Method for recovering positive electrode active material

Abstract

To provide a method for recovering a positive electrode active material in which quality of the recovered positive electrode active material is good and productivity is high.SOLUTION: A method for recovering a positive electrode active material from a battery having a positive electrode plate in which a positive electrode mixture containing a positive electrode active material is laminated on a positive electrode foil includes a step of separating and recovering the positive electrode mixture from the positive electrode plate and supplying at least one of ozone and hydrogen peroxide to a slurry containing the positive electrode mixture to oxidize the positive electrode mixture.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a method for recovering positive electrode active material particles from a battery. [Background technology]

[0002] Patent Document 1 discloses a method in which a positive electrode active material layer on a current collector foil is transferred to an adhesive tape, and then the positive electrode active material particles are recovered using a solvent. Patent Document 2 discloses a method for recovering lithium from a LiFePO4-containing portion. More specifically, the LiFePO4-containing portion is treated with an acid solution in the presence of an oxidizing agent, and the dissolved lithium ions are separated and precipitated as a salt from the lithium-containing solution. It is described that the hydrometallurgical post-treatment is carried out at a temperature range of 80°C to 120°C using dilute sulfuric acid, and by introducing oxygen or ozone or adding hydrogen peroxide. Patent Document 3 discloses a method in which an electrode is immersed in an acid solution to separate the current collector from the active material, and valuable metals are recovered. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2014-203567 A [Patent Document 2] WO2012 / 072619 [Patent Document 3] Japanese Patent Application Publication No. 11-097076 Summary of the Invention [Problem to be solved by the invention]

[0004] However, according to the conventional techniques such as Patent Document 1, a large amount of carbon components such as dispersants and binders adhere to the surface of the recovered positive electrode active material, and it is not possible to recover a positive electrode active material having the same crystallinity as a new positive electrode active material. More specifically, when a lithium-ion secondary battery is charged and discharged, a film of phosphorus (P) and fluorine (F) compounds derived from salts and additives in the electrolyte is formed on the positive electrode active material, and this film remains on the recovered positive electrode active material.

[0005] In addition, there are techniques for removing binders that involve using large amounts of organic solvents or exposing the material to special high-pressure environments, but these are unsuitable (high cost) for industrial mass production, and recent life cycle assessment (LCA) calculations have shown that these methods emit large amounts of CO2.

[0006] Therefore, an object of the present disclosure is to provide a method for recovering a positive electrode active material, which allows the recovered positive electrode active material to be of good quality and is highly productive. [Means for solving the problem]

[0007] The present application discloses a method for recovering a positive electrode active material from a battery having a positive electrode plate in which a positive electrode mixture containing a positive electrode active material is laminated on a positive electrode foil, the method including a step of separating and recovering the positive electrode mixture from the positive electrode plate, and supplying at least one of ozone and hydrogen peroxide to a slurry containing the positive electrode mixture to oxidize the positive electrode mixture.

[0008] In the oxidation step, the slurry can be controlled to have a pH greater than 9.

[0009] The ozone may be supplied by bubbling. Effect of the Invention

[0010] According to the present disclosure, it is possible to provide a method for recovering a positive electrode active material with high productivity and with which the recovered positive electrode active material is of good quality. [Brief description of the drawings]

[0011] [Figure 1] FIG. 1 is a diagram illustrating the flow of the positive electrode active material recovery method S10. [Diagram 2] FIG. 2 is a diagram illustrating the difference in the positive electrode active material obtained with or without the oxidative decomposition step. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0012] 1.Battery The subject of the positive electrode active material recovery method of the present disclosure is a battery (secondary battery), for example, a sealed nonaqueous electrolyte secondary battery or an all-solid-state battery mounted on vehicles such as hybrid cars and electric cars, specifically a lithium ion secondary battery. The form of the battery is not particularly limited and is as known, but here, a sealed nonaqueous electrolyte secondary battery is taken as an example, having the following configuration. The battery is composed of a rectangular parallelepiped exterior case, a flat wound electrode assembly housed in the exterior case, and a positive electrode terminal member and a negative electrode terminal member supported by the exterior case, etc. A non-aqueous electrolyte is held in the exterior case.

