Powdered fuel alternative

Abstract

The present invention relates to a method for producing a powdered alternative fuel by grinding pellets, the pellets being produced by the following steps: (i) providing a waste material comprising greater than 40% by total dry weight of the waste material of one or more thermoplastic materials and greater than 30% by total dry weight of the waste material of one or more cellulosic materials, the waste material having a particle size distribution of greater than 80% by weight greater than 5 mm and greater than 95% by weight less than 60 mm, and a moisture content of about 8% by weight or less; (ii) passing the waste material through a pelletizer having 4-8 mm holes and a length ratio greater than 10 to achieve an output temperature of about 85° C. or less; (iii) passing the pellets through a second pelletizer having 2-8 mm holes and a length ratio greater than 14 to achieve an output temperature of about 110° C. or more; (iv) providing the pellets; and (v) cooling the pellets to a temperature of about 30° C. or less. The powdered alternative fuel can be transported in bulk through an injection line.

Description

[Technical field]

[0001] The present invention relates to powdered alternative fuels, processes for preparing such powdered alternative fuels from waste materials, and uses thereof. [Background technology]

[0002] Municipal waste remains a significant problem. Currently, waste is generally sorted and valuable fractions are separated. However, recycling is difficult because many different components are present in varying amounts. Furthermore, mixed waste streams, such as mixtures of plastics and paper (or cellulose fibers in general), are light fractions for which suitable outlets remain a challenge.

[0003] One of the uses of such light fractions is its use as an alternative fuel, also called secondary fuel. The cheapest way to use this fraction is as obtained after sorting. This fraction is a fluff-like material, hence the name fluff. Fluff is difficult to transport (unless packaged, it is difficult to obtain a fluff fraction that can be used as fuel). Another disadvantage of fluff is that it is very heterogeneous and can only be burned in "low-end" furnaces (i.e. furnaces without a concentrated flame).

[0004] The fluff can be pelletized to improve transport and handling characteristics. The pellets can be easily transported over long distances and can be used as whole pellets in certain fuel applications or can be crushed before use as fuel. In general, pellets or crushed pellets can be used as a partial replacement for the primary fuel (coal, peat or oil). However, it has been extremely difficult to provide an alternative fuel that can be easily transported, used without further crushing, and used in high-end furnaces, preferably to completely replace the primary fuel.

[0005] Additionally, alternative fuels currently require additional investment in one or more of adapted burners, adapted distribution systems, grinders, and the like.

[0006] Combustion in industrial furnaces is a process used, for example, in the production of electricity. Furnaces for producing electricity are the most demanding and efficient furnaces currently in use. Other industrial furnaces that require high process stability are blast furnaces in steel production, cement kilns and lime kilns.

[0007] Typically, furnaces are fed with powdered coal (pulverized coal), oil or gas (as the primary fuel). The fuel is typically fed through a number of burners, lances (or tuyere). When the furnace is used to produce electricity, the heat of combustion is used to generate steam, which is used to drive a turbine.

[0008] The amount of pulverized coal that can be introduced depends on the quality of the coal and coke, the geometry of the furnace, and the operating practices. Furthermore, pulverized coal has a low bulk density and poor storage properties. Therefore, the coal is pulverized immediately before use. The main drawback of pulverized coal is the fact that it comes from a non-renewable source and therefore causes substantial CO2 emissions.

[0009] To reduce the burden of CO2 emissions, alternative fuels, i.e. secondary fuels, are also used to some extent. Such alternative fuels need to allow their use in a seamless process. They should be transportable before and after grinding. Furthermore, alternative fuels need to be able to be introduced into the flame where they should exhibit good combustion characteristics (sufficient combustion in hot spots and time to virtually complete combustion).

[0010] Alternative fuels proposed for use in high-end industrial furnaces include plastic pellets, mixed plastic / biomass pellets, wood pellets, and sewage sludge pellets.

