Frame manufacturing method
By adopting a frame manufacturing method in the OLED manufacturing process, utilizing the bonding technology of metal sheets and movable plates and multiple wet etching processes, the problems of mask sagging and misalignment are solved, stable support and high-precision alignment of the mask are achieved, and the production quality of OLED products is improved.
Patent Information
- Application Number
- CN202410921127.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2024-07-01
- Filing Date
- 2024-07-10
- Publication Date
- 2025-09-09
AI Technical Summary
In the existing OLED manufacturing process, there are problems with mask sagging, twisting and misalignment during the connection between the mask and the frame. Especially in ultra-high-definition OLEDs, the pixel size requires high-precision alignment that is difficult to achieve, resulting in low product yield.
A frame manufacturing method is adopted, which uses bonding technology of metal sheets and moving plates in the connection between the mask and the frame, applies tensile force and controls temperature changes to ensure stable support and accurate alignment of the mask, including multiple wet etching processes to improve the accuracy of the mask pattern.
It achieves deformation-free support and stable movement of the mask, ensures accurate alignment between mask units and clear formation of the edge of the frame, and improves the production efficiency and quality of OLED products.
Smart Images

Figure CN120614969A_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to a method for manufacturing a frame. More specifically, the method relates to a method for manufacturing a frame used in a mask-frame connector, wherein the connector includes a mask formed with a high-resolution mask pattern, can stably form the mask without deformation, and can accurately align each mask unit. Background Art
[0002] As a technology for forming pixels in the OLED (Organic Light Emitting Diode) manufacturing process, the FMM (Fine Metal Mask) method is mainly used. In this method, a thin film metal mask (Shadow Mask) is closely attached to a substrate and organic matter is deposited at a desired position.
[0003] In the existing OLED manufacturing process, after the mask is manufactured into a strip shape, a plate shape, etc., the mask is welded and fixed to the OLED pixel evaporation frame and used. One mask can have multiple units corresponding to one display. In addition, in order to manufacture large-area OLEDs, multiple masks can be fixed to the OLED pixel evaporation frame. During the process of fixing them to the frame, each mask is stretched to make it flat. Adjusting the stretching force to make the entire part of the mask flat is a very difficult task. In particular, in order to flatten each unit while aligning the mask pattern with a size of several to tens of μm, the following difficult task is required: while finely adjusting the stretching force applied to each side of the mask, the alignment status is confirmed in real time.
[0004] Despite this, the process of securing multiple masks to a single frame still presents problems with poor alignment between masks and between mask units. Furthermore, during the process of welding the masks to the frame, the mask film is too thin and has a large surface area, causing the mask to sag or twist under the load. Furthermore, wrinkles and burrs generated at the welded parts during welding can lead to misalignment of the mask units.
[0005] In ultra-high-definition OLEDs, existing QHD image quality is 500-600 PPI (pixels per inch), with pixel sizes reaching approximately 30-50 μm. 4K UHD and 8K UHD have even higher resolutions, such as -860 PPI and -1600 PPI. Given the pixel size of ultra-high-definition OLEDs, alignment errors between units must be reduced to a few μm. Exceeding this error will result in defective products, potentially leading to extremely low yields. Therefore, it is necessary to develop technologies that prevent mask deformation, such as sagging or twisting, and ensure precise alignment, as well as technologies for securing the mask to the frame. Summary of the Invention
[0006] Technical issues
[0007] Therefore, the present invention is proposed to solve the many problems of the prior art as described above, and its purpose is to provide a frame manufacturing method, which is used in a connector between the mask and the frame, can support and move the mask stably without deformation, prevent deformation of the mask such as sagging or twisting, and can accurately align the mask.
[0008] Another object of the present invention is to provide a frame manufacturing method that can clearly perform alignment between mask units and more clearly form a frame edge portion.
[0009] However, these technical problems are only exemplary and are not intended to limit the scope of the present invention.
[0010] Technical Solution
[0011] The above-mentioned object of the present invention is achieved through a frame manufacturing method, which is used in a connector between a mask and a frame for forming OLED pixels. The method includes the following steps: (a) bonding the first side of a metal sheet to a movable plate; (b) forming a plurality of mask unit areas on the second side opposite to the first side of the metal sheet and manufacturing a unit sheet portion; (c) connecting the unit sheet portion to an edge frame portion, the edge frame portion including a hollow area, and in the (a) step, applying a tensile force toward the side direction of the unit sheet portion.
[0012] In the step (a), the movable plate and the metal sheet may be bonded together by interposing a dry film resist layer.
[0013] The step of applying a tensile force toward the side direction of the unit sheet portion may include the following steps: (1) bonding the movable plate and the metal sheet at a temperature at least lower than room temperature; and (2) raising the temperature to room temperature.
[0014] The step of applying a tensile force toward the side direction of the unit sheet portion may include the following steps: (1) contacting the movable plate and the metal sheet at a temperature at least higher than room temperature; (2) bonding the movable plate and the metal sheet during the process of the temperature decreasing toward room temperature.
[0015] The step (1) may include sandwiching a temporary bonding portion between the movable plate and the metal sheet, and raising the process temperature until the bonding strength (push-pull strength) of the temporary bonding portion is at least 0 to 5 kgf / cm 2The step (2) may include lowering the process temperature to a temperature where the bonding strength of the temporary bonding portion is at least greater than 5 kgf / cm 2 and bonding the metal sheet to the moving plate.
[0016] The movable plate may be made of borosilicate glass, and the width×length of the movable plate may be at least greater than 1500 mm×900 mm.
[0017] In the step (b), the unit sheet portion may include: an edge sheet portion; a plurality of first grid sheet portions, which are formed extending along a first direction and connected to the edge sheet portion at both ends; and a plurality of second grid sheet portions, which are formed extending along a second direction perpendicular to the first direction and intersecting with the first grid sheet portion and connected to the edge sheet portion at both ends. In the step (c), at least a portion of the edge sheet portion may be connected to the edge frame portion.
[0018] The step of applying a tensile force toward the side direction of the unit sheet portion may include the following steps: (1) a suction cup provides heat to the movable plate and the metal sheet, and the suction cup is used to adsorb one side of the movable plate and move the movable plate; (2) the movable plate and the metal sheet are bonded during the process of the suction cup interrupting or reducing the heat supply.
[0019] The metal sheet can be bonded to the movable plate in a state elongated compared to its original length.
[0020] The unit sheet portion may have a quadrilateral planar shape, and a tensile force is applied to all sides along a radial direction.
[0021] The alignment error of each side of the mask unit region may be equal to or less than 20 μm compared to each side of a design value.
[0022] Compared with the comparative example in which the edge of the unit sheet portion is stretched in the lateral direction and connected to the edge frame portion in a state of clamping the edge of the unit sheet portion, as the (1) step and the (2) step are performed, when the unit sheet portion to which a tensile force is applied in the lateral direction on the movable plate is connected to the edge frame portion, the edge position value of the mask unit area deviates less than the design value of the mask unit area.
[0023] For the comparative example, adjacent mask unit regions may be tilted toward a specific corner direction.
[0024] In the comparative example, a first tensile force may be applied in a direction parallel to a specific edge of the mask unit region, and a second tensile force may be applied in a direction perpendicular to the first tensile force.
[0025] The movable plate may include at least one of silicon dioxide, quartz, aluminum oxide (Al2O3), borosilicate glass, zirconium oxide, silicate ceramics, titanium (Ti), molybdenum (Mo), silver (Ag), copper (Cu), platinum (Pt), gold (Au), polyimide, and polymers, or may be a material in which at least one of titanium (Ti), molybdenum (Mo), silver (Ag), copper (Cu), platinum (Pt), gold (Au), polyimide, and polymers is coated on the surface of any one of Invar, Super Invar, and stainless steel (SUS).
[0026] In addition, the above-mentioned object of the present invention is achieved by a frame, which is used in a connector between a mask for forming OLED pixels and a frame, the frame including: an edge frame portion, which includes a hollow area; and a unit sheet portion, which is connected to the edge frame portion and forms a plurality of mask unit areas, and the alignment error of each side of the mask unit area can be equal to or less than 20 μm compared to each side of the design value.
[0027] The mask unit region may be in a quadrilateral shape, and an alignment error of any side of the mask unit region compared to any side of a design value may be equal to or less than 10 μm.
[0028] Beneficial effects
[0029] The present invention according to the above structure has the effect of enabling the mask to be stably supported and moved without deformation, and preventing the mask from being deformed such as sagging or twisting, and enabling accurate alignment.
[0030] Furthermore, the present invention has the effect of enabling accurate alignment between mask units and more clearly forming the edge portion of the frame.
[0031] Of course, the scope of the present invention is not limited by the above-mentioned effects. BRIEF DESCRIPTION OF THE DRAWINGS
[0032] Figure 1 1 and 2 are a front view and a side cross-sectional view of a connection body between a mask and a frame according to an embodiment of the present invention.
[0033] Figure 2 1 and 2 are front and side cross-sectional views of a frame according to an embodiment of the present invention.
[0034] Figure 3 FIG. 1 is a schematic diagram of a mask according to an embodiment of the present invention.
[0035] Figure 4 It is a schematic diagram of the existing mask manufacturing process.
[0036] Figures 5 to 7 FIG. 4 is a schematic diagram of a mask manufacturing process according to an embodiment of the present invention.
[0037] Figure 8 Schematic diagram of the mask etching degree of a comparative example of the present invention.
[0038] Figure 9 FIG. 4 is a schematic diagram of the mask etching degree according to an embodiment of the present invention.
[0039] Figure 10 FIG. 4 is a schematic diagram of adjusting the cone angle according to an embodiment of the present invention.
[0040] Figures 11 to 15 Schematic diagram of a frame manufacturing process according to an embodiment of the present invention.
[0041] Figure 16 Schematic diagram of the stretched state of the unit sheet portion and the movable plate based on the change of process temperature according to one embodiment of the present invention.
[0042] Figures 17 and 18 FIG. 1 is a schematic diagram of a manufacturing process of a unit sheet portion according to an embodiment of the present invention.
[0043] Figure 19 FIG. 1 is a schematic diagram of a unit pattern of a unit sheet portion according to an embodiment of the present invention.
[0044] Figure 20 FIG. 1 is a schematic diagram showing a mask connected to a unit sheet portion according to an embodiment of the present invention.
[0045] Figure 21 This is an electron microscope photograph of a unit pattern according to one embodiment of the present invention.
[0046] Figure 22 FIG. 1 is a schematic diagram showing an alignment state of a mask cell region of a unit sheet portion according to a comparative example.
[0047] Figure 23 Based on the comparative example Figure 22 Schematic diagram of the edge position values of each mask unit area.
[0048] Figure 24 FIG. 1 is a schematic diagram illustrating an alignment state of a mask unit region of a unit sheet portion according to an embodiment of the present invention.
[0049] Figure 25 This is an embodiment of the present invention Figure 24 Schematic diagram of the edge position values of each mask unit area.
