Lubricating oil composition

Abstract

To provide a lubricant oil composition with excellent abrasion resistance in a soot contaminated state.SOLUTION: A lubricant oil composition contains a base oil (A) and a dispersed viscosity index improver (B). A nitrogen atom content in terms of a solid basis of the dispersed viscosity index improver (B) is 0.50 to 1.50 mass%, a weight-average molecular weight (Mw) of the dispersed viscosity index improver (B) is 100,000 or more, and a content in terms of a solid basis of the dispersed viscosity index improver (B) on the whole composition basis is more than 0.05 mass% and less than 5.0 mass%.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a lubricating oil composition. [Background technology]

[0002] It has been known for some time that lubricating oils used in internal combustion engines such as gasoline engines and diesel engines have the problem of soot generation as the lubricating oil deteriorates. In order to disperse soot in the oil, dispersants are sometimes added.

[0003] In addition, viscosity index improvers are sometimes blended into lubricating oil compositions for the purpose of improving the viscosity index, and dispersant-type viscosity index improvers that are imparted with dispersant properties using comonomers having polar groups are also known. Known examples of such dispersant-type viscosity index improvers include those having nitrogen atoms in the molecule. For example, Patent Document 1 discloses a reaction product of an olefin copolymer, an acylating agent, and a polyamine, and Patent Document 2 discloses a dispersant-type polyalkyl(meth)acrylate obtained by copolymerizing an N-dispersant monomer. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2019-77864 A [Patent Document 2] Special Publication No. 2016-534213 Summary of the Invention [Problem to be solved by the invention]

[0005] However, as a result of investigations conducted by the present inventors, it was found that when lubricating oil containing soot is used, the wear resistance is not necessarily good. The present invention has been made in view of the above problems, and an object of the present invention is to provide a lubricating oil composition which has excellent wear resistance even when soot is mixed in. [Means for solving the problem]

[0006] As a result of extensive investigations, the present inventors have found that the above problems can be solved by a lubricating oil composition containing a specific dispersant-type viscosity index improver, and have completed the present invention.

[0007] That is, the present invention provides the following [1]. [1] A lubricating oil composition comprising a base oil (A) and a dispersant type viscosity index improver (B), wherein the dispersant type viscosity index improver (B) has a nitrogen atom content of 0.50 to 1.50 mass% based on the solid content and a weight average molecular weight (Mw) of 100,000 or more, and the content of the dispersant type viscosity index improver (B) in terms of solid content based on the total amount of the composition is more than 0.05 mass% and less than 5.0 mass%. [2] A method for producing a lubricating oil composition according to [1], comprising the step of mixing the base oil (A) and the dispersant-type viscosity index improver (B). [3] A diesel engine comprising the lubricating oil composition according to [1]. [4] A method for lubricating an engine, comprising using the lubricating oil composition according to [1]. Effect of the Invention

[0008] According to the present invention, it is possible to provide a lubricating oil composition that has excellent wear resistance even when soot is present. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] The upper and lower limit values ​​of the numerical ranges described in this specification can be combined in any way. For example, when "A to B" and "C to D" are described as numerical ranges, the numerical ranges "A to D" and "C to B" are also included in the scope of the present invention. In addition, unless otherwise specified, a numerical range of "lower limit value to upper limit value" described in this specification means not less than the lower limit value and not more than the upper limit value. In this specification, the numerical values ​​in the examples are numerical values ​​that can be used as upper or lower limits. In this specification, for example, "(meth)acrylate" is used as a term indicating both "acrylate" and "methacrylate", and the same applies to other similar terms and similar labels.

[0010] [Lubricating oil composition] The lubricating oil composition of this embodiment is a lubricating oil composition containing a base oil (A) and a dispersant type viscosity index improver (B), wherein the nitrogen atom content of the dispersant type viscosity index improver (B) is 0.50 to 1.50 mass%, the weight average molecular weight (Mw) is 100,000 or more, and the content of the dispersant type viscosity index improver (B) in terms of solids content based on the total amount of the composition is more than 0.05 mass% and less than 5.0 mass%.

[0011] As a result of intensive research by the inventors to solve the above-mentioned problems, it was found that soot dispersed by a dispersant wears away the lubricating coating formed on the surface of a metal component, thereby deteriorating the wear resistance. Furthermore, the inventors discovered that even when a dispersant-type viscosity index improver is used, wear resistance does not necessarily improve depending on the type of the agent, and that by blending a predetermined amount of a dispersant-type viscosity index improver having a specific nitrogen atom content and weight-average molecular weight, wear resistance between metal components in an environment where soot is present can be improved, which led to the completion of the present invention.

[0012] Each component contained in the lubricating oil composition of this embodiment will be described below.

[0013] <Base oil (A)> The lubricating oil composition of the present embodiment contains a base oil (A). As the base oil (A), one or more types selected from mineral oils and synthetic oils conventionally used as base oils for lubricating oils can be used without any particular limitation.

[0014] Examples of the mineral oil include atmospheric residual oil obtained by atmospheric distillation of crude oil such as paraffin-based crude oil, intermediate-based crude oil, naphthene-based crude oil, etc.; lubricating oil fraction obtained by vacuum distillation of the atmospheric residual oil; and mineral oil obtained by subjecting the lubricating oil fraction to one or more refining treatments such as solvent deasphalting, solvent extraction, hydrofinishing, hydrocracking, advanced hydrocracking, solvent dewaxing, catalytic dewaxing, and hydroisomerization dewaxing.

[0015] Examples of the synthetic oils include poly-α-olefins such as α-olefin homopolymers and α-olefin copolymers (for example, α-olefin copolymers having 8 to 14 carbon atoms, such as ethylene-α-olefin copolymers); isoparaffins; various esters such as polyol esters and dibasic acid esters; various ethers such as polyphenyl ether; polyalkylene glycols; alkylbenzenes; alkylnaphthalenes; and GTL base oils obtained by isomerizing wax produced from natural gas by the Fischer-Tropsch process or the like (GTL wax, Gas To Liquids WAX).

[0016] The base oil (A) used in this embodiment is preferably a base oil classified as Group II or III of the base oil category of API (American Petroleum Institute), more preferably a base oil classified as Group III.

[0017] As the base oil (A), one type selected from mineral oils may be used alone or two or more types may be used in combination. Also, one type selected from synthetic oils may be used alone or two or more types may be used in combination. Furthermore, one or more types of mineral oils may be used in combination with one or more types of synthetic oils.

[0018] The kinematic viscosity and viscosity index of the base oil (A) are preferably in the following ranges, with the upper limit being from the viewpoint of achieving good fuel economy, and the lower limit being from the viewpoint of reducing loss of the lubricating oil composition due to evaporation and ensuring oil film retention. The base oil (A) has a kinematic viscosity at 100°C of 2.0mm 2 / s or more is preferable, and 20.0 mm 2 / s or less is preferable, and 10.0 mm2 / s or less is preferable, and 8.0 mm 2 / s or less is more preferable, and 7.0 mm 2 The upper and lower limits of these numerical ranges can be arbitrarily combined. Specifically, 2.0 mm 2 / s~20.0mm 2 / s is preferred, 2.0 mm 2 / s~10.0mm 2 / s is more preferable, 2.0 mm 2 / s~8.0mm 2 / s is more preferable, and 2.0 mm 2 / s~7.0mm 2 / s is even more preferred. The viscosity index of the base oil (A) is preferably 80 or more, more preferably 90 or more, even more preferably 100 or more, even more preferably 105 or more, and even more preferably 120 or more. The 40° C. kinematic viscosity, the 100° C. kinematic viscosity, and the viscosity index can be measured or calculated in accordance with JIS K 2283:2000. When the base oil (A) is a mixed base oil containing two or more kinds of base oils, the kinematic viscosity and viscosity index of the mixed base oil preferably fall within the above ranges.

