Manufacturing method of sintered ore

By adjusting the amount, grain size, or addition position of condensed material in the sintered ore manufacturing process based on the FeO concentration of the return ore, the method addresses the complexity and yield issues in existing sintered ore production, resulting in improved product yield and simplified control processes.

JP2025068270APending Publication Date: 2025-04-28NIPPON STEEL CORPORATION
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Patent Information

Application Number
JP2023178054
Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Filing Date
2023-10-16
Publication Date
2025-04-28

AI Technical Summary

Technical Problem

The existing method for manufacturing sintered ore for blast furnaces involves complex control processes due to continuous measurement of component concentrations, leading to increased complexity and reduced product yield.

Method used

A method that involves charging a compounded raw material containing iron ore, auxiliary materials, and condensed material into a sintering machine, sintering to produce a sintered cake, and then adjusting the amount, grain size, or addition position of the condensed material based on the measured FeO concentration of the return ore to achieve target concentrations.

Benefits of technology

This method simplifies the control process, increases the heat amount during sintering, and improves the product yield of sintered ore by ensuring optimal FeO concentration in the return ore.

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Abstract

To improve a yield of a sintered ore product to be manufactured with a simpler method.SOLUTION: A manufacturing method of a sintered ore includes: charging a mixed material including an iron ore, an auxiliary material and a coagulant material into a sintering machine; sintering the charged mixed material to produce a sinter cake; and screening the sinter cake into a sintered ore product and return fines by a classifier. The manufacturing method of a sintered ore further includes: a step of measuring the FeO concentration of the return fines; and an action execution step of executing, if the measured FeO concentration of the return fines is threshold concentration lower than target concentration, an action of adjusting at least one of the mixture amount of the coagulant material, the grain size of the coagulant material, and the addition location of the coagulant material.SELECTED DRAWING: Figure 1
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Description

[Technical field]

[0001] The present invention relates to a method for producing sintered ore for producing sintered ore for blast furnaces. [Background technology]

[0002] Currently, the main raw material for blast furnace pig iron production is sintered ore. Sintered ore (product sintered ore) used as a blast furnace feedstock is generally produced by sintering raw materials for sintered ore production (sintering raw materials), including iron ore, in a downward suction type Dwight Lloyd (DL) sintering machine, and then regulating the grain size to a specified size by crushing, sieving, etc.

[0003] Conventionally, in order to improve the yield of sintered ore, it has been common to carefully control the blending ratio of sintering raw materials in the sintered ore production process in accordance with fluctuations in the components of the sintered ore. Patent Document 1 describes a method for producing sintered ore in which the amount of coagulant mixed is adjusted using the results of a first measurement process in which the component concentration of at least one of the iron-containing raw material, the sintering raw material, and the granulated sintering raw material is continuously measured, and the results of a second measurement process in which the component concentration of at least one of the cooled sintered ore, the finished sintered ore, and the return ore is continuously measured. This is a technology for adjusting the amount of sintering raw material mixed and the production conditions of sintered ore based on the fluctuation in the component concentration of the sintering raw material during sintered ore production, or the change in the component concentration that changes due to the sintering reaction. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2019-131847 A Summary of the Invention [Problem to be solved by the invention]

[0005] However, in the manufacturing method described in Patent Document 1, the change in component concentration caused by the sintering reaction is monitored, and therefore, it is necessary to continuously measure the component concentrations of the sintering raw material before sintering in the first measurement step, and to continuously measure the component concentrations of the sintered ore in the second measurement step, which makes the control complicated.