[0011] One advantage of using only plastic waste is that it generally has a low thermal conductivity and a high energy content. A disadvantage of using only plastic waste is that such mixtures, e.g. from household waste, municipal waste or urban waste, are relatively valuable products that can be used to make (recycled) plastic products. A further disadvantage is that, despite the high calorific value, waste plastic pellets are difficult to process to obtain a suitable particle size distribution. Grinding causes a temperature increase and causes the rubbery behavior of the plastic to such an extent that cryogenic grinding is required. However, cryogenic grinding is too expensive.

[0012] A disadvantage of mixed plastic / biomass pellets in particular is that the pellets need to be ground near the furnace because the powder flow characteristics of the ground pellets are such that they cause substantial handling problems for transport from the mill to bulk shipping containers, then to bulk storage containers, and then for use. In particular, the powder has a significant amount of fibrous material that causes lumps or tufts, thus blocking the pipes. Therefore, the pellets are transported to the furnace and the grinding operation is carried out immediately prior to transport to the furnace.

[0013] Wood pellets have a relatively low energy content and are therefore less attractive for high-end burners. Furthermore, the use of wood pellets is increasingly suspected to be environmentally unfriendly as forests are cut down, while drying and transportation require significant energy. Sludge pellets, in addition to wood pellets, have an even lower energy content and a relatively high ash content, which is a drawback.

[0014] Alternative fuels are only used in practice to partially replace fossil fuels in high-end furnaces. Generally, in practice, the amount of alternative fuel is less than 30% relative to pulverized coal, but in any case less than 50%. Pulverized coal is a relatively homogeneous material, and the substantial base load of coal dampens the variability of the waste-derived pellet material.

[0015] WO 2020 / 127473 describes a process for making pellets that can be ground into particulate material that allows high-end furnaces to be 100% fired with alternative fuels.

[0016] Additionally, there is a continuing need for processes where the alternative fuel is in a form that can be easily used by companies that have furnaces without the need to have a mill nearby. In particular, there is a need for powdered alternative fuels that can be blown multiple times through the transfer pipes without causing clogging, allowing for uniform distribution to multiple burners. [Prior art documents] [Patent documents]

[0017] [Patent Document 1] International Publication No. 2020 / 127473 Summary of the Invention

[0018] The object of the present invention is to provide a powdered alternative fuel that can be transported through pipes via bulk transportation by gas injection without clogging and can be used to reliably replace fossil fuels in all furnaces including high end industrial furnaces, cement or lime kilns or blast furnaces used in modern installations for producing electricity, for example.

[0019] In a first aspect, the present invention provides a process for producing pellets from municipal and / or other waste materials which can be ground to provide a free-flowing powdered fuel suitable for transport, comprising the steps of: (i) a waste material comprising greater than 40% of one or more thermoplastic materials, based on the total dry weight of the waste, and greater than 30% of one or more cellulosic materials, based on the total dry weight of the waste, comprising the steps (ii) providing a waste material, the waste material provided having a particle size distribution of more than 80% by weight greater than 5 mm and more than 95% by weight less than 60 mm, and having a moisture content of about 8% by weight or less; -(ii) passing the waste material through a pelletizer having holes of 4-8 mm, preferably 4-6 mm, and a length ratio of greater than 10, so that the product temperature is about 85°C or less; - (iii) passing the pellets through a second pelletizer having holes of 2-8 mm, preferably 4-6 mm, and a length ratio of more than 14, so that the product temperature is about 110°C or higher; - (iv) providing pellets having a diameter of 2-8 mm and a length of about 3 mm or more, preferably more than 8 mm, the pellets having a product temperature of 110-130°C; -(v) cooling the pellets to a temperature of about 40°C or less, preferably about 30°C or less.

[0020] A second aspect of the invention provides that the pellets are milled, for example in a hammer mill, after cooling to obtain a powder exhibiting good flow properties.

