Wear-resistant and tear-resistant chinlon fabric and processing method thereof

Abstract

The invention belongs to the technical field of chinlon fabrics, and particularly provides a wear-resistant and tear-resistant chinlon fabric which comprises a fabric base body and a wear-resistant coating arranged on the surface of the fabric base body. The fabric base body is prepared from the following raw materials in parts by weight: 85-95 parts of chinlon master batch, 2-5 parts of graphene, 1-3 parts of silicon carbide, 0.5-1.5 parts of a coupling agent, 0.2-0.5 part of an antioxidant and 0.3-0.8 part of a lubricant; the wear-resistant coating comprises a resin adhesive and a wear-resistant filler. The wear-resistant and tear-resistant chinlon fabric prepared by the invention has the advantage of good wear resistance.

Description

Technical Field

[0001] The present application belongs to the technical field of nylon fabrics, and in particular relates to a wear-resistant and tear-resistant nylon fabric and a processing method thereof. Background Art

[0002] Nylon fabrics are widely used in many fields due to their excellent strength and wear resistance. However, in some specialized industries with extremely high requirements for wear and tear resistance, such as outdoor sports equipment, industrial protective clothing, and military equipment, the performance of ordinary nylon fabrics still cannot meet actual use needs.

[0003] In response to the problem of insufficient wear resistance and tear resistance of nylon fabrics, researchers have proposed a variety of modification methods. For example, by increasing the twist of the yarn, adopting a high-density weaving process or increasing the thickness of the fabric, its wear resistance can be improved to a certain extent. However, these methods often cause the fabric to feel harder and its breathability to decrease, affecting wearing comfort. In addition, some companies use coating or impregnation processes to form a wear-resistant protective layer on the surface of the fabric, such as polyurethane (PU) coating, polytetrafluoroethylene (PTFE) coating, etc. Although these coatings can enhance the wear resistance of the fabric to a certain extent, their durability is limited. They are easy to peel off after multiple washings or long-term use, affecting the long-term performance of the fabric.

[0004] For example, patent application publication number CN115897225A discloses a high-strength, wear-resistant nylon fabric and its preparation process. The process comprises the following steps: first, preparing a modified nylon fiber containing nylon, a black masterbatch, and a transition metal salt; then, blending and twisting the modified nylon fiber with other fiber materials to form a grey fabric; and finally, cleaning, impregnating, and drying the fabric to form the nylon fabric. By adding the modified nylon fiber to the nylon fabric, the resulting nylon fabric possesses the characteristics of the modified nylon fiber, resulting in enhanced wear resistance.

[0005] For example, the patent application document with application publication number CN118422369A discloses an antibacterial and wear-resistant nylon fiber and a preparation method thereof. By adding composite fillers to the raw materials for preparing the nylon fiber and coating the outside of the fiber with a coating made of a composite finishing agent as raw material, the nylon fiber has good antibacterial and wear-resistant properties; the cross-linked network formed by the composite finishing agent is combined with the rigid group, and it also contains a structure that undergoes self-repairing behavior under ultraviolet irradiation, so that the coating formed by it has good wear resistance, and because the coating and the fiber are connected by a strong chemical bond, the coating is prevented from falling off.

[0006] While existing technologies have improved the wear resistance of nylon fabrics to some extent, they still face numerous limitations. First, many modification methods improve performance while sacrificing comfort and lightness, making them difficult to meet the demands of the high-end textile market. Second, some modification processes rely on high-cost materials or complex processing steps, limiting their large-scale application. Therefore, developing a nylon fabric that maintains its inherent excellent properties while significantly improving its wear and tear resistance is of great significance. Summary of the Invention

[0007] In view of the above problems, in order to further improve the wear resistance of nylon fabric and meet specific application environments, the present application provides a wear-resistant and tear-resistant nylon fabric and a processing method thereof.

[0008] The present application first provides a wear-resistant and tear-resistant nylon fabric, including a fabric base and a wear-resistant coating arranged on the surface of the fabric base; the fabric base is made of raw materials including the following parts by weight: 85-95 parts of nylon masterbatch, 2-5 parts of graphene, 1-3 parts of silicon carbide, 0.5-1.5 parts of coupling agent, 0.2-0.5 parts of antioxidant, and 0.3-0.8 parts of lubricant; the wear-resistant coating includes a resin adhesive and a wear-resistant filler.

