Corrosion-resistant glass and preparation method thereof

Abstract

The invention discloses corrosion-resistant glass and a preparation method thereof, and relates to the field of glass. When the corrosion-resistant glass is prepared, a glass plate sequentially reacts with trimethoxy (thiophene-2-yl) silane, thiophene, 4-hydroxythieno [2, 3-B] pyridine-5-formonitrile and 4-dimethylaminobenzonitrile, and a functionalized glass plate is prepared; the preparation method comprises the following steps: polymerizing methyl methacrylate, acetoacetic acid glycol methacrylate, butyl acrylate and 1-allyl-4-(trifluoromethyl) benzene, mixing with 4-bromo-1-butene, illuminating, coating on a functional glass plate, and curing to obtain the corrosion-resistant glass. The corrosion-resistant glass prepared by the invention has antibacterial, antistatic and anti-aging capabilities.

Description

Technical Field

[0001] The present invention relates to the field of glass, in particular to corrosion-resistant glass and a preparation method thereof. Background Art

[0002] Modern life is inseparable from glass products. Glass is usually an amorphous inorganic non-metallic material. It is generally made of a variety of inorganic minerals as the main raw materials, and a small amount of auxiliary raw materials. Due to its transparency and beauty, it is widely used in outdoor places such as windows, solar tubes, photovoltaic panels, windshields and greenhouses.

[0003] However, outdoor places, especially the seaside, are very prone to salt spray corrosion on glass, which can cause the glass surface to become rough, reduce transparency, and even reduce strength, affecting its use; and when the glass is exposed to ultraviolet rays for a long time, the ultraviolet rays will cause chemical reactions on the glass surface, resulting in cracks and fissures in the glass. Therefore, this application introduces a corrosion-resistant glass with aging resistance and a preparation method thereof. Summary of the Invention

[0004] A corrosion-resistant glass is prepared by polymerizing methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate, and 1-allyl-4-(trifluoromethyl)benzene, mixing the mixture with 4-bromo-1-butene, irradiating the mixture with light, coating the mixture on a functionalized glass plate, and curing the mixture.

[0005] The functionalized glass plate is prepared by sequentially reacting a glass plate with trimethoxy(thiophene-2-yl)silane, thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and 4-dimethylaminobenzonitrile.

[0006] A method for preparing corrosion-resistant glass, the method mainly comprising the following preparation steps:

[0007] (1) Ferric chloride and chloroform are mixed uniformly in a mass ratio of 1:9 to 9.4 to prepare a ferric chloride solution; thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform are mixed in a mass ratio of 5 to 7:1:13, and ultrasonicated for 5 to 7 minutes to prepare a thiophene mixed solution; under nitrogen protection, a pre-modified glass plate is immersed in the thiophene mixed solution, and a ferric chloride solution 3 to 4 times the mass of the thiophene mixed solution is added at a uniform rate within 4 to 6 minutes, and the glass plate is allowed to stand for 3 to 5 minutes, and the pre-modified glass plate is taken out until no liquid drops, and the glass plate is allowed to stand for 46 to 50 hours at 30 to 40°C under nitrogen protection, and washed with chloroform 3 to 5 times, and vacuum dried at -10 to 0°C for 22 to 26 hours to prepare a modified glass plate;

[0008] (2) Polyacrylate emulsion, 4-bromo-1-butene, 4-methoxythiophenol and lithium formate are mixed in a mass ratio of 1:0.08-0.12:0.25-0.35:0.08-0.12, stirred at 600-800 r / min, argon protection, 427 nm LED light for 22-26 h, and evenly applied on a functionalized glass plate with a thickness of 0.4-0.6 mm. The mixture is allowed to stand at 55-65 ° C under argon protection for 8-12 h, washed with deionized water and ethanol for 3-5 times in sequence, and vacuum dried at -10-0 ° C for 22-26 h to obtain corrosion-resistant glass.

