Light blue ultra-high-transmittance single-silver glass

Abstract

The utility model discloses light blue ultra-high-transmittance single-silver glass. The light blue ultra-high-transmittance single-silver glass sequentially comprises a glass substrate, a first dielectric layer, a second dielectric layer, a third dielectric layer, a silver layer, a protective layer, a fourth dielectric layer, a fifth dielectric layer and a sixth dielectric layer from bottom to top, the appearance is light blue, the transmittance reaches up to 86% or above, the visible light transmittance is extremely high, and indoor light rays are bright, the visual field is wide, and the daylighting effect is extremely good after the coating is used.

Description

Technical Field

[0001] The utility model belongs to the technical field of single-silver glass, and particularly relates to a light blue ultra-high-transmittance single-silver glass. Background Art

[0002] Single-silver glass, that is, single-silver Low-E glass, is a low-emissivity (Low-E) glass with a single-layer ultra-thin silver film coated on the glass surface. According to different light transmittance and sun-shading performance, single-silver Low-E glass can be divided into high-transmittance Low-E glass and sun-shading Low-E glass. High-transmittance single-silver glass has a good visible light transmittance, making the indoor light bright, the field of vision open, and the daylighting effect better. However, the visible light transmittance of the existing single-silver Low-E glass can only reach about 80%, still unable to meet the requirements of customers for higher transmittance.

[0003] Chinese Patent CN 212199019 U discloses a high-transmittance single-silver low-emissivity coated glass, including a glass substrate layer and a coating layer. The coating layer is successively compounded with eight film layers from the glass substrate layer outwards. The first layer is a SiNx layer, the second layer is a ZnAl layer, the third layer is an Ag layer, the fourth layer is a NiCr layer, the fifth layer is a ZnAl layer, the sixth layer is a ZnSn layer, the seventh layer is a SiNx layer, and the eighth layer is a ZrOx layer; the first layer and the second layer are the first dielectric combination layer, the third layer is the low-emissivity functional layer, the fourth layer is the first barrier protection layer, the fifth layer and the sixth layer are the second dielectric combination layer, and the seventh layer is the film layer protection layer. The utility model has the advantages of high light transmittance, good antioxidant performance, etc. Although the glass disclosed in this patent has the characteristics of high light transmittance and good antioxidant performance, the light transmittance of the whole glass can only reach more than 80%, and the outdoor color is also monotonous colorless. Summary of the Invention

[0004] To solve the above technical problems, the utility model provides a light blue ultra-high-transmittance single-silver glass with a transmittance ≥ 86%, having the characteristics of high transmittance, low reflection, and low radiation.

[0005] The technical solution adopted by the utility model is as follows:

[0006] The utility model provides a light blue ultra-high-transmittance single-silver glass, which successively includes from bottom to top: a glass substrate, a first dielectric layer, a second dielectric layer, a third dielectric layer, a silver layer, a protection layer, a fourth dielectric layer, a fifth dielectric layer, and a sixth dielectric layer.

[0007] The first dielectric layer is a non-metallic nitride layer; the thickness of the first dielectric layer is 25 - 35 nm.

[0008] The second dielectric layer is a metal oxide layer; the thickness of the second dielectric layer is 10 - 15 nm.

[0009] The third dielectric layer is a metal oxide layer; the thickness of the third dielectric layer is 10 - 15 nm.

[0010] The thickness of the silver layer is 5 - 10 nm.

[0011] The protective layer is a metal nitride layer; the thickness of the protective layer is 1.5 - 3 nm.

[0012] The fourth dielectric layer is an AZO layer; the thickness of the fourth dielectric layer is 5 - 10 nm.

[0013] The fifth dielectric layer is a non - metal nitride layer; the thickness of the fifth dielectric layer is 25 - 30 nm.

[0014] The sixth dielectric layer is a metal nitride layer; the thickness of the sixth dielectric layer is 25 - 30 nm.

