Hollow package and method for manufacturing same

Abstract

To provide a sealing technique for obtaining a package which is superior in the resistance to molding of a device provided with a hollow part and the fillability into a narrow gap.SOLUTION: A hollow package 103 includes a substrate 109, a device 111, a partition wall 113 and a top plate 115, and is provided with one or more closed hollow parts 117 covered by the substrate 109, the partition wall 113 and the top plate 115. The substrate 109, the partition wall 113 and the top plate 115 are sealed by a cured product of a sealing resin composition thereof. The top plate 115 and the partition wall 113 are both formed by an organic material, and a thickness of the top plate 115, a thickness of the partition wall 113, a width of the partition wall, and a longest width of the hollow part 117 each fall in a particular range. The sealing resin composition comprises: (A)an epoxy resin including one or more kinds selected from a group consisting of an epoxy resin including two epoxy groups in its molecule and an epoxy resin including three or more epoxy resins in its molecule; and (B)an inorganic filler.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a hollow package and a method for manufacturing the same. [Background technology]

[0002] A technology relating to sealing of semiconductor packages is described in Patent Document 1 (US Patent Application Publication No. 2017 / 0047232). This document describes mounting a surface mount element such as a bulk acoustic wave (BAW) filter element on the upper surface of a substrate, and covering and sealing the surface mount element with a sheet-like sealing resin composition. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] US Patent Application Publication No. 2017 / 0047232 Summary of the Invention [Problem to be solved by the invention]

[0004] In recent package development environments, in light of the increasing demand for thinner packages, smaller packages, and narrower terminal pitches, the present inventors have examined the technology described in the above-mentioned documents and found that there is room for improvement in terms of obtaining a package that can stably maintain the hollow structure after molding, even when sealing elements having a hollow portion, and that has excellent filling ability in narrow gaps under the chip.

[0005] Therefore, the present invention provides a sealing technique for obtaining a package that has excellent molding resistance for an element having a hollow portion and excellent filling ability into narrow gaps. [Means for solving the problem]

[0006] According to the present invention, A substrate; one or more elements selected from the group consisting of semiconductor elements, MEMS, and electronic components mounted on the substrate; a partition wall provided on an upper portion of the substrate so as to surround an outer periphery of the element; a top plate provided in contact with an upper surface of the partition wall and covering an upper portion of the element; Equipped with a hollow package having one or more closed hollow portions covered with the substrate, the partition wall, and the top plate, the substrate, the partition wall, and the top plate being sealed with a cured product of an encapsulating resin composition, the top plate and the partition wall are both made of an organic material, The thickness of the top plate is 10 μm or more and 50 μm or less, The thickness of the partition wall is 5 μm or more and 30 μm or less, and the width of the partition wall is 5 μm or more and 200 μm or less, the maximum width of the hollow portion in a cross section perpendicular to the element mounting surface of the substrate is 60 μm or more and 1000 μm or less; The encapsulating resin composition comprises: (A) an epoxy resin containing one or more selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule; and (B) Inorganic filler A hollow package is provided, comprising:

[0007] Further, according to the present invention, Steps 1 and 2 below: (Step 1) A step of forming a partition wall and a top plate made of at least one kind of organic material on a substrate to provide one or more closed hollow portions. (Step 2) A step of compressing and molding the encapsulating resin composition at a low pressure of 0.1 MPa or more and less than 5.0 MPa to resin-encapsulate the substrate, the partition wall, and the top plate. A method for manufacturing a hollow package, comprising: the step 1 includes a step of mounting one or more elements selected from the group consisting of a semiconductor element, a MEMS, and an electronic component on the substrate so that the element is disposed in the hollow portion; The encapsulating resin composition comprises: (A) an epoxy resin containing one or more selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule, and (B) Inorganic filler A method for manufacturing a hollow package is provided, comprising: Effect of the Invention

[0008] According to the present invention, it is possible to provide a sealing technique for obtaining a package that has excellent molding resistance for an element having a hollow portion and excellent filling ability into narrow gaps. [Brief description of the drawings]

[0009] [Figure 1] FIG. 2 is a cross-sectional view showing the configuration of a structure in the present embodiment. [Diagram 2] 5A to 5C are cross-sectional views showing a manufacturing process of the structure in the present embodiment. [Diagram 3] 5A to 5C are cross-sectional views showing a manufacturing process of the structure in the present embodiment. [Figure 4] FIG. 13 is a diagram showing evaluation results of molding resistance of a structure provided with a hollow portion. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] Hereinafter, the embodiments will be described with reference to the drawings. In all the drawings, similar components are given the same reference numerals and the description will be omitted as appropriate. The drawings are schematic diagrams and do not necessarily correspond to the actual dimensional ratios. In addition, the numerical range "X to Y" means "X or more and Y or less" unless otherwise specified.

