Surrounding type anode titanium basket and carbon fiber metal electro-deposition device

By designing a surrounding titanium anode basket, the problems of uneven coating and uneven electric field distribution in carbon fiber metal electrodeposition were solved, achieving uniform coating and efficient current utilization, and reducing metal waste and anode sludge accumulation.

CN224133232UActive Publication Date: 2026-04-17SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
Filing Date
2025-05-23
Publication Date
2026-04-17

AI Technical Summary

Technical Problem

Traditional titanium baskets for anodes result in uneven coating thickness and uneven distribution of electric field lines during carbon fiber metal electrodeposition. This leads to a thicker coating on the lower part of the carbon fiber bundle and a thinner coating on the upper part. Furthermore, the metal above the titanium basket dissolves quickly, generating anode sludge that affects current efficiency.

Method used

A ring-shaped anode titanium basket is used, designed as a ring-shaped tubular frame with a titanium screen fixed on the surface. The anode metal is filled inside, and the carbon fiber moves near the axis of the titanium basket to form uniformly diverging electric lines. The cations are evenly distributed around the carbon fiber, and uniform metal electrodeposition is completed through the electric field force.

Benefits of technology

It achieves uniform thickness of carbon fiber metal coating, reduces coating unevenness and black core problems, improves current efficiency, reduces metal waste, and improves electric field distribution and tip discharge effect.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model discloses a surrounding type anode titanium basket and a carbon fiber metal electro-deposition device. The surrounding type anode titanium basket comprises a conductive supporting frame and a titanium basket main body, the titanium basket main body is of an annular cylindrical structure, and the conductive supporting frame and the titanium basket main body are fixed and electrically connected; a containing cavity used for containing anode metal materials is formed in the titanium basket body, an anode metal material filling opening and a plurality of hole-shaped structures are further arranged on the surface of the titanium basket body, and the anode metal material filling opening and the hole-shaped structures are both communicated with the containing cavity. The central area of the titanium basket main body is provided with a hole cavity structure which is integrally enclosed by the titanium basket main body and is provided with two open ends, and the titanium basket main body is also provided with a gap which is directly communicated with the hole cavity structure. According to the annular anode titanium basket provided by the embodiment of the utility model, the problem that anode mud is accumulated and blocked in the titanium basket is solved, the metal electro-deposition current efficiency is improved, and the utilization rate of soluble anode metal is increased.
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Description

Technical Field

[0001] This utility model specifically relates to a circumferential anode titanium basket and a carbon fiber metal electrodeposition device, belonging to the field of electrodeposition technology. Background Technology

[0002] Carbon fiber metallization involves coating the surface of carbon fibers with a uniform thickness of metal or alloy. The main reaction apparatus is an electrodeposition tank, including conductive cathode rollers and anode titanium baskets. The carbon fiber is in contact with the cathode rollers at both ends of the electrodeposition tank, providing electrical conductivity. The portion of the carbon fiber immersed in the plating solution serves as the workpiece to be plated. The soluble metal to be plated, filled within the titanium basket, acts as the anode. Under energized conditions, precipitated cations enter the plating solution and move towards the carbon fiber bundle. The metal cations gain electrons on the carbon fiber surface, are reduced to metal particles, and deposit to form the coating.

[0003] Traditional anode titanium baskets are rectangular frames placed at the bottom of the electrodeposition tank, with carbon fibers suspended directly above the basket and submerged near the surface of the plating solution. Due to the relative positions of the carbon fibers and the basket, the electric field lines are unevenly distributed; they are denser below the carbon fiber bundle and denser above the basket. The lower part of the carbon fiber bundle accumulates more electrons, resulting in a stronger cation absorption capacity and a thicker coating. Conversely, the upper part has sparser electric field lines, fewer electrons, and a weaker cation absorption capacity, resulting in a thinner coating. This leads to uneven coating thickness and black cores within the carbon fiber bundle. Furthermore, the denser electric field lines above the basket cause the metal to dissolve quickly. The anolyte produced by the dissolution of the upper metal covers the surface of the undissolved metal below, affecting cation deposition, reducing current efficiency, and wasting the metal to be plated. Utility Model Content

[0004] The main objective of this invention is to provide a circumferential titanium anode basket and a carbon fiber metal electrodeposition device. The main body of the titanium basket is an annular tubular frame with a titanium screen fixed on its surface. The cavities between the screens are filled with soluble anode metal. Current is transmitted to the metal to be plated through the titanium basket screen. The carbon fiber moves at a constant speed near the axis of the titanium basket, and the distance between the carbon fiber and each point on the titanium basket is approximately equal, forming uniformly diverging electric field lines. The anode metal loses electrons and releases cations into the plating solution, which are uniformly distributed around the carbon fiber bundles. Under the action of the electric field, the cations move towards the surface of the carbon fiber and gain electrons to complete the metal electrodeposition, resulting in a coating of uniform thickness, thereby overcoming the shortcomings of the prior art.