[0009] As an optimization, the pre-modified glass plate in step (1) is prepared by mixing a glass plate, trimethoxy(thiophene-2-yl)silane and isopropyl alcohol in a mass ratio of 1:0.14-0.16:10-12, adjusting the pH to 3.8-4.2 with a 0.1 mol / L acetic acid solution, stirring at 85-95°C and 200-300 r / min for 5-7 hours, filtering, washing with deionized water for 3-5 times, and drying at 90-100°C for 2-4 hours.

[0010] As an optimization, the glass plate is ordinary flat glass with a thickness of 5 mm, and the purchase manufacturer is Handan Mina Trading Co., Ltd.

[0011] As an optimization, the polyacrylate emulsion in step (2) is prepared by taking 4 to 6 parts of initiator solution, 14 to 16 parts of emulsifier solution and 12 to 14 parts of mixed monomers by mass, mixing the emulsifier solution, 10% of the initiator solution and 10% of the mixed monomers, stirring at 80 to 90° C., 300 to 500 r / min, under nitrogen protection for 14 to 16 minutes, adding the remaining initiator solution and mixed monomers at a uniform rate within 10 to 14 minutes, and continuing to stir for 3 to 5 hours.

[0012] As an optimization, the initiator solution is prepared by uniformly mixing ammonium persulfate and deionized water in a mass ratio of 1:350-370.

[0013] As an optimization, the emulsifier solution is prepared by uniformly mixing sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water in a mass ratio of 2:1:140-160.

[0014] As an optimization, the mixed monomer is prepared by mixing methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene in a mass ratio of 5-7:1.5-2.5:4-6:1.5-2.5.

[0015] As an optimization, the functionalized glass plate in step (2) is prepared by mixing 4-dimethylaminobenzonitrile and zinc chloride in a mass ratio of 1:0.04-0.06, grinding the mixture to 90-110 mesh, and evenly spreading the mixture on the surface of the modified glass plate with a thickness of 0.4-0.6 mm. The mixture is allowed to stand at 290-310° C. for 46-50 h, washed with ethanol for 3-5 times, and vacuum dried at -10-0° C. for 22-26 h.

[0016] Compared with the prior art, the present invention has the following beneficial effects:

[0017] When preparing the corrosion-resistant glass, the present invention comprises the following steps: reacting a glass plate with trimethoxy(thiophene-2-yl)silane, thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and 4-dimethylaminobenzonitrile in sequence to prepare a functionalized glass plate; polymerizing methyl methacrylate, ethylene glycol acetoacetate methacrylate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene, mixing the mixture with 4-bromo-1-butene, irradiating the mixture with light, coating the mixture on the functionalized glass plate and solidifying the mixture to prepare the corrosion-resistant glass.

[0018] First, the glass plate is reacted with trimethoxy(thiophene-2-yl)silane, thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and 4-dimethylaminobenzonitrile in sequence to produce a functionalized glass plate. The glass plate is then reacted with trimethoxy(thiophene-2-yl)silane, thiophene and 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile in sequence to form a polythiophene polymer on the glass surface. Polythiophene is a polymer compound with good conductivity. Polythiophene can effectively conduct static charge, avoid static electricity accumulation, and improve the antistatic ability of the material. The glass plate is then reacted with 4-dimethylaminobenzonitrile to form a triazine ring, which forms a stable conjugated six-membered ring with triazine through hydrogen bonding. Triazine can absorb ultraviolet light, convert the light into heat energy and release it, achieving an aging-resistant effect. The conjugated six-membered ring formed by hydrogen bonding with triazine also has the effect of absorbing ultraviolet light, and works together with the triazine structure to enhance the aging resistance of the material.