[0011] (Hollow packages, structures) Fig. 1 is a cross-sectional view showing an example of the configuration of a structure in this embodiment. The structure 100 shown in Fig. 1 has a hollow package 103 and a package 105 mounted on a substrate 101. As the substrate 101, for example, an organic substrate such as an interposer can be used. Both the hollow package 103 and the package 105 are sealed with a sealing material 107. The sealing material 107 is made of a cured product of a sealing resin composition. The hollow package 103 and the package 105 will be described below.

[0012] First, the hollow package 103 will be described. The hollow package 103 includes a substrate 109, one or more elements 111 selected from the group consisting of semiconductor elements, MEMS, and electronic components mounted on the substrate 109, a partition wall 113 provided on the upper portion of the substrate 109 so as to surround the outer periphery of the element 111, and a top plate 115 provided in contact with the upper surface of the partition wall 113 and covering the upper portion of the element 111. The hollow package 103 includes one or more closed hollow portions 117 covered by the substrate 109, the partition wall 113, and the top plate 115. The substrate 109, the partition wall 113, and the top plate 115 are sealed with a sealing material 107. The sealing material 107 is a cured product of a sealing resin composition. The configuration of the sealing resin composition will be described later. The hollow package 103 is flip-chip connected to the substrate 101 by bumps 119 provided on the top plate 115. Wiring (not shown) connecting the bumps 119 to conductors on the substrate 101 may be provided over the upper and side surfaces of the top plate 115, the side surfaces of the partition wall 113, and the upper surface of the substrate 101.

[0013] The element 111 may be one or more selected from the group consisting of a semiconductor element, a MEMS, and an electronic component, and specifically, is an element applied to a package having a hollow structure. Specific examples of such element 111 include high-frequency filters such as a BAW filter and a surface acoustic wave (SAW) filter.

[0014] The material of the substrate 109 can be selected depending on the type of the element 111. The substrate 109 may be a semiconductor substrate such as a silicon substrate. When the element 111 is a high-frequency filter, the material of the substrate 109 is preferably a piezoelectric material such as lithium tantalate (LT) or lithium niobate (LN).

[0015] The sizes of the partition wall 113 and the top plate 115 can be set depending on the size of the element 111 . The thickness of the partition 113 is preferably 5 μm or more, and more preferably 7 μm or more, from the viewpoint of ensuring the hollow space 117 around the element 111. Moreover, from the viewpoint of making the hollow package 103 thinner, the thickness of the partition 113 is preferably 30 μm or less, and more preferably 20 μm or less. From the viewpoint of improving molding resistance, the width of the partition 113 is preferably 5 μm or more, and more preferably 20 μm or more. Also, from the viewpoint of miniaturizing the hollow package 103, the width of the partition 113 is preferably 200 μm or less, and more preferably 100 μm or less. Here, the thickness of the partition wall 113 refers to the length of the partition wall 113 in a direction perpendicular to the substrate 109 , and the width of the partition wall 113 refers to the length of the partition wall 113 in an in-plane direction of the substrate 109 .

[0016] From the viewpoint of improving mold resistance, the thickness of the top plate 115 is preferably 10 μm or more, and more preferably 15 μm or more. Also, from the viewpoint of thinning the hollow package 103, the thickness of the top plate 115 is preferably 50 μm or less, and more preferably 30 μm or less. Here, the thickness of the top plate 115 refers to the length of the top plate 115 in the direction perpendicular to the substrate 109 .

[0017] The maximum width of hollow portion 117 in a cross section perpendicular to the element mounting surface of substrate 109 is preferably 60 μm or more, and more preferably 100 μm or more, from the viewpoint of ensuring hollow portion 117 around element 111. Moreover, from the viewpoint of miniaturizing hollow package 103, the maximum width of hollow portion 117 is preferably 1000 μm or less, and more preferably 800 μm or less. The cross-sectional shape of hollow portion 117 may be, for example, rectangular. The planar shape of hollow portion 117 may be, for example, square, rectangular, polygonal, circular, elliptical, or a combination thereof.