[0009] Furthermore, the resin adhesive is one of polyvinyl chloride, polyvinyl alcohol, polyethylene, epoxy resin, and polyurethane.

[0010] Furthermore, the wear-resistant filler is prepared by the following steps:

[0011] 1) After alkali leaching and acid washing, the cellulose is crushed and ground to obtain an intermediate material;

[0012] 2) zirconium tetrachloride, 2-aminoterephthalic acid, intermediate material and solvent are mixed evenly, sealed for reaction, washed, dried, roasted and ground to obtain the product.

[0013] Furthermore, the mass ratio of the zirconium tetrachloride to the intermediate material is 1:(1.5-2).

[0014] Furthermore, the average particle size of the wear-resistant filler is 200-350 nm.

[0015] The present application also provides a process for processing wear-resistant and tear-resistant nylon fabric, comprising the following steps:

[0016] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant in proportion, mix them evenly, melt-spin to obtain fiber material, and weave the fiber material to obtain a fabric matrix;

[0017] S2: placing the fabric substrate in the impregnation liquid for impregnation treatment, taking it out and drying it for later use;

[0018] S3: taking a resin adhesive and a wear-resistant filler and mixing them evenly to obtain a modifying liquid, then padding the impregnated fabric substrate in the modifying liquid, and drying and solidifying it to obtain the fabric substrate, which is prepared by the above-mentioned preparation method.

[0019] Furthermore, the impregnation solution includes water, organic acid and divalent metal salt.

[0020] Furthermore, the divalent metal salt is one or more of calcium chloride, copper chloride, and zinc chloride.

[0021] Furthermore, the concentration of the divalent metal salt in the impregnation solution is 2-5 wt %.

[0022] Furthermore, the organic acid is at least one of formic acid, acetic acid, and hydroxyproline.

[0023] Compared with the prior art, this application has the following beneficial effects:

[0024] 1. This application uses nylon masterbatch and graphene, silicon carbide and other components for mixed melt spinning. The resulting fiber material has better wear resistance and surface adhesion. On the one hand, it improves the overall wear resistance of the fabric. On the other hand, it also enhances the bonding force between the wear-resistant coating and the fabric matrix, improving the problem of subsequent peeling and shedding of the coating due to factors such as use and washing.

[0025] 2. After the fabric substrate of the present application is treated with the impregnation liquid, the metal ions can undergo complexation with the amide groups on the fiber surface, which can increase the number of polar groups and specific surface area on the fabric fiber surface, and further enhance the interfacial bonding strength between the wear-resistant coating and the fabric.

[0026] 3. The wear-resistant coating of the present application is composed of a resin binder and a wear-resistant filler. The wear-resistant filler uses cellulose as a carrier. Then, zirconium ions react with 2-aminoterephthalic acid in the carrier to form a porous organic material. After calcination, it can form toughened porous particles, which can form an anisotropic dispersion system in the wear-resistant coating, thereby improving the crosslinking density and adhesion of the wear-resistant coating. In addition, the introduction of the wear-resistant filler can effectively anchor the coating. The porous structure of the wear-resistant filler can limit the movement of the surrounding resin binder macromolecules, reduce the friction loss of the wear-resistant coating, and thus improve the wear resistance of the fabric. BRIEF DESCRIPTION OF THE DRAWINGS

[0027] Figure 1 Schematic diagram of friction performance test data of fabrics of Examples 1-3 and Control Groups 1-2 of the present application. DETAILED DESCRIPTION

[0028] The following will be combined with the drawings in the embodiments of this application to clearly and completely describe the technical solutions in the embodiments of this application. Obviously, the embodiments described are only part of the embodiments of this application, not all of the embodiments. Based on the embodiments in this application, all other embodiments obtained by ordinary technicians in this field without making creative efforts are within the scope of protection of this application.

[0029] After a large number of experimental studies, this application selected porous nanoparticles as the development direction based on traditional wear-resistant fillers such as carbon nanotubes, silica, titanium dioxide, boron nitride, etc., which further improved the wear resistance of wear-resistant nylon fabrics and broadened the application range of nylon fabrics in more harsh use environments.