[0019] Secondly, methyl methacrylate, ethylene glycol methacrylate acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene are polymerized, and then mixed with 4-bromo-1-butene, exposed to light, coated on a functionalized glass plate, and cured to produce corrosion-resistant glass; methyl methacrylate, ethylene glycol methacrylate acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene are polymerized to introduce fluorine groups. The fluorine atoms have extremely strong electronegativity and can form a tightly arranged fluorine atom layer to provide chemically inert protection. The strong adsorption effect and small atomic radius of fluorine atoms enable fluorine atoms to be tightly arranged around carbon atoms to form a protective barrier, thereby improving the corrosion resistance of the material. The aromatic trifluoromethyl group can react with olefins under light to introduce chlorine groups, which react with tertiary olefins on the glass plate. Amines react to form quaternary ammonium salts. Quaternary ammonium salts carry a positive charge and can be firmly adsorbed on the negatively charged bacterial cell surface through electrostatic attraction. After adsorbing to the bacterial surface, the quaternary ammonium salt inserts the hydrophobic group into the lipid layer, changing the permeability of the cell membrane, destroying the membrane structure, and causing leakage of intracellular substances; it can also interfere with the proton pump protein on the bacterial cell membrane, causing it to degrade or denature, affecting the cell's material transport and energy metabolism, and ultimately leading to the death of the bacteria, achieving an antibacterial effect. In addition, the quaternary ammonium salt cation can form a conductive layer on the material surface, increasing the mobility of the charge on the material surface, thereby reducing the surface resistance and allowing the static charge to dissipate faster. It can also react with the negative charge on the material surface to reduce the surface charge density, balance the charge distribution on the material surface, and achieve an antistatic effect. DETAILED DESCRIPTION

[0020] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the embodiments described are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts are within the scope of protection of the present invention.

[0021] Example 1:

[0022] A method for preparing corrosion-resistant glass mainly includes the following preparation steps:

[0023] (1) A 5 mm thick glass plate, trimethoxy(thiophene-2-yl)silane and isopropanol were mixed in a mass ratio of 1:0.14:10, the pH was adjusted to 3.8 with 0.1 mol / L acetic acid solution, stirred at 85 ° C, 200 r / min for 5 h, filtered, washed with deionized water 3 times, and dried at 90 ° C for 2 h to prepare a pre-modified glass plate; ferric chloride and chloroform were mixed in a mass ratio of 1:9 to prepare a ferric chloride solution; thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform were mixed in a mass ratio of 5:1:13, ultrasonicated for 5 min, and a thiophene mixture was prepared; under nitrogen protection The pre-modified glass plate was immersed in the thiophene mixture, and a ferric chloride solution 3 times the mass of the thiophene mixture was uniformly added within 4 minutes. The mixture was allowed to stand for 3 minutes, and the pre-modified glass plate was taken out until no liquid dripped. The mixture was allowed to stand at 30°C under nitrogen protection for 46 hours, washed with chloroform 3 times, and vacuum dried at -10°C for 22 hours to obtain a modified glass plate. 4-Dimethylaminobenzonitrile and zinc chloride were mixed in a mass ratio of 1:0.04, ground to 90 mesh, and evenly spread on the surface of the modified glass plate with a thickness of 0.4 mm. The mixture was allowed to stand at 290°C for 46 hours, washed with ethanol 3 times, and vacuum dried at -10°C for 22 hours to obtain a functionalized glass plate.

[0024] (2) ammonium persulfate and deionized water were mixed at a mass ratio of 1:350 to prepare an initiator solution; sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water were mixed at a mass ratio of 2:1:140 to prepare an emulsifier solution; methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene were mixed at a mass ratio of 5:1.5:4:1.5 to prepare a mixed monomer; 4 parts of the initiator solution, 14 parts of the emulsifier solution and 12 parts of the mixed monomer were taken by mass, and the emulsifier solution, 10% of the initiator solution and 10% of the mixed monomer were mixed, and heated at 80°C and 300r / min. min, stirred for 14 min under nitrogen protection, and the remaining initiator solution and mixed monomers were added at a uniform rate within 10 min and continued to stir for 3 h to prepare a polyacrylate emulsion; the polyacrylate emulsion, 4-bromo-1-butene, 4-methoxythiophenol and lithium formate were mixed in a mass ratio of 1:0.08:0.25:0.08, stirred for 22 h at 600 r / min, argon protection and 427 nm LED light, and evenly applied on a functional glass plate with a thickness of 0.4 mm. The mixture was allowed to stand at 55°C under argon protection for 8 h, washed with deionized water and ethanol three times in sequence, and vacuum dried at -10°C for 22 h to prepare corrosion-resistant glass.

