The compound or its N-oxide according to claim 1, wherein, Q is a group represented by formula Q5.

4. The compound or its N-oxide according to any one of claims 1 to 3, wherein, Het is a group represented by Het1, A 2 is a nitrogen atom, B 1 is CR 6a , B 2 is CR 6e , B 3 is CR 6c , B 4 is CR 6d .

5. The compound or its N-oxide according to any one of claims 1 to 3, wherein, Het is a group represented by Het3, B 1 is CR 6a , B 2 is CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d .

6. A pest arthropod control composition, which contains an inert carrier and the compound or its N-oxide according to any one of claims 1 to 5.

7. A composition, which contains one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound or its N-oxide according to any one of claims 1 to 5. Group (a): A group consisting of an insecticidal active ingredient, a miticidal active ingredient, and a nematicidal active ingredient. Group (b): A bactericidal active ingredient. Group (c): A plant growth regulating ingredient. Group (d): A repellent ingredient.

8. A method for controlling harmful arthropods, wherein, Apply an effective amount of the compound or its N-oxide according to any one of claims 1 to 5 or an effective amount of the composition according to claim 7 to pest arthropods or the habitats of pest arthropods.

9. A seed or vegetative propagation organ, which retains an effective amount of the compound or its N-oxide according to any one of claims 1 to 5 or an effective amount of the composition according to claim 7.

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