[0013] The electrode body is formed by stacking a band-shaped positive electrode plate and a band-shaped negative electrode plate with a pair of band-shaped separators made of porous resin between them, winding them around an axis, and compressing them into a flat shape. The positive electrode plate has a strip-shaped positive electrode foil made of aluminum as a core material. A porous positive electrode active material layer is formed on a part of the front and back surfaces of this positive electrode foil. This positive electrode active material layer is composed of a positive electrode mixture formed from positive electrode active material particles, conductive material particles, and a binder. In this embodiment, lithium-cobalt-nickel-manganese composite oxide particles can be used as the positive electrode active material particles, acetylene black (AB) particles can be used as the conductive material, and polyvinylidene fluoride (PVdF) can be used as the binder. The negative electrode plate has a strip-shaped negative electrode foil made of copper as a core material. A porous negative electrode active material layer is formed on the front and back sides of this negative electrode foil. This negative electrode active material layer is composed of a negative electrode mixture formed from negative electrode active material particles, a binder, and a thickener. In this embodiment, natural graphite particles can be used as the negative electrode active material particles, styrene butadiene rubber (SBR) can be used as the binder, and carboxymethyl cellulose (CMC) can be used as the thickener.

[0014] 2. Recovery method of positive electrode active material The method for recovering a positive electrode active material according to the present disclosure recovers the positive electrode active material from such a battery. Fig. 1 shows a flow of a method for recovering a positive electrode active material S10 according to one embodiment. As can be seen from Fig. 1, the method for recovering a positive electrode active material S10 according to this embodiment includes steps S11 to S20. Each step will be described below.

[0015] 2.1.Dismantling process S11 (process S11) The dismantling process S11 is a process for dismantling the discharged batteries. Specifically, the batteries are put into a crusher (shredder) and pulverized. There are no particular limitations on the degree of pulverization, and the optimal particle size differs depending on the separation method used in the next process, but it is generally recommended to pulverize the batteries to a size of 500 mm or less. 2 Less than 100mm, preferably 2 If the particles are too large, they will be collected as a composite material, which reduces the collection rate, and if the particles are too small, the finely divided components with a high specific gravity will be mixed in during air flow separation, which may reduce the quality of the collected material.

[0016] 2.2. Separation process S12 (process S12) The separation process S12 is a process of removing heavy components (exterior case, positive electrode terminal member, and negative electrode terminal member) and light components (separator, insulating film) from the battery miniaturized in the disassembly process S11, and separating and obtaining positive and negative electrode plates. The method of separation is not particularly limited, but examples thereof include air flow separation in the case of a dry method and gravity separation using a liquid in the case of a wet method.

[0017] 2.3.Dissolution process S13 (process S13) The dissolving step S13 is a step of immersing the positive and negative electrode plates separated and obtained in the separating step S12 in an NaOH aqueous solution having a pH of 10 or more. This dissolves the aluminum foil (positive electrode foil) and separates the positive electrode mixture from the positive electrode plate to form a slurry. Therefore, the dissolving step S13 produces a mixture containing the finely divided negative electrode plate and the slurried positive electrode mixture.

[0018] Although an aqueous NaOH solution was used here, LiOH can be used instead. However, if LiOH is used, it is necessary to separately remove Al ions from the waste liquid after step S15 (cleaning step S15) described later.

[0019] 2.4. Positive electrode composite slurry recovery process S14 (process S14) In the positive electrode composite slurry recovery step S14, a slurry containing the positive electrode composite is separated and recovered from the mixture obtained in the dissolving step S13. Specifically, the negative electrode plates and other undissolved aggregates are separated and removed from the slurry by coarse filtration using a filter with an opening size of 100 μm to 1000 μm or by gravity separation, and the positive electrode composite slurry is recovered.