[0005] To achieve the aforementioned objectives, the technical solution adopted by this utility model includes:

[0006] The first aspect of this utility model provides a circumferential anode titanium basket, which includes: a conductive support frame and a titanium basket body, wherein the titanium basket body is a circular cylindrical structure, and the conductive support frame is fixed and electrically connected to the titanium basket body;

[0007] The interior of the titanium basket body has a receiving cavity for accommodating the anode metal material, and the surface of the titanium basket body is also provided with an anode metal material filling port and a plurality of perforated structures, the anode metal material filling port and the perforated structures being connected to the receiving cavity;

[0008] The central region of the titanium basket body has a cavity structure with open ends formed by its own overall enclosure. Furthermore, the titanium basket body is provided with a slit that directly communicates with the cavity structure. The slit allows carbon fibers to enter and exit the cavity structure radially along the titanium basket body, and the cavity structure allows carbon fibers to pass continuously along their own axial direction.

[0009] A second aspect of this utility model provides a carbon fiber metal electrodeposition apparatus, comprising:

[0010] An electrodeposition reaction tank, which is used to contain the electroplating mother liquor and provide space for the electrodeposition reaction to occur;

[0011] A cathode roller assembly, comprising two conductive cathode rollers, wherein the two cathode rollers are respectively disposed on both sides of the electrodeposition reaction tank along a first direction;

[0012] The surrounding anode titanium basket is disposed in the electrodeposition reaction tank, and the axial direction of the main body of the surrounding anode titanium basket is parallel to the first direction.

[0013] A power source, the positive terminal of which is electrically connected to the surrounding anode titanium basket, and the negative terminal of which is electrically connected to the two cathode rollers.

[0014] Compared with the prior art, the advantages of this utility model include:

[0015] This utility model provides a carbon fiber metal electrodeposition device, which innovates the design of the carbon fiber metallization anode device by proposing an annular anode titanium basket. The anode titanium basket has an annular barrel-shaped structure. The carbon fiber moves near the axis of the annular anode titanium basket. Under the condition of energization, electric field lines are uniformly distributed from far to near the carbon fiber bundle as the center. The cations are uniformly distributed around the carbon fiber under the action of the electric field force, so that the electron distribution on each filament in the carbon fiber bundle is uniform and the cation attraction ability is equal. Each carbon fiber can obtain a metal coating of uniform thickness, which solves the problems of uneven metal coating and black core of carbon fiber. At the same time, the optimized distribution of electric field lines also improves the tip discharge effect of carbon fiber and reduces the problem of fuzz on the fiber surface after metal deposition.

[0016] The present invention provides an annular anode titanium basket that solves the problem of anode mud accumulation and obstruction inside the titanium basket, improves the efficiency of metal electrodeposition current, and increases the utilization rate of soluble anode metal. Attached Figure Description

[0017] To more clearly illustrate the technical solutions in the embodiments of this application or the prior art, the drawings used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings described below are only some embodiments recorded in this application. For those skilled in the art, other drawings can be obtained based on these drawings without creative effort.

[0018] Figure 1 This is an overall top view of a carbon fiber metal electrodeposition device provided in a typical embodiment of this utility model;

[0019] Figure 2 This is a schematic diagram of the structure of a carbon fiber metal electrodeposition component provided in a typical embodiment of this utility model;

[0020] Figure 3 This is a schematic diagram of the structure of an annular anode titanium basket provided in a typical embodiment of this utility model. Detailed Implementation

[0021] In view of the shortcomings of the prior art, the inventor of this case, through long-term research and extensive practice, has come up with the technical solution of this utility model. The following will further explain the technical solution, its implementation process, and its principles.

