A radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode

Abstract

The utility model relates to the field of self-supporting electrode application, concretely relates to a radiation preparation device suitable for active material in situ growth in self-supporting electrode. The in situ observation device includes radiation resistant stopper, radiation tube, high-conductivity self-supporting base, radiation resistant fine wire and connecting piece. The utility model provides the radiation preparation device of active material in situ growth in self-supporting electrode provided by the utility model, can avoid using binder when constructing electrode, exposes more electrode active sites, greatly improves the electrochemical performance of electrode active substance and the device of current device, can realize that active substance grows on the conductive self-supporting base evenly.

Description

TECHNICAL FIELD

[0001] The utility model relates to the application field of self-supporting electrode, specifically relates to a radiation preparation device suitable for active material in situ growth on self-supporting electrode. BACKGROUND

[0002] In the irradiation process of the aqueous solution system in the self-supporting electrode preparation process, in order to improve the yield, isopropyl alcohol needs to be added as an oxidative free radical scavenger in the aqueous solution system, and the added isopropyl alcohol can be oxidized or radiolyzed into a small amount of by-products such as CH3COO- and CH3. The by-products can be adsorbed on the surface of the powdery active material, covering the active sites. In addition, when the powdery active material is used to build an electrode, a binder (Nafion, PTFE or PVDF reagent) needs to be added to improve the stability. The addition of the binder can increase the resistance of the electrode and cover the active sites, greatly reducing the electrochemical performance of the electrode active material.

[0003] At present, in order to improve the electrochemical performance of the powdery active material, a highly conductive self-supporting substrate is directly added to the solution system, so that the active material can grow in situ on the self-supporting substrate, but the active material is difficult to grow uniformly on the conductive self-supporting substrate.

[0004] Therefore, it is necessary to design a radiation preparation device suitable for active material in situ growth on self-supporting electrode to overcome the above technical problems. UTILITY MODEL CONTENTS

[0005] The utility model aims at providing a radiation preparation device suitable for active material in situ growth on self-supporting electrode to solve the problems raised in the above background technology.

[0006] To achieve the above-mentioned purpose, the utility model provides the following technical scheme:

[0007] A radiation preparation device suitable for active material in situ growth on self-supporting electrode, comprising a radiation-resistant plug 1, an irradiation tube 2, a highly conductive self-supporting substrate 3, a radiation-resistant fine wire 4 and a connecting piece 5.

[0008] The irradiation tube 2 is a transparent tube body with one end open;

[0009] One end of the radiation-resistant fine wire 4 is fixed to the highly conductive self-supporting substrate 3, and the other end is fixed to the bottom end of the connecting piece 5; the top end of the connecting piece 5 is inserted into the radiation-resistant plug 1; the radiation-resistant plug 1 covers the opening of the irradiation tube 2, sealing the irradiation tube 2;

[0010] The radiation-resistant thin wire 4 is fixed above the high-conductivity self-supporting substrate 3, and the self-supporting substrate 3 is perpendicular to the active material precursor aqueous solution by the gravity of the high-conductivity self-supporting substrate 3, so that the active material is uniformly grown on the conductive self-supporting substrate.

[0011] The connecting piece 5 is inserted into the radiation-resistant plug 1, and the distance of the connecting piece 5 inserted into the radiation-resistant rubber plug 1 is used to adjust the distance between the self-supporting substrate 3 and the active material precursor aqueous solution, so that the active material is more uniformly grown on the conductive self-supporting substrate.

[0012] Preferably, the radiation-resistant plug 1 is a conical rubber plug or a conical silica gel plug.

[0013] Preferably, the irradiation tube 2 is a glass test tube.

[0014] Preferably, the radiation-resistant thin wire 4 is an iron wire or a textile wire.

[0015] Preferably, the connecting piece 5 is a sewing needle, and the radiation-resistant thin wire 4 is connected at the threading position of the sewing needle.

[0016] Further, the sewing needle penetrates the radiation-resistant plug 1 from the top, so that the distance of the radiation-resistant rubber plug 1 is adjusted without removing the radiation-resistant plug 1.

[0017] Further, the irradiation tube 2 is 10-20 cm high and 1-5 cm in diameter.

[0018] Further, the radiation-resistant plug 1 has an upper hole diameter of 1-4 cm, a lower hole diameter of 0.5-2 cm, and a height of 1-3 cm.

[0019] Further, the radiation-resistant thin wire 4 is 10-20 cm long and 1-5 mm in diameter.

[0020] Further, the connecting piece 5 is 5-10 cm long.

[0021] The active material in-situ growth on the self-supporting electrode of the radiation preparation device provided by the utility model can avoid using adhesive when constructing the electrode, expose more electrode active sites, and greatly improve the electrochemical performance of the electrode active material.

[0022] 1) The active material in-situ growth on the self-supporting electrode of the radiation preparation device provided by the utility model can avoid using adhesive when constructing the electrode, expose more electrode active sites, and greatly improve the electrochemical performance of the electrode active material.

