A wear-resistant anticorrosive coating and a preparation method thereof

Abstract

The application discloses a wear-resistant and corrosion-resistant paint and a preparation method thereof, and relates to the technical field of paints. The paint is prepared from the following raw materials in parts by weight: 25-35 parts of bisphenol A type epoxy vinyl resin, 5-8 parts of vinyl fluorosilicone oil, 10-15 parts of polyether sulfone type hyperbranched epoxy resin, 8-12 parts of corrosion-resistant filler, 15-25 parts of wear-resistant filler, 3-5 parts of coupling agent, 0.2-0.5 parts of initiator, 10-15 parts of curing agent, 3-5 parts of additive, and 20-30 parts of solvent; the curing agent is a compound of 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 1-3:1. The paint has good corrosion resistance, excellent wear resistance, good environmental adaptability and strong adhesion.

Description

TECHNICAL FIELD

[0001] The present application relates to the field of coating technology, in particular to a wear-resistant and corrosion-resistant coating and a preparation method thereof. BACKGROUND

[0002] With the rapid development of industry, the corrosion and wear of metal materials in various harsh environments are increasingly prominent, which directly affects the performance and service life of equipment. In the fields of chemical industry, petroleum, metallurgy, marine engineering, etc., the equipment is exposed to acid and alkali medium, high temperature and mechanical friction environment for a long time. The traditional coating is difficult to meet the requirements of wear resistance, corrosion resistance and structural stability at the same time, especially in facilities frequently contacting corrosive medium, the early failure of the coating will cause significant economic loss and safety hazards.

[0003] The traditional wear-resistant and corrosion-resistant coating has many defects when facing complex working conditions, such as physical property decline at high temperature, easy blistering and peeling in high humidity environment, insufficient protection performance under strong acid and alkali corrosion, and gradual reduction of protection performance after long-term use. The wear-resistant and corrosion-resistant coatings on the market are difficult to balance wear resistance and corrosion resistance, and more or less have technical defects such as insufficient wear resistance, poor corrosion resistance, and further improved adhesion and environmental adaptability.

[0004] For example, the patent for invention with the authorization announcement number CN104212298B discloses a kind of anticorrosive wear-resistant coating, which is composed of epoxy resin, petroleum resin, pigment, graphite powder, solvent, multifunctional additive, thickening agent, composite rare earth and flame retardant, and its weight percentage composition is as follows: epoxy resin 11-13%, petroleum resin 20-23%, pigment 6-8%, graphite powder 3-5%, solvent 17-20%, multifunctional additive 7-9%, flame retardant 8-10%, composite rare earth 0.5-0.8%, and the rest is thickening agent; the preparation method of the anticorrosive wear-resistant coating is also disclosed; the anticorrosive wear-resistant coating is claimed to have good corrosion resistance and friction resistance, and has a long service life, and the coating will not have problems such as blistering, cracking, whitening and delamination. However, its wear resistance and environmental adaptability still need to be further improved.

[0005] Therefore, it is particularly important to develop a wear-resistant and corrosion-resistant coating with good corrosion resistance, excellent wear resistance, good environmental adaptability and strong adhesion, and a preparation method thereof. SUMMARY

[0006] The present application aims to overcome the deficiencies in the prior art and provide a wear-resistant and corrosion-resistant coating with good corrosion resistance, excellent wear resistance, good environmental adaptability and strong adhesion, and a preparation method thereof.

[0007] To achieve the above object, the technical scheme adopted by the present application is: a wear-resistant and corrosion-resistant coating is made of the following raw materials in parts by weight: bisphenol A type epoxy vinyl resin 25-35 parts, vinyl fluorosilicone oil 5-8 parts, polyether sulfone type hyperbranched epoxy resin 10-15 parts, corrosion-resistant filler 8-12 parts, wear-resistant filler 15-25 parts, coupling agent 3-5 parts, initiator 0.2-0.5 parts, curing agent 10-15 parts, auxiliary agent 3-5 parts, and solvent 20-30 parts.

[0008] Preferably, the bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin.

[0009] Preferably, the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019 provided by Fuzhou Taipuda New Material Co., Ltd.