[0021] A further aspect of the present invention is a powdered alternative fuel having the following characteristics: - a mixture of 40-70% by weight of a thermoplastic material and 30-50% by weight of one or more cellulosic materials, preferably a substantially homogeneous mixture, preferably previously largely melted; - a particle size distribution such that more than 50% by weight of the particles are between 1 and 3.5 mm and more than 60% by weight are smaller than 2 mm; Angle of repose -41-43°; - Bulk density (tapped) of approximately 220 g / L or more The present invention relates to a powdered alternative fuel having the following properties:

[0022] Powdered alternative fuels can unexpectedly be transported through blowpipes in bulk containers and the like without causing blockages or handling problems.

[0023] Thus, the present invention also relates to a shipping container for road, rail or ship traffic having at least about 1 ton, preferably at least about 3 tonnes, of a bulk powdered alternative fuel as described herein.

[0024] The present invention further relates to a method of transporting a powdered alternative fuel, wherein the bulk powdered alternative fuel as described herein is moved at least 1 kilometer in a shipping container for road, train or ship traffic, the container having about 1 ton or more, preferably about 3 ton or more, of the bulk powdered alternative fuel.

[0025] This powdered alternative fuel can completely replace pulverized coal in industrial furnaces such as those used in cement kilns, electrical manufacturing plants, and blast furnaces. It is also possible to only partially replace pulverized coal in such applications, as such a choice may be based on simple economics. Dosing can be accomplished using existing equipment installed for coal / lignite, and distribution to one or more burners generally does not require additional investment.

[0026] Further benefits and advantages of the present invention will become apparent in the detailed description. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0027] In a first aspect, the present invention provides a process for producing pellets comprising the steps of: (i) providing a waste material comprising greater than 40% by weight of one or more thermoplastic materials, based on the total dry weight of the waste, and greater than 30% by weight of one or more cellulosic materials, based on the total dry weight of the waste, wherein the waste provided in step (ii) has a particle size distribution of greater than 80% by weight greater than 5 mm and greater than 95% by weight less than 60 mm, and has a moisture content of about 8% by weight or less; (ii) passing the waste material through a pelletizer having holes of 4-8 mm and a length ratio of greater than 10 such that the product temperature is about 85° C. or less; (iii) passing the pellets through a second pelletizer having holes of 2-8 mm and a length ratio of greater than 14 such that the product temperature is about 110° C. or greater; (iv) providing pellets having a diameter of 2-8 mm and a length of about 3 mm or more, preferably greater than 8 mm, the pellets having a product temperature of 110-130° C.; (v) cooling the pellets to a temperature of about 40° C. or less, preferably about 30° C. or less.

[0028] Waste materials The term "thermoplastic material" means a thermoplastic polymer. The waste material used to prepare the pellets of the present invention comprises at least 40% thermoplastic material, preferably at least 45% or at least 50% by weight of thermoplastic material (such as about 55% or about 60% by weight of thermoplastic material).

[0029] Generally, the amount of plastic material in the pellets will be about 80% or less, preferably 70% or less. Suitable ranges therefore include 40-80% by weight plastic, or most preferably 50-70% by weight plastic.

[0030] Examples of thermoplastic polymers for use herein are listed in US Patent Application Publication No. 2010 / 0116181. Typically, the thermoplastic material or component may be packaging material or any type of plastic waste.

[0031] Preferably, at least 20% by weight of the thermoplastic material is a polyethylene homo- or copolymer, more preferably at least 40% by weight, even more preferably at least 50% by weight, and most preferably at least 60% by weight.

[0032] The term "cellulosic material" as used in the present invention relates to, for example, paper, cardboard, wood, cardboard, cotton, rayon and / or viscose and other textiles. The waste material used in the present invention comprises at least 30% by weight of cellulosic material, preferably 35% by weight or more of cellulosic material. Generally, the amount of cellulosic material is about 60% by weight or less, preferably about 50% by weight or less of cellulosic material, based on the total dry weight of the pellet. A suitable range includes 30-60% by weight of cellulosic material, preferably 30-50% by weight of cellulosic material. Cellulosic material can also be referred to as biomass.