[0050] Figure 26 FIG. 1 is a schematic diagram showing an overlapped comparison of alignment states of mask unit regions in a comparative example and an embodiment of the present invention.
[0051] [Description of Reference Numerals]
[0052] 10: Connector between mask and frame
[0053] 80: Suction Cup
[0054] 90: Mobile board
[0055] 95: Temporary adhesive part, dry film resist layer
[0056] 100: Mask
[0057] 110: Mask film, metal sheet
[0058] 200: Framework
[0059] 210: Edge frame
[0060] 220: Unit sheet
[0061] 220′: Metal sheet for manufacturing unit sheet
[0062] 221: Edge sheet part
[0063] 223: First grid sheet portion
[0064] 225: Second grid sheet portion
[0065] 1000: OLED pixel deposition device
[0066] C: unit, mask unit
[0067] Ca, Cb, Cc: first unit pattern, second unit pattern, third unit pattern
[0068] CP: Cell Pattern
[0069] CR: Mask cell region
[0070] Ma, Mb, Mc: first insulating part
[0071] R: Hollow area of edge frame
[0072] P: mask pattern
[0073] P1, P1-1, P1-2: first mask pattern
[0074] P2, P2-1, P2-2: second mask pattern DETAILED DESCRIPTION
[0075] For the detailed description of the present invention described below, reference may be made to the accompanying drawings which illustrate specific embodiments in which the present invention may be implemented. In order to enable those skilled in the art to implement the present invention, these embodiments are described in detail below. These embodiments are described in sufficient detail so that those skilled in the art can implement the present invention. The various embodiments of the present invention should be understood to be different from each other but not mutually exclusive. For example, the specific shapes, structures and characteristics described herein can be implemented as other embodiments of one embodiment without exceeding the spirit and scope of the present invention. In addition, the position or arrangement of the individual components in each disclosed embodiment should be understood to be subject to change without exceeding the spirit and scope of the present invention. Therefore, the following detailed description is not intended to limit the present invention, and the scope of the present invention is limited only by the appended claims and all equivalents thereto. Similar reference numerals in the drawings refer to the same or similar functions in various aspects, and for convenience, length, area, thickness, etc. and their forms may also be exaggerated.
[0076] Hereinafter, in order to enable those skilled in the art to easily implement the present invention, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
[0077] Figure 1 This is a front view of a frame-integrated mask according to an embodiment of the present invention. Figure 1 (a)] and side cross-sectional view [ Figure 1 (b)]. Figure 2 This is a front view of a frame according to an embodiment of the present invention. Figure 2 (a)] and side cross-sectional view [ Figure 2 (b)].
[0078] Below, although this specification describes the structure of the mask and frame connection body (or frame-integrated mask), the structure and manufacturing process of the mask and frame connection body can be understood as including the entire content of Korean Patent Application No. 2018-0016186.
[0079] Reference Figure 1 as well as Figure 2 The mask-frame connector 10 (or frame-integrated mask) can include multiple masks 100 and a frame 200. In other words, multiple masks 100 are individually connected to the frame 200. Below, for ease of explanation, a square mask 100 is used as an example. However, before the mask 100 is attached to the frame 200, it can be a strip-shaped mask with protrusions on both sides for clamping. After attachment to the frame 200, the protrusions can be removed.
[0080] A plurality of mask patterns P are formed on each mask 100, and one cell C may be formed on one mask 100. One mask cell C may correspond to one display of a smartphone or the like.
[0081] The mask 100 may also be made of materials such as invar, super invar, nickel (Ni), nickel-cobalt (Ni-Co), etc. The mask 100 may be made of a metal sheet produced by rolling or electroforming.
[0082] The frame 200 can be formed to connect multiple masks 100. Considering thermal deformation, the frame 200 is preferably formed from a material such as Invar, Super Invar, nickel, or nickel-cobalt, which has a thermal expansion coefficient equal to that of the masks. The frame 200 can include a roughly quadrangular or square edge frame portion 210. The interior of the edge frame portion 210 can be hollow.
[0083] In addition, the frame 200 has a plurality of mask unit regions CR and may include a unit sheet portion 220 connected to the edge frame portion 210. The unit sheet portion 220 may be composed of an edge sheet portion 221, a first grid sheet portion 223, and a second grid sheet portion 225. The edge sheet portion 221, the first grid sheet portion 223, and the second grid sheet portion 225 are sections divided on the same sheet and are integrally formed with each other.
[0084] The thickness of the edge frame portion 210 can be greater than that of the unit sheet portion 220, and can be formed with a thickness ranging from several millimeters to several centimeters. Although thinner than the edge frame portion 210, the unit sheet portion 220 is thicker than the mask 100, and can be approximately 0.1 mm to 1 mm. The width of the first grid sheet portion 223 and the second grid sheet portion 225 can be approximately 1 to 5 mm.
[0085] In addition to the areas occupied by the edge sheet portion 221, the first grid sheet portion 223, and the second grid sheet portion 225, a plurality of mask unit regions CR (CR11 to CR56) can be provided in the planar sheet. This specification uses the example of forming a 6×5 mask unit region CR (CR11 to CR56). There can be five first grid sheet portions 223 and four second grid sheet portions 225.
[0086] The frame 200 has multiple mask cell regions CR, and each mask 100 can be attached so that each mask cell C corresponds to each mask cell region CR. The mask cells C correspond to the mask cell regions CR of the frame 200, and part or all of the dummy portion can be attached to the frame 200 (cell sheet portion 220). Thus, the mask 100 and frame 200 can form an integrated structure.
[0087] The specific manufacturing process of the frame 200 will be described in detail in Figures 11 to 15The process of forming the mask unit region CR of the unit sheet portion 220 will be described in Figure 17 Described in.
[0088] Figure 3 FIG. 1 is a schematic diagram of a mask 100 according to an embodiment of the present invention.
[0089] Each mask 100 may include a mask cell C formed with a plurality of mask patterns P and a dummy portion (equivalent to the portion of the mask film 110 excluding the cell C) surrounding the mask cell C. The dummy portion may comprise only the mask film 110, or may comprise the mask film 110 formed with a predetermined dummy portion pattern having a similar form to the mask pattern P. The mask cell C corresponds to the mask cell region CR of the frame 200, and part or all of the dummy portion may be attached to the frame 200 (cell sheet portion 220). Thus, the mask 100 and the frame 200 may form an integrated structure.
[0090] On the other hand, according to another embodiment, the frame is not manufactured by attaching the unit sheet portion 220 to the edge frame portion 210. Instead, a grid frame (equivalent to the grid sheet portions 223 and 225) can be directly formed in the hollow region R of the edge frame portion 210 to be integrated with the edge frame portion 210. This type of frame also includes at least one mask unit region CR, and the mask 100 can be aligned with the mask unit region CR to manufacture the mask-frame connection body 10.
[0091] Next, a process of manufacturing the mask 100 will be described.
[0092] Figure 4 It is a schematic diagram of the existing mask manufacturing process.
[0093] Reference Figure 4 , the existing mask manufacturing process only performs wet etching.
[0094] First, if Figure 4 As shown in (a), a patterned photoresist M may be formed on the planar film 110' (sheet). Then, as shown in Figure 4 (b) Wet etching WE can be performed through the spaces between the patterned photoresist M. After wet etching WE, some of the spaces between the film 110′ are penetrated, thereby forming a mask pattern P′. Then, if the photoresist M is cleaned, the film 110′ having the mask pattern P′ formed thereon is completed, thereby completing the manufacture of the mask 100′.
[0095] like Figure 4As shown in (b), the existing mask 100′ has the problem of non-constant size of the mask pattern P′. Since the wet etching WE is performed isotropically, the shape after etching is roughly arc-shaped. Moreover, since it is difficult to keep the etching speed of each part consistent during the wet etching WE process, the widths R1′, R1″, and R1″′ of the through pattern after penetrating the film 110′ are different. In particular, in patterns where undercuts UC occur more frequently, not only the lower width R1″ but also the upper width R2″ of the mask pattern P′ will be wider, while in patterns where undercuts UC occur less frequently, the lower widths R1′, R1″′ and the upper widths R2′, R2″′ are relatively narrow.
[0096] As a result, the existing mask 100′ suffers from uneven dimensions across the mask patterns P′. For ultra-high-definition OLEDs, current QHD resolution is 500-600 PPI (pixels per inch), with pixel sizes reaching approximately 30-50 μm. 4K UHD and 8K UHD resolutions reach even higher resolutions, reaching ~860 PPI and ~1600 PPI, respectively. Therefore, even slight dimensional differences can lead to product defects.
[0097] Therefore, a feature of the present invention is to improve the pattern accuracy of the insulating mask during the wet etching process by performing wet etching twice.
[0098] Figures 5 to 7 FIG. 4 is a schematic diagram of a mask manufacturing process according to an embodiment of the present invention.
[0099] Reference Figure 5 In step (a), a metal sheet 110 for mask manufacturing may be provided. As described above, the material of the metal sheet 110 may be invar, super invar, nickel (Ni), nickel-cobalt (Ni-Co), or the like.
[0100] Then, a patterned first insulating portion M1 may be formed on one side (upper side) of the metal sheet 110. The first insulating portion M1 may be formed of a photoresist material by a printing method or the like.
[0101] The first insulating portion M1 may be a black matrix photoresist or a photoresist material with a metal coating formed on the top. The black matrix photoresist may be a material comprising a black matrix resin, which is used to form a black matrix of a display panel. The black matrix photoresist has a better light-shielding effect than a general photoresist. In addition, the photoresist with a metal coating formed on the top can enhance the light-shielding effect of light irradiated from above by the metal coating liquid.
[0102] Then, refer to Figure 5 In step (b), a first mask pattern P1 having a predetermined depth can be formed on one side (the upper side) of the metal sheet 110 by wet etching WE1. When wet etching WE1 is performed, the first mask pattern P should not penetrate the metal sheet 110. Therefore, the first mask pattern P can be formed generally in an arc shape and not penetrate the metal sheet 110. In other words, the depth of the first mask pattern P1 can be less than the thickness of the metal sheet 110.
[0103] Because the wet etching process WE1 has isotropic etching characteristics, the width R2 of the first mask pattern P1 differs from the spacing R3 between patterns in the first insulating portion M1 and can be wider than the spacing R3 between patterns in the first insulating portion M1. In other words, because undercuts UC are formed below both sides of the first insulating portion M1, the width R2 of the first mask pattern P1 can be wider than the spacing R3 between patterns in the first insulating portion M1 by a width sufficient to form the undercuts UC.
[0104] Then, refer to Figure 5 (c) A second insulating portion M2 can be formed on one side (top) of the metal sheet 110. The second insulating portion M2 can be formed from a photoresist material by printing or the like. Since the second insulating portion M2 needs to be retained in the space for forming the undercut UC described later, a positive photoresist material is preferably used.
[0105] Since the second insulating portion M2 is formed on one side (upper side) of the metal sheet 110 , a portion of the second insulating portion M2 is formed on the first insulating portion M1 , and the other portion is filled inside the first mask pattern P1 .