[0006] The present invention provides a method for producing sintered ore, which can improve the product yield of the produced sintered ore by a simpler method. [Means for solving the problem]

[0007] [1] A method for producing sintered ore, comprising: charging a blended raw material containing iron ore, auxiliary raw materials, and a coagulating agent into a sintering machine; sintering the charged blended raw materials to produce a sintered cake; and sieving the sintered cake into a finished sintered ore and return ore with a classification device, the method comprising: a step of measuring the FeO concentration of the return ore; and an action implementation step of implementing an action to adjust at least one of the blending amount of the coagulating agent, the particle size of the coagulating agent, and the addition position of the coagulating agent when the measured FeO concentration of the return ore becomes a threshold concentration lower than a target concentration. [2] A method for producing sintered ore, comprising: charging a blended raw material containing iron ore, auxiliary raw materials, and a coagulating agent into a sintering machine; sintering the charged blended raw materials to produce a sintered cake; and sieving the sintered cake into a finished sintered ore and return ore using a classification device, the method comprising the steps of: measuring the FeO concentration of the return ore; measuring the FeO concentration of the finished sintered ore; and, when a difference between the FeO concentration of the finished sintered ore and the FeO concentration of the return ore reaches a threshold value lower than an initial value, carrying out an action to adjust at least one of the amount of the coagulating agent, the particle size of the coagulating agent, and the addition position of the coagulating agent. [3] A method for producing sintered ore described in [1] or [2], which includes a step of measuring the reducibility of the product sintered ore, and if the reducibility falls below an operational standard value after the action implementation step, an action different from the action implemented in the action implementation step is implemented. Effect of the Invention

[0008] According to the present invention, the FeO concentration of the return ore is measured, and at least one of the amount of the agglomerating agent, the particle size of the agglomerating agent, and the addition position of the agglomerating agent is adjusted so that the measured FeO concentration of the return ore becomes the target concentration. This increases the amount of heat during sintering, and improves the product yield (hereinafter simply referred to as yield). [Brief description of the drawings]

[0009] [Figure 1] FIG. 2 is a diagram illustrating a method for producing sintered ore according to the first embodiment of the present invention. [Diagram 2] FIG. 2 is a diagram illustrating the position at which the agglomeration material is added to the granulator. [Diagram 3] 1 is a graph showing the relationship between FeO contained in sintered ore and the reducibility (RI) of the sintered ore. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] <First embodiment> In the method for producing sintered ore according to the present embodiment, a blended raw material (sintering raw material) including iron ore, auxiliary raw material, and aggregating agent (carbon material) is charged into a sintering machine, the blended raw material is sintered to produce a sintered cake, the sintered cake is sieved into a product sintered ore and return ore by a classifier, and the sieved product sintered ore is transported to a blast furnace facility. In this method, an action is taken to adjust the blending amount of the aggregating agent, etc., using the FeO concentration of the return ore as an index. Hereinafter, a first embodiment of the present invention will be described with reference to the drawings. Fig. 1 is a diagram showing an example of a method for producing sintered ore.

[0011] As shown in Fig. 1, the method for producing sintered ore includes a raw material blending process S1, a granulation process S2, a sintering process S3, and a sizing process S4. After each process, the raw materials and semi-finished products are transported to the next process by a transport device such as a belt conveyor.

[0012] The raw material blending step S1 is a step of blending raw materials (blended raw materials) for sintered ore. The raw materials used in the blend include iron raw materials such as iron ore (powder), iron-containing miscellaneous materials such as scale and steelmaking dust, and SiO 2 The raw materials are appropriately used, such as MgO-containing auxiliary raw materials such as olivine, CaO-containing auxiliary raw materials such as limestone, return ore, and agglomeration materials (carbonaceous material, coke powder, anthracite, etc.) that serve as fuel for sintering (agglomeration). Each blended raw material is stored in a plurality of raw material tanks, and a predetermined amount of each blended raw material is cut out onto a belt conveyor, blended in a predetermined ratio (blending ratio), and sent to the granulation process S2.

[0013] The granulation step S2 is a step of granulating the blended raw materials (adjusting the particle size distribution) for the purpose of ensuring the breathability of the raw material packed bed. The mixed raw materials transported by the belt conveyor are fed into the granulator. After mixing for a specified time in the granulator, water is added (humidity control), and granulation is performed by mixing for a specified time, and pseudo-particles are created, which are the aggregates of the primary particles of the raw materials. The mixed raw materials after granulation (hereinafter also referred to as the mixed raw material granules) are sent to the sintering process S3. In the granulation process S2, some of the mixed raw material particles become pseudo-particles. In general, as described in the 3rd Edition Iron and Steel Handbook II, Pig Iron and Steelmaking, p. 84 (Figure 2.4) [October 15, 1979], fine raw materials with a particle size of less than 0.25 mm, which are the main target of granulation, form pseudo-particles by adhering to the periphery of particles of 1.00 mm or more as core particles, but it is said that particles of intermediate particle sizes between 0.25 mm and less than 1.00 mm are difficult to granulate and are difficult to become pseudo-particles.