[0033] The waste material generally originates from municipal waste or other waste streams. Mixed plastic / biomass waste (containing different types of plastics and biomass / paper) is generally considered to be "non-recyclable" material. This type of waste material is considered to be very heterogeneous, causing considerable difficulties in continuous processing. The process of the present invention converted the very heterogeneous material into a substantially homogeneous material (in the form of pellets). By substantially homogeneous, it is meant that in a sample size equal to the volume of the pellet, there is less than 5% by weight of separately identifiable material upon disruption of the pellet. The grinding of the pellets thereby results in a ground material that can be handled in various processing steps.

[0034] The pellets can be produced by selecting waste plastics and biomass, such as from garbage or paper recycling plants. Different selected waste streams can be used in combination to achieve the required mix of plastic and cellulosic materials. The feedstock is chopped to a size of 5 cm or less, preferably 4 cm or less in the largest dimension. In a further embodiment, the feedstock is chopped to a size of about 3.5 cm or less, preferably about 2.5 cm.

[0035] Preferably, the waste has a particle size distribution such that more than 80% by weight is greater than 5 mm and more than 95% by weight is less than 60 mm. Preferably, more than 90% by weight is less than 40 mm. In a more preferred embodiment, the waste has a particle size such that about 20% by weight or more has a size greater than 30 mm.

[0036] The material is dried to a moisture content of 8% by weight or less, and the material is pressed through a die having suitable holes. Preferably, the moisture content of the material fed to the first die is about 2% to about 5%. Too high a moisture content may prevent sufficient melting of the plastic. This is because it is believed that the temperature may not rise high enough to cause sufficient melting of the plastic.

[0037] Drying is preferably carried out after shredding.

[0038] The temperature of the material fed to the first die is preferably about 30 to 50°C, more preferably about 35 to 45°C.

[0039] Pelletization As used herein, the term "pellet" or "pellets" is used to refer to the pellets of the present invention that include one or more thermoplastic materials and one or more cellulosic materials. The pellets are not limited by the degree of heterogeneity.

[0040] The pelletizer dies are preferably cylindrical dies, although flat dies are known and can be used as well, and a first flat die and a second cylindrical die can be used, or a first cylindrical die and a second flat die can be used.

[0041] Preferably, the diameter of the holes in the first and / or second pelletizer is 4, 5 or 6 mm.

[0042] Preferably, the diameter to thickness ratio of the first die is 10-16, preferably 12-14.

[0043] Preferably, the second die has a diameter to thickness ratio of 14-20, preferably 16-20.

[0044] The favorable diameter to thickness ratio also allows for smooth operation with respect to the temperature of the product of each die.

[0045] Preferably, the first die is operated such that the temperature of the product (pellets) is between 60 and 80°C.

[0046] Typically, there will be a buffer vessel between the first and second pelletizers to facilitate operation. Preferably, the buffer vessel has means for measuring the pellet level and the pellet temperature. The buffer vessel is preferably isolated and / or includes heating means to keep the pellets at the required temperature as described below.

[0047] The temperature of the material supplied to the second die is preferably about 50 to 80°C, and more preferably about 60 to 75°C.

[0048] Preferably, the second die is operated such that the temperature of the product (pellets) is between 110 and 130° C. Preferably, the product temperature is between 115 and 125° C. (such as about 120° C.).

[0049] Preferably, the temperature increase of the product of the first die and the product of the second die is about 40° C. or more, preferably about 45° C. or more. This allows for proper melting of the plastic in the second die without becoming too sticky.

[0050] pellet The pellets have a uniform size range (diameter) generally within the range of 4-8 mm, preferably 6-8 mm, and most preferably about 6 mm. The length of the pellets is generally 3-50 mm, preferably greater than 8 mm, more preferably 10-40 mm, and even more preferably 15-25 mm.

[0051] The heating value or calorific value or calorific heating value of any fuel is the energy released per unit mass or volume of the fuel when it is completely burned. This amount is determined by returning all the combustion products to the original pre-combustion temperature, and in particular by condensing the steam produced. In other words, this amount is the amount of heat released during the complete combustion of a particular amount of fuel.