[0106] The second insulating portion M2 can be made of a photoresist diluted in a solvent. If a high-concentration photoresist solution is formed on the metal sheet 110 and the first insulating portion M1, it will react with the photoresist in the first insulating portion M1, potentially dissolving a portion of the first insulating portion M1. Therefore, to minimize the effect on the first insulating portion M1, the second insulating portion M2 can be made of a photoresist with a reduced concentration after dilution in a solvent.
[0107] Then, refer to Figure 6(d) The second insulating portion M2 can be partially volatilized by baking. After the solvent in the second insulating portion M2 is volatilized by baking, only the photoresist component remains. As a result, a thin portion of the second insulating portion M2′ remains in the exposed portion of the first mask pattern P1 and on the surface of the first insulating portion M1, like a coated film. The remaining thickness of the second insulating portion M2′ is preferably less than several μm, so as not to affect the pattern width R3 of the first insulating portion M1 or the pattern width R2 of the first mask pattern P1.
[0108] Then, refer to Figure 6 (e) can be exposed on one side (top) of the metal sheet 110. When the exposure L is performed above the first insulating portion M1, the first insulating portion M1 can act as an exposure mask. Since the first insulating portion M1 is a black matrix photoresist or a photoresist material with a metal coating formed on the upper portion, it has an excellent light shielding effect. Therefore, the second insulating portion M2 "[refer to Figure 6 (f)] will not be exposed to L, while the other insulating parts M2′ will be exposed to L.
[0109] Then, refer to Figure 6 (f), if the exposure L is followed by development, the portion of the second insulating portion M2 ″ that is not exposed to the exposure L will remain, while the other second insulating portions M2′ will be removed. Since the second insulating portion M2′ is a positive photoresist, the portion exposed to the exposure L will be removed. The space left for the second insulating portion M2″ can form an undercut UC below both sides of the first insulating portion M1 [refer to Figure 5 (b) step] corresponds to the space.
[0110] Then, refer to Figure 7 (g) Wet etching WE2 can be performed on the first mask pattern P1 of the metal sheet 110. The wet etching liquid penetrates the spaces between the patterns of the first insulating portion M1 and the spaces of the first mask pattern P1, and wet etching WE2 is performed. The second mask pattern P2 can be formed through the metal sheet 110. In other words, it is formed by penetrating from the lower end of the first mask pattern P1 to the other side of the metal sheet 110.
[0111] At this time, a second insulating portion M2″ is left on the first mask pattern P1. The remaining second insulating portion M2″ can act as a mask for wet etching. That is, the second insulating portion M2″ masks the etching liquid and prevents the etching liquid from etching toward the side of the first mask pattern P1, and etches toward the lower surface of the first mask pattern P1.
[0112] Since the second insulating portion M2″ is arranged in the undercut UC space vertically below the first insulating portion M1, the pattern width of the second insulating portion M2″ substantially corresponds to the pattern width R3 of the first insulating portion M1. Therefore, the second mask pattern P2 is equivalent to wet etching WE2 on the spacing R3 between the patterns of the first insulating portion M1. Therefore, the width R1 of the second mask pattern P2 can be smaller than the width R2 of the first mask pattern P1.
[0113] Because the width of the second mask pattern P2 defines the width of the pixel, its width is preferably less than 35 μm. If the second mask pattern P2 is too thick, it becomes difficult to control its width R1, and the uniformity of width R1 decreases, potentially resulting in the mask pattern P not having a tapered or inverted tapered shape overall. Therefore, the thickness of the second mask pattern P2 is preferably less than that of the first mask pattern P1. The thickness of the second mask pattern P2 is preferably close to zero. Considering the pixel size, for example, the thickness of the second mask pattern P2 is preferably 0.5 to 3.0 μm, and more preferably 0.5 to 2.0 μm.
[0114] The mask pattern P is formed by combining the connected first mask pattern P1 and the second mask pattern P2 .
[0115] Then, refer to Figure 7 (h) The mask 100 can be manufactured by removing the first insulating portion M1 and the second insulating portion M2. The first mask pattern P1 includes an inclined surface, and the height of the second mask pattern P2 is very low. Therefore, if the shapes of the first mask pattern P1 and the second mask pattern P2 are combined, the overall shape is tapered or inverted tapered.
[0116] Figure 8 Schematic diagram of the mask etching degree of a comparative example of the present invention.
[0117] Reference Figure 8, since the wet etching WE is performed isotropically, the shape after etching is roughly in the shape of a circular arc. Moreover, during the wet etching process, it is difficult for the etching speeds of each part to be exactly the same. If only one wet etching is performed to penetrate the metal sheet 110 to form the mask pattern, the deviation will be greater. For example, although the wet etching speeds of the mask pattern 111 and the mask pattern 112 are different, the difference in the upper width (bottom cut) is not very large. However, the difference between the lower penetration width PD1 of the metal sheet 110 caused by the formation of the mask pattern 111 and the lower penetration width PD2 of the metal sheet 110 caused by the formation of the mask pattern 112 is much larger than the upper width difference. This is a result of the fact that the wet etching is performed isotropically. In other words, it is the lower widths PD1 and PD2 of the mask patterns 111 and 112, rather than the upper width, that determine the width of the pixel size. Therefore, compared to one wet etching, it is easier to control the lower widths PD1 and PD2 if two wet etchings are performed. Below, Figure 9 The present invention is further described by taking an embodiment of the present invention as an example.
[0118] Figure 9 FIG. 4 is a schematic diagram of the mask etching degree according to an embodiment of the present invention.
[0119] Figure 9 The process up to (a) Figure 5 The process is the same as described in (a) to (b) of Figure 9 In (a), the first mask pattern P1-1 and the first mask pattern P1-2 showing different etching degrees in the wet etching WE1 of the first insulating portion M1 are compared and described.
[0120] Reference Figure 9 In (a), even with the same wet etching process WE1-1 and WE1-2, different etching degrees can occur depending on the etched portion, as shown in the first mask pattern P1-1 and the first mask pattern P1-2. The pattern width R2-1 of the first mask pattern P1-1 is smaller than the pattern width R2-2 of the first mask pattern P1-2. This difference in pattern widths R2-1 and R2-2 can adversely affect pixel resolution.
[0121] Then, refer to Figure 9 (b), it can be confirmed that when executing Figure 5 (c) to Figure 6After the process described in (f), the second insulating parts M2″-1 and M2″-2 are respectively formed in the space vertically below the first insulating part M1. Depending on the size of the undercut space below the first insulating part, the sizes of the second insulating parts M2″-1 and M2″-2 will be different. Although the size of the second insulating part M2″-1 is smaller than the size of the second insulating part M2″-2, the pattern widths of the second insulating parts M2″-1 and M2″-2 will be equal. The pattern widths of the second insulating parts M2″-1 and M2″-2 may be equal to correspond to the pattern width R3 of the first insulating part M1.
[0122] Then, refer to Figure 9 (c) The second insulating portions M2″-1 and M2″-2 are respectively used as masks for wet etching and a second wet etching WE2 is performed, thereby penetrating the metal sheet 110. As a result, the deviation of the width R1-1 and R1-2 of the formed second mask patterns P2-1 and P2-2 will be significantly smaller than the deviation of the width R2-1 and R2-2 of the first mask patterns P1-1 and P1-2. This is because, after the metal sheet 110 is first wet-etched with the depth of the first mask patterns P1-1 and P1-2, and then the thickness of the remaining metal sheet 110 is wet-etched for the second time, the pattern width of the second insulating portions M2″-1 and M2″-2 subjected to the second wet etching is substantially equal to the pattern width of the first insulating portion M1 subjected to the first wet etching.
[0123] As described above, the mask manufacturing method of the present invention can effectively form a mask pattern P with the desired dimensions by performing two wet etching steps. In particular, since a portion of the second insulating portion M2″ is left, the second wet etching step allows the second mask pattern P2 to be etched narrower and thinner than the first wet etching step, thereby making it easier to control the width R1 of the second mask pattern P2. Furthermore, since the wet etching step can form an inclined surface, it is possible to form a mask pattern P that prevents shadowing.
[0124] Figure 10 2 is a schematic diagram of adjusting the cone angles a1 and a2 according to an embodiment of the present invention.
[0125] In addition, the mask manufacturing method of the present invention has the advantage that the mask pattern P composed of the first mask pattern P1 and the second mask pattern P2 is easy to form a tapered angle. Moreover, the present invention has the effect of easily adjusting the tapered angles a1 and a2. Figure 10 (a), if the thickness T1 of the second mask pattern P2 is thinner, the taper angle a1 will become larger. In other words, if the thickness of the first mask pattern P1 is thick and the thickness T1 of the second mask pattern P2 is thinner, the taper angle a1 will become larger as a result of isotropic wet etching (R1 is the radius). On the contrary, referring to Figure 10(b), if the thickness T2 of the second mask pattern P2 becomes thicker, the taper angle a2 will become smaller. In other words, compared to Figure 10 In (a), if the thickness of the first mask pattern P1 is thin and the thickness T2 of the second mask pattern P2 is thicker, the tapered angle a2 will increase as a result of isotropic wet etching (R1 is the radius). Therefore, the present invention has the advantage of being able to adjust the tapered angles a1 and a2 by adjusting the thickness of the second mask pattern P2.
[0126] Hereinafter, the manufacturing process of the mask and frame connection body 10 of the present invention will be further described.
[0127] Figures 11 to 15 Schematic diagram of a frame manufacturing process according to an embodiment of the present invention.
[0128] To manufacture a connected body of the mask 100 and the frame 200 (or a frame-integrated mask), the frame 200 may be provided. First, the unit sheet portion 220 is manufactured and then the frame 200 is manufactured by connecting the unit sheet portion 220 to the edge frame portion 210. Alternatively, the unit sheet portion 220 may be manufactured and then connected to the edge frame portion 210 after the edge frame portion 210 is prepared.
[0129] Reference Figure 11 , a metal sheet 220' for manufacturing the unit sheet portion 220 of the frame 200 can be prepared. The material of the metal sheet 220' is similar to the metal sheet 110 for mask manufacturing [refer to Figure 5 (a)], it can be invar, super invar, nickel (Ni), nickel-cobalt (Ni-Co), etc.
[0130] The metal sheet 220' is used as the unit sheet portion 220 for supporting the mask 100 and may be thicker than the mask 100. The thickness of the metal sheet 220' may be greater than that of the mask 100 and be approximately 70 μm to 200 μm.
[0131] In addition, a movable plate 90 may be provided. The movable plate 90 is a medium that can adhere to the first surface (lower surface) of the metal sheet 220' and support it while moving. To support the metal sheet 220' as a whole, the movable plate 90 is a flat plate with an area greater than or equal to that of the metal sheet 220'.
