Multilayer composite with thermal barrier properties

Abstract

To provide a multilayer composite material having an improved barrier design for protecting against high thermal potential in a thermal barrier in a battery pack of an electric vehicle, a thermal barrier cover in high temperature cable protection, a thermal barrier container for thermal spray containment, and the like.SOLUTION: A multi-layer composite is provided that can include a first barrier layer and a first foam layer. The first foam layer can include a silicone-based matrix component, a flame-retardant filler component, and an insulating filler component. The multilayer composite can have a thickness of at least about 0. 5mm and less than or equal to about 10mm.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present disclosure relates to multilayer composites, particularly for use in a variety of applications, such as thermal barriers in battery packs. The present invention relates to a multi-layer composite for use as a rear and a method for forming the same. Summary of the Invention [Problem to be solved by the invention]

[0002] Multilayer composite films are used for high temperature protection in a variety of applications, e.g., electric vehicles Thermal barriers in battery packs, thermal barrier covers for high temperature cable protection, thermal spray encapsulation However, they may be designed for use as thermal barrier containers for In this and other applications, the potential thermal growth continues to increase due to improvements in technology. Therefore, improved barrier designs that protect against such high thermal latency are needed. Continued support is needed.

[0003] According to a first aspect, a multilayer composite may include a first barrier layer and a first foam layer. The first foam layer comprises a silicone matrix component, a flame-retardant filler component, and a thermal insulating The multilayer component may include a polymeric filler component. The multilayer component may also have a thickness of HB measured in accordance with ASTM D4986. It may have an F flammability rating.

[0004] According to another embodiment, a multilayer composite can include a first barrier layer and a first foam layer. The first foam layer comprises a silicone matrix component, a flame-retardant filler component, and a thermal insulating material. The multilayer component may include a filler component. The multilayer component was also subjected to a hot plate test at 650°C. The self-ignition time may be at least about 1 minute.

[0005] According to yet another aspect, a multilayer composite includes a first barrier layer and a first foam layer. The first foam layer comprises a silicone matrix component, a flame-retardant filler component, and an insulating material. The first barrier layer may include a thermal filler component. The first barrier layer may include a mica, a mica fiberglass cloth, a glass cloth, or the like. , silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, non-woven glass cloth, Any combination thereof, and any laminate thereof The flame-retardant filler component of the first foam layer may include metal hydrates, borate compounds, platinum Compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, silicic acid Magnesium, glass frit, alkali salts, vermiculite, and any combination thereof The first foam layer may comprise a filler selected from the group consisting of a fluororesin, ... The ingredients are expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite. -miculite, expanded glass, zeolite, aerogel, silica, porous silica, porous alumina, and any combination thereof. The multi-layer composite may have a thickness of at least about 0.5 mm and no more than about 10 mm.

[0006] According to another aspect, a thermal barrier composite includes a first barrier layer and a first foam layer. The first foam layer comprises a silicone matrix component, a flame-retardant filler component, and an insulating material. The multilayer component may include a thermal filler component. The multilayer component may also have a thickness of H measured in accordance with ASTM D4986. May have a BF flammability rating.

[0007] According to another aspect, a thermal barrier composite includes a first barrier layer and a first foam layer. The first foam layer comprises a silicone matrix component, a flame-retardant filler component, and an insulating material. The multilayer component may include a thermal filler component. The multilayer component may also be subjected to a hot plate test at 650°C. When the ignition time is at least about 1 minute, the ignition time may be at least about 1 minute.

[0008] According to yet another aspect, a thermal barrier composite includes a first barrier layer and a first foam layer. The first foam layer may comprise a silicone-based matrix component, a flame-retardant filler component, and The first barrier layer may comprise mica, mica fiberglass cloth, glass, and a heat insulating filler component. glass cloth, silica cloth, basalt cloth, vermiculite-coated glass cloth, aerogel, nonwoven glass A material selected from the group consisting of fabrics, any combination thereof, and any laminate thereof. The flame-retardant filler component of the first foam layer may include metal hydrates, borate compounds, Platinum compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium carbonate, glass frit, alkali salts, vermiculite, and any of the foregoing The insulating filler of the first foam layer may comprise a filler selected from the group consisting of: Filler ingredients include expanded perlite, non-expanded perlite, glass beads, vermiculite, and expanded expanded vermiculite, expanded glass, zeolite, aerogel, silica, porous silica, poly and any combination thereof. The thermal barrier composite may have a thickness of at least about 0.5 mm and no greater than about 10 mm. [Brief explanation of the drawings]

[0009] Embodiments are illustrated by way of example and not limitation in the accompanying figures. [Figure 1] FIG. 1 includes an illustration of an exemplary multi-layer composite according to certain embodiments described herein. [Figure 2] FIG. 2 includes an illustration of an exemplary multi-layer composite according to certain embodiments described herein. [Figure 3] FIG. 3 includes an illustration of an exemplary multi-layer composite according to certain embodiments described herein. [Figure 4] FIG. 4 includes an illustration of an exemplary thermal barrier composite according to certain embodiments described herein. [Figure 5] FIG. 5 includes an illustration of an exemplary thermal barrier composite according to certain embodiments described herein. [Figure 6] FIG. 6 includes an illustration of an exemplary thermal barrier composite according to certain embodiments described herein.

[0010] Those skilled in the art will appreciate that elements in the figures are illustrated for simplicity and clarity and are not necessarily to scale. Please understand that it is not drawn to scale. DETAILED DESCRIPTION OF THE INVENTION

[0011] The following discussion focuses on specific implementations and embodiments of the teachings. are provided to help describe particular embodiments and are within the scope of this disclosure or teachings. The disclosure and the information provided herein should not be construed as limitations on the scope or applicability of the present invention. It will be understood that other embodiments may be used based on the teachings herein.

[0012] "comprises," "comprising," "including" The words "deals," "including," "has," and "having" The words "a," "b," "c," "d," "e," "f," "g," "h," "i," "j," "j," "k," "k," "m," "m," "m," "m," "i," "j," "j," "k," "m ...j," "k," "j," "k," "j," "k," "j," "k," "j For example, a method, article, or apparatus that includes a list of features is not necessarily limited to only those features. However, other features not expressly recited, or any such method, article, or or other features inherent to the device. Further, unless expressly stated to the contrary, "or" " refers to an inclusive or, not an exclusive or. For example, condition A or B: Satisfied by one of the following: A is true (or exists) and B is false ( A is false (or does not exist), B is true (or exists), and and both A and B are true (or exist).

[0013] Also, the use of "a" or "an" describes elements and components described herein. This is done merely for convenience and to give a general sense of the scope of the invention. This explanation is given for one or a few At least one, or the singular should be understood as including the plural and vice versa For example, where a single item is described herein, two items may be used instead of a single item. Similarly, two or more of the articles described herein may be used. If two or more items are in a single unit, they may be replaced by a single item.

[0014] The embodiments described herein generally include a first barrier layer and a first foam layer. According to a particular embodiment, the first foam layer is a silicone-based It may include a matrix component, a flame retardant filler component, and a thermal insulating filler component. According to the embodiment, the multilayer composite exhibits a combination of improved performance in flame resistance and compression. possible.

[0015] For illustrative purposes, FIG. 1 shows a multi-layer composite 100 according to an embodiment described herein. As shown in FIG. 1, the multi-layer composite 100 includes a first barrier layer 102 and a first foam The first foam layer 104 may include a silicone-based matrix component 11. 0, a flame retardant filler component 120, and a thermal insulating filler component 130.

[0016] According to certain embodiments, the silicone-based matrix component of the first foam layer 104 110 may comprise a platinum catalyzed addition cure silicone foam. The silicone-based matrix component 110 may include a peroxide-cured silicone foam. According to yet another embodiment, the silicone-based matrix component 110 is a tin-catalyzed silicone. According to yet another embodiment, the silicone-based matrix component may comprise corn foam. 110 is a platinum catalyst addition cure silicone foam, a peroxide cure silicone foam, and and tin catalyzed silicone foams.

[0017] According to certain embodiments, the silicone-based matrix component 110 is a platinum-catalyzed curing agent. According to yet another embodiment, the silicone matrix may be a fluorinated silicone foam. The foam component 110 may comprise a peroxide-cured silicone foam. According to the patent, the silicone matrix component 110 is made of a tin-catalyzed silicone foam. According to yet another embodiment, the silicone-based matrix component 110 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam It may consist of any combination of information.

[0018] According to certain embodiments, the silicone-based matrix component 110 is a platinum-catalyzed curing agent. According to yet another embodiment, the layer may be a silicone-based matrix. The foam component 110 can be a peroxide-cured silicone foam layer. According to the patent, the silicone matrix component 110 is a tin-catalyzed silicone foam layer. According to yet another embodiment, the silicone-based matrix component 110 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam The layer may be any combination of layers of foam.

[0019] According to yet another embodiment, the flame-retardant filler component 120 is selected from a specific group of materials. For example, the flame-retardant filler component 120 may be a metal hydrate, a borate compound, a platinum compound, or the like. Substances, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate Nesium, glass frit, alkali salts, vermiculite, and any combination thereof The compound may be selected from the group consisting of:

[0020] According to yet other embodiments, the flame-retardant filler component 120 may include certain materials. For example, the flame-retardant filler component 120 may include a metal hydrate. The fire-retardant filler component 120 may include a borate compound. The flame-retardant filler component 120 may include a platinum compound. The filler component 120 may include a transition metal oxide. According to another embodiment, the flame-retardant filler component According to yet another embodiment, the flame-retardant filler component 120 may include a metal carbonate. According to yet another embodiment, the flame retardant filler component 10 may comprise calcium silicate. According to yet another embodiment, the flame retardant filler composition may comprise aluminum silicate. The component 120 may include magnesium silicate. According to yet another embodiment, the flame-retardant filler Component 120 may include glass frit. According to yet another embodiment, the flame retardant filler component According to yet another embodiment, the flame retardant filler component 120 may include an alkali salt. According to yet another embodiment, the flame-retardant filler component 1 may comprise vermiculite. 20 is a metal hydrate, borate compound, platinum compound, transition metal oxide, metal carbonate, silica calcium silicate, aluminum silicate, magnesium silicate, glass frit, alkali salt , or vermiculite.

[0021] According to yet other embodiments, the flame-retardant filler component 120 may be made of specific materials. For example, the flame-retardant filler component 120 may comprise a metal hydrate. For example, the flame-retardant filler component 120 may comprise a borate compound. For example, the flame-retardant filler component 120 may comprise a platinum compound. The flame-retardant filler component 120 may comprise a transition metal oxide. According to yet another embodiment, the flame-retardant filler component 120 may comprise a metal carbonate. The filler component 120 may comprise calcium silicate. The reactive filler component 120 may comprise aluminum silicate. In yet another embodiment, the flame-retardant filler component 120 may comprise magnesium silicate. For example, the flame-retardant filler component 120 may comprise glass frit. For example, the flame-retardant filler component 120 may comprise an alkali salt. For example, the fire-retardant filler component 120 may comprise vermiculite. For example, the flame retardant filler component 120 may be a metal hydrate, a borate compound, a platinum compound, a transition metal Oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate, gallium silicate It may consist of any combination of lath frit, alkali salts, or vermiculite.

[0022] According to yet other embodiments, the flame-retardant filler component 120 can be a specific material. For example, the flame-retardant filler component 120 can be a metal hydrate filler. For example, the flame-retardant filler component 120 may be a borate filler. For example, the flame-retardant filler component 120 can be a platinum compound filler. For example, the flame-retardant filler component 120 can be a transition metal oxide filler. For example, the flame-retardant filler component 120 can be a metal carbonate filler. For example, the flame-retardant filler component 120 can be a calcium silicate filler. According to an embodiment, the flame-retardant filler component 120 may be an aluminum silicate filler. According to another embodiment, the flame-retardant filler component 120 may be a magnesium silicate filler. According to yet another embodiment, the flame-retardant filler component 120 is a glass frit filler. According to yet another embodiment, the flame-retardant filler component 120 is an alkali salt filler. According to yet another embodiment, the fire-retardant filler component 120 may be a vermiculite filler. According to yet another embodiment, the flame-retardant filler component 120 may be a metal hydrate, Borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, silicic acid Aluminum, magnesium silicate, glass frit, alkali salt, or vermiculite The filler may be any combination of the above.

[0023] According to yet another embodiment, the flame-retardant filler component 120 is a specific group of metal hydrate materials. For example, the flame retardant filler component 120 may be selected from aluminum trihydrate, dihydrate, Magnesium chloride, boehmite, calcium hydroxide, huntite, gypsum, hydromagnesa and any combination thereof.

[0024] According to yet another embodiment, the flame-retardant filler component 120 includes certain metal hydrate materials. For example, the flame-retardant filler component 120 may include aluminum trihydrate. According to this embodiment, the flame-retardant filler component 120 may include magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 120 may include boehmite. According to an embodiment, the fire-retardant filler component 120 may include calcium hydroxide. According to an embodiment, the flame-retardant filler component 120 may include huntite. According to an embodiment, the fire-retardant filler component 120 may include gypsum. The reactive filler component 120 may include hydromagnesite. Flame retardant filler component 120 is aluminum trihydrate, magnesium dihydroxide, boehmite , calcium hydroxide, huntite, gypsum, or any combination of hydromagnesite may include:

[0025] According to yet another embodiment, the flame-retardant filler component 120 is made from certain metal hydrate materials. For example, the flame-retardant filler component 120 may comprise aluminum trihydrate. According to another embodiment, the flame-retardant filler component 120 may comprise magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 120 may consist of boehmite. According to another embodiment, the fire-retardant filler component 120 may consist of calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 120 may comprise huntite. According to yet another embodiment, the fire-retardant filler component 120 may comprise gypsum. According to another embodiment, the flame-retardant filler component 120 may comprise hydromagnesite. According to an embodiment, the flame retardant filler component 120 is aluminum trihydrate, magnesium dihydroxide, Calcium, boehmite, calcium hydroxide, huntite, gypsum, or hydromagnesite It can consist of any combination.

[0026] According to yet another embodiment, the flame-retardant filler component 120 is a specific metal hydrate material filler. For example, the flame-retardant filler component 120 may be an aluminum trihydrate filler. According to yet another embodiment, the flame-retardant filler component 120 is a magnesium dihydroxide filler. According to yet another embodiment, the flame-retardant filler component 120 may be boehmite. According to another embodiment, the flame-retardant filler component 120 may be calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 120 may be a tantalum filler. According to yet another embodiment, the fire-retardant filler component 120 may be a gypsum filler. According to another embodiment, the flame-retardant filler component 120 may be hydromagnesa. According to yet another embodiment, the flame-retardant filler component 120 may be an aluminum filler. nium trihydrate, magnesium dihydroxide, boehmite, calcium hydroxide, huntite, The filler may be any combination of gypsum, or hydromagnesite.

[0027] According to yet another embodiment, the fire-retardant filler component 120 is selected from a specific group of borate materials. For example, the flame-retardant filler component 120 may be selected from zinc borate, calcium borate, Sodium borate, potassium borate, lithium borate, and any combination thereof The compound may be selected from the group consisting of:

[0028] According to yet another embodiment, the fire-retardant filler component 120 includes certain borate materials. For example, the flame-retardant filler component 120 may include zinc borate. According to another embodiment, the flame-retardant filler component 120 may include calcium borate. For example, the flame-retardant filler component 120 may include sodium borate. For example, the flame-retardant filler component 120 may include potassium borate. For example, the flame-retardant filler component 120 may include lithium borate. For example, the flame retardant filler component 120 may be zinc borate, calcium borate, sodium borate, or The composition may include any combination of potassium borate, potassium phosphate, or lithium borate.

[0029] According to yet another embodiment, the fire-retardant filler component 120 is comprised of certain borate materials. For example, the flame-retardant filler component 120 may comprise zinc borate. According to an embodiment, the fire-retardant filler component 120 may comprise calcium borate. According to an embodiment, the flame-retardant filler component 120 may comprise sodium borate. In some embodiments, the flame-retardant filler component 120 may comprise potassium borate. According to an embodiment, the flame-retardant filler component 120 may comprise lithium borate. According to an embodiment, the fire-retardant filler component 120 is zinc borate, calcium borate, sodium borate, or the like. The borate may consist of any combination of thorium, potassium borate, or lithium borate.

[0030] According to yet another embodiment, the flame-retardant filler component 120 is a specific borate material filler. For example, the flame-retardant filler component 120 can be a zinc borate filler. According to another embodiment, the fire-retardant filler component 120 may be a calcium borate filler. According to another embodiment, the flame-retardant filler component 120 may be a sodium borate filler. According to yet another embodiment, the flame-retardant filler component 120 is a potassium borate filler. According to yet another embodiment, the flame-retardant filler component 120 may be a lithium borate filler. According to yet another embodiment, the flame-retardant filler component 120 may be zinc borate, boron nitride, or the like. Any combination of calcium borate, sodium borate, potassium borate, or lithium borate It may be a composite filler.

[0031] According to yet another embodiment, the flame-retardant filler component 120 is selected from a specific group of platinum compound materials. For example, the flame retardant filler component 120 may be selected from platinum-1,3-divinyl-1, 1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof The compound may be selected from the group consisting of:

[0032] According to yet another embodiment, the flame-retardant filler component 120 includes certain platinum compound materials. For example, the flame retardant filler component 120 may be platinum-1,3-divinyl-1,1,3,3 According to yet another embodiment, the flame retardant filler composition may include tetramethyldisiloxane. The component 120 may include hexachloroplatinic acid. According to yet another embodiment, the flame-retardant filler Component 120 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxane and and hexachloroplatinic acid.

[0033] According to yet another embodiment, the flame-retardant filler component 120 is made from certain platinum compound materials. For example, the flame retardant filler component 120 can be platinum-1,3-divinyl-1,1,3, According to yet another embodiment, the flame retardant filling may consist of 3-tetramethyldisiloxane. The agent component 120 may comprise hexachloroplatinic acid. Filler component 120 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxy The composition may consist of any combination of tetrachloroplatinic acid and hexachloroplatinic acid.

[0034] According to yet another embodiment, the flame-retardant filler component 120 is a filler of certain platinum compound materials. For example, the flame retardant filler component 120 may be platinum-1,3-divinyl-1,1, According to yet another embodiment, the filler may be 3,3-tetramethyldisiloxane. The flame retardant filler component 120 can be a hexachloroplatinic acid filler. For example, the flame retardant filler component 120 may be a filler or a platinum-1,3-divinyl-1,1,3, It can be any combination of 3-tetramethyldisiloxane and hexachloroplatinic acid.

[0035] According to yet another embodiment, the flame-retardant filler component 120 is a specific transition metal oxide material. For example, the flame retardant filler component 120 may be selected from the group consisting of iron oxide, cerium oxide, acid The inorganic filler may be selected from the group consisting of titanium dioxide, zinc oxide, and any combination thereof.

[0036] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 120 may include iron oxide. According to an embodiment, the flame-retardant filler component 120 may include cerium oxide. For example, the flame-retardant filler component 120 may include zinc oxide. The reactive filler component 120 may be any combination of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It may include a combination.

[0037] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 120 may comprise iron oxide. According to an embodiment, the flame-retardant filler component 120 may comprise cerium oxide. According to one embodiment, the flame-retardant filler component 120 may comprise zinc oxide. For example, the flame-retardant filler component 120 may be any of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It can consist of any combination of

[0038] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 120 may be an iron oxide filler. According to yet another embodiment, the flame-retardant filler component 120 may be a cerium oxide filler. According to another embodiment, the flame-retardant filler component 120 may be a zinc oxide filler. According to this embodiment, the flame retardant filler component 120 may be selected from the group consisting of iron oxide, cerium oxide, titanium oxide, or zinc oxide filler in any combination.

[0039] According to yet another embodiment, the fire-retardant filler component 120 is selected from a specific group of metal carbonate materials. For example, the flame-retardant filler component 120 may be selected from huntite, calcium carbonate, and any combination thereof.

[0040] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 120 may include huntite. According to an embodiment, the flame-retardant filler component 120 may include calcium carbonate. According to the embodiment, the fire-retardant filler component 120 may be any combination of huntite or calcium carbonate. It may include a combination.

[0041] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 120 may consist of huntite. According to one embodiment, the flame-retardant filler component 120 may comprise calcium carbonate. According to this embodiment, the fire-retardant filler component 120 is either huntite or calcium carbonate. It can consist of a combination of:

[0042] According to yet another embodiment, the flame-retardant filler component 120 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 120 can be a huntite filler. According to yet another embodiment, the flame-retardant filler component 120 is a calcium carbonate filler. According to yet another embodiment, the flame-retardant filler component 120 is huntite or calcium carbonate. The filler may be any combination of sodium.

[0043] According to yet another embodiment, the fire-retardant filler component 120 is a metal carbonate mixture containing For example, the flame-retardant filler component 120 may be selected from the group consisting of hydromagnesite and han natural mixtures with tait, synthetic magnesium carbonate hydroxide pentahydrate, and any combination thereof The compound may be selected from the group consisting of:

[0044] According to yet another embodiment, the fire-retardant filler component 120 comprises a mixture of certain metal carbonates. For example, the fire-retardant filler component 120 may include a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 120 is a hydromagnesite sol. According to yet another embodiment, the flame-retardant filler component 120 may include a hydrophilic or hydrophilic mixture. Natural mixture of magnesite and huntite, or synthetic magnesium hydroxide carbonate pentahydrate Any combination may be included.

[0045] According to yet another embodiment, the flame-retardant filler component 120 is made from a specific metal carbonate mixture. For example, the fire-retardant filler component 120 may be a natural mixture of hydromagnesite or According to another embodiment, the flame-retardant filler component 120 can comprise hydromagnesite. According to yet another embodiment, the flame-retardant filler component 120 may comprise a natural mixture of A natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate pentahydrate The compound may be any combination of solvates.

[0046] According to yet another embodiment, the fire-retardant filler component 120 is a specific metal carbonate mixture filler. For example, the fire-retardant filler component 120 may be a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 120 may be a hydromatrix filler. According to yet another embodiment, the fire-retardant filler may be a natural mixture of gnesite. Ingredient 120 is a natural mixture of hydromagnesite and huntite, or a synthetic hydroxycarbonate. The filler may be any combination of magnesium pentahydrate.

[0047] According to yet another embodiment, the flame-retardant filler component 120 is an alumina silicate material or For example, the flame retardant filler component 120 may be selected from a specific group of magnesium carbonate materials. , wollastonite, mica, kaolin, clay, talc, vermiculite, and their Any combination may be selected from the group consisting of:

[0048] According to yet another embodiment, the flame-retardant filler component 120 is a specific alumina silicate material. For example, the flame-retardant filler component 120 may include a wollastonite or magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 120 may include mica. According to yet another embodiment, the flame-retardant filler component 120 may include clay. According to this embodiment, the flame-retardant filler component 120 may include kaolin. According to one embodiment, the flame-retardant filler component 120 may include talc. The fire-retardant filler component 120 may include vermiculite. The flame retardant filler component 120 may be selected from the group consisting of wollastonite, mica, clay, kaolin, talc, and basil. The composition may include any combination of cellulose, cellulose acetate, cellulose nitrate, cellulose acetate, cellulose acetate nitrate ...

[0049] According to yet another embodiment, the flame-retardant filler component 120 is a specific alumina silicate material. or magnesium silicate material. For example, the flame-retardant filler component 120 may be composed of a wallaceite or a magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 120 may consist of myrtle. According to yet another embodiment, the flame-retardant filler component 220 may comprise clay. According to another embodiment, the flame-retardant filler component 120 may comprise kaolin. According to yet another embodiment, the flame-retardant filler component 120 may comprise talc. According to an embodiment, the flame-retardant filler component 120 may comprise vermiculite. According to the embodiment, the flame retardant filler component 120 may be selected from the group consisting of wollastonite, mica, clay, kaolin, The granular material may be any combination of talc, or vermiculite.

[0050] According to yet another embodiment, the flame-retardant filler component 120 is a specific alumina silicate material. or a magnesium silicate material filler. For example, the flame-retardant filler component 120 may be: According to yet another embodiment, the flame retardant filler component 12 may be a wollastonite filler. According to yet another embodiment, the flame-retardant filler component 220 is According to another embodiment, the fire-retardant filler component 120 may be kaolin, According to yet another embodiment, the flame-retardant filler component 120 may be a talc filler. According to another embodiment, the fire-retardant filler component 120 may be vermiculite. According to yet another embodiment, the flame-retardant filler component 120 may be a wollastonite filler. Filled with any combination of ash, mica, clay, kaolin, talc, or vermiculite It may be a filler.

[0051] According to yet another embodiment, the flame retardant filler component 120 is selected from a specific group of alkali salt materials. For example, the flame-retardant filler component 120 may be selected from sodium carbonate, potassium carbonate, and any combination thereof.

[0052] According to yet another embodiment, the flame-retardant filler component 120 includes certain alkali salt materials. For example, the flame-retardant filler component 120 may include sodium carbonate. According to an embodiment, the flame-retardant filler component 120 may include potassium carbonate. According to an embodiment, the flame retardant filler component 120 may be any combination of sodium carbonate or potassium carbonate. It may include a combination.

[0053] According to yet another embodiment, the flame retardant filler component 120 is made from certain alkali salt materials. For example, the flame-retardant filler component 120 may comprise sodium carbonate. According to one embodiment, the flame-retardant filler component 120 may comprise potassium carbonate. According to an embodiment, the flame retardant filler component 120 is either sodium carbonate or potassium carbonate. It can consist of a combination of:

[0054] According to yet another embodiment, the fire-retardant filler component 120 is a filler of a specific alkali salt material. For example, the flame-retardant filler component 120 can be a sodium carbonate filler. According to yet another embodiment, the flame-retardant filler component 120 may be potassium carbonate filler. According to yet another embodiment, the flame-retardant filler component 120 is sodium carbonate or calcium carbonate. The filler may be any combination of sodium.

[0055] According to yet another embodiment, the insulating filler component 130 is selected from a specific group of materials. For example, the insulating filler component 130 may be expanded perlite, unexpanded perlite, glass, or the like. Subeeds, vermiculite, expanded vermiculite, expanded glass, zeolite, aero Gel, silica, porous silica, porous alumina, and any combination thereof It may be selected from the group:

[0056] According to yet other embodiments, the insulating filler component 130 may include certain materials. For example, the insulating filler component 130 may include expanded perlite. Alternatively, the insulating filler component 130 may include unexpanded perlite. According to still other embodiments, the insulating filler component 130 may include glass beads. In other embodiments, insulating filler component 130 may include vermiculite. Accordingly, the insulating filler component 130 may include expanded vermiculite. According to an embodiment, the insulating filler component 130 may include expanded glass. According to another embodiment, the insulating filler component 130 may include zeolite. For example, the insulating filler component 130 may include an aerogel. The insulating filler component 130 may include silica. The filler component 130 may comprise porous silica. According to another embodiment, the insulating filler component 130 may comprise porous alumina. According to yet another embodiment, the insulating filler component 1 30 is a list of expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite -miculite, expanded glass, zeolite, aerogel, silica, porous silica, or poly The porous alumina may comprise any combination of porous alumina.