[0052] Calorimetry measures the higher heating value (HHV) and uses the following procedure: A sample is completely combusted using pure oxygen, which then produces carbon dioxide and water. The water is initially produced as steam. However, once the entire sample is combusted (i.e., the test is complete), the water vapor condenses. This condensation process releases additional heat. Technically, this additional heat is the latent heat from the conversion of water from a steam to a liquid phase. The combination of the heat released during the combustion of the sample and the subsequent heat released during the conversion of water vapor to a liquid allows the maximum heat to be obtained. This is known as the Higher calorific value (HCV) or Higher heating value (HHV).

[0053] If the process keeps the produced water in a steam state, no latent heat is recovered. This is known as the Lower calorific value (LCV) or Lower heating value (LHV). LHV is only the heat of combustion and does not include the heat released during condensation of the water vapor. LHV is an important measurement for most combustion systems that convert heat to power or energy.

[0054] The HHV and LHV are effective for the complete combustion of fuel into CO2 and H2O.

[0055] The calorific value (LCV) of pellets is generally about 19-28 GJ / tonne, which is lower than fully plastic materials, which generally have a calorific value of 31-35 GJ / tonne (on a dry weight basis).

[0056] Preferably, halogen elements such as chlorine are present in the pellets in an amount of less than 1 wt.%, more preferably less than 0.3 wt.%, as high loadings of this element can cause corrosion in dry and / or wet gas cleaning systems, as well as chlorine emissions with the drain water of top gas scrubbers.

[0057] The oxygen content of the pellets is preferably in the range of 20 to 30 w % of the dry weight of the pellets.

[0058] The hydrogen content of the pellets is preferably in the range of 6 to 8 w % of the dry weight of the pellets.

[0059] Preferably, the pellets may contain up to 5% moisture by weight, although the moisture content may be less than 2% or even less than 1%.

[0060] Preferably, the strength of the pellets is about 10 kgf or more, more preferably about 15 kgf or more. Generally, the strength is about 40 kgf or less, and often about 25 kgf or less. However, it is possible to have harder pellets, for example having a strength of up to 70 kgf or less, such as 60 kgf or less. It may be preferable to have a strength of about 30 kgf or less.

[0061] The pellets obtained by one pelletization have a hardness of about 15 kgf, whereas two pelletizations according to the method of the present invention increased the hardness to more than 20 kgf, e.g. 22 kgf. The pellets of the present invention most preferably have a hardness of 20-25 kgf, at which hardness a very suitable powder is obtained, which appears to be capable of long distance transportation. This powder did not (or showed very few) problems caused by poor flow behavior caused by plastic strands, fluffy agglomerates, etc.

[0062] Hardness can be measured with a Kahl pellet hardness tester available from Amandus Kahl GmbH & Co KG, Hamburg. The Kahl pellet hardness tester is one of the standard testing methods in the industry.

[0063] Sufficient strength also has the advantage that the pellets have a relatively high density, which allows for efficient transport of the pellets themselves, and strength prevents the formation of large amounts of fines during transport.

[0064] These pellets unexpectedly allow for bulk shipping of powdered alternative fuels after crushing of the pellets.

[0065] The pellets obtained according to the present invention have a high bulk density. The pellets according to the present invention generally have a bulk density of 500 g / L, preferably 520 g / L or more, and even more preferably about 540 g / L or more, such as about 550 g / L. Generally, the density is 600 g / L or less.

[0066] Preferably, the pellets have a bulk density of 540 g / L or greater.

[0067] Crushed and powdered alternative fuels The pellets can be ground in a hammer mill (eg, a 11.5×28 with a 6.4 mm or 3.5 mm screen and a tip speed of 108 m / sec, such as a California Pellet Mill).

[0068] Pellets according to WO2020 / 127473 are described as being ground on a 6.4 mm screen. Smaller screen sizes can cause such pellets to be ground, producing excessive fluffiness or tufts and reducing transportability. Furthermore, pellets according to the present invention can be ground on a 3.5 mm screen and still produce a powder that can be easily transported without clogging.