[0019] In the lubricating oil composition of the present embodiment, the content of the base oil (A) is not particularly limited, but from the viewpoint of making it easier to exhibit the effects of the present invention, it is preferably 60 mass% to 99 mass%, more preferably 70 mass% to 95 mass%, and even more preferably 80 mass% to 93 mass%, based on the total amount (100 mass%) of the lubricating oil composition.

[0020] <Dispersant type viscosity index improver (B)> The dispersant type viscosity index improver (B) used in the lubricating oil composition of this embodiment must have a nitrogen atom content of 0.50 to 1.50 mass% based on the solid content of the dispersant type viscosity index improver (B). If the nitrogen atom content of the dispersant type viscosity index improver (B) is less than 0.50 mass% or exceeds 1.50 mass%, the wear resistance improving effect is not achieved. The nitrogen atom content of the dispersant type viscosity index improver (B) is preferably 0.55 mass% or more, more preferably 0.60 mass% or more, even more preferably 0.65 mass% or more, and is preferably 1.45 mass% or less, more preferably 1.40 mass% or less, even more preferably 1.30 mass% or less. The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, it is preferably 0.55 to 1.45 mass%, more preferably 0.60 to 1.40 mass%, even more preferably 0.65 to 1.30 mass%.

[0021] In addition, the dispersion type viscosity index improver (B) must have a weight average molecular weight (Mw) of 100,000 or more, and if the weight average molecular weight (Mw) of the dispersion type viscosity index improver (B) is less than 100,000, soot will penetrate into the lubricated surface and wear away the coating on the lubricated surface, so the wear resistance improving effect of this embodiment will not be achieved. In addition, the weight average molecular weight (Mw) of the dispersion type viscosity index improver (B) is preferably 400,000 or less, more preferably 300,000 or less, and even more preferably 250,000 or less from the viewpoint of improving wear resistance. Furthermore, from the viewpoint of improving the wear resistance of the lubricated surface, the molecular weight distribution (Mw / Mn) of the dispersant type viscosity index improver (B) is preferably 3.0 or less, more preferably 2.8 or less, and even more preferably 2.6 or less. In this specification, the weight average molecular weight (Mw) and number average molecular weight (Mn) of each component are values ​​calculated as standard polystyrene measured by gel permeation chromatography (GPC).

[0022] As the dispersant-type viscosity index improver (B), nitrogen-containing poly(meth)acrylates and nitrogen-containing polyolefins are preferably used.

[0023] (Nitrogen-containing poly(meth)acrylate) Specific examples of the nitrogen-containing poly(meth)acrylate include methacrylic acid ester copolymers obtained by copolymerizing a (meth)acrylic acid ester not containing a nitrogen atom with a nitrogen-containing comonomer, and hydrogenated products thereof. Specific examples of the nitrogen atom-containing comonomer include nitrogen atom-containing vinyl compounds and nitrogen atom-containing (meth)acrylic acid esters. Nitrogen atom-containing vinyl compounds include lactams having vinyl groups, specifically N-vinyl-2-pyrrolidone. Nitrogen atom-containing (meth)acrylic acid esters include aminoalkyl (meth)acrylates, and specific examples of aminoalkyl (meth)acrylates include ethylaminoethyl (meth)acrylate.

[0024] (Nitrogen-containing polyolefin) Further, the nitrogen-containing polyolefin may also include a nitrogen-containing olefin copolymer which is a reaction product of an olefin copolymer, an acylating agent, and a polyamine, and a hydrogenated product thereof.

[0025] As the olefin copolymer, a copolymer of ethylene and an α-olefin having 3 to 28 carbon atoms is preferable, and an ethylene-propylene copolymer is particularly preferable. Specific examples of the olefin include ethylene, propylene, 1-butene, 2-butene, isobutene, 3-methyl-1-butene, 4-phenyl-1-butene, 1-pentene, 3-methyl-1-pentene, 4-methyl-1-pentene, 3,3-dimethyl-1-pentene, 3,4-dimethyl-1-pentene, 4,4-dimethyl-1-pentene, 1-hexene, 4-methyl-1-hexene, 5-methyl-1-hexene, 6-phenyl-1-hexene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene, and 1-eicosene.

[0026] As the acylating agent, an unsaturated carboxylic acid or an anhydride thereof is preferably used. The unsaturated carboxylic acid includes acrylic acid, methacrylic acid, cinnamic acid, crotonic acid, maleic acid, fumaric acid, and itaconic acid. Moreover, examples of the anhydrides of the unsaturated carboxylic acids include maleic anhydride.

[0027] As the polyamine, an aromatic diamine or an aromatic triamine is preferably used, more specifically, an N-arylphenylenediamine is preferably used, and even more specifically, an N-phenylphenylenediamine is preferably used.

[0028] The content of the dispersant type viscosity index improver (B) used in the lubricating oil composition of this embodiment must be more than 0.05 mass% and less than 5.0 mass% in terms of solid content based on the total amount of the composition. If the content of the dispersant type viscosity index improver is less than 0.05 mass%, the effect of improving wear resistance is not achieved, and if it exceeds 5.0 mass%, the viscosity properties deteriorate. The content of the dispersant type viscosity index improver (B) is preferably 0.06% by mass or more, more preferably 0.08% by mass or more, and even more preferably 0.10% by mass or more, and is preferably 2.0% by mass or less, more preferably 1.0% by mass or less, and even more preferably 0.50% by mass or less, calculated as solid content based on the total amount of the composition. The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, the range is preferably 0.06 to 2.0% by mass, more preferably 0.08 to 1.0% by mass, and even more preferably 0.10 to 0.50% by mass.

[0029] <Non-dispersant viscosity index improver (C)> The lubricating oil composition of this embodiment may further contain a nitrogen-free non-dispersant viscosity index improver (C). Examples of the non-dispersant viscosity index improver (C) include polymers such as non-dispersant poly(meth)acrylate, star polymer, olefin copolymer (e.g., ethylene-propylene copolymer, etc.), styrene copolymer (e.g., styrene-diene copolymer, styrene-isoprene copolymer, etc.), etc. Among these, non-dispersant poly(meth)acrylate is preferred. These may be used alone or in combination of two or more.

[0030] From the viewpoint of keeping the viscosity of the lubricating oil composition low, the non-dispersant viscosity index improver (C) preferably has a weight average molecular weight (Mw) of 200,000 or more, more preferably 250,000 or more, and even more preferably 280,000 or more. The amount of the non-dispersant viscosity index improver (C) is preferably 0.2 mass% or more, more preferably 0.5 mass% or more, even more preferably 1.0 mass% or more, and is preferably 10.0 mass% or less, more preferably 7.0 mass% or less, even more preferably 5.0 mass% or less, as a solid content content based on the total amount of the lubricating oil composition. The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, it is preferably 0.2 to 10.0 mass%, more preferably 0.5 to 7.0 mass%, even more preferably 1.0 to 5.0 mass%.