[0132] As an example, the width×height of 6G can be about 1500mm×1800mm, and half of 6G can be about 1500mm×900mm. Figure 1The size of the plurality of masks 100 excluding the edge frame portion 210 and the unit sheet portion 220 to which the plurality of masks 100 are attached can be half the size of the 6G. In view of this, the size of the movable plate 90 for supporting the unit sheet portion 220 is preferably about 1500 mm in width × 900 mm in length or more.
[0133] The movable plate 90 may be made of a material that is transparent to the laser light L. Examples of materials that may be used include glass, silica, quartz, alumina (Al 2 O 3 ), borosilicate glass, zirconia, and silicate ceramics.
[0134] According to one embodiment, the movable plate 90 has a large area corresponding to half of the 6G, and is preferably made of a glass material that is easy to form, easy to process, and low in cost, and more preferably a silicate glass or borosilicate glass material. In particular, borosilicate glass having excellent heat resistance, chemical resistance, mechanical strength, transparency, etc. can be used. 33 materials. In addition, The thermal expansion coefficient of 33 is about 3.3, which is not much different from the thermal expansion coefficient of the Invar alloy metal sheet 220', and has the advantage of being easy to control the metal sheet 220'.
[0135] According to another embodiment, the moving plate 90 may be made of materials such as titanium (Ti), molybdenum (Mo), silver (Ag), copper (Cu), platinum (Pt), and gold (Au) to have corrosion resistance against etching solutions such as F2Cl3.
[0136] According to another embodiment, the movable plate 90 may be made of Invar, Super Invar, stainless steel (SUS) coated with a corrosion-resistant metal such as titanium, molybdenum, silver, copper, platinum, gold, or the like, or a material coated with a polymer such as polyimide or plastic. Furthermore, a hard polymer such as polyimide or plastic may also be used as the movable plate 90. This has the advantage that the movable plate 90 can be easily configured to the aforementioned 6G half-grade or 6G grade sizes.
[0137] A temporary adhesive portion 95 may be provided between the movable plate 90 and the metal sheet 220′. The temporary adhesive portion 95 may be a device that provides an adhesive force for bonding the metal sheet 220′ to the movable plate 90. In particular, a dry film resist layer 95 (DFR layer) may be provided as the temporary adhesive portion 95. A thin film of photoresist may be provided as the dry film resist layer 95. As an example, a soft bake (baking) may be performed at a temperature of approximately 60°C for 60 seconds and a lamination process may be performed directly. While peeling off the protective film of the DFR, the photoresist layer of the DFR may be laminated on the first surface (lower surface) of the metal sheet 220′. Lamination may be performed with a predetermined roller pressure and a low-temperature process below approximately 60°C. Lamination is preferably performed under a vacuum state. Lamination under a vacuum state can prevent bubbles from being trapped at the interface between the dry film resist layer 95 and the metal sheet 220′ / movable plate 90.
[0138] The present invention utilizes a dry film resist layer 95 to perform bonding and lithography processes at low temperatures below approximately 60°C, effectively preventing heat-induced deformation of the metal sheet 200' during the process. Furthermore, the use of dry film resist 95 significantly reduces baking and exposure times compared to liquid photoresist. While the degassing baking and exposure process takes approximately one hour with liquid photoresist, using dry film resist only takes approximately two minutes, significantly reducing process time.
[0139] According to Korean Patent Application No. 2020-0043485 Figure 11 The prior art uses liquid wax to bond the mask metal film to the substrate supporting the mask metal film. The liquid wax layer is baked at a temperature of about 100 to 160°C in order to vaporize the solvent during use, and the lamination process is also carried out at a temperature of about 110°C. Therefore, in the high temperature range above 100°C, the mask metal film or metal sheet may have the problem of thermal deformation. In addition, liquid wax is also used to form a pattern for etching. That is, in the prior art, a liquid wax layer and a liquid photoresist layer are used between the mask metal film and the substrate supporting the mask metal film.
[0140] In contrast, the present invention utilizes a dry film resist layer 95, enabling bonding processes at temperatures below approximately 60°C. Furthermore, the dry film resist layer 95 alone achieves both bonding and etching pattern formation, eliminating the need for separate layers of liquid wax and liquid photoresist. Furthermore, as will be described later, the dry film resist layer 95 even provides etching resistance and adhesion to the metal sheet 220′ during the formation of the third unit pattern Cc.
[0141] in addition, Figure 11 Although not shown, it can also be found in Figure 11 The steps will be as follows Figure 14 The components such as the suction cup 80 shown in FIG. 8 are adsorbed on the moving plate 90 to control the movement of the moving plate 90 .
[0142] Then, refer to Figure 12 , a patterned insulating portion MM may be formed on the metal sheet 220 ′. The insulating portion MM may be formed of a photoresist material using a printing method or the like.
[0143] Next, the metal sheet 220' can be etched EC. Etching can be performed using dry etching, wet etching, or other methods, without particular limitation. As a result, the exposed portion of the metal sheet 220' between the insulating portions MM is etched. The etched portion of the metal sheet 220' can be sized to the size of the mask unit region CR, the size of the mask 100, or the size of the display on which the OLED pixel is formed.
[0144] Then, refer to Figure 13 , the insulating portion MM can be removed. After etching EC, the metal sheet 220′ can be a metal sheet portion 220 formed with an edge sheet portion 221, a first grid sheet portion 223, and a second grid sheet portion 225. The movable plate 90 can be provided in a form in which the unit sheet portion 220 is bonded thereto with a temporary bonding portion 95 (or dry film resist layer 95) interposed therebetween. The unit sheet portion 220 is formed with an edge sheet portion 221, a first grid sheet portion 223, and a second grid sheet portion 225.
[0145] Then, refer to Figure 14 The movable plate 90, to which the unit sheet portion 220 is bonded and supported, can be loaded onto the edge frame portion 210. The movable plate 90 can be transferred by a vacuum suction cup (not shown). For example, the movable plate 90 can be transferred by suctioning the surface opposite to the surface to which the unit sheet portion 220 is bonded using the vacuum suction cup 80.
[0146] The unit sheet portion 220 can contact and correspond to the edge frame portion 210. That is, the edge sheet portion 221 of the unit sheet portion 220 can contact and correspond to the upper surface of the edge frame portion 210. By loading the movable plate 90 onto the edge frame portion 210, the unit sheet portion 220 can be aligned with the edge frame portion 210. Since the movable plate 90 presses the unit sheet portion 220, the unit sheet portion 220 and the edge frame portion 210 can be closely abutted.
[0147] Next, laser light L is irradiated between the unit sheet portion 220 (or the edge sheet portion 221) and the edge frame portion 210, and the unit sheet portion 220 can be connected to the edge frame portion 210 by laser welding. A weld bead WB is generated between the laser-welded edge sheet portion 221 and the edge frame portion 210, and the edge sheet portion 220 can be connected to the edge frame portion 210 through the weld bead WB.
[0148] Then, refer to Figure 15 After the unit sheet portion 220 and the edge frame portion 210 are connected, the movable plate 90 is separated (debonded) from the unit sheet portion 220. The unit sheet portion 220 and the movable plate 90 can be separated by heating, chemically treating, applying ultrasound, or applying ultraviolet light to the temporary adhesive portion 95 [or the dry film resist layer 95]. By heating, chemically treating, applying ultrasound, or applying ultraviolet light to the temporary adhesive portion 95, the bonding force between the unit sheet portion 220 and the movable plate 90 is weakened, thereby separating the movable plate 90 from the unit sheet portion 220. After separating the movable plate 90, the temporary adhesive portion 95 remaining in the unit sheet portion 220 can be removed by cleaning or other methods.
[0149] Therefore, if Figure 15 (a) [lateral cross-sectional view], Figure 15 As shown in (b) [front view] of FIG, the unit sheet portion 220 is connected to the edge frame portion 210 . This can be provided as the frame 200 .
[0150] According to another embodiment, the edge sheet portion 221 and the edge frame portion 210 may be connected by metal connecting portions instead of laser welding. Figure 14 As shown, the movable plate 90, to which the unit sheet portion 220 is bonded and supported, can be loaded onto the edge frame portion 210. In this case, a metal connection portion (not shown) can be interposed between the unit sheet portion 220 (or the edge sheet portion 221) and the edge frame portion 210. The metal connection portion (not shown) can be formed on the lower surface of the edge sheet portion 221 facing the edge frame portion 210. Alternatively, the metal connection portion (not shown) can be formed on the upper surface of the edge frame portion 210 facing the edge sheet portion 221.
[0151] The metal connection portion may include at least one material selected from the group consisting of Cu, Ni, Au, Ag, Al, Sn, In, Bi, Zn, Sb, Ge, and Cd. The metal connection portion is preferably formed by sputtering or soldering, which are not limited to any material and can easily form a thin film.
[0152] Next, at least one of heat and pressure may be applied to the metal connection portion. The unit sheet portion 220 and the metal connection portion, i.e., the edge frame portion 210, may be heated to perform a heat treatment. Alternatively, by simultaneously heating the unit sheet portion 220, the metal connection portion, and the edge frame portion 210 while applying pressure, a heat treatment can be performed with minimal heat.
[0153] The heat treatment by applying heat and pressure can be performed within the range where the metal connection portion can connect the unit sheet portion 220 and the edge frame portion 210. As an example, the metal of the metal connection portion can be melted during the heat treatment and then resolidified to connect the unit sheet portion 220 and the edge frame portion 210. As another example, the interface state of the unit sheet portion 220 and the edge frame portion 210 can be changed and connected by the diffusion of metal components of the metal connection portion into the unit sheet portion 220 and the edge frame portion 210, or conversely, by the diffusion of components of the unit sheet portion 220 and the edge frame portion 210 into the metal connection portion, or by mutual diffusion of components.
[0154] The heat treatment may be performed at a temperature of about 200°C to 800°C, and more preferably, at a low temperature range of about 200°C to 400°C.
[0155] After the unit sheet portion 220 and the edge frame portion 210 are connected, the movable plate 90 may be separated from the unit sheet portion 220. The above-described separation process of the movable plate 90 may be directly employed.
[0156] Figure 16 Schematic diagram of the stretched state of the unit sheet portion and the movable plate based on the change of process temperature according to one embodiment of the present invention.
[0157] In the prior art, when aligning the unit sheet portion 220 with the edge frame portion 210, all sides of the unit sheet portion 220 are first stretched to flatten the unit sheet portion 220, and then the edge sheet portion 221 is aligned with the edge frame portion 210. Next, the edge sheet portion 221 is connected to the edge frame portion 210. Furthermore, after the planar sheet is stretched and attached to the edge frame portion 210, the mask unit regions CR can be removed by laser scribing, etching, or the like, to form the unit sheet portion 220. However, because the conventional method directly stretches the side surfaces of the unit sheet portion 220 by connecting a clamping device such as a jig, there is a problem of increased alignment error between the mask unit regions CR.
[0158] On the contrary, the present invention forms the mask unit area CR in a state where the metal sheet 220′ is bonded and supported on the movable plate 90, without stretching the manufactured unit sheet portion 220. The supporting unit sheet portion 220 is connected to the edge frame portion 210 in a state where it is bonded and supported by the movable plate 90, thereby having the effect of reducing alignment errors.