[0018] Both the partition wall 113 and the top plate 115 are preferably made of an organic material, and the materials of the partition wall 113 and the top plate 115 may be the same or different. When at least one of the partition 113 and the top plate 115 is an organic material, such organic material is preferably a photosensitive dry film resist, more preferably a negative type photosensitive dry film resist, and even more preferably a negative type photosensitive dry film resist containing a photoacid generator and an epoxy resin, from the viewpoint of stably forming the partition 113 and the top plate 115 in a simple process. From the same viewpoint, the partition walls 113 and the top plate 115 are preferably made of a cured product of a photosensitive resin composition. The composition of the photosensitive resin composition will be specifically described below.

[0019] (Photosensitive resin composition) As the photosensitive resin composition used to form the partition wall 113 or the top plate 115, various photosensitive resin compositions containing polyimide, polyamide, benzocyclobutene, polybenzoxazole, maleimide, acrylate resin, phenol resin, epoxy resin, or the like as a main component can be used, and for example, those described in International Publication No. 2012 / 008472 can be used. In this case, the photosensitive resin composition preferably contains a photoacid generator and an epoxy resin.

[0020] The photoacid generator preferably contains tris(4-(4-acetylphenyl)thiophenyl)sulfonium tetrakis(pentafluorophenyl)borate, more preferably tris(4-(4-acetylphenyl)thiophenyl)sulfonium tetrakis(pentafluorophenyl)borate. As the tris(4-(4-acetylphenyl)thiophenyl)sulfonium tetrakis(pentafluorophenyl)borate, for example, Irgacure (registered trademark) PAG 290 manufactured by BASF can be used.

[0021] The content of the photoacid generator in the photosensitive resin composition is preferably 0.1% by mass or more and preferably 15% by mass or less, with the total amount of the photoacid generator and the epoxy resin being 100% by mass.

[0022] The epoxy equivalent of the epoxy resin is preferably 150 g / eq or more from the viewpoint of reducing the cure shrinkage rate of the photosensitive resin composition. Also, from the viewpoint of preventing an excessive decrease in the crosslink density of the photosensitive resin composition, which would result in a decrease in the strength, chemical resistance, heat resistance, crack resistance, and the like of the cured film, the epoxy equivalent of the epoxy resin is preferably 500 g / eq or less. Here, the epoxy equivalent is measured by a method in accordance with JIS K7236.

[0023] Moreover, from the viewpoint of suppressing mask sticking and suppressing softening at room temperature, the softening point of the epoxy resin is preferably 40° C. or higher, and more preferably 50° C. or higher. Moreover, from the viewpoint of improving the adhesion to the substrate 109, the softening point of the epoxy resin is preferably 120° C. or lower, and more preferably 100° C. or lower. The softening point is measured by a method in accordance with JIS K7234.

[0024] The epoxy resin more preferably has an epoxy equivalent and a softening point in the above-mentioned ranges. Specific examples of such epoxy resins include EOCN-102S, EOCN-103S, EOCN-104S, EOCN-1020, EOCN-4400H, EPPN-201, EPPN-501H, EPPN-502H, XD-1000, BREN-S, NER-7604, NER-7403, NER-1302, NER-7516, NC-3000H (all trade names, manufactured by Nippon Kayaku Co., Ltd.), Epicoat 157S70 (trade name, manufactured by Mitsubishi Chemical Corporation), and EHPE3150 (trade name, manufactured by Daicel Chemical Industries, Ltd.).