[0025] Example 2:

[0026] A method for preparing corrosion-resistant glass mainly includes the following preparation steps:

[0027] (1) A 5 mm thick glass plate, trimethoxy(thiophene-2-yl)silane and isopropanol were mixed in a mass ratio of 1:0.15:11, the pH was adjusted to 4 with 0.1 mol / L acetic acid solution, stirred at 90 ° C and 250 r / min for 6 h, filtered, washed with deionized water 4 times, and dried at 95 ° C for 3 h to obtain a pre-modified glass plate; ferric chloride and chloroform were mixed in a mass ratio of 1:9.2 to obtain a ferric chloride solution; thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform were mixed in a mass ratio of 6:1:13, ultrasonicated for 6 min to obtain a thiophene mixed solution; under nitrogen protection The pre-modified glass plate was immersed in the thiophene mixture, and a ferric chloride solution with a mass 3.5 times that of the thiophene mixture was uniformly added within 5 minutes. The mixture was allowed to stand for 4 minutes, and the pre-modified glass plate was taken out until no liquid droplets fell. The mixture was allowed to stand at 35°C under nitrogen protection for 48 hours, washed with chloroform four times, and vacuum dried at -5°C for 24 hours to obtain a modified glass plate. 4-Dimethylaminobenzonitrile and zinc chloride were mixed in a mass ratio of 1:0.05, ground to 100 mesh, and evenly spread on the surface of the modified glass plate with a thickness of 0.5 mm. The mixture was allowed to stand at 300°C for 48 hours, washed with ethanol four times, and vacuum dried at -5°C for 24 hours to obtain a functionalized glass plate.

[0028] (2) ammonium persulfate and deionized water were mixed at a mass ratio of 1:360 to prepare an initiator solution; sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water were mixed at a mass ratio of 2:1:150 to prepare an emulsifier solution; methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene were mixed at a mass ratio of 6:2:5:2 to prepare a mixed monomer; 5 parts of the initiator solution, 15 parts of the emulsifier solution and 13 parts of the mixed monomer were taken by mass, and the emulsifier solution, 10% of the initiator solution and 10% of the mixed monomer were mixed, and heated at 85°C and 400r / min, stirred for 15 min under nitrogen protection, and the remaining initiator solution and mixed monomers were added at a uniform rate within 12 min and continued to stir for 4 h to prepare a polyacrylate emulsion; polyacrylate emulsion, 4-bromo-1-butene, 4-methoxythiophenol and lithium formate were mixed in a mass ratio of 1:0.1:0.3:0.1, stirred for 24 h at 700 r / min, argon protection and 427 nm LED light, and evenly applied on a functionalized glass plate with a thickness of 0.5 mm. The mixture was allowed to stand at 60°C under argon protection for 10 h, washed with deionized water and ethanol four times in sequence, and vacuum dried at -5°C for 24 h to prepare corrosion-resistant glass.

[0029] Example 3:

[0030] A method for preparing corrosion-resistant glass mainly includes the following preparation steps:

[0031] (1) A 5 mm thick glass plate, trimethoxy(thiophene-2-yl)silane and isopropanol were mixed in a mass ratio of 1:0.16:12, the pH was adjusted to 4.2 with 0.1 mol / L acetic acid solution, the mixture was stirred at 95 °C and 300 r / min for 7 h, filtered, washed with deionized water 5 times, and dried at 100 °C for 4 h to prepare a pre-modified glass plate; ferric chloride and chloroform were mixed in a mass ratio of 1:9.4 to prepare a ferric chloride solution; thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform were mixed in a mass ratio of 7:1:13, and ultrasonicated for 7 min to prepare a thiophene mixture; in nitrogen Under nitrogen protection, the pre-modified glass plate was immersed in the thiophene mixture, and a ferric chloride solution 4 times the mass of the thiophene mixture was added at a uniform rate within 6 minutes. The mixture was allowed to stand for 5 minutes, and the pre-modified glass plate was taken out until no liquid dripped. The mixture was allowed to stand at 40°C under nitrogen protection for 50 hours, washed with chloroform 5 times, and vacuum dried at 0°C for 26 hours to obtain a modified glass plate. 4-Dimethylaminobenzonitrile and zinc chloride were mixed in a mass ratio of 1:0.06, ground to 110 mesh, and evenly spread on the surface of the modified glass plate with a thickness of 0.6 mm. The mixture was allowed to stand at 310°C for 50 hours, washed with ethanol 5 times, and vacuum dried at 0°C for 26 hours to obtain a functionalized glass plate.

