Environment-friendly ink diluent composition and preparation method thereof

By using tuna oil and ethanol fractions secreted by stink bugs to replace harmful substances in traditional diluents, an environmentally friendly ink diluent is prepared, which solves the problem of replacing harmful substances in ink compositions and achieves improvements in environmental friendliness and quick-drying properties.

CN120699474APending Publication Date: 2025-09-26张稷守
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Patent Information

Application Number
CN202410435270.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2024-03-25
Filing Date
2024-04-11
Publication Date
2025-09-26

AI Technical Summary

Technical Problem

There is a lack of substitutes for harmful substances such as acetone and toluene commonly used in existing ink diluents, resulting in insufficient environmental friendliness of the ink composition. In addition, a large amount of ethanol is used, which affects coloring and quick-drying properties.

Method used

Natural products tuna oil and ethanol fractions secreted by bedbugs are used to replace acetone and toluene, and an environmentally friendly ink diluent composition is prepared through low-temperature drying, supercritical extraction, purification and mixing, thereby reducing the use of ethanol.

Benefits of technology

The invention provides an environmentally friendly ink diluent, which replaces harmful substances, improves the environmental friendliness and quick-drying properties of the ink, and improves the solubility and adhesion of the ink.

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Abstract

The invention relates to an environment-friendly ink diluent composition and a preparation method thereof, in particular to an environment-friendly ink diluent composition and a preparation method thereof, which utilize natural products of tuna oil and bug secreted ethanol fraction to replace harmful substances of acetone and toluene in the traditional diluent, and reduce the use of ethanol at the same time. The coloring and quick-drying properties of the ink are improved.
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Description

Technical Field

[0001] The present invention relates to an environmentally friendly ink diluent composition and a preparation method thereof, in particular to an environmentally friendly ink diluent composition and a preparation method thereof, which utilizes natural products such as tuna oil and ethanol fraction secreted by bedbugs to replace harmful substances such as acetone and toluene in traditional diluents, while reducing the use of ethanol and improving the coloring and quick-drying properties of ink. Background Art

[0002] Ink refers to various liquid or solid substances used for writing, painting and printing, including pigments and pigments, and is used in various fields where fonts or paintings are used.

[0003] Generally speaking, there are printing inks for multiple publications, inks for recording or writing in one's own handwriting, and inks for drawing.

[0004] However, these inks have the characteristic that dyes easily clump, and commercially available inks tend to add additives such as diluents to prevent dye aggregation, control ink viscosity, and produce effects such as quick drying and improved texture.

[0005] However, since commercially available diluents mainly use harmful components such as acetone or toluene, research has recently been conducted to develop ink diluents that replace these harmful substances or ink compositions containing them.

[0006] In this regard, Korean Patent Publication No. 10-2011-0115635 discloses a method for manufacturing ink that has the functions of absorbing and deodorizing electromagnetic waves, emitting anionic components, and eliminating harmful substances.

[0007] However, there is currently a lack of research on diluent compositions that can be used in ink compositions, and further research is needed.

[0008] Prior art literature

[0009] Patent Literature

[0010] (Patent Document 1) Korean Patent Gazette No. 10-2011-0115635 Summary of the Invention

[0011] Problems to be solved by the invention

[0012] In order to solve the above problems, the present invention provides an environmentally friendly ink diluent composition and a preparation method thereof, which utilizes natural products tuna oil and ethanol fraction secreted by bedbugs to replace harmful substances such as acetone and toluene in traditional diluents, while reducing the use of ethanol.

[0013] Means used to solve problems

[0014] The above purpose is to dry the tuna at low temperature and extract the oil by supercritical method in the tuna oil extraction step; fractionate the bed bug secretion with ethanol to obtain the bed bug secretion ethanol fraction; prepare a primary mixture by mixing tuna oil, the bed bug secretion ethanol fraction, shellac, fig fiber and dimethyl sulfoxide (DMSO) in the primary mixing stage; and prepare a secondary mixture by mixing the primary mixture, cypress oil and ethanol in the secondary mixing stage. This can be achieved by the method for manufacturing an environmentally friendly ink diluent composition.