[0031] In the lubricating oil composition of this embodiment, the ratio of the content of the non-dispersant viscosity index improver (C) to the content of the dispersant viscosity index improver (B) [(C) / (B)] is preferably 0.50 or more, more preferably 1.5 or more, even more preferably 3.0 or more, and is preferably 30.0 or less, more preferably 20.0 or less, and even more preferably 15.0 or less, in terms of the mass ratio of the solid content. The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, are preferably 0.50 to 30.0, more preferably 1.5 to 20.0, and even more preferably 3.0 to 15.0. In particular, when a dispersant type viscosity index improver (B) having a weight average molecular weight (Mw) of 100,000 to 250,000 and a non-dispersant type viscosity index improver (C) having a weight average molecular weight (Mw) of 280,000 or more are contained in such a ratio of the content of the non-dispersant type viscosity index improver (C) to the content of the dispersant type viscosity index improver (B) [(C) / (B)]] that is a mass ratio of the solid contents of 3.0 to 15.0, this is particularly preferred because the dispersant type viscosity index improver (B) having a moderate molecular weight exhibits excellent wear resistance, while the non-dispersant type viscosity index improver (C) having a relatively large molecular weight realizes a low viscosity and a high viscosity index.

[0032] <Molybdenum-based friction modifier (D)> The lubricating oil composition of this embodiment may further contain a molybdenum-based friction modifier (D). By containing the molybdenum-based friction modifier (D) in the lubricating oil composition, the friction reducing effect can be further improved. In particular, the friction reducing effect can be effectively exerted in an environment where the temperature of the lubricating oil composition is high.

[0033] As the molybdenum-based friction modifier (D), any compound having a molybdenum atom can be used, and examples thereof include molybdenum dithiocarbamate (MoDTC), molybdenum dithiophosphate (MoDTP), amine salts of molybdic acid, etc. Among these, from the viewpoint of lowering the metal-metal friction coefficient and obtaining excellent fuel economy, molybdenum dithiocarbamate (MoDTC) and molybdenum dithiophosphate (MoDTP) are preferred, and molybdenum dithiocarbamate (MoDTC) is more preferred.

[0034] Examples of molybdenum dithiocarbamate (MoDTC) include dinuclear molybdenum dithiocarbamate containing two molybdenum atoms in one molecule, and trinuclear molybdenum dithiocarbamate containing three molybdenum atoms in one molecule.

[0035] Examples of the dinuclear molybdenum dithiocarbamate include a compound represented by the following general formula (D-1) and a compound represented by the following general formula (D-2).

[0036] [ka]

[0037] In the above general formulas (D-1) and (D-2), R 11 ~R 14 each independently represents a hydrocarbon group, and these may be the same or different. X 11 ~X 18Each independently represents an oxygen atom or a sulfur atom, and may be the same as or different from each other. However, X in formula (D-1) 11 ~X 18 At least two of the groups are sulfur atoms. R 11 ~R 14 The hydrocarbon group that can be selected as the aryl group preferably has 6 to 22 carbon atoms.

[0038] R in the above general formulas (D-1) and (D-2) 11 ~R 14 Examples of the hydrocarbon group that can be selected as include an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkylaryl group, and an arylalkyl group. Examples of the alkyl group include a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, a pentadecyl group, a hexadecyl group, a heptadecyl group, and an octadecyl group. Examples of the alkenyl group include a hexenyl group, a heptenyl group, an octenyl group, a nonenyl group, a decenyl group, an undecenyl group, a dodecenyl group, a tridecenyl group, a tetradecenyl group, and a pentadecenyl group. Examples of the cycloalkyl group include a cyclohexyl group, a dimethylcyclohexyl group, an ethylcyclohexyl group, a methylcyclohexylmethyl group, a cyclohexylethyl group, a propylcyclohexyl group, a butylcyclohexyl group, and a heptylcyclohexyl group. Examples of the aryl group include a phenyl group, a naphthyl group, an anthracenyl group, a biphenyl group, and a terphenyl group. Examples of the alkylaryl group include a tolyl group, a dimethylphenyl group, a butylphenyl group, a nonylphenyl group, and a dimethylnaphthyl group. Examples of the arylalkyl group include a methylbenzyl group, a phenylmethyl group, a phenylethyl group, and a diphenylmethyl group.

[0039] Among these, molybdenum dialkyldithiocarbamate represented by the following structural formula (D-3) (hereinafter also referred to as "compound (D3)") is preferable. [ka]

[0040] In the general formula (D-3), R 1 , R 2 , R 3 , and R 4 each independently represents a short-chain substituent group (α) which is an aliphatic hydrocarbon group having 4 to 12 carbon atoms, or a long-chain substituent group (β) which is an aliphatic hydrocarbon group having 13 to 22 carbon atoms. The molar ratio [(α) / (β)] of the short-chain substituent group (α) to the long-chain substituent group (β) in the entire molecule of the compound (D3) is 0.10 to 2.0. In addition, in the general formula (D-3), X 1 , X 2 , X 3 , and X 4 each independently represents an oxygen atom or a sulfur atom.

[0041] Examples of the aliphatic hydrocarbon group having 4 to 12 carbon atoms that can be selected as the short-chain substituent group (α) include an alkyl group having 4 to 12 carbon atoms and an alkenyl group having 4 to 12 carbon atoms. Specific examples include butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, butenyl, pentenyl, hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, and dodecenyl groups. These may be linear or branched. The number of carbon atoms in the aliphatic hydrocarbon group that can be selected as the short-chain substituent group (α) is preferably 5 to 11, more preferably 6 to 10, and even more preferably 7 to 9, from the viewpoint of making it easier to exhibit the effects of the present invention.

[0042] Examples of the aliphatic hydrocarbon group having 13 to 22 carbon atoms that can be selected as the long-chain substituent group (β) include an alkyl group having 13 to 22 carbon atoms and an alkenyl group having 13 to 22 carbon atoms. Specific examples include tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, icosyl, henicosyl, docosyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, oleyl, nonadecenyl, icosenyl, henicosyl, and docosenyl groups. These may be linear or branched. The number of carbon atoms in the aliphatic hydrocarbon group that can be selected as the long-chain substituent group (β) is preferably 13 to 20, more preferably 13 to 16, and even more preferably 13 to 14, from the viewpoint of making it easier to exhibit the effects of the present invention.

[0043] Here, the compound (D3) represented by the general formula (D-3) has a molar ratio [(α) / (β)] of the short-chain substituent group (α) to the long-chain substituent group (β) in the whole molecule of 0.10 to 2.0. When the molar ratio [(α) / (β)] is 0.10 or more, the effect of the compound (D3) on copper corrosion resistance is small, and the friction reducing effect is easily improved. In addition, when the molar ratio [(α) / (β)] is 2.0 or less, low-temperature storage stability is easily ensured. Here, from the viewpoint of minimizing the effect on copper corrosion resistance and of making it easier to improve the friction reducing effect, the molar ratio [(α) / (β)] is preferably 0.15 or more, and more preferably 0.20 or more. In order to more easily ensure low-temperature storage stability, the molar ratio [(α) / (β)] is preferably 1.2 or less, more preferably 1.0 or less, even more preferably 0.80 or less, and still more preferably 0.60 or less. The upper and lower limits of these numerical ranges can be arbitrarily combined. Specifically, the range is preferably 0.15 to 1.2, more preferably 0.20 to 1.0, even more preferably 0.20 to 0.80, and still more preferably 0.20 to 0.60.