[0032] (2) ammonium persulfate and deionized water were mixed at a mass ratio of 1:370 to prepare an initiator solution; sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water were mixed at a mass ratio of 2:1:160 to prepare an emulsifier solution; methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene were mixed at a mass ratio of 7:2.5:6:2.5 to prepare a mixed monomer; 6 parts of the initiator solution, 16 parts of the emulsifier solution and 14 parts of the mixed monomer were taken by mass, and the emulsifier solution, 10% of the initiator solution and 10% of the mixed monomer were mixed, and heated at 90°C and 500r / min, stirred for 16 minutes under nitrogen protection, and the remaining initiator solution and mixed monomers were added at a uniform rate within 14 minutes and continued to stir for 5 hours to obtain a polyacrylate emulsion; polyacrylate emulsion, 4-bromo-1-butene, 4-methoxythiophenol and lithium formate were mixed in a mass ratio of 1:0.12:0.35:0.12, stirred for 26 hours at 800r / min, argon protection, and 427nm LED light, and evenly applied on a functional glass plate with a thickness of 0.6mm. It was allowed to stand at 65℃ under argon protection for 12 hours, washed with deionized water and ethanol in sequence for 5 times, and vacuum dried at 0℃ for 26 hours to obtain corrosion-resistant glass.

[0033] Comparative Example 1:

[0034] The difference between the preparation method of the corrosion-resistant glass of Comparative Example 1 and Example 2 lies in the difference in step (1). Step (1) is modified as follows: a glass plate with a thickness of 5 mm, trimethoxy(thiophene-2-yl)silane and isopropyl alcohol are mixed in a mass ratio of 1:0.15:11, the pH is adjusted to 4 with a 0.1 mol / L acetic acid solution, the mixture is stirred at 90°C and 250 r / min for 6 h, filtered, washed with deionized water 4 times, and dried at 95°C for 3 h to obtain a pre-modified glass plate; ferric chloride and chloroform are mixed uniformly in a mass ratio of 1:9.2 to obtain a ferric chloride solution. Thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform were mixed in a mass ratio of 6:1:13 and ultrasonicated for 6 minutes to prepare a thiophene mixed solution; under nitrogen protection, a pre-modified glass plate was immersed in the thiophene mixed solution, and a ferric chloride solution 3.5 times the mass of the thiophene mixed solution was uniformly added over 5 minutes. The mixture was allowed to stand for 4 minutes, and the pre-modified glass plate was taken out until no liquid dripped. The mixture was allowed to stand at 35°C under nitrogen protection for 48 hours, washed with chloroform four times, and vacuum dried at -5°C for 24 hours to prepare a modified glass plate; the remaining steps were the same as those in Example 2.

[0035] Comparative Example 2:

[0036] The preparation method of the corrosion-resistant glass of Comparative Example 2 differs from that of Example 2 only in that the glass plate is not modified. The remaining steps are the same as those of Example 2.