[0014] The sintering step S3 is a step of sintering the blended raw material granules to produce a sintered cake (sinter cake). The granulated raw materials are stored in a mixed raw material surge hopper from the belt conveyor, and then loaded onto the pallet of a Dwight Lloyd (DL) sintering machine to form a raw material packed bed. The raw material packed bed is ignited by an ignition furnace, and sintered by the combustion heat of the coagulant in the raw material packed bed. The sintered cake obtained by sintering is discharged from the ore discharge end of the sintering machine, and roughly crushed into sintered ore with a particle size of less than 200 mm by a crusher (primary crushing), and sent to the sizing process S4.

[0015] The sizing step S4 is a step of cooling and pulverizing the roughly crushed lump-shaped sintered ore, and then sizing the pulverized sintered ore for use in a blast furnace. The lump sintered ore is cooled by a cooling device to a temperature at which it can be transported on a belt conveyor, and then crushed by a crusher (secondary crushing). The crushed sintered ore is sized by screening using a multi-stage classification device. Sintered ore (product sintered ore) of a particle size suitable for blast furnace charging is selected by the sizing process. The particle size suitable for blast furnace charging is, for example, sintered ore with a particle size of 5 mm or more and less than 50 mm. Here, a particle size of 5 mm or more and less than 50 mm refers to a particle size that is an oversize particle when sieved through a 5 mm sieve and an undersize particle when sieved through a 50 mm sieve. Note that sintered ore with a particle size of 50 mm or more is crushed to a particle size of less than 50 mm, and then sized again.

[0016] Each classifier is, for example, a rocking classifier with an inclined screen (sieve mesh), and the rocking motion is imparted by an eccentric drive mechanism. The classification intensity can be adjusted by changing the rotation speed of the motor that rotates this drive mechanism. The product sintered ore selected by the classifier is transferred to the blast furnace transfer line L2, and the remaining fine sintered ore is transferred to the return ore transfer line L1 as return ore.

[0017] The return ore transport line L1 is a line that returns fine sintered ore that is not suitable for use as a blast furnace raw material to the raw material blending process S1. The return ore transport line L1 is equipped with a transport device such as a conveyor, and transports sintered ore with a particle size of less than 5 mm, which is smaller than the finished sintered ore (hereinafter, sintered ore with a particle size of less than 5 mm is also referred to as -5 mm sintered ore), into the raw material tank for return ore described above. A particle size of less than 5 mm refers to the particle size that falls under the sieve when sieved through a 5 mm sieve. The transported -5 mm sintered ore is mixed into the raw material mix as return ore.

[0018] The blast furnace transport line L2 is a line that transports the finished sintered ore to the blast furnace facility. The blast furnace transport line L2 is equipped with conveyors and other transport devices. The product sintered ore with a particle size of 5 mm or more but less than 50 mm is transported to the blast furnace equipment and used as the raw material for blast furnace iron production. The product sintered ore is charged into the blast furnace by multiple belt conveyors together with reducing materials such as coke, limestone, and olivine produced in a separate process.

[0019] Next, a method for adjusting the amount of coagulant to be used, etc., using the FeO concentration of the return fines as an index will be described. The product yield, which is the ratio of the actual sintered ore to the sinter cake (excluding the bedding ore), can be improved by reducing the amount of return ore generated. Conventionally, the yield has been monitored based on the information on the increase in the amount of return ore stored in the raw material tank for storing return ore (information on the rate of return ore generation).