[0159] The present invention does not use a clamping device such as a clamp directly connected to the side of the unit sheet portion 220 to perform stretching. Instead, it utilizes the difference in thermal expansion coefficient between the movable plate 90 and the metal sheet 220' to control the temperature and apply internal tensile force to the metal sheet 220' on the movable plate 90. The large-area metal sheet 220' can apply uniform tensile force in all directions or radial directions on the large-area movable plate 90. Figure 16 The operation of the metal sheet 220 ′ in the process of contacting the moving plate 90 will be described.
[0160] According to one embodiment, Figure 16 As shown, the degree of stretching or the stretching force IT of the metal sheet 220 ′ can be controlled by controlling the process temperature. Figure 16 In (a), in order to compare the extent of expansion and contraction of the metal sheet 220 ′ and the movable plate 90 , the initial lengths are the same, but the movable plate 90 may be greater than or equal to the length of the metal sheet 220 ′, and vice versa.
[0161] Reference Figure 16 (a) A movable plate 90 and a metal sheet 220 ′ (or a unit sheet portion 220 having a mask unit region CR formed thereon) are prepared at a room temperature RT (Room Temperature) of approximately 25° C. Figure 16Taking the example of metal sheet 220' being made of Invar and movable plate 90 being made of quartz, which has a lower thermal expansion coefficient than Invar, as an example, temporary adhesive portion 95 (or dry film resist 95) may be formed on one side of movable plate 90 or / and metal sheet 220'.
[0162] Next, refer to Figure 16 (b) The process temperature can be raised to a level where the push-pull strength of the temporary bonding portion 95 becomes 0 to 5 kgf / cm 2 The first process temperature TS1 may be about 50 to 70° C. At the first process temperature TS1, the temporary adhesive portion 95 may be 0 to 5 kgf / cm 2 , it is as if the temporary adhesive portion 95 does not have the adhesive force to bond the metal sheet 220′ and the movable plate 90. That is, the temporary adhesive portion 95 is in a non-sticky state, that is, the metal sheet 220′ and the movable plate 90 are not easily bonded. This can be understood as a state where the metal sheet 220′ can be easily separated from the movable plate 90 even without load or external force. Therefore, the metal sheet 220′ and the movable plate 90 are only in a state of contact with each other with the temporary adhesive portion 95 [and the first insulating portion 23] sandwiched between them, and are not bonded. The metal sheet 220′ can be linearly stretched as the temperature rises without being hindered by the temporary adhesive portion 95. Moreover, the thermal expansion coefficient of the movable plate 90 is lower than that of the metal sheet 220′. Therefore, at the first process temperature TS1, the stretching degree L1 of the metal sheet 220′ can be greater than the stretching degree L2 of the movable plate 90.
[0163] Next, refer to Figure 16 (c), with the metal sheet 220' in contact with the movable plate 90, the process temperature can be lowered to a level where the bonding strength of the temporary bonding portion 95 is at least greater than 5 kgf / cm 2 The second process temperature TS2 is approximately 40 to 60°C lower than the first process temperature TS1 and may be higher than room temperature. At the second process temperature TS2, the temporary adhesive portion 95 exhibits adhesive strength, allowing the metal sheet 220′ to bond to the movable plate 90. As the temperature decreases, the movable plate 90 contracts (L2 -> L3), and the metal sheet 220′ also contracts accordingly.
[0164] However, the process temperature Figure 16When the process from step (b) to step (c) is lowered (TS1->TS2), the temporary bonding portion 95 cools and hardens first, while the temperature of the metal sheet 220' decreases at a slower rate than that of the temporary bonding portion 95. As a result, the metal sheet 220' can be bonded to the movable plate 90 in a stretched state. In other words, compared to directly raising the temperature to the second process temperature TS2 at room temperature RT and then bonding the metal sheet 220' to the movable plate 90, Figure 16 As shown, by adding a step of increasing the temperature to the first process temperature TS1 between room temperature RT and the second process temperature TS2, the metal sheet 220' can be bonded to the movable plate 90 in a further stretched state. After directly increasing the temperature from room temperature RT to the second process temperature TS2, when the metal sheet 220' is bonded to the movable plate 90, the temporary bonding portion 95 has a considerable bonding force. Therefore, the metal sheet 220' is hindered by the temporary bonding portion 95 and may not experience linear stretching as the temperature rises. The further stretching of the metal sheet 220' corresponds to a further increase in the tensile force IT contained in the metal sheet 220' supported on the movable plate 90, which means that after the unit sheet portion 220 is aligned / attached to the edge frame portion 210 in the subsequent process, the unit sheet portion 220 may be in a further expanded state.
[0165] However, it should be noted that this does not exclude the process of directly raising the temperature from room temperature RT to the second process temperature TS2 and then bonding the metal sheet 220 ′ to the movable plate 90 .
[0166] Next, refer to Figure 16 (e) The process temperature can be raised to room temperature RT. As the temperature drops, the movable plate 90 can shrink (equivalent to L3), and the metal sheet 220' also shrinks accordingly. The movable plate 90 can be restored to Figure 16 The length of the metal sheet 220′ in the initial state at room temperature (RT) is obtained by bonding and fixing the metal sheet 220′ to the movable plate 90 in a state stretched by L5 compared to the initial state at room temperature (RT). The degree of stretching L5 and the tensile force IT contained in the metal sheet 220′ are greater than those in the process of bonding the metal sheet 220′ to the movable plate 90 after directly raising the temperature from room temperature (RT) to the second process temperature TS2.
[0167] In addition, Figure 16 Between steps (c) and (e), a process of lowering the process temperature to a process temperature TS3 lower than the room temperature RT may be performed. Then, the temperature may be raised to the room temperature RT again. As the temperature drops to the process temperature TS3, the movable plate 90 further contracts by L4 compared to the room temperature state, and the metal sheet 220' may contract accordingly. The process temperature TS3 may be approximately 5 to 15°C. Moreover, the maintenance time of the process temperature TS3 may be at least equal to or greater than Figure 16The maintenance time of process temperature TS1 and TS2 of (b) and (c) is determined. For example, if the maintenance time of TS1 is 1 minute and the maintenance time of TS2 is 1 minute, the maintenance time of TS3 can be more than 2 minutes. As described above, by rapidly decreasing rather than slowly decreasing, the viscosity of temporary adhesive portion 95 can be increased, and the bonding strength can also be increased. As the viscosity of temporary adhesive portion 95 is maximized, metal sheet 220' is more firmly bonded to movable plate 90, Figure 16 The length of the metal sheet 220' further stretched in step (b) can still be maintained after the temperature drops.
[0168] described Figure 16 This is based on an embodiment of providing an internal tensile force IT to the metal sheet 220 ′ on the movable plate 90 through temperature control, but is not limited thereto. Other temperature control methods may also be used to provide the internal tensile force IT to the metal sheet 220 ′.
[0169] According to another embodiment, the metal sheet 220' can be made of an Invar alloy sheet, and the moving plate 90 can be made of a material having a thermal expansion coefficient greater than that of the Invar alloy. 33. In this case, compared to Figure 16 In the embodiment, the temperature control can be performed in the reverse direction. First, the process temperature can be lowered to a temperature at least lower than room temperature (20±5°C). The temperature lower than room temperature can include a range from sub-zero to room temperature.
[0170] In the next step, the metal sheet 220 ′ and the moving plate 90 are bonded to each other by sandwiching a temporary bonding portion 95 made of a dry film resist material.
[0171] Next, the process temperature can be raised to room temperature. During this process, due to the high coefficient of thermal expansion of movable plate 90, the metal sheet 220' is stretched to a greater degree. Since metal sheet 220' is bonded to movable plate 90, movable plate 90 is stretched further than metal sheet 220'. Consequently, tensile forces can be applied to all sides of metal sheet 220'. Metal sheet 220' can be bonded and supported on movable plate 90 while being subjected to lateral tensile forces.
[0172] According to another embodiment, if the metal sheet 220′ is directly stretched and then bonded to the movable plate 90, the large area of the movable plate 90 may bend due to the tensile force of the large area of the metal sheet 220′. If the metal sheet 220′ [or the unit sheet portion 220] is bonded to the movable plate 90, there is a possibility that it will bend concavely in the direction of the metal sheet 220′. In other words, the movable plate 90 located at the bottom may bend downward. In this case, after the movable plate 90 is turned over and aligned with the edge frame portion 210, the upward-bent movable plate 90 is flattened by its own weight and pressurizes the bonded metal sheet 220′ [or the unit sheet portion 220] to flatten the bent portion together. As a result, the metal sheet 220′ [or the unit sheet portion 220] can be connected to the edge frame portion 210 in a taut state.
[0173] On this basis, Figure 14 The suction cup 80 may further include a heating device. The suction cup 80 generates heat, which is transferred to the metal sheet 220' and the moving plate 90. Figure 16 As described in , the metal sheet 220 ′ can also be stretched based on temperature control.
[0174] In addition, unlike the above-mentioned process of forming the mask pattern P with a tiny size, in the unit sheet portion 220, more emphasis is placed on the accurate alignment of multiple mask unit areas CR along the X-axis and Y-axis directions. The OLED pixel-forming organic matter that passes through one mask unit area CR constitutes a pixel of a display after passing through multiple mask patterns P of the mask 100. In other words, different mask unit areas CR can correspond to different displays. In order to ensure the mass production quality of OLED pixels, the X-axis and Y-axis length error range between the mask unit areas CR should be below about ±30 to 40μm. With the development of OLED technology, minimizing the frame has become a trend. In order to minimize the frame width, the edge width of the mask unit area CR, the peripheral portion of the mask 100 through which the pixel-forming organic matter passes, needs to be more constant.
[0175] In addition, if wet etching is performed during the process of forming the mask unit region CR in the unit sheet portion 220, Figure 8 As described in the above, when etching liquid enters the surface and the opposite surface based on isotropic etching, the size difference of the mask unit region CR will inevitably become larger. Based on the consideration of minimizing the frame, the dead space at the edge of the mask unit region CR where wet etching is performed needs to be minimized.
[0176] Therefore, a manufacturing method capable of reducing edge errors between mask unit regions CR and minimizing dead zones will be described below.
[0177] Figures 17 and 18FIG. 1 is a schematic diagram of a manufacturing process of a unit sheet portion according to an embodiment of the present invention. Figure 19 FIG. 1 is a schematic diagram of a unit pattern of a unit sheet portion according to an embodiment of the present invention.
[0178] For convenience of description, the following description will be made by taking the formation of one mask unit region CR in the unit sheet portion 220 as an example. However, it can also be understood that a plurality of mask unit regions CR need to be formed simultaneously.
[0179] Reference Figure 17 (a), first, a metal sheet 220' for manufacturing the unit sheet portion 220 of the frame 200 may be prepared. Figure 11 As described above, the metal sheet 220 ′ may be bonded to the movable plate 90 with the temporary bonding portion 95 (or dry film resist layer 95 ) interposed therebetween.
