COSMETIC COMPOSITIONS FOR HAIR AND HAIR TREATMENT METHODS

Abstract

COSMETIC HAIR COMPOSITIONS AND HAIR TREATMENT METHOD The present invention relates to cosmetic hair compositions comprising at least one organic acid, a non-aqueous solvent comprising at least one compound with at least one hydroxyl group, at least one amino acid, at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof, water, and at least one surfactant selected from cationic surfactants, non-ionic surfactants and mixtures thereof. The invention also relates to a hair treatment method, particularly for curly hair. Figure for the abstract: none

Description

Description Title of the invention: COSMETIC COMPOSITIONS FOR HAIR AND Hair Treatment Method FIELD OF THE INVENTION

[0001] — The present invention relates to cosmetic compositions for hair comprising (a) at least one organic acid, (b) a non-aqueous solvent comprising at least at least one compound with at least one hydroxyl group, (c) at least one amino acid, (d) at least one fatty compound chosen from vegetable oils, vegetable resins, vegetable waxes and their mixtures, (e) water and (f) at least one selected surfactant among cationic surfactants, non-ionic surfactants and their mixtures. The invention also relates to a method of treating hair, in particular curly hair. CONTEXT OF THE INVENTION

[0002] — People use different cosmetic and personal care compositions for improve the look and feel of keratin fibers, such as hair.

[0003] Particularly with regard to curly hair, consumers are still facing issues related to loop definition such as frizz, volume and shape. Curly hair tends to frizz and expand considerably when exposed to high humidity conditions, chemical treatments, in particular. In addition, the shape and definition of the curls are lost after sleep.

[0004] — Numerous product development attempts to discipline, define and control hair, especially curly hair, improve / maintain de- curl finishing, curl retention and curl consistency, without lose the feeling and / or have an unnatural, stiff appearance of hair have been made, but such products have resulted in additional problems or maintenance difficulties.

[0005] — Thus, state-of-the-art products generally require a large amount of product to give good combing and hair feel. But, since the effect of these products is not long-lasting, consumers must reapply the product several times during the day or after sleeping to regain definition and control of frizz, which leads to buildup of the product to the surface of the hair, and gives a heavy appearance, a wet appearance, a unnatural feel and greasy sensation, as these products do not penetrate the keratin fibers and remain on the surface of the hair.