[0030] Specifically, the present application provides a wear-resistant and tear-resistant nylon fabric, comprising a fabric base and a wear-resistant coating arranged on the surface of the fabric base; the fabric base is made of raw materials comprising the following parts by weight: 85-95 parts of nylon masterbatch, 2-5 parts of graphene, 1-3 parts of silicon carbide, 0.5-1.5 parts of coupling agent, 0.2-0.5 parts of antioxidant, and 0.3-0.8 parts of lubricant; the wear-resistant coating comprises a resin adhesive and a wear-resistant filler.

[0031] In some specific embodiments, the fabric substrate can be made from the following raw materials in parts by weight: 85 parts nylon masterbatch, 5 parts graphene, 1 part silicon carbide, 0.5 parts coupling agent, 0.2 parts antioxidant, and 0.8 parts lubricant. Alternatively, it can be made from the following raw materials in parts by weight: 95 parts nylon masterbatch, 2 parts graphene, 3 parts silicon carbide, 1.5 parts coupling agent, 0.5 parts antioxidant, and 0.3 parts lubricant. Typically, when the fabric substrate is made from the following raw materials in parts by weight: 90 parts nylon masterbatch, 3 parts graphene, 2 parts silicon carbide, 1 part coupling agent, 0.5 parts antioxidant, and 0.5 parts lubricant, better experimental results can be achieved.

[0032] Furthermore, the resin adhesive is one of polyvinyl chloride, polyvinyl alcohol, polyethylene, epoxy resin, and polyurethane.

[0033] In some specific embodiments, better experimental results can be obtained when the resin adhesive is polyvinyl alcohol and epoxy resin. More preferably, the resin adhesive is composed of polyvinyl alcohol and epoxy resin in a mass ratio of 1:0.2.

[0034] Furthermore, the wear-resistant filler is prepared by the following steps:

[0035] 1) After alkali leaching and acid washing, the cellulose is crushed and ground to obtain an intermediate material;

[0036] 2) zirconium tetrachloride, 2-aminoterephthalic acid, intermediate material and solvent are mixed evenly, sealed for reaction, washed, dried, roasted and ground to obtain the product.

[0037] Furthermore, the mass ratio of the zirconium tetrachloride to the intermediate material is 1:(1.5-2).

[0038] Furthermore, the average particle size of the wear-resistant filler is 200-350 nm.

[0039] In some specific embodiments, the mass ratio of the zirconium tetrachloride to the intermediate material can be 1:1.5, 1:1.55, 1:1.6, 1:1.65, 1:1.7, 1:1.75, 1:1.8, 1:1.85, 1:1.9, 1:1.95, or 1:2. Generally, when the mass ratio of the zirconium tetrachloride to the intermediate material is 1:1.85, better experimental results can be obtained.

[0040] In some specific embodiments, the average particle size of the wear-resistant filler can be 200 nm, 250 nm, 280 nm, 300 nm, 320 nm, or 350 nm. Generally, when the average particle size of the wear-resistant filler is 250 nm, better experimental results can be obtained.

[0041] The present application also provides a process for processing wear-resistant and tear-resistant nylon fabric, comprising the following steps:

[0042] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant in proportion, mix them evenly, melt-spin to obtain fiber material, and weave the fiber material to obtain a fabric matrix;

[0043] S2: placing the fabric substrate in the impregnation liquid for impregnation treatment, taking it out and drying it for later use;

[0044] S3: taking a resin adhesive and a wear-resistant filler and mixing them evenly to obtain a modifying liquid, then padding the impregnated fabric substrate in the modifying liquid, and drying and solidifying it to obtain the fabric substrate, which is prepared by the above-mentioned preparation method.

[0045] Furthermore, the impregnation solution includes water, organic acid and divalent metal salt.

[0046] Furthermore, the divalent metal salt is one or more of calcium chloride, copper chloride, and zinc chloride.

[0047] Furthermore, the concentration of the divalent metal salt in the impregnation solution is 2-5 wt %.

[0048] Furthermore, the organic acid is at least one of formic acid, acetic acid, and hydroxyproline.

