Method for removing photoresist

By spraying photoresist onto a rotating support platform and controlling the reaction time, a liquid film is formed to dissolve the photoresist, solving the problem of large amounts of photoresist used and achieving a cost-effective photoresist removal method.

CN122284237APending Publication Date: 2026-06-26TAIWAN ASIA SEMICONDUCTOR CORPORATION

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TAIWAN ASIA SEMICONDUCTOR CORPORATION
Filing Date
2025-03-14
Publication Date
2026-06-26

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Abstract

The present invention provides a photoresist removal method, comprising the following steps: (S1) immersing a wafer in a container containing a photoresist remover; (S2) removing the wafer from the container and placing it on a support stage; (S3) rotating the support stage during the spraying time and spraying the wafer with a photoresist remover using a spraying unit at a flow rate of 1 ml / sec to 10 ml / sec; (S4) stopping the spraying of the photoresist remover onto the wafer during the reaction time; and (S5) performing a cleaning and drying process on the wafer.
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Description

Technical Field

[0001] This invention relates to a photoresist removal method, and more particularly to a photoresist removal method that effectively reduces the amount of photoresist used. Background Technology

[0002] Lithography is a crucial technology in semiconductor component manufacturing. It typically involves creating the circuit patterns required for semiconductor components through exposure and photoresist applications, culminating in the removal of the photoresist from the semiconductor component surface. Since photoresist materials are mostly composed of organic compounds such as carbon, hydrogen, and oxygen, photoresist stripping agents are commonly used to peel the photoresist from the semiconductor component surface. In practice, the wafer to be processed is first immersed in a recyclable photoresist stripper, then removed and rinsed with fresh photoresist stripper. However, during the rinsing process with fresh photoresist stripper, to achieve the desired photoresist removal rate, the rinsing time can be as high as 360 seconds or even longer. If the photoresist stripper flow rate is calculated at 1-10 ml per second, the consumption can reach 360-3600 ml or more, significantly increasing the manufacturing and processing costs of semiconductor components.

[0003] Therefore, how to design a photoresist removal method that can improve the aforementioned problems is a topic worthy of research. Summary of the Invention

[0004] The purpose of this invention is to provide a photoresist removal method that effectively reduces the amount of photoresist used.

[0005] To achieve the above objectives, the present invention provides a photoresist removal method applied to a wafer containing photoresist. The method includes the following steps: (S1) immersing the wafer in a receiving tank containing photoresist remover; (S2) removing the wafer from the receiving tank and placing it on a support stage; (S3) rotating the support stage during the spraying time and spraying the wafer with photoresist remover using a spraying unit at a flow rate of 1 ml / sec to 10 ml / sec; (S4) stopping the spraying of photoresist remover onto the wafer during the reaction time; and (S5) performing a cleaning and drying process on the wafer.

[0006] In one embodiment of the present invention, in step (S3), the rotational speed of the support platform is not less than 500 revolutions per second.

[0007] In one embodiment of the present invention, in step (S3), the rotational speed of the support platform is 500 revolutions per second to 1000 revolutions per second.

[0008] In one embodiment of the present invention, in step (S4), the support platform remains stationary.

[0009] In one embodiment of the present invention, in step (S4), the rotational speed of the support platform is not higher than 20 revolutions per second.

[0010] In one embodiment of the present invention, the spraying time is 5 to 30 seconds.

[0011] In one embodiment of the present invention, the reaction time is 10 seconds to 180 seconds.

[0012] In one embodiment of the present invention, in step (S3), the spraying unit moves back and forth along a straight path through the center of the wafer to spray photoresist.

[0013] In one embodiment of the present invention, the following step is included before step (S5): (S6) repeating the cycle of steps (S3) to (S4) 1 to 3 times.

[0014] The present invention also provides a photoresist removal system that applies the aforementioned photoresist removal method.

[0015] Other objects of the present invention, as well as the technical means and implementation methods of the present invention, will be understood by those skilled in the art upon referring to the accompanying drawings and the embodiments described below. Attached Figure Description

[0016] Figure 1 This is a flowchart of the photoresist removal method of the present invention.

[0017] Figure 2 This is a flowchart of another embodiment of the photoresist removal method of the present invention.

[0018] Explanation of reference numerals in the attached figures

[0019] Steps S1-S6. Detailed Implementation

[0020] Since the various solutions and embodiments are merely exemplary and not limiting, those skilled in the art may devise other solutions and embodiments without departing from the scope of the invention after reading this specification. The features and advantages of the embodiments will become more apparent from the following detailed description and claims.

[0021] Throughout this document, the terms "a" or "an" are used to describe the components and elements described herein. This is used merely for ease of explanation and to provide a general meaning regarding the scope of the invention. Therefore, unless it is clearly intended otherwise, this description should be understood to include one or at least one, and the singular also includes multiples.

[0022] In this document, the terms “comprising,” “having,” or any other similar terms are intended to cover non-exclusive inclusions. For example, a component or structure containing multiple elements is not limited to those listed herein, but may include other elements not expressly listed but which are generally inherent to the component or structure.