[0069] The pellets obtained or obtainable by the process of the present invention can be ground in a hammer mill so that the powder exhibits good flowability and preferably so that 30-60% by weight of the powder has a particle size of 1-2 mm and more than 80% by weight is less than 2 mm.

[0070] The resulting particles preferably have a bulk density (tap) of 220 g / L or greater.

[0071] The pellets, when ground in a hammer mill, are substantially free of strand-like material that would cause tufting, which is believed to be detrimental to flow properties, unlike material that has been pelletized once.

[0072] The pellets are crushed into relatively small particles less than 3.15 mm. Generally, the percentage of particles larger than 3.15 mm is about 15% by weight or less, preferably about 10% by weight or less, and even more preferably about 7.5% by weight or less.

[0073] More preferably, greater than 95% by weight, more preferably greater than 98% by weight, of the ground material is smaller than 5 mm. Further, the particles are not dusty.

[0074] (Tapped) bulk density is measured as follows: a quantity of pellets is poured into a 100 mL cylinder (diameter 2.5 cm) and the amount of pellets present is measured in grams. Tapping is performed by placing the beaker on a vibrating surface (0.5 mm vertical vibration: 240 times / min) for 5 minutes and measuring the volume of the pellets. Tapped density is the amount in grams divided by the measured volume.

[0075] Comminution is tested in a hammer mill (California Pellet Mill, 11.5×28) with a screen with holes of 3.5 mm diameter and a tip speed of 108 m / s.

[0076] The bulk density (tap) of the crushed pellets (particulate material) is generally greater than or equal to 220 g / L, preferably greater than or equal to 230 g / L.

[0077] Preferably, the average particle size of the ground particles is less than 2.5 mm, preferably greater than 1 mm.

[0078] The angle of repose of material suitable for transport obtained by double pelletizing has a well-defined angle of repose which is greater than the angle of repose of fluff or crushed pellets obtained by pelletizing through a single die.

[0079] The angle of repose of a granular material is the steepest angle of descent or inclination with respect to a horizontal surface at which the material can be piled without falling. At this angle, the material on the inclined surface is at the boundary of sliding. The angle of repose can range from 0° to 90°. The morphology of the material affects the angle of repose. Smooth, rounded sand grains cannot be stacked as steeply as coarse, interlocking sand. The angle of repose may also be affected by the addition of solvents. If a small amount of water can fill the gaps between the particles, the electrostatic attraction of the water to the mineral surface increases the angle of repose, and related quantities such as soil strength. When bulk granular material is poured onto a horizontal surface, a cone-shaped pile is formed. The included angle between the surface of the pile and the horizontal surface is known as the angle of repose and is related to the density, surface area and shape of the particles, as well as the coefficient of friction of the material. Materials with smaller angles of repose form flatter piles than materials with larger angles of repose.

[0080] The angle of repose has been measured in two ways. In the first method, 500 grams of material is poured through a funnel with a distance of 20 cm to the table and a funnel outlet width of 3 cm in diameter. The material forms a small deposit whose height and diameter can be measured. The angle calculated from the height and radius can be used as the angle of repose. The second method is the tilted table method, in which the table on which the material is present in a thin layer is slowly tilted until the material starts to move. The angle at which the material starts to move is the angle of repose.

[0081] The results of the two methods are shown in the following table.

[0082] [Table 1]

[0083] The present invention also provides a powdered alternative fuel having the following characteristics: - a mixture of 40-70% by weight of a mostly molten thermoplastic material and 30-50% by weight of one or more cellulosic materials, preferably a substantially homogeneous mixture, preferably mostly molten; - a particle size distribution such that more than 50% by weight of the particles are between 1 and 3.5 mm and more than 60% by weight are smaller than 2 mm; Angle of repose -41-43°; - Bulk density (tapped) of approximately 220 g / L or more The present invention relates to a powdered alternative fuel having the following properties:

[0084] Grinding in an industrial setting is generally carried out in a suitable mill such as a hammer mill, a jet mill, etc. Preferably, a hammer mill is used.

