Biological water-based fuel liquid and preparation method thereof

Abstract

The invention discloses a biological water-based fuel liquid and a preparation method thereof, and belongs to the technical field of water-based liquid fuels. The preparation principle of the biological water-based fuel liquid is as follows: the biological water-based fuel liquid is prepared from clean energy, sanitary and environment-friendly novel fuel liquid which is generated by finding out biological raw materials and one oxygen and two hydrogen of water and is synthesized by oxidizing microorganisms. The biological water-based fuel liquid can be added into other fuels with high calorific value to be mixed, the mixture is heated to 350 DEG C to generate steam, an energy fission reaction is generated in the combustion process through electronic pulse ignition and excitation, direct injection blue and white flames are generated, the gas energy is harder than oil flame short explosion type raging fire, and the temperature calorific value can instantly reach more than 1000 DEG C. The device is safe, energy-saving, economical, environment-friendly, convenient to transport and non-combustible at an open fire point; and after combustion, no carbon residue is generated and the pot bottom is not black. And the material is not solidified at a low temperature of-20 DEG C, and can be combusted to be most suitable for northern use. And during combustion, firepower is strong, heat value is high and time consumption is low.

Description

TECHNICAL FIELD

[0001] The present application belongs to the technical field of aqueous liquid fuel, and particularly relates to a biological aqueous fuel liquid and a preparation method thereof. BACKGROUND

[0002] Fuel is widely used in industrial and agricultural production and people's life, and can release energy through chemical reaction. There are many kinds of fuel, the most common ones are coal, coke, petroleum, natural gas and biogas, etc. The combustion of these fuels emits carbon, hydrocarbons, carbon monoxide, nitrogen oxides, sulfides and solid particles, etc., which causes the environment to deteriorate day by day, and the carbon deposition is easily caused during the combustion process, thereby affecting the combustion effect. Energy researchers in the world are actively exploring and looking for environmentally friendly alternative fuels.

[0003] At present, heating devices and the like mostly use diesel fuel, but the exhaust gas of diesel combustion contains a large amount of dust, and after combustion, polycyclic benzene carcinogens such as sulfur dioxide and nitrogen dioxide are easily produced, which can cause serious environmental pollution. Methanol is a new type of alternative energy that has been researched in recent years, which is abundant in resources and cheap in price, and can be prepared from coal, charcoal or directly prepared from carbon dioxide and hydrogen. Alcohol fuel is a relatively clean alternative fuel, and the carbon-hydrogen ratio of methanol is 1:4, which can be completely burned in air to produce water and carbon dioxide, which can effectively reduce the emission of CO and other carbon-containing substances.

[0004] The aqueous fuel is a kind of liquid high-quality combustion produced by filtering and refining method and oxidation of water molecules with one oxygen and two hydrogens. Water molecules combine with one oxygen and two hydrogens, and six molecules constitute a drop of water. Compared with liquefied gas, diesel and traditional fuel, the aqueous fuel has the advantages of less consumption, less emission, lower carbon and environmental protection, and is a new energy that can be developed and utilized. It is inexhaustible. In use, it is smokeless, odorless, pollution-free, residue-free, black pot-free, clean and sanitary. The carbon dioxide produced during its combustion is lower than that of diesel and liquefied gas, the heat value is high, and the firepower is fierce. Moreover, its transportation and storage are safer, and the aqueous fuel can be stored, transported and used at normal temperature and pressure without the need for high-pressure steel cylinder storage and any transportation qualification, and ordinary plastic containers can be used, which is a rare clean fuel. SUMMARY

[0005] The first object of the present application is to provide a biological aqueous fuel liquid, which can be mixed with other high-calorific-value fuels, heated to 350 degrees Celsius to generate steam without the need for air blower oxygenation equipment and the like, and the steam is pumped into the hearth by an electromagnetic pump, and a straight-injection blue-white flame is generated by electronic pulse ignition and energy fission reaction during the combustion process, the gas energy is shorter than the oil flame, and the explosion is fierce, the temperature in the hearth air can reach above 1,000 degrees Celsius instantaneously.

[0006] The second object of the present application is to provide a kind of biological aqueous fuel liquid, with, energy saving, economic, environmental protection, convenient transportation, open fire point is not flammable;After combustion, no carbon residue is not black bottom of pot.