[0015] Specifically, the tuna oil extraction step may further include a purification step to obtain only the supernatant after centrifugation at a temperature of 2 to 5° C. for 10 to 30 minutes after the oil extraction.

[0016] Specifically, the secondary mixing step may further include generating ultrasonic waves for 20 to 60 minutes and stirring for secondary mixing.

[0017] Specifically, the primary mixing step may be performed at a pressure of 1800 to 2200 mmHg and a temperature of 140 to 160°C.

[0018] Furthermore, the object can be achieved by an environmentally friendly ink diluent composition prepared by a manufacturing method.

[0019] Effects of the Invention

[0020] The environmentally friendly ink diluent composition of the present invention uses the natural product Quame Nuari oil and the ethanol fraction secreted by bedbugs to replace the harmful substances acetone and toluene in existing diluents, while reducing the use of ethanol, so it can be used as an environmentally friendly ink diluent. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] Figure 1 is a flow chart illustrating a method for preparing an environmentally friendly ink thinner composition according to a single embodiment. DETAILED DESCRIPTION

[0022] Hereinafter, the embodiments are described in detail with reference to the accompanying drawings. However, various modifications may be made to the embodiments, and thus the scope of the patent application is not limited or restricted by these embodiments. Any modification, equalization, or replacement of the embodiments should be understood to be included within the scope of the rights.

[0023] The specific structure or function description of the embodiment is only for illustrative purposes and can be changed and implemented in various forms. Therefore, the embodiment is not limited to the specific form disclosed, and the scope of this specification includes changes, unifications or replacements included in the descriptive concepts.

[0024] Terms such as first or second may be used to describe various components, but these terms should be interpreted only to distinguish one component from another. For example, the first component can be named the second component, and similarly, the second component can be named the first component.

[0025] When a component is referred to as being “connected” to another component, it will be understood that it may be directly connected to or coupled to the other component, but another component may be intervening.

[0026] The terms used in the examples are for illustrative purposes only and should not be construed as limiting. Singular expressions include plural expressions unless the context clearly indicates otherwise. In this specification, the terms "including" or "having" should be understood to specify the presence of the features, numbers, steps, actions, components, parts, or combinations thereof described herein, and do not preclude the presence or addition of one or more other features or numbers, steps, actions, components, parts, or combinations thereof.

[0027] Unless otherwise defined, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which the embodiments belong. Terms defined in commonly used dictionaries should be interpreted as having a meaning consistent with their meaning in the relevant description and should not be interpreted in an idealistic or overly formal sense unless expressly defined in this application.

[0028] The advantages and features of the present invention and the methods for achieving the advantages and features will be explained with reference to the embodiments described in detail below and the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but can be embodied in various forms, and the embodiments are provided only to ensure that the disclosure of the present invention is complete and to provide a person with ordinary knowledge in the technical field to which the invention belongs with a full understanding of the scope of the invention. The present invention is defined only by the categories of the claims.

[0029] In the embodiments of the present invention, all terms used herein, including technical or scientific terms, unless otherwise defined, have the same meaning as commonly understood by a person with ordinary knowledge in the technical field to which the present invention belongs. Terms such as those defined in commonly used dictionaries should be interpreted as having a meaning consistent with their meaning in the relevant description and should not be interpreted in an ideal or overly formal sense unless explicitly defined in the embodiments of the present invention.

[0030] The shapes, sizes, proportions, angles, and quantities disclosed in the figures for illustrating the embodiments of the present invention are illustrative and are not limited to those shown. In addition, when describing the present invention, if it is judged that a detailed description of the known technology involved may unnecessarily obscure the main points of the present invention, the detailed description should be omitted. If the words "including", "having", and "manufactured" mentioned in this specification are used, other parts may be added unless "~only" is used. This includes the case where the component is represented in the singular and includes the plural, unless otherwise explicitly stated.

[0031] When interpreting a component, it will be interpreted as including a margin of error even if not explicitly stated.