[0006] In this sense, there is a need in the market for curly hair products that define curls in a lasting way, without the need to reapply the product before the next wash or after sleeping, which also reduces the need to use large amounts of product between washes. Additionally, the standard curly hair routine involves using multiple cosmetic products along the entire length of the hair and needs to be reset every three days, as curls tend to lose definition and freshness after this period—it's a very time-consuming routine that involves consumers repeating all the steps approximately every three days, including washing their hair and applying different cosmetic products. Therefore, it is desirable to have a cosmetic product for curly hair that not only helps define curls, but also provides long-lasting cosmetic benefits to the client's hair, such as resistance to frizz, leaving hair shiny, and being easy to apply and not leaving hair wet or heavy, which improves with the use of such a product. It is also necessary for the cosmetic product for curly hair to reduce the amount of products used by the consumer and prolong the effects of the composition so that the consumer can gain additional days before having to restart the cosmetic routine for curly hair. The inventors of the present invention have surprisingly and unexpectedly obtained cosmetic compositions for hair, specially designed for curly hair, comprising (a) at least one organic acid, (b) a non-aqueous solvent comprising at least one compound with at least one hydroxyl group, (c) at least one amino acid, (d) at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof, (e) water and (f) at least one surfactant selected from cationic surfactants, non-ionic surfactants and mixtures thereof, which are capable not only of penetrating the hair fiber without accumulating on the surface of the fiber, while also providing curl definition until the next wash, long-lasting curl definition, frizz control, a natural look and desirable volume, and which does not look heavy on the hair, but also provides cosmetic benefits,such as: smooth feel, shine and good spreadability. It was also discovered that these cosmetic benefits were more pronounced with multi-application of the product (cumulative effect) and give the consumer at least one extra day before having to resume the curly hair routine. Summary of the invention The present invention relates to cosmetic compositions for hair comprising (a) at least one organic acid, (b) a non-aqueous solvent comprising at least at least one compound with at least one hydroxyl group, (c) at least one amino acid, (d) at least one fatty compound chosen from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof, (e) water and (f) at least one surfactant chosen from cationic surfactants, non-ionic surfactants and mixtures thereof. The present invention also relates to a method for treating hair, in particular curly hair, comprising the step of contacting the hair with the cosmetic composition for hair of the invention. DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a cosmetic composition for hair, mainly for curly hair, comprising: (a) at least one organic acid; (b) a non-aqueous solvent comprising at least one compound with at least one hydroxyl group; (c) at least one amino acid; (d) at least one fatty compound chosen from vegetable oils, vegetable resins, vegetable waxes and their mixtures; (e) water and (At least one surfactant selected from cationic surfactants, non-ionic surfactants and mixtures thereof. In one embodiment, the at least one organic acid is selected from short-chain organic acids, preferably α-hydroxy acids (AHAs), β-hydroxy acids, and a mixture thereof. In one embodiment, the at least one organic acid of the cosmetic hair composition of the present invention is selected from tartaric acid, lactic acid, glutaric acid, etidronic acid, salicylic acid, glycolic acid, citric acid, and mixtures thereof. In a preferred embodiment, the at least one organic acid is tartaric acid. In a preferred embodiment, the at least one organic acid is lactic acid. In one embodiment, the at least one organic acid includes tartaric acid and a second organic acid selected from lactic acid, glutaric acid, etidronic acid, salicylic acid, glycolic acid, and citric acid. In a preferred embodiment, the at least one organic acid includes tartaric acid and lactic acid. Additionally, the amount of the at least one organic acid ranges from about 0.1% to about 25.0% by weight, 0.5% to about 20.0% by weight, preferably from about 0.5% to about 10.0% by weight, more preferably from about 0.75% to about 6.0% by weight, and even more preferably from about 1.0% to about 5.0%, and most preferably from about 1.0% to about 4.0%, based on the total weight of the composition. The cosmetic composition for hair according to the present invention also comprises a non-aqueous solvent comprising at least one compound with at least one hydroxyl group. Without being limited to any theory, it is believed that the non-aqueous solvent comprising at least one compound with at least one hydroxyl group acts as a penetrating agent, i.e. capable of forming the dipole-dipole interaction with the keratin fibers, such as the hair, and of binding to polar sites on the surface of said keratin fiber and of decreasing the protection, thus promoting the penetration of the hair composition into the keratin fibers. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic composition for hair of the present invention is selected from polyols, C to C monoalcohols and a mixture thereof. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic hair composition of the present invention is selected from polyols. In one embodiment, the polyol is a glycol selected from propylene glycol, dipropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, glycerin and mixtures thereof. In one embodiment, the polyol comprises propylene glycol and dipropylene glycol. In one embodiment, the polyol is glycerin. In one embodiment, the polyol comprises propylene glycol and glycerin. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic composition for hair of the present invention is selected from C; to C5 monoalcohols. In one embodiment, the C; to C, monoalcohols include ethanol and / or propanol and / or isopropyl alcohol (isopropanol) and / or butanol and / or hexanol. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic hair composition of the present invention comprises a mixture of C; to C, polyols and monohydric alcohols. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic hair composition of the present invention comprises propylene glycol and ethanol. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic hair composition of the present invention comprises propylene glycol and isopropyl alcohol. In a In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic composition for hair of the present invention comprises propylene glycol, isopropyl alcohol and ethanol. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic composition for hair of the present invention comprises propylene glycol, isopropyl alcohol, ethanol and glycerin. In one embodiment, the non-aqueous solvent comprising at least one compound with at least one hydroxyl group of the cosmetic composition for hair of the present invention comprises propylene glycol, ethanol and glycerin. The amount of the non-aqueous solvent comprising at least one compound with at least one hydroxyl group ranges from about 0.1% to about 20.0% by weight, preferably from about 0.3% to about 15.0% by weight, or from about 0.5% to about 12.0% by weight, or from about 0.5% to about 11.0% by weight, or from about 1.0% to about 11.0% by weight, based on the total weight of the composition. According to the present invention, the at least one amino acid is selected from arginine. In one embodiment, the at least one amino acid is selected from arginine. In one embodiment, the at least one amino acid is selected from glycine. In one embodiment, the at least one amino acid is selected from arginine and glycine. The amount of the at least one amino acid ranges from about 0.1% to about 7.0% by weight, preferably from about 0.1% to about 6.0% by weight, more preferably from about 0.1% to about 5.0% by weight, even more preferably from about 0.5% to about 3.0% by weight, based on the total weight of the composition. Other suitable ranges are from about 0.5% to about 2.0% by weight, or from about 0.7% to about 1.2% by weight, based on the total weight of the composition. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof is selected from Copaiba Officinalis (Balsam Copaiba) resin (oily resin or resin form). In another embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof is selected from coconut oil, soybean oil (soybean germ oil) and mixtures thereof. In one embodiment, the at least one fatty compound includes coconut oil. In one embodiment, the at least one fatty compound includes germ oil. of soy. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof includes Copaiba resin, Candeia resin and breu branco resin. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof is copaiba resin. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof includes copaiba resin, coconut oil and soybean oil. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes, and mixtures thereof includes copaiba resin and coconut oil. In one embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof includes candelilla wax. In another embodiment, the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof includes Carnauba wax. The amount of the at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof ranges from about 0.1% to about 15.0% by weight, preferably from about 0.1% to about 14.0% by weight, preferably from about 0.15% to about 10.0% by weight, preferably from about 0.17% to about 4.0% by weight, or such that about 0.1%, about 0.17%, about 0.2%, about 0.36%, about 0.4%, about 0.5% to about 4.0% by weight, relative to the total weight of the composition. In one embodiment, the at least one surfactant selected from cationic surfactants, nonionic surfactants and mixtures thereof includes at least one cationic surfactant. In a preferred embodiment, the at least one cationic surfactant is selected from quaternary ammonium salts such as cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, and from cationizable surfactants, for example, amidoamine compounds such as oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, behenamidopropyldiethylamine, behenamidopropyl thyldiethylamine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamido-propylidiethylamine, arachidamidoethylidiethylamine, arachidamidoethylidimethylamine, brassicamidopropyldimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine, palmitamidopropyl dimethylamine and mixtures thereof. In one embodiment, the at least one surfactant selected from cationic surfactants, nonionic surfactants and mixtures thereof includes at least one cationic surfactant selected from behentrimonium chloride, cetrimonium chloride, behentrimonium methosulfate and mixtures thereof. In one embodiment, the at least one surfactant selected from cationic surfactants, nonionic surfactants and mixtures thereof includes at least one cationic surfactant selected from stearamidopropyl dimethylamine, brassicamidopropyldimethylamine and mixtures thereof. In one embodiment, the at least one surfactant selected from cationic surfactants, nonionic surfactants and mixtures thereof includes at least one nonionic surfactant. In a preferred embodiment, the at least one nonionic surfactant is selected from fatty alcohols. In one embodiment, the fatty alcohols include cetyl alcohol, cetearyl alcohol, stearyl alcohol, lauryl alcohol, myristyl alcohol, and mixtures thereof. In one embodiment, the fatty alcohols include cetearyl alcohol. In one embodiment, the fatty alcohols include cetyl alcohol. In one embodiment, the fatty alcohols include stearyl alcohol. In one embodiment, the fatty alcohols include cetearyl alcohol and stearyl alcohol. In one embodiment, the fatty alcohols include an alkoxylated alcohol. In one embodiment, the fatty alcohols include an alkoxylated alcohol selected from steareth-20, laureth-12, ceteareth-20, deceth-10, trideceth-6 and mixtures thereof. In one embodiment, the at least one surfactant comprises at least one cationic surfactant selected from behentrimonium chloride, cetrimonium chloride, behentrimonium methosulfate, stearamidopropyl dimethylamine, brassicamidopropyldimethylamine and mixtures thereof, and at least one non-ionic surfactant selected from cetyl alcohol, cetearyl alcohol, stearyl alcohol, lauryl alcohol, myristyl alcohol and mixtures thereof. When the at least one surfactant includes an amidoamine such as stearamidopropyl dimethylamine or brassicamidopropyldimethylamine, a pH adjusting agent such as triethanolamine may be included in the composition. The amount of the at least one surfactant selected from cationic surfactants, nonionic surfactants and mixtures thereof ranges from about 0.05% to about 15.0% by weight, preferably from about 1.0% to about 14.0% by weight, preferably from about 1.5% to about 12.0% by weight, more preferably from about 1% to about 12% by weight, from about 2.0% to about 11.0%, from about 3.0% to about 10.0% by weight, including all ranges and sub-ranges, relative to the total weight of the cosmetic composition for hair. Individually, each surfactant may be present in an amount such as about 0.05%, about 0.5%, about 1.0%, about 1.5%, about 1.8%, about 2.4%, about 3.0%, about 3.5%, about 4.0%, about 5.0%, about 5.5%, about 6.0%, about 6.5%, about 7.0%, about 7.5%, about 8.0%, about 8.5%, about 9.0%, about 9.5%, about 10. 0%, about 10.5%, about 11.0%, about 11.5%, about 12.0% by weight, based on the total weight of the composition. In a preferred embodiment, the at least one surfactant is at least one cationic surfactant ranging from about 0.1% to about 10.0% by weight, such as from about 1.0% to about 10.0% by weight, from about 1.4% to about 9.0% by weight, from about 1.4% to about 8.0% by weight, from about 1.4% to about 6.0% by weight, from about 2.0 to about 6.0% by weight, from about 2.4 to about 6.0% by weight, based on the total weight of the composition. In a preferred embodiment, the at least one surfactant is at least one nonionic surfactant selected from at least one fatty alcohol ranging from about 0.1 to about 12.0% by weight, such as from about 3.0 to about 12.0% by weight, from about 4.0% to about 12.0% by weight, from about 5.0% to about 10.0% by weight, from about 6.0% to about 9.0% by weight relative to the total weight of the composition. In one embodiment, the cosmetic composition for hair of the present invention further comprises at least one ester, which may be selected from isopropyl palmitate, dicaprylyl carbonate, cetyl esters and mixtures thereof. In a preferred embodiment, the cosmetic hair composition of the present invention is in the form of an emulsion (oil in water or water in oil). In another preferred embodiment, the cosmetic hair composition may be, but is not limited to, free or substantially free of silicon, behentrimonium chloride and / or a quaternary ammonium salt. In one embodiment, the hair cosmetic compositions according to the invention are free or substantially free of anionic surfactants. The pH of the cosmetic hair composition of the present invention is from about 1 to about 10, preferably from about 2 to about 7, or from about 2 to about 6. For a lasting definition, the pH is about 3 to about 5, preferably about 2.5 to about 4.5, or about 3.0 to about 4.5, or about 3.5 to about 4.5, or about 3.0 to about 4.0, or about 2, about 3, about 3, 3, about 3.5, about 4, about 4.5. Furthermore, the present invention relates to a method for treating hair, in particular curly hair, comprising the step of contacting the hair with the cosmetic composition for hair of the invention. In a preferred embodiment, the composition of the invention is used as a leave-in or rinse-out product to provide long-lasting curl definition without buildup or frizz, which improves curl evenness, discipline, volume control, curl individualization and fast drying, among other attributes. ORGANIC ACID The at least one organic acid of the compositions may be chosen from alpha hydroxy acids, beta hydroxy acids and a mixture thereof. The term "alpha-hydroxy acid" is intended to mean, according to the present invention, a carboxylic acid having at least one hydroxyl functional group occupying an alpha position on said acid (carbon adjacent to a carboxylic acid functional group). A beta-hydroxy acid is closely related to an alpha-hydroxy acid, except that the carboxylic and hydroxyl functional groups are separated by two carbon atoms. A hydroxy acid may be present in the final composition in the form of the free acid and / or in the form of one of its associated salts (salts with an organic base or an alkali metal, in particular), in particular depending on the final pH imposed on the composition. Suitable alpha hydroxy acid present in the composition according to the invention includes, but is not limited to, tartaric acid, glycolic acid, citric acid, lactic acid, methyllactic acid, glucuronic acid, pyruvic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, 2-hydroxyhexanoic acid, 2-hydroxyheptanoic acid, 2-hydroxyoctanoic acid, 2-hydroxynonanoic acid, 2-hydroxydecanoic acid, 2-hydroxyundecanoic acid, 2-hydroxydodecanoic acid, 2-hydroxytetradecanoic acid, 2-hydroxyhexadecanoic acid, 2-hydroxyoctadecanoic acid, acid 2-hydroxytetracosanoic acid, 2-hydroxyeicosanoic acid, mandelic