[0044] Here, the short-chain substituent group (α) and the long-chain substituent group (β) may or may not coexist in the same molecule. That is, the average molar ratio [(α) / (β)] of the short-chain substituent group (α) to the long-chain substituent group (β) in all molecules of the compound (D3) represented by the general formula (D-3) may be within the range of 0.10 to 2.0. Therefore, the compound (D3) contains R 1 , R 2 , R 3 and R 4 may be mixed with a group of molecules (D3-1) in which all of R 1 , R 2 , R 3 and R 4 A group of molecules (D3-2) in which all are long-chain substituent groups (β) may be mixed, and R 1 , R 2 , R 3 and R 4 A molecular group (D3-3) in which a part of the substituents is a short-chain substituent group (α) and the rest is a long-chain substituent group (β) may be mixed.

[0045] An example of the trinuclear molybdenum dithiocarbamate is a compound represented by the following general formula (D-4). Mo3S k E m L n A p Q z (D-4)

[0046] In the general formula (D-4), k is an integer of 1 or more, m is an integer of 0 or more, and k+m is an integer of 4 to 10, and preferably an integer of 4 to 7. n is an integer of 1 to 4, and p is an integer of 0 or more. z is an integer of 0 to 5, including non-stoichiometric values. Each E is independently an oxygen atom or a selenium atom, which may, for example, replace sulfur in the core described below. Each L is independently an anionic ligand having an organic group containing a carbon atom, the total number of carbon atoms in the organic group in each ligand is 14 or more, and each ligand may be the same or different. Each A is independently an anion other than L. Each Q is independently an electron donating neutral compound that is present to fill a vacant coordination site on the trinuclear molybdenum compound.

[0047] In the lubricating oil composition of this embodiment, the content of the molybdenum-based friction modifier (D) is, from the viewpoint of reducing the metal-to-metal friction coefficient and achieving excellent fuel economy, preferably 0.02 mass % or more, more preferably 0.05 mass % or more, even more preferably 0.08 mass % or more, based on the total amount (100 mass %) of the lubricating oil composition, and is preferably 5.0 mass % or less, more preferably 3.0 mass % or less, even more preferably 1.5 mass % or less. The upper and lower limits of these numerical ranges can be arbitrarily combined. Specifically, the range is preferably 0.02 mass % to 5.0 mass %, more preferably 0.05 mass % to 3.0 mass %, and even more preferably 0.08 mass % to 1.5 mass %.

[0048] In the lubricating oil composition of this embodiment, the content of molybdenum atoms derived from the molybdenum-based friction modifier (D) is preferably 50 mass ppm or more, more preferably 80 mass ppm or more, and even more preferably 100 mass ppm or more, based on the total amount (100 mass%) of the lubricating oil composition, from the viewpoint of improving the friction reducing effect, and is also preferably 2,000 mass ppm or less, more preferably 1,200 mass ppm or less, and even more preferably 800 mass ppm or less. The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, it is preferably 50 to 2,000 mass ppm, more preferably 80 to 1,200 mass ppm, and even more preferably 100 to 800 mass ppm.

[0049] <Dispersant> The lubricating oil composition of this embodiment may further contain a dispersant. As the dispersant, one or more types selected from non-boron-modified succinimides and boron-modified succinimides can be used, and it is preferable to combine one or more types selected from non-boron-modified succinimides with one or more types selected from boron-modified succinimides. However, in the lubricating oil composition of this embodiment, since the dispersant may induce soot to the lubricated surface and deteriorate the wear resistance, the content of the dispersant is preferably 12.00 mass % or less, more preferably 8.50 mass % or less, and even more preferably 6.50 mass % or less, based on the total amount (100 mass %) of the lubricating oil composition.

[0050] The content of nitrogen atoms derived from the dispersant (more specifically, the total amount of nitrogen atoms derived from the non-boron-modified succinimide and the boron-modified succinimide) is preferably 0.15 mass% or less, more preferably 0.12 mass% or less, and even more preferably 0.10 mass% or less, based on the total amount (100 mass%) of the lubricating oil composition. The nitrogen atom content can be measured in accordance with JIS K 2609:1998.

[0051] <Other ingredients> The lubricating oil composition of this embodiment may contain components other than those described above, as necessary, to the extent that the effects of the present invention are not impaired. Examples of additives as the other components include metal-based detergents, pour point depressants, antioxidants, anti-wear agents, friction modifiers other than the molybdenum-based friction modifier (D), extreme pressure agents, viscosity index improvers, rust inhibitors, antifoaming agents, oiliness improvers, metal deactivators, and demulsifiers. These may be used alone or in combination of two or more.

[0052] -Metal-based cleaning agents- Examples of metal-based detergents include organic acid metal salt compounds containing a metal atom selected from alkali metals and alkaline earth metals. Specific examples include metal salicylates, metal phenates, and metal sulfonates, each of which contains a metal atom selected from alkali metals and alkaline earth metals. In this specification, the term "alkali metal" refers to lithium, sodium, potassium, rubidium and cesium. Additionally, the term "alkaline earth metal" refers to beryllium, magnesium, calcium, strontium, and barium. As the metal atom contained in the metal-based detergent, from the viewpoint of improving the detergency at high temperatures, sodium, calcium, magnesium, or barium is preferred, and calcium and magnesium are more preferred.

[0053] The metal salicylate is preferably a compound represented by the following general formula (1), the metal phenate is preferably a compound represented by the following general formula (2), and the metal sulfonate is preferably a compound represented by the following general formula (3).

[0054] [ka]

[0055] In the above general formulas (1) to (3), M is a metal atom selected from alkali metals and alkaline earth metals, preferably sodium, calcium, magnesium, or barium, more preferably calcium or magnesium. E is an alkaline earth metal, preferably calcium, magnesium, or barium, more preferably calcium or magnesium; q is the valence of M, which is 1 or 2; R 31 and R 32 are each independently a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms. S represents a sulfur atom. r is an integer of 0 or more, and preferably an integer of 0 to 3. R 31 and R 32Examples of the hydrocarbon group that can be selected as the aryl group include an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, a cycloalkyl group having 3 to 18 ring carbon atoms, an aryl group having 6 to 18 ring carbon atoms, an alkylaryl group having 7 to 18 carbon atoms, and an arylalkyl group having 7 to 18 carbon atoms. These may be used alone or in combination of two or more. Among these, from the viewpoint of improving high-temperature detergent dispersibility and solubility in base oil, it is preferable to use one or more selected from calcium salicylate, calcium phenate, calcium sulfonate, magnesium salicylate, magnesium phenate, and magnesium sulfonate.

[0056] These metallic detergents may be neutral, basic, overbased salts and mixtures thereof. The base number of the metallic detergent is preferably 0 to 600 mgKOH / g. When the metallic detergent is a basic salt or an overbased salt, the base number of the metallic detergent is preferably from 10 to 600 mgKOH / g, more preferably from 20 to 500 mgKOH / g. In this specification, the "base number" refers to the base number measured by the perchloric acid method in accordance with 7. of JIS K 2501:2003 "Petroleum products and lubricants -- Determination of neutralization number".

[0057] In the lubricating oil composition of this embodiment, the content of the metallic detergent is, from the viewpoint of making it easier to exert the effects of the present invention, preferably 0.01 mass % to 10 mass %, more preferably 0.1 mass % to 5.0 mass %, even more preferably 0.2 mass % to 3.0 mass %, and even more preferably 0.3 mass % to 2.0 mass %, based on the total amount (100 mass %) of the lubricating oil composition. The metallic detergent may be used alone or in combination of two or more kinds. When two or more kinds are used, the suitable total content is the same as the above content.