[0020] The inventors have repeatedly studied methods for reducing the amount of return ore generated, and have found that the FeO concentration in return ore is lower than that in the finished sintered ore. The inventors have also considered that, since a large amount of heat during sintering increases the amount of FeO generated during sintering, and a small amount of FeO is generated during sintering, the temperature during sintering is relatively low in the areas where return ore is generated, resulting in insufficient melting. Based on this, it was thought that the product yield could be improved by taking action to increase the heat generated during sintering when the FeO concentration in the return ore becomes low.

[0021] A specific method for measuring the FeO concentration in the return fines and a method for adjusting the amount of the coagulant to be used will be described below. (1) Measurement of FeO concentration in return fines In the sinter ore manufacturing method of the present embodiment, a predetermined amount of return ore is collected, for example, every 4 hours, in the return ore conveying line L1, and the FeO concentration of the return ore is measured. The FeO concentration can be measured by the method described in JIS M8213 (iron ore-acid soluble iron (II) determination method). An operator checks the measured FeO concentration of the return ore. The method for measuring the FeO concentration of the return ore is not limited to the above-mentioned method, and a component analyzer capable of online analysis of the return ore on the return ore transport line L1 (while being transported by a belt conveyor, hereinafter referred to as on-belt) (hereinafter, the measurement target on the belt is also referred to as an on-belt sample) may be used.

[0022] (2) Implementing Actions Based on the measured FeO concentration of the return ore, the operator performs at least one of the actions described below (action performing step). Specifically, when the FeO concentration of the return ore is lower than a target FeO concentration (hereinafter referred to as a target concentration), an action is performed to increase the FeO concentration so that the FeO concentration becomes the target concentration. The target concentration can be set based on past manufacturing results. The target concentration can be, for example, 6.5% by mass. The threshold concentration, which is the threshold for taking an action, can be 95% of the target concentration. When the target concentration is 6.5% by mass, the threshold concentration is 6.175% by mass (≒6.2% by mass).

[0023] Next, the details of the action to be taken when the FeO concentration of the return ore is reduced will be described. The operator can appropriately select the action to be taken from the following three actions. (2-1) Action 1: Adjustment of the amount of coagulant The amount of the coagulant in the raw material mix is ​​increased. In other words, the amount of the coagulant fed from the raw material tank to the granulator is increased, and the ratio of the coagulant in the raw material mix (concentration of the coagulant) is increased. This increases the amount of coagulant in the entire raw material packed bed, which increases the sintering temperature of the entire raw material packed bed and promotes melting.

[0024] (2-2) Action 2: Adjustment of the particle size of the aggregate The particle size of the granulator is made finer. In other words, the particle size of the granulator fed from the raw material tank to the granulator is made smaller. This promotes segregation of the granulator, and increases the concentration of the granulator in the upper layer of the raw material packed bed, which is insufficient in heat when sintering with a DL-type sintering machine, and the sintering temperature of the upper layer increases, promoting melting. The particle size of the aggregate can be reduced, for example, by decreasing the amount of aggregate fed per unit time to the aggregate crusher.

[0025] (2-3) Action 3: Adjustment of the position of the coagulant injection The position where the coagulating agent is charged into the granulator is adjusted. Specifically, in the raw material mixing step S1, the coagulating agent is charged separately from the other mixed raw materials, and is divided into several portions and charged into the granulator (divided charging). FIG. 2 is a diagram for explaining the position of the coagulating agent to be fed into the granulator. The mixed raw materials M (excluding the coagulating agent C) fed from the raw material tanks 1 are fed into the granulator 3 and granulated, and then charged into the sintering machine 4. The coagulating agent C fed from the coagulating agent tank 2 provided independently from the raw material tanks 1 is fed into the granulator 3 at least one of the upstream position P1 (pre-addition) and downstream position P2 (post-addition) of the granulator 3. The operator can adjust the ratio of pre-addition and post-addition of the coagulating agent C. As shown in FIG. 2, the pre-addition of the coagulating agent C is fed into the granulator 3 together with the mixed raw materials M (excluding the coagulating agent C). In addition, the coagulating agent tank 2 for storing the coagulating agent C to be fed in portions may be provided in multiple tanks for pre-addition and post-addition.