acid, phenyllactic acid, gluconic acid, galacturonic acid, aleuritic acid, ribonic acid, tartronic acid, malic acid, fumaric acid, their salts and mixtures thereof. It is also possible to use mixtures of these different acids. In some embodiments, the composition includes alpha hydroxy acids including tartaric acid and lactic acid. When combined, the more than one alpha hydroxy acid may be present in the same or different amounts. The beta-hydroxy acid, when present in the composition according to the disclosure, includes, but is not limited to, one or more of salicylic acid and derivatives thereof (including n-octanoylsalicylic acid, salicylate, sodium salicylate and willow extract), beta-hydroxybutanoic acid, tropic acid and trethocanic acid. In some embodiments, the composition includes tartaric acid. In some embodiments, the composition includes tartaric acid and lactic acid. COMPOUND WITH AT LEAST ONE HYDROXYL GROUP The non-aqueous solvent of the present invention comprises at least one compound with at least one hydroxyl group. Said compound with at least one hydroxyl group may be chosen from polyols, and / or C; to €; monoalcohols such as ethyl alcohol, isopropyl alcohol, propyl alcohol, ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, propane diol and glycerin. Other non-limiting examples include alkanediols (polyhydric alcohols) such as glycerin, 1,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, dipropylene glycol, 2-butene-1,4-diol, 2-ethyl-1,3-hexanediol, 2-methyl-2,4-pentanediol, caprylyl glycol, 1,2-hexanediol, 1,2-pentanediol, and 4-methyl-1,2-pentanediol; alkyl alcohols having 1 to 4 carbon atoms such as ethanol, methanol, butanol, propanol, isopropanol and a mixture thereof. In some cases, the compound with at least one hydroxyl group may be selected from the group consisting of one or more glycols, C1-4 alcohols, glycerin, and a mixture thereof. In some cases, the compound with at least one hydroxyl group is selected from the group consisting of hexylene glycol, propylene glycol, caprylyl glycol, glycerin, isopropyl alcohol, and a mixture thereof. Polyhydric alcohols are useful. Examples of polyhydric alcohols include glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,3-butanediol, 2,3-butanediol, 1,4-butanediol, 3-methyl-1,3-butanediol, 1,5-pentanediol, tetraethylene glycol, 1,6-hexanediol, 2-methyl-2,4-pentanediol, polyethylene glycol, 1,2,4-butanetriol, 1,2,6-hexanetriol and a mixture thereof. Polyol compounds may also be used. Non-limiting examples include aliphatic diols, such as 2-ethyl-2-methyl-1,3-propanediol, 3,3-dimethyl-1,2-butanediol, 2,2-diethyl-1,3-propanediol, 2-methyl-2-propyl-1,3-propanediol, 2,4-dimethyl-2,4-pentanediol, 2,5-dimethyl-2,5-hexanediol, 5-hexene-1,2-diol and 2-ethyl-1,3-hexanediol and a mixture thereof. AMINO ACID The compositions according to the disclosure comprise at least one amino acid. As used herein, the term "amino acid" includes amino acids such as proteinogenic amino acids, sulfonic amino acids and their salts. Amino acids are simple organic compounds containing both a carboxylic acid group (-COOH) and an amino group (-NH;). Sulfonic amino acids are simple organic compounds containing both a sulfonic acid group (—SO,OH) and an amino group (—NH;). Therefore, the amino acids useful according to the disclosure may, in certain embodiments, be selected from the compounds of formula (I) and formula (IT): 2 20 AA Le Horn, HO ÉSÏrn, R È {h 4 in which: - R represents a hydrogen atom, a linear or branched, preferably linear, C,-C, alkyl group, said alkyl group being optionally substituted by at least one group selected from hydroxyl, -C(O)-OH, -S(O),-OH, -C(O)-O- and M+, and S(O)-O- and M+, where M7 represents a cationic counterion such as an alkali metal, an alkaline earth metal or ammonium and n is 0 or 1. Amino acids can be found in their non-ionized form (I) and (II) or their ionized or betaine form (T') and (IT): 9 9 WA NH ze NE NHy R {F} qe 20 HO SCENE, = o” San,” R RR 1 8 in which R and n are as defined above. The one or more amino acids can also occur in their basic conjugated form (Ib) and (IIb): Q MOT NATENH, 2o M 0” SAN, { RR iib) {Ub} in which R and n are as defined above. The known bicn amino acids include the twenty amino acids that form the proteins of living organisms (standard proteinogenic amino acids): alanine, arginine, asparagine, aspartic acid, cysteine, glutamic acid, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine and valine. The amino acids of the present disclosure are not limited, however, to standard proteinogenic amino acids.Non-limiting examples of amino sulfonic acids include aminomethane sulfonic acid, 2-aminoethane sulfonic acid (taurine), aminopropane sulfonic acid, aminobutane sulfonic acid, aminohexane sulfonic acid, aminoisopropyl sulfonic acid, aminododecyl sulfonic acid, aminobenzene sulfonic acid, aminotoluene sulfonic acid, sulfanilic acid, chlorosulfanilic acid, diamino benzene sulfonic acid, amino phenol sulfonic acid, amino propyl benzene sulfonic acid, aminohexyl benzene sulfonic acid and mixtures thereof. In some cases, charged amino acids may be used. Non-limiting examples of charged amino acids include arginine, lysine, aspartic acid, and glutamic acid. In some cases, polar amino acids are useful. Non-limiting examples of polar amino acids include glutamine, asparagine, histidine, serine, threonine, tyrosine, cysteine, methionine, and tryptophan. In some cases, hydrophobic amino acids may be employed. Non-limiting examples of hydrophobic amino acids include alanine, isoleucine, leucine, phenylalanine, valine, proline, and glycine. FATTY COMPOUND The at least one fatty compound of the cosmetic composition for hair of the present invention may be chosen from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof. Vegetable oil In one embodiment, the fatty compound of the cosmetic composition for hair of the present invention selected from vegetable oils, vegetable resins, vegetable waxes and their mixtures comprises at least one vegetable oil. In a non-limiting and preferred embodiment, the at least one vegetable oil is selected from coconut oil, almond oil, aloe vera oil, avocado oil, soybean oil, camelina oil, coffee oil, castor oil, grape seed oil, jojoba oil, basil oil, bay oil, bergamot oil, black pepper essential oil, birch oil, camphor, cannabis oil, caraway oil, cardamom seed oil, carrot seed oil, chamomile oil, calamus root oil, cinnamon oil, lemongrass oil, clary sage oil, clove leaf oil, coffee, coriander, oil of mint-cock, cranberry seed oil, cubeb oil, cumin oil, cubeb oil, dill oil, eucalyptus oil, fennel oil, fennel seed oil, fenugreek oil, fir oil, frankincense oil, geranium oil,ginger oil, grapefruit oil, grapeseed oil, henna oil, horseradish oil, jasmine oil, juniper berry oil, lavender oil, lemon oil, lemongrass, marjoram, melaleuca oil, lemon oil, lemon balm oil, mountain savory oil, mugwort oil, mustard oil, myrrh oil, myrtle oil, neem oil, neroli oil, nutmeg oil, orange oil, oregano oil, iris oil, palo santo oil, parsley oil, peppermint oil, pine oil, plum oil, rose oil, rosehip oil, rosemary oil, rosewood oil, sandalwood oil, spruce oil, star anise oil, tarragon oil, tea tree oil, thyme oil, and mixtures thereof, In some embodiments, vegetable oils suitable for use The oils used in the hair care compositions of the present invention are selected from coconut oil, soybean oil, canola oil, rapeseed oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, sunflower oil, linseed oil, palm kernel oil, wheat germ oil, apricot oil, pistachio oil, poppy seed oil, hazelnut oil, rapeseed oil, peach kernel oil, jojoba oil, helianthus annuus (sunflower) oil, and mixtures thereof. If necessary, vegetable oil can improve the penetration effect. In a preferred embodiment, the vegetable oil of the present invention is coconut oil, which is mainly composed of lauric acid, myristic acid, palmitic acid, oleic acid, caprylic acid, capric acid. Other oils of the same composition could be applied to the invention, such as babassu oil. In another preferred embodiment, the cosmetic hair composition of the present invention further comprises at least one vegetable oil selected from argan oil, soybean oil and mixtures thereof. In a preferred embodiment, the cosmetic hair compositions of the present invention comprise a mixture of vegetable oils and vegetable resins, such as coconut oil and Copaiba Officinalis (Balsam Copaiba Resin) (Copaiba Resin or Copaiba Oleoresin). Plant resin In one embodiment, the fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and their mixtures of the cosmetic composition for hair of the present invention comprises at least one vegetable resin. Preferably, the plant resin of the present invention is Copaifera officinalis (COPAIBA BALSAM) RESIN (INCI name) which may