[0180] The metal sheet 220' is used as the unit sheet portion 220 for supporting the mask 100, and its thickness may be greater than that of the mask 100. According to one embodiment, the thickness of the metal sheet 220' may be approximately 70 μm to 200 μm. The thickness of the metal sheet 220' may be at least twice the thickness of the mask 100. In addition, within a thickness range that is greater than or more than twice the thickness of the mask 100, the thickness of the metal sheet 220' may also be determined to be approximately 50 μm to 200 μm. As an example, when the thickness of the mask 100 is approximately 2 μm to 50 μm, the thickness of the metal sheet 220' is several times to dozens of times greater, and the width of the mask unit region CR [or, unit pattern CP] is in the range of tens of mm to hundreds of mm, which is also much greater than the width of the mask pattern P of approximately tens of μm. Therefore, the wet etching process also needs to be performed in a different manner to form the mask unit region CR [or, unit pattern CP]. Thus, a process for forming at least three unit patterns Ca, Cb, and Cc is used for the unit sheet portion 220. Below, an example of forming the mask unit region CR using three unit patterns Ca, Cb, and Cc will be described, given a thickness of approximately 150 μm. However, depending on the thickness of the unit sheet portion 220, the mask unit region CR can also be formed using at least four unit patterns by adding an etching process.
[0181] A patterned first insulating portion Ma may be formed on one side (top) of the metal sheet 220'. The first insulating portion Ma may be formed of a photoresist material by a printing method or the like. The material and forming method of the first insulating portion Ma may be Figure 5 (a) Formation process of the first insulating portion M1.
[0182] Then, refer to Figure 17(b) A first unit pattern Ca having a predetermined depth can be formed on one side (top) of the metal sheet 220 by a first wet etching process WEA. When the first wet etching process WEA is performed, the metal sheet 220 should not be penetrated. Therefore, the first unit pattern Ca can be formed so as not to penetrate the metal sheet 220′a and to have a generally arc shape.
[0183] Because the first wet etch process WEA has isotropic etching characteristics, the width Rb of the first unit pattern Ca is not equal to the width of the spacing Ra between the patterns of the first insulating portion Ma, and is larger than the spacing Ra between the patterns of the first insulating portion Ma. In other words, because undercuts are formed at the lower portions of both sides of the first insulating portion Ma, the width Rb of the first unit pattern Ca can be greater than the spacing Ra between the patterns of the first insulating portion M1 by the width of the undercut UC. The spacing Ra between patterns can roughly correspond to the width of the mask cell region CR (or, the unit pattern CP), equivalent to tens to hundreds of millimeters.
[0184] The first unit pattern Ca may be formed to a depth of 60% to 70% of the thickness of the metal sheet 220'. For example, when a metal sheet 220' having a thickness of approximately 150 μm is used, the first unit pattern Ca may be formed to a depth of approximately 90 to 105 μm. Therefore, the difference between the width Rb of the first unit pattern Ca due to the undercut and the spacing Ra between the patterns of the first insulating portion Ma may be equal to or less than the depth of the first unit pattern Ca.
[0185] Then, refer to Figure 17 (c) The second insulating portion Mb may be formed at least in the first unit pattern Ca. In the state where the first unit pattern Ca is formed, the process of forming the second insulating portion Mb may be performed by Figure 5 (c) and Figure 6 After forming the second insulating portion Mb on one side (top) of the metal sheet 220′c and baking and volatilizing a portion of the second insulating portion Mb, exposure L is performed from above so that the first insulating portion Ma can be used as an exposure mask. Since the second insulating portion Mb is a positive photoresist, the portion exposed L will be removed. The space left for the second insulating portion Mb can correspond to the space for forming the undercut at the lower part of both sides of the first insulating portion Ma [refer to Figure 5 (b) step]. The interval Ra between the patterns of the second insulating portion Mb may be equal to the interval Ra between the patterns of the first insulating portion Ma.
[0186] Then, refer to Figure 18(d) A second wet etching process WEb can be performed on the first unit pattern Ca of the metal sheet 220'b. The wet etching solution can penetrate the spaces between the patterns of the first insulating portion Ma and the spaces between the first unit patterns Ca and perform the second wet etching process WEb. The second wet etching process WEb can form the second unit pattern Cb to a predetermined depth. When the second wet etching process WEb is performed, the metal sheet 220'a should not be penetrated. Therefore, the second unit pattern Cb can be formed so as not to penetrate the metal sheet 220'b and to have a generally arc shape.
[0187] Because the second wet etch process WEb has isotropic etching characteristics, the width Rc of the second unit pattern Cb is not equal to the spacing Ra between the second insulating portion Mb patterns, and is larger than the spacing Ra between the second insulating portion Mb patterns. In other words, because undercuts are formed at the lower portions of both sides of the second insulating portion Mb, the width Rc of the second unit pattern Cb can be greater than the spacing Ra between the second insulating portion Mb patterns by a width sufficient to form the undercuts.
[0188] The second unit pattern Cb may be formed to a depth of approximately 20% to 30% of the thickness of the metal sheet 220'. For example, when a metal sheet 220' having a thickness of approximately 150 μm is used, the second unit pattern Cb may be formed to a depth of approximately 30 to 45 μm. Therefore, the difference between the width Rc of the second unit pattern Cb due to undercutting and the spacing Ra between the patterns of the second insulating portion Mb may be equal to or less than the formation depth of the second unit pattern Cb.
[0189] In addition, the formation depth of the first unit pattern Ca is greater than the formation depth of the second unit pattern Cb, and the difference between the width Rb of the first unit pattern and the spacing Ra between the first insulating part Ma or the second insulating part Mb pattern may be greater than the difference between the width Rc of the second unit pattern and the spacing Ra between the first insulating part Ma or the second insulating part Mb pattern.
[0190] Then, refer to Figure 18 (e) A third insulating portion Mc may be formed at least in the second unit pattern Cb. In a state where the second unit pattern Cb is formed, the process of forming the third insulating portion Mc may be the same as that of Figure 17 The formation process of the second insulating portion Mb described in (c) is the same. The space left for the third insulating portion Mc can correspond to the space used to form undercuts at the lower portions of both sides of the second insulating portion Mb. The spacing Ra between the patterns of the third insulating portion Mc can be equal to the spacing Ra between the patterns of the first insulating portion Ma.
[0191] Then, refer to Figure 18(f) A third wet etch process WEc can be performed on the second unit patterns Cb of the metal sheet 220'b. The wet etching solution can penetrate the spaces between the patterns of the third insulating portion Mc and the spaces between the second unit patterns Cb, and the third wet etch process WEb can be performed. The third wet etch process WEc penetrates the metal sheet 220'b to form the third unit pattern Cc. Specifically, the third unit pattern Cc can be formed by penetrating the other side of the metal sheet 220'c from the lower end of the second unit pattern Cb through the bottom end of the second unit pattern Cb.
[0192] Furthermore, when using liquid wax or photoresist to bond the movable plate 90 to the metal sheet 220', as in the prior art, the metal sheet 220'c surrounding the third unit pattern Cc loses contact with the liquid wax / photoresist layer during the third wet etching process WEc, resulting in a warped portion. Due to the weak adhesion between the liquid wax / photoresist layer, the warped portion can further warp. In this case, if the third wet etching solution intrudes between the warped portions, the desired third unit pattern Cc may not be formed.
[0193] However, in the present invention, the dry film resist layer 95 used to bond the movable plate 90 to the metal sheet 220' exhibits superior adhesion and etching resistance compared to conventional liquid wax / photoresist layers. The metal sheet 220' adheres tightly to the dry film resist layer 95 with strong adhesion, resulting in no raised portions of the metal sheet 220'c surrounding the third unit pattern Cc. This absence of raised portions allows for the clear formation of the desired third unit pattern Cc.
[0194] Because the third wet etch process WEc has isotropic etching characteristics, the width Rd of the third mask pattern Cd is not equal to the spacing Ra between the patterns of the third insulating portion Mc, and is larger than the spacing Ra between the patterns of the third insulating portion Mc. In other words, because undercuts are formed below both sides of the third insulating portion Mc, the width Rd of the third unit pattern Cc can be greater than the spacing Ra between the patterns of the third insulating portion Mc by a width sufficient to form the undercuts.
[0195] The third unit pattern Cc may be formed to a depth of approximately 10% to 20% of the thickness of the metal sheet 220 ′. For example, when the metal sheet 220 ′ is approximately 150 μm thick, the third unit pattern Cc may be formed to a depth of approximately 15 μm to 30 μm.
[0196] In addition, since the formation depth of the second unit pattern Cb is greater than the formation depth of the third unit pattern Cc, the difference between the width Rc of the second unit pattern and the spacing Ra between the patterns of the first insulating part Ma, the second insulating part Mb and the third insulating part Mc can be greater than the difference between the width Rd of the third unit pattern and the spacing Ra between the patterns of the first insulating part Ma, the second insulating part Mb and the third insulating part Mc.
[0197] Because the lower width of the third cell pattern Cc defines the width of the mask cell region CR, the smaller the difference between the width Rd of the third cell pattern and the spacing Ra between the patterns of the first insulating portion Ma, the second insulating portion Mb, and the third insulating portion Mc, the smaller the X-axis or Y-axis width error range between the mask cell regions CR. Therefore, the difference between the width Rd of the third cell pattern and the spacing Ra between the patterns of the first insulating portion Ma, the second insulating portion Mb, and the third insulating portion Mc is preferably approximately 30 μm or less.
[0198] Then, refer to Figure 19 By removing the first insulating portion Ma, the second insulating portion Mb, and the third insulating portion Mc, the production of the unit sheet portion 220 is completed. The shapes of the connected first unit pattern Ca, the second unit pattern Cb, and the third unit pattern Cc are combined to form the unit pattern CP (or the mask unit region CR).
[0199] As described above, the thickness Tc of the first unit pattern Ca may be approximately 60% to 70% of the thickness T of the unit sheet portion 220, the thickness Tb of the second unit pattern Cb may be approximately 20% to 30% of the thickness T of the unit sheet portion 220, and the thickness Ta of the third unit pattern Cc may be approximately 10% to 20% of the thickness of the unit sheet portion 220. The sum of the thicknesses of the first unit pattern Ca, the second unit pattern Cb, and the third unit pattern Cc may correspond to the thickness T of the unit sheet portion 220.
[0200] In addition, according to another embodiment, the thickness T of the first unit pattern Ca may be equal to the thickness Tb of the second unit pattern Cb. In this case, the thickness Ta of the third unit pattern Cc is also less than or equal to the thickness Tc of the first unit pattern Ca or the thickness Tb of the second unit pattern Cb, which is more beneficial for reducing the error range of the width of the opening (mask unit region CR).
