USE OF A POLYETHER-BASED URETHANE FOAM

Description

[Technical Field]

[0001] This disclosure relates to use of a polyether-based urethane foam impregnated with a cosmetic composition as a carrier for supporting and retaining the cosmetic composition.[Background Art]

[0002] In the old days, cosmetic compositions were used mainly indoors. However, as leisure activities have been generalized recently and modern life styles have been changed correspondingly, cosmetic compositions have been frequently used outdoors. Particularly, in the old days, UV protecting cosmetic compositions were used mostly in summer seasons. However, as modern people enjoy outdoor activities and recognize hazard of UV rays more and more, there is a tendency for UV protecting cosmetic compositions to be used frequently throughout all the seasons besides summer seasons. Therefore, there is an increasing need for cosmetic compositions convenient to use and easy to carry.

[0003] Polyester-based urethane foam was developed accidentally by a German technical specialist in the late 1940's during which development of plastics was in the midst. Since such urethane foam is based on polyester, it is also called ester foam. Producing such urethane foam requires no advanced technology. Thus, polyester-based urethane foam has been produced generally and used in various industrial fields, particularly those requiring strong tensile force.

[0004] However, polyester-based urethane foam tends to be broken easily under a wet environment. In addition, it has a microcellular structure and low air permeability, and thus shows low cushiony feel, softness and flexibility. As a result, polyester-based urethane foam is not suitable for use in impregnating a cosmetic composition, particularly a liquid cosmetic composition. Under these circumstances, there is an imminent need for developing urethane foam suitable for use in impregnating a cosmetic composition.[Disclosure][Technical Problem]

[0005] This disclosure is directed to providing use of a polyether-based urethane foam impregnated with a cosmetic composition as a carrier for supporting and retaining the cosmetic composition, the urethane foam being capable of maintaining high stability of the cosmetic composition and high post-impregnation stability.[Technical Solution]

[0006] In one general aspect, there is provided use of a polyether-based urethane foam impregnated with a cosmetic composition as defined in claim 1.[Advantageous Effects]

[0007] The polyether-based urethane foam disclosed herein maintains high stability even after carrying out impregnation with a cosmetic composition, and improves portability and touch feel of a cosmetic composition.[Description of Drawings]

[0008] Figure 1 is a microscopic view of wet polyether-based urethane foam; Figure 2 shows a packed make-up product in which a urethane foam impregnated with a W / O type emulsion make-up composition is enclosed; Figure 3 is a microscopic view of the urethane foams listed in Table 2, each magnified at 10 x 0.3; Figure 4 is a microscopic view of the urethane foams listed in Table 3, each magnified at 10 x 0.3; and Figure 5 shows photographs of Example 1, Comparative Example 1 and Comparative Example 2 after storing them at 50°C for 2 hours. [Mode for Invention]

[0009] In one aspect, there is provided use of a polyether-based urethane foam impregnated with a cosmetic composition as a carrier in which a cosmetic composition is supported and retained.

[0010] As used herein, the term 'urethane foam' means a foamed and solidified polyurethane resin, and is also referred to as 'foamed urethane'.

[0011] The polyether-based urethane foam is more resistant against humidity as compared to polyester-based urethane foam, and thus is not broken easily under a high-humidity condition and shows high stability. In addition, the polyether-based urethane foam has a larger cellular structure than polyester-based urethane foam, and thus has improved air permeability, cushiony feel, softness and flexibility. Further, the polyether-based urethane foam requires reduced cost for production, and thus has higher cost-efficiency than polyester-based urethane foam.

[0012] In one aspect, urethane foam may include dry urethane foam or wet urethane foam. Particularly, wet polyether-based urethane foam has the properties as shown in the following Table 1. [Table 1]ItemPore size200 µmSurface PropertiesHydrophilicASKER DUROMETER HARDNESS90Type C hardnessTensile strength15 kgf / cm 2< Elongation260%Apparent specific gravity (g / cm 3< )0.21Moisture holding ratio420%

[0013] In general, wet polyether-based urethane foam has a smaller pore size and more dense structure than dry polyether-based urethane foam. While dry polyether-based urethane foam has oleophilic surface properties, wet polyether-based urethane foam has hydrophilic surface properties as a result of wet foaming. Wet polyether-based urethane foam is continuous microporous urethane foam having uniform and high porosity, shows high water / oil absorbability, and produces no particles spontaneously. Figure 1 is a microscopic view of wet polyether-based urethane foam.