[0058] In the lubricating oil composition of the present embodiment, when the metal atoms contained in the metallic detergent are calcium, the content of calcium atoms derived from the metallic detergent is preferably 0.05 mass % or more, more preferably 0.10 mass % or more, and even more preferably 0.11 mass % or more, based on the total amount (100 mass %) of the lubricating oil composition, from the viewpoint of high-temperature detergent dispersancy. Furthermore, from the viewpoint of reducing sulfated ash and preventing LSPI (abnormal combustion), the content of calcium atoms derived from the metallic detergent is preferably 0.50 mass % or less, more preferably 0.40 mass % or less, even more preferably 0.30 mass % or less, still more preferably 0.20 mass % or less, even more preferably 0.15 mass % or less, and even more preferably 0.13 mass % or less, based on the total amount (100 mass %) of the lubricating oil composition.

[0059] In the lubricating oil composition of this embodiment, when the metal atom contained in the metallic detergent is magnesium, the content of magnesium atoms derived from the metallic detergent is preferably 0.02 mass % or more, more preferably 0.03 mass % or more, and even more preferably 0.04 mass % or more, based on the total amount (100 mass %) of the lubricating oil composition, from the viewpoint of high-temperature detergent dispersibility. Furthermore, from the viewpoint of reducing sulfated ash and preventing LSPI (abnormal combustion), the content of magnesium atoms derived from the metallic detergent is preferably 0.07 mass % or less, more preferably 0.06 mass % or less, and even more preferably 0.05 mass % or less, based on the total amount (100 mass %) of the lubricating oil composition.

[0060] -Pour point depressant- Examples of pour point depressants include ethylene-vinyl acetate copolymers, condensates of chlorinated paraffin and naphthalene, condensates of chlorinated paraffin and phenol, polymethacrylates (PMA; polyalkyl (meth)acrylates, etc.), polyvinyl acetate, polybutene, polyalkylstyrene, etc., and polymethacrylates are preferably used. The weight average molecular weight (Mw) of these polymers used as pour point depressants is preferably 50,000 to 150,000. These may be used alone or in combination of two or more.

[0061] -Antioxidants- Examples of the antioxidant include amine-based antioxidants and phenol-based antioxidants. Examples of the amine-based antioxidants include diphenylamine-based antioxidants such as diphenylamine and alkylated diphenylamine having an alkyl group having 3 to 20 carbon atoms; naphthylamine-based antioxidants such as phenyl-α-naphthylamine, phenyl-β-naphthylamine, substituted phenyl-α-naphthylamine having an alkyl group having 3 to 20 carbon atoms, and substituted phenyl-β-naphthylamine having an alkyl group having 3 to 20 carbon atoms; and the like. Examples of the phenol-based antioxidants include monophenol-based antioxidants such as 2,6-di-tert-butylphenol, 2,6-di-tert-butyl-4-methylphenol, 2,6-di-tert-butyl-4-ethylphenol, isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, and octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate; diphenol-based antioxidants such as 4,4'-methylenebis(2,6-di-tert-butylphenol) and 2,2'-methylenebis(4-ethyl-6-tert-butylphenol); hindered phenol-based antioxidants; and the like. These may be used alone or in combination of two or more.

[0062] -Anti-wear agent- Examples of anti-wear agents include zinc-containing compounds such as zinc dialkyldithiophosphate (ZnDTP) and zinc phosphate; sulfur-containing compounds such as disulfides, sulfurized olefins, sulfurized oils and fats, sulfurized esters, thiocarbonates, thiocarbamates, and polysulfides; phosphorus-containing compounds such as phosphites, phosphates, phosphonates, and amine salts or metal salts thereof; and sulfur- and phosphorus-containing anti-wear agents such as thiophosphites, thiophosphates, thiophosphonates, and amine salts or metal salts thereof. Of these, zinc dialkyldithiophosphate (ZnDTP) is preferred. These may be used alone or in combination of two or more. The content of the zinc dithiophosphate is preferably 200 to 5,000 ppm by mass, and more preferably 300 to 2,000 ppm by mass, calculated as phosphorus atoms based on the total amount of the composition.

[0063] -Friction modifiers other than component (D)- The lubricating oil composition of the present embodiment may contain a friction modifier other than component (D). Component (D) is excellent in effectively exerting a friction-reducing effect when the temperature of the lubricating oil composition is in a high temperature environment, but by including a friction modifier other than component (B) in the lubricating oil composition, the friction-reducing effect can be effectively exerted even when the temperature of the lubricating oil composition is in a low temperature environment. Examples of friction modifiers other than the molybdenum-based friction modifier (D) include ashless friction modifiers such as aliphatic amines, fatty acid esters, fatty acid amides, fatty acids, aliphatic alcohols, and aliphatic ethers; fats and oils, amines, amides, sulfur esters, phosphate esters, phosphites, and phosphate amine salts. These may be used alone or in combination of two or more. Here, the friction modifier other than component (D) is preferably an aliphatic amine, and among the aliphatic amines, an aliphatic amine having at least one alkyl or alkenyl group having 2 to 30 carbon atoms in the molecule is preferred.

[0064] Among aliphatic amines having at least one alkyl or alkenyl group having 2 to 30 carbon atoms in the molecule, diethanolamine compounds represented by the following general formula (4) are preferred.

[0065] [ka]

[0066] In the above general formula (4), R 1 is a monovalent aliphatic hydrocarbon group having 12 to 30 carbon atoms. R 1 Preferred examples of the aliphatic hydrocarbon group having 12 to 30 carbon atoms include linear or branched alkyl groups having 12 to 30 carbon atoms and linear or branched alkenyl groups having 12 to 30 carbon atoms. The number of carbon atoms in these groups is more preferably 12 to 24, and further preferably 16 to 20.

[0067] For example, examples of linear or branched alkyl groups having 12 to 30 carbon atoms include various dodecyl groups such as n-dodecyl, isododecyl, sec-dodecyl, tert-dodecyl, and neododecyl groups (hereinafter, functional groups having a predetermined number of carbon atoms, including linear, branched, and isomers thereof, may be abbreviated as "various functional groups"). Various tridecyl groups, various tetradecyl groups, various pentadecyl groups, various hexadecyl groups, various heptadecyl groups, various octadecyl groups, various nonadecyl groups, various icosyl groups, various henicosyl groups, various docosyl groups, various tricosyl groups, various tetracosyl groups, various pentacosyl groups, various hexacosyl groups, various heptacosyl groups, various octacosyl groups, various nonacosyl groups, and various triacontyl groups. Furthermore, examples of linear or branched alkenyl groups having 12 to 30 carbon atoms include various dodecenyl groups, various tridecenyl groups, various tetradecenyl groups, various pentadecenyl groups, various hexadecenyl groups, various heptadecenyl groups, various octadecenyl groups, various nonadecenyl groups, various icosenyl groups, various henicosenyl groups, various docosenyl groups, various tricosenyl groups, various tetracosenyl groups, various pentacosenyl groups, various hexacosenyl groups, various heptacosenyl groups, various octacosenyl groups, various nonacosenyl groups, and various triacontinyl groups. Among these, taking into consideration the effect of improving the long drain property, alkyl groups having 16 to 18 carbon atoms, such as various hexadecyl groups, various heptadecyl groups, and various octadecyl groups, and alkenyl groups having 16 to 18 carbon atoms, such as various hexadecenyl groups, various heptadecenyl groups, and various octadecenyl groups, are preferred, with the various hexadecyl groups, various octadecyl groups, and various octadecenyl groups being more preferred, and the n-hexadecyl group (palmityl group), n-octadecyl group (stearyl group), and n-octadecenyl group (oleyl group) being even more preferred.