[0057] According to yet other embodiments, the insulating filler component 130 may be made of specific materials. For example, the insulating filler component 130 may consist of expanded perlite. According to yet another embodiment, the insulating filler component 130 may comprise unexpanded perlite. In some embodiments, the insulating filler component 130 may consist of glass beads. In some embodiments, the insulating filler component 130 may comprise vermiculite. According to an embodiment, the insulating filler component 130 may comprise expanded vermiculite. According to yet another embodiment, the insulating filler component 130 may be comprised of expanded glass. According to yet another embodiment, the insulating filler component 130 may comprise a zeolite. According to this embodiment, the insulating filler component 130 may comprise an aerogel. According to an embodiment, the insulating filler component 130 may comprise silica. According to an embodiment, the insulating filler component 130 may comprise porous silica. For example, the insulating filler component 130 may be comprised of porous alumina. For example, the insulating filler component 130 may be expanded perlite, non-expanded perlite, glass beads, Vermiculite, expanded vermiculite, expanded glass, zeolite, aerogel, silica The porous silica may be any combination of quartz, porous silica, or porous alumina.

[0058] According to yet another embodiment, the insulating filler component 130 is a filler of a specific material. For example, the insulating filler component 130 can be expanded perlite filler. According to this embodiment, the insulating filler component 130 may be a non-expanded perlite filler. According to yet another embodiment, the insulating filler component 130 may be a glass bead filler. According to yet another embodiment, the insulating filler component 130 is a vermiculite filler. According to yet another embodiment, the insulating filler component 130 can be expanded vermiculite. According to yet another embodiment, the insulating filler component 130 may be a foamed or swelled filler. According to yet another embodiment, the flame-retardant filler component 220 may be: According to yet another embodiment, the insulating filler component 130 may be a zeolite filler. According to yet another embodiment, the insulating filler component 130 can be an aerogel filler. According to yet another embodiment, the insulating filler component 130 may be: According to another embodiment, the insulating filler component 130 may be a porous silica filler. According to yet another embodiment, the insulating filler component 130 can be a porous alumina filler. , expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite durite, expanded glass, zeolite, aerogel, silica, porous silica, or porous aluminum The filler may be any combination of Lumina.

[0059] According to a particular embodiment, the first foam layer 104 comprises a specific content of silicone-based For example, the first foam layer 104 may include a matrix component 110. At least about 20% by weight, for example, at least about 25% by weight, based on the total weight of the rubber layer 104 , or at least about 30% by weight, or at least about 35% by weight, or at least about 40% by weight %, or at least about 45% by weight, or even at least about 50% by weight of silicone-based According to yet another embodiment, the first foam layer 1 The first foam layer 104 is about 85% by weight or less, for example, about 80% by weight or less, based on the total weight of the first foam layer 104. % by weight or less, or about 75% by weight or less, or about 70% by weight or less, or even about 65% by weight or less The silicone matrix component content of the first foam layer 104 may be The content of the inorganic matrix component may be within a range between any of the values ​​above. It will be understood that the silicone matrix component content of the first foam layer 104 is It will be further understood that the minimum and maximum values ​​may be any value between any of the values ​​set forth above. cormorant.

[0060] According to yet another embodiment, the first foam layer 104 contains a specific content of a flame-retardant filling. For example, the first foam layer 104 may include a foam component 120. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the flame-retardant filler component may comprise at least about 15% of a flame-retardant filler component. The first foam layer 104 comprises about 35% by weight or less of the total weight of the first foam layer 104. , for example, about 34% by weight or less, or about 33% by weight or less, or about 32% by weight or less, or about 3 1% by weight or less, or about 30% by weight or less, or about 28% by weight or less, or about 25% by weight or less; Alternatively, the flame-retardant filler component may contain no more than about 23% by weight, or no more than about 20% by weight. The flame-retardant filler component content of the foam layer 104 of the first embodiment is in the range between any of the above values. It will be understood that the flame-retardant filler component content of the first foam layer 104 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0061] According to yet another embodiment, the first foam layer 104 may have a specific content of insulating filler. For example, the first foam layer 104 may include a foam component 120. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the insulating filler component may contain at least about 15% insulating filler component. The first foam layer 104 comprises about 25% by weight or less of the total weight of the first foam layer 104. , for example, about 24% by weight or less, or about 23% by weight or less, or about 22% by weight or less, or about 2 1% by weight or less, or about 20% by weight or less, or about 19% by weight or less, or about 18% by weight or less; Alternatively, the insulating filler component may contain no more than about 17% by weight, or no more than about 16% by weight. The insulating filler content of the foam layer 104 may range between any of the values ​​above. It will be understood that the insulating filler content of the first foam layer 104 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0062] According to certain embodiments, the first foam layer 104 is made in accordance with ASTM D4986. In particular, the foam layer may have a specific flammability rating as measured by ASTM D4986. The flame retardant may have an HBF flammability rating measured in accordance with the HBF flammability rating.

[0063] According to certain embodiments, the first foam layer 104 is made in accordance with ASTM D3801. In particular, the foam layer may have a specific flammability rating as measured by ASTM D3801. It may have a V-0 flammability rating as measured in accordance with

[0064] According to certain embodiments, the multi-layer composite 100 has a thickness of 100 sq ft (100 sq m) measured in accordance with ASTM D4986. In particular, the foam layer may have a specific flammability rating according to ASTM D4986. It may have an HBF flammability rating measured by

[0065] According to certain embodiments, the multi-layer composite 100 has a thickness of 100 sq ft (100 sq m) measured in accordance with ASTM D3801. In particular, the foam layer may have a specific flammability rating according to ASTM D3801. It may have a V-0 flammability rating as measured by

[0066] According to yet another embodiment, the first foam layer 104 is hot rolled at a temperature of 650°C. The present invention relates to a method for producing a fluorine-containing polymer having a specific autoignition time when exposed to a plate test. For morphology purposes, hot plate testing prepare 1 inch x 1 inch specimens of the material. This is done by placing the test piece on a hot plate. The cold surface temperature was measured by fixing it to a steel weight (1 inch diameter, 2 inches high) placed on top of the The temperature curve is recorded and the point of autoignition, if any, is noted. For example, the first foam layer 104 may be heated for at least about 1 minute, such as at least about 1.5 minutes, or is at least about 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least at least about 3.5 minutes, or at least about 4.0 minutes, or at least about 4.5 minutes, or even less The first foam layer 104 may have an autoignition time of at least about 5.0 minutes. It will be understood that the value of the first formula may range between any of the above values. The self-ignition time of the rubber layer 104 can be any value between any of the above values. will be further understood.

[0067] According to yet another embodiment, the multi-layer composite 100 is hot plated at a temperature of 650°C. The embodiments described herein may have a specific autoignition time when exposed to a test. For the purposes of the hot plate test, a 1 inch x 1 inch specimen of the material is prepared and This is done by placing the specimen on a hot plate. Then, a thermocouple is placed on the specimen. The cold surface temperature is measured by fixing it to a steel weight (1 inch in diameter, 2 inches in height) placed on the The temperature curve is recorded and the point of autoignition, if any, is noted. The layer composite 100 may be heated for at least about 1 minute, for example, at least about 1.5 minutes, or at least About 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least about 3.5 minutes , or at least about 4.0 minutes, or at least about 4.5 minutes, or even at least about 5. The multilayer composite 100 may have an autoignition time of 0 minutes. It will be understood that the autoignition time of the multi-layer composite 100 may range anywhere between. It will be further understood that σ can be any value between any of the above values.

[0068] According to yet another embodiment, the first foam layer 104 is made up of 6 layers of foam 3 mm thick. It has a specific cold side temperature measured at 5 minutes when exposed to a 50°C hot plate test. For purposes of the embodiments described herein, the hot plate test is performed on one This was performed by preparing a 1 inch x 1 inch test specimen and placing it on a hot plate. The thermocouple is then attached to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to a specific embodiment, the first foam layer 10 4 is about 300°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less or about 200°C or less, or about 175°C or less, or even about 150°C or less According to yet another embodiment, the first foam layer 104 may have a viscosity of at least about 25 ° C. The cold side temperature of the first foam layer 104 may be It will be understood that the cold side of the first foam layer 104 can be anywhere in between. It will be further understood that the temperature can be any value between any of the above values.

[0069] According to yet another embodiment, the multi-layer composite 100 is heat-resistant when a 3 mm thick foam is heated to 650°C. may have a specific cold side temperature measured at 5 minutes when exposed to a hot plate test of For purposes of the embodiments described herein, the hot plate test is performed on a 1 inch x 1 inch section of material. This is done by preparing a 1 inch test specimen and placing it on a hot plate. The thermocouple was then fixed to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to a particular embodiment, the multilayer composite 100 is heated to approximately 30 0°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less, or about 2 The catalyst may have a low temperature of about 100°C or less, or about 175°C or less, or even about 150°C or less. According to yet another embodiment, the multi-layer composite 100 has a cold side temperature of at least about 25°C. The low-side temperature of the multilayer composite 100 may be within a range between any of the above values. It will be appreciated that the cold side temperature of the multi-layer composite 100 may be any of the above values. It will be further understood that the value may be any value between these.

[0070] According to yet another embodiment, the multi-layer composite 100 is subjected to a temperature of 1000°C. The composition may have a specific burn-through time that is measured when exposed to a blast test. For purposes of the described embodiment, the torch test involves preparing a 1 inch by 1 inch specimen of the material. This is done by placing the thermocouple 1.5 inches from the torch. The second thermocouple is fixed to the side to measure the "hot side" temperature and adjust it to 1000°C. Position it on the opposite side of the sample to measure the "cold side" temperature. If this occurs, the torch will burn the sample. The time until the film is burned out (burn-through time) is measured. The composite 100 may be heated for at least about 6 minutes, e.g., at least about 6.5 minutes, or at least about 7 minutes. minutes, or at least about 7.5 minutes, or at least about 8 minutes, or at least about 8.5 minutes, or is at least about 9.0 minutes, or at least about 9.5 minutes, or even at least about 10.0 minutes The burn-through time of the multilayer composite 100 may be greater than or equal to the above values. It will be understood that the burn-in temperature of the multilayer composite 100 may be within a range between any of the above. It is further understood that the slew time can be any value between any of the above values. Hello.

[0071] According to still other embodiments, the first foam layer 104 may have a particular thickness. For example, the first foam layer 104 may be at least about 0.5 mm, e.g., at least about 1 0.0 mm, or at least about 1.5 mm, or at least about 2.0 mm, or at least About 2.5 mm, or at least about 3.0 mm, or at least about 3.5 mm, or less Both are about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm. According to yet another embodiment, the first foam layer 104 may have a thickness of about 10 mm or more. or less, for example, about 9.5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less The thickness of the first foam layer 104 may be about 6.0 mm or less. It will be understood that the range may be between any of the minimum and maximum values ​​set forth above. The thickness of the foam layer 104 may be any value between any of the minimum and maximum values ​​listed above. It will be further appreciated that the value may be:

[0072] According to still other embodiments, the multi-layer composite 100 may have a particular thickness, for example , the multilayer composite 100 may be at least about 0.5 mm, e.g., at least about 1.0 mm, or is at least about 1.5 mm, or at least about 2.0 mm, or at least about 2.5 mm , or at least about 3.0 mm, or at least about 3.5 mm, or at least about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm thick. According to yet another embodiment, the multi-layer composite 100 is about 10 mm or less, for example, about 9. 5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or is about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less, or even about 6. The thickness of the multilayer composite 100 may be within the above minimum and maximum values. It will be understood that the thickness of the multilayer composite 100 may range between any of the following: It is further understood that the value may be any value between any of the above minimum and maximum values. Hello.

[0073] According to yet another embodiment, the first foam layer 104 has a specific 25% strain compression. For purposes of the embodiments described herein, a 25% strain compression grade is: Defined as the compressive strength of a specimen measured at 25% strain, Force-to-compression is determined by measuring the deflection. FTC is defined as the peak force (or stress) that compresses a sample to a given strain. The compression-force-deflection (CFD) is the desired strain (i.e., 2 as the plateau or relaxation force (or stress) sustained by the sample when held at 5% Defined as: 60 second hold time, 0.16 mm / sec compression speed, and 10 gram trigger. - Texture analyzer to find and record both FTC and CFD values ​​after force Use to take measurements.

[0074] According to certain embodiments, the first foam layer 104 has a pressure of about 500 kPa or less, e.g. , about 475 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 40 0 kPa or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or is about 225 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 15 25% strain compression at 0 kPa or less, or approximately 125 kPa or less, or approximately 100 kPa or less According to yet another embodiment, the first foam layer 104 may have a viscosity of at least about 5 kPa, for example, at least about 10 kPa, or at least about 15 kPa, or at least The first may also have a 25% strain compression rating of about 20 kPa, or at least about 25 kPa. The 25% strain compression rating of the foam layer 104 is either of the minimum and maximum values ​​set forth above. It will be understood that the strain of the first foam layer 104 can be within a range between 50% strain and 100% strain. It is understood that the compression rating may be any value between any of the minimum and maximum values ​​listed above. Let's understand more.

[0075] According to yet another embodiment, the multi-layer composite 100 may have a specific 25% strain compression rating. For purposes of the embodiments described herein, a 25% strain compressive grade may have a strain of 25%. It is defined as the compressive strength of the specimen measured at 25% strain and The compressive force (FTC) is determined by measuring the deflection of the specimen. The compressive force deflection (CFD) is defined as the peak force (or stress) that compresses the specimen to the desired The plateau or strain maintained by the sample when held at the desired strain (i.e., 25%) Defined as the relaxation force (or stress), with a holding time of 60 seconds and a compression rate of 0.16 mm / s. and find and record both the FTC and CFD values ​​after 10 grams of trigger force. Measurements are taken using a texture analyzer.

[0076] According to certain embodiments, the multilayer composite 100 has a compressive strength of about 500 kPa or less, e.g., about 4 75 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 400 kPa a or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or about 2 25 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 150 kPa a or less, or about 125 kPa or less, or about 100 kPa or less at 25% strain compression. According to yet another embodiment, the multi-layer composite 100 may have a compressibility of at least about 5 kPa, e.g. For example, at least about 10 kPa, or at least about 15 kPa, or at least about 20 kPa a, or a 25% strain compression rating of at least about 25 kPa. The 25% strain compression grade of the material falls within the range between any of the minimum and maximum values ​​above. It will be understood that the 50% strain compression rating of the multi-layer composite 100 may be greater than or equal to the minimum value set forth above. It will be further understood that the maximum value may be any value between any of the above.

[0077] According to still other embodiments, the first foam layer 104 may have a particular density. For purposes of the embodiments described herein, the density of the first foam layer 104 is determined by ASTM According to certain embodiments, the first foam layer 104 is approximately 1200 kg / m 3 Below, for example, about 1175 kg / m 3 or less, or about 1150k g / m 3 or less than 1125 kg / m 3 or less than 1100 kg / m 3 Below, or 105 0kg / m 3 or less than 1000 kg / m 3 or less, or 950 kg / m 3 or less, or 90 0kg / m 3 or less, or 850 kg / m 3 or less than 800 kg / m 3 or less, or 750 kg / m 3 or less than 700 kg / m 3 or less, or even 650 kg / m 3 The density of According to yet another embodiment, the first foam layer 104 may have a thickness of at least about 10 0kg / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m 3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or less At least about 200 kg / m 3 , or at least about 220 kg / m 3 , or even at least Approximately 240 kg / m 3 The density of the first foam layer 104 may be at least the above-mentioned minimum. It will be understood that the value may be within a range between any of the values ​​and the maximum value. The density of the foam layer 104 is any value between any of the minimum and maximum values ​​described above. It will be further understood that

[0078] According to still other embodiments, the multi-layer composite 100 may have a particular density. For purposes of the embodiments described herein, the density of the first foam layer 104 is ASTM D1 According to certain embodiments, the multilayer composite 100 may be formed at a temperature of about 150 0kg / m 3 For example, about 1475 kg / m 3 or less, or about 1450 kg / m 3 below , or 1425 kg / m 3 or less than 1400 kg / m 3 or less, or 1350 kg / m 3 or less than 1300 kg / m 3 or less than 1250 kg / m 3 or less than 1200kg / m 3 or less than 1150 kg / m 3 or less than 1100 kg / m 3 Below, or 1050k g / m 3 or less than 1000 kg / m 3 or even 950 kg / m 3 The density of According to yet another embodiment, the multi-layer composite 100 can have a weight capacity of at least about 100 kg. / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m 3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or at least Approximately 200 kg / m 3 , or at least about 220 kg / m 3 , or even at least about 2 40kg / m3 The density of the multilayer composite 100 may be between the above minimum and maximum values. It will be appreciated that the density of the multilayer composite 100 may be within a range between any of the following: It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0079] According to yet another embodiment, the first foam layer 104 is made of a material conforming to ASTM C518. For example, the first foam layer 104 may have a particular thermal conductivity as measured by At least about 0.01 W / mK, for example, at least about 0.02 W / mK, or at least about 0 0.03 W / mK, or at least about 0.04 W / mK, or even at least about 0.05 According to yet another embodiment, the first foam layer 104 may have a thermal conductivity of , about 0.15 W / mK or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less or less, or about 0.12 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less, about 0.09 W / mK or less, or about 0.08 W / mK, or even about 0.07 W The thermal conductivity of the first foam layer 104 may be less than or equal to the minimum value. It will be understood that the range may be anywhere between 0.01 and 0.02. The thermal conductivity of the rubber layer 104 is any value between any of the minimum and maximum values ​​listed above. It will be further understood that this is possible.

[0080] According to yet another embodiment, the multi-layer composite 100 is For example, the multilayer composite 100 may have a specific thermal conductivity of at least about 0.0 1 W / mK, e.g., at least about 0.02 W / mK, or at least about 0.03 W / m K, or at least about 0.04 W / mK, or even at least about 0.05 W / mK According to yet another embodiment, the multilayer composite 100 may have a conductivity of about 0.15 W / m K or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less, or about 0.1 2 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less, about 0.0 Thermal conductivity of 9 W / mK or less, or about 0.08 W / mK, or even about 0.07 W / mK or less The thermal conductivity of the multilayer composite 100 may be any of the minimum and maximum values ​​listed above. It will be appreciated that the thermal conductivity of the multilayer composite 100 may be within a range between the above values. It will be further understood that the minimum and maximum values ​​may be any value between any of the minimum and maximum values.

[0081] According to yet another embodiment, the first barrier layer 102 is made of mica, mica fiberglass cloth, , glass cloth, silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, non-woven glass cloth, any combination thereof, and any laminate thereof. It can be a material that can be used.

[0082] According to yet another embodiment, the first barrier layer 102 may comprise a specific material. For example, the first barrier layer 102 may include mica. The rear layer 102 may comprise a mica fiberglass cloth. According to yet another embodiment, the first The barrier layer 102 may comprise a glass cloth. According to another embodiment, the first barrier layer 102 According to yet another embodiment, the first barrier layer 102 may comprise a basal According to yet another embodiment, the first barrier layer 102 may comprise a vermicular According to another embodiment, the first barrier layer 102 may comprise an aerosol coated glass cloth. According to yet another embodiment, the first barrier layer 102 may comprise a nonwoven glass cloth. According to yet another embodiment, the first barrier layer 102 may comprise mica, mica fibers, Glass cloth, glass cloth, silica cloth, basalt cloth, vermiculite-coated glass cloth, aerogel According to still other embodiments, the first and second layers may include any combination of glass fiber, glass fiber reinforced plastic ... The barrier layer 102 may be made of mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, or the like. , including any laminate of vermiculite-coated glass cloth, aerogel, or nonwoven glass cloth. obtain.

[0083] According to yet another embodiment, the first barrier layer 102 may be made of a specific material. For example, the first barrier layer 102 may be made of mica. The barrier layer 102 may be made of mica fiberglass cloth. The first barrier layer 102 may consist of glass cloth. According to another embodiment, the first barrier Layer 102 may be made of silica cloth. According to yet another embodiment, first barrier layer 102 According to yet another embodiment, the first barrier layer 102 may be made of basalt fabric. According to another embodiment, the first barrier layer 1 may be made of vermiculite coated glass cloth. According to yet another embodiment, the first barrier layer 102 may be made of aerogel. According to yet another embodiment, the first barrier layer 102 may be made of a non-woven glass cloth. Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It may be made of any combination of glass cloth, aerogel, or non-woven glass cloth. According to an embodiment, the first barrier layer 102 may be made of mica, mica fiberglass cloth, glass cloth, Silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or non-woven glass cloth The laminate may be any laminate of the above.

[0084] According to yet another embodiment, the first barrier layer 102 can be a layer of a specific material. For example, the first barrier layer 102 can be a mica layer. The barrier layer 102 may be a mica fiberglass cloth layer. The first barrier layer 102 can be a glass cloth layer. According to another embodiment, the first barrier Layer 102 can be a silica cloth layer. According to yet another embodiment, first barrier layer 102 According to yet another embodiment, the first barrier layer 102 may be a basalt fabric layer. According to another embodiment, the first barrier layer 1 may be a vermiculite-coated glass cloth layer. According to yet another embodiment, the first barrier layer 102 may be an aerogel layer. According to yet another embodiment, the first barrier layer 102 is Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It can be a layer of glass cloth, aerogel, or any combination of non-woven glass cloth. According to this embodiment, the first barrier layer 102 is made of mica, mica fiber glass cloth, glass cloth, , silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or nonwoven glass It can be any laminate layer of fabric.

[0085] According to still other embodiments, the first barrier layer 102 may have a particular thickness. For example, the first barrier layer 102 may be at least about 0.05 mm, e.g., at least about 0. 1 mm, or at least about 0.2 mm, or at least about 0.3 mm, or at least about 0.4 mm, or at least about 0.5 mm, or at least about 0.6 mm, or at least at least about 0.7 mm, or at least about 0.8 mm, or at least about 0.9 mm, or less at least about 1.0 mm, or at least about 1.1 mm, or at least about 1.2 mm, or It may have a thickness of at least about 1.3 mm, or even at least about 1.4 mm. According to this embodiment, the first barrier layer 102 is about 7 mm or less, for example, about 6.5 mm or less. or less than about 6.0 mm, or less than about 5.5 mm, or less than about 5.0 mm, or less than about 4. 5 mm or less, or about 4.0 mm or less, or about 3.5 mm or less, or about 3.0 mm or less, or is about 2.9 mm or less, or about 2.8 mm or less, or about 2.7 mm or less, or about 2.6 mm or less, or about 2.5 mm or less, or about 2.4 mm or less, or about 2.3 mm or less, or even The thickness of the first barrier layer 102 may be less than or equal to the above minimum value. It will be understood that the first barrier layer may be in a range between any of the above values. The thickness of 102 can be any value between any of the minimum and maximum values ​​listed above. This will be further understood.

[0086] FIG. 2 illustrates another multi-layer composite 200 according to embodiments described herein. As shown, the multi-layer composite 200 includes a first barrier layer 202, a first foam layer 204, and a , and a second barrier layer 206. The first foam layer 204 may comprise a silicone-based matrix. The composition may include a flame retardant filler component 210, a flame retardant filler component 220, and a thermal insulating filler component 230.

[0087] Multilayer composite 200 and all of the components described with respect to multilayer composite 200 shown in FIG. The components may have any of the characteristics described herein with respect to the corresponding components in FIG. In particular, the multi-layer composite 200 shown in FIG. a foam layer 202, a first foam layer 204, a silicone matrix component 210, a flame-retardant filler The properties of the filler component 220 and the insulating filler component 230 are respectively the same as those of the multilayer structure shown in FIG. Composite 100, first barrier layer 102, first foam layer 104, silicone matrix The present specification is concerned with the flame retardant filler component 110, the flame retardant filler component 120, and the heat insulating filler component 130. The ion exchangeable material may have any of the corresponding characteristics described in the document.

[0088] According to yet another embodiment, the second barrier layer 206 may be made of mica, mica fiberglass cloth, or the like. , glass cloth, silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, non-woven glass cloth, any combination thereof, and any laminate thereof. It can be a material that can be used.

[0089] According to yet other embodiments, the second barrier layer 206 may comprise a specific material. For example, the second barrier layer 206 may include mica. The rear layer 206 may include a mica fiberglass cloth. According to yet another embodiment, the second The barrier layer 206 may include glass cloth. According to another embodiment, the second barrier layer 206 According to yet another embodiment, the second barrier layer 206 may comprise a basal According to yet another embodiment, the second barrier layer 206 may comprise a vermicular According to another embodiment, the second barrier layer 206 may comprise an aerosol coated glass cloth. According to yet another embodiment, the second barrier layer 206 may comprise a non-woven glass cloth. According to yet another embodiment, the second barrier layer 206 may include mica, mica fibers, Glass cloth, glass cloth, silica cloth, basalt cloth, vermiculite-coated glass cloth, aerogel According to still other embodiments, the first and second layers may include any combination of glass fiber, glass fiber reinforced plastic ... The second barrier layer 206 may be made of mica, mica fiberglass cloth, glass cloth, silica cloth, or basalt cloth. , including any laminate of vermiculite-coated glass cloth, aerogel, or nonwoven glass cloth. obtain.

[0090] According to yet other embodiments, the second barrier layer 206 may be made of a specific material. For example, the second barrier layer 206 may be made of mica. The barrier layer 206 may be made of mica fiberglass cloth. The second barrier layer 206 may be made of glass cloth. According to another embodiment, the second barrier Layer 206 may be made of silica cloth. According to yet another embodiment, second barrier layer 206 According to yet another embodiment, the second barrier layer 206 may be made of basalt fabric. According to another embodiment, the second barrier layer 2 may be made of vermiculite coated glass cloth. According to yet another embodiment, the second barrier layer 206 may be made of aerogel. According to yet another embodiment, the second barrier layer 206 may be made of a non-woven glass cloth. Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It may be made of any combination of glass cloth, aerogel, or non-woven glass cloth. According to an embodiment, the second barrier layer 206 may be made of mica, mica fiberglass cloth, glass cloth, Silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or non-woven glass cloth The laminate may be any laminate of the above.

[0091] According to yet another embodiment, the second barrier layer 206 can be a layer of a specific material. For example, the second barrier layer 206 can be a mica layer. The barrier layer 206 may be a mica fiberglass cloth layer. The second barrier layer 206 can be a glass cloth layer. According to another embodiment, the second barrier Layer 206 may be a silica cloth layer. According to yet another embodiment, second barrier layer 206 According to yet another embodiment, the second barrier layer 206 may be a basalt fabric layer. According to another embodiment, the second barrier layer 2 may be a vermiculite-coated glass cloth layer. According to yet another embodiment, the second barrier layer 206 may be an aerogel layer. According to yet another embodiment, the second barrier layer 206 is Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It can be a layer of glass cloth, aerogel, or any combination of non-woven glass cloth. According to this embodiment, the second barrier layer 206 is made of mica, mica fiber glass cloth, glass cloth, , silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or nonwoven glass It can be any laminate layer of fabric.