[0014] The urethane foam has a reticulated structure. In particular, the urethane foam has a reticulated structure that allows uniform and easy impregnation with a cosmetic composition and provides a high impregnation ratio.

[0015] The urethane foam has a density of 16.02 - 48.06 kg / m 3< (1 to 3 pounds per cubic feet (pcf)), particularly 16.02 - 32.04 kg / m 3< (1 to 2 pcf). When urethane foam has a density less than 16.02 kg / m 3< (1 pcf), a cosmetic composition may be liberated excessively and thus is not convenient to use. When urethane foam has a density higher than 48.06 kg / m 3< (3 pcf), it is not possible to provide a sufficient number of pores through which a cosmetic composition is impregnated, thereby making it difficult to impregnate a cosmetic composition effectively.

[0016] In one aspect, urethane foam may have a pore number of 2755.9 - 4724.4 pores per meter (70 to 120 pores per inch (ppi)), particularly 2952.7 - 3740.1 pores per meter (75 to 95 ppi). When urethane foam has a pore numer less than 2755.9 pores per meter (70 ppi), it has poor elasticity, is not convenient to use and is not amenable to control of the flowability of a cosmetic composition. When urethane foam has a pore number greater than 4724.4 pores per meter (120 ppi), it provides low durability and poor touch feel of a cosmetic composition during use.

[0017] In one aspect, urethane foam may have an ASKER hardness of 10 to 70, particularly 20 to 60, and more particularly 30 to 50 as measured by DUROMETER HARDNESS TESTER (Type F) available from ASKER. When urethane foam is too soft such that it has a hardness less than 10, a cosmetic composition impregnated in the urethane foam may be liberated excessively, while it is taken by cosmetic tools used for a make-up composition enclosed in a packed container, for example by nitrile butadiene rubber (NBR) puff, or hands. When urethane foam is too hard such that it has a hardness greater than 70, a cosmetic composition may not be liberated easily.

[0018] In one aspect, urethane foam may have an open cell structure. When urethane foam has a closed cell structure, air bubbles are kept in urethane so that a low-viscosity emulsion type cosmetic composition may not be impregnated therein easily. Thus, urethane foam having an open cell structure may be used specifically.

[0019] In one aspect, the cosmetic composition to be impregnated in urethane foam includes a liquid cosmetic composition, particularly an emulsion type cosmetic composition, and more particularly a water in oil (W / O) type or oil in water (O / W) type emulsion cosmetic composition.

[0020] In one aspect, the emulsion cosmetic composition may have a low viscosity, particularly of 5,000 to 15,000 mPa.s (centi poise (cps)), and more particularly of 6,000 to 10,000 mPa.s (cps). When the emulsion cosmetic composition has a viscosity than 5,000 mPa.s (cps), it may undergo separation into an oil phase and an aqueous phase, thereby making it difficult to impregnate urethane foam uniformly with the composition. When the emulsion cosmetic composition has a viscosity higher 15,000 mPa.s (cps), it may provide an undesirably tacky and heavy touch feel while applied onto the skin.

[0021] In one aspect, the cosmetic composition includes both a skin care composition and a make-up composition. Particular non-limiting examples of the cosmetic composition may include make-up primer, make-up base, foundation, powder, lipstick, lip gloss, eye shadow, eyebrow cosmetic composition, concealer, lip liner, blusher, UV protecting agent, lotion, or cream. More particularly, the cosmetic composition may be formulated into make-up primer, make-up base, liquid or solid foundation, powder, lipstick, lip gloss, eye shadow, eyebrow cosmetic composition, concealer or blusher, but is not limited thereto.