take the form of COPAIBA oil resin or COPAIBA resin. Copaifera officinalis (COPAIBA BALSAM) RESIN is commercially available under the trade name RAIN FOREST RF3310 (also known by the chemical name COPAIBA Oleoresin) or under the trade name RAIN FOREST 03370 (also known by the chemical name COPAIBA resin), both from the supplier Beraca Ingredientes Naturais. Vegetable waxes In one embodiment, the fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof comprises a vegetable wax. If necessary, the vegetable wax can be chosen from Candelilla wax, Carnauba, beeswax and their mixtures. WATER The cosmetic compositions for hair according to the present invention comprise water. The water used may be sterile demineralized water and / or deionized water and / or floral water such as rose water, cornflower water, chamomile water or linden water, and / or natural thermal or mineral water such as, for example: Vittel water, Vichy basin water, Uriage water, La Roche Posay water, La Bourboule water, Enghien-les-Bains water, Saint Gervais-les-Bains water, Néris-les-Bains water, Allevar-les-Bains water, Digne water, Maizières water, Neyrac-les-Bains water, Lons-le-Saunier water, Eaux-Bonnes water, Rochefort water, Saint Christau water, Fumades, Tercis-les-Bains water or Avène water. The water can also include reconstituted thermal water, that is, water containing trace elements such as zinc, copper, magnesium, etc.restoring the characteristics of thermal water. The cosmetic hair composition of the present invention may comprise water in an amount of from about 30.0% to about 99.0% by weight, preferably from about 65.0% to about 95.0% by weight, and more preferably from about 70.0% to about 92.0% by weight, based on the total weight of the cosmetic hair composition. Esters In preferred embodiments, the cosmetic composition for hair of the present invention comprises at least one ester. The at least one ester may be chosen from, in particular, isopropyl palmitate, dicaprylyl carbonate, cetyl esters and mixtures thereof. Where applicable, the amount of the at least one ester ranges from about 0.5% to about 10.0% by weight, from about 1.5% to about 5.0% by weight, from about 0.5% to about 2.5% by weight, from about 1.0% to about 3.0% by weight, from about 2.0% to about 5.0% by weight, from about 2.0% to about 3.0% by weight, from about 5.0% to about 8.5% by weight, including all ranges and sub-ranges, based on the total weight of the composition. Additional ingredients In addition to the essential components described above, the hair composition of the present invention may further comprise any usual cosmetically acceptable ingredient, which may be chosen in particular from cosmetically acceptable ingredients selected from perfumes / fragrances, preservatives, vitamins, plant extracts, pH correctors and mixtures thereof. A person skilled in the art will take care to select the optional additional ingredients and / or their quantity so that the advantageous properties of the composition according to the invention are not, or not significantly, compromised by the envisaged addition. Additional ingredients may range from about 1% to about 70% by weight, based on the total weight of the composition. Terms The expression "at least one" means one or more and therefore includes individual components as well as mixtures / combinations. In this document, all ranges provided are intended to include each specific range within the given ranges, as well as a combination of intermediate subranges. Thus, a range of 1 to 5 specifically includes 1, 2, 3, 4, and 5, as well as subranges such as 2-5, 3-5, 2-3, 2-4, 1-4, etc. All ranges and values ​​disclosed herein are inclusive and combinable. For example, any value or point described herein that falls within a range described herein may serve as a minimum or maximum value to derive a subrange, etc. The term "substantially free" or "essentially free" as used herein means that less than about 5% by weight of a specific material is added to a composition, based on the total weight of the compositions. However, the compositions may include less than about 2% by weight, less than about 1% by weight, less than about 0.5% by weight, less than about 0.1% by weight, less than about 0.01% by weight, or none of the specified material. The term "active ingredient," as used herein with respect to the percentage amount of an ingredient or raw material, refers to 100% of the activity of the ingredient or raw material. “Cosmetically acceptable” means that the article in question is compatible with a keratin substrate such as skin and hair. For example, a “cosmetically acceptable carrier” means a carrier compatible with a keratin substrate such as skin and hair. The term "hair cosmetic composition" as used herein may also be a hair styling composition, hair care composition, or a hair treatment composition. The term “cationic surfactant” means a positively charged surfactant. This surfactant may carry one or more positive permanent charges or may contain one or more functionalities that are cationizable in the composition according to the disclosure. Throughout the disclosure, the expression "a combination thereof" (or a mixture thereof) is used, after a list of elements as shown in the following example where the letters A to F represent the elements: "one or more elements selected from the group consisting of A, B, C, D, E, F, and a combination thereof." The phrase "a combination thereof" does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a combination of two or more of A, B, C, D, E, and F may be included. In other words, it is equivalent to the phrase "one or more elements selected from the group consisting of A, B, C, D, E, F, and a combination of two or more of A, B, C, D, E, and F." Similarly, the phrase "a salt thereof" also refers to "salts thereof." Thus, when the disclosure refers to "a member selected from the group consisting of A, B, C, D, E, F, a salt thereof, or a combination thereof," it indicates that one or more of A, B, C, D, and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included, or a combination of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included. Salts referred to throughout the disclosure may include salts having a counterion such as an alkali metal, an alkaline earth metal, or an ammonium counterion. This list of counterions is not, however, limiting. Some of the compounds discussed throughout the disclosure may be present as a salt in the composition or may be added to the composition as a salt (and dissociate in the composition). Thus, all compounds and amounts of compounds refer to both the salt form of the compound and the dissociated form of the compound. In other words, even if the phrase "a salt thereof" is not specifically or expressly stated with respect to ingredients capable of forming salts or available as salts, it is understood that the salt form of the compound is included. The term "inclusive" for a concentration range means that the limits of that range are included in the defined interval. The term "INCI" is an abbreviation for International Nomenclature of Cosmetic Ingredients, which is a system of names provided by the Personal Care Products Council's International Nomenclature Committee to describe the ingredients of personal care products. All components and elements positively presented in this disclosure may be negatively excluded from the claims. In other words, the compositions of the present disclosure may be free or substantially free of all components and elements positively recited throughout this disclosure. Some of the various categories of components identified may overlap. In such cases where an overlap may exist and the composition includes both components (or the composition includes more than two overlapping components), an overlapping compound or ingredient does not represent more than one component. For example, if a polyacrylate falls within the description of a thickening polymer and the description of a film-forming polymer, the specifically cited polyacrylate is considered to be only the thickening polymer or only the film-forming polymer. A specific polyacrylate cannot be simultaneously interpreted as a thickening polymer and a film-forming polymer, for example, where the claims disclose both a thickening polymer and a film-forming polymer (even though the polyacrylate can function as both a thickening polymer and a film-forming polymer).In other words, a single compound or ingredient cannot simultaneously have the function of two different components of a claimed composition. PROCESS FOR MANUFACTURING A COSMETIC COMPOSITION FOR HAIR The hair care composition of the present invention can be manufactured using conventional cosmetic processes. An illustrative process comprises the following steps: - Step (1): In a