[0092] According to still other embodiments, the second barrier layer 206 may have a particular thickness. For example, the second barrier layer 206 may be at least about 0.05 mm, e.g., at least about 0. 1 mm, or at least about 0.2 mm, or at least about 0.3 mm, or at least about 0.4 mm, or at least about 0.5 mm, or at least about 0.6 mm, or at least at least about 0.7 mm, or at least about 0.8 mm, or at least about 0.9 mm, or less at least about 1.0 mm, or at least about 1.1 mm, or at least about 1.2 mm, or It may have a thickness of at least about 1.3 mm, or even at least about 1.4 mm. According to this embodiment, the second barrier layer 206 is about 3.7 mm or less, for example, about 6.5 mm. mm or less, or about 6.0 mm or less, or about 5.5 mm or less, or about 5.0 mm or less, or about Not more than 4.5 mm, or not more than about 4.0 mm, or not more than about 2.9 mm, or not more than about 2.8 mm or less, or about 2.7 mm or less, or about 2.6 mm or less, or about 2.5 mm or less, or It may have a thickness of about 2.4 mm or less, or about 2.3 mm or less, or even about 2.2 mm or less. The thickness of the second barrier layer 206 may be in a range between any of the above minimum and maximum values. It will be understood that the thickness of the second barrier layer 206 may be within the above minimum and It will be further understood that the maximum value may be any value between any of the maximum values.

[0093] FIG. 3 illustrates another multi-layer composite 300 according to embodiments described herein. As shown, the multi-layer composite 300 includes a first barrier layer 302, a first foam layer 304, and a , a second foam layer 308, and a second barrier layer 306. 04 is a silicone matrix component 310, a flame retardant filler component 320, and a heat insulating filler component The second foam layer 308 may include a silicone-based matrix component 330. 340, a flame retardant filler component 350, and a thermal insulating filler component 360. As shown, both the first foam layer 304 and the second foam layer 308 are It is between the rear layer 302 and the second barrier layer 308 .

[0094] Multilayer composite 300, and all of the components described with respect to multilayer composite 200 shown in FIG. The components may have the characteristics described herein with respect to the corresponding components in FIG. 1 and / or FIG. 2. It will be appreciated that the multilayer composite 30 shown in FIG. 0, first barrier layer 302, first foam layer 304, second barrier layer 306, silicone a flame-retardant filler component 320; and a heat-insulating filler component 330. The properties are shown in Fig. 1 (Fig. 2) for the multilayer composite 100 (200), the first barrier layer 102 (202), first foam layer 104 (204), silicone matrix composition component 110 (210), flame retardant filler component 120 (220), and insulating filler component 130 It may have any of the corresponding properties described herein for (230).

[0095] According to certain embodiments, the silicone-based matrix component of the second foam layer 308 340 may comprise a platinum catalyzed addition cure silicone foam. The silicone-based matrix component 340 may include a peroxide-cured silicone foam. According to yet another embodiment, the silicone-based matrix component 340 is a tin-catalyzed silicone. According to yet another embodiment, the silicone-based matrix component may comprise corn foam. 340 is a platinum catalyst addition cure silicone foam, a peroxide cure silicone foam, and and tin catalyzed silicone foams.

[0096] According to certain embodiments, the silicone-based matrix component 340 is a platinum-catalyzed curing agent. According to yet another embodiment, the silicone matrix may be a fluorinated silicone foam. The foam component 340 may comprise a peroxide-cured silicone foam. According to the patent, the silicone matrix component 340 is comprised of a tin-catalyzed silicone foam. According to yet another embodiment, the silicone-based matrix component 340 may be a platinum-catalyzed Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam It may consist of any combination of information.

[0097] According to certain embodiments, the silicone-based matrix component 340 is a platinum-catalyzed curing agent. According to yet another embodiment, the layer may be a silicone-based matrix. The foam component 340 can be a peroxide-cured silicone foam layer. According to the patent, the silicone matrix component 340 is a tin-catalyzed silicone foam layer. According to yet another embodiment, the silicone-based matrix component 340 may be a platinum-catalyzed Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam The layer may be any combination of layers of foam.

[0098] According to yet another embodiment, the flame-retardant filler component 350 is selected from a specific group of materials. For example, the flame-retardant filler component 350 may be a metal hydrate, a borate compound, a platinum compound, or the like. Substances, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate Nesium, glass frit, alkali salts, vermiculite, and any combination thereof The compound may be selected from the group consisting of:

[0099] According to yet other embodiments, the flame-retardant filler component 350 may include certain materials. For example, the flame-retardant filler component 350 may include a metal hydrate. The flame-retardant filler component 350 may include a borate compound. The flame-retardant filler component 350 may include a platinum compound. Filler component 350 may include a transition metal oxide. According to another embodiment, the flame-retardant filler component According to yet another embodiment, the flame-retardant filler component 350 may include a metal carbonate. According to yet another embodiment, the flame retardant filler component 3 may comprise calcium silicate. According to yet another embodiment, the flame retardant filler composition may comprise aluminum silicate. The component 350 may include magnesium silicate. According to yet another embodiment, the flame-retardant filler Component 350 may include glass frit. According to yet another embodiment, the flame-retardant filler component According to yet another embodiment, the flame retardant filler component 350 may include an alkali salt. According to yet another embodiment, the flame retardant filler component 3 may comprise vermiculite. 50 is a metal hydrate, borate compound, platinum compound, transition metal oxide, metal carbonate, silica calcium silicate, aluminum silicate, magnesium silicate, glass frit, alkali salt , or vermiculite.

[0100] According to yet other embodiments, the flame-retardant filler component 350 may be made of specific materials. For example, the flame-retardant filler component 350 may comprise a metal hydrate. For example, the flame-retardant filler component 350 may comprise a borate compound. For example, the flame-retardant filler component 350 may comprise a platinum compound. The flame-retardant filler component 350 may comprise a transition metal oxide. According to yet another embodiment, the flame-retardant filler component 350 may comprise a metal carbonate. Filler component 350 may comprise calcium silicate. The reactive filler component 350 may comprise aluminum silicate. In yet another embodiment, the flame-retardant filler component 350 may comprise magnesium silicate. For example, the flame-retardant filler component 350 may comprise glass frit. For example, the flame-retardant filler component 350 may comprise an alkali salt. For example, the fire-retardant filler component 350 may comprise vermiculite. For example, the flame retardant filler component 350 may be a metal hydrate, a borate compound, a platinum compound, a transition metal Oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate, gallium silicate It may consist of any combination of lath frit, alkali salts, or vermiculite.

[0101] According to yet other embodiments, the flame-retardant filler component 350 can be a specific material. For example, the flame-retardant filler component 350 can be a metal hydrate filler. For example, the flame-retardant filler component 350 may be a borate filler. For example, the flame-retardant filler component 350 can be a platinum compound filler. For example, the flame-retardant filler component 350 can be a transition metal oxide filler. For example, the flame-retardant filler component 350 can be a metal carbonate filler. For example, the flame-retardant filler component 350 can be a calcium silicate filler. According to an embodiment, the flame-retardant filler component 350 can be an aluminum silicate filler. According to another embodiment, the flame-retardant filler component 350 may be a magnesium silicate filler. According to yet another embodiment, the flame-retardant filler component 350 is a glass frit filler. According to yet another embodiment, the flame-retardant filler component 350 is an alkali salt filler. According to yet another embodiment, the flame-retardant filler component 350 may be a vermiculite filler. According to yet another embodiment, the flame-retardant filler component 350 may be a metal hydrate, Borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, silicic acid Aluminum, magnesium silicate, glass frit, alkali salt, or vermiculite The filler may be any combination of the above.

[0102] According to yet another embodiment, the flame-retardant filler component 350 is a specific group of metal hydrate materials. For example, the flame retardant filler component 350 may be selected from aluminum trihydrate, dihydrate, Magnesium chloride, boehmite, calcium hydroxide, huntite, gypsum, hydromagnesa and any combination thereof.

[0103] According to yet another embodiment, the flame-retardant filler component 350 includes certain metal hydrate materials. For example, the flame-retardant filler component 350 may include aluminum trihydrate. According to this embodiment, the flame-retardant filler component 350 may include magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 350 may include boehmite. According to an embodiment, the flame-retardant filler component 350 may include calcium hydroxide. According to an embodiment, the flame-retardant filler component 350 may include huntite. According to an embodiment, the fire-retardant filler component 350 may include gypsum. The polymeric filler component 350 may include hydromagnesite. Flame retardant filler component 350 is aluminum trihydrate, magnesium dihydroxide, boehmite , calcium hydroxide, huntite, gypsum, or any combination of hydromagnesite may include:

[0104] According to yet another embodiment, the flame-retardant filler component 350 is made from certain metal hydrate materials. For example, the flame-retardant filler component 350 may comprise aluminum trihydrate. According to another embodiment, the flame-retardant filler component 350 may comprise magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 350 may consist of boehmite. According to another embodiment, the fire-retardant filler component 350 may comprise calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 350 may comprise huntite. According to yet another embodiment, the fire-retardant filler component 350 may comprise gypsum. According to another embodiment, the flame-retardant filler component 350 may comprise hydromagnesite. According to an embodiment, the flame retardant filler component 350 is aluminum trihydrate, magnesium dihydroxide, Calcium, boehmite, calcium hydroxide, huntite, gypsum, or hydromagnesite It can consist of any combination.

[0105] According to yet another embodiment, the flame-retardant filler component 350 is a specific metal hydrate material filler. For example, the flame retardant filler component 350 may be an aluminum trihydrate filler. According to yet another embodiment, the flame-retardant filler component 350 is a magnesium dihydroxide filler. According to yet another embodiment, the flame-retardant filler component 350 may be boehmite. According to another embodiment, the flame-retardant filler component 350 may be calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 350 may be a ham filler. According to yet another embodiment, the fire-retardant filler component 350 may be a gypsum filler. According to another embodiment, the flame-retardant filler component 350 may be hydromagnesa. According to yet another embodiment, the flame-retardant filler component 350 may be an aluminum filler. nium trihydrate, magnesium dihydroxide, boehmite, calcium hydroxide, huntite, The filler may be any combination of gypsum, or hydromagnesite.

[0106] According to yet another embodiment, the fire-retardant filler component 350 is selected from a specific group of borate materials. For example, the flame-retardant filler component 350 may be selected from zinc borate, calcium borate, Sodium borate, potassium borate, lithium borate, and any combination thereof The compound may be selected from the group consisting of:

[0107] According to yet another embodiment, the fire-retardant filler component 350 includes certain borate materials. For example, the flame-retardant filler component 350 may include zinc borate. According to another embodiment, the flame-retardant filler component 350 may include calcium borate. For example, the flame-retardant filler component 350 may include sodium borate. For example, the flame-retardant filler component 350 may include potassium borate. For example, the flame-retardant filler component 350 may include lithium borate. For example, the flame retardant filler component 350 may be zinc borate, calcium borate, sodium borate, or The composition may include any combination of potassium borate, potassium phosphate, or lithium borate.

[0108] According to yet another embodiment, the flame-retardant filler component 350 is comprised of certain borate materials. For example, the flame-retardant filler component 350 may comprise zinc borate. According to an embodiment, the flame-retardant filler component 350 may comprise calcium borate. According to an embodiment, the flame-retardant filler component 350 may comprise sodium borate. In some embodiments, the flame-retardant filler component 350 may comprise potassium borate. According to an embodiment, the flame-retardant filler component 350 may comprise lithium borate. According to an embodiment, the flame retardant filler component 350 is selected from the group consisting of zinc borate, calcium borate, sodium borate, and the like. The borate may consist of any combination of thorium, potassium borate, or lithium borate.

[0109] According to yet another embodiment, the flame-retardant filler component 350 is a specific borate material filler. For example, the flame-retardant filler component 350 can be a zinc borate filler. According to another embodiment, the fire-retardant filler component 350 may be a calcium borate filler. According to another embodiment, the flame-retardant filler component 350 may be a sodium borate filler. According to yet another embodiment, the flame-retardant filler component 350 is a potassium borate filler. According to yet another embodiment, the flame-retardant filler component 350 may be a lithium borate filler. According to yet another embodiment, the flame-retardant filler component 350 may be zinc borate, boron nitride, or the like. Any combination of calcium borate, sodium borate, potassium borate, or lithium borate It may be a composite filler.

[0110] According to yet another embodiment, the flame-retardant filler component 350 is selected from a specific group of platinum compound materials. For example, the flame retardant filler component 350 may be selected from platinum-1,3-divinyl-1, 1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof The compound may be selected from the group consisting of:

[0111] According to yet another embodiment, the flame-retardant filler component 350 includes certain platinum compound materials. For example, the flame retardant filler component 350 may be platinum-1,3-divinyl-1,1,3,3 According to yet another embodiment, the flame retardant filler composition may include tetramethyldisiloxane. The component 350 may include hexachloroplatinic acid. According to yet another embodiment, the flame-retardant filler Component 350 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxane and and hexachloroplatinic acid.

[0112] According to yet another embodiment, the flame-retardant filler component 350 is made from certain platinum compound materials. For example, the flame retardant filler component 350 can be platinum-1,3-divinyl-1,1,3, According to yet another embodiment, the flame retardant filling may consist of 3-tetramethyldisiloxane. The agent component 350 may comprise hexachloroplatinic acid. Filler component 350 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxy The composition may consist of any combination of tetrachloroplatinic acid and hexachloroplatinic acid.

[0113] According to yet another embodiment, the flame-retardant filler component 350 is a filler of certain platinum compound materials. For example, the flame retardant filler component 350 may be platinum-1,3-divinyl-1,1, According to yet another embodiment, the filler may be 3,3-tetramethyldisiloxane. The flame retardant filler component 350 may be a hexachloroplatinic acid filler. In this case, the flame retardant filler component 350 is a filler or platinum-1,3-divinyl-1,1,3, It can be any combination of 3-tetramethyldisiloxane and hexachloroplatinic acid.

[0114] According to yet another embodiment, the flame-retardant filler component 350 is a specific transition metal oxide material. For example, the flame retardant filler component 350 may be selected from the group consisting of iron oxide, cerium oxide, acid The inorganic filler may be selected from the group consisting of titanium dioxide, zinc oxide, and any combination thereof.

[0115] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 350 may include iron oxide. According to an embodiment, the flame-retardant filler component 350 may include cerium oxide. For example, the flame-retardant filler component 350 may include zinc oxide. The reactive filler component 350 may be any combination of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It may include a combination.

[0116] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 350 may comprise iron oxide. According to an embodiment, the flame-retardant filler component 350 may comprise cerium oxide. According to one embodiment, the flame-retardant filler component 350 may comprise zinc oxide. For example, the flame retardant filler component 350 may be any of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It can consist of any combination of

[0117] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 350 may be an iron oxide filler. According to yet another embodiment, the flame-retardant filler component 350 may be a cerium oxide filler. According to another embodiment, the flame-retardant filler component 350 may be a zinc oxide filler. According to this embodiment, the flame retardant filler component 350 may be selected from the group consisting of iron oxide, cerium oxide, titanium oxide, or zinc oxide filler in any combination.

[0118] According to yet another embodiment, the fire-retardant filler component 350 is selected from a specific group of metal carbonate materials. For example, the flame-retardant filler component 350 may be selected from huntite, calcium carbonate, and any combination thereof.

[0119] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 350 may include huntite. According to an embodiment, the flame-retardant filler component 350 may include calcium carbonate. According to the embodiment, the fire retardant filler component 350 is any combination of huntite or calcium carbonate. It may include a combination.

[0120] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 350 may consist of huntite. According to one embodiment, the flame-retardant filler component 350 may comprise calcium carbonate. According to this embodiment, the fire-retardant filler component 350 is either huntite or calcium carbonate. It can consist of a combination of:

[0121] According to yet another embodiment, the flame-retardant filler component 350 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 350 can be a huntite filler. According to yet another embodiment, the flame-retardant filler component 350 is a calcium carbonate filler. According to yet another embodiment, the flame-retardant filler component 350 is huntite or calcium carbonate. The filler may be any combination of sodium.

[0122] According to yet another embodiment, the flame-retardant filler component 350 is a metal carbonate mixture containing For example, the flame-retardant filler component 350 may be selected from the group consisting of hydromagnesite and han natural mixtures with tait, synthetic magnesium carbonate hydroxide pentahydrate, and any combination thereof The compound may be selected from the group consisting of:

[0123] According to yet another embodiment, the flame-retardant filler component 350 comprises a mixture of certain metal carbonates. For example, the flame-retardant filler component 350 may include a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 350 is a hydromagnesite sol. According to yet another embodiment, the flame-retardant filler component 350 may include a hydro- Natural mixture of magnesite and huntite, or synthetic magnesium hydroxide carbonate pentahydrate Any combination may be included.

[0124] According to yet another embodiment, the flame-retardant filler component 350 is made from a specific metal carbonate mixture. For example, the fire-retardant filler component 350 may be a natural mixture of hydromagnesite or According to another embodiment, the flame-retardant filler component 350 can comprise hydromagnesite. According to yet another embodiment, the flame-retardant filler component 350 may comprise a natural mixture of A natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate pentahydrate The compound may be any combination of solvates.

[0125] According to yet another embodiment, the fire-retardant filler component 350 is a specific metal carbonate mixture filler. For example, the fire-retardant filler component 350 may be a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 350 may be hydromagnesium carbonate. According to yet another embodiment, the flame retardant filler component 35 may be a natural mixture of fillers. 0 is a natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate. The filler may be any combination of ammonium pentahydrate.

[0126] According to yet another embodiment, the flame-retardant filler component 350 is an alumina silicate material or For example, the flame retardant filler component 350 may be selected from a specific group of magnesium carbonate materials. , wollastonite, mica, clay, kaolin, talc, vermiculite, and their Any combination may be selected from the group consisting of:

[0127] According to yet another embodiment, the flame-retardant filler component 350 is a specific alumina silicate material. For example, the flame-retardant filler component 350 may include a wollastonite or magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 350 may include mica. According to another embodiment, the flame-retardant filler component 350 may include kaolin. According to yet another embodiment, the flame-retardant filler component 350 may include talc. According to an embodiment, the flame-retardant filler component 350 may include vermiculite. According to the embodiment, the flame retardant filler component 350 is selected from the group consisting of wollastonite, mica, clay, kaolin, and tar. The composition may include any combination of silica, silica gel ...

[0128] According to yet another embodiment, the flame-retardant filler component 350 is a specific alumina silicate material. or magnesium silicate material. For example, the flame-retardant filler component 350 may be composed of a walnut or a magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 350 may comprise mittite. According to another embodiment, the flame-retardant filler component 350 may comprise kaolin. According to yet another embodiment, the flame-retardant filler component 350 may consist of talc. According to another embodiment, the fire-retardant filler component 350 may comprise vermiculite. According to another embodiment, the flame retardant filler component 350 may be selected from the group consisting of wollastonite, mica, clay, It may consist of any combination of kaolin, talc, or vermiculite.

[0129] According to yet another embodiment, the flame-retardant filler component 350 is a specific alumina silicate material. or a magnesium silicate material filler. For example, the flame-retardant filler component 350 may be: According to yet another embodiment, the flame retardant filler component 35 may be a wollastonite filler. According to another embodiment, the flame-retardant filler component 350 may be a mica filler. According to yet another embodiment, the flame-retardant filler component 350 may be a tarpaulin filler. According to another embodiment, the fire-retardant filler component 350 may be a vermiculite filler. According to yet another embodiment, the flame-retardant filler component 350 may be a straw-light filler. any combination of stonite, mica, clay, kaolin, talc, or vermiculite It can be a filler of any kind.

[0130] According to yet another embodiment, the flame retardant filler component 350 is selected from a specific group of alkali salt materials. For example, the flame retardant filler component 350 may be selected from sodium carbonate, potassium carbonate, and any combination thereof.

[0131] According to yet another embodiment, the flame-retardant filler component 350 includes certain alkali salt materials. For example, the flame-retardant filler component 350 may include sodium carbonate. According to an embodiment, the flame-retardant filler component 350 may include potassium carbonate. According to an embodiment, the flame retardant filler component 350 may be any combination of sodium carbonate or potassium carbonate. It may include a combination.

[0132] According to yet another embodiment, the flame retardant filler component 350 is made from certain alkali salt materials. For example, the flame-retardant filler component 350 may comprise sodium carbonate. According to one embodiment, the flame-retardant filler component 350 may comprise potassium carbonate. According to an embodiment, the flame retardant filler component 350 is either sodium carbonate or potassium carbonate. It can consist of a combination of:

[0133] According to yet another embodiment, the flame retardant filler component 350 is a filler of a particular alkali salt material. For example, the flame-retardant filler component 350 can be a sodium carbonate filler. According to yet another embodiment, the flame-retardant filler component 350 may be potassium carbonate filler. According to yet another embodiment, the flame-retardant filler component 350 is sodium carbonate or calcium carbonate. The filler may be any combination of sodium.

[0134] According to yet another embodiment, the insulating filler component 360 is selected from a specific group of materials. For example, the insulating filler component 360 may be expanded perlite, unexpanded perlite, glass, or the like. Subeeds, vermiculite, expanded vermiculite, expanded glass, zeolite, aero Gel, silica, porous silica, porous alumina, and any combination thereof It may be selected from the group:

[0135] According to yet other embodiments, the insulating filler component 360 may include certain materials. For example, the insulating filler component 360 may include expanded perlite. In other embodiments, the insulating filler component 360 may include unexpanded perlite. According to still other embodiments, the insulating filler component 360 may include glass beads. In other embodiments, insulating filler component 360 may include vermiculite. Accordingly, the insulating filler component 360 may include expanded vermiculite. According to an embodiment, the insulating filler component 360 may include expanded glass. According to another embodiment, the insulating filler component 360 may include zeolite. For example, the insulating filler component 360 may include an aerogel. The insulating filler component 360 may include silica. The filler component 360 may comprise porous silica. According to another embodiment, the insulating filler component 360 may comprise porous alumina. According to yet another embodiment, insulating filler component 3 60 is a list of expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite, -miculite, expanded glass, zeolite, aerogel, silica, porous silica, or poly The porous alumina may comprise any combination of porous alumina.

[0136] According to yet other embodiments, the insulating filler component 360 may be made of specific materials. For example, the insulating filler component 360 may consist of expanded perlite. According to yet another embodiment, the insulating filler component 360 may comprise unexpanded perlite. In some embodiments, the insulating filler component 360 may comprise glass beads. In some embodiments, the insulating filler component 360 may comprise vermiculite. According to an embodiment, the insulating filler component 360 may comprise expanded vermiculite. According to yet another embodiment, the insulating filler component 360 may be comprised of expanded glass. According to yet another embodiment, insulating filler component 360 may comprise zeolite. According to this embodiment, the insulating filler component 360 may comprise an aerogel. According to an embodiment, the insulating filler component 360 may comprise silica. According to another embodiment, the insulating filler component 360 may comprise porous silica. For example, the insulating filler component 360 may be comprised of porous alumina. For example, the insulating filler component 360 may be expanded perlite, non-expanded perlite, glass beads, Vermiculite, expanded vermiculite, expanded glass, zeolite, aerogel, silica The porous silica may be any combination of quartz, porous silica, or porous alumina.

[0137] According to yet another embodiment, the insulating filler component 360 is a filler of a specific material. For example, the insulating filler component 360 may be expanded perlite filler. According to this embodiment, the insulating filler component 360 may be a non-expanded perlite filler. According to yet another embodiment, the insulating filler component 360 may be a glass bead filler. According to yet another embodiment, the insulating filler component 360 is a vermiculite filler. According to yet another embodiment, the insulating filler component 360 may be expanded vermiculite. According to yet another embodiment, the insulating filler component 360 may be a foamed or swelled filler. According to yet another embodiment, the flame-retardant filler component 220 may be: According to yet another embodiment, the insulating filler component 360 may be a zeolite filler. According to yet another embodiment, the insulating filler component 360 can be an aerogel filler. According to yet another embodiment, the insulating filler component 360 may be: According to another embodiment, the insulating filler component 360 may be a porous silica filler. According to yet another embodiment, the insulating filler component 360 can be a porous alumina filler. , expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite durite, expanded glass, zeolite, aerogel, silica, porous silica, or porous aluminum The filler may be any combination of Lumina.

[0138] According to a particular embodiment, the second foam layer 308 comprises a silicone-based For example, the second foam layer 308 may include a matrix component 340. At least about 20 wt. %, for example, at least about 25 wt. %, based on the total weight of the rubber layer 308 , or at least about 30% by weight, or at least about 35% by weight, or at least about 40% by weight %, or at least about 45% by weight, or even at least about 50% by weight of silicone-based According to yet another embodiment, the second foam layer 3 may include a matrix component content. The second foam layer 308 is about 85% by weight or less, for example, about 80% by weight or less, based on the total weight of the second foam layer 308. % by weight or less, or about 75% by weight or less, or about 70% by weight or less, or even about 65% by weight or less The silicone matrix component content of the second foam layer 308 may be The content of the inorganic matrix component may be within a range between any of the values ​​above. It will be understood that the silicone matrix component content of the second foam layer 308 is It will be further understood that the minimum and maximum values ​​may be any value between any of the values ​​set forth above. cormorant.

[0139] According to yet another embodiment, the second foam layer 308 may contain a specific content of flame-retardant filling. For example, the second foam layer 308 may include a foam component 350. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the flame-retardant filler component may comprise at least about 15% of a flame-retardant filler component. The second foam layer 308 comprises about 35% by weight or less of the total weight of the second foam layer 308. , for example, about 34% by weight or less, or about 33% by weight or less, or about 32% by weight or less, or about 3 1% by weight or less, or about 30% by weight or less, or about 28% by weight or less, or about 25% by weight or less; Alternatively, the flame-retardant filler component may contain no more than about 23% by weight, or no more than about 20% by weight. The flame-retardant filler component content of the second foam layer 308 is in a range between any of the above values. It will be understood that the flame-retardant filler component content of the second foam layer 308 may be within the range. It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0140] According to yet another embodiment, the second foam layer 308 may have a specific content of insulating filler. For example, the second foam layer 308 may include a foam component 350. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the insulating filler component may contain at least about 15% insulating filler component. The second foam layer 308 comprises about 25% by weight or less of the total weight of the second foam layer 308. , for example, about 24% by weight or less, or about 23% by weight or less, or about 22% by weight or less, or about 2 1% by weight or less, or about 20% by weight or less, or about 19% by weight or less, or about 18% by weight or less; Alternatively, the insulating filler component may contain no more than about 17% by weight, or no more than about 16% by weight. The insulating filler content of the second foam layer 308 may range between any of the values ​​above. It will be understood that the insulating filler content of the second foam layer 308 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0141] According to certain embodiments, the second foam layer 308 is made in accordance with ASTM D4986. In particular, the foam layer may have a specific flammability rating as measured by ASTM D4986. The flame retardant may have an HBF flammability rating measured in accordance with the HBF flammability rating.