[0025] Specific examples of epoxy resins include novolac type epoxy resins and epoxy resins obtained by oxidation reaction of compounds having olefins. Specific examples of preferred epoxy resins, which have high chemical resistance, plasma resistance and transparency of the cured product and low moisture absorption, include bisphenol A novolac epoxy resins such as Epicoat 157 (manufactured by Mitsubishi Chemical Corporation, epoxy equivalent 180 to 250 g / eq., softening point 80 to 90° C.) and EPON SU-8 (trade name, manufactured by Resolution Performance Products, Inc., epoxy equivalent 195 to 230 g / eq., softening point 80 to 90° C.); Biphenyl-phenol novolac type epoxy resins such as NC-3000 (product name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 270 to 300 g / eq., softening point 55 to 75° C.); Bisphenol A-type or F-type epoxy resins in which some of the alcoholic hydroxyl groups have been epoxidized, such as NER-7604 and NER-7403 (trade names, bisphenol F-type epoxy resins in which some of the alcoholic hydroxyl groups have been epoxidized, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent of 200 to 500 g / eq., softening point of 55 to 75°C), NER-1302 and NER-7516 (trade names, bisphenol A-type epoxy resins in which some of the alcoholic hydroxyl groups have been epoxidized, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent of 200 to 500 g / eq., softening point of 55 to 75°C); Cresol novolac epoxy resins such as EOCN-1020 (product name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 190 to 210 g / eq., softening point 55 to 85° C.); Multifunctional epoxy resins such as NC-6300 (product name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 230 to 235 g / eq., softening point 70 to 72° C.); An epoxy resin obtained by reacting a reaction product of an epoxy resin having at least two epoxy groups in one molecule, such as a polycarboxylic acid epoxy resin (epoxy equivalent is usually 300 to 900 g / eq.), the preparation of which is described in JP-A-10-97070, with a compound having at least one hydroxyl group and one carboxyl group in one molecule, with a polybasic acid anhydride; Trisphenolmethane type epoxy resins such as EPPN-201 (product name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 180 to 200 g / eq., softening point 65 to 78° C.); EPPN-501H (trade name, Nippon Kayaku Co., Ltd., epoxy equivalent 162~172g / eq., softening point 51~57℃), EPPN-501HY (trade name, Nippon Kayaku Co., Ltd., epoxy equivalent 163~175) g / eq., softening point 57~63℃), triphenylmethane type epoxy resin such as EPPN-502H (trade name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 158~178g / eq., softening point 60~72℃); Alicyclic epoxy resins such as EHPE3150 (product name, manufactured by Daicel Chemical Industries, Ltd., epoxy equivalent 170 to 190 g / eq., softening point 70 to 85° C.); Dicyclopentadiene type epoxy resins such as XD-1000 (trade name, manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 245 to 260 g / eq., softening point 68 to 78° C.); and Examples of the epoxy resin include an epoxy resin (having an epoxy equivalent of usually 400 to 900 g / eq.) which is a co-condensation product obtained by the method described in JP-A-2007-291263.

[0026] In order to improve the molding resistance of hollow portion 117, the content of the epoxy resin in the photosensitive resin composition is preferably 85% by mass or more and preferably 99.9% by mass or less, with the total amount of the photoacid generator and the epoxy resin being 100% by mass.

[0027] The photosensitive resin composition may contain components other than the photoacid generator and the epoxy resin. Specific examples of such components include one or more of a miscible reactive epoxy monomer and a solvent. The photosensitive resin composition contains a reactive epoxy monomer, which can improve the performance of the pattern. Specific examples of the reactive epoxy monomer include diethylene glycol diglycidyl ether, hexanediol diglycidyl ether, dimethylolpropane diglycidyl ether, polypropylene glycol diglycidyl ether (ADEKA, ED506), trimethylolpropane triglycidyl ether (ADEKA, ED505), trimethylolpropane triglycidyl ether (low chlorine type, Nagase Chemtex, EX321L), pentaerythritol tetraglycidyl ether, etc., and among these, the low chlorine type that has undergone a low chlorine production method or purification process is preferable. When the total of the photoacid generator, epoxy resin and appropriate reactive epoxy monomer is taken as the solid content of the resist, the content of the reactive epoxy monomer is preferably 10 mass % or less, and more preferably 7 mass % or less, in terms of preventing mask sticking. In this specification, the reactive epoxy monomer refers to an epoxy compound that is liquid at room temperature and has a weight average molecular weight of 1,000 or less calculated in terms of polystyrene based on the results of GPC measurement.

[0028] In addition, by including a solvent in the photosensitive resin composition, the viscosity of the photosensitive resin composition can be reduced and the coating properties can be improved. As the solvent, any organic solvent that is normally used in inks, paints, etc. and can dissolve each component of the photosensitive resin composition can be used without limitation. Specific examples of the solvent include ketones such as acetone, ethyl methyl ketone, cyclohexanone, and cyclopentanone; aromatic hydrocarbons such as toluene, xylene, and tetramethylbenzene; glycol ethers such as dipropylene glycol dimethyl ether and dipropylene glycol diethyl ether; esters such as ethyl acetate, butyl acetate, butyl cellosolve acetate, carbitol acetate, propylene glycol monomethyl ether acetate, and γ-butyrolactone; alcohols such as methanol, ethanol, cellosolve, and methyl cellosolve; aliphatic hydrocarbons such as octane and decane; and petroleum solvents such as petroleum ether, petroleum naphtha, hydrogenated petroleum naphtha, and solvent naphtha. From the viewpoint of appropriately maintaining the solubility of the main component, the volatility of the components, the liquid viscosity of the composition, and the like, the content of the solvent is preferably 10 mass % or more and preferably 95 mass % or less, and more preferably 90 mass % or less, based on the entire photosensitive resin composition.

