Ionic rare earth ore smelting method based on collaborative precipitation and resource circulation

By combining acid leaching with multi-stage pH control, along with co-precipitation of ferric hydroxide, alkali conversion, and stepwise precipitation, efficient impurity removal and resource recycling were achieved. This solved the problems of low rare earth recovery rate and environmental protection in traditional ion-type rare earth ore smelting, producing high-purity rare earth products and realizing wastewater resource utilization.

CN122279272APending Publication Date: 2026-06-26LESHAN SHENGHE RARE EARTH CO LTD
0 Cites 0 Cited by

Patent Information

Application Number
CN202610258270.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-03-04
Publication Date
2026-06-26

AI Technical Summary

Technical Problem

Traditional ion-adsorption rare earth ore smelting processes suffer from problems such as low rare earth recovery rates, severe ammonia nitrogen pollution, serious impurity interference, rare earth loss due to sulfate, prominent fluorine hazards, and significant environmental and resource utilization pressures. Existing technologies have failed to systematically solve these problems.

Method used

The method employs acid leaching and multi-stage precise pH control. Barium chloride is added to eliminate sulfate, and ferric hydroxide co-precipitation and alkali conversion are used to achieve deep impurity removal. Iron and fluoride are removed by a stepped pH precipitation process. Alkali wash water is recycled to achieve full wastewater recycling, and valuable elements are recovered through lime precipitation and evaporation crystallization.

Benefits of technology

It improved the rare earth yield, reduced the rare earth content in the tailings, enabled the production of high-purity rare earth products, treated wastewater for resource recovery, and recovered valuable elements such as aluminum and iron, thus solving environmental protection and resource recovery issues.

✦ Generated by Eureka AI based on patent content.
Patent Text Reader

Abstract

The invention relates to the technical field of hydrometallurgy, and particularly discloses an ionic rare earth ore smelting method based on collaborative precipitation and resource circulation, which comprises the following steps: S1, adding water, ionic rare earth ore and ferric hydroxide into a reaction container, adding hydrochloric acid, and quantitatively adding barium chloride according to the content of sulfate radicals after detecting that the residual acidity is greater than 0.3 mol / L in the reaction process; s2, adding a pH regulator into the reaction system, controlling the temperature to adjust the pH value, adjusting the pH value to 2.5-3 and then adjusting the pH value to 4.5 to form gradient precipitates, and performing clarification and separation after the reaction to obtain a supernatant A and an enriched product A; s3, carrying out alkali transfer reaction on the obtained enriched product A and caustic soda liquid, and carrying out washing and filter pressing on alkali slurry after alkali transfer to obtain alkali cake slag; s4, mixing the obtained alkali cake slag with the supernatant A, adjusting the value, controlling the pH value to be 5.2, controlling the temperature to be 80 DEG C, and carrying out reaction clarification, so as to obtain value-adjusted slag and supernatant B; s5, acid is added into the value-adjusted residues obtained in the step S4 for leaching, the residual acidity is controlled to be larger than 0.5 mol / L, and supernate C and an enriched product C are obtained after reaction clarification; s6, adjusting the pH value of the supernatant C obtained in the step S5 at a stage, adjusting the pH value to 2.0, then stably adjusting the pH value to 3.5, and reacting to obtain a supernatant D and an enriched product D; and S7, adjusting the pH value of the supernatant D obtained in the step S6, stabilizing the pH value at 5.2, and reacting to obtain a supernatant E and an enriched product E.
Need to check novelty before this filing date? Find Prior Art