[0022] The first aspect of this utility model provides a circumferential anode titanium basket, which includes: a conductive support frame and a titanium basket body, wherein the titanium basket body is a circular cylindrical structure, and the conductive support frame is fixed and electrically connected to the titanium basket body;

[0023] The interior of the titanium basket body has a receiving cavity for accommodating the anode metal material, and the surface of the titanium basket body is also provided with an anode metal material filling port and a plurality of perforated structures, the anode metal material filling port and the perforated structures being connected to the receiving cavity;

[0024] The central region of the titanium basket body has a cavity structure with open ends formed by its own overall enclosure. Furthermore, the titanium basket body is provided with a slit that directly communicates with the cavity structure. The slit allows carbon fibers to enter and exit the cavity structure radially along the titanium basket body, and the cavity structure allows carbon fibers to pass continuously along their own axial direction.

[0025] Furthermore, the plurality of the pore-like structures are distributed on a plurality of concentric circumferences or a plurality of coaxial cylindrical surfaces, the centers of the plurality of circumferences being located on the axis of the titanium basket body, or the plurality of cylindrical surfaces being coaxial with the titanium basket body.

[0026] Furthermore, the titanium basket body has an inner ring surface, an outer ring surface, a first end face, a second end face, a first side face, and a second side face. The outer ring surface surrounds the periphery of the inner ring surface. The first end face and the second end face are located at both ends of the titanium basket body along the axial direction. The first side face and the second side face are spaced apart along the circumference of the titanium basket. The gap is located between the first side face and the second side face. The first side face and the second side face are closed structures. The perforated structure is distributed on the inner ring surface, the outer ring surface, the first end face, and the second end face.

[0027] Furthermore, the shapes and sizes of multiple pore-like structures located on the same circumference or the same cylindrical surface are all identical.

[0028] Furthermore, the titanium basket body includes a non-closed inner ring screen, a non-closed outer ring screen, a first end face screen, a second end face screen, a first side plate, and a second side plate. The outer ring screen is arranged around the periphery of the inner ring screen. The first end face screen and the second end face screen are located at both ends of the inner ring screen and the outer ring screen along the axial direction of the inner ring screen, and are fixedly connected to the inner ring screen and the outer ring screen. The first side plate and the second side plate are respectively fixed to the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The first side plate and the second side plate are arranged at intervals along the circumference of the inner ring screen. The inner ring screen, the outer ring screen, the first end face screen, the second end face screen, the first side plate, and the second side plate surround to form the annular receiving cavity. The inner ring screen surrounds to form the cavity structure. The gap is formed between the first side plate and the second side plate. The hole structure is the mesh of the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The conductive support frame is fixedly connected to the outer ring screen.

[0029] Furthermore, the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen are all non-closed annular structures.

[0030] Furthermore, the main body of the titanium basket is a non-closed annular structure.

[0031] Furthermore, the width of the gap along the circumference of the titanium basket is 1cm to 2cm.

[0032] Furthermore, the width of the receiving cavity along the radial direction of the titanium basket body is 3cm to 5cm.

[0033] A second aspect of this utility model provides a carbon fiber metal electrodeposition apparatus, comprising:

[0034] An electrodeposition reaction tank, which is used to contain the electroplating mother liquor and provide space for the electrodeposition reaction to occur;

[0035] A cathode roller assembly, comprising two conductive cathode rollers, wherein the two cathode rollers are respectively disposed on both sides of the electrodeposition reaction tank along a first direction;

[0036] The surrounding anode titanium basket is disposed in the electrodeposition reaction tank, and the axial direction of the main body of the surrounding anode titanium basket is parallel to the first direction.

[0037] A power source, the positive terminal of which is electrically connected to the surrounding anode titanium basket, and the negative terminal of which is electrically connected to the two cathode rollers.

[0038] In a more specific embodiment, the carbon fiber metal electrodeposition apparatus further includes: a guide roller group, the guide roller group including a plurality of guide rollers disposed in the electrodeposition reaction tank, the plurality of guide rollers being disposed on both sides of the surrounding anode titanium basket along the first direction, the guide roller group being used to guide carbon fibers through the cavity structure of the surrounding anode titanium basket.

[0039] In a more specific embodiment, the carbon fiber metal electrodeposition apparatus further includes: a pay-off roller assembly and a take-up roller assembly. The pay-off roller assembly is disposed upstream of the electrodeposition reaction tank, and the take-up roller assembly is disposed downstream of the electrodeposition reaction tank. The pay-off roller assembly is used to pay off one or more rolls of carbon fiber, ensuring that each roll of carbon fiber maintains the same pay-off rate and tension. The take-up roller assembly is used to pull the carbon fiber, causing the carbon fiber to travel along the first direction and through the electrodeposition reaction tank, and to collect the carbon fiber after the selected metal electrodeposition is completed.