container, add 30 to 70% water and at least one organic acid, and mix for about 10 minutes at room temperature; - Step (2): add at least one amino acid, mix the ingredients until completely dissolved; - Step (3): adding non-aqueous solvent comprising at least one compound with at least one hydroxyl group, at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and their mixtures and at least one surfactant selected from cationic surfactants, non-ionic surfactants and their mixtures; - Step (4): Heat the mixture to about 60°C to about 75°C for about 15 minutes. - Step (5): Add the remaining water to the mixture and cool. - Step (6): Add additional ingredients (if any) cooling to about 25°C, pH adjustment (if necessary) using a pH corrector. METHODS OF IMPLEMENTATION An example of a suitable cosmetic composition for hair according to the present invention comprises: In a preferred embodiment, the cosmetic composition for hair of the present invention comprises: (a) from about 0.5% to about 8.0% by weight of at least one organic acid selected from tartaric acid, lactic acid, glutaric acid, etidronic acid, salicylic acid and a mixture thereof, preferably from tartaric acid, lactic acid and mixtures thereof; (b) from about 0.1% to about 20.0% by weight of non-aqueous solvent comprising at least one compound with at least one hydroxyl group, said compound selected from polyols, C, to C, monoalcohols, and a mixture thereof; (c) from about 0.1% to about 7.0% by weight of arginine; (d) from about 0.1% to about 7.0% by weight of at least one fatty compound selected from vegetable oils, vegetable resins, vegetable waxes and mixtures thereof; (e) water and (D) from about 0.5% to about 7.0% by weight of a cationic surfactant selected from behentrimonium chloride, brassicamidopropyl dimethylamine, stearamidopropyl dimethylamine and mixtures thereof and from about 6.0% to about 9.0% by weight of a nonionic surfactant selected from cetearyl alcohol, stearyl alcohol and mixtures thereof. Another preferred embodiment of the cosmetic hair composition of the present invention comprises: (a) from about 0.5% to about 8.0% by weight of at least one organic acid selected from tartaric acid, lactic acid, glutaric acid, etidronic acid, salicylic acid and a mixture thereof, preferably from tartaric acid, lactic acid and mixtures thereof; (b) from about 0.1% to about 20.0% by weight of a non-aqueous solvent comprising at least one compound with at least one hydroxyl group, said compound selected from propylene glycol, C, to C monohydric alcohols, glycerin and a mixture thereof; (c) from about 0.1% to about 7.0% by weight of arginine; (d) from about 0.1% to about 7.0% by weight of Copaiba Officinalis (Balsam Copaiba) resin; (e) water, (£) from about 0.5% to about 7.0% by weight of a cationic surfactant selected from behentrimonium chloride, brassicamidopropyl dimethylamine, stearamidopropyl dimethylamine and mixtures thereof and from about 6.0% to about 9.0% by weight of a nonionic surfactant selected from cetearyl alcohol, stearyl alcohol and mixtures thereof. (g) from about 1.0% to about 5.0% by weight of at least one vegetable oil selected from coconut oil. In some embodiments, the compositions of the present disclosure include from about 0.5% to about 1.2% by weight of glycine. In some embodiments, the compositions of the present disclosure include from about 0.5% to about 5% by weight of esters selected from isopropyl esters (e.g., isopropyl palmitate), dialkyl esters (e.g., dicaprylyl carbonate), cetyl esters, and mixtures thereof. In another embodiment, the cosmetic hair composition of the present invention comprises: (a) from about 0.5% to about 2.0% by weight of tartaric acid and lactic acid; (b) from about 0.4% to about 3.5% by weight of propylene glycol, isopropyl alcohol and glycerin; (c) from about 0.75% to about 2.5% by weight of arginine and glycine; (d) from about 4.0% to about 6.0% by weight of Copaifera officinalis (balsam copaiba) resin and Cocos nucifera (coconut) oil; (e) water, (D from about 5.0% to about 9.0% by weight of cetearyl alcohol and behentrimonium chloride; (g) from about 1.0% to about 3.0% by weight of dicaprylyl carbonate and cetyl esters. A further suitable embodiment of the cosmetic hair composition of the present invention comprises: (a) from about 2.0% to about 4.0% by weight of tartaric acid; (b) from about 4.5% to about 9.5% by weight of propylene glycol, ethanol, isopropyl alcohol and cetearyl alcohol; (c) from about 0.5% to about 2.0% by weight of glycine; (d) from about 3.0% to about 5.0% by weight of Candelilla wax; (e) water, ({) from about 1.5% to about 2.5% by weight of behentrimonium chloride; (g) from about 2.0% to about 5.5% by weight of isopropyl palmitate, dicaprylyl carbonate and cetyl esters. EXAMPLES By way of non-limiting illustration, the invention will now be described with reference to the following examples. Examples 1 to 20 A suitable cosmetic composition for hair according to the state of the art is, as examples 1 to 2, as follows: [Tables 1] Function / Type | Amino acid Organic acid [Plant resin [Vegetable oil Non-aqueous solvent Non-aqueous solvent Non-aqueous solvent Surfactant | Surfactant Alkanolamine | Surfactant 1.50 1.0 |Various ingredients / additives |v= 2.0 |v= 2.0 one or more flavors, preservatives, vitamins Water Aqueous solvent a Water QSQS Suitable cosmetic compositions for hair according to the present invention are such as the following examples 3 to 10: [Tables 2] 11 40ILéUA2] |Ingredient |Ex. 3 |Ex. 4 |Ex. 5 |ex. 6 |Ex. 7 |Ex. #5 9 10 arginine 10 |1o |uo |no |Lo |1o |1o |1o tartaric acid 3.0 Copaifera resin of- 0.17 [0.17 [0.17 (0.17 10.17 |0.17 [0.17 0.17 | ficinalis (balsam copaiba) Cocos nucifera oil «Jé32 [432 [432 [4.32 4.32 |4.32 4.32 |432 | (coconut) , | 1 T 1 1 T 1 | 1 Propylene glycol 0.74 |0.74 |0.74 |0.74 10.74 |1.29 |0.74 |1.29 Ethano! 0.55 |- Isopropyl alcohol 0.54 Cetearyl alcohol 60 |s0 |so |so |so |so |6o | 6.0 Stearamidopropyl dime- |- F 15 [0.71 |1.0 |- | |L5 = |124 |186 1 + + 12 [12 [12 |1L2 |L2 |LS |- 2.37 |2.37 |2.37 |2.37 |2.37 |2.37 |- Cetearyl alcohol 60 60 60 60 6.0 160 (60 |6.0 Stearamidopropyl dime- |- F 1.5 [0.71 |1.0 |- | ethylamine Brassicamidopropyl dime- |- [L5 | [124 |L86 |- EU ethylamine triethanolamine 12 1.2 |1.2 |L2 |1.2 |1.5 |- |- Behen- 2.37 12.37 12.37 |2.37 |2.37 |2.37 |- | Trimonium chloride isopropyl palmitate 1.5 F | 1.25 [0.7 |1.5 | | Carbonate = 155 0.5 |2.42 |1.5 |- |- Cetyl esters 10 |10 1.0 |1.0 [1.0 |1.0 [10 |1.0 [Dicaprylyl carbonate [15 qL5 1.5 0.5 [2.42 1.5 |* | Cetyl esters 10 |10 [1.0 |10 [1.0 |1.0 [1.0 |1.0 one or more perfumes, | < / = | |d= | (<= = = conservateurs, vitamines |2.0 20 20 20 20 j20 20 20 Additional hair cosmetic compositions according to the present invention are examples 11 to 14, as follows: [Tables 3] PE — = DE Amino acid [arginine 1.0 1.0 1.0 1.0 Organic acid tartaric acid 1.17 Organic acid Lactic acid 0.36 [Vegetable resin Copaiferaofficinalis resin 0.17 [0.17 [0.17 |0.17 (copaiba balsam)] [Vegetable oil Cocos nucifera oil (coconut [432 [432 [432 |432 coconut)] Non-aqueous solvent | |propylene glycol [The 129 129 129 pa non-aqueous [isopropyl alcohol |- |- 0.54 |0.54 || | [054 |o.54 60 |60 |60 |60 in pot 1 [14 j14 + + [Surfactant [stearyl alcohol 20 3.0 |- | |Surfactant Stearamidopropyl dime- [La j14 + |Non-aqueous solvent |propylene glycol Non-aqueous solvent |isopropyl alcohol Surfactant cetearyl alcohol |Surfactant stearyl alcohol - |Surfactant Stearamidopropyl dimethylamine Alkanolamine triethanolamine |Surfactant behentrimonium chloride - 045 [05 |07 |07 TE 2.37 |L5 Juice |1s | 15 |L5 |L5 |Lo Lo [Lo io |Lo isopropyl palmitate dicaprylyl carbonate cetyl esters one or more flavors, preservatives, vitamins water <J= <= <= dJ= 2.0 2.0 2.0 2.0 Gr hr as es Other cosmetic compositions for hair according to the present invention are such as Examples 15 to 19, as follows: [Tables 4] [Vegetable oil [Coconut oil [32 4.02 0.57 [079 Ja16 0.54 Jo54 Joss Joss Joss [125 |L29 [15 [15 10 | 046 |jo76 [023 |104 Function / Type Ingredient Ex.15 |Ex.16 |Ex.17 |Ex.18 |Ex.19 |Amino acid larginine 1.0 1.0 1.0 1.0 1.0 Amino acid elycine |- 105 |o67 086 Organic acid tartaric acid |1.17 1.09 0.8 0.69 1.11 Organic acid |Lactic acid |- 0.79 0.99 0.17 |Vegetable resin [Resin of 0.17 0.17 0.17 0.17 0.17 Copaiferaofficin lis (balsam copaiba) [Vegetable oil [Coconut oil |4.32 |402 Jos? jo |&16 nucifera (coconut) Non-aqueous solvent iso- 0.54 0.54 0.54 0.54 0.54 propyl alcohol Non-aqueous solvent propylene [129 [129 | 1.29 | 1.29 | 1.29 aqueous glycol Non-aqueous solvent [glycerin | 0.46 0.76 0.23 | 1.04 |v=20 |v= 2.0 |v= 20 |d=20 |4=20 game |Surfactant ce- [6.0 |6.0 [6.0 [6.0 [6.0 téaryl alcohol |Surfactant be- |2.37 2.37 2.37 237 2.37 hentrimonium chloride |Ester Di-[10 [10 [Lo L0 LO caprylyl carbonate Ester Cetyl esters |1.0 1.0 1.0 1.0 1.0 Miscellaneous ingredients / |one or more |v= 20 | < / =2.0 |ÿ=2.0 |d= 2.0 |d= 2.0 Additifs parfums, conservateurs, vitamines Alcanolamine triéthanolamine |0,7 0,5 0,5 0,5 0,5 Solvant aqueux |eau Q.s. Q.S. Q.S. Q.S. Q.S. The pH of the formulation examples of the invention ranged from about 3 to about 4. It It was also found that the presence of the esters in the formulation examples of the invention and / or the vegetable waxes improved the spreading of the formulas during the application of the formulations to the hair. TESTS Test 1- Application and evaluation | duration (d: è A cosmetic composition for hair according to Ex. 8 of the present invention was compared with a state-of-the-art composition comprising water, cetearyl alcohol, stearamidopropyl dimethylamine, dimethiconol, glycerin, perfume, lactic acid, paraffin oil, methylparaben, petrolatum, dimethyloldimethylhydantoin, disodium EDTA, cyclopentasilane, methoxypolyoxymethylene mamine, arginine, trimethylsiloxysilicate, benzyl benzoate, butylphenyl methylpropional, citronellol, geraniol, hexyl cinnamal, limonene, linalool. In a randomized in vivo study on a half-head (curly type) of human volunteers, both hair cosmetic compositions were applied simultaneously to wet hair and evaluated with respect to various cosmetic attributes. The consumer / volunteer reports whether there is a difference / no difference in the performance of the attributes and, if there is, describes it according to the intensity of the product difference (slight, medium, high or the same). Assessments were made at 4 time points: during application, while the hair was wet, after the hair had become dry (without breaking the coating on the hair surface), and after breaking the coating on the hair (by running fingers or a comb or brush through the hair). When applying the hair cosmetic composition to wet hair, consumers / volunteers noticed a noticeable increase in product penetration into the hair (as assessed by product spread from roots to ends of hair and cosmetic feel during application). Better and longer-lasting results were achieved. The hair cosmetic composition according to Ex. 8 provided better curl definition for all consumers / volunteers, as well as improved manageability for the majority of consumers / volunteers after the coating on the hair broke. Furthermore, the volunteers stated that after a second application of the cosmetic hair compositions the following day, the composition according to Ex. 8 provided greater flexibility and definition of the hair curls. In summary, the Formula of Ex. 8 provided significantly better and longer-lasting curl definition to the hair, significantly improved the care routine and hair treatment by replacing several products in the routine and does not need to be reapplied, which extended the interval between washes and allowed less product to be applied to the hair. With a reduction in the amount of product required, an improvement in cosmetic effects was achieved, including hair remaining light and natural. Test 2 - User Experiences In two separate studies, the cosmetic hair compositions according to Ex. 13 and Ex. 14 of the present invention were each compared to a state-of-the-art composition comprising water, cetearyl alcohol, stearamidopropyl dimethylamine, dimethiconol, glycerin, fragrance, lactic acid, paraffin oil, methylparaben, petrolatum, dimethyloldimethylhydantoin, disodium EDTA, cyclopentasilane, methoxypolyoxymethylene melamine, arginine, trimethylsiloxysilicate, benzyl benzoate, butylphenyl methylpropional, citronellol, geraniol, hexyl cinnamal, limonene, linalool. For each randomized in vivo study on hair (curly type) on half a head of human volunteers, six consumers / volunteers used the cosmetic hair composition according to Ex. 14 as a leave-in refreshing / styling treatment on the hair after washing their hair with the cosmetic hair composition according to Ex. 14, without the need for touch-ups for up to three days. The volunteers observed that curl definition was maintained for increasingly longer intervals between washes, which gained an additional day in the curly hair routine between applications for most consumers / volunteers. In particular, the use of the cosmetic hair composition according to Ex. 14 gained two additional days without the need to reapply the cosmetic hair composition of the invention. Thus, the cosmetic hair composition according to the invention did not have to be reapplied to the hair until the 3rd or 4th day after the first application. In summary, Ex. 14 provided long-lasting cosmetic effects and benefits to the hair, lasting until the day after reapplication, approximately 3 to 4 days after the first application. This eliminated the need to use multiple products on the hair or to use multiple applications of a product on the hair on the same day or the day after the first application. It was also observed that a good balance between curl definition and a light feel on the hair was achieved. These cosmetic effects and benefits were achieved by applying only a small amount of the cosmetic composition for hair according to the disclosure to the hair. In comparison, consumers / volunteers reported that while using the Although the product was mentioned as having the highest quality composition, it was necessary to reapply the product several times a day as the curl definition did not last long. They also observed product buildup over multiple applications due to the need for multiple touch-ups, which resulted in a shorter wash interval for the curly hair routine. Similar results were obtained when comparing the hair cosmetic composition according to Ex. 13 with a state-of-the-art composition. In the first application, the application of the inventive composition according to Ex. 13 resulted in more individualized hair fibers. Furthermore, the inventive composition according to Ex. 13 tended to penetrate the hair more and, in the wet hair phase, the hair treated with the inventive composition according to Ex. 13 had better definition and regularity of the curls and less coating. On the first day after the first application, the hair of the volunteers who were treated with the inventive composition according to Ex. 13 was better disciplined and had better frizz control, more flexibility and a better visual appearance. The day after reapplication of the test compositions to the hair (i.e., the last day of the study), it was observed that the hair cosmetic composition according to Ex. 13 provided better definition, greater curl regularity and better control of hair volume compared to the peak composition. Test 3 - Purely comparative evaluation A cosmetic composition for hair according to Ex. 12 of the present invention was compared with a state-of-the-art composition comprising water, cetearyl alcohol, stearamidopropyl dimethylamine, dimethiconol, glycerin, perfume, lactic acid, paraffin oil, methylparaben, petrolatum, dimethyloldimethylhydantoin, disodium EDTA, cyclopentasilane, methoxypolyoxymethylene melamine, arginine, trimethylsiloxysilicate, benzyl benzoate, butylphenyl methylpropional, citronellol, geraniol, hexyl cinnamal, limonene, linalool. The hair cosmetic composition according to Ex. 12 and the advanced composition were each tested in a randomized in vivo half-head study on the hair (curly type) of 6 human volunteers. The hair cosmetic composition according to Ex. 12 exhibited better performance in terms of manageability attributes (more discipline and less volume and frizz) compared to the results obtained using the advanced composition, in addition to greater curl regularity and better visual appearance on the first day after the first application. On the second following day, the hair treated with the inventive composition retained the attributes of curl regularity and better visual appearance, but showed more frizz, with a reduction in cosmeticity. Test 4 — In vitro tests on hair strands The formulations according to Examples 14, 16, 17, 18 and 19 and the peak composition were applied to virgin curly hair strands (three strands of 2.7 grams per formulation), and were evaluated according to a curl definition score (from 0 to 10) at 24 hours after treatment of the hair (T24, 1st time point), before breakdown of the coating on the hair (2nd time point), and after breakdown of the coating (passing fingers or a comb or brush through the hair) (3rd time point). The higher the score, the greater the degree of curl definition. The formulation of Ex. 14, 16, 17, 18 and 19 and the peak composition had a curl score of about 7.5 to about 8.8 at the 1st and 2nd time points. The formulation of Ex. 14, 16, 17, 18 and 19 and the peak composition had a loop score of about 7.4 to about 9 at the 3rd time point. The formula in Ex.18 had a loop score of about 6 to about 6.5.