[0085] transportation The powdered alternative fuel can be transported through blowing pipes such as bulk containers, unexpectedly, without causing handling problems. The transport by blowing can be done using a gas, which can be any suitable gas, such as air or a carbon dioxide rich gas, such as flue gas. Furthermore, a conveyor belt can be used without handling problems.

[0086] Thus, the present invention also relates to a shipping container for road, rail or ship traffic having at least about 1 ton, preferably at least about 3 tonnes, of a bulk powdered alternative fuel as described herein.

[0087] Shipping containers are well known and are preferably standard containers such as road bulk carriers, ships, bulk carriers that may be deployed during rail transport, or road container carriers. 3walking floor containers of 60-65-90m can be used, which can be filled through a conveyor and emptied via a conveyor or by using a blowing device. 3 Silo containers of 100m2 are available, which can be filled / emptied e.g. through a blowpipe. For example, a 6m tank-type container can be used with a nominal loading capacity of about 26 tonnes. If the bulk density is e.g. 220 kg / tonne, then about 5.5-6 tonnes of material can be loaded into such a container. A 12m container can be loaded with twice the amount. Shipping containers preferably accommodate about 5-20 tonnes of material.

[0088] A shipping container may be, for example, a full ship with a bulk capacity of up to 20,000 tons.

[0089] The present invention further relates to a method of transporting a powdered alternative fuel, wherein the bulk powdered alternative fuel as described herein is moved at least 1 kilometer in a shipping container for road, train or ship traffic, the container having about 1 ton or more, preferably about 3 ton or more, of the bulk powdered alternative fuel.

[0090] In a preferred embodiment of the invention, the pulverized alternative fuel may be blown from a transport vehicle into a bulk silo near the furnace that uses the fuel.

[0091] use This powdered alternative fuel can completely replace pulverized coal in industrial furnaces such as those used in cement kilns, lime kilns, electrical manufacturing plants, and blast furnaces. It is also possible to only partially replace pulverized coal in such applications, as such a choice may be based on simple economics. Dosing can be accomplished using existing equipment installed for coal / lignite, and distribution to one or more burners generally does not require additional investment.

[0092] The particles preferably have an adiabatic flame temperature in the range of about 1200°C to about 2500°C and a flame resistance of 1280 to 2000 Nm 3 / kg * Air is blown into the furnace flame at amounts ranging from 1000 to 1000 psi. The temperature generally depends on the type of furnace.

[0093] The present invention will be described in more detail and specifically below with reference to examples, but the present invention is not limited to these examples.

[0094] Working Example Examples 1-2 A series of tests were conducted using RDF containing approximately 48% plastic, approximately 42% biomass, approximately 6% other materials, and approximately 4% moisture.

[0095] The first pelletizing step was carried out through a die with 6 mm holes and a length of 72 mm with an aspect ratio of 12. The die speed was about 200 rpm and the resulting pellets after the first pelletizing step had a temperature of about 70° C.

[0096] The second pelletizing step was carried out immediately after the first pelletizing step so that the inlet temperature of the product entering the pelletizer had a temperature of about 50-60° C. The second pelletizer used a die with holes of 6 mm diameter and 102 mm length (ratio 17). The outlet temperature of the pellets with a length of about 25-35 mm was about 120° C.

[0097] The twice pelletized pellets had a bulk density of about 520 g / L. Grinding was carried out using a hammer mill (vertical spindle mill at a speed of 108 Hz) equipped with a screen with 0.35 mm holes.

[0098] The products of examples 1 and 2 were analyzed for particle size distribution according to the methods of DIN 18123:2011-04 and DIN-EN 15149-1&-2:2011-01. The sieve fractions over 0.5 mm, 1 mm, 2 mm, 3.5 mm and >3.5 mm gave the following results:

[0099] [Table 2]

[0100] From these results it appears that when the double pelletized pellets were ground in a hammer mill equipped with a screen having 0.35 mm holes, over 50% by weight of the particles were between 1 and 3.5 mm and over 60% by weight of the particles had a particle size smaller than 2 mm.

