Positive electrode active material for lithium secondary batteries, method for manufacturing the same, and lithium secondary battery containing the same

A nickel-containing lithium transition metal oxide with an Al and W coating layer addresses the issues of conventional NCM-based materials, enhancing capacity and high-temperature life by optimizing composition and particle strength in lithium secondary batteries.

JP2026516520APending Publication Date: 2026-05-25POSCO FUTURE M CO LTD
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Patent Information

Authority / Receiving Office
JP Ā· JP
Patent Type
Applications
Current Assignee / Owner
POSCO FUTURE M CO LTD
Filing Date
2024-05-23
Publication Date
2026-05-25

AI Technical Summary

Technical Problem

Conventional NCM-based lithium composite transition metal oxides for lithium secondary batteries have large specific surface areas, low particle strength, high lithium by-product content, leading to gas generation, reduced lifespan, and stability issues, while single-particle cathode active materials suffer from larger crystal grain size and degraded capacitance characteristics.

Method used

A positive electrode active material in the form of a single particle, composed of a nickel-containing lithium transition metal oxide with an Al and W-containing coating layer, where Al and W content ranges from 2000 to 6000 ppm, with a ratio of 0.28 to 0.7, and a composition of nickel, cobalt, and manganese optimized to improve capacity and high-temperature life characteristics.

Benefits of technology

The solution results in improved capacity, high-temperature life, and stability of lithium secondary batteries by reducing gas generation and enhancing particle strength, with a compressed density of 2.2 g/cc and low residual lithium content, thereby increasing energy density and lifespan.

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Abstract

The present invention relates to a positive electrode active material for lithium secondary batteries in the form of a single particle, comprising a nickel-containing lithium transition metal oxide and an Al and W-containing coating layer disposed on the surface of the lithium transition metal oxide, wherein the total content of Al and W is 2000 to 6000 ppm based on the total weight of the positive electrode active material.
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