[0037] Comparative Example 3:

[0038] The difference between the preparation method of the corrosion-resistant glass of Comparative Example 3 and Example 2 lies in the difference in step (2). Step (2) is modified as follows: ammonium persulfate and deionized water are mixed uniformly in a mass ratio of 1:360 to prepare an initiator solution; sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water are mixed uniformly in a mass ratio of 2:1:150 to prepare an emulsifier solution; methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene are mixed in a mass ratio of 6:2:5:2 to prepare a mixed monomer; 5 parts of the initiator solution and 15 parts of the emulsifier solution are taken by mass. The polyacrylate emulsion was prepared by mixing 13 parts of the mixed monomer, 10% of the initiator solution, and 10% of the mixed monomer. The mixture was stirred at 85°C, 400 rpm, and nitrogen for 15 minutes. The remaining initiator solution and the mixed monomer were added at a uniform rate over 12 minutes and stirred for 4 hours to obtain a polyacrylate emulsion. The polyacrylate emulsion was stirred at 700 rpm and argon for 24 hours, and evenly applied to a functionalized glass plate to a thickness of 0.5 mm. The mixture was allowed to stand at 60°C under argon for 10 hours, washed four times with deionized water and ethanol, and dried in vacuo at -5°C for 24 hours to obtain corrosion-resistant glass. The remaining steps were the same as those in Example 2.

[0039] Comparative Example 4:

[0040] The preparation method of the corrosion-resistant glass of Comparative Example 4 is different from that of Example 2 in that step (2) is modified as follows: ammonium persulfate and deionized water are mixed uniformly in a mass ratio of 1:360 to prepare an initiator solution; sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water are mixed uniformly in a mass ratio of 2:1:150 to prepare an emulsifier solution; methyl methacrylate, ethylene glycol acetoacetate and butyl acrylate are mixed in a mass ratio of 6:2:5 to prepare a mixed monomer; 5 parts of the initiator solution, 15 parts of the emulsifier solution and 13 parts of the mixed monomer are taken by mass, An emulsifier solution, 10% initiator solution, and 10% mixed monomer were mixed and stirred at 85°C, 400 rpm, and nitrogen for 15 minutes. The remaining initiator solution and mixed monomer were added at a constant rate over 12 minutes and stirred for another 4 hours to produce a polyacrylate emulsion. The polyacrylate emulsion was stirred at 700 rpm and argon for 24 hours and evenly applied to a functionalized glass plate to a thickness of 0.5 mm. The emulsion was allowed to stand at 60°C under argon for 10 hours, washed four times with deionized water and ethanol, and dried in vacuo at -5°C for 24 hours to produce corrosion-resistant glass. The remaining steps were the same as in Example 2.

[0041] Test Example 1:

[0042] Antibacterial testing:

[0043] Test method: Tested in accordance with GB / T31402-2015, using Staphylococcus aureus and Escherichia coli. Results are shown in Table 1.

[0044] Table 1

[0045]

[0046]

[0047] From the comparison of the experimental data in Table 1, it can be found that the corrosion-resistant glass prepared in the present invention has good antibacterial ability.

[0048] From the comparison of the experimental data of Examples 1, 2, and 3 and Comparative Example 1 in Table 1, it can be found that the antibacterial rates of Examples 1, 2, and 3 are high. The difference between Comparative Example 1 and the Examples is that no tertiary amine group is introduced on the glass surface by forming a triazine ring, and it is impossible to react with the bromine group on the polyacrylate emulsion to form a quaternary ammonium salt. The quaternary ammonium salt has a positive charge and can be firmly adsorbed on the negatively charged bacterial cell surface by electrostatic attraction. After adsorbing on the bacterial surface, the quaternary ammonium salt inserts the hydrophobic group into the lipid layer, changes the permeability of the cell membrane, destroys the membrane structure, and causes leakage of intracellular substances; it can also interfere with the proton pump protein on the bacterial cell membrane, causing it to degrade or denature, affecting the material transport and energy metabolism of the cell, and ultimately causing the death of the bacteria, thereby achieving an antibacterial effect.

[0049] Test Example 2:

[0050] Corrosion resistance and durability testing:

[0051] Durability test: UV aging test was conducted. The glass prepared in each embodiment and comparative example was irradiated under a fluorescent UV lamp UV-A340 for 15 days to observe whether the glass turned yellow.

[0052] Corrosion resistance test: A salt bath test was conducted. Glass prepared in each example and comparative example was cut into 50 mm long and 20 mm wide strips in a constant temperature water bath. The strips were immersed in a 10% sodium chloride aqueous solution at 50°C for 8 hours, and the mass loss was measured. The results are shown in Table 2.

