Sulfonated side phenyl phthalazinone copolyether sulfone hollow fiber membrane as well as preparation method and application thereof

By adding inorganic salts and small organic molecule additives to the spinning solution, sulfonated side-phenylenediamine biphenyl copolyethersulfone hollow fiber membranes were prepared, solving the problem of high cost of existing membrane materials and achieving high water vapor permeability and selectivity at low cost, which is suitable for medical gas dehumidification and other fields.

CN122399602APending Publication Date: 2026-07-17DALIAN UNIV OF TECH
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Patent Information

Application Number
CN202610600366.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

While existing membrane materials offer high water vapor permeation selectivity in the field of air dehumidification, their high cost limits their widespread application in industrial and residential dehumidification.

Method used

Sulfonated side-phenyl naphthalene biphenyl copolyether sulfone hollow fiber membranes are used. By adding inorganic salts and small organic molecule additives to the spinning solution, a dense selective layer and a porous support layer structure are formed, which improves water vapor permeability and water vapor/nitrogen selectivity, and reduces costs.

Benefits of technology

It achieves high water vapor permeability and water vapor/nitrogen selectivity at low cost, making it suitable for fields such as medical gas dehumidification. It also has good hydrophilicity, thermal stability and mechanical properties, making it suitable for large-scale application.

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Abstract

The invention belongs to the technical field of polymer separation membrane materials, and particularly relates to a sulfonated side phenyl phthalazinone copolyether sulfone hollow fiber membrane as well as a preparation method and application of the sulfonated side phenyl phthalazinone copolyether sulfone hollow fiber membrane. The spinning solution comprises the following components: sulfonated side phenyl phthalazinone copolyethersulfone, an inorganic salt additive, an organic small molecule additive and a first organic solvent, and the sulfonated side phenyl phthalazinone copolyethersulfone has a structure as shown in formula (1). The sulfonated side phenyl phthalazinone copolyether sulfone hollow fiber membrane provided by the invention has excellent water vapor permeability and water vapor / nitrogen selectivity, and compared with perfluorinated sulfonic acid resin, the hollow fiber membrane is lower in cost.
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