[0049] In some specific embodiments, the divalent metal salt is composed of calcium chloride and zinc chloride in a mass ratio of 1:(3-5). More preferably, the divalent metal salt can be composed of calcium chloride and zinc chloride in a mass ratio of 1:3, 1:35, 1:4, 1:4.5, or 1:5. Generally, when the divalent metal salt is composed of calcium chloride and zinc chloride in a mass ratio of 1:5, better experimental results can be obtained.

[0050] In some specific embodiments, the concentration of the divalent metal salt in the impregnation solution can be 2wt%, 2.5wt%, 2.8wt%, 3wt%, 3.2wt%, 3.5wt%, 3.7wt%, 4wt%, 4.3wt%, 4.5wt%, 4.6wt%, 4.8wt%, or 5wt%. Generally, when the concentration of the divalent metal salt in the impregnation solution is 3wt%, better experimental results can be obtained.

[0051] In some specific embodiments, the organic acid may be composed of formic acid and hydroxyproline. More preferably, when the organic acid is composed of formic acid and hydroxyproline at a mass ratio of 1:0.15, better experimental results can be obtained.

[0052] In some specific embodiments, the mass ratio of the resin binder to the wear-resistant filler is 1:(0.01-0.02). Generally, a mass ratio of the resin binder to the wear-resistant filler of 1:0.015 can achieve better experimental results.

[0053] Example 1

[0054] The wear-resistant and tear-resistant nylon fabric of this embodiment includes a fabric base and a wear-resistant coating provided on the surface of the fabric base.

[0055] The fabric matrix of this embodiment is made of raw materials including the following parts by weight: 90 kg of nylon masterbatch, 3 kg of graphene, 2 kg of silicon carbide, 1 kg of coupling agent, 0.5 kg of antioxidant, and 0.5 kg of lubricant.

[0056] The nylon masterbatch has a relative viscosity of 2.6-3.2 and a number average molecular weight of 20,000. The graphene particle size is 2000 mesh. The average particle size of the silicon carbide is 300 nm. The coupling agent is KH-550. The antioxidant is antioxidant 1010. The lubricant is calcium stearate.

[0057] The wear-resistant coating of this embodiment includes a resin binder and a wear-resistant filler, wherein the resin binder is polyvinyl alcohol (PVA-205) and epoxy resin (E-51) in a mass ratio of 1:0.2. The wear-resistant filler is aluminum oxide with an average particle size of 250 nm.

[0058] The processing technology of the wear-resistant and tear-resistant nylon fabric of this embodiment includes the following steps:

[0059] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant according to the above weight proportions, mix them evenly, melt-spin to obtain a fiber material, and weave the fiber material to obtain a fabric matrix;

[0060] S2: The fabric substrate is immersed in an impregnation solution for 5 hours at a temperature of 30°C, and then taken out and dried for later use; the impregnation solution is prepared by mixing 10 kg of deionized water and 150 g of phosphoric acid;

[0061] S3: Take 10kg of resin adhesive, 0.15kg of wear-resistant filler, and 5kg of xylene (diluent) and mix them evenly to obtain a modifying liquid. Then, the impregnated fabric substrate is dipped and rolled twice in the modifying liquid, with the first rolling rate being 70% and the second rolling rate being 60%. The fabric substrate is dried and solidified at a temperature of 60°C.

[0062] Example 2

[0063] The wear-resistant and tear-resistant nylon fabric of this embodiment includes a fabric base and a wear-resistant coating provided on the surface of the fabric base.

[0064] The fabric matrix of this embodiment is made of raw materials including the following parts by weight: 90 kg of nylon masterbatch, 3 kg of graphene, 2 kg of silicon carbide, 1 kg of coupling agent, 0.5 kg of antioxidant, and 0.5 kg of lubricant.

[0065] The nylon masterbatch has a relative viscosity of 2.6-3.2 and a number average molecular weight of 20,000. The graphene particle size is 2000 mesh. The average particle size of the silicon carbide is 300 nm. The coupling agent is KH-550. The antioxidant is antioxidant 1010. The lubricant is calcium stearate.

[0066] The wear-resistant coating of this embodiment includes a resin binder and a wear-resistant filler, wherein the resin binder polyvinyl alcohol (PVA-205) and epoxy resin (E-51) are composed in a mass ratio of 1:0.2.