[0142] According to certain embodiments, the second foam layer 308 is made in accordance with ASTM D3801. In particular, the foam layer may have a specific flammability rating as measured by ASTM D3801. It may have a V-0 flammability rating as measured in accordance with

[0143] According to yet another embodiment, the second foam layer 308 is hot rolled at a temperature of 650°C. The present invention relates to a method for producing a fluorine-containing polymer having a specific autoignition time when exposed to a plate test. For morphology purposes, hot plate testing prepare 1 inch x 1 inch specimens of the material. This is done by placing the test piece on a hot plate. The cold surface temperature was measured by fixing it to a steel weight (1 inch diameter, 2 inches high) placed on top of the The temperature curve is recorded and the point of autoignition, if any, is noted. For example, the second foam layer 308 may be heated for at least about 1 minute, such as at least about 1.5 minutes, or is at least about 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least at least about 3.5 minutes, or at least about 4.0 minutes, or at least about 4.5 minutes, or even less The second foam layer 308 may have an autoignition time of at least about 5.0 minutes. It will be understood that the second formula may range between any of the above values. The self-ignition time of the rubber layer 308 can be any value between any of the above values. will be further understood.

[0144] According to yet another embodiment, the second foam layer 308 is made up of 6 layers of foam 3 mm thick. It has a specific cold side temperature measured at 5 minutes when exposed to a 50°C hot plate test. For purposes of the embodiments described herein, the hot plate test is performed on one This was performed by preparing a 1 inch x 1 inch test specimen and placing it on a hot plate. The thermocouple is then attached to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to a specific embodiment, the second foam layer 30 8 is about 300°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less or about 200°C or less, or about 175°C or less, or even about 150°C or less According to yet another embodiment, the second foam layer 308 may have a viscosity of at least about 25 The cold side temperature of the second foam layer 308 may be within the range of 0.25°C. It will be understood that the cold side of the second foam layer 308 can be anywhere in between. It will be further understood that the temperature can be any value between any of the above values.

[0145] According to still other embodiments, the second foam layer 308 may have a particular thickness. For example, the second foam layer 308 may be at least about 0.5 mm, e.g., at least about 1 0.0 mm, or at least about 1.5 mm, or at least about 2.0 mm, or at least About 2.5 mm, or at least about 3.0 mm, or at least about 3.5 mm, or less Both are about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm. According to yet another embodiment, the second foam layer 308 may have a thickness of about 10 mm or more. or less, for example, about 9.5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less The thickness of the second foam layer 308 may be about 6.0 mm or less. It will be understood that the range may be between any of the minimum and maximum values ​​set forth above. The thickness of the second foam layer 308 may be any value between any of the minimum and maximum values ​​listed above. It will be further appreciated that the value may be:

[0146] According to yet another embodiment, the second foam layer 308 has a specific 25% strain compression. For purposes of the embodiments described herein, a 25% strain compression grade is: Defined as the compressive strength of a specimen measured at 25% strain, The compressive force (FTC) is determined by measuring the specimen's compressive deflection. Compressive Force Deflection (CFD) is defined as the peak force (or stress) that compresses a material to a certain strain. is the plateau maintained by the sample when held at the desired strain (i.e., 25%). The force (or stress) is defined as the relaxation force (or stress) of the specimen. Locate and record both the FTC and CFD values ​​after retraction speed and 10 grams of trigger force. Measurements are taken using a texture analyzer.

[0147] According to certain embodiments, the second foam layer 308 has a pressure of about 500 kPa or less, e.g. , about 475 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 40 0 kPa or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or is about 225 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 15 25% strain compression at 0 kPa or less, or approximately 125 kPa or less, or approximately 100 kPa or less According to yet another embodiment, the second foam layer 308 may have a viscosity of at least about 5 kPa, for example, at least about 10 kPa, or at least about 15 kPa, or at least The second may also have a 25% strain compression rating of about 20 kPa, or at least about 25 kPa. The 25% strain compression rating of the foam layer 308 is either of the minimum and maximum values ​​set forth above. It will be appreciated that the strain of the second foam layer 308 may be within a range between 50% strain and 50% strain. It is understood that the compression rating may be any value between any of the minimum and maximum values ​​listed above. Let's understand more.

[0148] According to still other embodiments, the second foam layer 308 may have a particular density. For purposes of the embodiments described herein, the density of the second foam layer 308 is determined according to ASTM According to certain embodiments, the second foam layer 308 is approximately 1200 kg / m 3Below, for example, about 1175 kg / m 3 or less, or about 1150k g / m 3 or less than 1125 kg / m 3 or less than 1100 kg / m 3 Below, or 105 0kg / m 3 or less than 1000 kg / m 3 or less, or 950 kg / m 3 or less, or 90 0kg / m 3 or less, or 850 kg / m 3 or less than 800 kg / m 3 or less, or 750 kg / m 3 or less than 700 kg / m 3 or less, or even 650 kg / m 3 The density of According to yet another embodiment, the second foam layer 308 may have a viscosity of at least about 10 0kg / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m 3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or less At least about 200 kg / m 3 , or at least about 220 kg / m 3 , or even at least Approximately 240 kg / m 3 The density of the second foam layer 308 may be at least the above minimum. It will be understood that the second form may be within a range between any of the values ​​and the maximum value. The density of the foam layer 308 is any value between any of the minimum and maximum values ​​listed above. It will be further understood that

[0149] According to yet another embodiment, the second foam layer 308 may be formed in accordance with ASTM C518. For example, the second foam layer 308 may have a particular thermal conductivity as measured by At least about 0.01 W / mK, for example, at least about 0.02 W / mK, or at least about 0 0.03 W / mK, or at least about 0.04 W / mK, or even at least about 0.05 According to yet another embodiment, the second foam layer 308 may have a thermal conductivity of , about 0.15 W / mK or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less or less, or about 0.12 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less, about 0.09 W / mK or less, or about 0.08 W / mK, or even about 0.07 W The thermal conductivity of the second foam layer 308 may be less than or equal to the minimum value. It will be understood that the second formula may be in the range between any of the above values. The thermal conductivity of the rubber layer 308 may be any value between any of the minimum and maximum values ​​listed above. It will be further understood that this is possible.

[0150] According to certain embodiments, the multilayer composites described herein may be prepared using any of the methods described above for multilayer composites. According to certain embodiments, the multilayer composite may be formed according to any acceptable forming process. may be formed using a lamination process, where the porous foam and barrier layer , for example, silicone adhesives, rubber adhesives, acrylic adhesives, phenolic adhesives, polyurethane adhesives, laminated using a transfer adhesive such as a styrene-based adhesive, or any combination thereof According to yet another embodiment, the multi-layer composite utilizes a porous foam and an overlying barrier layer. It may be formed using a lamination process, where the coating on the barrier layer is a silicone adhesive. adhesive, rubber adhesive, acrylic adhesive, phenolic adhesive, polyurethane adhesive, or According to yet another embodiment, the multilayer composite is , may be formed using a direct cast forming process, where the foam is a barrier It is cast directly onto the film or between barrier films.

[0151] Turning now to additional embodiments described herein, such embodiments include: Generally, the present invention relates to a thermal barrier composite that may include a first barrier layer and a first foam layer. According to this embodiment, the first foam layer comprises a silicone-based matrix component, a flame-retardant filler, According to yet another embodiment, the thermal barrier composite may include a filler component, a heat insulating component, and a thermal barrier filler component. may exhibit a combination of improved performance in flame resistance and compression.

[0152] For illustrative purposes, FIG. 4 shows a thermal barrier composite 400 according to an embodiment described herein. As shown in FIG. 4, the thermal barrier composite 400 includes a first barrier layer 402 and a first and a foam layer 404. The first foam layer 404 may comprise a silicone-based matrix. component 410 , a flame retardant filler component 420 , and a thermal insulating filler component 430 .

[0153] According to certain embodiments, the silicone-based matrix component of the first foam layer 404 410 may comprise a platinum catalyzed addition cure silicone foam. The silicone-based matrix component 410 may include a peroxide-cured silicone foam. According to yet another embodiment, the silicone-based matrix component 410 is a tin-catalyzed silicone. According to yet another embodiment, the silicone-based matrix component may comprise corn foam. 410 is a platinum-catalyzed addition-cure silicone foam, a peroxide-cure silicone foam, and and tin catalyzed silicone foams.

[0154] According to certain embodiments, the silicone-based matrix component 410 is a platinum-catalyzed curing agent. According to yet another embodiment, the silicone matrix may be a fluorinated silicone foam. The foam component 410 may comprise a peroxide-cured silicone foam. According to the patent, the silicone matrix component 410 is comprised of a tin-catalyzed silicone foam. According to yet another embodiment, the silicone-based matrix component 410 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam It may consist of any combination of information.

[0155] According to certain embodiments, the silicone-based matrix component 410 is a platinum-catalyzed curing agent. According to yet another embodiment, the layer may be a silicone-based matrix. The foam component 410 can be a peroxide-cured silicone foam layer. According to the patent, the silicone matrix component 410 is a tin-catalyzed silicone foam layer. According to yet another embodiment, the silicone-based matrix component 410 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam The layer may be any combination of layers of foam.

[0156] According to yet another embodiment, the flame-retardant filler component 420 is selected from a specific group of materials. For example, the flame-retardant filler component 420 may be a metal hydrate, a borate compound, a platinum compound, or the like. Substances, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate Nesium, glass frit, alkali salts, vermiculite, and any combination thereof The compound may be selected from the group consisting of:

[0157] According to yet other embodiments, the flame-retardant filler component 420 may include certain materials. For example, the flame-retardant filler component 420 may include a metal hydrate. The fire-retardant filler component 420 may include a borate compound. The flame-retardant filler component 420 may include a platinum compound. The filler component 420 may include a transition metal oxide. According to another embodiment, the flame-retardant filler component According to yet another embodiment, the flame-retardant filler component 420 may include a metal carbonate. According to yet another embodiment, the flame retardant filler component 4 may comprise calcium silicate. According to yet another embodiment, the flame retardant filler composition may comprise aluminum silicate. The component 420 may include magnesium silicate. According to yet another embodiment, the flame-retardant filler Component 420 may include glass frit. According to yet another embodiment, the flame-retardant filler component According to yet another embodiment, the flame retardant filler component 420 may include an alkali salt. According to yet another embodiment, the flame-retardant filler component 4 20 is a metal hydrate, borate compound, platinum compound, transition metal oxide, metal carbonate, silica calcium silicate, aluminum silicate, magnesium silicate, glass frit, alkali salt , or vermiculite.

[0158] According to yet other embodiments, the flame-retardant filler component 420 may be made of specific materials. For example, the flame-retardant filler component 420 may comprise a metal hydrate. For example, the flame-retardant filler component 420 may comprise a borate compound. For example, the flame-retardant filler component 420 may comprise a platinum compound. The flame-retardant filler component 420 may comprise a transition metal oxide. According to yet another embodiment, the flame-retardant filler component 420 may comprise a metal carbonate. The filler component 420 may comprise calcium silicate. The reactive filler component 420 may comprise aluminum silicate. In yet another embodiment, the flame-retardant filler component 420 may comprise magnesium silicate. For example, the flame-retardant filler component 420 may comprise glass frit. For example, the flame-retardant filler component 420 may comprise an alkali salt. For example, the fire-retardant filler component 420 may comprise vermiculite. For example, the flame retardant filler component 420 may be a metal hydrate, a borate compound, a platinum compound, a transition metal Oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate, gallium silicate It may consist of any combination of lath frit, alkali salts, or vermiculite.

[0159] According to yet other embodiments, the flame-retardant filler component 420 can be a specific material. For example, the flame-retardant filler component 420 can be a metal hydrate filler. For example, the flame-retardant filler component 420 may be a borate filler. For example, the flame-retardant filler component 420 can be a platinum compound filler. For example, the flame-retardant filler component 420 can be a transition metal oxide filler. For example, the flame-retardant filler component 420 can be a metal carbonate filler. For example, the flame-retardant filler component 420 can be a calcium silicate filler. According to an embodiment, the flame-retardant filler component 420 can be an aluminum silicate filler. According to another embodiment, the flame-retardant filler component 420 may be a magnesium silicate filler. According to yet another embodiment, the flame-retardant filler component 420 is a glass frit filler. According to yet another embodiment, the flame-retardant filler component 420 is an alkali salt filler. According to yet another embodiment, the fire-retardant filler component 420 may be a vermiculite filler. According to yet another embodiment, the flame-retardant filler component 420 may be a metal hydrate, Borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, silicic acid Aluminum, magnesium silicate, glass frit, alkali salt, or vermiculite The filler may be any combination of the above.

[0160] According to yet another embodiment, the flame-retardant filler component 420 is a specific group of metal hydrate materials. For example, the flame-retardant filler component 420 may be selected from aluminum trihydrate, dihydrate, Magnesium chloride, boehmite, calcium hydroxide, huntite, gypsum, hydromagnesa and any combination thereof.

[0161] According to yet another embodiment, the flame-retardant filler component 420 includes certain metal hydrate materials. For example, the flame-retardant filler component 420 may include aluminum trihydrate. According to this embodiment, the flame-retardant filler component 420 may include magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 420 may include boehmite. According to an embodiment, the fire-retardant filler component 420 may include calcium hydroxide. According to an embodiment, the flame-retardant filler component 420 may include huntite. According to an embodiment, the fire-retardant filler component 420 may include gypsum. The polymeric filler component 420 may include hydromagnesite. Flame retardant filler component 420 is aluminum trihydrate, magnesium dihydroxide, boehmite , calcium hydroxide, huntite, gypsum, or any combination of hydromagnesite may include:

[0162] According to yet another embodiment, the flame-retardant filler component 420 is made from certain metal hydrate materials. For example, the flame-retardant filler component 420 may comprise aluminum trihydrate. According to another embodiment, the flame-retardant filler component 420 may comprise magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 420 may consist of boehmite. According to another embodiment, the fire-retardant filler component 420 may consist of calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 420 may comprise huntite. According to yet another embodiment, the fire-retardant filler component 420 may comprise gypsum. According to another embodiment, the flame-retardant filler component 420 may comprise hydromagnesite. According to an embodiment, the flame retardant filler component 420 is aluminum trihydrate, magnesium dihydroxide, Calcium, boehmite, calcium hydroxide, huntite, gypsum, or hydromagnesite It can consist of any combination.

[0163] According to yet another embodiment, the flame-retardant filler component 420 is a specific metal hydrate material filler. For example, the flame-retardant filler component 420 may be an aluminum trihydrate filler. According to yet another embodiment, the flame-retardant filler component 420 is a magnesium dihydroxide filler. According to yet another embodiment, the flame-retardant filler component 420 may be boehmite. According to another embodiment, the flame-retardant filler component 420 may be calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 420 may be a tantalum filler. According to yet another embodiment, the fire-retardant filler component 420 may be a gypsum filler. According to another embodiment, the flame-retardant filler component 420 may be hydromagnesa. According to yet another embodiment, the flame-retardant filler component 420 may be an aluminum filler. nium trihydrate, magnesium dihydroxide, boehmite, calcium hydroxide, huntite, The filler may be any combination of gypsum, or hydromagnesite.

[0164] According to yet another embodiment, the fire-retardant filler component 420 is selected from a specific group of borate materials. For example, the flame-retardant filler component 420 may be selected from zinc borate, calcium borate, Sodium borate, potassium borate, lithium borate, and any combination thereof The compound may be selected from the group consisting of:

[0165] According to yet another embodiment, the fire-retardant filler component 420 includes certain borate materials. For example, the flame-retardant filler component 420 may include zinc borate. According to another embodiment, the flame-retardant filler component 420 may include calcium borate. For example, the flame-retardant filler component 420 may include sodium borate. For example, the fire-retardant filler component 420 may include potassium borate. For example, the flame-retardant filler component 420 may include lithium borate. For example, the flame retardant filler component 420 may be zinc borate, calcium borate, sodium borate, or The composition may include any combination of potassium borate, potassium phosphate, or lithium borate.

[0166] According to yet another embodiment, the fire-retardant filler component 420 is comprised of certain borate materials. For example, the flame-retardant filler component 420 may comprise zinc borate. According to an embodiment, the fire-retardant filler component 420 may comprise calcium borate. According to an embodiment, the flame-retardant filler component 420 may comprise sodium borate. According to one embodiment, the flame-retardant filler component 420 may comprise potassium borate. According to an embodiment, the flame-retardant filler component 420 may comprise lithium borate. According to an embodiment, the fire-retardant filler component 420 is selected from the group consisting of zinc borate, calcium borate, sodium borate, and the like. The borate may consist of any combination of thorium, potassium borate, or lithium borate.

[0167] According to yet another embodiment, the fire-retardant filler component 420 is a specific borate material filler. For example, the flame-retardant filler component 420 can be a zinc borate filler. According to another embodiment, the fire-retardant filler component 420 may be a calcium borate filler. According to another embodiment, the flame-retardant filler component 420 may be a sodium borate filler. According to yet another embodiment, the fire-retardant filler component 420 is a potassium borate filler. According to yet another embodiment, the flame-retardant filler component 420 may be a lithium borate filler. According to yet another embodiment, the flame-retardant filler component 420 may be zinc borate, boron nitride, or the like. Any combination of calcium borate, sodium borate, potassium borate, or lithium borate It may be a composite filler.

[0168] According to yet another embodiment, the flame-retardant filler component 420 is selected from a specific group of platinum compound materials. For example, the flame retardant filler component 420 may be selected from platinum-1,3-divinyl-1, 1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof The compound may be selected from the group consisting of:

[0169] According to yet another embodiment, the flame-retardant filler component 420 includes certain platinum compound materials. For example, the flame retardant filler component 420 may be platinum-1,3-divinyl-1,1,3,3 According to yet another embodiment, the flame retardant filler composition may include tetramethyldisiloxane. The component 420 may include hexachloroplatinic acid. According to yet another embodiment, the flame-retardant filler Ingredient 420 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxane and and hexachloroplatinic acid.

[0170] According to yet another embodiment, the flame-retardant filler component 420 is made from certain platinum compound materials. For example, the flame retardant filler component 420 can be platinum-1,3-divinyl-1,1,3, According to yet another embodiment, the flame retardant filling may consist of 3-tetramethyldisiloxane. The agent component 420 may comprise hexachloroplatinic acid. Filler component 420 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxy The composition may consist of any combination of tetrachloroplatinic acid and hexachloroplatinic acid.

[0171] According to yet another embodiment, the flame-retardant filler component 420 is a filler of certain platinum compound materials. For example, the flame retardant filler component 420 can be platinum-1,3-divinyl-1,1, According to yet another embodiment, the filler may be 3,3-tetramethyldisiloxane. The flame retardant filler component 420 may be a hexachloroplatinic acid filler. For example, the flame retardant filler component 420 may be a filler or a platinum-1,3-divinyl-1,1,3, It can be any combination of 3-tetramethyldisiloxane and hexachloroplatinic acid.

[0172] According to yet another embodiment, the flame-retardant filler component 420 is a specific transition metal oxide material. For example, the flame retardant filler component 420 may be selected from the group consisting of iron oxide, cerium oxide, acid The inorganic filler may be selected from the group consisting of titanium dioxide, zinc oxide, and any combination thereof.

[0173] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 420 may include iron oxide. According to an embodiment, the flame-retardant filler component 420 may include cerium oxide. For example, the flame-retardant filler component 420 may include zinc oxide. The reactive filler component 420 may be any combination of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It may include a combination.

[0174] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 420 may comprise iron oxide. According to an embodiment, the flame-retardant filler component 420 may comprise cerium oxide. According to one embodiment, the flame-retardant filler component 420 may comprise zinc oxide. For example, the flame-retardant filler component 420 may be any of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It can consist of any combination of

[0175] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 420 can be an iron oxide filler. According to yet another embodiment, the flame-retardant filler component 420 may be a cerium oxide filler. According to another embodiment, the flame-retardant filler component 420 may be a zinc oxide filler. According to this embodiment, the flame retardant filler component 420 may be selected from the group consisting of iron oxide, cerium oxide, titanium oxide, or zinc oxide filler in any combination.

[0176] According to yet another embodiment, the fire-retardant filler component 420 is selected from a specific group of metal carbonate materials. For example, the flame-retardant filler component 420 may be selected from huntite, calcium carbonate, and any combination thereof.

[0177] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 420 may include huntite. According to an embodiment, the fire-retardant filler component 420 may include calcium carbonate. According to the embodiment, the fire-retardant filler component 420 is any combination of huntite or calcium carbonate. It may include a combination.

[0178] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 420 may consist of huntite. According to this embodiment, the flame-retardant filler component 420 may comprise calcium carbonate. According to this embodiment, the fire-retardant filler component 420 is either huntite or calcium carbonate. It can consist of a combination of:

[0179] According to yet another embodiment, the flame-retardant filler component 420 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 420 can be a huntite filler. According to yet another embodiment, the flame-retardant filler component 420 is a calcium carbonate filler. According to yet another embodiment, the flame-retardant filler component 420 is huntite or calcium carbonate. The filler may be any combination of sodium.

[0180] According to yet another embodiment, the fire-retardant filler component 420 is a metal carbonate mixture containing For example, the flame-retardant filler component 420 may be selected from the group consisting of hydromagnesite and han natural mixtures with tait, synthetic magnesium carbonate hydroxide pentahydrate, and any combination thereof The compound may be selected from the group consisting of:

[0181] According to yet another embodiment, the fire-retardant filler component 420 comprises a mixture of certain metal carbonates. For example, the flame-retardant filler component 420 may include a natural mixture of hydromagnesite. According to another embodiment, the fire-retardant filler component 420 is a hydromagnesite sol. According to yet another embodiment, the flame-retardant filler component 420 may include a hydro- Natural mixture of magnesite and huntite, or synthetic magnesium hydroxide carbonate pentahydrate Any combination may be included.

[0182] According to yet another embodiment, the fire-retardant filler component 420 is made from a specific metal carbonate mixture. For example, the fire-retardant filler component 420 may be a natural mixture of hydromagnesite or According to another embodiment, the flame-retardant filler component 420 can comprise hydromagnesite. According to yet another embodiment, the flame-retardant filler component 420 may comprise a natural mixture of A natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate pentahydrate The compound may be any combination of solvates.

[0183] According to yet another embodiment, the fire-retardant filler component 420 is a specific metal carbonate mixture filler. For example, the fire-retardant filler component 420 may be a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 420 may be a hydromatrix filler. According to yet another embodiment, the fire-retardant filler may be a natural mixture of gnesite. Ingredient 420 is a natural mixture of hydromagnesite and huntite, or a synthetic hydroxycarbonate. The filler may be any combination of magnesium pentahydrate.

[0184] According to yet another embodiment, the flame-retardant filler component 420 is an alumina silicate material or For example, the flame retardant filler component 420 may be selected from a specific group of magnesium carbonate materials. , wollastonite, mica, clay, kaolin, talc, vermiculite, and their Any combination may be selected from the group consisting of:

[0185] According to yet another embodiment, the flame-retardant filler component 420 is a specific alumina silicate material. For example, the flame-retardant filler component 420 may include a wollastonite or magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 420 may include mica. According to yet another embodiment, the flame-retardant filler component 420 may include clay. According to this embodiment, the flame-retardant filler component 420 may include kaolin. According to one embodiment, the flame-retardant filler component 420 may include talc. The fire-retardant filler component 420 may include vermiculite. The flame retardant filler component 420 may be selected from the group consisting of wollastonite, mica, clay, kaolin, talc, and basil. The composition may include any combination of cellulose, cellulose acetate, cellulose nitrate, cellulose acetate, cellulose acetate nitrate ...

[0186] According to yet another embodiment, the flame-retardant filler component 420 is a specific alumina silicate material. or magnesium silicate material. For example, the flame-retardant filler component 420 may be composed of a wallaceite or a magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 420 may consist of myrtle. According to yet another embodiment, the flame-retardant filler component 420 may comprise clay. According to another embodiment, the flame-retardant filler component 420 may comprise kaolin. According to yet another embodiment, the flame-retardant filler component 420 may comprise talc. According to an embodiment, the flame-retardant filler component 420 may comprise vermiculite. According to the embodiment, the flame retardant filler component 420 may be selected from the group consisting of wollastonite, mica, clay, kaolin, The granular material may be any combination of talc, or vermiculite.

[0187] According to yet another embodiment, the flame-retardant filler component 420 is a specific alumina silicate material. or a magnesium silicate material filler. For example, the flame-retardant filler component 420 may be: According to yet another embodiment, the flame-retardant filler component 42 may be a wollastonite filler. According to yet another embodiment, the flame-retardant filler component 420 is According to another embodiment, the fire-retardant filler component 420 may be kaolin, According to yet another embodiment, the flame-retardant filler component 420 may be a talc filler. According to another embodiment, the fire-retardant filler component 420 may be vermiculite. According to yet another embodiment, the flame-retardant filler component 420 may be a wollastonite. Filled with any combination of ash, mica, clay, kaolin, talc, or vermiculite It may be a filler.

[0188] According to yet another embodiment, the fire-retardant filler component 420 is selected from a specific group of alkali salt materials. For example, the flame retardant filler component 420 may be selected from sodium carbonate, potassium carbonate, and any combination thereof.

[0189] According to yet another embodiment, the flame-retardant filler component 420 includes certain alkali salt materials. For example, the flame-retardant filler component 420 may include sodium carbonate. According to an embodiment, the flame-retardant filler component 420 may include potassium carbonate. According to an embodiment, the flame retardant filler component 420 may be any combination of sodium carbonate or potassium carbonate. It may include a combination.

[0190] According to yet another embodiment, the flame retardant filler component 420 is made from certain alkali salt materials. For example, the flame-retardant filler component 420 may comprise sodium carbonate. According to this embodiment, the flame-retardant filler component 420 may comprise potassium carbonate. According to an embodiment, the flame retardant filler component 420 is either sodium carbonate or potassium carbonate. It can consist of a combination of:

[0191] According to yet another embodiment, the fire-retardant filler component 420 is a filler of a specific alkali salt material. For example, the flame-retardant filler component 420 can be a sodium carbonate filler. According to yet another embodiment, the flame-retardant filler component 420 may be potassium carbonate filler. According to yet another embodiment, the flame-retardant filler component 420 is sodium carbonate or calcium carbonate. The filler may be any combination of sodium.