[0032] For the sake of convenience of explanation, the size and thickness of each configuration shown in the drawings are shown, and the present invention is not necessarily limited to the size and thickness of the shown structures.

[0033] The features of each of the various embodiments of the present invention may be combined with each other in part or in whole, and as can be fully understood by those skilled in the art, they may be technically interlocked and driven, and each embodiment may be performed independently of each other or together in an associated relationship.

[0034] One aspect of our clinic is the extraction stage of tuna oil, which is to extract the oil in a supercritical manner by drying tuna at low temperature; the fractionation of bedbug secretions with ethanol to obtain a bedbug secretion ethanol fraction; the primary mixing stage, which is to prepare a primary mixture by mixing tuna oil, bedbug secretion ethanol fraction, shellac, fig fiber and dimethyl sulfoxide (DMSO); and the secondary mixing stage, which is to mix the primary mixture, cypress oil and ethanol to prepare a secondary mixture; it provides a method for preparing an environmentally friendly ink diluent composition.

[0035] Next, you can use Figure 1 The preparation method of the environmentally friendly ink diluent composition according to one embodiment of the present invention is described below.

[0036] First, the oil is supercritically extracted by drying the tuna at low temperatures.

[0037] Grateloupia filicina is a species of seaweed in the genus Rhodophyta that grows in rock pools in intertidal zones. It is commonly eaten as a seasoning or pickled food. The tuna oil in the present invention can be used as a substitute for acetone and toluene in ink thinner compositions. Specifically, tuna oil in the present invention can be mixed with an ethanol fraction secreted by stink bugs to provide an acetone and toluene replacement.

[0038] If an extraction method other than supercritical is used, the composition of the oil may vary, which may reduce the effectiveness of the diluent produced by that method.

[0039] In one embodiment, the tuna oil extraction process may further include a purification step to obtain a supernatant after centrifugation at a temperature of 2 to 5° C. for 10 to 30 minutes.

[0040] The purification process of the present invention is to remove impurities by centrifuging tuna oil at low temperature to precipitate impurities and obtain only supernatant, so as to make the mixture with the ethanol fraction secreted by the stinking ash smooth, thereby improving the ink solubility of the ink diluent prepared thereby.

[0041] Next, the bed bug secretions are fractionated with ethanol to obtain a bed bug secretion ethanol fraction.

[0042] The above-mentioned bed bug secretions are secretions secreted by bed bugs (Pentatomidae) of the family Cimex. Bed bug secretions are characterized by a foul odor and are used by bed bugs to protect their bodies from predators.

[0043] The bed bug secretion ethanol fraction of the present invention can be used as a substitute for acetone and toluene by fractionating the stink bug secretion into ethanol to remove unnecessary components and purify the components, which is then mixed with tuna oil.

[0044] Next, a primary mixture was prepared by mixing tuna oil, stink bug secretion ethanol fraction, shellac, fig fiber, and dimethyl sulfoxide (DMSO).

[0045] Shellac is a solvent made by extracting the secretions of the Laccifer lacca. When scale insects colonize tree trunks in the forest to reproduce, they suck the sap, secreting resin that accumulates thickly like bark. When scraped off with a knife, it peels off like cork bark. The shellac is ground, sieved to remove foreign matter, cleaned, refined, dried, heated, melted, and placed through a strainer. Squeezed out like a rag, the dark brown shellac, melted by the heat, flows out like glue. After refining, it is cooled, drawn, and stretched into a thin layer, like a sheet of paper. It is then hung outside to dry like clothing before being cut into small pieces for sale.

[0046] Shellac of the present invention may be included in the thinner composition to improve thinner application and adhesion.

[0047] Fig fiber refers to fiber extracted from figs, the fruit of the fig tree (Ficus carica), a deciduous shrub in the dicotyledonous Urticaceae family.

[0048] Fig fiber of the present invention may be included in thinner compositions to provide the thinner fibers with quick drying properties and improved adhesion.

[0049] Dimethyl sulfoxide (DMSO) is a colorless, odorless, hygroscopic liquid that is a powerful solvent that can dissolve many aromatic and unsaturated hydrocarbons, organic compounds, and many other substances because it is a highly polar organic liquid.

