一种从丙烯腈电解产物精馏残液中萃取分离己二腈和己烷三腈的方法

By using a composite extractant consisting of benzene, ester, and alcohol solvents, the problem of separating adiponitrile and hexanetrionitrile in the distillation residue of acrylonitrile electrolysis products was solved, achieving efficient recovery, extending equipment operating cycle, and reducing separation costs.

CN121698781BActive Publication Date: 2026-07-17EAST CHINA UNIV OF SCI & TECH +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
EAST CHINA UNIV OF SCI & TECH
Filing Date
2025-12-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to efficiently separate and recover adiponitrile and hexanetrionitrile from the distillation residues of acrylonitrile electrolysis products, leading to resource waste and equipment blockage. Furthermore, there is a lack of a complete separation method suitable for industrial applications.

Method used

A composite extractant composed of benzene, ester, and alcohol solvents is used to selectively dissolve adiponitrile and hexanetrionitrile through composite extraction, cooling phase separation, and distillation steps. The extractant is then recovered by distillation, achieving efficient removal of polymers and separation of products.

Benefits of technology

It achieves high-purity recovery of adiponitrile and hexanetrionitrile, with a polymer removal rate of 98.59%, extends equipment operating cycle, reduces separation costs and energy consumption, and improves resource utilization and economic benefits.

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Abstract

本发明公开了一种从丙烯腈电解产物精馏残液中萃取分离己二腈和己烷三腈的方法,涉及有机化工分离技术领域。本发明采用由苯类、酯类、醇类组成的复合萃取剂,利用极性协同效应选择性溶解ADN和HTCN,并通过降温实现轻重相快速分离,多聚物去除率≥98%;分离后的轻相经蒸馏回收溶剂并循环使用,再通过精馏获得高纯度产品,其中ADN纯度≥99.5%,回收率≥98%;HTCN纯度≥98.5%,回收率≥94%。本发明实现了精馏残液中有价值组分的高效回收,解决了传统工艺中多聚物结焦堵塞、副产物浪费等问题,显著提升分离效率与装置运行周期,具有良好的工业化应用前景和经济效益。
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