[0023] 2) The active material in-situ growth on the self-supporting electrode of the radiation preparation device provided by the utility model can realize uniform growth of the active material on the conductive self-supporting substrate. BRIEF DESCRIPTION OF DRAWINGS

[0024] Figure 1It is the radiation preparation device layout schematic diagram that the active material in situ growth of embodiment 1 described in the utility model is in self-supporting electrode. DETAILED DESCRIPTION

[0025] The technical scheme of the utility model will be described clearly and completely by embodiments in combination with drawings. Based on the embodiments in the utility model, all other embodiments obtained by the person skilled in the art without creative labor are within the protection scope of the utility model.

[0026] Embodiment 1

[0027] As Figure 1 shown, a kind of radiation preparation device suitable for active material in situ growth of self-supporting electrode, including radiation-resistant plug 1, irradiation tube 2, high-conductivity self-supporting substrate 3, radiation-resistant fine line 4 and connecting piece 5;

[0028] The irradiation tube 2 is round mouth type transparent material, and the radiation-resistant fine line 4 is fixed in high-conductivity self-supporting substrate 3 in one section, and the other end is fixed in connecting piece 5, and connecting piece 5 is inserted into radiation-resistant rubber plug 1;

[0029] The radiation-resistant fine line 4 is fixed in high-conductivity self-supporting substrate 3 in one section, and the gravity of high-conductivity self-supporting substrate 3 is used, so that active material is evenly grown on the conductive self-supporting substrate from the high-conductivity supporting substrate 3 perpendicular to the active substance precursor aqueous solution;

[0030] Connecting piece 5 is inserted into radiation-resistant plug 1, and the distance that connecting piece 5 is inserted into radiation-resistant rubber plug 1 can be used to adjust the distance between self-supporting substrate 3 and active substance precursor aqueous solution, so that active material is more evenly grown on the conductive self-supporting substrate.

[0031] The irradiation plug 1 is rubber plug with upper aperture 2cm, lower aperture 1cm and height 2cm;The irradiation tube 2 is glass test tube with height 15cm and diameter 1.5cm;The radiation-resistant fine line 4 is textile line with height 10cm and diameter 1mm;Connecting piece 5 is embroidery needle.

[0032] Using the embodiment, the use of adhesive when constructing electrode can be avoided, more electrode active sites are exposed, the electrochemical performance of electrode active substance is greatly improved, and active substance can be evenly grown on the conductive self-supporting substrate.

[0033] The above only describes the embodiment of the utility model, and does not limit the protection scope of the utility model, and equivalent structure or equivalent process conversion using the content of the utility model specification, or direct or indirect application in other related technical fields, are also included in the protection scope of the utility model.

Claims

1. A radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode, characterized in that, It comprises a radiation-resistant plug (1), a radiation tube (2), a highly conductive self-supporting substrate (3), a radiation-resistant thin wire (4) and a connecting piece (5). The radiation tube (2) is a transparent tube body with one end open. The radiation-resistant thin wire (4) is fixed at one end of the highly conductive self-supporting substrate (3) and at the other end of the bottom end of the connecting piece (5); the top end of the connecting piece (5) is inserted into the radiation-resistant plug (1); the radiation-resistant plug (1) covers the opening of the radiation tube (2) to seal the radiation tube (2); The radiation-resistant thin wire (4) is fixed above the highly conductive self-supporting substrate (3), and the self-supporting substrate (3) is perpendicular to the active substance precursor aqueous solution by the gravity of the highly conductive self-supporting substrate (3), so that the active substance grows uniformly on the conductive self-supporting substrate; The connecting piece (5) is inserted into the radiation-resistant plug (1), and the distance between the connecting piece (5) and the radiation-resistant plug (1) is used to adjust the distance between the self-supporting substrate (3) and the active substance precursor aqueous solution, so that the active substance grows more uniformly on the conductive self-supporting substrate.

2. The radiation fabrication device suitable for in-situ growth of active material on a self-supporting electrode according to claim 1, wherein, The radiation-resistant plug (1) is a conical rubber plug or a conical silica gel plug. 3.The radiation preparation device suitable for in-situ growth of active materials on self-supporting electrodes according to claim 1, characterized in that, The radiation tube (2) is a glass test tube. 4.The radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode according to claim 1, wherein, The radiation-resistant thin wire (4) is an iron wire or a textile wire. 5.The radiation preparation device suitable for in-situ growth of active materials on self-supporting electrodes according to claim 1, wherein, The connecting piece (5) is a sewing needle, and the radiation-resistant thin wire (4) is connected at the sewing needle threading position. 6.The radiation preparation device suitable for in-situ growth of active materials on self-supporting electrodes according to claim 5, characterized in that, The sewing needle penetrates the radiation-resistant plug (1) from the top.

7. The radiation preparation device suitable for in-situ growth of active material on a self-supporting electrode according to claim 6, characterized in that, The radiation tube (2) is 10-20 cm high and 1-5 cm in diameter. 8.The radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode according to claim 7, wherein, The radiation-resistant plug (1) has an upper hole diameter of 1-4 cm, a lower hole diameter of 0.5-2 cm, and a height of 1-3 cm. 9.The radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode according to claim 8, characterized in that, The radiation-resistant thin wire (4) is 10-20 cm long and 1-5 mm in diameter. 10.The radiation preparation device suitable for in-situ growth of active materials on a self-supporting electrode according to claim 9, wherein, The connecting piece (5) is 5-10 cm long.

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