[0026] The state of the agglomeration material C in the raw pseudo-particles changes by adjusting the ratio of pre-addition and post-addition. That is, the combustion speed of the agglomeration material C changes depending on whether the agglomeration material C is coated with the blended raw materials (iron ore, limestone, etc.), and the sintering temperature changes accordingly. For example, the sintering temperature can be increased by feeding 50% by mass of the agglomeration material C from position P1 on the upstream side of the granulator 3 and feeding the remaining 50% by mass from position P2 on the downstream side of the granulator 3.

[0027] The above describes the action of adjusting the amount of the coagulating agent, but the operator can select an appropriate action depending on the configuration of the sintering machine, for example. In terms of more reliably increasing the sintering temperature, the adjustment of the amount of the coagulating agent is given priority.

[0028] According to the above embodiment, the FeO concentration of the return ore is measured, and at least one of the amount of the agglomeration agent, the particle size of the agglomeration agent, and the addition position of the agglomeration agent is adjusted so that the measured FeO concentration of the return ore becomes the target concentration. This increases the amount of heat during sintering and improves the product yield.

[0029] <Second embodiment> Next, a method for producing sintered ore according to a second embodiment of the present invention will be described. The method for producing sintered ore according to this embodiment uses the reducibility (RI) of sintered ore as an index in addition to the FeO concentration of return ore. The reducibility of sintered ore is an index showing how easily the sintered ore is reduced in the upper and middle parts of the shaft inside the blast furnace, and sintered ore with high reducibility is desired.

[0030] The relationship between the FeO contained in sintered ore and the reducibility (RI) of sintered ore is shown in Figure 3. If the amount of FeO contained in sintered ore is large, the reducibility (RI) of the sintered ore will be low. The FeO melt produced at high temperatures during the sintering process blocks the pores in the sintered body, reducing the surface area that comes into contact with the reducing gas in the blast furnace, making it difficult for the reduction reaction to occur. As a result, if the sintered ore contains a lot of FeO, the reducibility (RI) of the sintered ore will be low. In the first embodiment, when the FeO concentration of the return ore decreases, the FeO concentration of the return ore is increased. However, there is a concern that the reducibility (RI) may decrease due to the increase in the FeO concentration of the return ore.

[0031] In the sintered ore manufacturing method according to the second embodiment, the reducibility of the product sintered ore is measured, for example, every 4 hours on the blast furnace conveying line L2. The reducibility of the product sintered ore can be measured, for example, by a method described in JIS M8713 (iron ore-reducibility test method). The worker checks the FeO concentration of the return ore and the reducibility of the product sinter.

[0032] The operator takes action based on the measured FeO concentration of the return ore and the reducibility of the product sintered ore so that the FeO concentration will become the target concentration. Specifically, when the FeO concentration of the return ore becomes lower than the target concentration, the first action is taken. The first action taken based on the FeO concentration of the return ore is preferably action 1, which increases the amount of the coagulant.

[0033] If the reducibility of the product sintered ore becomes lower than the standard operating value after the first action is carried out, the first action is returned to its original state (the amount of the agglomerating agent is returned to its original state) and a second action different from the first action is carried out. The second action is preferably an action to adjust the particle size of the agglomerating agent. The operational standard value of reducibility can be set based on past production results. The operational standard value of reducibility can be, for example, 65%. The threshold value for implementing the second action can be 95% of the operational standard value.

[0034] According to the above embodiment, by taking an action to adjust the mixing amount of the agglomeration agent, etc., using the reducibility of the product sintered ore as an index in addition to the FeO concentration of the return ore, it is possible to improve the product yield while suppressing the decrease in reducibility.

[0035] <Third embodiment> Next, a method for producing sintered ore according to a third embodiment of the present invention will be described. The method for producing sintered ore according to this embodiment uses the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore as an index instead of the FeO concentration of the return ore. In the sintered ore manufacturing method of the present embodiment, the FeO concentration of the return ore is measured, for example, every 4 hours, on the return ore transport line L1, and the FeO concentration of the product sintered ore is measured, for example, every 4 hours, on the blast furnace transport line L2.