[0023] The photoresist removal method of this invention is mainly applied to wafers containing photoresist, but it can also be applied to other semiconductor components requiring photoresist removal. Please refer to [link / reference]. Figure 1 This is a flowchart of the photoresist removal method of the present invention. Figure 1 As shown, the photoresist removal method of the present invention includes the following steps:

[0024] Step (S1): Immerse the wafer in a container with photoresist removed.

[0025] First, this invention provides a receiving tank, into which photoresist is poured to ensure sufficient volume. Next, a wafer is placed into the receiving tank (e.g., using a robotic arm for handling) and immersed in the photoresist to induce initial swelling and dissolution of the photoresist on the wafer surface. In this invention, the receiving tank can simultaneously hold multiple wafers, ensuring each wafer is immersed in the photoresist, and the photoresist in the tank can be repeatedly recycled.

[0026] Step (S2): Remove the wafer from the self-contained slot and place it on the support stage.

[0027] After immersing the wafer in the aforementioned step (S1), the present invention then removes one of the multiple wafers to be processed from the receiving tank and places the removed wafer on a support platform (e.g., using a robotic arm for handling). At this time, the remaining wafers to be processed remain immersed in the photoresist remover in the receiving tank.

[0028] Step (S3): During the spraying time, rotate the support stage and use the spraying unit to spray the wafer with photoresist at a flow rate of 1 ml / sec to 10 ml / sec.

[0029] After placing the wafer on the support stage in the aforementioned step (S2), the present invention can continuously rotate the support stage holding the wafer to be processed within a set spraying time, and continuously spray fresh photoresist (different from the recyclable photoresist in the containment tank) onto the wafer using a spraying unit. The spraying unit mainly includes a nozzle and a control component, which can control the movement of the nozzle and start / stop the spraying of the photoresist. In one embodiment of the present invention, the spraying unit moves the nozzle back and forth along a straight path passing through the center of the wafer to spray the photoresist. Combined with the rotation of the support stage, the photoresist can be sprayed more evenly onto the surface of the wafer to be processed. In one embodiment of the present invention, the spraying unit sprays the photoresist at a flow rate of 1 ml / sec to 10 ml / sec, but the present invention is not limited thereto. In one embodiment of the present invention, the set spraying time is 5 seconds to 30 seconds to save on the amount of photoresist used, but the present invention is not limited thereto.

[0030] In one embodiment of the present invention, in step (S3), the rotation speed of the support stage is not less than 500 revolutions per second. Preferably, in step (S3), the rotation speed of the support stage is between 500 and 1000 revolutions per second. Accordingly, by performing high-speed rotation of the support stage to drive the wafer to rotate, the photoresist sprayed by the spraying unit can be more uniformly distributed on the wafer surface.

[0031] Step (S4): Stop spraying the photoresist onto the wafer within the reaction time.

[0032] After spraying the photoresist remover onto the wafer in step (S3) above, the present invention can then continuously stop spraying the photoresist remover onto the wafer within a set reaction time. Through the surface tension of the photoresist remover remaining on the wafer surface after spraying, a liquid film of the photoresist remover can be formed on the wafer surface, allowing sufficient time for the photoresist remover to react with the photoresist on the wafer surface, promoting further swelling and dissolution of the photoresist. In one embodiment of the present invention, the set reaction time is 10 seconds to 180 seconds to provide sufficient reaction time between the photoresist remover and the photoresist on the wafer surface, but the present invention is not limited thereto.

[0033] In one embodiment of the present invention, in step (S4), the support stage remains stationary. That is, during the set reaction time, except for stopping the spraying of photoresist onto the wafer, the wafer is placed on the support stage to allow the photoresist to fully react with the surface of the wafer being contacted.

[0034] In one embodiment of the present invention, in step (S4), the rotation speed of the support stage is no higher than 20 revolutions per second. That is, within the set reaction time, except for stopping the spraying of photoresist on the wafer, the wafer is rotated at a low speed by the support stage, so that the photoresist remaining on the wafer surface can move appropriately and be more evenly distributed on the wafer surface, thereby improving the reaction rate and reaction effect.

[0035] Step (S5): Perform cleaning and drying processes on the wafer.

[0036] After stopping the spraying of photoresist on the wafer in the aforementioned step (S4), the present invention can then perform a cleaning and drying process on the wafer, using clean water to rinse the wafer surface to remove residual photoresist and photoresist, and using a rotating support stage to drive the wafer to rotate to accelerate the drying of the wafer surface, thereby completing the entire photoresist removal process of the wafer.

[0037] Please refer to Figure 2 This is a flowchart of another embodiment of the photoresist removal method of the present invention. Figure 2 As shown, the photoresist removal method of the present invention further includes the following steps:

[0038] Step (S6): Repeat steps (S3) to (S4) 1 to 3 times.