[0101] Example 3 The product from Example 2 was prepared in a quantity of 50 tonnes. Approximately 3 tonnes of the product was pumped into a bulk trailer, transported over 50 km and emptied again with pressurised air through a pipe. All products could be loaded and unloaded by simple compressed air using standard bulk transport systems.

Claims

1. A method for manufacturing pellets, comprising: (i) providing a waste material comprising one or more thermoplastic materials in an amount greater than 40% based on the total dry weight of the waste, and one or more cellulosic materials in an amount greater than 30% based on the total dry weight of the waste, wherein the waste provided in step (ii) has a particle size distribution in which more than 80% by weight is larger than 5 mm and more than 95% by weight is smaller than 60 mm, and has a water content of about 8% by weight or less; (ii) passing the waste material through a pelletizer having holes between 4 and 8 mm and a length ratio exceeding 10 such that the extrusion temperature is about 85°C or less; (iii) passing the pellets through a second pelletizer having holes between 2 and 8 mm and a length ratio exceeding 14 such that the extrusion temperature is about 110°C or more; (iv) providing pellets having a diameter between 2 and 8 mm, a length of about 3 mm or more, preferably longer than 8 mm, and an extrusion temperature of the pellets of 110 - 130°C; (v) cooling the pellets to a temperature of about 40°C or less, preferably about 30°C or less.

2. The method according to claim 1, wherein the water content of the material supplied to the first die is between about 2% and about 5%.

3. The method according to claim 1, wherein the diameter of the holes in the first and / or second pelletizer is 4 - 6 mm.

4. The method according to claim 1, wherein the ratio of the diameter to the thickness of the first die is between 10 and 16, preferably between 12 and 14.

5. The method according to claim 1, wherein the ratio of the diameter to the thickness of the second die is between 14 and 20, preferably between 16 and 20.

6. The method according to claim 1, wherein the first die is operated such that the extrusion temperature is between 60 and 80°C.

7. The method according to claim 1, wherein the second die is operated such that the extrusion temperature is preferably between 115 and 125°C.

8. The method according to claim 1, wherein the increase in the extrusion temperature of the first die and the extrusion temperature of the second die is about 40°C or more, preferably about 45°C or more.

9. The method according to claim 1, wherein the temperature of the material supplied to the first die is between about 30 and 50°C, preferably between about 35 and 45°C.

10. The method according to claim 1, wherein the temperature of the material supplied to the second die is between about 50 and 80 °C, preferably between about 60 and 75 °C.

11. A method for providing a powdered alternative fuel by grinding pellets obtainable by the method of claim 1.

12. The method according to claim 11, wherein the grinding is carried out in a hammer mill, jet mill, roller mill or ball mill, preferably a hammer mill.

13. A powdered alternative fuel having the following characteristics: a. A mixture of 40 to 70% by weight of a thermoplastic material and 30 to 50% by weight of one or more cellulosic materials, preferably substantially homogeneous; b. A particle size distribution such that more than 50% by weight of the particles are between 1 and 3.5 mm and more than 60% by weight are smaller than 2 mm; c. An angle of repose between 41 and 43°; d. A tapped bulk density of 220 g / L or more Powdered alternative fuel having the above.

14. A transport container for road, train or ship traffic having a bulk of powdered alternative fuel obtainable by the method according to claim 11 or 12 or according to claim 13 of about 1 ton or more, preferably about 3 tons or more.

15. A method for transporting a powdered alternative fuel, wherein a bulk powdered alternative fuel obtainable by the method according to claim 11 or 12 or according to claim 13 is moved at least 1 kilometer in a transport container for road, train or ship traffic, and the container has a bulk of powdered alternative fuel of about 1 ton or more, preferably about 3 tons or more.