[0029] The photosensitive resin composition may further contain an adhesion imparting agent from the viewpoint of improving the adhesion of the composition to a substrate. The adhesion imparting agent is, for example, a coupling agent such as a silane coupling agent or a titanium coupling agent, and is preferably a silane coupling agent. The content of the adhesion imparting agent is preferably 15% by mass or less, and more preferably 5% by mass or less, based on the total amount of the photosensitive resin composition, from the viewpoint of suppressing deterioration in the physical properties of the cured film.

[0030] The photosensitive resin composition may further contain a sensitizer from the viewpoint of absorbing ultraviolet light and providing the absorbed light energy to the photoacid generator. Specific examples of the sensitizer include thioxanthones such as 2,4-diethylthioxanthone, and anthracene compounds having C1-C4 alkoxy groups at the 9- and 10-positions (9,10-dialkoxyanthracene derivatives) such as 9,10-dimethoxy-2-ethylanthracene. The 9,10-dialkoxyanthracene derivatives may further have a substituent. More preferably, the sensitizers are 2,4-diethylthioxanthone and 9,10-dimethoxy-2-ethylanthracene. Since the sensitizer is effective even in small amounts, the content thereof is, for example, more than 0 mass % relative to the photoacid generator, and is preferably 30 mass % or less, and more preferably 20 mass % or less.

[0031] In addition, when it is necessary to reduce the influence of ions derived from the photoacid generator, the photosensitive resin composition may further contain an ion scavenger such as an organoaluminum compound. The amount of the ion scavenger blended is, for example, more than 0 mass % and preferably 10 mass % or less, relative to the solid content of the resist, where the total of the photoacid generator, epoxy resin, and appropriately reactive epoxy monomer is the solid content of the resist.

[0032] The photosensitive resin composition may contain various additives such as a thermoplastic resin, a colorant, a thickener, a defoaming agent, and a leveling agent. Examples of the thermoplastic resin include polyethersulfone, polystyrene, and polycarbonate. Examples of colorants include phthalocyanine blue, phthalocyanine green, iodine green, crystal violet, titanium oxide, carbon black, and naphthalene black. Examples of the thickening agent include orben, bentone, and montmorillonite. The antifoaming agent may be, for example, a silicone-based, a fluorine-based, or a polymer-based antifoaming agent. The amount of these additives to be added can be appropriately determined depending on the purpose of use, but is, for example, 0.1% by mass or more and 30% by mass or less, respectively, based on the entire photosensitive resin composition.

[0033] The photosensitive resin composition may further contain an inorganic filler, specific examples of which include barium sulfate, barium titanate, silicon oxide, amorphous silica, talc, clay, magnesium carbonate, calcium carbonate, aluminum oxide, aluminum hydroxide, and mica powder. The mixing ratio of the inorganic filler in the photosensitive resin composition is, for example, more than 0 mass % and, for example, 60 mass % or less.

[0034] From the viewpoint of improving the molding resistance of hollow portion 117, the photosensitive resin composition preferably contains 0.1 parts by mass or more and 15 parts by mass or less of a photoacid generator, 85 parts by mass or more and 99.9 parts by mass or less of an epoxy resin, 1 part by mass or more and 10 parts by mass or less of a reactive epoxy monomer, and 5.8 parts by mass or more and 2090 parts by mass or less of a solvent, and may, if necessary, contain the above-mentioned adhesion imparting agent, sensitizer, ion scavenger, thermoplastic resin, colorant, thickener, defoamer, leveling agent, and inorganic filler.

[0035] Next, a method for producing the photosensitive resin composition will be described. In this embodiment, the photosensitive resin composition is obtained, for example, by mixing and stirring the raw material components in predetermined amounts by a normal method, and may be dispersed and mixed using a dispersing machine such as a dissolver, a homogenizer, a three-roll mill, etc. After mixing, the mixture may be filtered using a mesh, a membrane filter, etc.

[0036] