Treatment system for continuous and efficient defluorination in zinc sulfate solution

By processing the waste cathode aluminum plate of the zinc electrostatic accumulation system into aluminum chips and used to remove fluoride ions in the zinc sulfate solution, the problem of difficult to reduce the concentration of fluorine ion in the wet zinc smelting system is solved, and efficient defluorination and secondary utilization of waste materials is achieved, reducing production costs and energy consumption.

CN222665949UActive Publication Date: 2025-03-25HULUN BUIR CHIHONG MINING CO LTD
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Patent Information

Application Number
CN202421460160.X
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-06-24
Publication Date
2025-03-25
Estimated Expiration
2034-06-24

AI Technical Summary

Technical Problem

The prior art is difficult to effectively reduce the concentration of HCFCs in the zinc sulfate solution in the wet zinc smelting system, resulting in equipment corrosion, difficulty in peeling off the electro-zinc adhesive plate, and increased energy consumption.

Method used

By cutting and processing the waste cathode aluminum plate of the wet zinc smelting zinc electrolysis system into aluminum chips, and using it to remove fluoride ions in the waste liquid produced by the zinc electrolysis system, reacting the aluminum chips with hydrogen ions in the solution to generate trivalent aluminum ions, and then combining with the fluoride ions to form precipitated aluminum fluoride, thereby achieving continuous and efficient defluorination of the zinc sulfate solution.

Benefits of technology

The wet zinc smelting system has been achieved to significantly defluoride, reduce the concentration of fluorine-chloro-ion, avoid equipment corrosion and increase energy consumption, and at the same time, the secondary comprehensive utilization of waste cathode aluminum plates has been achieved, reducing production costs.

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Abstract

The utility model discloses a treatment system for continuous and efficient defluorination in a zinc sulfate solution, and belongs to the technical field of nonferrous metallurgy-waste material recycling. Comprising a material preparation unit, an acid dissolution-defluorination unit and a discharging unit, the acid dissolution-defluorination unit comprises a high-fluorine waste electrolyte tank and a plurality of defluorination tanks; wherein the discharge port of the high-fluorine waste electrolyte tank is connected with the feed ports of the plurality of defluorination tanks respectively. According to the utility model, fluorine ions in the self-produced waste liquid of the zinc electrodeposition system are directly removed through aluminum scraps produced by cutting and processing waste cathode aluminum plates of the zinc electrodeposition system in the zinc hydrometallurgy, so that the defluorination of the zinc hydrometallurgy system can be realized.
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