[0015] The light blue ultra - high - transmittance single - silver glass preferably comprises, from bottom to top in sequence: a glass substrate, a silicon nitride layer, a zinc oxide tin layer, a zinc oxide layer, a silver layer, a nickel chromium nitride layer, an AZO layer, a silicon nitride layer, and a silicon aluminum zirconium nitride layer.

[0016] In the light blue ultra - high - transmittance single - silver glass provided by the present utility model, the first dielectric layer, the second dielectric layer, and the third dielectric layer are anti - reflection film layers, which play a role in connecting the glass substrate and the functional silver layer, can effectively prevent Na⁺ in the glass substrate from penetrating into other film layers, have good bonding performance between each film layer and the glass, and can relieve the internal stress of the entire low - emissivity film; the protective layer can play a good protective role for the silver layer; the fourth dielectric layer is an AZO layer, and the AZO layer is formed by using an AZO target, and it has a lower resistance and can significantly improve the transmittance of the glass; the three dielectric layers above the protective layer can ensure that the single - silver glass has excellent scratch - resistance, wear - resistance, oxidation - resistance, and corrosion - resistance performances.

[0017] Compared with the prior art, the present utility model has the following beneficial effects:

[0018] The appearance of the light blue ultra - high - transmittance single - silver glass provided by the present utility model is light blue, and its transmittance is as high as over 86%, having an extremely high visible light transmittance. After use, it can make the indoor light bright, the field of vision wide, and the daylighting effect excellent; its reflectance is relatively high, which can effectively block the external heat from entering the room and at the same time reduce the heat dissipation in the room, achieving a good heat - insulation effect, and it is suitable for popularization to civil buildings. BRIEF DESCRIPTION OF THE DRAWINGS

[0019] Figure 1Schematic diagram of the structure of the light blue ultra-high transmittance single silver glass in the present utility model. In the figure, 1 - glass substrate, 2 - first dielectric layer, 3 - second dielectric layer, 4 - third dielectric layer, 5 - silver layer, 6 - protective layer, 7 - fourth dielectric layer, 8 - fifth dielectric layer, 9 - sixth dielectric layer. Specific implementation mode

[0020] The present utility model provides a light blue ultra-high transmittance single silver glass, which sequentially includes from bottom to top: a glass substrate, a first dielectric layer, a second dielectric layer, a third dielectric layer, a silver layer, a protective layer, a fourth dielectric layer, a fifth dielectric layer, and a sixth dielectric layer.

[0021] The first dielectric layer is a non-metallic nitride layer; the thickness of the first dielectric layer is 25 - 35 nm.

[0022] The second dielectric layer is a metal oxide layer; the thickness of the second dielectric layer is 10 - 15 nm.

[0023] The third dielectric layer is a metal oxide layer; the thickness of the third dielectric layer is 10 - 15 nm.

[0024] The thickness of the silver layer is 5 - 10 nm.

[0025] The protective layer is a metal nitride layer; the thickness of the protective layer is 1.5 - 3 nm.

[0026] The fourth dielectric layer is an AZO layer; the thickness of the fourth dielectric layer is 5 - 10 nm.

[0027] The fifth dielectric layer is a non-metallic nitride layer; the thickness of the fifth dielectric layer is 25 - 30 nm.

[0028] The sixth dielectric layer is a metal nitride layer; the thickness of the sixth dielectric layer is 25 - 30 nm.

[0029] The present utility model will be described in detail below in conjunction with the embodiments.

[0030] Embodiment 1

[0031] A light blue ultra-high transmittance single silver glass, which sequentially includes from bottom to top: white float glass, a 25-nm-thick silicon nitride layer, an 11-nm-thick zinc oxide tin layer, a 14-nm-thick zinc oxide layer, a 5-nm-thick silver layer, a 2.0-nm-thick nickel chromium nitride layer, a 5-nm-thick AZO layer, a 25-nm-thick silicon nitride layer, and a 30-nm-thick silicon aluminum zirconium nitride layer.