[0036] Based on the measured difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore, the operator performs at least one of the actions described in the first embodiment. Specifically, when the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore becomes high relative to the initial value, the operator performs an action so that the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore returns to the initial value. The threshold value for taking the action can be set to, for example, 140% of the initial value. If the initial value is 0.8% by mass, the threshold value is 1.12% by mass (≈1.1% by mass).

[0037] (Analysis of Onbelt samples) The blast furnace conveying line L2 and the return ore conveying line L1 are each provided with a component analyzer (not shown), and the product sinter and return ore (on-belt sample) on the belt conveyor are directly (while being conveyed) analyzed by the component analyzer. The component analyzer is, for example, a laser analyzer, an infrared analyzer, a neutron analyzer, a microwave analyzer, or the like. By continuously measuring the components of the on-belt sample and performing online analysis, it is possible to sequentially obtain component content data of the on-belt sample. Here, continuous measurement means a form in which an object to be analyzed is continuously irradiated with electromagnetic waves, neutrons, or the like, and measurement values ​​are continuously obtained. When the electromagnetic waves are a pulsed laser, etc., the time interval between pulses may be on the order of microseconds to seconds depending on the number of pulse repetitions. In addition, continuous measurements may be performed intermittently. There may be a finite rest period between consecutive measurements. Such a rest period can be appropriately selected so that the desired control is possible. From another point of view, continuous measurement may be a form in which the analysis target moving on a conveying means such as a belt conveyor or a pallet is measured in a non-contact manner without picking up (sampling) the analysis target from the conveying means.

[0038] For example, if the component contents of an on-belt sample are measured and analyzed using a LIBS (Laser Induced Breakdown Spectroscopy) analyzer, a laser with a peak output per pulse of 10 mJ to 150 mJ, a pulse width of 1 to 10 nm, and a repetition frequency of about 10 to 100 Hz is irradiated onto the on-belt sample to be analyzed using an optical system such as lenses and mirrors, and the resulting light emission is introduced into a spectrometer directly or using an optical fiber, etc., and the light emission spectrum is analyzed to identify the elements and quantify their concentrations. When the on-belt sample has a high moisture content or contains a large amount of fine powder, a pretreatment is performed to remove surface deposits and / or moisture from the on-belt sample by irradiating the on-belt sample with a laser beam separate from that for analysis, and then at least a part of the area irradiated with the laser beam in the pretreatment is irradiated with a laser beam for analysis to perform a component analysis by laser-induced breakdown spectroscopy analysis, thereby obtaining component content data for the on-belt sample. This pretreatment is a process to remove surface deposits and moisture from on-belt sample particles by so-called laser ablation.

[0039] The LIBS analysis device is equipped with the components necessary for measurement and analysis, such as a pre-processing laser light source and an analytical laser light source arranged in sequence in the conveying direction, a spectrometer (e.g., AvanSpec-ULS2048CL-EVO manufactured by Avantes) that detects the wavelengths and intensity of light contained in the emission caused by the analytical laser light, a processing unit, and a control device.The processing unit acquires measurement data regarding the emission generated from the on-belt sample (data regarding the emission intensity at each wavelength) output from the spectrometer, and analyzes the component composition of the on-belt sample using LIBS based on this measurement data.

[0040] It is also preferable to measure the position of the analysis portion to be irradiated with the analytical laser light (e.g., the height from the conveying surface of a conveying facility such as a belt conveyor) and irradiate the analysis portion with the analytical laser light based on the measured position information. Methods for measuring the position include laser ranging and acoustic ranging, but in the case of a belt conveyor, laser ranging is more preferable because acoustic disturbances are large. It becomes possible to identify the analysis position of the on-belt sample to be analyzed, and it becomes possible to more reliably focus the analytical laser light on the analysis portion (surface) of the on-belt sample particle to be analyzed. As a result, it becomes possible to measure the component content of the on-belt sample with even greater accuracy.

[0041] According to the above embodiment, by using the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore as an index, it is possible to take action based on the difference in FeO concentration from the actual product sintered ore, rather than on the target value of the product sintered ore, and therefore it is possible to more directly correct the change in yield, compared to a method in which only the FeO concentration of the return ore is used as an index.