[0007] The present application is realized by the following technical solutions:

[0008] A kind of biological aqueous fuel liquid, the biological aqueous fuel liquid is mainly prepared from the following mass fraction of raw materials:

[0009] Natural glycerol 30-45 parts, ethanol 10-15 parts, water 35-40 parts, combustion improver 1-3 parts, catalyst 1-2 parts, emulsifying speed combustion improver 1-2 parts, balance thickening agent 0.5-1 part, active emulsifier 0.5-1 part, metal combustion improver 0.5-1 part and fusion catalyst 0.5-1 part.

[0010] The biological aqueous fuel liquid is composed of three main materials (natural glycerol, ethanol and water) and seven additional components (combustion improver, catalyst, emulsifying speed combustion improver, balance thickening agent, active emulsifier, metal combustion improver and fusion catalyst).

[0011] 1. Natural glycerol: alias: organic compound, chemical formula C3H8O3;Natural glycerol is a kind of organic compound viscous liquid, can absorb moisture from air, also can absorb hydrogen sulfide, hydrogen cyanide and sulfur dioxide, with water and alcohol soluble in any proportion, is the main organic chemical raw material, also can be used as analytical reagent and lubricating laxative, etc.

[0012] 2. Ethanol (ethanol) organic compound, structural formula is CH3CH2OH or C2H5OH, molecular formula is C2H6O, commonly known as alcohol;Organic compound, volatile colorless transparent liquid at room temperature and normal pressure, non-toxic pure liquid can not be directly drunk. Ethanol is a fuel that can be mixed with water and glycerol in any proportion. In medical treatment, water is diluted to 70%-75% to make disinfectant.

[0013] 3. Water: alias: hydrogen peroxide, oxygen alkane, hydrogen peroxide;Chemical formula: H2O;Molecular weight 18.0152. Water is a necessary factor for oxygen support combustion, commonly used in high temperature combustion, oxygen has the characteristics of high purity, high pressure and high flow, which can provide sufficient oxygen source and promote combustion effect. The product uses 5-grade reverse osmosis purification RO water, the aperture of reverse osmosis membrane is only 0.0001 microns, while the diameter of virus is generally 0.02-0.4 microns, and the diameter of ordinary bacteria is 0.4-1 microns, so that calcium ions and magnesium ions in water are completely separated, which plays an absolute oxygen assisting role.

[0014] As preferably, the mass concentration of the ethanol is 70-75wt%.

[0015] As preferably, the combustion improver is dimethyl sulfoxide;

[0016] The catalyst is aqueous sulfuric acid with a mass concentration not greater than 70wt%.

[0017] As preferably, the emulsified speed-increasing combustion improver is dodecanol;

[0018] The equilibrium thickening agent is sodium carboxymethyl starch.

[0019] As preferably, the active emulsifier is Perkadox O;

[0020] The metal combustion improver is aluminum hydroxide.

[0021] As preferably, the fusion catalyst is sodium hydroxide.

[0022] Dimethyl sulfoxide, Chinese name: dimethyl sulfoxide; English name: Dimethyl sulfoxide (DMSO); alias: dimethyl sulfoxide; chemical formula: C2H6OS; molecular weight: 78.13. As a combustion improver, dimethyl sulfoxide is a sulfur-containing organic compound, which is a colorless and odorless transparent liquid at room temperature, and is a hygroscopic flammable liquid. It has the characteristics of high polarity, high boiling point, good thermal stability, non-protic, and water-soluble, and is soluble in ethanol and most organic substances, and is known as "universal solvent", and has been widely used in medicine. This organic combustion improver has the characteristics of high heat value, high hydrogen-oxygen ratio and high combustion rate, which can improve the combustion speed and temperature, thereby improving the fuel efficiency. When encountering acid, it reacts in the combustion process to produce blue flame.

[0023] Sulfuric acid, English name: dilute sulfuric acid; chemical formula: H2SO4(aq). As a catalyst, aqueous sulfuric acid with a mass fraction less than or equal to 70%. In this configuration, dodecanol generates dodecyl sulfate. It plays a role in combustion, oxygenation and hydrogenation during the combustion process.