[0201] The two side surfaces of the unit pattern CP (mask unit region CR) are curved. The side surfaces of the first unit pattern Ca, the second unit pattern Cb, and the third unit pattern Cc can be curved or concave. Overall, the two side surfaces of the unit pattern CP can be inclined.
[0202] More specifically, the inclination between a horizontal plane and any straight line L1 extending from the upper corner Ca1 of the first unit pattern Ca to the upper corner Cb1 of the second unit pattern Cb, and the inclination between a horizontal plane and any straight line L2 extending from the upper corner Cb1 of the second unit pattern Cb to the upper corner Cc1 of the third unit pattern Cc, can be non-perpendicular. Furthermore, because the thickness of the first unit pattern Ca is greater than that of the second unit pattern Cb, and due to the isotropic etching morphology, the inclination between a horizontal plane and any straight line L2 extending from the upper corner Cb1 of the second unit pattern Cb to the upper corner Cc1 of the third unit pattern Cc can be greater than the inclination between a horizontal plane and any straight line L1 extending from the upper corner Ca1 of the first unit pattern Ca to the upper corner Cb1 of the second unit pattern Cb.
[0203] Figure 20 FIG. 1 is a schematic diagram illustrating a state in which the mask 100 is connected to the unit sheet portion 220 according to an embodiment of the present invention.
[0204] Reference Figure 20 , the unit sheet portion 220 is welded on the edge frame portion 210 to form a weld bead WB1 and connected. In addition, the mask 100 is welded on each mask unit region CR of the unit sheet portion 220 to form a weld bead WB2, so that the mask 100 can be connected to the unit sheet portion 220. Figure 20 As a reference, the mask 100 may be connected to the upper portion of the third unit pattern Cc. That is, the opening width on the third unit pattern Cc may substantially provide the mask unit region CR.
[0205] The mask 100 may completely cover the mask cell region CR. In addition, only when the cells C of the plurality of mask patterns P of the mask 100 are formed [refer to Figure 3 ] is within the width of the mask cell region CR, the dummy portion of the mask 100 can be supported on the mask cell region CR. Therefore, the exposed area [opening width] of the third cell pattern Cc can be larger than the area of the multiple mask patterns P formed on the mask 100, that is, the cell C.
[0206] The width of the mask unit region CR (or unit pattern CP) along the X-axis or Y-axis is tens to hundreds of millimeters. Therefore, the organic matter deposited during the OLED pixel deposition process that enters from the center of the mask unit region CR has a high degree of uniformity. However, there is also the possibility that the organic matter may enter from the edge of the mask unit region CR. According to one embodiment, the inclination a3 between any straight line L1 from the upper corner Cal of the first unit pattern Ca to the upper corner Cb1 of the second unit pattern Cb and the horizontal plane [refer to Figure 19] can be 50° or less. That is, during the OLED pixel deposition process, deposited organic matter can enter the first unit pattern Ca, which it passes through first, along the surface with a smaller inclination of less than 50° and a wider area (arrows indicate the direction of entry of the organic matter). This reduces the amount of organic matter that scatters from the inner walls of the first unit pattern Ca and enters the center. Conversely, the amount of organic matter that enters from the corners of the unit pattern CP increases, allowing the organic matter to enter more evenly throughout the entire mask unit region CR before passing through the mask pattern P of the mask 100.
[0207] In addition, if Figure 19 As described in the foregoing, the inclination between an arbitrary straight line L2 from the upper corner Cb1 of the second unit pattern Cb to the upper corner Cc1 of the third unit pattern Cc and the horizontal plane is greater than the inclination between an arbitrary straight line L1 from the upper corner Ca1 of the first unit pattern Ca to the upper corner Cb1 of the second unit pattern Cb and the horizontal plane, so that the deposited organic matter can start to enter along a wider surface in the first unit pattern Ca and gradually concentrate toward the edge portion of the mask unit region CR. Therefore, before passing through the mask pattern P of the mask 100, the organic matter can enter the entire area of the mask unit region CR more uniformly.
[0208] Figure 21 This is an electron microscope photograph of a unit pattern according to one embodiment of the present invention.
[0209] Reference Figure 21 As can be seen, the thickness of mask 100 is approximately 140μm. The first, second, and third unit patterns Ca, Cb, and Cc are isotropically etched, resulting in curved side surfaces. The darker layers above unit pattern CP correspond to the first, second, and third insulating portions Ma, Mb, and Mc. The angle a3 of any straight line L1 from the upper corner Ca1 of first pattern Ca to the upper corner Cb1 of second unit pattern Cb is approximately 47.8°, with a greater inclination in the lower portion. This allows organic matter entering from the corners of first unit pattern Ca to be more uniformly concentrated toward third unit pattern Cc. Organic matter that passes through third unit pattern Cc (or, mask unit region CR) can pass through mask pattern P of mask 100 and form OLED pixels on the target substrate where they are to be formed.
[0210] Figure 22 FIG. 1 is a schematic diagram showing an alignment state of a mask cell region of a unit sheet portion according to a comparative example. Figure 23 Based on the comparative example Figure 22 Schematic diagram of the edge position values of each mask unit area.
[0211] Figure 22 and Figure 23In the description, a total of 10 mask cell regions CR: CR11-CR25 consisting of 5×2 are used as a reference. However, it should be noted that the tendency is substantially also applicable to mask cell regions formed in other regions. Figure 22 The portion indicated by the middle dotted line is the design setting value of the mask cell region formation position in the initial design, and the portion indicated by the solid line is the actual measured value.
[0212] The comparative example does not use a state where the unit sheet portion 220 [or metal sheet 220′] is bonded and supported on the movable plate 90. After the unit sheet portion 220 is manufactured, a clamping device such as a gripper is connected to the side or edge of the unit sheet portion 220 and stretched. In particular, in order to facilitate the application of a tensile force to the entire unit sheet portion 220, it is generally adopted to connect the clamping device to the ends of the first grid sheet portion 223 and the second grid sheet portion 225 and stretch them. Figure 22 As a reference, the clamping device can be connected to the left and right ends of the first grid sheet portion 223 and apply a tensile force F1 in the left-right direction. In addition, the clamping device can be connected to the upper and lower ends of the second grid sheet portion 225 and apply a tensile force F2 in the vertical direction. That is, the first tensile force F1 can be applied in a direction parallel to the edge of the mask unit area (the left-right direction), and the second tensile force F2 can be applied in a direction perpendicular to the edge of the mask unit area (the vertical direction). Figure 22 The arrow positions of the intermediate tensile forces F1 and F2 can be understood as the points where the tensile forces are directly applied.
[0213] As described above, by applying tensile forces F1 and F2 to the respective ends of the first and second grid sheet sections 223 and 225 and controlling the tensile forces of the unit sheet section 220, the tensile forces are distributed across the entire unit sheet section 220. Specifically, since the tensile forces F1 and F2 are adjusted at the ends (or tensile axis) of the first and second grid sheet sections 223 and 225, the center of the mask cell region CR can be kept constant (uniform position over a large area). However, since the tensile forces F1 and F2 are adjusted locally at the respective ends (or tensile axis) of the first and second grid sheet sections 223 and 225, distortion or jagged distortion can easily occur from the perspective of each mask cell region CR (non-uniform position over a small area). In practical applications, the deviation between the sides of the mask cell region CR and the design values is preferably within a range of approximately 20 μm or less.
[0214] Figure 23 yes Figure 22 The numerical value of the degree to which the actual measured value (solid line) deviates from the design value (dashed line) ( Figure 23The 10 quadrilaterals correspond to 10 mask unit regions CR: CR11 to CR25.
[0215] Reference Figure 22 and Figure 23 It can be seen that the upper mask cell regions CR11 to CR15 have a similar tendency and are twisted, and the lower mask cell regions CR21 to CR25 have a similar tendency and are twisted. The tendency that can be confirmed is that the upper portions of the upper mask cell regions CR11 to CR15 are tilted to the right, and the lower portions are tilted to the left.
[0216] Reference Figure 23 The values show that the upper right edge of the mask cell regions CR11-CR15 in the upper row is tilted with a deviation of approximately +9 to +23 μm, and the lower left edge is tilted with a deviation of approximately +12 to +21 μm. Conversely, the lower right edge of the mask cell regions CR11-CR15 in the upper row is tilted with a deviation of approximately -17 to -25 μm, and the upper left edge is tilted with a deviation of approximately -8 to +1 μm.
[0217] The lower row of mask cell regions CR21-CR25 exhibits a tilt in the opposite direction to the upper row of mask cell regions CR11-CR15. It can be confirmed that the upper right end portion of the lower row of mask cell regions CR21-CR25 is tilted with a deviation of approximately -17 to -22 μm, and the lower left end portion is tilted with a deviation of approximately -5 to +1 μm. Conversely, the lower right end portion of the lower row of mask cell regions CR21-CR25 is tilted with a deviation of approximately +4 to +15 μm, and the upper left end portion is tilted with a deviation of approximately +4 to +18 μm. Furthermore, it can be confirmed that the lower row of mask cell regions CR21-CR25 exhibits an overall downward misalignment compared to the design value, with an upper side of approximately -12 to -20 μm and a lower side of approximately +4 to +18 μm.
[0218] Overall based on Figure 23 It can be seen from the numerical values that the mask unit areas CR11 to CR15 in the upper row are further distorted along the upper right end and the lower left end (i.e., the diagonal direction), and the mask unit areas CR21 to CR25 in the lower row are further distorted along the upper left end and the lower right end (i.e., the diagonal direction).
[0219] From another perspective, according to Figure 23 The numerical values show the deviations of the four sides of each mask cell region CR11 to CR25 with respect to the X-axis or Y-axis of the design value.
[0220] Table 1 below shows the parallel deviations between the top and bottom edges of the ten mask cell regions CR11 to CR25 and the X-axis, and the parallel deviations between the left and right edges and the Y-axis. The X-axis parallel deviations are shown using the left and right ends of each top and bottom edge of the mask cell regions CR11 to CR25 as a reference, while the Y-axis parallel deviations (in μm) are shown using the top and bottom edges of each left and right edge as a reference. For example, the top edge of CR11 has a left and right end of -8 and a difference of 0, so it is considered parallel to the X-axis. The top and bottom ends of CR11 have a difference of 1 and 21, so it is considered non-parallel to the Y-axis and tilted by -20 μm. Larger values indicate non-parallelism with the X and Y axes, and more severe distortion.
[0221] [Table 1]
[0222]
[0223] As shown in Table 1, the absolute values of the top and bottom sides of the mask cell region CR are equal to or less than 10 μm, resulting in a generally small difference in inclination with respect to the X-axis. However, the absolute values of the left and right sides of the mask cell region CR are approximately 20 to 50 μm, resulting in a significant difference in inclination with respect to the Y-axis. The left and right sides exhibit a diagonal distortion, with negative / integer and integer / negative values.
[0224] Figure 24 FIG. 1 is a schematic diagram illustrating an alignment state of a mask unit region of a unit sheet portion according to an embodiment of the present invention. Figure 25 This is an embodiment of the present invention Figure 24 Schematic diagram of the edge position values of each mask unit area.