[0068] A preferred specific example of the diethanolamine compound represented by the above general formula (4) is stearyldiethanolamine (in general formula (4), R 1 is an n-octadecyl group (stearyl group), oleyldiethanolamine (in general formula (4), R 1 is an n-octadecenyl group (oleyl group), and palmityldiethanolamine (in general formula (4), R 1 is an n-hexadecyl group (palmityl group).) Among these, oleyldiethanolamine is preferred. These may be used alone or in combination of two or more.

[0069] -Extreme pressure agent- Examples of the extreme pressure agent include sulfur-based extreme pressure agents such as sulfides, sulfoxides, sulfones, and thiophosphinates, halogen-based extreme pressure agents such as chlorinated hydrocarbons, and organometallic extreme pressure agents. Of the above-mentioned antiwear agents, compounds having a function as an extreme pressure agent can also be used. These may be used alone or in combination of two or more.

[0070] -Rust inhibitor- Examples of the rust inhibitor include fatty acids, alkenyl succinic acid half esters, fatty acid soaps, alkyl sulfonates, polyhydric alcohol fatty acid esters, fatty acid amines, paraffin oxide, and alkyl polyoxyethylene ethers. These may be used alone or in combination of two or more.

[0071] - Defoaming agent - Examples of the antifoaming agent include silicone oils such as dimethylpolysiloxane, fluorosilicone oils, and fluoroalkyl ethers. These may be used alone or in combination of two or more.

[0072] -Oilability improver- Examples of oiliness improvers include aliphatic saturated or unsaturated monocarboxylic acids such as stearic acid and oleic acid; polymerized fatty acids such as dimer acid and hydrogenated dimer acid; hydroxy fatty acids such as ricinoleic acid and 12-hydroxystearic acid; aliphatic saturated or unsaturated monoalcohols such as lauryl alcohol and oleyl alcohol; aliphatic saturated or unsaturated monoamines such as stearylamine and oleylamine; aliphatic saturated or unsaturated monocarboxylic acid amides such as lauric acid amide and oleic acid amide; partial esters of polyhydric alcohols such as glycerin and sorbitol with aliphatic saturated or unsaturated monocarboxylic acids; and the like.

[0073] -Metal deactivator- Examples of the metal deactivator include benzotriazole-based compounds, tolyltriazole-based compounds, thiadiazole-based compounds, imidazole-based compounds, and pyrimidine-based compounds. These may be used alone or in combination of two or more.

[0074] -Demulsifier- Examples of demulsifiers include anionic surfactants such as sulfate salts of castor oil and petroleum sulfonates; cationic surfactants such as quaternary ammonium salts and imidazolines; polyalkylene glycol-based nonionic surfactants such as polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers and polyoxyethylene alkyl naphthyl ethers; polyoxyalkylene polyglycols and their dicarboxylic acid esters; alkylene oxide adducts of alkylphenol-formaldehyde polycondensates; and the like. These may be used alone or in combination of two or more.

[0075] The contents of the above-mentioned other components can be appropriately adjusted within a range that does not impair the effects of the present invention, and each of them is usually 0.001 to 15 mass%, preferably 0.005 to 10 mass%, more preferably 0.01 to 7 mass%, and even more preferably 0.03 to 5 mass%, based on the total amount (100 mass%) of the lubricating oil composition. In this specification, the additives as the other components may be blended with other components in the form of a solution diluted and dissolved in a part of the base oil (A) in consideration of handling properties, solubility in the base oil (A), etc. In such a case, in this specification, the above-mentioned content of the additives as the other components means the content in terms of active ingredients (solid content) excluding the diluent oil.

[0076] [Physical properties of lubricating oil composition] <Kinematic viscosity at 100°C and viscosity index> The 100°C kinematic viscosity of the lubricating oil composition of this embodiment is preferably 4.5 mm from the viewpoint of achieving good fuel economy and 4.5 mm from the viewpoint of reducing loss of the lubricating oil composition due to evaporation and ensuring oil film retention. 2 / s or more, preferably 5.0 mm 2 / s or more, more preferably 6.1 mm 2 / s or more, and preferably 21.9 mm 2 / s or less, preferably 16.3 mm 2 / s or less, more preferably 12.5 mm 2 The upper and lower limits of these numerical ranges can be arbitrarily combined, and specifically, the preferred range is 4.5 to 21.9 mm. 2 / s, and more preferably 5.0 to 16.3 mm 2 / s, and more preferably 6.1 to 12.5 mm 2 / s. The viscosity index of the lubricating oil composition of this embodiment is preferably at least 120, more preferably at least 140, even more preferably at least 160, and even more preferably at least 180. When the viscosity index is within the above range, the viscosity change due to temperature is small. The 40° C. kinematic viscosity, the 100° C. kinematic viscosity, and the viscosity index can be measured or calculated in accordance with JIS K 2283:2000.

[0077] [Nitrogen atom content] The nitrogen atom content in the lubricating oil composition of this embodiment is preferably 0.03 mass% or more, more preferably 0.04 mass% or more, based on the total amount (100 mass%) of the lubricating oil composition, from the viewpoint of maintaining high-temperature detergency and dispersibility for a long period of time.Furthermore, the nitrogen atom content is preferably 0.20 mass% or less, more preferably 0.15 mass% or less, even more preferably 0.10 mass% or less, and even more preferably 0.09 mass% or less, based on the total amount (100 mass%) of the lubricating oil composition, from the viewpoint of low viscosity. The nitrogen atom content can be measured in accordance with JIS K 2609:1998.

[0078] [150℃HTHS viscosity (HTHS 150 )] The 150°C HTHS viscosity (HTHS 150 ) is preferably 2.0 mPa·s or more, more preferably 2.3 mPa·s or more, and is preferably less than 3.7 mPa·s, more preferably less than 3.0 mPa·s. The 150°C HTHS viscosity (HTHS 150 ) was measured at a shear rate of 10 6 It can be measured in / s.

[0079] The lubricating oil composition of this embodiment preferably has a wear scar diameter of 200 μm or less, and more preferably 165 μm or less, in a wear resistance test using an HFRR tester. The wear scar diameter in the wear resistance test using the above-mentioned HFRR tester refers to the wear scar diameter measured by the method described in the examples described later.

[0080] [Uses of lubricating oil composition] The lubricating oil composition of this embodiment is excellent in the effect of reducing the friction coefficient. Therefore, the lubricating oil composition of the present embodiment is preferably used in internal combustion engines, and more preferably in internal combustion engines of four-wheeled vehicles and motorcycles. The lubricating oil composition of the present embodiment is preferably used as an engine oil, and more preferably used as a diesel engine oil. The lubricating oil composition of the present embodiment is suitable for use as a lubricating oil composition for internal combustion engines (engine oil for internal combustion engines) used in automobiles and the like, but may also be used in other applications.

[0081] [Method of manufacturing lubricating oil composition] The method for producing the lubricating oil composition according to this embodiment is not particularly limited. For example, the method for producing a lubricating oil composition according to this embodiment includes a step of mixing the base oil (A) and the dispersant type viscosity index improver (B), and, if necessary, may further include one or more components selected from the non-dispersant type viscosity index improver (C), the molybdenum-based friction modifier (D) and other components.