[0040] In a more specific embodiment, the carbon fiber metal electrodeposition apparatus further includes: a pretreatment component and a posttreatment component, wherein the pretreatment component is disposed between the pay-off roller assembly and the electrodeposition reaction tank, and the posttreatment component is disposed between the electrodeposition reaction tank and the take-up roller assembly; the pretreatment component is used to remove sizing agent from the surface of the carbon fiber and / or to clean the carbon fiber; and the posttreatment component is used to clean and dry the carbon fiber after metal electrodeposition treatment.

[0041] The following will provide a further explanation of the technical solution, its implementation process, and its principles, in conjunction with the accompanying drawings and specific implementation examples.

[0042] In a more typical implementation scheme, please refer to Figure 1A carbon fiber metal electrodeposition apparatus includes a pay-off roller assembly 100, a pretreatment assembly 200, an electrodeposition reaction assembly 300, a post-treatment assembly 400, and a take-up roller assembly 500 arranged sequentially along a first direction. The pay-off roller assembly 100 and the take-up roller assembly 500 cooperate to realize the pay-off and take-up of carbon fiber 600, so that the carbon fiber 600 can travel continuously along the first direction, and the carbon fiber 600 passes sequentially from the pay-off roller assembly 100 through the pretreatment assembly 200, the electrodeposition reaction assembly 300, and the post-treatment assembly 400, and is finally wound onto the take-up roller assembly 500. The pretreatment assembly 200 is used to pretreat the carbon fiber, the electrodeposition reaction assembly 300 is used to perform metal electrodeposition on the carbon fiber, and the post-treatment assembly 400 is used to post-treat the carbon fiber 600 after metal electrodeposition.

[0043] Specifically, the structures of the pay-off roller assembly 100, pretreatment assembly 200, posttreatment assembly 400 and take-up roller assembly 500 in this application are all known in the art and are not considered improvements to the present invention. Therefore, only a simple overview and description of their structures are given below.

[0044] Specifically, the pay-off roller assembly 100 is used to pay off one or more rolls of carbon fiber, and the take-up roller assembly 500 is used to take up one or more rolls of carbon fiber. As known to those skilled in the art, the pay-off roller assembly 100 generally includes one or more freely rotatable pay-off rollers, which are used to fix the carbon fiber rolls, and the carbon fiber rolls can rotate together with the pay-off rollers. Preferably, the pay-off roller assembly 100 may also include a speed adjustment mechanism for adjusting the speed of the pay-off rollers, etc., and by adjusting the speed of the pay-off rollers, the tension and pay-off rate of the carbon fiber during travel can be adjusted. Preferably, the pay-off roller assembly 100 may also include a guide wheel for guiding the carbon fiber to maintain a straight line of travel, and the pay-off roller assembly 100 may also include a pay-off frame, on which the pay-off rollers and guide wheels can be mounted. The take-up roller assembly 500 generally includes one or more take-up rollers and a rotary drive mechanism, which are connected in a transmission manner. The take-up rollers can rotate under the drive of the rotary drive mechanism to achieve the traction and collection of carbon fiber / metal composite fibers. Preferably, the take-up roller assembly 500 may further include a guide wheel for guiding the carbon fiber 600 to maintain a straight path, and the take-up roller assembly 500 may further include a take-up frame, on which the take-up roller and the guide wheel may be mounted.

[0045] Specifically, the pretreatment component 200 is used to remove the sizing agent from the surface of the carbon fibers and / or to clean the carbon fibers, i.e., the aforementioned pretreatment. For example, the pretreatment component 200 may include a high-temperature treatment chamber, a pre-impregnation tank, and / or a spraying mechanism, etc., whereby the high-temperature treatment chamber is used to remove the sizing agent from the surface of the carbon fibers, and the pre-impregnation tank and / or the spraying mechanism is used to clean the carbon fibers. Specifically, the post-treatment component 400 is used to clean and dry the carbon fibers after metal electrodeposition treatment. Specifically, the post-treatment component 400 may include a washing mechanism and an oven, etc.