Claims

Claims

1. Cosmetic hair composition comprising: (a) at least one organic acid; (b) a non-aqueous solvent comprising at least one compound with at least minus one hydroxyl group; (c) at least one amino acid; (d) at least one fatty compound chosen from vegetable oils, vegetable resins, vegetable waxes and their mixtures; (e) water and (f) at least one surfactant selected from cationic surfactants, non-ionic surfactants and their mixtures.

2. A composition according to claim 1, wherein the organic acid is selected from short-chain α-hydroxy acids (AHAs), beta- hydroxy acids and a mixture thereof, preferably at least one organic acid is chosen from tartaric acid, lactic acid, glutaric acid, etidronic acid, salicylic acid, acid glycolic acid, citric acid and their mixtures, the amount of acid organic ranging from 0.1% to 25.0% by weight, relative to the total weight of the composition.

3. A composition according to claim 1, wherein the non-solvent aqueous comprising at least one compound with at least one group hydroxyl is selected from polyols, C, to C, monoalcohols, and their mixtures, in which the polyol is chosen from propylene glycol, dipropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, glycerin and mixtures thereof, wherein the amount of the non-aqueous solvent comprising at least one compound with at least one hydroxyl group ranges from 0.1% to 20.0% by weight, by relative to the total weight of the composition.

4. Composition according to claim 1, in which the at least one acid amino acid is selected from arginine, glycine and mixtures thereof, in in which the amount of the at least one amino acid ranges from 0.1% to 7.0% in weight, relative to the total weight of the composition.

5. Composition, according to claim 1, in which the at least one fatty compound comprises plant resins selected from resin Copaiba Officinalis (Balsam Copaiba) (oily resin or in the form of resin), Candeia resin, breu branco resin and their mixtures, in in which the amount of the at least one fatty compound ranges from 0.1% to 14.0% by weight, relative to the total weight of the composition.

6. A composition according to claim 1, wherein the at least one fatty compound includes vegetable oils selected from oil coconut, soybean oil (soybean oil) and their mixtures.

7. A composition according to claim 1, wherein the at least one fatty compound comprises vegetable waxes chosen from Candelilla, Carnauba wax, beeswax and mixtures thereof.

8. A composition according to claim 1, wherein the at least one ten- surfactant comprises at least one cationic surfactant is a salt quaternary ammonium chosen from the following elements: chloride cetrimonium, stearimonium chloride, behen- chloride trimonium, behentrimonium methosulfate, behentrimonium methosulfate midopropyltrimonium, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, chloride dicetyldimonium, tricetylmonium chloride, and / or at least one cationic surfactant is a selected amino-amide cationizable surfactant among the following: oleamidopropyl dimethylamine, linoleami- dopropyl dimethylamine, isostearamidopropyl dimethylamine, stearami- dopropyl dimethylamine, behenamidopropyl dimethylamine, behenami- dopropyldiethylamine, behenamidoethyldidiethylamine, behenamidoé- thyldimethylamine, arachamidopropyldimethylamine, arachamido- ethyldimethylamine arachamido-propyldiethylamine, arachidamido- thyldiethylamine, brassicamidopropyldimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine, palmitamidopropyl dimethylamine and mixtures thereof, in which the amount of the at least one cationic surfactant ranges from 0.05% to 15.0% by weight, relative to the total weight of the composition.

9. Composition, according to claim 1, in which the at least one ten- surfactant includes at least one non-ionic surfactant selected from at least minus one fatty alcohol selected from cetearyl alcohol, alcohol cetyl alcohol, stearyl alcohol, lauryl alcohol, myristyl alcohol, an alkoxylated alcohol, and mixtures thereof, wherein the amount of the less fatty alcohol ranges from 1.0% to 12.0% by weight, relative to the total weight of the composition.

10. Composition, according to claim 1, further comprising at least one ester selected from isopropyl palmitate, dicaprylyl carbonate, cetyl esters and mixtures thereof, in which the amount of the less one ester ranges from 0.5% to 10.0% by weight, relative to the total weight of the composition.