[0082] The method for mixing the above components is not particularly limited, and may be, for example, a method having a step of blending each component (one or more selected from component (B), component (C), component (D), and the other components) with base oil (A). Each component may be blended after being made into a solution (dispersion) by adding a diluent oil or the like. After blending each component, it is preferable to stir and uniformly disperse it by a known method.

[0083] [engine] The present embodiment also provides an engine comprising the lubricating oil composition of the present invention as described above. As described above, the engine may be an engine for a vehicle such as an automobile, and is preferably an automobile engine, and more preferably an automobile diesel engine. The lubricating oil composition of this embodiment is able to exhibit excellent anti-wear properties even in diesel engines which are prone to soot contamination.

[0084] [Engine lubrication method] The present invention also provides a method for lubricating an engine, comprising lubricating the engine with the lubricating oil composition of the present embodiment described above. As mentioned above, the engine may be an engine for a vehicle such as an automobile, but an automobile engine is preferred, and an automobile diesel engine is more preferred since soot is likely to be mixed into the lubricating oil composition. The lubricating oil composition of the present invention can improve the wear resistance between metal members in an environment where soot is mixed in. Therefore, the engine lubrication method of the present embodiment can impart excellent wear resistance between metal members to the engine.

[0085] [One aspect of the present invention provided] According to one aspect of the present invention, the following [1] to

[12] are provided. [1] A lubricating oil composition comprising a base oil (A) and a dispersant type viscosity index improver (B), wherein the dispersant type viscosity index improver (B) has a nitrogen atom content of 0.50 to 1.50 mass% based on the solid content and a weight average molecular weight (Mw) of 100,000 or more, and the content of the dispersant type viscosity index improver (B) in terms of solid content based on the total amount of the composition is more than 0.05 mass% and less than 5.0 mass%. [2] The lubricating oil composition according to [1], wherein the dispersant-type viscosity index improver (B) has a weight average molecular weight (Mw) of 250,000 or less. [3] The lubricating oil composition according to [1] or [2], further comprising a non-dispersant viscosity index improver (C) having a weight average molecular weight (Mw) of 200,000 or more in an amount of 0.2 to 10.0 mass%, calculated as solid content based on the total amount of the composition. [4] The lubricating oil composition according to [3], wherein the content of the non-dispersant viscosity index improver (C) relative to the content of the dispersant viscosity index improver (B) is 0.50 to 20.0 times the solid content mass ratio [(C) / (B)]. [5] Kinematic viscosity at 100°C is 3.0 to 16.0 mm 2 The lubricating oil composition according to any one of [1] to [4], wherein the lubricating oil composition has a molecular weight of 1.0 to 1.5. [6] The lubricating oil composition according to any one of [1] to [5], which has a viscosity index of 150 or more. [7] The lubricating oil composition according to any one of [1] to [6], wherein the dispersant type viscosity index improver (B) has a molecular weight distribution (Mw / Mn) of 3.0 or less. [8] The lubricating oil composition according to any one of [1] to [7], further comprising a molybdenum-based friction modifier (D). [9] The lubricating oil composition according to [8], wherein the content of the molybdenum-based friction modifier (D) is 50 to 2,000 ppm by mass in terms of molybdenum atom based on the total amount of the composition.

[10] The lubricating oil composition according to any one of [1] to [9], further comprising zinc dithiophosphate.

[11] The lubricating oil composition according to

[10] , wherein the content of the zinc dithiophosphate is 200 to 5,000 ppm by mass in terms of phosphorus atoms based on the total amount of the composition.

[12] The lubricating oil composition according to any one of [1] to

[11] , wherein the content of nitrogen atoms derived from the dispersant is 0.10 mass% or less based on the total amount of the composition.

[13] The lubricating oil composition according to

[12] , wherein the content of nitrogen atoms derived from the dispersant is the total amount of nitrogen atoms derived from the non-boron-modified succinimide and the boron-modified succinimide.

[14] The lubricating oil composition according to any one of [1] to

[13] , wherein the content of the base oil (A) is 60 to 99 mass % based on the total amount of the composition.

[15] The lubricating oil composition according to any one of [1] to

[14] , which is used in a diesel engine.

[16] A method for producing a lubricating oil composition according to any one of [1] to

[15] , comprising the step of mixing the base oil (A) and the dispersant-type viscosity index improver (B).

[17] A diesel engine comprising the lubricating oil composition according to any one of [1] to

[15] .

[18] A method for lubricating an engine, comprising using the lubricating oil composition according to any one of [1] to

[15] . EXAMPLES

[0086] The present invention will be described in detail with reference to the following examples, but the present invention is not limited to the following examples. The various properties of the components used in the examples and comparative examples and the obtained lubricating oil compositions were measured by the following methods.

[0087] [Kinematic viscosity at 40°C, kinematic viscosity at 100°C, and viscosity index] The 40°C kinematic viscosity, 100°C kinematic viscosity and viscosity index of the lubricating oil compositions were measured or calculated in accordance with JIS K 2283:2000.

[0088] [150℃HTHS viscosity] The 150°C HTHS viscosity was measured or calculated in accordance with JPI-5S-36-03.

[0089] [Molybdenum and phosphorus atom content] The molybdenum atom and phosphorus atom contents were measured in accordance with JPI-5S-38-03.

[0090] [Weight average molecular weight (Mw) measurement] The weight average molecular weight (Mw) was measured in terms of polystyrene by gel permeation chromatography (GPC).

[0091] [Examples 1 to 11 and Comparative Examples 1 to 6] The components shown below were added in the amounts shown in Tables 1 and 2 and mixed thoroughly to obtain lubricating oil compositions. Details of each component used in Examples 1 to 11 and Comparative Examples 1 to 6 are as follows. The contents in Tables 1 and 2 are calculated as solid contents.

[0092] <Base oil (A)> Mineral oil (classification in API base oil category: Group III, kinematic viscosity at 40°C: 19.8 mm 2 / s, 100℃ kinematic viscosity: 4.0mm 2 / s, viscosity index: 125)

[0093] <Dispersant type viscosity index improver> [Dispersant-type viscosity index improver equivalent to component (B)] Dispersed olefin copolymer (weight average molecular weight (Mw): 120,000, molecular weight distribution (Mw / Mn): 2.0, nitrogen atom content based on solid content: 0.77% by mass, nitrogen-containing olefin copolymer having the following repeating units) [ka] Dispersed polymethacrylate 1 (weight average molecular weight (Mw): 240,000, molecular weight distribution (Mw / Mn): 2.5, nitrogen atom content based on solid content: 1.05 mass%, nitrogen-containing poly(meth)acrylate, comonomer: N-vinyl-2-pyrrolidone) [Other dispersant type viscosity index improvers] Dispersed polymethacrylate 2 (weight average molecular weight (Mw): 90,000, molecular weight distribution (Mw / Mn): 3.5, nitrogen atom content based on solid content: 0.46 mass%, comonomer: ethylaminoethyl (meth)acrylate) Dispersed polymethacrylate 3 (weight average molecular weight (Mw): 57,000, molecular weight distribution (Mw / Mn): 2.2, nitrogen atom content based on solid content: 1.20 mass%, comonomer: ethylaminoethyl (meth)acrylate) Dispersed polymethacrylate 4 (weight average molecular weight (Mw): 38,900, molecular weight distribution (Mw / Mn): 6.5, nitrogen atom content based on solid content: 0.27 mass%, comonomer: ethylaminoethyl (meth)acrylate) Dispersed polymethacrylate 5 (weight average molecular weight (Mw): 140,000, molecular weight distribution (Mw / Mn): 5.4, nitrogen atom content based on solid content: 0.34 mass%, comonomer: N-vinyl-2-pyrrolidone) Dispersed polymethacrylate 6 (weight average molecular weight (Mw): 143,000, molecular weight distribution (Mw / Mn): 2.4, nitrogen atom content based on solid content: 0.49 mass%, comonomer: N-vinyl-2-pyrrolidone)