[0022] In one aspect, there is provided a make-up product in which polyether-based urethane foam impregnated with a cosmetic composition is enclosed. The make-up product includes a cosmetic composition applied to the polyether-based urethane foam disclosed herein, and thus allows high-quality packing of the cosmetic composition. In addition, the make-up product allows the cosmetic composition to be supported uniformly in urethane foam for a long period of time and to be liberated in an adequate amount when users take the cosmetic composition. Further, the make-up product maintains high long-term durability and stability. The make-up product disclosed herein may be provided as a packed container, abbreviated generally as 'pact', which includes a container having a lower part in which polyether-based urethane foam is received, and an upper part having a lid to which a mirror or the like may be attached. Figure 2 shows an exemplary image of polyether-based urethane foam provided in a packed container.

[0023] The examples, comparative examples, preparation examples and test examples will now be described. The following examples are for illustrative purposes only and not intended to limit the scope of this disclosure.[Test Example 1] Determination of Properties of Urethane Foam

[0024] To select urethane foam suitable for impregnation with a W / O type or O / W type low-viscosity emulsion cosmetic composition, various types of urethane foam are determined for their properties. The following Tables 2 and 3 show each type of urethane foam and the corresponding properties. In addition, Figure 3 and Figure 4 are microscopic views of each type of urethane foam magnified at 10 x 0.3. [Table 2]Polyester-based urethane foam 1 (conventional urethane foam)Polyester-based urethane foam 2 (Q100UT)Polyester-based urethane foam 3 (QS100EB)Pore per inch (ppi)80 ppi85 ppi85 ppiDensity (pcf)1.71.7-2.0Available fromGermanyFoamtec(Thailand)Foamtec(Thailand)RemarksFlexible polyurethane foamPolyester-Polyurethane, Quenched foamPolyester-Polyurethane, Reticulated foamHardness4548 [Table 3] Polyether-based urethane foam 1 (EZ93N)Polyester-based urethane foam 4 (ZH100KT)Polyester-based urethane foam 5 (ZH100LG)Pore per inch (ppi)88-100 ppi90 ppi90 ppiDensity (pcf)1.8-2.05.4-6.605.4-6.60Available fromFoamtec (Thailand)Foamtec (Thailand)Foamtec (Thailand)RemarksPolyether-Polyurethane, Reticulated foamPolyester-Polyurethane, Reticulated foamPolyester-Polyurethane, Reticulated foamHardness45

[0025] In Table 3, Polyether-based urethane foam 1 is dry polyether-based urethane foam.[Test Example 2] Evaluation of Formulation Stability

[0026] Among the different kinds of urethane foam listed in Tables 2 and 3, Polyether-based urethane foam 1 (Example 1), Polyester-based urethane foam 2 (Comparative Example 1) and Polyester-based urethane foam 3 (Comparative Example 2) are selected and subjected to impregnation with a W / O type emulsion make-up composition. Then, their stabilities are evaluated as a function of storage temperature and time. The results are shown in the following Table 4 and Fig 5. Figure 5 shows photographs of Example 1, Comparative Example 1 and Comparative Example 2 after storing them at 50°C for 2 hours. [Table 4]55°C, after 7 days45°C→3°C→frozen at - 10°C (each for 8 hours), after 5 days30°C, after 7daysExample 1StableStableStableComparative Example 1Urethane foam brokenUrethane foam brokenStableComparative Example 2Urethane foam brokenUrethane foam brokenStable

[0027] As can be seen from the above results, when each foam is impregnated with a W / O type emulsion make-up composition, each urethane foam according to Comparative Examples 1 and 2 is broken, causes separation of the make-up composition and generates air bubbles with time under a high temperature or severe change in temperature, and thus is shown to be very unstable. On the contrary, Example 1 substantially maintains its original state and shows high stability.

[0028] Therefore, it can be seen that polyether-urethane foam shows higher stability than polyester-based urethane foam upon impregnation with a cosmetic composition, and thus is more suitable for impregnating a cosmetic composition.[Preparation Examples 1 and 2] Preparation of UV Protecting Cosmetic Composition

[0029] In Preparation Examples 1 and 2, W / O type emulsion UV protecting cosmetic compositions are prepared according to the formulation of the following Table 5.