[0050] Specifically, the content of each material used to prepare the primary mixture can be 15-20% by weight of tuna oil, 8-10% by weight of bedbug secretion ethanol fraction, 15-20% by weight of shellac, 2-5% by weight of fig fiber and 45-60% by weight of DMSO.

[0051] In one embodiment, the primary mixing step may be performed at a pressure of 1800 to 2200 mmHg and a temperature of 140 to 160° C. If the pressure exceeds the above conditions, the ink solvent, application, and adhesion of the diluent composition prepared thereby may be reduced. If the temperature exceeds the above conditions, the primary mixture may not be mixed smoothly.

[0052] Finally, asphalt and ethanol are mixed into a primary mixture to prepare a secondary mixture, thereby completing the environmentally friendly ink diluent composition.

[0053] Cypress oil refers to oil extracted from the cypress tree (Chamaecyparis obtusa), an evergreen shrub belonging to the genus Cupressus. Cypress oil contains a large amount of natural antibacterial substances called phytoncides, which have excellent antibacterial effects. Due to its strong, unique aroma, it is also used as an ingredient in air fresheners.

[0054] Specifically, the content of each material used to prepare the secondary mixture may be 70-80% by weight of the primary mixture, 10-15% by weight of asphalt, and 10-15% by weight of ethanol.

[0055] In one embodiment, the secondary mixing step may further include a stirring step by generating ultrasonic waves for 20 to 60 minutes during the secondary mixing.

[0056] In the present invention, the process of stirring by generating ultrasonic waves can improve the stability of the ink diluent composition, thereby stabilizing the molecular structure of the secondary mixture and making the mixing smoother.

[0057] Another aspect of the clinic is to provide an environmentally friendly ink diluent composition prepared by the above manufacturing method.

[0058] Below, we will explain the composition of the present invention and its effect in more detail through specific embodiment and comparative example.However, this embodiment is intended to describe the present invention in more detail, and the scope of the present invention is not limited to these embodiments.

[0059] [Example 1]

[0060] First, the tuna is dried at low temperature and then the oil is extracted using supercritical fluid to obtain tuna nuari oil.

[0061] Next, bed bug secretions were collected from the bed bug glands and then used with ethanol powder to prepare a bed bug secretion ethanol fraction.

[0062] Then, 18 wt% of tuna oil, 8 wt% of bed bug secretion ethanol fraction, 16% of shellac, 5% of fig fiber and 53% of DMSO were mixed at a pressure of 2000 mmHg and a temperature of 155°C to prepare a primary mixture.

[0063] Finally, 75 wt% of the primary mixture, 15 wt% of asphalt, and 10 wt% of ethanol were mixed to prepare a secondary mixture, thereby completing the environmentally friendly ink thinner composition. The completed environmentally friendly ink thinner composition was named Example 1.

[0064] [Example 2]

[0065] The preparation method of Example 1 was the same, but after the tuna oil was extracted during the tuna oil extraction process, the tuna oil was centrifuged at 4° C. for 20 minutes, and then a purification step was additionally included to obtain only the supernatant. The true ink diluent composition was named Example 2.

[0066] [Example 3]

[0067] The preparation method of Example 1 is the same, but in the secondary mixing process, an environmentally friendly ink diluent composition is prepared by further comprising the steps of generating ultrasonic waves for 20 to 60 minutes and stirring for secondary mixing, and is named Example 3.

Claims

1. The stage of supercritical oil extraction by drying at low temperature; fractionating the bed bug secretions with ethanol to obtain a bed bug secretion ethanol fraction; a primary mixing stage, preparing a primary mixture by mixing tuna oil, bed bug secretion ethanol fraction, shellac, fig fiber, and dimethyl sulfoxide (DMSO); and The secondary mixing step comprises mixing the primary mixture, cypress oil and ethanol to prepare a secondary mixture; and a method for preparing an environmentally friendly ink diluent composition.

Citation Information

Patent Citations

  • Diluent for epoxy varnish for low temperature curing, and manufacturing method for the same

    KR1020110115635A