[0053] Table 2

[0054]

[0055]

[0056] From the comparison of the experimental data in Table 2, it can be found that the corrosion-resistant glass prepared by the present invention has good durability and corrosion resistance.

[0057] From the comparison of the experimental data of Examples 1, 2, 3 and Comparative Example 1 in Table 2, it can be found that Examples 1, 2, and 3 do not turn yellow. The difference between Comparative Example 1 and the Example is that no triazine ring is formed on the glass surface and no stable six-membered ring is formed through hydrogen bonding. Triazine can absorb ultraviolet light, convert light into heat energy and release it, thereby achieving an aging-resistant effect. In addition, the triazine formed by 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and 4-dimethylaminobenzonitrile, the hydroxyl group on 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile can form a stable conjugated six-membered ring with triazine through hydrogen bonding, which also has the effect of absorbing ultraviolet light and works together with the triazine structure to enhance the aging resistance of the material.

[0058] From the comparison of the experimental data of Examples 1, 2, 3 and Comparative Example 4, it can be found that the mass loss of Examples 1, 2, and 3 is small. The difference between Comparative Example 4 and the Examples is that 1-allyl-4-(trifluoromethyl)benzene monomer is not introduced into the polyacrylate emulsion. The electronegativity of fluorine atoms is extremely strong, and a tightly arranged fluorine atom layer can be formed to provide chemical inertness protection. In addition, the strong adsorption effect and small atomic radius of fluorine atoms enable fluorine atoms to be tightly arranged around carbon atoms, forming a protective barrier, thereby improving the corrosion resistance of the material.

[0059] Test Example 3:

[0060] Antistatic test:

[0061] Test method: Surface resistivity was tested at 20°C. The results are shown in Table 3.

[0062] Table 3

[0063]

[0064]

[0065] From the comparison of the experimental data in Table 3, it can be found that the corrosion-resistant glass prepared in the present invention has good antistatic ability.

[0066] From the comparison of the experimental data of Examples 1, 2, 3 and Comparative Example 1 in Table 3, it can be found that the surface resistivity of Examples 1, 2, and 3 is low. The difference between Comparative Example 1 and the embodiment is that no quaternary ammonium salt is formed on the glass surface. The quaternary ammonium salt cation can form a conductive layer on the material surface, increase the mobility of the charge on the material surface, thereby reducing the surface resistance, so that the static charge can be dissipated more quickly, and can also react with the negative charge on the material surface to neutralize, reduce the surface charge density, balance the charge distribution on the material surface, and achieve an antistatic effect.

[0067] From the comparison of the experimental data of Examples 1, 2, 3 and Comparative Example 2, it can be found that the surface resistivity of Examples 1, 2, and 3 is low. The difference between Comparative Example 2 and the Example is that no polythiophene is formed on the glass surface. Polythiophene is a polymer compound with good electrical conductivity. Polythiophene can effectively conduct static charge, avoid the accumulation of static electricity, and achieve an antistatic effect.

[0068] The specific implementation methods described above further illustrate the objectives, technical solutions and beneficial effects of the present invention in detail. It should be understood that the above description is only a specific implementation method of the present invention and is not intended to limit the scope of protection of the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the scope of protection of the present invention.

Claims

1. A corrosion-resistant glass, characterized in that: The corrosion-resistant glass is prepared by polymerizing methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate, and 1-allyl-4-(trifluoromethyl)benzene, mixing the mixture with 4-bromo-1-butene, irradiating the mixture with light, coating the mixture on a functionalized glass plate, and curing the mixture. The functionalized glass plate is prepared by sequentially reacting a glass plate with trimethoxy(thiophene-2-yl)silane, thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and 4-dimethylaminobenzonitrile.