[0020] 2.5. Cleaning step S15 (step S15) The washing step S15 is a step of filtering the positive electrode mixture slurry obtained in the positive electrode mixture slurry recovery step S14 using filter paper with a pore size of 1 μm (No. 5C) to recover the positive electrode mixture as a solid content. After that, the obtained positive electrode mixture is washed with water to wash away the Na ions and Al ions attached to the positive electrode mixture. However, it is preferable not to wash with water excessively because Li ions are also washed away from the positive electrode mixture during this washing. In this case, it is preferable to wash with water with an NV (nonvolatile) value of about 50 mass%. The "NV value" indicates the mass ratio of components other than the dispersion medium.

[0021] 2.6. Slurrying step S16 (step S16) The slurrying step S16 is a step of reslurrying the positive electrode mixture (solid) obtained in the washing step S15. Specifically, the positive electrode mixture is added to water to which 0.1 mol or more of a base has been added. An example of the base is LiOH. In this case, the NV (nonvolatile) value of the slurry is preferably about 50 mass%. The "NV value" indicates the mass ratio of components other than the dispersion medium.

[0022] 2.7. Oxidative decomposition step S17 (step S17) The oxidative decomposition step S17 is a step of applying an oxidation means to the slurry obtained in the slurrying step S16. Specifically, at least one of oxidation by supplying ozone and oxidation by supplying hydrogen peroxide can be mentioned. Ozone (O3) is supplied from an ozone generator while stirring the slurry. Hydrogen peroxide is added to the slurry. When ozone is supplied, hydrogen peroxide is generated by the reaction of ozone and water, so the supply of ozone and hydrogen peroxide is parallel.

[0023] In a lithium-ion secondary battery that has been charged and discharged, as described above, the positive electrode active material is covered with a coating of phosphorus (P), fluorine (F) compounds derived from the salts and additives in the electrolyte, and carbon (C) compounds such as binders. Even if this is placed in an oxidizing atmosphere (baked) at 900°C or higher, it remains without volatilizing. In contrast, as in this embodiment, by placing the slurried positive electrode mixture in an oxidizing environment under wet conditions (in water), the coating components are directly oxidized and deteriorated (oxidatively decomposed), and some of them are ionized, dissolving in water and being separated from the positive electrode active material.

[0024] In this step, the oxidation of the slurry advances as the oxidation advances, and from the viewpoint of avoiding deterioration and dissolution of the positive electrode active material itself due to this, it is preferable to keep the pH in a range greater than 9. A more preferable pH is 10 or less. A specific method for achieving this is not particularly limited, but can be achieved by adjusting the supply amounts of ozone and hydrogen peroxide. In particular, when ozone is supplied, the ozone reacts with water in the aqueous solution during ozone aeration, generating some hydrogen peroxide, causing the pH of the slurry to continue to drop, turning the solution into an acidic solution, which may cause deterioration of the positive electrode active material, so that deterioration (dissolution) of the positive electrode active material can be suppressed by controlling the pH so that it does not become 9 or lower. Therefore, it is preferable that ozone is continuously supplied by bubbling from an ozone generator into the slurry, and the supply amount is adjusted to control the pH. This makes it possible to remove the coating component and the carbon component while suppressing the deterioration and dissolution of the positive electrode active material.

[0025] 2.8. Positive electrode active material recovery step S18 (step S18) The positive electrode active material recovery step S18 is a step of separating and recovering the positive electrode active material from the slurry after the oxidative decomposition step S17. The separation is performed by, for example, filtration, and filter paper with a pore size of 1 μm (No. 5C) can be used for this purpose. The positive electrode active material obtained in this step does not need to be washed with water.