[0225] Figure 24 and Figure 25 In the description, 10 mask cell regions CR: CR11 to CR25 formed by 5×2 are used as a reference. However, it should be noted that the tendency of mask cell regions formed by other regions is substantially also applicable. Figure 24 The dotted line portion indicates a design setting value related to the position for forming the mask cell region in the initial design, and the solid line portion indicates an actual measured value.
[0226] One embodiment of the present invention adopts Figures 11 to 16The state in which the unit sheet portion 220 [or the metal sheet 220'] is bonded and supported on the movable plate 90 is described. Instead of using a clamping device to directly stretch the unit sheet portion 220, an internal tensile force is applied through temperature control. The unit sheet portion 220 [or the metal sheet 220'] can uniformly apply tensile forces F3 and F4 in all directions or radial directions on the large-area movable plate 90. Observed from another angle, the unit sheet portion 220 can apply more uniform tensile forces F3 and F4 in all directions or radial directions based on the mask unit area CR, regardless of the first grid sheet portion 223 and the second grid sheet portion 225. Based on this, unlike Figure 22 , Figure 24 The actual effects of the tensile forces F3 and F4 may be independent of the directions and positions of the arrows of the tensile forces F3 and F4 shown in the figure.
[0227] Therefore, the present invention has an effect of facilitating the distribution of tensile force (uniform position within a small range) not only from the perspective of the entire unit sheet portion 220 but also from the perspective of each mask unit region CR.
[0228] Figure 25 yes Figure 24 The numerical value of the degree to which the actual measured value (solid line) deviates from the design value (dashed line) ( Figure 25 The 10 quadrilaterals correspond to 10 mask unit regions CR: CR11 to CR25.
[0229] Reference Figure 24 and Figure 25 As can be seen, the upper row of mask cell regions CR11-CR15 and the lower row of mask cell regions CR21-CR25 do not exhibit similar distortion. The edges of each mask cell region CR:CR11-CR25 are generally uniformly stretched. Furthermore, the deviations of the edges of each mask cell region CR:CR11-CR25 from the design value (dashed line) are generally random.
[0230] Reference Figure 25 The values of CR11 to CR15 show that the positions of the mask unit regions CR11 to CR15 in the upper row are shifted to the left or the left side is stretched to the left compared to the design values. However, it has not been confirmed that Figure 23 The distortion along the diagonal direction is shown. The four sides of the mask cell regions CR21 to CR25 in the lower row are not distorted, and the overall linear stretching is uniform. Given that the alignment error of the mask cell regions CR is preferably equal to or less than 20μm, it can be seen that most mask cell regions CR fall within this range.
[0231] From another perspective, according to Figure 25The numerical values show the deviations of the four sides of each mask cell region CR11 to CR25 with respect to the X-axis and Y-axis of the design values.
[0232] Table 2 below shows the parallel deviations between the upper and lower sides of the ten mask unit regions CR11 to CR25 and the X axis, and the parallel deviations between the left and right sides and the Y axis. The calculation process is as described in Table 1.
[0233] [Table 2]
[0234]
[0235] As shown in Table 2, the absolute values of the upper and lower edges of the mask cell region CR are equal to or less than 10 μm, resulting in a generally small difference in inclination with respect to the X-axis. Furthermore, the absolute values of the left and right edges of the mask cell region CR are approximately equal to or less than 20 μm, significantly reducing the difference in inclination with respect to the Y-axis compared to Table 1. Furthermore, the deviations of the edges of the mask cell region CR from the design values are within a range of approximately 20 μm or less, with at least one specific edge having a deviation of 10 μm or less. This indicates that uniform tension is applied to the mask cell region CR in all directions or radial directions.
[0236] Figure 26 FIG. 1 is a schematic diagram showing an overlapped comparison of alignment states of mask unit regions in a comparative example and an embodiment of the present invention.
[0237] Figure 22 and Figure 24 The data is presented overlappingly in Figure 26 The mask cell region CR of the comparative example is indicated by a dotted line, and the mask cell region CR of the embodiment of the present invention is indicated by a solid line.
[0238] It can be confirmed that the edge alignment of the mask unit region of the embodiment of the present invention (solid line) is uniform, without any tilt along a specific corner direction, and the deviation occurs substantially randomly.
[0239] In contrast, the ends of the first grid sheet portion 223 and the second grid sheet portion 225 of the mask cell regions CR in the comparative example (dashed line) are directly stretched, and thus tilting in specific corner directions can be confirmed. The upper right corner of the mask cell regions CR in the upper row of the comparative example (dashed line) exhibits a more pronounced tilting tendency S1, while the lower right corner of the mask cell regions CR in the lower row exhibits a more pronounced tilting tendency S4. Furthermore, the lower left corner of the mask cell regions CR in the upper row of the comparative example (dashed line) exhibits a more pronounced tilting tendency S2, while the upper left corner of the mask cell regions CR in the lower row exhibits a more pronounced tilting tendency S3. Because the upper and lower rows of mask cell regions CR share the first grid sheet portion 223, the tensile force acting on the ends of the first grid sheet portion 223 allows them to exhibit the same tilting tendencies S2 and S3.
[0240] As described above, the present invention does not directly stretch the unit sheet 220 using a clamping device. Instead, it applies an internal tensile force through temperature control during the bonding process of the unit sheet 220 (or metal sheet 220') to the movable plate 90. Consequently, the unit sheet 220 (or metal sheet 220') exerts a uniform tensile force in all directions or radial directions across the large area of the movable plate 90. This allows for accurate alignment of the mask cell region CR when the unit sheet 220 is attached to the edge frame 210.
[0241] As described above, the present invention has been illustrated and described with reference to preferred embodiments. However, the present invention is not limited to the above-described embodiments. Various modifications and variations can be made by those skilled in the art without departing from the spirit of the present invention. Such modifications and variations should be deemed to fall within the scope of the present invention and the appended claims.
Claims
1. A method for manufacturing a frame used in a connection between a mask for forming an OLED pixel and a frame, the method comprising the following steps: (a) bonding a first side of a metal sheet to a movable plate; (b) forming a plurality of mask unit regions on a second surface, which is opposite to the first surface, of the metal sheet to produce a unit sheet portion; (c) connecting the unit sheet portion to an edge frame portion, the edge frame portion including a hollow area, In the step (a), a tensile force is applied toward the side surface of the unit sheet portion.
2. The frame manufacturing method according to claim 1, wherein: In the step (a), the movable plate and the metal sheet are bonded together by interposing a dry film resist layer.
3. The frame manufacturing method according to claim 2, wherein: The step of applying a tensile force toward the side direction of the unit sheet portion includes the following steps: (1) bonding the movable plate and the metal sheet at a temperature at least lower than room temperature; (2) Raise the temperature to room temperature.
4. The frame manufacturing method according to claim 1, wherein: The step of applying a tensile force toward the side direction of the unit sheet portion includes the following steps: (1) contacting the movable plate and the metal sheet at a temperature at least higher than room temperature; (2) The movable plate and the metal sheet are bonded together while the temperature is decreasing toward room temperature.
5. The frame manufacturing method according to claim 4, wherein: The step (1) comprises sandwiching a temporary bonding portion between the movable plate and the metal sheet, raising the process temperature until the bonding strength of the temporary bonding portion is at least 0 to 5 kgf / cm 2 the temperature, and contacting the metal sheet to the moving plate, The step (2) includes lowering the process temperature to a level where the bonding strength of the temporary bonding portion is at least greater than 5 kgf / cm 2 and bonding the metal sheet to the moving plate.
6. The frame manufacturing method according to claim 1, wherein: The movable plate is made of borosilicate glass, and the width×length of the movable plate is at least greater than 1500 mm×900 mm.
7. The frame manufacturing method according to claim 1, wherein: In the step (b), the unit sheet portion includes: an edge sheet portion; a plurality of first grid sheet portions, which are formed extending along a first direction and connected to the edge sheet portion at both ends; and a plurality of second grid sheet portions, which are formed extending along a second direction perpendicular to the first direction and intersecting with the first grid sheet portion and connected to the edge sheet portion at both ends. In the step (c), at least a portion of the edge sheet portion is connected to the edge frame portion.
8. The frame manufacturing method according to claim 1, wherein: The step of applying a tensile force toward the side direction of the unit sheet portion includes the following steps: (1) A suction cup provides heat to the movable plate and the metal sheet, and the suction cup is used to absorb one side of the movable plate and move the movable plate; (2) The movable plate and the metal sheet are bonded together while the suction cup interrupts or reduces the heat supply.
9. The frame manufacturing method according to claim 2, 3 or 7, wherein: The metal sheet is bonded to the movable plate in a state where the metal sheet is elongated compared to its original length.
10. The frame manufacturing method according to claim 2, 3 or 7, wherein: The unit sheet portion has a quadrilateral planar shape, and a tensile force is applied to all sides along a radial direction.
11. The frame manufacturing method according to claim 1, wherein: Compared with the sides of the design value, the alignment error of each side of the mask unit area is equal to or less than 20 μm.
12. The frame manufacturing method according to claim 2, 3 or 7, wherein: Compared with the comparative example in which the edge of the unit sheet portion is stretched in the lateral direction and connected to the edge frame portion in a state of clamping the edge of the unit sheet portion, as the (1) step and the (2) step are performed, when the unit sheet portion to which a tensile force is applied in the lateral direction on the movable plate is connected to the edge frame portion, the edge position value of the mask unit area deviates less than the design value of the mask unit area.
13. The frame manufacturing method according to claim 12, wherein: In the comparative example, adjacent mask unit regions are tilted toward a specific corner direction.
14. The frame manufacturing method according to claim 12, wherein: In the comparative example, a first tensile force is applied in a direction parallel to a specific edge of the mask unit region, and a second tensile force is applied in a direction perpendicular to the first tensile force.
15. The frame manufacturing method according to claim 1, wherein: The movable plate includes at least one material selected from the group consisting of silicon dioxide, quartz, aluminum oxide (Al2O3), borosilicate glass, zirconium oxide, silicate ceramics, titanium (Ti), molybdenum (Mo), silver (Ag), copper (Cu), platinum (Pt), gold (Au), polyimide, and polymer, or a material obtained by coating at least one of titanium (Ti), molybdenum (Mo), silver (Ag), copper (Cu), platinum (Pt), gold (Au), polyimide, and polymer on the surface of any one of Invar alloy, super Invar alloy, and stainless steel (SUS).
16. A frame used in a connection body between a mask for forming an OLED pixel and a frame, the frame comprising: an edge frame portion including a hollow region; a unit sheet portion connected to the edge frame portion and having a plurality of mask unit regions formed therein, Compared with the sides of the design value, the alignment error of each side of the mask unit area is equal to or less than 20 μm.
17. The frame of claim 16, wherein: The mask unit region is a quadrilateral, and an alignment error of any side of the mask unit region compared to any side of a design value is equal to or less than 10 μm.