[0067] The wear-resistant filler of this embodiment is prepared by the following steps:

[0068] 1) 100 g of cellulose (lignocellulose powder, 100 mesh) was added to a beaker, followed by the addition of 500 mL of 15% sodium hydroxide solution. The mixture was alkali-leached for 30 min, filtered and washed, and then transferred to another beaker. 500 mL of deionized water, 10 g of sodium hypochlorite, and 5 g of benzoic acid were added. The mixture was acid-washed at a stirring speed of 150 rpm for 20 min, filtered and washed, and then pulverized to obtain an intermediate material (300 mesh).

[0069] 2) Take 2.33gZrCl4, 1.22g2-aminoterephthalic acid, and 4.31g intermediate material and place them in a 500mL reactor (Teflon liner), then add 350mL of glacial acetic acid and 300mL DMF, followed by ultrasonic mixing for 10min, and then magnetic stirring for 1h to allow the materials to be completely mixed, and then react at 120°C for 24h. After cooling to room temperature, wash alternately with deionized water and ethanol, place it in a vacuum drying oven at 80°C and dry it for 12h, then transfer it to a muffle furnace, calcine it at 500°C for 3h, and grind it to obtain the wear-resistant filler with an average particle size of 250nm.

[0070] The processing technology of the wear-resistant and tear-resistant nylon fabric of this embodiment includes the following steps:

[0071] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant according to the above weight proportions, mix them evenly, melt-spin to obtain a fiber material, and weave the fiber material to obtain a fabric matrix;

[0072] S2: The fabric substrate is immersed in an impregnation solution for 5 hours at a temperature of 30°C, and then taken out and dried for later use; the impregnation solution is prepared by mixing 10 kg of deionized water and 150 g of phosphoric acid;

[0073] S3: Take 10kg of resin adhesive, 0.15kg of wear-resistant filler, and 5kg of xylene (diluent) and mix them evenly to obtain a modifying liquid. Then, the impregnated fabric substrate is dipped and rolled twice in the modifying liquid, with the first rolling rate being 70% and the second rolling rate being 60%. The fabric substrate is dried and solidified at a temperature of 60°C.

[0074] Example 3

[0075] The wear-resistant and tear-resistant nylon fabric of this embodiment includes a fabric base and a wear-resistant coating provided on the surface of the fabric base.

[0076] The fabric matrix of this embodiment is made of raw materials including the following parts by weight: 90 kg of nylon masterbatch, 3 kg of graphene, 2 kg of silicon carbide, 1 kg of coupling agent, 0.5 kg of antioxidant, and 0.5 kg of lubricant.

[0077] The nylon masterbatch has a relative viscosity of 2.6-3.2 and a number average molecular weight of 20,000. The graphene particle size is 2000 mesh. The average particle size of the silicon carbide is 300 nm. The coupling agent is KH-550. The antioxidant is antioxidant 1010. The lubricant is calcium stearate.

[0078] The wear-resistant coating of this embodiment includes a resin binder and a wear-resistant filler, wherein the resin binder polyvinyl alcohol (PVA-205) and epoxy resin (E-51) are composed in a mass ratio of 1:0.2.

[0079] The wear-resistant filler of this embodiment is prepared by the following steps:

[0080] 1) 100 g of cellulose (lignocellulose powder, 100 mesh) was added to a beaker, followed by the addition of 500 mL of 15% sodium hydroxide solution. The mixture was alkali-leached for 30 min, filtered and washed, and then transferred to another beaker. 500 mL of deionized water, 10 g of sodium hypochlorite, and 5 g of benzoic acid were added. The mixture was acid-washed at a stirring speed of 150 rpm for 20 min, filtered and washed, and then pulverized to obtain an intermediate material (300 mesh).

[0081] 2) Take 2.33gZrCl4, 1.22g2-aminoterephthalic acid, and 4.31g intermediate material and place them in a 500mL reactor (Teflon liner), then add 350mL of glacial acetic acid and 300mL DMF, followed by ultrasonic mixing for 10min, and then magnetic stirring for 1h to allow the materials to be completely mixed, and then react at 120°C for 24h. After cooling to room temperature, wash alternately with deionized water and ethanol, place it in a vacuum drying oven at 80°C and dry it for 12h, then transfer it to a muffle furnace, calcine it at 500°C for 3h, and grind it to obtain the wear-resistant filler with an average particle size of 250nm.