[0039] In this embodiment, after stopping the spraying of photoresist remover onto the wafer in step (S4), the present invention can return to step (S3), recalculate another spraying time to rotate the support stage and spray photoresist remover onto the wafer, and then recalculate another reaction time to stop spraying photoresist remover onto the wafer, thus completing another cycle of steps (S3) to (S4). Depending on the type of photoresist on the wafer surface, the photoresist removal method of the present invention can selectively repeat the cycle of steps (S3) to (S4) 1 to 3 times after step (S4), but the present invention is not limited thereto. Only after all the cycles of steps (S3) to (S4) have been completed will the subsequent cleaning and drying process (S5) be executed.

[0040] For example, in one embodiment of the present invention, the photoresist removal method of the present invention sets the rotation speed of the stage to 500 revolutions per second in step (S3), the spraying unit sprays the photoresist remover at a flow rate of 1 ml / sec, and the spraying time is 90 seconds. In step (S4), the reaction time is set to 90 seconds, and steps (S3) to (S4) are repeated once. After executing the photoresist removal method of the present invention under the aforementioned conditions, the total time consumed is 360 seconds, but the total amount of photoresist used is only 180 ml. Compared to the conventional method, which continuously rinses the wafer with photoresist remover under the same time and flow rate conditions to achieve a similar photoresist removal effect, requiring 360 ml of photoresist remover, the photoresist removal method of the present invention significantly saves on the amount of photoresist used.

[0041] For example, in one embodiment of the present invention, the photoresist removal method sets the rotation speed of the stage to 500 revolutions per second in step (S3), the spraying unit sprays the photoresist remover at a flow rate of 1 ml / sec for 30 seconds, and the reaction time is set to 150 seconds in step (S4). Steps (S3) to (S4) are then repeated once. Based on the aforementioned settings, the total time for executing the photoresist removal method of the present invention is 360 seconds, but the total amount of photoresist used is only 60 ml. Compared to traditional methods that achieve similar photoresist removal by simply rinsing the wafer with photoresist under the same time and flow rate conditions, which requires 360 ml of photoresist remover, the photoresist removal method of the present invention significantly saves on the amount of photoresist used.

[0042] The present invention also provides a photoresist removal system that applies the aforementioned photoresist removal method. The photoresist removal system of the present invention performs the aforementioned photoresist removal method to remove photoresist from the wafer surface.

[0043] In summary, the photoresist removal method of this invention, through its design of spraying the photoresist remover and increasing the reaction time between the photoresist remover and the wafer, utilizes the surface tension of the interaction between the photoresist remover and the wafer to form a liquid film of the photoresist remover on the wafer surface, promoting the swelling and dissolution of the photoresist after the reaction. This photoresist removal method of the present invention requires only 10-50% of the amount of photoresist remover used in conventional techniques, effectively reducing the amount of photoresist used and related process costs.

[0044] The above embodiments are merely illustrative in nature and are not intended to limit the embodiments of this application or their application or use. Furthermore, although at least one exemplary embodiment has been presented in the foregoing embodiments, it should be understood that numerous variations are possible with respect to the invention. Similarly, it should be understood that the embodiments described herein are not intended to limit the scope, use, or configuration of the protection claimed in any way. Rather, the foregoing embodiments will provide a simple guide for those skilled in the art to implement one or more of the described embodiments. Moreover, various changes can be made to the function and arrangement of the components without departing from the scope defined by the claims, and the claims include known equivalents and all foreseeable equivalents at the time of filing of this patent application.

Claims

1. A photoresist removal method, applied to a wafer containing photoresist, the method comprising the following steps: (S1): Immerse the wafer in a container with a photoresist remover; (S2): The wafer is removed from the receiving tank and placed on a support platform; (S3): Rotate the support platform within a spraying time and spray the photoresist onto the wafer using a spraying unit at a flow rate of 1 ml / sec to 10 ml / sec; (S4): Stop spraying the photoresist onto the wafer within a reaction time; and (S5): Perform a cleaning and drying process on the wafer.

2. The photoresist removal method as described in claim 1, wherein in step (S3), the rotation speed of the stage is not less than 500 revolutions per second.

3. The photoresist removal method as described in claim 2, wherein in step (S3), the rotation speed of the stage is between 500 and 1000 revolutions per second.

4. The photoresist removal method as claimed in claim 1, wherein in step (S4), the support stage remains stationary.

5. The photoresist removal method as described in claim 1, wherein in step (S4), the rotational speed of the stage is not higher than 20 revolutions per second.

6. The photoresist removal method as described in claim 1, wherein the spraying time is 5 to 30 seconds.

7. The photoresist removal method as described in claim 1, wherein the reaction time is 10 seconds to 180 seconds.

8. The photoresist removal method as claimed in claim 1, wherein in step (S3), the spraying unit moves back and forth along a straight path passing through the center of the wafer to spray the photoresist remover.

9. The photoresist removal method as described in claim 1, wherein the method further comprises the following step before step (S5): (S6): Repeat steps (S3) to (S4) 1 to 3 times.

10. A photoresist removal system applying the photoresist removal method according to any one of claims 1 to 9.