[0042] In this embodiment, the FeO concentration of the finished sintered ore on the blast furnace conveying line L2 is used as the FeO concentration of the finished sintered ore. However, this is not limited to this, and the difference between the FeO concentration of the return ore and the FeO concentration of the finished sintered ore may be calculated using the FeO concentration of the finished sintered ore estimated from the blending ratio of the blended raw materials, or a target value set when determining the blending ratio of the blended raw materials. Furthermore, the method for measuring the FeO concentration in the product sintered ore and the return ore is not limited to the above-mentioned method, and a component analyzer capable of online analysis of the on-belt product sintered ore and return ore may be used. EXAMPLES

[0043] Example 1 Next, an embodiment of the present invention will be described. In Example 1, a blended raw material containing iron ore, auxiliary raw materials, and a coagulant was charged into a sintering machine, and the charged blended raw material was sintered to produce a sintered cake. In the return ore conveying line L1, return ore was collected every 4 hours, and the FeO concentration was measured by the method described in JIS M8213 (iron ore-acid soluble iron (II) determination method). The FeO concentration of the return ore was 6.5% by mass, which was set as the target concentration, and the threshold concentration was set to 6.3% by mass. The product yield was 77.8% by mass.

[0044] In the production of sintered ore, the blending ratio of the blended raw materials may be changed depending on the type (brand) of iron ore. When the blending ratio of the blended raw materials was changed in this example, the FeO concentration of the return ore became less than the threshold concentration of 6.3 mass%, and the product yield also decreased to 77.7%. In response to this, the amount of coagulant (proportion relative to new raw materials (excluding the amount)) was increased from 4.4% by mass to 4.5% by mass. This action increased the FeO concentration in the return ore to 6.5% by mass, the same as before the mix change. As a result, the yield, which had been declining after the mix ratio change, recovered to 77.8%, the same as before the change.

[0045] Example 2 In Example 2, return ore was collected every 4 hours on the return ore transport line L1 in the same manner as in Example 1, and the FeO concentration was measured by the method described in JIS M8213 (iron ore-acid soluble iron (II) determination method). The FeO concentration of the return ore was 6.5 mass%, which was set as the target concentration, and the threshold concentration was set to 6.3 mass%. In addition, product sinter was collected every 4 hours on the blast furnace transport line L2, and the reducibility of the product sinter was measured. The operational standard value of the reducibility of the product sinter was set to 65%, and the threshold value was set to 62%. The product yield was 78.0 mass%.

[0046] When the blending ratio of the raw materials was changed, the FeO concentration in the return ore decreased to less than 6.2 mass%, which is below the threshold concentration, and the product yield also decreased to 77.7 mass%. In response to this, an action was taken to increase the amount of the agglomeration agent (ratio to new raw materials (excl. number)) from 4.5% by mass to 4.6% by mass. This action increased the FeO concentration of the return ore to 6.5% by mass, the same as before the mix change. However, the reducibility of the finished sintered ore began to decrease, falling below the threshold of 62%, so the amount of the agglomeration agent was returned to the original amount (4.5% by mass) and the particle size of the agglomeration agent was reduced from 1.7 mm to 1.6 mm. This action increased the FeO concentration of the return ore to 6.5% by mass, the same as before the mix change, without causing any particular deterioration in permeability. As a result, the yield, which had been on a downward trend after the mix ratio change, recovered to 78.0% by mass, the same as before the change.

[0047] Example 3 In Example 3, return ore was collected every 4 hours on the return ore transport line L1, and product sintered ore was collected every 4 hours on the blast furnace transport line L2, and the FeO concentration was measured by the method described in JIS M8213 (iron ore-acid soluble iron (II) determination method). The initial value of the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore was 0.8% by mass, and the product yield was 78.0% by mass.