2. A method for preparing corrosion-resistant glass, characterized in that: The preparation method of the corrosion-resistant glass mainly includes the following preparation steps: (1) Ferric chloride and chloroform are mixed uniformly in a mass ratio of 1:9 to 9.4 to prepare a ferric chloride solution; thiophene, 4-hydroxythieno[2,3-B]pyridine-5-carbonitrile and chloroform are mixed in a mass ratio of 5 to 7:1:13, and ultrasonicated for 5 to 7 minutes to prepare a thiophene mixed solution; under nitrogen protection, a pre-modified glass plate is immersed in the thiophene mixed solution, and a ferric chloride solution 3 to 4 times the mass of the thiophene mixed solution is added at a uniform rate within 4 to 6 minutes, and the glass plate is allowed to stand for 3 to 5 minutes, and the pre-modified glass plate is taken out until no liquid drops, and the glass plate is allowed to stand for 46 to 50 hours at 30 to 40°C under nitrogen protection, and washed with chloroform 3 to 5 times, and vacuum dried at -10 to 0°C for 22 to 26 hours to prepare a modified glass plate; (2) Polyacrylate emulsion, 4-bromo-1-butene, 4-methoxythiophenol and lithium formate are mixed in a mass ratio of 1:0.08-0.12:0.25-0.35:0.08-0.12, stirred at 600-800 r / min, argon protection, 427 nm LED light for 22-26 h, and evenly applied on a functionalized glass plate with a thickness of 0.4-0.6 mm. The mixture is allowed to stand at 55-65 ° C under argon protection for 8-12 h, washed with deionized water and ethanol for 3-5 times in sequence, and vacuum dried at -10-0 ° C for 22-26 h to obtain corrosion-resistant glass.

3. The method for preparing corrosion-resistant glass according to claim 2, wherein: The pre-modified glass plate in step (1) is prepared by mixing a glass plate, trimethoxy(thiophene-2-yl)silane and isopropyl alcohol in a mass ratio of 1:0.14-0.16:10-12, adjusting the pH to 3.8-4.2 with a 0.1 mol / L acetic acid solution, stirring at 85-95° C. and 200-300 r / min for 5-7 hours, filtering, washing with deionized water for 3-5 times, and drying at 90-100° C. for 2-4 hours.

4. The method for preparing corrosion-resistant glass according to claim 3, wherein: The glass plate is ordinary flat glass with a thickness of 5 mm.

5. The method for preparing corrosion-resistant glass according to claim 2, wherein: The polyacrylate emulsion in step (2) is prepared by mixing 4 to 6 parts of an initiator solution, 14 to 16 parts of an emulsifier solution and 12 to 14 parts of a mixed monomer by mass, the emulsifier solution, 10% of the initiator solution and 10% of the mixed monomer, stirring at 80 to 90° C., 300 to 500 r / min and under nitrogen protection for 14 to 16 minutes, adding the remaining initiator solution and the mixed monomer at a uniform rate within 10 to 14 minutes, and continuing to stir for 3 to 5 hours.

6. The method for preparing corrosion-resistant glass according to claim 5, characterized in that: The initiator solution is prepared by uniformly mixing ammonium persulfate and deionized water in a mass ratio of 1:350-370.

7. The method for preparing corrosion-resistant glass according to claim 5, characterized in that: The emulsifier solution is prepared by uniformly mixing sodium lauryl sulfate, alkylphenol polyoxyethylene ether and distilled water in a mass ratio of 2:1:140-160.

8. The method for preparing corrosion-resistant glass according to claim 5, characterized in that: The mixed monomer is prepared by mixing methyl methacrylate, ethylene glycol acetoacetate, butyl acrylate and 1-allyl-4-(trifluoromethyl)benzene in a mass ratio of 5-7:1.5-2.5:4-6:1.5-2.

5.

9. The method for preparing corrosion-resistant glass according to claim 2, wherein: The functionalized glass plate in step (2) is prepared by mixing 4-dimethylaminobenzonitrile and zinc chloride in a mass ratio of 1:0.04-0.06, grinding the mixture to 90-110 mesh, evenly spreading the mixture on the surface of the modified glass plate to a thickness of 0.4-0.6 mm, standing the mixture at 290-310° C. for 46-50 hours, washing the mixture with ethanol for 3-5 times, and vacuum drying the mixture at -10-0° C. for 22-26 hours.

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