[0094] <Non-dispersant viscosity index improver (C)> Non-dispersed polymethacrylate 1 (weight average molecular weight (Mw): 310,000, molecular weight distribution (Mw / Mn): 2.5) Non-dispersed polymethacrylate 2 (weight average molecular weight (Mw): 310,000, molecular weight distribution (Mw / Mn): 1.9)

[0095] <Molybdenum-based friction modifier (D)> Molybdenum dithiocarbamate: Molybdenum dialkyldithiocarbamate (MoDTC) represented by the following structural formula: molybdenum atom content: 10.0% by mass [ka] [In the above structural formula, R 1 , R 2 , R 3 , and R 4 are each independently selected from an isooctyl group (carbon number 8: short chain substituent group) and an isotridecyl group (carbon number 13: long chain substituent group), and the molar ratio of isooctyl groups to isotridecyl groups in all molecules of molybdenum dialkyldithiocarbamate is 50:50. 1 and X 2 is a sulfur atom, and X 3 and X 4 is an oxygen atom.]

[0096] <Dispersant> Dispersant 1: Non-boron modified polyisobutenyl succinic acid bisimide (mass average molecular weight (Mw) of polyisobutenyl group: 2,300, nitrogen atom content: 1.0 mass% Dispersant 2: Boron-modified polyisobutenyl succinimide (polybutene skeleton, mass average molecular weight (Mw) of polyisobutenyl group: 2,300, nitrogen atom content: 1.4 mass%, boron atom content: 1.3 mass%)

[0097] <Other ingredients> Pour point depressants, antioxidants, zinc dialkyldithiophosphate (ZnDTP), metal deactivators

[0098] [Atomic content] In Tables 1 and 2, the content of molybdenum atoms in the lubricating oil composition is a value reflecting the content of molybdenum atoms derived from the molybdenum-based friction modifier (D). In Tables 1 and 2, the content of phosphorus atoms in the lubricating oil composition is a value reflecting the content of phosphorus atoms derived from ZnDTP, which is another additive.

[0099] To 100 parts by mass of each of the lubricating oil compositions obtained in Examples 1 to 11 and Comparative Examples 1 to 6, 3 parts by mass of carbon black was added to prepare sample oils, and each sample oil was evaluated as follows. The results are shown in Tables 1 and 2.

[0100] [Evaluation of wear resistance] The wear scar diameter was measured using an HFRR tester (manufactured by PCS Instruments) under the following conditions when the prepared lubricating oil composition was used. The wear scar diameter was defined as the average value of the wear scar diameter in the direction parallel to the sliding direction and the wear scar diameter in the direction perpendicular to the sliding direction. Test piece: Upper ball (52100 steel), lower disk (800HV) Amplitude: 1.0mm Frequency: 20Hz Load capacity: 1000g ·Temperature: 85℃ Test duration: 20 minutes

[0101] [Table 1]

[0102] [Table 2]

[0103] As can be seen from Tables 1 and 2, the lubricating oil compositions of Examples 1 to 11, which satisfy all of the configurations of the present invention, have excellent wear resistance, with results of 165 μm or less in the wear resistance evaluation test, even in a state in which carbon black is added, which simulates the situation in which soot is generated due to deterioration of the lubricating oil assumed in diesel engine oil. On the other hand, it is clear that the lubricating oil compositions of Comparative Examples 1-6 have lower wear resistance than the lubricating oil compositions of Examples 1-11.

Claims

1. A lubricating oil composition comprising a base oil (A) and a dispersant type viscosity index improver (B), wherein the dispersant type viscosity index improver (B) is one or more selected from the group consisting of nitrogen-containing poly(meth)acrylates and nitrogen-containing polyolefins, the dispersant type viscosity index improver (B) has a nitrogen atom content of 0.50 to 1.50 mass% based on the solids content and a weight average molecular weight (Mw) of 100,000 or more and 250,000 or less, and the content of the dispersant type viscosity index improver (B) in terms of solids content based on the total amount of the composition is more than 0.05 mass% and less than 5.0 mass%.

2. The lubricating oil composition according to claim 1, further comprising a non-dispersant viscosity index improver (C) having a weight average molecular weight (Mw) of 200,000 or more in an amount of 0.2 to 10.0 mass % calculated as solid content based on the total amount of the composition.

3. The lubricating oil composition according to claim 2, wherein the content of the non-dispersant viscosity index improver (C) to the content of the dispersant viscosity index improver (B) is in a solid content mass ratio [(C) / (B)] of 0.50 to 30.

0.

4. Kinematic viscosity at 100°C: 3.0 to 16.0 mm ２ The lubricating oil composition according to any one of claims 1 to 3, wherein

5. The lubricating oil composition according to any one of claims 1 to 4, which has a viscosity index of 150 or more.

6. The lubricating oil composition according to any one of claims 1 to 5, wherein the dispersant-type viscosity index improver (B) has a molecular weight distribution (Mw / Mn) of 3.0 or less.

7. The lubricating oil composition according to any one of claims 1 to 6, further comprising a molybdenum-based friction modifier (D).

8. 8. The lubricating oil composition according to claim 7, wherein the content of the molybdenum-based friction modifier (D) is 50 to 2,000 ppm by mass in terms of molybdenum atom based on the total amount of the composition.

9. The lubricating oil composition according to any one of claims 1 to 8, further comprising a zinc dithiophosphate.

10. The lubricating oil composition according to claim 9, wherein the content of the zinc dithiophosphate is 200 to 5,000 ppm by mass in terms of phosphorus atoms based on the total amount of the composition.

11. The lubricating oil composition according to any one of claims 1 to 10, wherein the content of nitrogen atoms derived from the dispersant is 0.10 mass% or less based on the total amount of the composition.

12. The lubricating oil composition according to claim 11, wherein the content of nitrogen atoms derived from the dispersant is the total amount of nitrogen atoms derived from the non-boron-modified succinimide and the boron-modified succinimide.

13. The lubricating oil composition according to any one of claims 1 to 12, wherein the content of the base oil (A) is 60 to 99 mass% based on the total amount of the composition.

14. The lubricating oil composition according to any one of claims 1 to 13, which is used in a diesel engine.

15. 15. A method for producing a lubricating oil composition according to any one of claims 1 to 14, comprising the step of mixing a base oil (A) and a dispersant type viscosity index improver (B), the dispersant type viscosity index improver (B) being one or more selected from the group consisting of nitrogen-containing poly(meth)acrylates and nitrogen-containing polyolefins, the nitrogen atom content of the dispersant type viscosity index improver (B) being 0.50 to 1.50 mass% based on the solid content and the weight average molecular weight (Mw) being 100,000 or more and 250,000 or less, and the mixing step being performed such that the content of the dispersant type viscosity index improver (B) in terms of solid content based on the total amount of the composition is more than 0.05 mass% and less than 5.0 mass%.

16. A diesel engine comprising the lubricating oil composition according to any one of claims 1 to 14.

17. A method for lubricating an engine, comprising lubricating the engine with the lubricating oil composition according to any one of claims 1 to 14.

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