[0048] When the blending ratio of the raw materials was changed, the difference between the FeO concentration of the return ore and the FeO concentration of the product sinter increased from 0.8 mass% to the threshold value of 1.1 mass%, and the product yield also decreased to 77.8 mass%. In response to this, the amount of agglomerant mixed (proportion relative to new raw materials (excluding)) was increased from 4.4% by mass to 4.5% by mass. This action reduced the difference between the FeO concentration of the return ore and the FeO concentration of the finished sintered ore to 0.8% by mass, the same as before the mix change. As a result, the yield, which had been on a downward trend after the mix ratio change, rose to 78.1% by mass, higher than before the change.

[0049] Example 4 In Example 4, return ore was collected every 4 hours on the return ore transport line L1, and product sintered ore was collected every 4 hours on the blast furnace transport line L2, and the FeO concentration was measured by the method described in JIS M8213 (iron ore-acid soluble iron (II) determination method). The initial value of the difference between the FeO concentration of the return ore and the FeO concentration of the product sintered ore was 0.6 mass%. The operational standard value of the reducibility of the product sintered ore was 65%, and the threshold value was 62%. The product yield was 77.5 mass%.

[0050] When the blending ratio of the raw materials was changed, the difference between the FeO concentration of the return ore and the FeO concentration of the product sinter increased from 0.6 mass% to 1.0 mass%, which is above the threshold value, and the product yield also decreased to 77.2 mass%. In response to this, the amount of the coagulant (ratio to new raw materials (excl.)) was increased from 4.3% by mass to 4.4% by mass. This action reduced the difference between the FeO concentration of the return ore and the FeO concentration of the finished sintered ore to 0.6% by mass, the same as before the mix change. However, the reducibility of the finished sintered ore tended to decrease, so the amount of the coagulant was returned to the original amount (4.3% by mass) and the addition position of the coagulant was changed from 100% pre-addition to 50% pre-addition / 50% post-addition. This action reduced the difference between the FeO concentration of the return ore and the FeO concentration of the finished sintered ore to 0.6% the same as before the mix change, and the reducibility of the finished sintered ore also returned to the level before the mix change. As a result, the yield, which had been on a downward trend after the mix change, rose to 77.6% by mass, higher than before the change.

[0051] Although the present invention has been described in detail above with reference to the drawings, it is of course not limited to the above-mentioned configurations and various modifications can be made without departing from the gist of the present invention. [Explanation of symbols]

[0052] 1...raw material tank, 2...coagulation material tank, 3...granulator, 4...sintering machine, C...coagulation material, L1...return ore transport line, L2...blast furnace transport line, M...blended raw material, P1...position upstream of the granulator, P2...position downstream of the granulator, S1...raw material blending process, S2...granulation process, S3...sintering process, S4...size regulation process.

Claims

1. A mixture of raw materials including iron ore, auxiliary materials, and agglomerates is charged into a sintering machine; Sintering the charged blended raw materials to produce a sintered cake; In the method for producing sintered ore, the sintered cake is sieved into product sintered ore and return ore by a classification device, Measuring the FeO concentration of the return fines; and an action implementation step of implementing an action to adjust at least one of the amount of the coagulation agent, the particle size of the coagulation agent, and the addition position of the coagulation agent when the measured FeO concentration of the return ore becomes a threshold concentration lower than a target concentration.

2. A mixture of raw materials including iron ore, auxiliary materials, and agglomerates is charged into a sintering machine; Sintering the charged blended raw materials to produce a sintered cake; In the method for producing sintered ore, the sintered cake is sieved into product sintered ore and return ore by a classification device, Measuring the FeO concentration of the return fines; Measuring the FeO concentration of the product sintered ore; and an action implementation step of implementing an action to adjust at least one of the amount of the coagulation agent, the particle size of the coagulation agent, and the addition position of the coagulation agent when the difference between the FeO concentration of the finished sintered ore and the FeO concentration of the return ore becomes a threshold value lower than an initial value.

3. A step of measuring the reducibility of the product sintered ore, The method for producing sintered ore according to claim 1 or 2, further comprising the step of: implementing an action different from the action implemented in the action implementation step when the reducibility falls below an operational reference value after the action implementation step.

Citation Information

Patent Citations

  • Manufacturing method of sintered ore and blast furnace operation method

    JP2019131847A