[0192] According to yet another embodiment, the insulating filler component 430 is selected from a specific group of materials. For example, the insulating filler component 430 may be expanded perlite, unexpanded perlite, glass, or the like. Subeeds, vermiculite, expanded vermiculite, expanded glass, zeolite, aero Gel, silica, porous silica, porous alumina, and any combination thereof It may be selected from the group:

[0193] According to yet other embodiments, the insulating filler component 430 may include certain materials. For example, the insulating filler component 430 may include expanded perlite. Alternatively, insulating filler component 430 may include unexpanded perlite. According to still other embodiments, the insulating filler component 430 may include glass beads. In other embodiments, insulating filler component 430 may include vermiculite. Accordingly, the insulating filler component 430 may include expanded vermiculite. According to an embodiment, the insulating filler component 430 may include expanded glass. According to another embodiment, the insulating filler component 430 may include zeolite. For example, the insulating filler component 430 may include an aerogel. The insulating filler component 430 may include silica. The filler component 430 may comprise porous silica. According to another embodiment, the insulating filler component According to yet another embodiment, the insulating filler component 430 may comprise porous alumina. 30 is a list of expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite -miculite, expanded glass, zeolite, aerogel, silica, porous silica, or poly The porous alumina may comprise any combination of porous alumina.

[0194] According to yet other embodiments, the insulating filler component 430 may be made of specific materials. For example, the insulating filler component 430 may consist of expanded perlite. According to yet another embodiment, the insulating filler component 430 may comprise unexpanded perlite. In some embodiments, the insulating filler component 430 may comprise glass beads. In some embodiments, the insulating filler component 430 may comprise vermiculite. According to an embodiment, the insulating filler component 430 may comprise expanded vermiculite. According to yet another embodiment, the insulating filler component 430 may be comprised of expanded glass. According to yet another embodiment, insulating filler component 430 may comprise zeolite. According to this embodiment, the insulating filler component 430 may comprise an aerogel. According to an embodiment, the insulating filler component 430 may comprise silica. According to an embodiment, the insulating filler component 430 may comprise porous silica. For example, the insulating filler component 430 may be comprised of porous alumina. For example, the insulating filler component 430 may be expanded perlite, non-expanded perlite, glass beads, Vermiculite, expanded vermiculite, expanded glass, zeolite, aerogel, silica The porous silica may be any combination of quartz, porous silica, or porous alumina.

[0195] According to yet another embodiment, the insulating filler component 430 is a filler of a specific material. For example, the insulating filler component 430 can be expanded perlite filler. According to this embodiment, the insulating filler component 430 may be a non-expanded perlite filler. According to yet another embodiment, the insulating filler component 430 may be a glass bead filler. According to yet another embodiment, the insulating filler component 430 is a vermiculite filler. According to yet another embodiment, the insulating filler component 430 can be expanded vermiculite. According to yet another embodiment, the insulating filler component 430 may be a foamed or swelled filler. According to yet another embodiment, the flame-retardant filler component 220 may be: According to yet another embodiment, the insulating filler component 430 may be a zeolite filler. According to yet another embodiment, the insulating filler component 430 can be an aerogel filler. According to yet another embodiment, the insulating filler component 430 may be: According to another embodiment, the insulating filler component 430 may be a porous silica filler. According to yet another embodiment, the insulating filler component 430 can be a porous alumina filler. , expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite durite, expanded glass, zeolite, aerogel, silica, porous silica, or porous aluminum The filler may be any combination of Lumina.

[0196] According to a particular embodiment, the first foam layer 404 comprises a silicone-based For example, the first foam layer 404 may include a matrix component 410. At least about 20% by weight, for example, at least about 25% by weight, based on the total weight of the rubber layer 404 , or at least about 30% by weight, or at least about 35% by weight, or at least about 40% by weight %, or at least about 45% by weight, or even at least about 50% by weight of silicone-based According to yet another embodiment, the first foam layer 4 The first foam layer 404 is about 85% by weight or less, for example, about 80% by weight or less, based on the total weight of the first foam layer 404. % by weight or less, or about 75% by weight or less, or about 70% by weight or less, or even about 65% by weight or less The silicone matrix component content of the first foam layer 404 may be The content of the inorganic matrix component may be within a range between any of the values ​​above. It will be understood that the silicone matrix component content of the first foam layer 404 is It will be further understood that the minimum and maximum values ​​may be any value between any of the values ​​set forth above. cormorant.

[0197] According to yet another embodiment, the first foam layer 404 may contain a specific content of flame retardant filling. For example, the first foam layer 404 may include a foam component 420. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the flame-retardant filler component may comprise at least about 15% of a flame-retardant filler component. The first foam layer 404 comprises about 35% by weight or less of the total weight of the first foam layer 404. , for example, about 34% by weight or less, or about 33% by weight or less, or about 32% by weight or less, or about 3 1% by weight or less, or about 30% by weight or less, or about 28% by weight or less, or about 25% by weight or less; Alternatively, the flame-retardant filler component may contain no more than about 23% by weight, or no more than about 20% by weight. The flame-retardant filler component content of the foam layer 404 of one of the above ranges. It will be understood that the flame-retardant filler component content of the first foam layer 404 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0198] According to yet another embodiment, the first foam layer 404 may contain a specific content of insulating filler. For example, the first foam layer 404 may include a foam component 420. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the insulating filler component may contain at least about 15% insulating filler component. The first foam layer 404 comprises about 25% by weight or less of the total weight of the first foam layer 404. , for example, about 24% by weight or less, or about 23% by weight or less, or about 22% by weight or less, or about 2 1% by weight or less, or about 20% by weight or less, or about 19% by weight or less, or about 18% by weight or less; Alternatively, the insulating filler component may contain no more than about 17% by weight, or no more than about 16% by weight. The insulating filler content of the foam layer 404 may range between any of the values ​​above. It will be understood that the insulating filler content of the first foam layer 404 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0199] According to certain embodiments, layer 404 has a specific thickness measured according to ASTM D4986. In particular, the foam layer may have a flammability rating measured in accordance with ASTM D4986. It may have an HBF flammability rating.

[0200] According to certain embodiments, the first foam layer 404 is made in accordance with ASTM D3801. In particular, the foam layer may have a specific flammability rating as measured by ASTM D3801. It may have a V-0 flammability rating as measured in accordance with

[0201] According to certain embodiments, the thermal barrier composite 400 is formed according to ASTM D4986 In particular, the foam layer may have a specific flammability rating measured according to ASTM D4986. It may therefore have an HBF flammability rating measured.

[0202] According to certain embodiments, the thermal barrier composite 400 is formed according to ASTM D3801 In particular, the foam layer may have a specific flammability rating measured according to ASTM D3801. It may therefore have a measured V-0 flammability rating.

[0203] According to yet another embodiment, the first foam layer 404 is hot rolled at a temperature of 650°C. The present invention relates to a method for producing a fluorine-containing polymer having a specific autoignition time when exposed to a plate test. For morphology purposes, hot plate testing prepare 1 inch x 1 inch specimens of the material. This is done by placing the test piece on a hot plate. The cold surface temperature was measured by fixing it to a steel weight (1 inch diameter, 2 inches high) placed on top of the The temperature curve is recorded and the point of autoignition, if any, is noted. For example, the first foam layer 404 may be heated for at least about 1 minute, such as at least about 1.5 minutes, or is at least about 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least at least about 3.5 minutes, or at least about 4.0 minutes, or at least about 4.5 minutes, or even less The first foam layer 404 may have an autoignition time of at least about 5.0 minutes. It will be understood that the value of the first formula may range between any of the above values. The self-ignition time of the rubber layer 404 can be any value between any of the above values. will be further understood.

[0204] According to yet another embodiment, the thermal barrier composite 400 is hot-pressed at a temperature of 650°C. The material may have a specific autoignition time when subjected to a rate test. For the purpose of the hot plate test, a 1 inch x 1 inch specimen of the material is prepared. This is done by placing the specimen on a hot plate. Then, a thermocouple is inserted into the The cold surface temperature was measured by fixing it to a steel weight (1 inch diameter, 2 inches high) placed on top. The temperature curve is recorded and the point of autoignition, if any, is noted. The thermal barrier composite 400 may be heated for at least about 1 minute, for example, at least about 1.5 minutes, or less. at least about 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least about 3.5 minutes, or at least about 4.0 minutes, or at least about 4.5 minutes, or even at least The thermal barrier composite 400 may have an autoignition time of about 5.0 minutes. It will be appreciated that the thermal barrier composite 40 may be within a range between any of the values ​​of It is further understood that the autoignition time of 0 can be any value between any of the above values. Let's solve it.

[0205] According to yet another embodiment, the first foam layer 404 is made up of 6 layers of foam 3 mm thick. It has a specific cold side temperature measured at 5 minutes when exposed to a 50°C hot plate test. For purposes of the embodiments described herein, the hot plate test is performed on one This was performed by preparing a 1 inch x 1 inch test specimen and placing it on a hot plate. The thermocouple is then attached to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to a specific embodiment, the first foam layer 40 4 is about 300°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less or about 200°C or less, or about 175°C or less, or even about 150°C or less According to yet another embodiment, the first foam layer 404 may have a viscosity of at least about 25 ° C. The cold side temperature of the first foam layer 404 may be It will be understood that the cold side of the first foam layer 404 can be anywhere in between. It will be further understood that the temperature can be any value between any of the above values.

[0206] According to yet another embodiment, the thermal barrier composite 400 is made of a 3 mm thick foam with a thickness of 65 It has a specific cold side temperature measured at 5 minutes when exposed to a 0°C hot plate test. For purposes of the embodiments described herein, the hot plate test is performed on one inch of material. This is done by preparing a 1 inch x 1 inch test specimen and placing it on a hot plate. The thermocouple is then fixed to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to certain embodiments, the thermal barrier composite 400 is , about 300°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less; or having a lower temperature of about 200°C or less, or about 175°C or less, or even about 150°C or less. According to yet another embodiment, the thermal barrier composite 400 can withstand temperatures as low as at least about 25°C. The cold side temperature of the thermal barrier composite 400 may have any of the above values. It will be appreciated that the cold side temperature of the thermal barrier composite 400 may be within a range between It will be further understood that the value may be any value between any of the values ​​stated above.

[0207] According to yet another embodiment, the thermal barrier composite 400 is performed at a temperature of 1000° C. The material may have a specific burn-through time as measured when exposed to a torch test as described herein. For purposes of the embodiments described herein, the torch test is performed on a 1 inch by 1 inch specimen of the material. This is done by preparing a thermocouple and placing it 1.5 inches from the torch. Fix it to the flame side and measure the "hot side" temperature, which is adjusted to 1000°C. The pair is positioned on opposite sides of the sample to measure the "cold side" temperature. According to a particular embodiment, the time it takes for the heat to burn through (burn-through time) is measured. The barrier composite 400 may be resistant to moisture for at least about 6 minutes, for example, at least about 6.5 minutes, or less. At least about 7 minutes, or at least about 7.5 minutes, or at least about 8 minutes, or at least about 8. 5 minutes, or at least about 9.0 minutes, or at least about 9.5 minutes, or even at least about The thermal barrier composite 400 may have a burn-through time of 10.0 minutes. , it will be understood that the thermal barrier composite may range between any of the above values. It is understood that the burn-through time of material 400 can be any value between any of the above values. This will be further understood.

[0208] According to still other embodiments, the first foam layer 404 may have a particular thickness. For example, the first foam layer 404 may be at least about 0.5 mm, e.g., at least about 1 0.0 mm, or at least about 1.5 mm, or at least about 2.0 mm, or at least About 2.5 mm, or at least about 3.0 mm, or at least about 3.5 mm, or less Both are about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm. According to yet another embodiment, the first foam layer 404 may have a thickness of about 10 mm or more. or less, for example, about 9.5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less The thickness of the first foam layer 404 may be about 6.0 mm or less. It will be understood that the range may be between any of the minimum and maximum values ​​set forth above. The thickness of the foam layer 404 may be any value between any of the minimum and maximum values ​​listed above. It will be further appreciated that the value may be:

[0209] According to still other embodiments, the thermal barrier composite 400 may have a particular thickness. For example, the thermal barrier composite 400 may have a thickness of at least about 0.5 mm, e.g., at least about 1.0 mm. mm, or at least about 1.5 mm, or at least about 2.0 mm, or at least about 2 0.5mm, or at least about 3.0mm, or at least about 3.5mm, or at least A thickness of about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm According to yet another embodiment, the thermal barrier composite 400 may have a thickness of about 10 mm or less, e.g. For example, about 9.5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less, or The thermal barrier composite 400 may further have a thickness of about 6.0 mm or less. It will be understood that the thermal barrier composition may range between any of the values ​​and maximum values. The thickness of the composite 400 can be any value between any of the minimum and maximum values ​​listed above. It will be further understood that

[0210] According to yet another embodiment, the first foam layer 404 has a specific 25% strain compression. For purposes of the embodiments described herein, a 25% strain compression grade is: Defined as the compressive strength of a specimen measured at 25% strain, The compressive force (FTC) is determined by measuring the specimen's compressive deflection. Compressive Force Deflection (CFD) is defined as the peak force (or stress) that compresses a material to a certain strain. is the plateau maintained by the sample when held at the desired strain (i.e., 25%). The force (or stress) is defined as the relaxation force (or stress) of the specimen. Locate and record both the FTC and CFD values ​​after retraction speed and 10 grams of trigger force. Measurements are taken using a texture analyzer.

[0211] According to certain embodiments, the first foam layer 404 has a pressure of about 500 kPa or less, e.g. , about 475 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 40 0 kPa or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or is about 225 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 15 25% strain compression at 0 kPa or less, or approximately 125 kPa or less, or approximately 100 kPa or less According to yet another embodiment, the first foam layer 404 may have a viscosity of at least about 5 kPa, for example, at least about 10 kPa, or at least about 15 kPa, or at least The first may also have a 25% strain compression rating of about 20 kPa, or at least about 25 kPa. The 25% strain compression rating of the foam layer 404 is either of the minimum and maximum values ​​set forth above. It will be appreciated that the strain of the first foam layer 404 may be within a range between 50% strain and 50% strain. It is understood that the compression rating may be any value between any of the minimum and maximum values ​​listed above. Let's understand more.

[0212] According to yet another embodiment, the thermal barrier composite 400 may be formed to a specific 25% strain compression, etc. For purposes of the embodiments described herein, a 25% strain compression grade may be Defined as the compressive strength of the specimen measured at 5% strain and the compressive strength of the specimen at 25% strain The compressive force (FTC) is determined by measuring the deflection of the specimen. is defined as the peak force (or stress) that compresses a material to a strain of , the plateau maintained by the sample when held at the desired strain (i.e., 25%) or relaxation force (or stress). 60 seconds holding time, 0.16 mm / sec compression Find and record both the FTC and CFD values ​​after the velocity and 10 grams of trigger force. Measurements are taken using a texture analyzer.

[0213] According to certain embodiments, the thermal barrier composite 400 has a pressure of about 500 kPa or less, e.g., About 475 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 400 kPa or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or about 225 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 150 kPa or less, or about 125 kPa or less, or about 100 kPa or less, 25% strain compression grade According to yet another embodiment, the thermal barrier composite 400 may have a thermal conductivity of at least about 5 kP. a, for example, at least about 10 kPa, or at least about 15 kPa, or at least about The thermal barrier may have a 25% strain compression rating of 20 kPa, or at least about 25 kPa. The 25% strain compression rating of composite 400 is between the minimum and maximum values ​​listed above. It will be appreciated that the 50% strain compression rating of the thermal barrier composite 400 may be in the range of It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0214] According to still other embodiments, the first foam layer 404 may have a particular density. For purposes of the embodiments described herein, the density of the first foam layer 404 is determined according to ASTM According to certain embodiments, the first foam layer 404 is approximately 1200 kg / m 3 Below, for example, about 1175 kg / m 3 or less, or about 1150k g / m 3 or less than 1125 kg / m 3 or less than 1100 kg / m 3 Below, or 105 0kg / m 3 or less than 1000 kg / m 3 or less, or 950 kg / m 3 or less, or 90 0kg / m 3 or less, or 850 kg / m 3 or less than 800 kg / m 3 or less, or 750 kg / m 3 or less than 700 kg / m 3 or less, or even 650 kg / m 3 The density of According to yet another embodiment, the first foam layer 404 may have a thickness of at least about 10 0kg / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m 3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or less At least about 200 kg / m 3, or at least about 220 kg / m 3 , or even at least Approximately 240 kg / m 3 The density of the first foam layer 404 may be at least the above minimum. It will be understood that the value may be within a range between any of the values ​​and the maximum value. The density of the foam layer 404 is any value between any of the minimum and maximum values ​​listed above. It will be further understood that

[0215] According to still other embodiments, the thermal barrier composite 400 may have a particular density. For purposes of the embodiments described herein, the density of the first foam layer 404 is determined by ASTM According to certain embodiments, the thermal barrier composite 400 may be Approximately 1500kg / m 3 For example, about 1475 kg / m 3 Less than or equal to 1450 kg / m 3 or less, or 1425 kg / m 3 or less than 1400 kg / m 3 Below, or 1350k g / m 3 or less than 1300 kg / m 3 or less than 1250 kg / m 3 or less, or 120 0kg / m 3 or less than 1150 kg / m 3 or less than 1100 kg / m 3 Below, or 1 050kg / m 3 or less than 1000 kg / m 3 or even 950 kg / m 3 below According to yet another embodiment, the thermal barrier composite 400 may have a density of at least Approximately 100kg / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or at least about 200 kg / m 3 , or at least about 220 kg / m 3 , or even less At least about 240 kg / m 3 The density of the thermal barrier composite 400 may be It will be appreciated that the thermal barrier may be within a range between any of the minimum and maximum values. The density of the composite material 400 is any value between any of the minimum and maximum values ​​listed above. It will be further understood that this is possible.

[0216] According to yet another embodiment, the first foam layer 404 is made of a material conforming to ASTM C518. For example, the first foam layer 404 may have a particular thermal conductivity as measured by At least about 0.01 W / mK, for example, at least about 0.02 W / mK, or at least about 0 0.03 W / mK, or at least about 0.04 W / mK, or even at least about 0.05 According to yet another embodiment, the first foam layer 404 may have a thermal conductivity of , about 0.15 W / mK or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less or less, or about 0.12 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less, about 0.09 W / mK or less, or about 0.08 W / mK, or even about 0.07 W The thermal conductivity of the first foam layer 404 may be less than or equal to the minimum value. It will be understood that the range may be anywhere between 0.01 and 0.02. The thermal conductivity of the rubber layer 404 may be any value between any of the minimum and maximum values ​​listed above. It will be further understood that this is possible.

[0217] According to yet another embodiment, the thermal barrier composite 400 is made in accordance with ASTM C518. For example, the thermal barrier composite 400 may have a particular thermal conductivity measured at least about 0.01 W / mK, for example, at least about 0.02 W / mK, or at least about 0.0 3 W / mK, or at least about 0.04 W / mK, or even at least about 0.05 W / According to yet another embodiment, the thermal barrier composite 400 may have a thermal conductivity of about 0 0.15 W / mK or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less; or about 0.12 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less or less, about 0.09 W / mK or less, or about 0.08 W / mK, or even about 0.07 W / mK The thermal barrier composite 400 may have a thermal conductivity of: It will be understood that the thermal barrier composite 400 may range between any of the values. The thermal conductivity of the material may be any value between any of the minimum and maximum values ​​listed above. will be further understood.

[0218] According to yet another embodiment, the first barrier layer 402 is made of mica, mica fiberglass cloth, , glass cloth, silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, non-woven glass cloth, any combination thereof, and any laminate thereof. It can be a material that can be used.

[0219] According to yet another embodiment, the first barrier layer 402 may comprise a specific material. For example, the first barrier layer 402 may include mica. The rear layer 402 may include mica fiberglass cloth. According to yet another embodiment, the first The barrier layer 402 may include glass cloth. According to another embodiment, the first barrier layer 402 According to yet another embodiment, the first barrier layer 402 may comprise a basal According to yet another embodiment, the first barrier layer 402 may comprise a vermicular According to another embodiment, the first barrier layer 402 may comprise an aerosol coated glass cloth. According to yet another embodiment, the first barrier layer 402 may comprise a non-woven glass cloth. According to yet another embodiment, the first barrier layer 402 may include mica, mica fibers, Glass cloth, glass cloth, silica cloth, basalt cloth, vermiculite-coated glass cloth, aerogel According to still other embodiments, the first and second layers may include any combination of glass fiber, glass fiber reinforced plastic ... The barrier layer 402 may be made of mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, or the like. , including any laminate of vermiculite-coated glass cloth, aerogel, or nonwoven glass cloth. obtain.

[0220] According to yet another embodiment, the first barrier layer 402 may be made of a specific material. For example, the first barrier layer 402 may be made of mica. The barrier layer 402 may be made of mica fiberglass cloth. The first barrier layer 402 may be made of glass cloth. According to another embodiment, the first barrier Layer 402 may be made of silica cloth. According to yet another embodiment, first barrier layer 402 According to yet another embodiment, the first barrier layer 402 may be made of basalt fabric. According to another embodiment, the first barrier layer 4 may be made of vermiculite coated glass cloth. According to yet another embodiment, the first barrier layer 402 may be made of aerogel. According to yet another embodiment, the first barrier layer 402 may be made of a non-woven glass cloth. Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It may be made of any combination of glass cloth, aerogel, or non-woven glass cloth. According to an embodiment, the first barrier layer 402 may be made of mica, mica fiberglass cloth, glass cloth, Silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or non-woven glass cloth The laminate may be any laminate of the above.

[0221] According to yet another embodiment, the first barrier layer 402 can be a layer of a specific material. For example, the first barrier layer 402 can be a mica layer. The barrier layer 402 may be a mica fiberglass cloth layer. The first barrier layer 402 can be a glass cloth layer. According to another embodiment, the first barrier Layer 402 can be a silica cloth layer. According to yet another embodiment, first barrier layer 402 According to yet another embodiment, the first barrier layer 402 may be a basalt fabric layer. According to another embodiment, the first barrier layer 4 may be a vermiculite-coated glass cloth layer. According to yet another embodiment, the first barrier layer 402 may be an aerogel layer. According to yet another embodiment, the first barrier layer 402 is a non-woven glass fabric layer. Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It can be a layer of glass cloth, aerogel, or any combination of non-woven glass cloth. According to this embodiment, the first barrier layer 402 is made of mica, mica fiber glass cloth, glass cloth, , silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or nonwoven glass It can be any laminate layer of fabric.

[0222] According to still other embodiments, the first barrier layer 402 may have a particular thickness. For example, the first barrier layer 402 may be at least about 0.05 mm, e.g., at least about 0. 1 mm, or at least about 0.2 mm, or at least about 0.3 mm, or at least about 0.4 mm, or at least about 0.5 mm, or at least about 0.6 mm, or at least at least about 0.7 mm, or at least about 0.8 mm, or at least about 0.9 mm, or less at least about 1.0 mm, or at least about 1.1 mm, or at least about 1.2 mm, or It may have a thickness of at least about 1.3 mm, or even at least about 1.4 mm. According to this embodiment, the first barrier layer 402 is about 7 mm or less, for example, about 6.5 mm or less. or less than about 6.0 mm, or less than about 5.5 mm, or less than about 5.0 mm, or less than about 4. Not more than 5 mm, or not more than about 4.0 mm, or not more than about 2.9 mm, or not more than about 2.8 mm or less, or about 2.7 mm or less, or about 2.6 mm or less, or about 2.5 mm or less, or about 2 It may have a thickness of 0.4 mm or less, or about 2.3 mm or less, or even about 2.2 mm or less. The thickness of the first barrier layer 402 is within a range between any of the above minimum and maximum values. It will be appreciated that the thickness of the first barrier layer 402 may be within the above minimum and maximum values. It will be further understood that the value may be any value between any of the values.

[0223] FIG. 5 illustrates another thermal barrier composite 500 according to embodiments described herein. As shown, the thermal barrier composite 500 includes a first barrier layer 502 and a first foam layer 503. The first foam layer 504 may comprise a silicone barrier layer 506. The composite material includes a matrix component 510, a flame-retardant filler component 520, and a heat-insulating filler component 530. It can be seen.

[0224] The thermal barrier composite 500 and the thermal barrier composite 500 shown in FIG. All components shown in FIG. 4 have the same characteristics as those described herein with respect to the corresponding components in FIG. In particular, the thermal barrier composite 500 shown in FIG. , a first barrier layer 502, a first foam layer 504, a silicone-based matrix component 51 The properties of the flame retardant filler component 520 and the heat insulating filler component 530 are shown in FIG. The thermal barrier composite 400 shown includes a first barrier layer 402, a first foam layer 404, a silicone Corn-based matrix component 410, flame-retardant filler component 420, and insulating filler component 43 0.

[0225] According to yet another embodiment, the second barrier layer 506 is made of mica, mica fiberglass cloth, , glass cloth, silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, non-woven glass cloth, any combination thereof, and any laminate thereof. It can be a material that can be used.

[0226] According to yet another embodiment, the second barrier layer 506 may comprise a specific material. For example, the second barrier layer 506 may include mica. The rear layer 506 may include mica fiberglass cloth. According to yet another embodiment, the second The barrier layer 506 may comprise a glass cloth. According to another embodiment, the second barrier layer 506 According to yet another embodiment, the second barrier layer 506 may comprise a basal According to yet another embodiment, the second barrier layer 506 may comprise a vermicular According to another embodiment, the second barrier layer 506 may comprise an aerosol coated glass cloth. According to yet another embodiment, the second barrier layer 506 may comprise a non-woven glass cloth. According to yet another embodiment, the second barrier layer 506 may include mica, mica fibers, Glass cloth, glass cloth, silica cloth, basalt cloth, vermiculite-coated glass cloth, aerogel According to still other embodiments, the first and second layers may include any combination of glass fiber, glass fiber reinforced plastic ... The second barrier layer 506 may be made of mica, mica fiberglass cloth, glass cloth, silica cloth, or basalt cloth. , including any laminate of vermiculite-coated glass cloth, aerogel, or nonwoven glass cloth. obtain.

[0227] According to yet another embodiment, the second barrier layer 506 can be made of a specific material. For example, the second barrier layer 506 may be made of mica. The barrier layer 506 may be made of mica fiberglass cloth. The second barrier layer 506 may be made of glass cloth. According to another embodiment, the second barrier Layer 506 may be made of silica cloth. According to yet another embodiment, second barrier layer 506 According to yet another embodiment, the second barrier layer 506 may be made of basalt fabric. According to another embodiment, the second barrier layer 5 may be made of vermiculite coated glass cloth. According to yet another embodiment, the second barrier layer 506 may be made of aerogel. According to yet another embodiment, the second barrier layer 506 may be made of a non-woven glass cloth. Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It may be made of any combination of glass cloth, aerogel, or non-woven glass cloth. According to an embodiment, the second barrier layer 506 may be made of mica, mica fiberglass cloth, glass cloth, Silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or non-woven glass cloth The laminate may be any laminate of the above.

[0228] According to yet another embodiment, the second barrier layer 506 can be a layer of a specific material. For example, the second barrier layer 506 can be a mica layer. The barrier layer 506 may be a mica fiberglass cloth layer. The second barrier layer 506 can be a glass cloth layer. According to another embodiment, the second barrier Layer 506 can be a silica cloth layer. According to yet another embodiment, second barrier layer 506 According to yet another embodiment, the second barrier layer 506 may be a basalt fabric layer. According to another embodiment, the second barrier layer 5 may be a vermiculite-coated glass cloth layer. According to yet another embodiment, the second barrier layer 506 may be an aerogel layer. According to yet another embodiment, the second barrier layer 506 is Mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite coating It can be a layer of glass cloth, aerogel, or any combination of non-woven glass cloth. According to this embodiment, the second barrier layer 506 is made of mica, mica fiberglass cloth, glass cloth, , silica cloth, basalt cloth, vermiculite coated glass cloth, aerogel, or nonwoven glass It can be any laminate layer of fabric.

[0229] According to still other embodiments, the second barrier layer 506 may have a particular thickness. For example, the second barrier layer 506 may be at least about 0.05 mm, e.g., at least about 0. 1 mm, or at least about 0.2 mm, or at least about 0.3 mm, or at least about 0.4 mm, or at least about 0.5 mm, or at least about 0.6 mm, or at least at least about 0.7 mm, or at least about 0.8 mm, or at least about 0.9 mm, or less at least about 1.0 mm, or at least about 1.1 mm, or at least about 1.2 mm, or It may have a thickness of at least about 1.3 mm, or even at least about 1.4 mm. According to this embodiment, the second barrier layer 506 is about 3.7 mm or less, for example, about 6.5 mm. mm or less, or about 6.0 mm or less, or about 5.5 mm or less, or about 5.0 mm or less, or about Not more than 4.5 mm, or not more than about 4.0 mm, or not more than about 2.9 mm, or not more than about 2.8 mm or less, or about 2.7 mm or less, or about 2.6 mm or less, or about 2.5 mm or less, or It may have a thickness of about 2.4 mm or less, or about 2.3 mm or less, or even about 2.2 mm or less. The thickness of the second barrier layer 506 may be in a range between any of the above minimum and maximum values. It will be understood that the thickness of the second barrier layer 506 may be within the above minimum and It will be further understood that the maximum value may be any value between any of the maximum values.

[0230] FIG. 6 illustrates another thermal barrier composite 600 according to embodiments described herein. As shown, the thermal barrier composite 600 includes a first barrier layer 602 and a first foam layer 603. 604, a second foam layer 608, and a second barrier layer 606. The foam layer 604 comprises a silicone-based matrix component 610, a flame-retardant filler component 620, and The second foam layer 608 may include a silicone-based matrix. The composite may include a flame retardant filler component 640, a flame retardant filler component 650, and a thermal insulating filler component 660. As shown in FIG. 6, both the first foam layer 604 and the second foam layer 608 are It is between the first barrier layer 602 and the second barrier layer 608 .

[0231] The thermal barrier composite 600 and the thermal barrier composite 600 shown in FIG. All components shown are as described herein with respect to the corresponding components in FIG. 5 and / or FIG. 4. It will be understood that the thermal barrier may have any of the properties shown in FIG. The composite 600 includes a first barrier layer 602, a first foam layer 604, and a second barrier layer 606. 6. Silicone matrix component 610, flame retardant filler component 620, and heat insulating filler The properties of the component 630 are the same as those of the thermal barrier composite 400 (500) shown in FIG. 4 (FIG. 5), respectively. ), first barrier layer 402 (502), first foam layer 404 (504), silicone A matrix component 410 (510), a flame-retardant filler component 420 (520), and a thermal insulating Any of the corresponding properties described herein for filler component 430 (530) It may also have

[0232] According to certain embodiments, the silicone-based matrix component of the second foam layer 608 640 may comprise a platinum catalyzed addition cure silicone foam. The silicone-based matrix component 640 may include a peroxide-cured silicone foam. According to yet another embodiment, the silicone-based matrix component 640 is a tin-catalyzed silicone. According to yet another embodiment, the silicone-based matrix component may comprise corn foam. 640 is a platinum-catalyzed addition-cure silicone foam, a peroxide-cure silicone foam, and and tin catalyzed silicone foams.

[0233] According to certain embodiments, the silicone-based matrix component 640 is a platinum-catalyzed curing agent. According to yet another embodiment, the silicone matrix may be a fluorinated silicone foam. The foam component 640 may comprise a peroxide-cured silicone foam. According to the patent, the silicone matrix component 640 is comprised of a tin-catalyzed silicone foam. According to yet another embodiment, the silicone-based matrix component 640 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam It may consist of any combination of information.

[0234] According to certain embodiments, the silicone-based matrix component 640 is a platinum-catalyzed curing agent. According to yet another embodiment, the layer may be a silicone-based matrix. The foam component 640 can be a peroxide-cured silicone foam layer. According to the patent, the silicone matrix component 640 is a tin-catalyzed silicone foam layer. According to yet another embodiment, the silicone-based matrix component 640 may include a platinum catalyst. Addition-cure silicone foam, peroxide-cure silicone foam, and tin-catalyzed silicone foam The layer may be any combination of layers of foam.

[0235] According to yet another embodiment, the flame-retardant filler component 650 is selected from a specific group of materials. For example, the flame-retardant filler component 650 may be a metal hydrate, a borate compound, a platinum compound, or the like. Substances, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate Nesium, glass frit, alkali salts, vermiculite, and any combination thereof The compound may be selected from the group consisting of:

[0236] According to yet other embodiments, the flame-retardant filler component 650 may include certain materials. For example, the flame-retardant filler component 650 may include a metal hydrate. The fire-retardant filler component 650 may include a borate compound. The flame-retardant filler component 650 may include a platinum compound. The filler component 650 may include a transition metal oxide. According to another embodiment, the flame-retardant filler component According to yet another embodiment, the flame-retardant filler component 650 may include a metal carbonate. According to yet another embodiment, the flame retardant filler component 6 may comprise calcium silicate. According to yet another embodiment, the flame retardant filler composition may comprise aluminum silicate. The component 650 may include magnesium silicate. According to yet another embodiment, the flame-retardant filler Component 650 may include glass frit. According to yet another embodiment, the flame-retardant filler component According to yet another embodiment, the flame retardant filler component 650 may include an alkali salt. According to yet another embodiment, the flame retardant filler component 6 50 is a metal hydrate, borate compound, platinum compound, transition metal oxide, metal carbonate, silica calcium silicate, aluminum silicate, magnesium silicate, glass frit, alkali salt , or vermiculite.

[0237] According to yet other embodiments, the flame-retardant filler component 650 may be made of specific materials. For example, the flame-retardant filler component 650 may comprise a metal hydrate. For example, the flame-retardant filler component 650 may comprise a borate compound. For example, the flame-retardant filler component 650 may comprise a platinum compound. The flame-retardant filler component 650 may comprise a transition metal oxide. According to yet another embodiment, the flame-retardant filler component 650 may comprise a metal carbonate. The filler component 650 may comprise calcium silicate. The polymeric filler component 650 may comprise aluminum silicate. In yet another embodiment, the flame-retardant filler component 650 may comprise magnesium silicate. For example, the flame-retardant filler component 650 may comprise glass frit. For example, the flame-retardant filler component 650 may comprise an alkali salt. For example, the fire-retardant filler component 650 may comprise vermiculite. For example, the flame retardant filler component 650 may be a metal hydrate, a borate compound, a platinum compound, a transition metal Oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate, gallium silicate It may consist of any combination of lath frit, alkali salts, or vermiculite.

[0238] According to yet other embodiments, the flame-retardant filler component 650 can be a specific material. For example, the flame-retardant filler component 650 can be a metal hydrate filler. For example, the flame-retardant filler component 650 may be a borate filler. For example, the flame-retardant filler component 650 can be a platinum compound filler. For example, the flame-retardant filler component 650 can be a transition metal oxide filler. For example, the flame-retardant filler component 650 can be a metal carbonate filler. For example, the flame-retardant filler component 650 can be a calcium silicate filler. According to an embodiment, the flame-retardant filler component 650 can be an aluminum silicate filler. According to another embodiment, the flame-retardant filler component 650 may be a magnesium silicate filler. According to yet another embodiment, the flame-retardant filler component 650 is a glass frit filler. According to yet another embodiment, the flame-retardant filler component 650 is an alkali salt filler. According to yet another embodiment, the fire-retardant filler component 650 may be a vermiculite filler. According to yet another embodiment, the flame-retardant filler component 650 may be a metal hydrate, Borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, silicic acid Aluminum, magnesium silicate, glass frit, alkali salt, or vermiculite The filler may be any combination of the above.

[0239] According to yet another embodiment, the flame-retardant filler component 650 is a specific group of metal hydrate materials. For example, the flame retardant filler component 650 may be selected from aluminum trihydrate, dihydrate, Magnesium chloride, boehmite, calcium hydroxide, huntite, gypsum, hydromagnesa and any combination thereof.

[0240] According to yet another embodiment, the flame-retardant filler component 650 includes certain metal hydrate materials. For example, the flame-retardant filler component 650 may include aluminum trihydrate. According to this embodiment, the flame-retardant filler component 650 may include magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 650 may include boehmite. According to an embodiment, the flame-retardant filler component 650 may include calcium hydroxide. According to an embodiment, the flame-retardant filler component 650 may include huntite. According to an embodiment, the fire-retardant filler component 650 may include gypsum. The polymeric filler component 650 may include hydromagnesite. Flame retardant filler component 650 is aluminum trihydrate, magnesium dihydroxide, boehmite , calcium hydroxide, huntite, gypsum, or any combination of hydromagnesite may include:

[0241] According to yet another embodiment, the flame-retardant filler component 650 is made from certain metal hydrate materials. For example, the flame-retardant filler component 650 can be aluminum trihydrate. According to another embodiment, the flame-retardant filler component 650 may comprise magnesium dihydroxide. According to yet another embodiment, the flame-retardant filler component 650 may consist of boehmite. According to another embodiment, the fire-retardant filler component 650 may comprise calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 650 may comprise huntite. According to yet another embodiment, the fire-retardant filler component 650 may comprise gypsum. According to another embodiment, the flame-retardant filler component 650 may comprise hydromagnesite. According to an embodiment, the flame retardant filler component 650 is aluminum trihydrate, magnesium dihydroxide, Calcium, boehmite, calcium hydroxide, huntite, gypsum, or hydromagnesite It can consist of any combination.

[0242] According to yet another embodiment, the flame-retardant filler component 650 is a specific metal hydrate material filler. For example, the flame retardant filler component 650 may be an aluminum trihydrate filler. According to yet another embodiment, the flame-retardant filler component 650 is a magnesium dihydroxide filler. According to yet another embodiment, the flame-retardant filler component 650 may be boehmite. According to another embodiment, the flame-retardant filler component 650 may be calcium hydroxide. According to yet another embodiment, the flame-retardant filler component 650 may be a tantalum filler. According to yet another embodiment, the fire-retardant filler component 650 may be a gypsum filler. According to another embodiment, the flame-retardant filler component 650 may be hydromagnesa. According to yet another embodiment, the flame-retardant filler component 650 may be an aluminum filler. nium trihydrate, magnesium dihydroxide, boehmite, calcium hydroxide, huntite, The filler may be any combination of gypsum, or hydromagnesite.

[0243] According to yet another embodiment, the fire-retardant filler component 650 is selected from a specific group of borate materials. For example, the flame-retardant filler component 650 may be selected from zinc borate, calcium borate, Sodium borate, potassium borate, lithium borate, and any combination thereof The compound may be selected from the group consisting of:

[0244] According to yet another embodiment, the fire-retardant filler component 650 includes certain borate materials. For example, the flame-retardant filler component 650 may include zinc borate. According to another embodiment, the flame-retardant filler component 650 may include calcium borate. For example, the flame-retardant filler component 650 may include sodium borate. For example, the flame-retardant filler component 650 may include potassium borate. For example, the flame-retardant filler component 650 may include lithium borate. For example, the flame retardant filler component 650 is zinc borate, calcium borate, sodium borate, The composition may include any combination of potassium borate, potassium phosphate, or lithium borate.

[0245] According to yet another embodiment, the flame-retardant filler component 650 is comprised of certain borate materials. For example, the flame-retardant filler component 650 may comprise zinc borate. According to an embodiment, the flame-retardant filler component 650 can comprise calcium borate. According to an embodiment, the flame-retardant filler component 650 can comprise sodium borate. According to one embodiment, the flame-retardant filler component 650 may comprise potassium borate. According to an embodiment, the flame-retardant filler component 650 may comprise lithium borate. According to an embodiment, the flame retardant filler component 650 is selected from the group consisting of zinc borate, calcium borate, sodium borate, and the like. The borate may consist of any combination of thorium, potassium borate, or lithium borate.

[0246] According to yet another embodiment, the flame-retardant filler component 650 is a specific borate material filler. For example, the flame-retardant filler component 650 can be a zinc borate filler. According to another embodiment, the fire-retardant filler component 650 may be a calcium borate filler. According to another embodiment, the flame retardant filler component 650 may be a sodium borate filler. According to yet another embodiment, the flame-retardant filler component 650 is a potassium borate filler. According to yet another embodiment, the flame-retardant filler component 650 may be a lithium borate filler. According to yet another embodiment, the flame-retardant filler component 650 may be zinc borate, boron nitride, or the like. Any combination of calcium borate, sodium borate, potassium borate, or lithium borate It may be a composite filler.

[0247] According to yet another embodiment, the flame-retardant filler component 650 is selected from a specific group of platinum compound materials. For example, the flame retardant filler component 650 may be selected from platinum-1,3-divinyl-1, 1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof The compound may be selected from the group consisting of:

[0248] According to yet another embodiment, the flame-retardant filler component 650 includes certain platinum compound materials. For example, the flame retardant filler component 650 may be platinum-1,3-divinyl-1,1,3,3 According to yet another embodiment, the flame retardant filler composition may include tetramethyldisiloxane. The component 650 may include hexachloroplatinic acid. According to yet another embodiment, the flame-retardant filler Component 650 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxane and and hexachloroplatinic acid.

[0249] According to yet another embodiment, the flame-retardant filler component 650 is made from certain platinum compound materials. For example, the flame retardant filler component 650 can be platinum-1,3-divinyl-1,1,3, According to yet another embodiment, the flame retardant filling may consist of 3-tetramethyldisiloxane. The agent component 650 may comprise hexachloroplatinic acid. Filler component 650 is platinum-1,3-divinyl-1,1,3,3-tetramethyldisiloxy The composition may consist of any combination of tetrachloroplatinic acid and hexachloroplatinic acid.

[0250] According to yet another embodiment, the flame-retardant filler component 650 is a filler material containing certain platinum compound materials. For example, the flame retardant filler component 650 can be platinum-1,3-divinyl-1,1, According to yet another embodiment, the filler may be 3,3-tetramethyldisiloxane. The flame retardant filler component 650 can be a hexachloroplatinic acid filler. If so, the flame retardant filler component 650 may be a filler or a platinum-1,3-divinyl-1,1,3, It can be any combination of 3-tetramethyldisiloxane and hexachloroplatinic acid.

[0251] According to yet another embodiment, the flame-retardant filler component 650 is a specific transition metal oxide material. For example, the flame retardant filler component 650 may be selected from the group consisting of iron oxide, cerium oxide, acid The inorganic filler may be selected from the group consisting of titanium dioxide, zinc oxide, and any combination thereof.

[0252] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 650 may include iron oxide. According to an embodiment, the flame-retardant filler component 650 may include cerium oxide. For example, the flame-retardant filler component 650 may include zinc oxide. The reactive filler component 650 may be any combination of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It may include a combination.

[0253] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 650 may comprise iron oxide. According to an embodiment, the flame-retardant filler component 650 may comprise cerium oxide. According to one embodiment, the flame-retardant filler component 650 may comprise zinc oxide. For example, the flame retardant filler component 650 may be any of iron oxide, cerium oxide, titanium oxide, or zinc oxide. It can consist of any combination of

[0254] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal oxide materials. For example, the flame-retardant filler component 650 can be an iron oxide filler. According to yet another embodiment, the flame-retardant filler component 650 may be a cerium oxide filler. According to another embodiment, the flame-retardant filler component 650 may be a zinc oxide filler. According to this embodiment, the flame retardant filler component 650 may be selected from the group consisting of iron oxide, cerium oxide, titanium oxide, or zinc oxide filler in any combination.

[0255] According to yet another embodiment, the flame-retardant filler component 650 is a specific group of metal carbonate materials. For example, the flame-retardant filler component 650 may be selected from huntite, calcium carbonate, and any combination thereof.

[0256] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 650 may include huntite. According to an embodiment, the flame-retardant filler component 650 may include calcium carbonate. According to the embodiment, the fire retardant filler component 650 is any combination of huntite or calcium carbonate. It may include a combination.

[0257] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 650 may consist of huntite. According to one embodiment, the flame-retardant filler component 650 may comprise calcium carbonate. According to this embodiment, the fire-retardant filler component 650 is either huntite or calcium carbonate. It can consist of a combination of:

[0258] According to yet another embodiment, the flame-retardant filler component 650 is selected from certain transition metal carbonate materials. For example, the flame-retardant filler component 650 can be a huntite filler. According to yet another embodiment, the flame-retardant filler component 650 is a calcium carbonate filler. According to yet another embodiment, the flame-retardant filler component 650 is huntite or calcium carbonate. The filler may be any combination of sodium.

[0259] According to yet another embodiment, the fire-retardant filler component 650 is a metal carbonate mixture containing For example, the flame-retardant filler component 650 may be selected from the group consisting of hydromagnesite and han natural mixtures with tait, synthetic magnesium carbonate hydroxide pentahydrate, and any combination thereof The compound may be selected from the group consisting of:

[0260] According to yet another embodiment, the fire-retardant filler component 650 comprises a mixture of certain metal carbonates. For example, the flame-retardant filler component 650 may include a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 650 is a hydromagnesite sol. According to yet another embodiment, the flame-retardant filler component 650 may include a hydro- Natural mixture of magnesite and huntite, or synthetic magnesium hydroxide carbonate pentahydrate Any combination may be included.

[0261] According to yet another embodiment, the flame-retardant filler component 650 is made from a specific metal carbonate mixture. For example, the fire-retardant filler component 650 may consist of a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 650 can comprise hydromagnesite. According to yet another embodiment, the flame-retardant filler component 650 may comprise a natural mixture of A natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate pentahydrate The compound may be any combination of solvates.

[0262] According to yet another embodiment, the fire-retardant filler component 650 is a specific metal carbonate mixture filler. For example, the fire-retardant filler component 650 may be a natural mixture of hydromagnesite. According to another embodiment, the flame-retardant filler component 650 may be hydromagnesium carbonate. According to yet another embodiment, the flame retardant filler component 65 may be a natural mixture of fillers. 0 is a natural mixture of hydromagnesite and huntite, or a synthetic magnesium hydroxide carbonate. The filler may be any combination of ammonium pentahydrate.

[0263] According to yet another embodiment, the flame-retardant filler component 650 is an alumina silicate material or For example, the flame retardant filler component 650 may be selected from a specific group of magnesium carbonate materials. , wollastonite, mica, clay, kaolin, talc, vermiculite, and their Any combination may be selected from the group consisting of:

[0264] According to yet another embodiment, the flame-retardant filler component 650 is a specific alumina silicate material. For example, the flame-retardant filler component 650 may include a wollastonite or magnesium silicate material. According to yet another embodiment, the flame-retardant filler component 650 may include mica. According to yet another embodiment, the flame-retardant filler component 650 may include clay. According to this embodiment, the flame-retardant filler component 650 may include kaolin. According to one embodiment, the flame-retardant filler component 650 may include talc. The fire-retardant filler component 650 may include vermiculite. The flame retardant filler component 650 is selected from the group consisting of wollastonite, mica, clay, kaolin, talc, and basil. The composition may include any combination of cellulose, cellulose acetate, cellulose nitrate, cellulose acetate, cellulose acetate nitrate ...

[0265] According to yet another embodiment, the flame-retardant filler component 650 is a specific alumina silicate material. or magnesium silicate material. For example, the flame-retardant filler component 650 may be composed of Walrus According to yet another embodiment, the flame-retardant filler component 650 may comprise mittite. According to yet another embodiment, the flame-retardant filler component 650 may comprise clay. According to another embodiment, the flame-retardant filler component 650 may comprise kaolin. According to yet another embodiment, the flame-retardant filler component 650 may comprise talc. According to an embodiment, the flame-retardant filler component 650 can comprise vermiculite. According to the form, the fire retardant filler component 650 is wollastonite, mica, clay, kaolin, The granular material may be any combination of talc, or vermiculite.

[0266] According to yet another embodiment, the flame-retardant filler component 650 is a specific alumina silicate material. or a magnesium silicate material filler. For example, the flame-retardant filler component 650 may be: According to yet another embodiment, the flame retardant filler component 65 may be a wollastonite filler. According to yet another embodiment, the flame-retardant filler component 650 is According to another embodiment, the fire-retardant filler component 650 may be kaolin, According to yet another embodiment, the flame-retardant filler component 650 may be a talc filler. According to another embodiment, the fire-retardant filler component 650 may be vermiculite. According to yet another embodiment, the flame-retardant filler component 650 may be a wollastonite filler. Filled with any combination of ash, mica, clay, kaolin, talc, or vermiculite It may be a filler.

[0267] According to yet another embodiment, the flame retardant filler component 650 is selected from a specific group of alkali salt materials. For example, the flame retardant filler component 650 may be selected from sodium carbonate, potassium carbonate, and any combination thereof.

[0268] According to yet another embodiment, the flame-retardant filler component 650 includes certain alkali salt materials. For example, the flame-retardant filler component 650 may include sodium carbonate. According to an embodiment, the flame-retardant filler component 650 may include potassium carbonate. According to an embodiment, the flame retardant filler component 650 may be any combination of sodium carbonate or potassium carbonate. It may include a combination.

[0269] According to yet another embodiment, the flame retardant filler component 650 is made from certain alkali salt materials. For example, the flame-retardant filler component 650 may comprise sodium carbonate. According to one embodiment, the flame-retardant filler component 650 may comprise potassium carbonate. According to an embodiment, the flame retardant filler component 650 is either sodium carbonate or potassium carbonate. It can consist of a combination of:

[0270] According to yet another embodiment, the flame retardant filler component 650 is a filler of a particular alkali salt material. For example, the flame-retardant filler component 650 can be a sodium carbonate filler. According to yet another embodiment, the flame-retardant filler component 650 may be potassium carbonate filler. According to yet another embodiment, the flame-retardant filler component 650 is sodium carbonate or calcium carbonate. The filler may be any combination of sodium.

[0271] According to yet another embodiment, the insulating filler component 660 is selected from a specific group of materials. For example, the insulating filler component 660 may be expanded perlite, unexpanded perlite, glass, or the like. Subeeds, vermiculite, expanded vermiculite, expanded glass, zeolite, aero Gel, silica, porous silica, porous alumina, and any combination thereof It may be selected from the group:

[0272] According to yet other embodiments, the insulating filler component 660 may include certain materials. For example, the insulating filler component 660 may include expanded perlite. In other embodiments, the insulating filler component 660 may include unexpanded perlite. According to still other embodiments, the insulating filler component 660 may include glass beads. In yet another embodiment, the insulating filler component 660 may include vermiculite. Accordingly, the insulating filler component 660 may include expanded vermiculite. According to an embodiment, the insulating filler component 660 may include expanded glass. According to another embodiment, the insulating filler component 660 may include zeolite. For example, the insulating filler component 660 may include an aerogel. The insulating filler component 660 may include silica. The filler component 660 may comprise porous silica. According to another embodiment, the insulating filler component 660 may comprise porous alumina. According to yet another embodiment, the insulating filler component 6 60 is a list of expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite, -miculite, expanded glass, zeolite, aerogel, silica, porous silica, or poly The porous alumina may comprise any combination of porous alumina.

[0273] According to yet other embodiments, the insulating filler component 660 may be made of a specific material. For example, the insulating filler component 660 may consist of expanded perlite. According to yet another embodiment, the insulating filler component 660 may comprise unexpanded perlite. In some embodiments, the insulating filler component 660 may comprise glass beads. In some embodiments, the insulating filler component 660 may comprise vermiculite. According to an embodiment, the insulating filler component 660 may comprise expanded vermiculite. According to yet another embodiment, the insulating filler component 660 may be comprised of expanded glass. According to yet another embodiment, insulating filler component 660 may comprise zeolite. According to this embodiment, the insulating filler component 660 may comprise an aerogel. According to an embodiment, the insulating filler component 660 may comprise silica. According to an embodiment, the insulating filler component 660 may comprise porous silica. For example, the insulating filler component 660 may be comprised of porous alumina. For example, the insulating filler component 660 may be expanded perlite, non-expanded perlite, glass beads, Vermiculite, expanded vermiculite, expanded glass, zeolite, aerogel, silica The porous silica may be any combination of quartz, porous silica, or porous alumina.

[0274] According to yet another embodiment, the insulating filler component 660 is a filler of a specific material. For example, the insulating filler component 660 can be expanded perlite filler. According to this embodiment, the insulating filler component 660 may be a non-expanded perlite filler. According to yet another embodiment, the insulating filler component 660 may be a glass bead filler. According to yet another embodiment, the insulating filler component 660 is a vermiculite filler. According to yet another embodiment, the insulating filler component 660 can be expanded vermiculite. According to yet another embodiment, the insulating filler component 660 may be a foamed or swelled filler. According to yet another embodiment, the flame-retardant filler component 220 may be: According to yet another embodiment, the insulating filler component 660 can be a zeolite filler. According to yet another embodiment, the insulating filler component 660 can be an aerogel filler. According to yet another embodiment, the insulating filler component 660 may be: According to another embodiment, the insulating filler component 660 may be a porous silica filler. According to yet another embodiment, the insulating filler component 660 can be a porous alumina filler. , expanded perlite, non-expanded perlite, glass beads, vermiculite, expanded vermiculite durite, expanded glass, zeolite, aerogel, silica, porous silica, or porous aluminum The filler may be any combination of Lumina.

