Plasma-doped modified hard carbon negative electrode material and preparation method and application thereof

By modifying hard carbon materials in N2 or O2 atmospheres using plasma treatment technology, the problems of low initial coulombic efficiency, insufficient rate performance, and poor cycle stability of hard carbon materials in sodium-ion batteries are solved, and the electrochemical performance optimization of high capacity and long cycle life is achieved.

CN122417883APending Publication Date: 2026-07-17HENAN UNIVERSITY +1
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Patent Information

Application Number
CN202610305893.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-03-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing hard carbon materials in sodium-ion batteries suffer from low initial coulombic efficiency, insufficient rate performance, and poor cycle stability, mainly due to surface defects and unstable oxygen-containing functional groups leading to irreversible electrolyte decomposition and excessive SEI film growth.

Method used

Plasma treatment technology is used to treat hard carbon materials in an N2 or O2 atmosphere. By adjusting the plasma power and gas flow rate, the modification of the hard carbon surface is precisely controlled, introducing nitrogen- or oxygen-containing functional groups with good conductivity, eliminating unstable defects, and constructing a stable interface layer.

Benefits of technology

It significantly improves the initial coulombic efficiency, reversible capacity, and cycle stability of hard carbon materials, optimizes electrochemical performance for different application needs, and achieves high-capacity and long-cycle-life sodium-ion battery performance.

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Abstract

本发明属于钠离子电池技术领域,涉及一种等离子体掺杂改性硬碳负极材料及其制备方法和应用。将基础硬碳材料粉末置于等离子体反应腔室内,抽真空后通入处理气体,进行等离子体处理;处理结束后收集粉末,即得等离子体掺杂改性的硬碳负极材料。处理气体为N2或O2中的一种或多种,气体流量为100‑200 mL / min,处理功率为40‑120 W,处理时间为5‑20 min。本发明有效提升了材料表面的电子导电性,清除了不稳定含氧官能团和结构缺陷,构建了稳定的人工界面层。本发明的改性硬碳材料作为钠离子电池负极时,表现出优异的首次库伦效率、高可逆容量和良好的循环稳定性。本申请工艺简单、可控性强、处理时间短,适合规模化生产应用。
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Citation Information

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