[0010] Preferably, the polyether sulfone type hyperbranched epoxy resin has no special requirements for its source, and in an embodiment of the present application, the polyether sulfone type hyperbranched epoxy resin is made according to the method in Case 18 of the Chinese Invention Patent with the authorized announcement number CN104311832B.

[0011] Preferably, the corrosion-resistant filler is compounded from glass flake and mica iron oxide at a mass ratio of (1-3):1.

[0012] Preferably, the glass flake has a particle size of 200-800 mesh.

[0013] Preferably, the mica iron oxide has an average particle size of 5-8 μm.

[0014] Preferably, the wear-resistant filler is at least one of silicon carbide powder, corundum powder, and diamond powder.

[0015] Preferably, the wear-resistant filler has a particle size of 1200-1500 mesh.

[0016] Preferably, the coupling agent is at least one of silane coupling agent KH550, silane coupling agent KH560, and silane coupling agent KH570.

[0017] Preferably, the initiator is dicumyl peroxide.

[0018] Preferably, the curing agent is compounded from 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of (1-3):1.

[0019] Preferably, the auxiliary agent is compounded from dispersant, defoaming agent, and leveling agent at a mass ratio of (1-2):(0.8-1.2):1.

[0020] Preferably, the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom 6800; and the leveling agent is non-silicon leveling agent Tech-1068.

[0021] Preferably, the solvent is a mixed solution of xylene and n-butanol in a mass ratio of 4-6:1.

[0022] Another object of the present application is to provide a preparation method of the wear-resistant and corrosion-resistant coating, comprising the following steps: uniformly mixing the raw materials according to the weight parts to obtain the wear-resistant and corrosion-resistant coating.

[0023] Due to the use of the above technical scheme, the present application has the following beneficial effects:

[0024] (1) The wear-resistant and corrosion-resistant coating disclosed by the present application is made of the following raw materials in parts by weight: bisphenol A type epoxy vinyl resin 25-35 parts, vinyl fluorosilicone oil 5-8 parts, polyether sulfone type hyperbranched epoxy resin 10-15 parts, corrosion-resistant filler 8-12 parts, wear-resistant filler 15-25 parts, coupling agent 3-5 parts, initiator 0.2-0.5 parts, curing agent 10-15 parts, auxiliary agent 3-5 parts, and solvent 20-30 parts. Through the mutual cooperation of the raw materials, the prepared coating has good corrosion resistance, excellent wear resistance, good environmental adaptability, and strong adhesion.

[0025] (2) The wear-resistant and corrosion-resistant coating disclosed by the present application is prepared by synergistically compounding bisphenol A type epoxy vinyl resin, vinyl fluorosilicone oil, and polyether sulfone type hyperbranched epoxy resin, thereby constructing a multi-element cross-linked resin matrix network. The bisphenol A type epoxy vinyl resin lays the foundation for the bonding and mechanical properties, the introduction of the vinyl fluorosilicone oil significantly improves the chemical inertness and weather resistance of the coating, and the branched structure of the polyether sulfone type hyperbranched epoxy resin not only enhances the interfacial bonding force between the matrix and the filler, but also optimizes the cross-linking density and stress dispersion capacity of the coating. The synergistic effect of the three makes the coating not only maintain excellent adhesion, but also break through the technical bottleneck that traditional coatings are difficult to balance wear resistance and corrosion resistance, thereby realizing the simultaneous leap of the two core performances.

[0026] (3) The wear-resistant and corrosion-resistant coating disclosed by the application adopts the corrosion-resistant filler system of glass flake and mica iron oxide compounded according to a specific proportion, wherein the 200-800 mesh glass flake can form a layer-upon-layer 'labyrinth effect' inside the coating, effectively prolonging the penetration path of the corrosion medium, the flaky structure of 5-8 μm mica iron oxide is complementary to the glass flake, further densifying the coating structure; in combination with 1200-1500 mesh high-particle-size silicon carbide powder, corundum powder and other wear-resistant fillers, the high-hardness particles are uniformly dispersed in the resin matrix to form 'rigid support points', which can directly bear the load and reduce the matrix wear when subjected to friction, and the synergistic design of the corrosion-resistant and wear-resistant fillers enables the coating to maintain long-term stable protection performance in harsh environments such as acid and alkali medium immersion, high temperature and humidity, solving the problems of easy blistering and peeling of the traditional coating and rapid attenuation of the protection performance.