[0275] According to a particular embodiment, the second foam layer 608 comprises a silicone-based For example, the second foam layer 608 may include a matrix component 640. At least about 20% by weight, for example, at least about 25% by weight, based on the total weight of the rubber layer 608 , or at least about 30% by weight, or at least about 35% by weight, or at least about 40% by weight %, or at least about 45% by weight, or even at least about 50% by weight of silicone-based According to yet another embodiment, the second foam layer 6 The second foam layer 608 is about 85% by weight or less, for example, about 80% by weight or less, based on the total weight of the second foam layer 608. % by weight or less, or about 75% by weight or less, or about 70% by weight or less, or even about 65% by weight or less The silicone matrix component content of the second foam layer 608 may be The content of the inorganic matrix component may be within a range between any of the values ​​above. It will be understood that the silicone matrix component content of the second foam layer 608 is It will be further understood that the minimum and maximum values ​​may be any value between any of the values ​​set forth above. cormorant.

[0276] According to yet another embodiment, the second foam layer 608 may contain a specific content of flame retardant filling. For example, the second foam layer 608 may include a foam component 650. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the flame-retardant filler component may comprise at least about 15% of a flame-retardant filler component. The second foam layer 608 comprises about 35% by weight or less of the total weight of the second foam layer 608. , for example, about 34% by weight or less, or about 33% by weight or less, or about 32% by weight or less, or about 3 1% by weight or less, or about 30% by weight or less, or about 28% by weight or less, or about 25% by weight or less; Alternatively, the flame-retardant filler component may contain no more than about 23% by weight, or no more than about 20% by weight. The flame-retardant filler component content of the second foam layer 608 is in a range between any of the above values. It will be understood that the flame-retardant filler component content of the second foam layer 608 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0277] According to yet another embodiment, the second foam layer 608 may have a specific content of insulating filler. For example, the second foam layer 608 may include a foam component 650. at least about 1 wt. %, for example, at least about 2 wt. %, or at least or at least about 3% by weight, or at least about 4% by weight, or at least about 5% by weight, or at least about 7% by weight, or at least about 10% by weight, or at least about 12% by weight, or even less According to yet another embodiment, the insulating filler component may contain at least about 15% insulating filler component. The second foam layer 608 comprises about 25% by weight or less of the total weight of the second foam layer 608. , for example, about 24% by weight or less, or about 23% by weight or less, or about 22% by weight or less, or about 2 1% by weight or less, or about 20% by weight or less, or about 19% by weight or less, or about 18% by weight or less; Alternatively, the insulating filler component may contain no more than about 17% by weight, or no more than about 16% by weight. The insulating filler content of the second foam layer 608 may range between any of the values ​​above. It will be understood that the insulating filler content of the second foam layer 608 may be within the range It is further understood that σ can be any value between any of the above minimum and maximum values. Let's do it.

[0278] According to certain embodiments, the second foam layer 608 is made in accordance with ASTM D4986. In particular, the foam layer may have a specific flammability rating as measured by ASTM D4986. The flame retardant may have an HBF flammability rating measured in accordance with the HBF flammability rating.

[0279] According to certain embodiments, the second foam layer 608 is made in accordance with ASTM D3801. In particular, the foam layer may have a specific flammability rating as measured by ASTM D3801. It may have a V-0 flammability rating as measured in accordance with

[0280] According to yet another embodiment, the second foam layer 608 is hot rolled at a temperature of 650°C. The present invention relates to a method for producing a fluorine-containing polymer having a specific autoignition time when exposed to a plate test. For morphology purposes, hot plate testing prepare 1 inch x 1 inch specimens of the material. This is done by placing the test piece on a hot plate. The cold surface temperature was measured by fixing it to a steel weight (1 inch diameter, 2 inches high) placed on top of the The temperature curve is recorded and the point of autoignition, if any, is noted. For example, the second foam layer 608 may be heated for at least about 1 minute, such as at least about 1.5 minutes, or is at least about 2 minutes, or at least about 2.5 minutes, or at least about 3 minutes, or at least at least about 3.5 minutes, or at least about 4.0 minutes, or at least about 4.5 minutes, or even less The second foam layer 608 may have an autoignition time of at least about 5.0 minutes. It will be understood that the second formula may range between any of the above values. The self-ignition time of the rubber layer 608 can be any value between any of the above values. will be further understood.

[0281] According to yet another embodiment, the second foam layer 608 is made up of 6 layers of foam 3 mm thick. It has a specific cold side temperature measured at 5 minutes when exposed to a 50°C hot plate test. For purposes of the embodiments described herein, the hot plate test is performed on one This was performed by preparing a 1 inch x 1 inch test specimen and placing it on a hot plate. The thermocouple is then attached to a steel weight (1 inch diameter, 2 inches high) placed on top of the test specimen. According to a specific embodiment, the second foam layer 60 8 is about 300°C or less, for example, about 275°C or less, or about 250°C or less, or about 225°C or less or about 200°C or less, or about 175°C or less, or even about 150°C or less According to yet another embodiment, the second foam layer 608 may have a viscosity of at least about 25 The cold side temperature of the second foam layer 608 may be between 0.25 and 0.5°C. It will be understood that the cold side of the second foam layer 608 can be anywhere in between. It will be further understood that the temperature can be any value between any of the above values.

[0282] According to still other embodiments, the second foam layer 608 may have a particular thickness. For example, the second foam layer 608 may be at least about 0.5 mm, e.g., at least about 1 0.0 mm, or at least about 1.5 mm, or at least about 2.0 mm, or at least About 2.5 mm, or at least about 3.0 mm, or at least about 3.5 mm, or less Both are about 4.0 mm, or at least about 4.5 mm, or even at least about 5.0 mm. According to yet another embodiment, the second foam layer 608 may have a thickness of about 10 mm or more. or less, for example, about 9.5 mm or less, or about 9.0 mm or less, or about 8.5 mm or less, or about 8.0 mm or less, or about 7.5 mm or less, or about 7.0 mm or less, or about 6.5 mm or less The thickness of the second foam layer 608 may be about 6.0 mm or less. It will be understood that the range may be between any of the minimum and maximum values ​​set forth above. The thickness of the second foam layer 608 may be any value between any of the minimum and maximum values ​​listed above. It will be further appreciated that the value may be:

[0283] According to yet another embodiment, the second foam layer 608 has a specific 25% strain compression. For purposes of the embodiments described herein, a 25% strain compression grade is: Defined as the compressive strength of a specimen measured at 25% strain, The compressive force (FTC) is determined by measuring the specimen's compressive deflection. Compressive Force Deflection (CFD) is defined as the peak force (or stress) that compresses a material to a certain strain. is the plateau maintained by the sample when held at the desired strain (i.e., 25%). The force (or stress) is defined as the relaxation force (or stress) of the specimen. Locate and record both the FTC and CFD values ​​after retraction speed and 10 grams of trigger force. Measurements are taken using a texture analyzer.

[0284] According to certain embodiments, the second foam layer 608 has a pressure of about 500 kPa or less, e.g. , about 475 kPa or less, or about 450 kPa or less, or about 425 kPa or less, or about 40 0 kPa or less, or about 375 kPa or less, or about 350 kPa or less, or about 325 kPa or less, or about 300 kPa or less, or about 275 kPa or less, or about 250 kPa or less, or is about 225 kPa or less, or about 200 kPa or less, or about 175 kPa or less, or about 15 25% strain compression at 0 kPa or less, or approximately 125 kPa or less, or approximately 100 kPa or less According to yet another embodiment, the second foam layer 608 may have a viscosity of at least about 5 kPa, for example, at least about 10 kPa, or at least about 15 kPa, or at least The second may also have a 25% strain compression rating of about 20 kPa, or at least about 25 kPa. The 25% strain compression rating of the foam layer 608 is either of the minimum and maximum values ​​set forth above. It will be appreciated that the strain of the second foam layer 608 may be within a range between 50% strain and 50% strain. It is understood that the compression rating may be any value between any of the minimum and maximum values ​​listed above. Let's understand more.

[0285] According to still other embodiments, the second foam layer 608 may have a particular density. For purposes of the embodiments described herein, the density of the second foam layer 608 is determined according to ASTM According to certain embodiments, the second foam layer 608 is approximately 1200 kg / m 3 Below, for example, about 1175 kg / m 3 or less, or about 1150k g / m 3 or less than 1125 kg / m 3 or less than 1100 kg / m 3 Below, or 105 0kg / m 3 or less than 1000 kg / m 3 or less, or 950 kg / m 3 or less, or 90 0kg / m 3 or less, or 850 kg / m 3 or less than 800 kg / m 3 or less, or 750 kg / m 3 or less than 700 kg / m 3 or less, or even 650 kg / m 3 The density of According to yet another embodiment, the second foam layer 608 may have a viscosity of at least about 10 0kg / m 3 , e.g., at least about 120 kg / m 3 , or at least about 140 kg / m 3 , or at least about 160 kg / m 3 , or at least about 180 kg / m 3 , or less At least about 200 kg / m 3 , or at least about 220 kg / m 3 , or even at least Approximately 240 kg / m3 The density of the second foam layer 608 may be at least the above minimum. It will be understood that the second form may be within a range between any of the values ​​and the maximum value. The density of the foam layer 608 may be any value between any of the minimum and maximum values ​​listed above. It will be further understood that

[0286] According to yet another embodiment, the second foam layer 608 is made of a material conforming to ASTM C518. For example, the second foam layer 608 may have a particular thermal conductivity as measured by At least about 0.01 W / mK, for example, at least about 0.02 W / mK, or at least about 0 0.03 W / mK, or at least about 0.04 W / mK, or even at least about 0.05 According to yet another embodiment, the second foam layer 608 may have a thermal conductivity of , about 0.15 W / mK or less, for example, about 0.14 W / mK or less, or about 0.13 W / mK or less or less, or about 0.12 W / mK or less, or about 0.11 W / mK or less, or about 0.10 W / mK or less, or about 0.09 W / mK or less, or about 0.08 W / mK, or even about 0.0 The thermal conductivity of the second foam layer 608 may be less than or equal to 7 W / mK. It will be understood that the second fraction may be within a range between any of the minimum and maximum values. The thermal conductivity of the foam layer 608 may be any value between any of the minimum and maximum values ​​listed above. It will be further appreciated that it may be possible.

[0287] According to certain embodiments, the thermal barrier composites described herein are According to certain embodiments, the thermal The barrier composite may be formed using a lamination process, where porous foam and The adhesive and barrier layer may be made of, for example, silicone adhesive, rubber adhesive, acrylic adhesive, phenolic adhesive, etc. Use a transfer adhesive such as a transfer adhesive, polyurethane adhesive, or any combination thereof. According to yet another embodiment, the thermal barrier composite is a laminate of a porous foam and a coating. It may be formed using a lamination process using a barrier layer, where a coating on the barrier layer Silicone adhesive, rubber adhesive, acrylic adhesive, phenolic adhesive, polyurethane In yet another embodiment, the adhesive is a polymeric adhesive, such as a polymeric adhesive, ... For example, the thermal barrier composite may be formed using a direct cast forming process, wherein The foam is cast directly onto or between the barrier films.

[0288] Many different aspects and embodiments are possible. After reading this specification, those skilled in the art will understand that these aspects and embodiments are illustrative and not restrictive. It will be understood that this is merely illustrative and does not limit the scope of the invention. The implementation may be according to any one or more of the embodiments listed below.

[0289] Embodiment 1. A first barrier layer, a silicone matrix component, and a flame-retardant filler component. and a first foam layer comprising a thermal insulating filler component, The composite material has a thickness of at least about 0.5 mm and not more than about 10 mm, and the multi-layer composite material is Multilayer composites, including HBF flammability ratings measured in accordance with STM D4986.

[0290] Embodiment 2. A first barrier layer, a silicone matrix component, and a flame-retardant filler component and a first foam layer comprising a thermal insulating filler component, The composite material has a thickness of at least about 0.5 mm and not more than about 10 mm, and the multi-layer composite material has a thickness of 6 Contains an autoignition time of at least about 1 minute when exposed to a hot plate test at 50°C. Mmm, multilayer composites.

[0291] Embodiment 3. A first barrier layer, a silicone matrix component, and a flame-retardant filler component and a first foam layer comprising a thermal insulating filler component, The barrier layer is made of mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, vermiculite durite-coated glass cloth, aerogel, nonwoven glass cloth, any combination thereof, and the like and a flame retardant filler component selected from the group consisting of a metal hydroxide, a fluorine-containing compound ... hydrates, borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, Aluminum silicate, magnesium silicate, glass frit, alkali salt, vermicular and any combination thereof, Filler components include expanded perlite, non-expanded perlite, glass beads, vermiculite, and expanded expanded vermiculite, expanded glass, zeolite, aerogel, silica, porous silica, poly a filler selected from the group consisting of porous alumina, and any combination thereof; A multilayer composite, wherein the multilayer composite comprises a thickness of at least about 0.5 mm and not more than about 10 mm. .

[0292] Embodiment 4. The silicone-based matrix component of the first foam layer is a platinum-catalyzed curing agent. Peroxide-cured silicone foam, Tin-catalyzed silicone foam and any combination thereof. Multilayer composite material.

[0293] Embodiment 5. The flame-retardant filler component of the first foam layer is selected from the group consisting of metal hydrates, borate compounds, and the like. , platinum compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, Magnesium silicate, glass frit, alkali salts, vermiculite, and any of the above. Any of embodiments 1, 2, and 3, comprising a filler selected from the group consisting of any combination of The multilayer composite material according to any one of claims 1 to 4.

[0294] Embodiment 6. The flame retardant filler component of the first foam layer is aluminum trihydrate, dihydrate Magnesium oxide, boehmite, calcium hydroxide, huntite, gypsum, hydromagnet and any combination thereof. 4. The multilayer composite material according to any one of aspects 1, 2, and 3.

[0295] Embodiment 7. The flame-retardant filler component of the first foam layer is selected from the group consisting of zinc borate, calcium borate, and the like. borate, sodium borate, potassium borate, lithium borate, and any combination thereof 4. The composition of any one of embodiments 1, 2, and 3, comprising a filler selected from the group consisting of: Multilayer composite material.

[0296] Embodiment 8. The flame-retardant filler component of the first foam layer is platinum-1,3-divinyl-1 ,1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof Any one of embodiments 1, 2, and 3, comprising a filler selected from the group consisting of a combination of The multilayer composite material according to any one of the preceding claims.

[0297] Embodiment 9. The flame-retardant filler component of the first foam layer is selected from the group consisting of iron oxide, cerium oxide, and cerium oxide. containing a filler selected from the group consisting of titanium, zinc oxide, and any combination thereof. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0298] Embodiment 10. The flame retardant filler of the first foam layer component is selected from the group consisting of huntite, calcium carbonate, and the like. and any combination thereof. 1. A multilayer composite material according to any one of claims 1 to 3.

[0299] Embodiment 11. The flame-retardant filler component of the first foam layer comprises hydromagnesite and halo. natural mixtures with pentite, synthetic magnesium hydroxide carbonate pentahydrate, and any combination thereof Any one of embodiments 1, 2, and 3, comprising a filler selected from the group consisting of a combination of The multilayer composite material according to any one of the preceding claims.

[0300] Embodiment 12. The flame-retardant filler component of the first foam layer is selected from the group consisting of wollastonite, mica, The group consisting of clay, kaolin, talc, vermiculite, and any combination thereof 4. The multilayer composite of any one of embodiments 1, 2, and 3, comprising a filler selected from Material.

[0301] Embodiment 13. The flame-retardant filler component of the first foam layer is sodium carbonate, potassium carbonate and any combination thereof. 4. The multilayer composite of any one of 1, 2, and 3.

[0302] Embodiment 14. The insulating filler component of the first foam layer is expanded perlite, non-expanded perlite. -lite, glass beads, vermiculite, expanded vermiculite, expanded glass, zeolite light, aerogel, silica, porous silica, porous alumina, and any combination thereof Any one of embodiments 1, 2, and 3, comprising a filler selected from the group consisting of The multilayer composite material according to claim 1.

[0303] Embodiment 15. The first foam layer comprises at least 4. The composition of claim 1, 2, or 3, comprising a silicone matrix component content of about 20% by weight. The multilayer composite material according to any one of claims 1 to 4.

[0304] Embodiment 16. The first foam layer has a thickness of about 85 weight percent based on the total weight of the first foam layer. % or less of a silicone-based matrix component. 10. The multilayer composite material according to claim 1.

[0305] Embodiment 17. The first foam layer has at least Any one of embodiments 1, 2, and 3, including a flame-retardant filler component content of about 1 wt. The multilayer composite material described herein.

[0306] Embodiment 18. The first foam layer has a thickness of about 35 weight percent based on the total weight of the first foam layer. 4. The multilayer coating of any one of embodiments 1, 2, and 3, comprising no more than 1% of a flame-retardant filler component. Composite material.

[0307] Embodiment 19. The first foam layer is about 25% by weight based on the total weight of the first foam layer. 4. The multilayer film of any one of embodiments 1, 2, and 3, comprising no more than 10% of an insulating filler component. Composite material.

[0308] Embodiment 20. The first foam layer comprises at least Any one of embodiments 1, 2, and 3, comprising an insulating filler component content of about 1 wt. The multilayer composite material described herein.

[0309] Embodiment 21. The first foam layer has an HB measured according to ASTM D4986 4. The multilayer composite of any one of embodiments 1, 2, and 3, comprising an F flammability rating.

[0310] Embodiment 22. A multilayer composite has a V-0 flame retardancy measured in accordance with ASTM D3801. 4. The multilayer composite of any one of embodiments 1, 2, and 3, comprising a thermal conductivity rating.

[0311] Embodiment 23. The first foam layer was exposed to a hot plate test at 650°C. Any one of embodiments 1, 2, and 3, sometimes including an autoignition time of at least about 1 minute. The multilayer composite material according to claim 1.

[0312] Embodiment 24. A multilayer structure having at least 100% porosity when exposed to a hot plate test at 650°C. 4. The multi-layer structure of any one of embodiments 1, 2, and 3, wherein each of the multi-layer structures has an autoignition time of about 1 minute. Composite material.

[0313] Embodiment 25. A multilayer composite material having at least 1000°C when exposed to a torch test. 4. The method of claim 1, wherein the burn-through time is about 6 minutes. Multilayer composite.

[0314] Embodiment 26. The first foam layer is a 3 mm thick foam that has been hot-pressed at 650 ° C. The implementation includes a low temperature of about 300°C or less measured in 5 minutes when exposed to the test. 4. The multilayer composite material according to any one of aspects 1, 2, and 3.

[0315] Embodiment 27. The first foam layer was exposed to a hot plate test at 650°C. 1, 2, and 3, wherein the cold side temperature is at least about 25° C., sometimes measured at 5 minutes. 3. A multilayer composite according to any one of claims 1 to 3.

[0316] Embodiment 28. Multilayer composite material, 3 mm foam, hot plate test at 650 ° C 1. A method for manufacturing a semiconductor device comprising: 2. A multilayer composite material according to any one of 2 and 3.

[0317] Embodiment 29. When the multilayer composite is exposed to a hot plate test at 650 ° C. Any of embodiments 1, 2, and 3, comprising a cold side temperature of at least about 25° C. measured at 5 minutes. 1. A multilayer composite material according to any one of claims 1 to 9.

[0318] Embodiment 30. An embodiment in which the first foam layer comprises a thickness of at least about 0.5 mm. 4. The multilayer composite material according to any one of aspects 1, 2, and 3.

[0319] Embodiment 31. The method of any one of embodiments 1 and 2, wherein the first foam layer has a thickness of about 10 mm or less. 3. The multilayer composite material according to any one of claims 1 to 3.

[0320] Embodiment 32. The method of embodiment 1, wherein the multilayer composite comprises a thickness of at least about 0.5 mm. 2. A multilayer composite material according to any one of 2 and 3.

[0321] Embodiment 33. The multilayer composite of embodiments 1, 2, and 3, wherein the multilayer composite comprises a thickness of about 10 mm or less. 3. A multilayer composite according to any one of claims 1 to 3.

[0322] Embodiment 34. The first foam layer has a 25% strain compression rating of at least about 5 kPa. 4. The multilayer composite of any one of embodiments 1, 2, and 3, comprising:

[0323] Embodiment 35. The first foam layer has a 25% strain compression rating of about 500 kPa or less. 4. The multilayer composite of any one of embodiments 1, 2, and 3, comprising:

[0324] Embodiment 36. The multilayer composite comprises a 25% strain compression rating of at least about 5 kPa. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0325] Embodiment 37. The multilayer composite comprises a 25% strain compression rating of about 500 kPa or less. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0326] Embodiment 38. The first foam layer has a strength of about 1200 kg / m 3 The following densities are included: 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0327] Embodiment 39. The first foam layer has a tensile strength of at least about 100 kg / m 3 Including the density of 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0328] Embodiment 40. The multilayer composite layer has a strength of about 1500 kg / m 3 Embodiments including the following densities: 4. The multilayer composite of any one of 1, 2, and 3.

[0329] Embodiment 41. The multilayer composite has a strength of at least about 100 kg / m 3 Implementation, including density 4. The multilayer composite material according to any one of aspects 1, 2, and 3.

[0330] Embodiment 42. The first foam layer has a thermal conductivity of at least about 0.01 W / mK. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0331] Embodiment 43. A thermally conductive material according to any one of the preceding embodiments, wherein the first foam layer has a thermal conductivity of about 0.15 W / mK or less. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0332] Embodiment 44. A multilayer composite comprising a thermal conductivity of at least about 0.01 W / mK. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0333] Embodiment 45. An embodiment wherein the multilayer composite comprises a thermal conductivity of about 0.15 W / mK or less. 4. The multilayer composite of any one of 1, 2, and 3.

[0334] Embodiment 46. The first barrier layer is made of mica, mica fiberglass cloth, glass cloth, silica Fabric, basalt fabric, vermiculite coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0335] Embodiment 47. The first barrier layer has a thickness of at least about 0.05 mm. 4. The multilayer composite of any one of embodiments 1, 2, and 3.

[0336] Embodiment 48. The method of any one of embodiments 1 and 2, wherein the first barrier layer has a thickness of about 7 mm or less. 3. A multilayer composite according to any one of claims 1 to 3.

[0337] Embodiment 49. The multilayer composite further comprises a second barrier layer, and the first foam layer is 4. Any one of embodiments 1, 2, and 3, wherein the first barrier layer is between the second barrier layer. The multilayer composite material described herein.

[0338] Embodiment 50. The second barrier layer is made of mica, mica fiberglass cloth, glass cloth, silica Fabric, basalt fabric, vermiculite coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof. 50. The multilayer composite of embodiment 49.

[0339] Embodiment 51. The second barrier layer has a thickness of at least about 0.05 mm. 50. The multilayer composite of claim 49.

[0340] Embodiment 52. The method of embodiment 49, wherein the second barrier layer has a thickness of about 7 mm or less. Multilayer composite material.

[0341] Embodiment 53. The multilayer composite further comprises a second foam layer and a second barrier layer, Both the first foam layer and the second foam layer are formed between the first barrier layer and the second barrier layer. 4. The multilayer composite of any one of embodiments 1, 2, and 3, wherein:

[0342] Embodiment 54. The second barrier layer is made of mica, mica fiberglass cloth, glass cloth, silica Fabric, basalt fabric, vermiculite coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof. 54. The multilayer composite of embodiment 53.

[0343] Embodiment 55. The second barrier layer has a thickness of at least about 0.05 mm. 54. The multilayer composite of claim 53.

[0344] Embodiment 56. The method of embodiment 53, wherein the second barrier layer has a thickness of about 7 mm or less. Multilayer composite material.

[0345] Embodiment 57. The silicone-based matrix component of the second foam layer is a platinum-catalyzed Cured silicone foam, peroxide cured silicone foam, tin catalyst silicone foam 54. The multilayer composite of embodiment 53, comprising: a polyimide film; ... and any combination thereof.

[0346] Embodiment 58. The flame-retardant filler component of the second foam layer is selected from the group consisting of metal hydrates, borate compounds, and the like. substances, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate , magnesium silicate, glass frit, alkali salts, vermiculite, and their 54. The multilayer composite of embodiment 53, comprising a filler selected from the group consisting of any combination. Mixture.

[0347] Embodiment 59. The flame-retardant filler component of the second foam layer is aluminum trihydrate, dihydrate. Magnesium hydroxide, boehmite, calcium hydroxide, huntite, gypsum, hydromag and any combination thereof. 54. The multilayer composite of claim 53.

[0348] Embodiment 60. The flame-retardant filler component of the second foam layer is selected from the group consisting of zinc borate, calcium borate, and the like. ammonium borate, sodium borate, potassium borate, lithium borate, and any combination thereof 54. The multilayer composite of embodiment 53, comprising a filler selected from the group consisting of:

[0349] Embodiment 61. The flame-retardant filler component of the second foam layer is platinum-1,3-divinyl- 1,1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any of these 54. The multilayer composite of embodiment 53, comprising a filler selected from the group consisting of a combination of

[0350] Embodiment 62. The flame-retardant filler component of the second foam layer is selected from the group consisting of iron oxide, cerium oxide, and acid. a filler selected from the group consisting of titanium dioxide, zinc oxide, and any combination thereof; 54. The multilayer composite of embodiment 53, comprising:

[0351] Embodiment 63. The flame-retardant filler component of the second foam layer is selected from the group consisting of huntite, calcium carbonate, and the like. and any combination thereof. 3. The multilayer composite material according to claim 3.

[0352] Embodiment 64. The flame-retardant filler component of the second foam layer is a mixture of hydromagnesite and hydroxybenzoates. natural mixtures with pentite, synthetic magnesium hydroxide carbonate pentahydrate, and any combination thereof 54. The multilayer composite of embodiment 53, comprising a filler selected from the group consisting of a fluororesin, a fluorocarbon polymer, a fluorocarbon copolymer ...

[0353] Embodiment 65. The flame-retardant filler component of the second foam layer is selected from the group consisting of wollastonite, mica, The group consisting of clay, kaolin, talc, vermiculite, and any combination thereof 54. The multilayer composite of embodiment 53, comprising a filler selected from:

[0354] Embodiment 66. The flame-retardant filler component of the second foam layer is sodium carbonate, potassium carbonate and any combination thereof. 53. A multilayer composite according to claim 53.

[0355] Embodiment 67. The insulating filler component of the second foam layer is expanded perlite, non-expanded perlite. -lite, glass beads, vermiculite, expanded vermiculite, expanded glass, zeolite light, aerogel, silica, porous silica, porous alumina, and any combination thereof 54. The multilayer composite of embodiment 53, comprising a filler selected from the group consisting of:

[0356] Embodiment 68. The second foam layer has at least 54. The multilayer of embodiment 53, comprising a silicone-based matrix component content of about 20% by weight. Composite material.

[0357] Embodiment 69. The second foam layer has a thickness of about 85 weight percent based on the total weight of the second foam layer. 54. The multilayer composite of embodiment 53, comprising a silicone-based matrix component content of no more than 100%. .

[0358] Embodiment 70. The second foam layer has at least 54. The multilayer composite of embodiment 53, comprising a flame-retardant filler component content of about 1 wt.%.