[0082] The processing technology of the wear-resistant and tear-resistant nylon fabric of this embodiment includes the following steps:

[0083] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant according to the above weight proportions, mix them evenly, melt-spin to obtain a fiber material, and weave the fiber material to obtain a fabric matrix;

[0084] S2: The fabric substrate is immersed in an impregnation solution for 5 hours at a temperature of 30°C, and then taken out and dried for later use; the impregnation solution is prepared by mixing 10 kg of deionized water, 300 g of a divalent metal salt, and 150 g of an organic acid; the divalent metal salt is composed of calcium chloride and zinc chloride in a mass ratio of 1:5, and the organic acid is composed of formic acid and hydroxyproline in a mass ratio of 1:0.15;

[0085] S3: Take 10kg of resin adhesive, 0.15kg of wear-resistant filler, and 5kg of xylene (diluent) and mix them evenly to obtain a modifying liquid. Then, the impregnated fabric substrate is dipped and rolled twice in the modifying liquid, with the first rolling rate being 70% and the second rolling rate being 60%. The fabric substrate is dried and solidified at a temperature of 60°C.

[0086] Control group 1

[0087] The nylon fabric of the control group includes a fabric base and a wear-resistant coating arranged on the surface of the fabric base.

[0088] The fabric matrix of the control group was made of raw materials including the following parts by weight: 90 kg of nylon masterbatch, 1 kg of coupling agent, 0.5 kg of antioxidant, and 0.5 kg of lubricant.

[0089] The nylon masterbatch has a relative viscosity of 2.6-3.2 and a number average molecular weight of 20,000. The coupling agent is KH-550. The antioxidant is antioxidant 1010. The lubricant is calcium stearate.

[0090] The wear-resistant coating in the control group includes a resin binder and a wear-resistant filler. The resin binder is polyvinyl alcohol (PVA-205) and epoxy resin (E-51) in a mass ratio of 1:0.2. The wear-resistant filler is aluminum oxide with an average particle size of 250nm.

[0091] The processing technology of the wear-resistant and tear-resistant nylon fabric of the control group includes the following steps:

[0092] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant according to the above weight proportions, mix them evenly, melt-spin to obtain a fiber material, and weave the fiber material to obtain a fabric matrix;

[0093] S2: The fabric substrate is immersed in an impregnation solution for 5 hours at a temperature of 30°C, and then taken out and dried for later use; the impregnation solution is prepared by mixing 10 kg of deionized water and 150 g of phosphoric acid;

[0094] S3: Take 10kg of resin adhesive, 0.15kg of wear-resistant filler, and 5kg of xylene (diluent) and mix them evenly to obtain a modifying liquid. Then, the impregnated fabric substrate is dipped and rolled twice in the modifying liquid, with the first rolling rate being 70% and the second rolling rate being 60%. The fabric substrate is dried and solidified at a temperature of 60°C.

[0095] Control group 2

[0096] The nylon fabric of the control group includes a fabric base and a wear-resistant coating arranged on the surface of the fabric base.

[0097] The fabric matrix of the control group was made of raw materials including the following parts by weight: 90 kg nylon masterbatch, 3 kg graphene, 2 kg silicon carbide, 1 kg coupling agent, 0.5 kg antioxidant, and 0.5 kg lubricant.

[0098] The nylon masterbatch has a relative viscosity of 2.6-3.2 and a number average molecular weight of 20,000. The graphene particle size is 2000 mesh. The average particle size of the silicon carbide is 300 nm. The coupling agent is KH-550. The antioxidant is antioxidant 1010. The lubricant is calcium stearate.

[0099] The wear-resistant coating in the control group includes a resin binder and a wear-resistant filler. The resin binder is polyvinyl alcohol (PVA-205) and epoxy resin (E-51) in a mass ratio of 1:0.2. The wear-resistant filler is aluminum oxide with an average particle size of 250nm.