[0027] (4) The wear-resistant and corrosion-resistant coating disclosed by the application adopts the curing agent compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane, the amino and unsaturated alkene in the molecular structure of the curing agent are efficiently reacted with the active groups of the resin matrix, at the same time, the introduction of fluorine elements, phenyl ether and triazine structure further improves the corrosion resistance of the coating, and the synergistic effect of the silane coupling agent can significantly improve the interfacial compatibility of the filler and the resin matrix, avoiding the performance shortcoming caused by the aggregation of the filler; the scientific compounding of the additive system ensures the construction fluidity and film-forming density of the coating, so that the coating can form a uniform and smooth film on the surface of different substrates, further improving the environmental adaptability of the coating.

[0028] (5) The wear-resistant and corrosion-resistant coating disclosed by the application can realize uniform dispersion of each raw material component under simple mixing process, without the need for complex preparation equipment and harsh process conditions, thereby reducing the cost and difficulty of industrial production; through the overall optimization of the resin system, filler combination and curing system, the wear resistance and environmental adaptability of the coating under complex working conditions such as high temperature, strong acid and alkali and high-frequency friction are significantly improved, and the service life of the coating is greatly prolonged, which can effectively reduce the maintenance cost and safety hazard of equipment in the fields of chemical industry, ocean engineering and the like, and has significant technical advantages and application value. DETAILED DESCRIPTION

[0029] The following description is used to disclose the application so that those skilled in the art can implement the application. The preferred embodiments in the following description are only as examples, and other obvious variants can be conceived by those skilled in the art.

[0030] Embodiment 1: A wear-resistant anticorrosive coating is made of the following raw materials in parts by weight: bisphenol A type epoxy vinyl resin 25 parts, vinyl fluorosilicone oil 5 parts, polyether sulfone type hyperbranched epoxy resin 10 parts, anticorrosive filler 8 parts, wear-resistant filler 15 parts, coupling agent 3 parts, initiator 0.2 parts, curing agent 10 parts, auxiliary agent 3 parts, solvent 20 parts.

[0031] The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin; the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019, provided by Fuzhou Taipuda New Material Co., Ltd.; the polyether sulfone type hyperbranched epoxy resin is made according to the method in the implementation case 18 of the Chinese invention patent with the authorized announcement number CN104311832B; the anticorrosive filler is compounded by glass flake and mica iron oxide at a mass ratio of 1:1; the particle size of the glass flake is 800 mesh; the average particle size of the mica iron oxide is 5 μm; the wear-resistant filler is silicon carbide powder; the particle size of the wear-resistant filler is 1200 mesh; the coupling agent is silane coupling agent KH550; the initiator is dicumyl peroxide; the curing agent is compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 1:1; the auxiliary agent is compounded by dispersant, defoaming agent, and leveling agent at a mass ratio of 1:0.8:1; the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom 6800; the leveling agent is non-silicon leveling agent Tech-1068; the solvent is a mixed liquid compounded by dimethylbenzene and n-butanol at a mass ratio of 4:1.

[0032] A preparation method of the wear-resistant anticorrosive coating, comprising the following steps: uniformly mixing the raw materials in parts by weight to obtain the wear-resistant anticorrosive coating.

[0033] Embodiment 2: A wear-resistant anticorrosive coating is made of the following raw materials in parts by weight: bisphenol A type epoxy vinyl resin 27 parts, vinyl fluorosilicone oil 6 parts, polyether sulfone type hyperbranched epoxy resin 11 parts, anticorrosive filler 9 parts, wear-resistant filler 17 parts, coupling agent 3.5 parts, initiator 0.3 parts, curing agent 12 parts, auxiliary agent 3.5 parts, solvent 23 parts.

[0034] The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin; the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019, provided by Fuzhou Taipuda New Material Co., Ltd.; the polyether sulfone type hyperbranched epoxy resin is made according to the method in the implementation case 18 of the Chinese patent for invention with the authorized announcement number CN104311832B; the anticorrosive filler is compounded by glass flake and mica iron oxide at a mass ratio of 1.5:1; the particle size of the glass flake is 800 mesh; the average particle size of the mica iron oxide is 6 μm; the wear-resistant filler is corundum powder; the particle size of the wear-resistant filler is 1300 mesh; the coupling agent is silane coupling agent KH560; the initiator is dicumyl peroxide; the curing agent is compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 1.5:1; the auxiliary agent is compounded by dispersant, defoaming agent, and leveling agent at a mass ratio of 1.3:0.9:1; the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom 6800; the leveling agent is non-silicon leveling agent Tech-1068; the solvent is a mixed liquid compounded by dimethylbenzene and n-butanol at a mass ratio of 4.5:1.