[0026] 2.9. Drying process S19 (process S19) The drying step S19 is a step of removing moisture from the positive electrode active material obtained in the positive electrode active material recovery step S18 and drying it. The drying method is not particularly limited, and examples of the drying method include drying by airflow and vacuum drying.

[0027] 2.10.Li supply process S20 (process S20) The Li replenishing step S20 is a step of replenishing Li when the positive electrode active material obtained by the above-mentioned recovery of the positive electrode active material is deficient in Li. Therefore, in this step, the composition of the positive electrode active material obtained in the drying step S19 is quantified by ICP analysis, and Li is replenished if it is insufficient. As a means for replenishing, for example, lithium carbonate (Li2CO3) or lithium hydroxide (LiOH) is mixed with the obtained positive electrode active material, and the mixture is fired in an electric furnace at a predetermined temperature of 600°C to 1000°C for several hours. The composition of the positive electrode active material obtained after firing is then confirmed again by ICP analysis, and the crystal structure is confirmed by XRD to make it a reusable positive electrode active material.

[0028] Figure 2 shows the XRD measurement results (104 plane) of the positive electrode active material after Li was replenished by this process. No. 1 and No. 2 shown by solid lines are examples of the recovery method S10 of the present disclosure described above (ozone was supplied in the oxidative decomposition process S17). For comparison, a new positive electrode active material is shown by a dashed line as "Ref", and "C1" and "C2" are shown by dashed lines as examples in which the oxidative decomposition process S17 was not performed. The horizontal axis is the diffraction angle 2θ, and the vertical axis is the X-ray diffraction intensity.

[0029] 2, the positive electrode active materials (No. 1 and No. 2) recovered by the recovery method of the present disclosure have recovered crystallinity (same X-ray diffraction intensity) to the same level as that of a new positive electrode active material (Ref.). In contrast, in the case where the oxidative decomposition step S17 was not performed, the crystallinity could not be recovered.

[0030] 3. Effects etc. According to the present disclosure, recycled positive electrode active materials can be obtained with such good quality (crystal structure similar to that of new materials) that they can be used directly in batteries. In addition, since the process does not require a reaction chamber under a special environment such as an autoclave, the equipment is simple, costs can be reduced, and productivity is high.

[0031] Furthermore, the present disclosure does not require the use of solvents, which require a lot of work to manage safety and disposal, and does not require the removal of the substance that covers the positive electrode active material by burning it, which significantly reduces CO2 emissions, making it advantageous from an environmental standpoint.

[0032] In addition, when considering recycling the positive electrode active material, there are three types of recycling: (1) recycling to obtain metal bullion from recovered batteries, (2) recycling to obtain compounds that serve as raw materials for the positive electrode active material, such as metal sulfates, and (3) recycling to directly obtain the positive electrode active material. (1) and (2) require further processing of the material obtained by recycling to produce the positive electrode active material, which generates additional CO2 in the process. In contrast, in the present disclosure, the positive electrode active material can be obtained directly as in (3), which also makes it possible to suppress CO2 emissions from this perspective. [Explanation of symbols]

[0033] S10 Method for recovering positive electrode active material S11 Demolition process S12 Separation process S13 Melting process S14 Mixture slurry recovery process S15 Cleaning process S16 Slurry process S17 Oxidative decomposition process S18 Positive electrode active material recovery process S19 Drying process S20 Li replenishment process

Claims

1. A method for recovering a positive electrode active material from a battery having a positive electrode plate in which a positive electrode mixture containing a positive electrode active material is laminated on a positive electrode foil, comprising: Separating and recovering a positive electrode mixture from the positive electrode plate; supplying at least one of ozone and hydrogen peroxide to a slurry containing the positive electrode mixture to oxidize the positive electrode mixture, thereby obtaining a slurry of the positive electrode active material; In the step, the pH of the slurry containing the positive electrode mixture is controlled to be greater than 9. A method for recovering positive electrode active material.

2. 2. The method for recovering a positive electrode active material according to claim 1, wherein the ozone is supplied by bubbling.

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