[0359] Embodiment 71. The second foam layer is about 25% by weight based on the total weight of the second foam layer. 54. The multilayer composite of embodiment 53, comprising no more than 10% of a flame-retardant filler component.

[0360] Embodiment 72. The second foam layer is about 25% by weight based on the total weight of the second foam layer. 54. The multilayer composite of embodiment 53, comprising no more than 100% of an insulating filler component.

[0361] Embodiment 73. The second foam layer comprises at least 54. The multilayer composite of embodiment 53, comprising an insulating filler component content of about 1 wt.%.

[0362] Embodiment 74. The second foam layer has an HB measured according to ASTM D4986 54. The multilayer composite of embodiment 53, comprising an F flammability rating.

[0363] Embodiment 75. The second foam layer is exposed to a hot plate test at 650°C. 54. The multilayer composite of embodiment 53, sometimes comprising an autoignition time of at least about 1 minute.

[0364] Embodiment 76. The second foam layer is exposed to a hot plate test at 650°C. 54. The multilayer of embodiment 53, comprising a cold side temperature of about 300° C. or less, sometimes measured at 5 minutes. Composite material.

[0365] Embodiment 77. The second foam layer has a thickness of at least about 0.05 mm. 54. The multilayer composite of claim 53.

[0366] Embodiment 78. The method of embodiment 53, wherein the second foam layer has a thickness of about 10 mm or less. The multilayer composite material described herein.

[0367] Embodiment 79. The second foam layer has a 25% strain compression rating of at least about 5 kPa. 54. The multilayer composite of embodiment 53, comprising:

[0368] Embodiment 80. The second foam layer has a 25% strain compression rating of about 500 kPa or less. 54. The multilayer composite of embodiment 53, comprising:

[0369] Embodiment 81. The second foam layer has a strength of about 1200 kg / m 3 The following densities are included: 54. The multilayer composite of claim 53.

[0370] Embodiment 82. The second foam layer has a foam layer strength of at least about 100 kg / m 3 of 54. The multilayer composite of embodiment 53, including, if present, density.

[0371] Embodiment 83. The second foam layer has a thermal conductivity of at least about 0.01 W / mK. 54. The multilayer composite of embodiment 53.

[0372] Embodiment 84. A thermally conductive material according to embodiment 8, wherein the second foam layer has a thermal conductivity of about 0.15 W / mK or less. 54. The multilayer composite of embodiment 53.

[0373] Embodiment 85. A first barrier layer and a silicone matrix component and a flame-retardant filler component. and a first foam layer comprising a thermal insulating filler component, The thermal barrier composite has a thickness of at least about 0.5 mm and not more than about 10 mm, The composite has a thermal barrier rating, including an HBF flammability rating measured in accordance with ASTM D4986. Composite material.

[0374] Embodiment 86. A first barrier layer and a silicone matrix component and a flame-retardant filler component. and a first foam layer comprising a thermal insulating filler component, The thermal barrier composite has a thickness of at least about 0.5 mm and not more than about 10 mm, The composite material was found to have a self-sustaining property of at least about 1 minute when exposed to a hot plate test at 650°C. Thermal barrier composites, including self-ignition times.

[0375] Embodiment 87. A first barrier layer and a silicone matrix component and a flame-retardant filler component. and a first foam layer comprising a thermal insulating filler component, The first barrier layer is made of mica, mica fiberglass cloth, glass cloth, silica cloth, basalt cloth, -miculite coated glass cloth, aerogel, nonwoven glass cloth, any combination thereof; and any laminate thereof, wherein the flame retardant filler component comprises: Metal hydrates, borate compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate um, aluminum silicate, magnesium silicate, glass frit, alkali salt, vermiculite and any combination thereof, The thermal filler component is expanded perlite, non-expanded perlite, glass beads, vermiculite expanded vermiculite, expanded glass, zeolite, aerogel, silica, porous silica a filler selected from the group consisting of kaolin, porous alumina, and any combination thereof; wherein the thermal barrier composite has a thickness of at least about 0.5 mm and not more than about 10 mm. Thermal barrier composites.

[0376] Embodiment 88. The silicone matrix component is a platinum-catalyzed addition-cure silicone for foam, peroxide-cured silicone foam, tin-catalyzed silicone foam, and any of their 88. The thermal barrier of any one of embodiments 85, 86, and 87, including any combination thereof. Composite material.

[0377] Embodiment 89. The flame-retardant filler component is selected from the group consisting of metal hydrates, borate compounds, platinum compounds, transition metal compounds, and the like. Transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate The material may be selected from rubber, glass frit, alkali salts, vermiculite, and any combination thereof. Any one of embodiments 85, 86, and 87, comprising a filler selected from the group consisting of: The thermal barrier composite described herein.

[0378] Embodiment 90. The flame-retardant filler component is aluminum trihydrate, magnesium dihydroxide , boehmite, calcium hydroxide, huntite, gypsum, hydromagnesite, and the like Embodiments 85, 86, and 87, further comprising a filler selected from the group consisting of any combination of: 87. A thermal barrier composite according to any one of claims 1 to 5.

[0379] Embodiment 91. The flame-retardant filler component is selected from the group consisting of zinc borate, calcium borate, and sodium borate. from the group consisting of ammonium borate, potassium borate, lithium borate, and any combination thereof 88. The thermal barrier of any one of embodiments 85, 86, and 87, comprising a selected filler. Composite material.

[0380] Embodiment 92. The flame-retardant filler component is platinum-1,3-divinyl-1,1,3,3-tetramethylbenzyl ether. tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof 88. Any one of embodiments 85, 86, and 87, comprising a filler selected from the group Thermal barrier composites.

[0381] Embodiment 93. The flame-retardant filler component is iron oxide, cerium oxide, titanium oxide, or zinc oxide. and any combination thereof. 88. A thermal barrier composite according to any one of claims 86, 87, and 88.

[0382] Embodiment 94. The flame-retardant filler component is selected from the group consisting of huntite, calcium carbonate, and any of the foregoing. Embodiments 85, 86, and 87, comprising a filler selected from the group consisting of any combination of 10. A thermal barrier composite according to any one of claims 1 to 9.

[0383] Embodiment 95. The flame-retardant filler component is a natural mixture of hydromagnesite and huntite. the group consisting of synthetic magnesium hydroxide carbonate pentahydrate, and any combination thereof 88. The thermal expansion coefficient of any one of embodiments 85, 86, and 87, comprising a filler selected from Barrier composite.

[0384] Embodiment 96. The flame-retardant filler component is selected from the group consisting of wollastonite, mica, clay, kaolin, and tar. a filler selected from the group consisting of quartz, vermiculite, and any combination thereof; 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising an agent.

[0385] Embodiment 97. The flame-retardant filler component is selected from the group consisting of sodium carbonate, potassium carbonate, and their derivatives. Embodiments 85, 86, and 8, comprising a filler selected from the group consisting of any combination 8. A thermal barrier composite according to any one of claims 7 to 77.

[0386] Embodiment 98. The insulating filler component is selected from the group consisting of expanded perlite, non-expanded perlite, and glass beads. Zeolite, vermiculite, expanded vermiculite, expanded glass, zeolite, aerogel , silica, porous silica, porous alumina, and any combination thereof. 88. The heat barrier of any one of embodiments 85, 86, and 87, comprising a filler selected from the group consisting of: Rear composite.

[0387] Embodiment 99. The first foam layer has at least Embodiments 85 and 86, and 87. A thermal barrier composite according to any one of claims 87 to 87.

[0388] Embodiment 100. The first foam layer has a thickness of about 85 weight percent relative to the total weight of the first foam layer. % or less of a silicone-based matrix component. 10. A thermal barrier composite according to any one of claims 1 to 9.

[0389] Embodiment 101. The first foam layer comprises at least Any of embodiments 85, 86, and 87, further comprising about 1 wt. % of a flame-retardant filler component. 10. A thermal barrier composite according to any one of claims 1 to 9.

[0390] Embodiment 102. The first foam layer has a thickness of about 35 weight percent relative to the total weight of the first foam layer. 88. The method of any one of embodiments 85, 86, and 87, comprising no more than 100% by weight of a flame-retardant filler component. Thermal barrier composite.

[0391] Embodiment 103. The first foam layer has a thickness of about 25 times the total weight of the first foam layer. 88. The method of any one of embodiments 85, 86, and 87, comprising an insulating filler component of up to 50% by weight. Thermal barrier composite.

[0392] Embodiment 104. The first foam layer comprises at least Any of embodiments 85, 86, and 87, further comprising about 1 wt. % of an insulating filler component. 10. A thermal barrier composite according to any one of claims 1 to 9.

[0393] Embodiment 105. The first foam layer has a H measured in accordance with ASTM D4986 88. The thermal barrier of any one of embodiments 85, 86, and 87, comprising a BF flammability rating. Composite material.

[0394] Embodiment 106. The thermal barrier composite has an HB measured in accordance with ASTM D4986. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising an F flammability rating. Mixture.

[0395] Embodiment 107. The first foam layer is subjected to a hot plate test at 650 ° C. 88. Any of embodiments 85, 86, and 87, wherein the self-ignition time is at least about 1 minute when The thermal barrier composite according to any one of claims 1 to 5.

[0396] Embodiment 108. A multilayer structure exhibits at least a small resistance when exposed to a hot plate test at 650 ° C. 88. The method of any one of embodiments 85, 86, and 87, including an autoignition time of at least about 1 minute. Thermal barrier composite.

[0397] Embodiment 109. When the thermal barrier composite is exposed to a torch test at 1000 ° C. Any of embodiments 85, 86, and 87, comprising a burn-through time of at least about 6 minutes. 1. A thermal barrier composite according to claim 1.

[0398] Embodiment 110. The first foam layer is a 3 mm thick foam hot pressed at 650 ° C. The test involves a low temperature of approximately 300°C or less measured in 5 minutes when exposed to a 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0399] Embodiment 111. A first foam layer is subjected to a hot plate test at 650 ° C. 85, 86, and the cold side temperature measured at 5 minutes when the 87. A thermal barrier composite according to any one of claims 1 to 86.

[0400] Embodiment 112. The thermal barrier composite is a 3 mm foam hot plate at 650 ° C. The implementation includes a low temperature of about 300°C or less measured in 5 minutes when exposed to the test. 88. The thermal barrier composite of any one of aspects 85, 86, and 87.

[0401] Embodiment 113. A thermal barrier composite is exposed to a hot plate test at 650°C. 85. Embodiments 85 and 86, which include a cold side temperature of at least about 25° C., sometimes measured at 5 minutes. and 87. A thermal barrier composite according to any one of claims 1 to 87.

[0402] Embodiment 114. The first foam layer has a thickness of at least about 0.5 mm. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0403] Embodiment 115. Embodiment 85, wherein the first foam layer comprises a thickness of about 10 mm or less. 88. A thermal barrier composite according to any one of claims 86, 87, and 88.

[0404] Embodiment 116. An embodiment in which the thermal barrier composite comprises a thickness of at least about 0.5 mm. 88. The thermal barrier composite of any one of aspects 85, 86, and 87.

[0405] Embodiment 117. Embodiment 85, wherein the thermal barrier composite comprises a thickness of about 10 mm or less. 86 and 87. A thermal barrier composite according to any one of claims 86 and 87.

[0406] Embodiment 118. The first foam layer has a compressive strength of at least about 5 kPa at 25% strain, 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising a grade.

[0407] Embodiment 119. The first foam layer has a 25% strain compression rating of about 500 kPa or less. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising:

[0408] Embodiment 120. The thermal barrier composite has a 25% strain compression rating of at least about 5 kPa. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising:

[0409] Embodiment 121. The thermal barrier composite has a 25% strain compression rating of about 500 kPa or less. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising:

[0410] Embodiment 122. The first foam layer has a strength of about 1200 kg / m 3 The following densities are included: 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0411] Embodiment 123. The first foam layer has a tensile strength of at least about 100 kg / m 3 Contains the density of 88. A thermal barrier composite according to any one of embodiments 85, 86, and 87.

[0412] Embodiment 124. The thermal barrier composite has a thermal barrier strength of about 1500 kg / m 3 The following densities are included: 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0413] Embodiment 125. The thermal barrier composite has a thermal conductivity of at least about 100 kg / m 3 Including the density of 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0414] Embodiment 126. The first foam layer has a thermal conductivity of at least about 0.01 W / mK. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, comprising:

[0415] Embodiment 127. The first foam layer comprises a thermal conductivity of about 0.15 W / mK or less. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0416] Embodiment 128. The thermal barrier composite comprises a thermal conductivity of at least about 0.01 W / mK. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0417] Embodiment 129. A thermal barrier composite comprising a thermal conductivity of about 0.15 W / mK or less. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0418] Embodiment 130. The first barrier layer is made of mica, mica fiberglass cloth, glass cloth, or silicon dioxide. woven fabric, basalt fabric, vermiculite-coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof, 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0419] Embodiment 131. A method for manufacturing a semiconductor device, wherein the first barrier layer has a thickness of at least about 0.05 mm. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87.

[0420] Embodiment 132. The method of embodiment 85, wherein the first barrier layer has a thickness of about 7 mm or less. 86 and 87. A thermal barrier composite according to any one of claims 86 and 87.

[0421] Embodiment 133. The thermal barrier composite further comprises a second barrier layer and a first foam layer. Any of embodiments 85, 86, and 87, wherein 1. A thermal barrier composite according to any one of claims 1 to 9.

[0422] Embodiment 134. The second barrier layer is made of mica, mica fiberglass cloth, glass cloth, or silicon dioxide. woven fabric, basalt fabric, vermiculite-coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof, 134. The thermal barrier composite of embodiment 133.

[0423] Embodiment 135. The second barrier layer has a thickness of at least about 0.05 mm. 134. The thermal barrier composite of embodiment 133.

[0424] Embodiment 136. The method of embodiment 133, wherein the second barrier layer has a thickness of about 7 mm or less. The thermal barrier composite according to claim 1.

[0425] Embodiment 137. The thermal barrier composite further includes a second foam layer and a second barrier layer. The first and second foam layers are both first and second barrier layers. 88. The thermal barrier composite of any one of embodiments 85, 86, and 87, between a layer .

[0426] Embodiment 138. The second barrier layer is made of mica, mica fiberglass cloth, glass cloth, or silicon dioxide. woven fabric, basalt fabric, vermiculite-coated glass fabric, aerogel, nonwoven glass fabric, and any combination thereof, and any laminate thereof, 138. The thermal barrier composite of embodiment 137.

[0427] Embodiment 139. The second barrier layer has a thickness of at least about 0.05 mm. 138. The thermal barrier composite of embodiment 137.

[0428] Embodiment 140. The method of embodiment 137, wherein the second barrier layer has a thickness of about 7 mm or less. The thermal barrier composite according to claim 1.

[0429] Embodiment 141. The silicone matrix component of the second foam layer is a platinum-catalyzed Pre-cured silicone foam, peroxide-cured silicone foam, tin-catalyzed silicone foam 138. The thermal barrier composite of embodiment 137, comprising: a glass fiber reinforced plastic; ...

[0430] Embodiment 142. The flame-retardant filler component of the second foam layer is a metal hydrate, borated compounds, platinum compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate magnesium silicate, glass frit, alkali salts, vermiculite, and 138. The thermal decomposition product of embodiment 137, comprising a filler selected from the group consisting of any combination of Barrier composite.

[0431] Embodiment 143. The flame-retardant filler component of the second foam layer comprises aluminum trihydrate, Magnesium dihydroxide, boehmite, calcium hydroxide, huntite, gypsum, hydroma and any combination thereof. 138. The thermal barrier composite of embodiment 137.

[0432] Embodiment 144. The flame-retardant filler component of the second foam layer is selected from the group consisting of zinc borate, calcium borate, and the like. Sodium borate, sodium borate, potassium borate, lithium borate, and any combination thereof 138. The thermal barrier composite of embodiment 137, comprising a filler selected from the group consisting of: .

[0433] Embodiment 145. The flame-retardant filler component of the second foam layer is platinum-1,3-divinyl -1,1,3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any of these 138. The thermal barrier of embodiment 137, comprising a filler selected from the group consisting of a combination of Composite material.

[0434] Embodiment 146. The flame-retardant filler component of the second foam layer is selected from the group consisting of iron oxide, cerium oxide, a filler selected from the group consisting of titanium oxide, zinc oxide, and any combination thereof; 138. The thermal barrier composite of embodiment 137, comprising:

[0435] Embodiment 147. The flame-retardant filler component of the second foam layer is selected from the group consisting of huntite, calcium carbonate, and the like. and any combination thereof. 137. A thermal barrier composite according to claim 137.

[0436] Embodiment 148. The flame-retardant filler component of the second foam layer comprises hydromagnesite and Natural mixture with huntite, synthetic magnesium carbonate hydroxide pentahydrate, and any of these. 138. The thermal barrier composite of embodiment 137, comprising a filler selected from the group consisting of a combination Mixture.

[0437] Embodiment 149. The flame-retardant filler component of the second foam layer is selected from the group consisting of wollastonite, mica, and the like. , clay, kaolin, talc, vermiculite, and any combination thereof 138. The thermal barrier composite of embodiment 137, comprising a filler selected from the group:

[0438] Embodiment 150. The flame-retardant filler component of the second foam layer is selected from the group consisting of sodium carbonate, calcium carbonate, and the like. and any combination thereof. 138. The thermal barrier composite according to claim 137.

[0439] Embodiment 151. The insulating filler component of the second foam layer is expanded perlite, non-expanded Perlite, glass beads, vermiculite, expanded vermiculite, expanded glass, aerogel, silica, porous silica, porous alumina, and any combination thereof 138. The thermal barrier composite of embodiment 137, comprising a filler selected from the group consisting of: Material.

[0440] Embodiment 152. The second foam layer comprises at least 138. The silicone matrix component of embodiment 137, further comprising about 20 wt. % of the silicone matrix component. Thermal barrier composites.

[0441] Embodiment 153. The second foam layer has a thickness of about 85 weight percent relative to the total weight of the second foam layer. 138. The thermal barrier of embodiment 137, comprising a silicone-based matrix component content of 0.001% or less. Composite material.

[0442] Embodiment 154. The second foam layer comprises at least 138. The thermal barrier composite of embodiment 137, comprising a flame-retardant filler component content of at most about 1 wt.%. .

[0443] Embodiment 155. The second foam layer is about 25 times the total weight of the second foam layer. 138. The thermal barrier composite of embodiment 137, comprising no more than 100% by weight of a flame-retardant filler component.

[0444] Embodiment 156. The second foam layer is about 25 times the total weight of the second foam layer. 138. The thermal barrier composite of embodiment 137, comprising an insulating filler component of up to 100 wt. %.

[0445] Embodiment 157. The second foam layer comprises at least 138. The thermal barrier composite of embodiment 137, comprising an insulating filler component content of at most about 1 wt.%. .

[0446] Embodiment 158. The second foam layer has a H measured in accordance with ASTM D4986 138. The thermal barrier composite of embodiment 137, comprising a BF flammability rating.

[0447] Embodiment 159. The second foam layer is subjected to a hot plate test at 650 ° C. 138. The thermal barrier composite of embodiment 137, comprising an autoignition time of at least about 1 minute when heated. Material.

[0448] Embodiment 160. The second foam layer is subjected to a hot plate test at 650 ° C. 138. The method of claim 137, comprising a cold side temperature of about 300° C. or less measured at 5 minutes upon heating. Thermal barrier composites.

[0449] Embodiment 161. The second foam layer has a thickness of at least about 0.5 mm. 138. The thermal barrier composite of claim 137.

[0450] Embodiment 162. The second foam layer of embodiment 13, wherein the second foam layer has a thickness of about 10 mm or less. 8. The thermal barrier composite according to claim 7.

[0451] Embodiment 163. The second foam layer has a compressive strength of at least about 5 kPa at 25% strain, etc. 138. The thermal barrier composite of embodiment 137, comprising a grade.

[0452] Embodiment 164. The second foam layer has a 25% strain compression rating of about 500 kPa or less. 138. The thermal barrier composite of embodiment 137, comprising:

[0453] Embodiment 165. The second foam layer has a strength of about 1200 kg / m 3 The following densities are included: 138. The thermal barrier composite of embodiment 137.

[0454] Embodiment 166. The second foam layer has a foam layer strength of at least about 100 kg / m 3 138. The thermal barrier composite of embodiment 137, wherein the thermal barrier composite comprises a density of

[0455] Embodiment 167. The second foam layer has a thermal conductivity of at least about 0.01 W / mK. 138. The thermal barrier composite of embodiment 137, comprising:

[0456] Embodiment 168. The second foam layer comprises a thermal conductivity of about 0.15 W / mK or less. 138. The thermal barrier composite of embodiment 137. [Example]

[0457] The concepts described herein are further illustrated in the examples below and in the claims. The invention is not intended to limit the scope of the invention described therein.

[0458] Example 1 Six sample multilayer composites S1, S2, S3, S4, S5, and S6 are described herein. For comparison with sample multilayer composites S1 to S6, one comparative The sample multilayer composite CS1 was formed. The multilayer composites S1 to S6 and the comparative sample multilayer composite CS The construction and composition of 1 are summarized in Table 1 below.

[0459] [Table 1]

[0460] The performance grades of the sample multilayer composites S1 to S6 and the comparative sample multilayer composite CS1 (i.e., Flammability ratings, self-ignition time, burn-through time, and cold side temperature are summarized in Table 2 below. The flame resistance rating is based on the performance of the specimen in the UL94 V0 test, and the self-ignition time is Burn-through time was measured in the 650°C hot plate test described herein. , measured in the 1000°C torch test described herein, and the cold side temperature is It will be understood that the results are measured in a 650°C hot plate test as described in

[0461] [Table 2]

[0462] Not all of the activities described above are required in the general description or examples. Some specific activities may not be required, and one or more activities in addition to those described may be required. Note that further actions may be performed. Still further, the order in which the actions are listed is , not necessarily the order in which they are performed.

[0463] Benefits, other advantages, and solutions to problems have been described above with regard to specific embodiments. However, benefits, advantages, solutions to problems, and any benefits, advantages, or solutions that Any feature that may render the invention less or more prominent may be included in any or all of the claims. They should not be construed as necessary or essential features.

[0464] The specification and illustrations of the embodiments set forth herein are provided to provide a general understanding of the structure of the various embodiments. The specification and illustrations are intended to provide a solution to the problems of the structures or methods described herein. Serves as a comprehensive and comprehensive description of all elements and features of the equipment and systems used It is not intended that separate embodiments be provided in combination in a single embodiment. Conversely, various features that are described in the context of a single embodiment for brevity may be combined. may be provided separately or in any subcombination. Reference includes each and every value within that range. Many other embodiments may be apparent to those skilled in the art after reading this specification. Structural substitutions, logical substitutions, and other variations may be made without departing from the scope of this disclosure. Other embodiments may be used and may be derived from this disclosure, as may logical substitutions or other modifications. Accordingly, the present disclosure is to be regarded as illustrative and not restrictive. It should be.

Claims

1. 1. A multilayer composite material comprising: a first barrier layer; and A first composition including a silicone matrix component, a flame-retardant filler component, and a heat-insulating filler component. a foam layer; the multilayer composite comprises a thickness of at least about 0.5 mm and not more than about 10 mm; The multilayer composite has an HBF flammability rating measured in accordance with ASTM D4986. Multilayer composites, including:

2. 1. A multilayer composite material comprising: a first barrier layer; and A first composition including a silicone matrix component, a flame-retardant filler component, and a heat-insulating filler component. a foam layer; the multilayer composite comprises a thickness of at least about 0.5 mm and not more than about 10 mm; The multilayer composite exhibits at least A multi-layer composite material with a self-ignition time of approximately 1 minute.

3. The silicone matrix component of the first foam layer is a platinum-catalyzed addition cure silicone. Silicone foam, peroxide cured silicone foam, tin catalyst silicone foam, and 3. The multilayer composite of claim 1 or 2, comprising:

4. The flame-retardant filler component of the first foam layer may comprise a metal hydrate, a borate compound, a white Gold compounds, transition metal oxides, metal carbonates, calcium silicate, aluminum silicate, silica magnesium oxide, glass frit, alkali salt, vermiculite, and any of these 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of a combination of 。

5. The flame retardant filler component of the first foam layer is aluminum trihydrate, dihydroxide Magnesium, boehmite, calcium hydroxide, huntite, gypsum, hydromagnesium 10. The method of claim 1, further comprising the step of:

2. A multilayer composite material according to claim 2.

6. the flame-retardant filler component of the first foam layer is selected from the group consisting of zinc borate, calcium borate, Sodium borate, potassium borate, lithium borate, and any combination thereof 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of:

7. The flame retardant filler component of the first foam layer is platinum-1,3-divinyl-1,1 , 3,3-tetramethyldisiloxane, hexachloroplatinic acid, and any combination thereof 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of:

8. The flame retardant filler component of the first foam layer may be selected from the group consisting of iron oxide, cerium oxide, titanium oxide, and the like. a filler selected from the group consisting of methacrylate, zinc oxide, and any combination thereof; 3. A multilayer composite according to claim 1 or 2.

9. The flame-retardant filler of the first foam layer component is selected from the group consisting of huntite, calcium carbonate, and and any combination thereof. The multilayer composite material described herein.

10. The flame-retardant filler component of the first foam layer is composed of hydromagnesite and hantaite. natural mixture with magnesium carbonate, synthetic magnesium hydroxide pentahydrate, and any combination thereof 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of:

11. The flame retardant filler component of the first foam layer may be selected from the group consisting of wollastonite, mica, clay, Selected from the group consisting of kaolin, talc, vermiculite, and any combination thereof 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of hydroxybenzoates, ...

12. The flame retardant filler component of the first foam layer may comprise sodium carbonate, potassium carbonate, and any combination thereof. The multilayer composite material according to claim 1.

13. The insulating filler component of the first foam layer may be expanded perlite, non-expanded perlite, or glass beads, vermiculite, expanded vermiculite, expanded glass, zeolite , aerogel, silica, porous silica, porous alumina, and any combination thereof 3. The multilayer composite of claim 1 or 2, comprising a filler selected from the group consisting of:

14. 1. A thermal barrier composite comprising: a first barrier layer; and A first composition including a silicone matrix component, a flame-retardant filler component, and a heat-insulating filler component. a foam layer; The thermal barrier composite has a thickness of at least about 0.5 mm and not more than about 10 mm. fruit, The thermal barrier composite has a HBF flammability measured in accordance with ASTM D4986, Thermal barrier composites, including grades.

15. The flame-retardant filler component is selected from the group consisting of metal hydrates, borate compounds, platinum compounds, transition metal oxides, and the like. substances, metal carbonates, calcium silicate, aluminum silicate, magnesium silicate, glass frit, alkali salt, vermiculite, and any combination thereof.

15. The thermal barrier composite of claim 14, comprising a filler selected from the group consisting of:

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