[0046] Please refer to the following: Figure 1 , Figure 2 The electrodeposition reaction assembly 300 includes an electrodeposition reaction tank 310, two cathode rollers 320, four guide rollers 330, an anode titanium basket 340, and a power supply. The two cathode rollers 320 are arranged on both sides of the electrodeposition reaction tank 310 along a first direction. The anode titanium basket 340 is arranged inside the electrodeposition reaction tank 310. The four guide rollers 330 are spaced apart on both sides of the anode titanium basket 340 along the first direction, with two on each side. The two cathode rollers 320 and the four guide rollers 330 together restrict the movement of the carbon fiber in the electrodeposition reaction tank 310 and allow the carbon fiber to pass through the anode titanium basket 340 along the axial direction within the electrodeposition reaction tank 310, especially allowing the carbon fiber to pass through the central region of the anode titanium basket 340. At the same time, the four guide rollers 330 can also adjust the tension of the carbon fiber.

[0047] Please refer to the following for details. Figure 1 and Figure 2 The cathode roller 320 is made entirely of conductive material. Its end is connected to the negative terminal of the power supply, and its surface is in close contact with the carbon fiber, which then absorbs electrons and acts as the cathode. Specifically, the cathode roller 320 can rotate around its own axis to reduce wear between the cathode roller 320 and the carbon fiber. More specifically, to ensure that the carbon fiber and the surface of the cathode roller 320 remain in contact, a limiting rod 350 is correspondingly provided above each cathode roller 320. The limiting rod 350 is arranged parallel to the cathode roller 320 and is used to compress the carbon fiber, keeping it in contact with the roller surface of the cathode roller 320. To reduce wear on the carbon fiber caused by the limiting rod 350, it is designed to rotate around its own axis. For example, the limiting rod 350 can be a sponge rod, etc.

[0048] Specifically, the guide roller 330 is made of insulating, corrosion-resistant, and high-temperature-resistant material. Its shaft is equipped with a bearing, allowing it to rotate passively to reduce contact friction with the carbon fiber and improve the surface fuzziness of the carbon fiber. After passing through multiple conductive rollers 330, the carbon fiber reverses its direction of travel and is completely immersed in the electroplating mother liquor within the electrodeposition reaction tank 310. The surface and interior of the carbon fiber are in full contact with the electroplating mother liquor. The compression by the guide rollers 330 and the immersion in the solution allow air bubbles on the carbon fiber surface to detach promptly, reducing the porosity of the coating and improving the corrosion resistance of the metal composite fiber.

[0049] Please refer to the following for details. Figure 2 and Figure 3 The anode titanium basket 340 includes a conductive support frame 341 and a titanium basket body 342. The conductive support frame 341 is fixed and electrically connected to the titanium basket body 342. The conductive support frame 341 is suspended or fixed on the electrodeposition reaction tank 310 and electrically connected to the positive terminal of the power supply. The titanium basket body 342 is a hollow, non-closed annular structure. The interior of the titanium basket body 342 is used to accommodate the anode metal material 700. The central area of ​​the titanium basket body 342 allows the electroplating mother liquor to be immersed and the carbon fiber to pass through. The anode metal material is filled in the annular titanium basket body 342. The dissolved metal cations are uniformly dispersed into the electroplating mother liquor and, with the cathode carbon fiber near its central axis, form an approximately annular electric field under the influence of electricity. The metal cations in the electroplating mother liquor are uniformly distributed around the carbon fiber monofilaments under the action of the electric field, gaining electrons from the surface of each carbon fiber to complete the metal electrodeposition on the carbon fiber surface.

[0050] Specifically, the interior of the titanium basket body 342 has a receiving cavity for accommodating the anode metal material. The surface of the titanium basket body 342 is also provided with an anode metal material filling port 3423 and multiple perforated structures. The anode metal material filling port and the perforated structures are all connected to the receiving cavity inside the basket body. The central region of the titanium basket body 342 has a perforated structure 3421 formed by the entire body and open at both ends. Furthermore, a slit 3422 is provided on the titanium basket body 342, which directly communicates with the perforated structure 3421. The slit 3422 allows carbon fibers to enter and exit the perforated structure 3421 along the radial direction of the titanium basket body 342, and the perforated structure 3421 allows carbon fibers to pass continuously along its own axial direction. The multiple perforated structures are distributed on multiple concentric circumferences or multiple coaxial cylindrical surfaces. The centers of the multiple circumferences are located on the axis of the titanium basket body 342, or the multiple cylindrical surfaces are coaxial with the titanium basket body 342. For example, the slit has a circumferential width of 1cm to 2cm, and the receiving cavity has a radial width of 3cm to 5cm.