[0024] Dodecanol, Chinese name: 2-dodecanol; English name: 2-Dodecanol; alias: 2-dodecanol; chemical formula: C 12 H 26 O; molecular weight: 186.3342. As an emulsified speed-increasing combustion improver, dodecanol is a natural fatty alcohol made from coconut oil, palm oil and beef tallow. It is the main raw material for manufacturing anionic, cationic and non-ionic surfactants, such as hydroxyethylated sulfuric acid reaction to form alkylated and other surface active speed-increasing combustion improvers.

[0025] Sodium Starch Glycolate; Alias: Sodium Carboxymethyl Starch; Molecular Weight: 5×10 5 -1×10 6 As a balance thickening agent, sodium starch glycolate is an anionic starch ether that can be dissolved in cold water electrolyte. It is a kind of modified starch, belongs to ether starch, and is a water-soluble anionic polymer compound. It is odorless, nontoxic and not easy to mildew, and is easily soluble in water when the substitution degree is greater than 0.2. It is also called industrial monosodium glutamate.

[0026] Peregal O; Chemical name: fatty alcohol polyoxyethylene ether; as active emulsifier, peregal 0 appearance: milky white or beige paste easily soluble in water, ethanol, is a non-ionic surfactant, the main component is polyoxyethylene fatty alcohol ether, in hard water, acid or alkali solution does not change and very stable.

[0027] Aluminium hydroxide; Chemical formula: Al(OH)3; Molecular weight: 78.004 CAS21645-51-2. As a metal combustion improver, aluminum metal combustion improver has strong reducing property, and aluminum hydroxide can react with oxygen rapidly to release a large amount of heat value, providing sufficient energy to speed up the combustion speed.

[0028] Sodium hydroxide; Alias: caustic soda, fire alkali, caustic soda; Chemical formula: NaOH; Molecular weight: 40.00. As a fusion catalyst, sodium hydroxide has strong alkaline and strong corrosion, which can be used as acid neutralizer. Because aluminum hydroxide is insoluble in water, two kinds of ionization must be generated by sodium hydroxide and aluminum hydroxide: When sodium hydroxide is added, the hydrated hydrogen ion ionized will react with the hydroxyl ion ionized by sodium hydroxide, which consumes the hydrated hydrogen ion, so that the ionization of aluminum hydroxide moves to the direction of metaborate, until complete ionization. The reaction equation of aluminum hydroxide and sodium hydroxide is: Al(OH)3+NaOH=NaAlO2+2H2O. The actual reaction with alkali generates tetrahydroxy aluminate ([Al(OH)4]-). Therefore, it is usually regarded as metaboric acid (HAlO2·H2O) with one water, and the generated water and salt produce hydrogen gas in the combustion process. Sodium hydroxide can be used as alkaline cleaning agent in water treatment, soluble in ethanol and glycerol; Play a fusion, comprehensive role.

[0029] A method for preparing a biological aqueous fuel liquid, comprising: selecting natural glycerol, ethanol, water, combustion improver, catalyst, emulsification and combustion improver, balance thickening agent, active emulsifier, metal combustion improver and fusion catalyst according to the corresponding mass fraction, and stirring in order, and then standing without stratification, and completing.

[0030] As preferably, the stirring duration is 30-35 min.

[0031] As preferably, the standing duration is 3-3.5 h.

[0032] The above raw materials are sequentially mixed and stirred for 30-35 min, the stirring plays a role of breaking wall and fusion, and the product can be used after standing for 3-3.5 h without stratification.

[0033] Compared with the prior art, the present application has at least the following technical effects:

[0034] (I) The present application provides a biological aqueous fuel liquid, which is not flammable at open fire point, aiming to facilitate the transportation of explosion and other dangers, and the initial design is to eliminate the dangers of poisoning, fire and explosion caused by liquefied gas and natural gas, and to bring significant economic losses to people's life and property. At the same time, the biological aqueous fuel liquid is not flammable at open fire point without special stove and high-temperature heating, and has high safety.

[0035] The invention principle is: finding out that biological raw materials and water generate 1 oxygen and 2 hydrogen to form a clean energy, hygienic and environmentally friendly new fuel liquid prepared by microbial oxidation.

