A surfactant system that produces ultra-low interfacial tension

By screening out specific ratios and concentrations of alkylbenzene sulfonate and C16-alkanolamide, a simple surfactant system is provided, which solves the problem that existing compound systems are difficult to achieve ultra-low interfacial tension and achieves efficient oil displacement effect.

CN122405296APending Publication Date: 2026-07-17LANZHOU INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
LANZHOU INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the prior art, although the combination system of sulfonate and alkanolamide surfactants can reduce the interfacial tension between oil and water, there is a lack of screening for the interfacial activity of different carbon chain alkanolamide systems, and other surfactants or auxiliaries are usually required to achieve ultra-low interfacial tension. It is not clear which carbon chain alkanolamide and alkylbenzene sulfonate combination can uniquely produce ultra-low interfacial tension.

Method used

When the mass ratio of alkylbenzene sulfonate to C16-alkanolamide is 2:1 to 1:3, and the total mass fraction of the surfactant system in the aqueous solution is not less than 0.05%, the oil-water interfacial tension is less than 1×10-3 mN/m.

Benefits of technology

It achieves the stable generation of ultra-low oil-water interfacial tension by a surfactant system consisting only of alkylbenzene sulfonate and C16-alkanolamide, without the need for the addition of other surfactants or additives, within a wide range of proportions and concentrations, significantly improving crude oil recovery and suitable for different formation conditions.

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Abstract

本发明公开了一种可产生超低界面张力的表面活性剂体系,属于油田化学驱油技术领域。该表面活性剂体系由烷基苯磺酸盐和C16‑烷醇酰胺组成,其中烷基苯磺酸盐与C16‑烷醇酰胺的质量比为2:1~1:3,且体系在水溶液中的总质量分数不低于0.05%时,油水界面张力低于1×10‑3mN / m。本发明通过系统比较不同碳链(C8、C10、C12、C14、C16、C18)的烷醇酰胺与烷基苯磺酸盐复配的界面活性,发现仅C16‑烷醇酰胺能够产生超低界面张力,其他碳链均无效。室内驱替实验表明,该复配体系提高原油采收率可达33.9%,远高于单一体系。本发明配方简单、界面性能优异、碳链选择性明确,为油田三次采油提供了高效驱油体系。
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Citation Information

Patent Citations

  • An oil displacement surfactant for high-temperature, high-salinity oil reservoirs, its preparation method and application

    CN112251208B