[0051] In a typical implementation, the titanium basket body 342 can be a one-piece structure. More specifically, the titanium basket body 342 has an inner ring surface, an outer ring surface, a first end face, a second end face, a first side face, and a second side face. The outer ring surface surrounds the outer periphery of the inner ring surface. The first end face and the second end face are located at both ends of the titanium basket body 342 along the axial direction of the titanium basket body 342. The first side face and the second side face are spaced apart along the circumference of the titanium basket. The gap 3422 is located between the first side face and the second side face. The first side face and the second side face are closed structures. The perforated structures are distributed on the inner ring surface, the outer ring surface, the first end face, and the second end face. The multiple perforated structures located on the same circumference or the same cylindrical surface have the same shape and size.

[0052] In another typical implementation, the titanium basket body 342 includes a non-closed inner ring screen, a non-closed outer ring screen, a first end face screen, a second end face screen, a first side plate, and a second side plate. The outer ring screen is arranged around the periphery of the inner ring screen. The first end face screen and the second end face screen are located at both ends of the inner ring screen and the outer ring screen along the axial direction of the inner ring screen, and are fixedly connected to the inner ring screen and the outer ring screen. The first side plate and the second side plate are respectively fixedly connected to the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The first side plate and the second side plate are arranged along the inner ring screen. The mesh is circumferentially spaced, and the inner ring screen, the outer ring screen, the first end face screen, the second end face screen, the first side plate, and the second side plate enclose and form a circular receiving cavity. The inner ring screen encloses and forms the cavity structure. The gap 3422 is formed between the first side plate and the second side plate. The hole structure is the mesh holes on the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The conductive support frame 341 is fixedly connected to the outer ring screen. It can be understood that the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen are all non-closed circular ring structures.

[0053] This invention provides a carbon fiber metal electrodeposition apparatus, which innovatively designs a carbon fiber metallization anode device by proposing an annular anode titanium basket. The anode titanium basket has an annular barrel-shaped structure, and the carbon fibers move near the axis of the annular anode titanium basket. Under energized conditions, electric field lines are uniformly distributed from the carbon fiber bundle towards the near end. Cations are uniformly distributed around the carbon fibers under the influence of the electric field, resulting in uniform electron distribution on each individual fiber within the carbon fiber bundle and equal cation attraction capacity. Each carbon fiber can obtain a metal coating of uniform thickness, solving the problems of uneven metal coating and black core in carbon fiber. At the same time, the optimized distribution of electric field lines also improves the tip discharge effect of the carbon fibers and reduces the problem of fuzzy fibers on the fiber surface after metal deposition. In addition, the annular anode titanium basket provided by this invention also solves the problem of anode mud accumulation and obstruction inside the titanium basket, improving the metal electrodeposition current efficiency and increasing the utilization rate of soluble anode metal.

[0054] It should be understood that the above embodiments are merely illustrative of the technical concept and features of this utility model, and are intended to enable those skilled in the art to understand the content of this utility model and implement it accordingly. They should not be construed as limiting the scope of protection of this utility model. All equivalent changes or modifications made in accordance with the spirit and essence of this utility model should be covered within the scope of protection of this utility model.

Claims

1. A circumferential anode titanium basket, characterized in that, include: A conductive support frame and a titanium basket body, wherein the titanium basket body is a circular cylindrical structure, and the conductive support frame is fixed to and electrically connected to the titanium basket body; The interior of the titanium basket body has a receiving cavity for accommodating the anode metal material, and the surface of the titanium basket body is also provided with an anode metal material filling port and a plurality of perforated structures, the anode metal material filling port and the perforated structures being connected to the receiving cavity; The central region of the titanium basket body has a cavity structure with open ends formed by its own overall enclosure. Furthermore, the titanium basket body is provided with a slit that directly communicates with the cavity structure. The slit allows carbon fibers to enter and exit the cavity structure radially along the titanium basket body, and the cavity structure allows carbon fibers to pass continuously along their own axial direction.

2. The circumferential anode titanium basket of claim 1, wherein: The plurality of the aforementioned perforated structures are distributed on a plurality of concentric circumferences or a plurality of coaxial cylindrical surfaces, wherein the centers of the plurality of circumferences are located on the axis of the titanium basket body, or the plurality of cylindrical surfaces are coaxial with the titanium basket body.