[0030] Particularly, a UV protecting agent is introduced to oily ingredients and dissolved and emulsified therein. Next, the oily ingredients are mixed with a surfactant and heated to and agitated at 80°C so that the mixture is homogenized. Then, a pigment is further added thereto, followed by agitation and homogenization, to provide an oily part. In a separate mixer, aqueous ingredients are mixed and heated to and agitated at 80°C to provide a completely dissolved aqueous part. The prepared aqueous part is introduced gradually to the oily part and subjected to emulsification by using a homogenizer mixer. After cooling to 50°C, skin protecting ingredients and fragrances are introduced thereto, followed by cooling, to provide a low-viscosity W / O type emulsion UV protecting cosmetic composition. [Table 5]Ingredients (wt%)Prep. Ex. 1Prep. Ex. 2Oily PartOily IngredientsOzokerite0.11.0Dicaprylyl carbonate10.0010.00Preservativ eMethyl paraben0.1000.100UV protecting agentsOctylmethoxy cinnamate7.0007.000Isoamyl p-methoxy cinnamate2.0002.000PigmentDisteardimonium hectorite0.201.50Oily IngredientsDecamethylcyclopentasilxan e16.0016.00EmulsifiersSorbitan sesquioleate2.0002.000Lauryl PEG / PPG-18 / 18 methicon1.5001.500PigmentsPolymethyl methacrylate5.005.00Titanium dioxide / Aluminum hydroxide / Stearic acid7.007.00Aq. PartWaterTo 100To 100MoisturizerGlycerin8.0008.000Emulsion stabilizerSodium chloride1.001.00Fragrance0.4000.400Total100100

[0031] In Table 5, disteardimonium hectorite functions as a thickening agent, polymethyl methacrylate serves as a pure body pigment, and titanium dioxide / aluminum hydroxide / stearic acid serves as an inorganic UV protecting agent.[Test Example 3] Evaluation of Preference Depending on Hardness of Urethane Foam

[0032] Different types of polyether-based urethane foam having a different value of hardness are impregnated with Preparation Examples 1 and 2, and user preference of each case is determined. Particularly, 50 females are divided into two groups (each group having 25 persons). They are allowed to apply each of Preparation Example 1 and Preparation Example 2 impregnated in polyether-based urethane foam having a different value of hardness to their skin with NBR puff for 2 days. Then, overall user preference including touch feel and coating quality is evaluated in each case. The results are shown in the following Tables 6 and 7. [Table 6]Cosmetic composition used for impregnationHardness of urethane foam (ASKER hardness, Type F)Preference (%)Example 2Preparation Example 155Example 3Preparation Example 18010Example 4Preparation Example 14085 [Table 7] Cosmetic composition used for impregnationHardness of urethane foam (ASKER hardness, Type F)Preference (%)Example 5Preparation Example 255Example 6Preparation Example 2805Example 7Preparation Example 24090

[0033] As can be seen from the above results, the highest preference is available when polyether-based urethane foam used for impregnation with both compositions according to Preparation Examples 1 and 2 has Asker hardness value of 40.

Claims

1. Use of a polyether-based urethane foam impregnated with a cosmetic composition as a carrier for supporting and retaining the cosmetic composition, wherein the polyether-based urethane foam has a reticulated structure and a density of 16.02 to 48.06 kg / m3 (density of 1 to 3 pcf), and wherein the cosmetic composition impregnated in the urethane foam is taken by cosmetic tools used for a make-up composition enclosed in a packed container, or hands.

2. Use of the polyether-based urethane foam according to claim 1, which has a pore number of 2755.9 to 4724.41 pores per meter (70 to 120 ppi (pores per inch)).

3. Use of the polyether-based urethane foam according to claim 1, which has a hardness of 10 to 70 being measured by an Asker durometer type F.

4. Use of the polyether-based urethane foam according to claim 1, which has an open cell structure.

5. Use of the polyether-based urethane foam according to claim 1, wherein the cosmetic composition is a water in oil (W / O) type or an oil in water (O / W) type emulsion cosmetic composition.

6. Use of the polyether-based urethane foam according to claim 1, wherein the emulsion cosmetic composition has a viscosity of 5,000-15,000 mPa.s (5,000-15,000 cps).

7. Use of the polyether-based urethane foam according to claim 1, wherein the cosmetic composition is provided as make-up primer, make-up base, foundation, powder, lipstick, lip gloss, eye shadow, eyebrow cosmetic composition, concealer, lotion, cream, or blusher.