[0036] (II) The biological aqueous fuel liquid has the following characteristics: all raw materials are dissolved in water, transparent and colorless, odorless, and no harmful gas in the whole process and combustion, which also protects the air. Its heat value is effectively realized in the following process:

[0037] 1. The biological aqueous fuel liquid is mixed with other high-heat-value fuels, and an electric stove is used without the need for a blower to increase oxygen and other equipment. The temperature is heated to 350 degrees to generate steam, and the (water) is pumped into the furnace by an electromagnetic pump. Through electronic pulse ignition, the combustion process generates (energy fission reaction) to generate a direct injection of blue-white flame. The gas energy is shorter than the oil flame, and the explosive fire is hard. The temperature in the furnace air can reach more than 1,000 degrees in an instant.

[0038] 2. Using chemical modification technology, glycerol with low combustion is added to other combustion-supporting molecular structures to become high-quality modified fuel, increase the length of molecular chains, and improve the comprehensive thermal energy quality.

[0039] 3. Through high-temperature pyrolysis technology, ethanol fuel is extended from the surface ignition point to the formation of steam after heating with water and other substances, and then (for the third time) reacts to generate transparent high-energy blue-white flame. This fully burns the active combustion of each element, making the surface activity of ethanol burn more deeply.

[0040] 4. The three carbon bases in glycerol fuel are used to synthesize ethanol, water and other bio-oxidized substances through fine processing, so that the energy is fully utilized, thereby improving the high calorific value of the fuel.

[0041] 5. The new technology development, such as catalytic cracking, synthesizes glycerol, ethanol and water and other substances to synthesize high molecular weight, high energy oxygen-containing compounds with a combustion heat value much higher than other types.

[0042] (Three) The bio-aqueous fuel is safe, energy-saving, economical, environmentally friendly, convenient to transport, non-flammable at the ignition point, and has no carbon residue after burning and no black pot bottom. It can also be burned at low temperature of minus 20 degrees without solidification, and is most suitable for use in the north. It has low carbon emissions and low economic cost, and has a significant advantage over bio-fuel in price. It can completely replace liquefied gas, diesel and other hotels, school canteens, industrial kilns or boilers, drying rooms, power generation and the like.

[0043] In actual cases, the bio-aqueous fuel is tested with liquefied gas, and five kilograms of boiling water is burned; the liquefied gas takes 7 minutes and 40 seconds, and the gas consumption is 0.5 kilograms; the bio-aqueous fuel takes 5 minutes and 20 seconds, and the consumption is 0.17 kilograms. This shows that the bio-aqueous fuel has a fierce fire, a high calorific value, a short time and a natural reduction in cost when burned. DETAILED DESCRIPTION

[0044] The embodiments of the present application will be described in detail below with reference to the examples, but those skilled in the art will understand that the following examples are only for illustration of the present application and should not be regarded as limiting the scope of the present application. The specific conditions not mentioned in the examples are carried out according to the conventional conditions or the conditions recommended by the manufacturer, and the reagents or instruments not mentioned by the manufacturer are conventional products that can be purchased on the market.

[0045] Example 1

[0046] A bio-aqueous fuel liquid is prepared from the following raw materials in mass parts:

[0047] 30 kg of natural glycerol, 10 kg of ethanol, 35 kg of water, 1 kg of combustion improver, 1 kg of catalyst, 1 kg of emulsified combustion improver, 0.5 kg of balanced thickening agent, 0.5 kg of active emulsifier, 0.5 kg of metal combustion improver and 0.5 kg of fusion catalyst.

[0048] The mass concentration of the ethanol is 70 wt%.

[0049] The combustion improver is dimethyl sulfoxide;

[0050] The catalyst is a sulfuric acid aqueous solution with a mass concentration of not more than 70 wt%.

[0051] The emulsified speed-increasing combustion improver is dodecanol.

[0052] The balanced thickening agent is sodium carboxymethyl starch.

[0053] The active emulsifier is Pingpingka O.

[0054] The metal combustion improver is aluminum hydroxide.

[0055] The fusion catalyst is sodium hydroxide.

[0056] A preparation method of a biological aqueous fuel liquid, comprising: selecting natural glycerol, ethanol, water, a combustion improver, a catalyst, an emulsified speed-increasing combustion improver, a balanced thickening agent, an active emulsifier, a metal combustion improver and a fusion catalyst according to corresponding mass fractions, and sequentially blending and stirring, and standing for 3 hours without stratification.