3. The circumferential anode titanium basket according to claim 1 or 2, characterized in that: The titanium basket body has an inner ring surface, an outer ring surface, a first end face, a second end face, a first side face, and a second side face. The outer ring surface surrounds the outer periphery of the inner ring surface. The first end face and the second end face are located at both ends of the titanium basket body along the axial direction. The first side face and the second side face are spaced apart along the circumference of the titanium basket. The gap is located between the first side face and the second side face. The first side face and the second side face are closed structures. The perforated structure is distributed on the inner ring surface, the outer ring surface, the first end face, and the second end face. And / or, multiple pore-like structures located on the same circumference or the same cylindrical surface have the same shape and size.

4. The circumferential anode titanium basket of claim 3, wherein: The titanium basket body includes a non-closed inner ring screen, a non-closed outer ring screen, a first end face screen, a second end face screen, a first side plate, and a second side plate. The outer ring screen is arranged around the periphery of the inner ring screen. The first end face screen and the second end face screen are located at both ends of the inner ring screen and the outer ring screen along the axial direction of the inner ring screen, and are fixedly connected to the inner ring screen and the outer ring screen. The first side plate and the second side plate are respectively fixedly connected to the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The first side plate and the second side plate are spaced apart along the circumference of the inner ring screen. The inner ring screen, the outer ring screen, the first end face screen, the second end face screen, the first side plate, and the second side plate enclose and form the annular receiving cavity. The inner ring screen encloses and forms the cavity structure. The gap is formed between the first side plate and the second side plate. The hole structure is the mesh on the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen. The conductive support frame is fixedly connected to the outer ring screen. And / or, the inner ring screen, the outer ring screen, the first end face screen, and the second end face screen are all non-closed circular ring structures.

5. The circumferential anode titanium basket according to claim 1 or 4, characterized in that: The main body of the titanium basket is a non-closed annular structure.

6. The circumferential anode titanium basket according to claim 1 or 4, characterized in that: The width of the gap along the circumference of the titanium basket is 1cm to 2cm; And / or, the width of the receiving cavity along the radial direction of the titanium basket body is 3cm to 5cm.

7. A carbon fiber metal electrodeposition apparatus characterized by comprising: include: An electrodeposition reaction tank, which is used to contain the electroplating mother liquor and provide space for the electrodeposition reaction to occur; A cathode roller assembly, comprising two conductive cathode rollers, wherein the two cathode rollers are respectively disposed on both sides of the electrodeposition reaction tank along a first direction; The circumferential anode titanium basket according to any one of claims 1-6 is disposed in the electrodeposition reaction tank, wherein the axial direction of the main body of the circumferential anode titanium basket is parallel to the first direction; A power source, the positive terminal of which is electrically connected to the surrounding anode titanium basket, and the negative terminal of which is electrically connected to the two cathode rollers.

8. The carbon fiber metal electrodeposition apparatus of claim 7, wherein Also includes: A guide roller assembly, comprising multiple guide rollers disposed within the electrodeposition reaction tank, the multiple guide rollers being arranged along the first direction on both sides of the surrounding anode titanium basket, the guide roller assembly being used to guide carbon fibers through the cavity structure of the surrounding anode titanium basket.

9. The carbon fiber metal electrodeposition apparatus of claim 7, wherein Also includes: The assembly includes a pay-off roller assembly and a take-up roller assembly. The pay-off roller assembly is located upstream of the electrodeposition reaction tank, and the take-up roller assembly is located downstream of the electrodeposition reaction tank. The pay-off roller assembly is used to pay off one or more rolls of carbon fiber, ensuring that each roll of carbon fiber maintains the same pay-off rate and tension. The take-up roller assembly is used to pull the carbon fiber, causing it to travel along the first direction and through the electrodeposition reaction tank, and to collect the carbon fiber after the selected metal electrodeposition is completed.

10. The carbon fiber metal electrodeposition apparatus of claim 9, wherein Also includes: The pretreatment component and posttreatment component are provided. The pretreatment component is disposed between the pay-off roller assembly and the electrodeposition reaction tank, and the posttreatment component is disposed between the electrodeposition reaction tank and the take-up roller assembly. The pretreatment component is used to remove sizing agent from the surface of carbon fibers and / or to clean the carbon fibers. The posttreatment component is used to clean and dry the carbon fibers that have undergone metal electrodeposition treatment.