[0032] Embodiment 2

[0033] A light blue ultra-high-transmittance single-silver glass, which sequentially includes from bottom to top: a white float glass, a 30-nm thick silicon nitride layer, a 15-nm thick zinc oxide tin layer, a 10-nm thick zinc oxide layer, an 8-nm thick silver layer, a 1.5-nm thick nickel chromium nitride layer, a 5-nm thick AZO layer, a 30-nm thick silicon nitride layer, and a 30-nm thick silicon aluminum zirconium nitride layer.

[0034] Example 3

[0035] A light blue ultra-high-transmittance single-silver glass, which sequentially includes from bottom to top: a white float glass, a 35-nm thick silicon nitride layer, a 15-nm thick zinc oxide tin layer, a 10-nm thick zinc oxide layer, a 10-nm thick silver layer, a 3-nm thick nickel chromium nitride layer, a 9-nm thick AZO layer, a 25-nm thick silicon nitride layer, and a 30-nm thick silicon aluminum zirconium nitride layer.

[0036] The colors of the light blue ultra-high-transmittance single-silver glass in the above-mentioned examples are shown in Table 1.

[0037] Table 1

[0038]

[0039] As can be seen from Table 1 above, the transmitted colors of the ultra-high-transmittance single-silver glass in the embodiments of the present invention are all light yellow, the reflected colors are all light blue, and the transmittance Tr is above 86%.

[0040] The detailed description of a light blue ultra-high-transmittance single-silver glass with reference to the embodiments above is illustrative rather than restrictive. Several embodiments can be listed within the defined scope. Therefore, changes and modifications without departing from the overall concept of the present invention shall fall within the protection scope of the present invention.

Claims

1. A light blue ultra-high transmittance single silver glass, characterized in that, The light blue ultra-high transmittance single silver glass comprises, from bottom to top, a glass substrate, a first dielectric layer, a second dielectric layer, a third dielectric layer, a silver layer, a protective layer, a fourth dielectric layer, a fifth dielectric layer, and a sixth dielectric layer.

2. The light blue ultra-high-transparency single-silver glass according to claim 1, wherein The first dielectric layer is a non-metallic nitride layer; the thickness of the first dielectric layer is 25 to 35 nm.

3. The light blue ultra-high-transmittance single-silver glass according to claim 1, wherein The second dielectric layer is a metal oxide layer; the thickness of the second dielectric layer is 10 to 15 nm.

4. The light blue ultra-high transmittance single silver glass according to claim 1, wherein The third dielectric layer is a metal oxide layer; the thickness of the third dielectric layer is 10 to 15 nm.

5. The light blue ultra-high transmittance single-silver glass according to claim 1, wherein The thickness of the silver layer is 5 to 10 nm.

6. The light blue ultra-high transmittance single silver glass according to claim 1, wherein, The protective layer is a metal nitride layer; the thickness of the protective layer is 1.5 to 3 nm.

7. The light blue ultra-high transmittance single silver glass according to claim 1, wherein, The fourth dielectric layer is an AZO layer; the thickness of the fourth dielectric layer is 5 to 10 nm.

8. The light blue ultra-high transmittance single-silver glass according to claim 1, characterized in that, The fifth dielectric layer is a non-metallic nitride layer; the thickness of the fifth dielectric layer is 25 to 30 nm.

9. The light blue ultra-high transmittance single silver glass according to claim 1, wherein, The sixth dielectric layer is a metal nitride layer; the thickness of the sixth dielectric layer is 25 to 30 nm.

10. The light blue ultra-high transmittance single silver glass according to any one of claims 1-9, characterized in that, The light blue ultra-high transmittance single silver glass comprises, from bottom to top, a glass substrate, a silicon nitride layer, a zinc oxide tin layer, a zinc oxide layer, a silver layer, a nickel chromium nitride layer, an AZO layer, a silicon nitride layer, and a silicon aluminum zirconium nitride layer.

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