[0100] The processing technology of the wear-resistant and tear-resistant nylon fabric of the control group includes the following steps:

[0101] S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant according to the above weight proportions, mix them evenly, melt-spin to obtain a fiber material, and weave the fiber material to obtain a fabric matrix;

[0102] S2: Take 10kg of resin adhesive, 0.15kg of wear-resistant filler, and 5kg of xylene (diluent) and mix them evenly to obtain a modifying liquid. Then, the fabric substrate is dipped and rolled twice in the modifying liquid, with the first rolling rate being 70% and the second rolling rate being 60%. The fabric substrate is dried and solidified at 60°C.

[0103] Performance testing

[0104] The fabrics of Examples 1-3 and Control Groups 1-2 were tested for friction performance using a friction and wear tester using a spherical method (a steel ball with a diameter of 6 mm). The load was set to 20 N, the amplitude was 5 mm, the sliding distance was 12.5 m, and the sliding speed was 2.5 m / min. The mass difference before and after friction was measured to analyze the friction performance of the fabrics. The results are as follows: Figure 1 shown.

[0105] Combine Figure 1 It can be seen that the fabric of the present application has stronger wear resistance and can adapt to various harsh friction use environments.

[0106] Although the present application has been described in detail with reference to the aforementioned embodiments, those skilled in the art can still modify the technical solutions described in the aforementioned embodiments, or make equivalent substitutions for some of the technical features therein. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present application should be included in the scope of protection of the present invention.

Claims

1. A wear-resistant and tear-resistant nylon fabric, characterized by: The invention comprises a fabric substrate and a wear-resistant coating arranged on the surface of the fabric substrate; the fabric substrate is made of raw materials comprising the following parts by weight: 85-95 parts of nylon masterbatch, 2-5 parts of graphene, 1-3 parts of silicon carbide, 0.5-1.5 parts of coupling agent, 0.2-0.5 parts of antioxidant, and 0.3-0.8 parts of lubricant; the wear-resistant coating comprises a resin adhesive and a wear-resistant filler.

2. The wear-resistant and tear-resistant nylon fabric according to claim 1, characterized in that: The resin adhesive is one of polyvinyl chloride, polyvinyl alcohol, polyethylene, epoxy resin and polyurethane.

3. The wear-resistant and tear-resistant nylon fabric according to claim 1, characterized in that: The wear-resistant filler is prepared by the following steps: 1) After alkali leaching and acid washing, the cellulose is crushed and ground to obtain an intermediate material; 2) zirconium tetrachloride, 2-aminoterephthalic acid, intermediate material and solvent are mixed evenly, sealed for reaction, washed, dried, roasted and ground to obtain the product.

4. The wear-resistant and tear-resistant nylon fabric according to claim 3, characterized in that: The mass ratio of the zirconium tetrachloride to the intermediate material is 1:(1.5-2).

5. The wear-resistant and tear-resistant nylon fabric according to claim 3, characterized in that: The average particle size of the wear-resistant filler is 200-350 nm.

6. A process for processing the wear-resistant and tear-resistant nylon fabric according to any one of claims 1 to 5, characterized in that: The steps include: S1: Weigh nylon masterbatch, graphene, silicon carbide, coupling agent, antioxidant, and lubricant in proportion, mix them evenly, melt-spin to obtain fiber material, and weave the fiber material to obtain a fabric matrix; S2: placing the fabric substrate in the impregnation liquid for impregnation treatment, taking it out and drying it for later use; S3: taking a resin adhesive and a wear-resistant filler and mixing them evenly to obtain a modified liquid, then immersing the impregnated fabric substrate in the modified liquid, and drying and solidifying the modified liquid.

7. The processing technology of wear-resistant and tear-resistant nylon fabric according to claim 6, characterized in that: The impregnation solution includes water, an organic acid and a divalent metal salt.

8. The processing technology of wear-resistant and tear-resistant nylon fabric according to claim 7, characterized in that: The divalent metal salt is one or more of calcium chloride, copper chloride and zinc chloride.

9. The processing technology of wear-resistant and tear-resistant nylon fabric according to claim 7, characterized in that: The concentration of the divalent metal salt in the impregnation solution is 2-5 wt %.

10. The processing technology of wear-resistant and tear-resistant nylon fabric according to claim 7, characterized in that: The organic acid is at least one of formic acid, acetic acid and hydroxyproline.

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