[0035] A preparation method of the wear-resistant and corrosion-resistant coating, comprising the following steps: uniformly mixing each raw material according to weight parts to obtain the wear-resistant and corrosion-resistant coating.

[0036] Example 3: A wear-resistant and corrosion-resistant coating is made of each raw material in the following weight parts: bisphenol A type epoxy vinyl resin 30 parts, vinyl fluorosilicone oil 6.5 parts, polyether sulfone type hyperbranched epoxy resin 13 parts, anticorrosive filler 10 parts, wear-resistant filler 20 parts, coupling agent 4 parts, initiator 0.35 parts, curing agent 13 parts, auxiliary agent 4 parts, and solvent 25 parts.

[0037] The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin; the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019, provided by Fuzhou Taipuda New Material Co., Ltd.; the polyether sulfone type hyperbranched epoxy resin is made according to the method in the implementation case 18 of the Chinese patent for invention with the authorized announcement number CN104311832B; the anticorrosive filler is compounded by glass flake and mica iron oxide at a mass ratio of 2:1; the particle size of the glass flake is 800 mesh; the average particle size of the mica iron oxide is 6.5 μm; the wear-resistant filler is corundum powder; the particle size of the wear-resistant filler is 1350 mesh; the coupling agent is silane coupling agent KH570; the initiator is dicumyl peroxide; the curing agent is compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 2:1; the auxiliary agent is compounded by dispersant, defoaming agent and leveling agent at a mass ratio of 1.5:1:1; the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom 6800; the leveling agent is non-silicon leveling agent Tech-1068; the solvent is a mixed liquid compounded by dimethylbenzene and n-butanol at a mass ratio of 5:1.

[0038] A preparation method of the wear-resistant anticorrosive coating, comprising the following steps: uniformly mixing each raw material according to weight parts to obtain the wear-resistant anticorrosive coating.

[0039] Example 4: A wear-resistant anticorrosive coating is made of each raw material in the following weight parts: bisphenol A type epoxy vinyl resin 33 parts, vinyl fluorosilicone oil 7.5 parts, polyether sulfone type hyperbranched epoxy resin 14 parts, anticorrosive filler 11 parts, wear-resistant filler 23 parts, coupling agent 4.5 parts, initiator 0.45 parts, curing agent 14 parts, auxiliary agent 4.5 parts, and solvent 28 parts.

[0040] The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin; the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019, provided by Fuzhou Taipuda New Material Co., Ltd.; the polyether sulfone type hyperbranched epoxy resin is prepared according to the method in the implementation case 18 of the Chinese patent for invention with the authorized announcement number CN104311832B; the anticorrosive filler is compounded by glass flake and mica iron oxide at a mass ratio of 2.5:1; the particle size of the glass flake is 800 mesh; the average particle size of the mica iron oxide is 7.5 μm; the wear-resistant filler is compounded by silicon carbide powder, corundum powder and diamond powder at a mass ratio of 1:2:3; the particle size of the wear-resistant filler is 1450 mesh; the coupling agent is compounded by silane coupling agent KH550, silane coupling agent KH560 and silane coupling agent KH570 at a mass ratio of 1:1:2; the initiator is dicumyl peroxide; the curing agent is compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 2.5:1; the auxiliary agent is compounded by dispersant, defoaming agent and leveling agent at a mass ratio of 1.8:1.1:1; the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom6800; the leveling agent is non-silicon leveling agent Tech-1068; the solvent is a mixed liquid compounded by dimethylbenzene and n-butanol at a mass ratio of 5.5:1.

[0041] A preparation method of the wear-resistant and corrosion-resistant coating, comprising the following steps: uniformly mixing the raw materials according to the weight parts to obtain the wear-resistant and corrosion-resistant coating.

[0042] Example 5: A wear-resistant and corrosion-resistant coating is prepared from the following raw materials according to the weight parts: bisphenol A type epoxy vinyl resin 35 parts, vinyl fluorosilicone oil 8 parts, polyether sulfone type hyperbranched epoxy resin 15 parts, anticorrosive filler 12 parts, wear-resistant filler 25 parts, coupling agent 5 parts, initiator 0.5 parts, curing agent 15 parts, auxiliary agent 5 parts, and solvent 30 parts.

[0043] The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin; the vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019, provided by Fuzhou Taipuda New Material Co., Ltd.; the polyether sulfone type hyperbranched epoxy resin is prepared according to the method in the implementation case 18 of the Chinese patent for invention with the authorized announcement number CN104311832B; the anticorrosive filler is compounded by glass flake and mica iron oxide at a mass ratio of 3:1; the particle size of the glass flake is 800 mesh; the average particle size of the mica iron oxide is 8 μm; the wear-resistant filler is silicon carbide powder; the particle size of the wear-resistant filler is 1500 mesh; the coupling agent is silane coupling agent KH550; the initiator is dicumyl peroxide; the curing agent is compounded by 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane at a mass ratio of 3:1; the auxiliary agent is compounded by dispersant, defoaming agent and leveling agent at a mass ratio of 2:1.2:1; the dispersant is super dispersant Tech-6320; the defoaming agent is defoaming agent Defom 6800; the leveling agent is non-silicon leveling agent Tech-1068; the solvent is a mixed liquid compounded by dimethylbenzene and n-butanol at a mass ratio of 6:1.

[0044] A preparation method of the wear-resistant and corrosion-resistant coating, comprising the following steps: uniformly mixing raw materials according to weight parts to obtain the wear-resistant and corrosion-resistant coating.

[0045] Comparative Example 1

[0046] This example provides a wear-resistant and corrosion-resistant coating and a preparation method thereof, which are basically the same as those in Example 5, except that an equal amount of bisphenol A type epoxy vinyl resin is used to replace the vinyl fluorosilicone oil.

[0047] Comparative Example 2

[0048] This example provides a wear-resistant and corrosion-resistant coating and a preparation method thereof, which are basically the same as those in Example 5, except that an equal amount of vinyl fluorosilicone oil is used to replace the bisphenol A type epoxy vinyl resin.

[0049] Comparative Example 3

[0050] This example provides a wear-resistant and corrosion-resistant coating and a preparation method thereof, which are basically the same as those in Example 5, except that an equal amount of bisphenol A type epoxy vinyl resin is used to replace the polyether sulfone type hyperbranched epoxy resin.

[0051] Comparative Example 4

[0052] This example provides a wear-resistant and corrosion-resistant coating and a preparation method thereof, which are basically the same as those in Example 5, except that an equal amount of polyether sulfone type hyperbranched epoxy resin is used to replace the bisphenol A type epoxy vinyl resin.

[0053] Comparative Example 5

[0054] This example provides a wear-resistant anticorrosive coating and a preparation method thereof, which is basically the same as that of Example 5, except that an equal amount of 2,4-diamino-6-diallylamino-1,3,5-triazine is used instead of 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane.

[0055] Comparative Example 6

[0056] This example provides a wear-resistant anticorrosive coating and a preparation method thereof, which is basically the same as that of Example 5, except that an equal amount of 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane is used instead of 2,4-diamino-6-diallylamino-1,3,5-triazine.

[0057] In order to further illustrate the beneficial technical effects of the wear-resistant anticorrosive coating involved in the embodiments of the present application, the wear-resistant anticorrosive coatings involved in Example 5 and Comparative Examples 1-6 are tested for relevant properties, and the test results are shown in Table 1, and the test methods are as follows: the coatings prepared in the above examples and comparative examples are coated on the surface of a sample plate (steel plate) to prepare a coating film with a thickness of 80 μm, which is cured at 100 ℃ for 30 min and then cured at 120 ℃ for 1 h to prepare a coating film, and the coating film is tested for properties,

[0058] (1) Adhesion test: tested and rated according to GB / T 9286-1998.

[0059] (2) Wear resistance: tested according to GB / T 1768-2006 “Determination of Abrasion Resistance of Paints and Varnishes - Rotating Cylinder Method”, with a load of 1000 g and a rotation speed of 60 r / min, and the abrasion amount after 1000 rotations is tested.

[0060] (3) Neutral salt spray test: tested according to GB / T 1771-2007 “Determination of Resistance to Neutral Salt Spray of Paints and Varnishes”, with a salt spray concentration of 5% and a temperature of 35 ℃, and the time of rusting or bubbling is recorded.

[0061] (4) Chemical medium resistance: tested according to GB / T 9274-1988 “Determination of Resistance to Liquid Media of Paints and Varnishes”, and the coating appearance is observed after 100 days of immersion in 50% sulfuric acid solution and 10% sodium hydroxide solution, respectively.

[0062] Table 1 Wear-resistant anticorrosive coating performance test results

[0063]

[0064] As shown in Table 1, the wear-resistant and corrosion-resistant coating prepared in the inventive example 5 exhibits significantly better adhesion, wear resistance and corrosion resistance than each of the comparative examples. The combination use of bisphenol A type epoxy vinyl resin, vinyl fluorosilicone oil, polyether sulfone type hyperbranched epoxy resin, 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane is beneficial to improving the above-mentioned properties.

[0065] The above examples are only for illustrating the technical concept and characteristics of the present application, and the purpose is to enable those skilled in the art to understand the content of the present application and to implement it, and cannot limit the protection scope of the present application. Any equivalent changes or modifications made according to the spirit and essence of the present application should be covered within the protection scope of the present application.

Claims

1. A wear resistant corrosion resistant coating characterized by, The anti-corrosion and wear-resistant paint is prepared from the following raw materials in parts by weight: 25-35 parts of bisphenol A type epoxy vinyl resin, 5-8 parts of vinyl fluorosilicone oil, 10-15 parts of polyether sulfone type hyperbranched epoxy resin, 8-12 parts of anti-corrosion filler, 15-25 parts of wear-resistant filler, 3-5 parts of coupling agent, 0.2-0.5 parts of initiator, 10-15 parts of curing agent, 3-5 parts of auxiliary agent, and 20-30 parts of solvent; the curing agent is a compound of 2,4-diamino-6-diallyl amino-1,3,5-triazine and 2,2-bis[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropane in a mass ratio of 1-3:1; and the anti-corrosion filler is a compound of glass flake and mica iron oxide in a mass ratio of 1-3:

1.

2. The abrasion-resistant anticorrosive coating according to claim 1, characterized in that, The bisphenol A type epoxy vinyl resin is ATLAC 430 bisphenol A type epoxy vinyl resin.

3. The abrasion-resistant corrosion-resistant coating of claim 1, wherein, The vinyl fluorosilicone oil is vinyl fluorosilicone oil TPD-FS8019.

4. The abrasion-resistant corrosion-resistant coating of claim 1, wherein, The glass flake has a particle size of 200-800 mesh, and the mica iron oxide has an average particle size of 5-8 μm.

5. The abrasion-resistant corrosion-resistant coating of claim 1, wherein, The wear-resistant filler is at least one of silicon carbide powder, corundum powder and diamond powder, and has a particle size of 1200-1500 mesh.

6. The abrasion-resistant corrosion-resistant coating of claim 1, wherein, The coupling agent is at least one of silane coupling agent KH550, silane coupling agent KH560 and silane coupling agent KH570, and the initiator is dicumyl peroxide.

7. The abrasion-resistant corrosion-resistant coating of claim 1, wherein, The auxiliary agent is a compound of dispersant, defoaming agent and leveling agent in a mass ratio of 1-2:0.8-1.2:1, the dispersant is super dispersant Tech-6320, the defoaming agent is defoaming agent Defom 6800, the leveling agent is non-silicon leveling agent Tech-1068, and the solvent is a mixture of dimethylbenzene and n-butanol in a mass ratio of 4-6:

1.

8. A method for the production of a wear-resistant corrosion-resistant coating according to any one of claims 1 to 7, characterized in that The method comprises the following steps: uniformly mixing the raw materials in parts by weight to obtain the anti-corrosion and wear-resistant paint. The method comprises the following steps: uniformly mixing the raw materials in parts by weight to obtain the anti-corrosion and wear-resistant paint.

Images