[0057] The stirring duration is 30 min.

[0058] The standing duration is 3 h.

[0059] The above raw materials are sequentially blended and stirred according to their properties, the stirring plays a role in breaking the wall and fusing, and the product can be used after standing for 3 hours without stratification.

[0060] Example 2:

[0061] A biological aqueous fuel liquid, which is mainly prepared from raw materials with the following mass fractions:

[0062] Natural glycerol 45 kg, ethanol 15 kg, water 40 kg, combustion improver 3 kg, catalyst 2 kg, emulsified speed-increasing combustion improver 2 kg, balanced thickening agent 1 kg, active emulsifier 1 kg, metal combustion improver 1 kg and fusion catalyst 1 kg.

[0063] The mass concentration of the ethanol is 75 wt%.

[0064] The combustion improver is dimethyl sulfoxide;

[0065] The catalyst is a sulfuric acid aqueous solution with a mass concentration of not more than 70 wt%.

[0066] The emulsified speed-increasing combustion improver is dodecanol;

[0067] The balanced thickening agent is sodium carboxymethyl starch.

[0068] The active emulsifier is Pingpingka O.

[0069] The metal combustion improver is aluminum hydroxide.

[0070] The fusion catalyst is sodium hydroxide.

[0071] A kind of preparation method of biological aqueous fuel liquid, comprising: selecting natural glycerol, ethanol, water, combustion improver, catalyst, emulsifying speed combustion improver, balanced thickener, active emulsifier, metal combustion improver and fusion catalyst according to corresponding mass fraction, sequentially blending and stirring in order, stratification does not appear after standing, complete.

[0072] As preferably, the stirring duration is 35 min.

[0073] As preferably, the standing duration is 3.5 h.

[0074] The above sequentially blends and stirs according to the attribute of raw material, and the stirring plays the role of breaking wall fusion, and it can be used after 3.5 hours of standing without stratification phenomenon.

[0075] Finally, it should be noted that: the above only for the preferred embodiments of the present application, and is not used to limit the protection scope of the present application.Any modification, equivalent replacement, improvement, etc.were made within the spirit and principles of the present application, should be included in the protection scope of the present application.

Claims

1. A bio-aqueous fuel liquid, characterized in that, The bio-aqueous fuel liquid is mainly prepared from the following raw materials in parts by weight: 30-45 parts natural glycerin, 10-15 parts ethanol, 35-40 parts water, 1-3 parts combustion improver, 1-2 parts catalyst, 1-2 parts emulsifying combustion improver, 0.5-1 part balanced thickener, 0.5-1 part active emulsifier, 0.5-1 part metal combustion improver and 0.5-1 part fusion catalyst.

2. The bio-aqueous fuel liquid according to claim 1, characterized in that, The ethanol concentration is 70-75 wt%.

3. The bio-aqueous fuel liquid according to claim 1, characterized in that, The combustion aid is dimethyl sulfoxide; The catalyst is an aqueous solution of sulfuric acid with a mass concentration of no more than 70 wt%.

4. The bio-aqueous fuel liquid according to claim 1, characterized in that, The emulsified combustion-promoting agent is dodecaneol; The balancing thickener is sodium carboxymethyl starch.

5. A bioaqueous fuel liquid according to claim 1, characterized in that, The active emulsifier is Pingpingjia O; The metal combustion aid is aluminum hydroxide.

6. The bio-aqueous fuel liquid according to claim 1, characterized in that, The fusion catalyst is sodium hydroxide.

7. A method for preparing a bio-aqueous fuel liquid as described in any one of claims 1-6, characterized in that, include: Select the appropriate mass proportions of natural glycerin, ethanol, water, combustion improver, catalyst, emulsifying combustion improver, balancing thickener, active emulsifier, metal combustion improver, and fusion catalyst, and mix them in sequence. If no stratification occurs after standing, the mixture is complete.

8. The method for preparing a bio-aqueous fuel liquid according to claim 7, characterized in that, The stirring time is 30-35 minutes.

9. A method for preparing a bio-aqueous fuel liquid according to claim 7, characterized in that, The settling time is 3-3.5 hours.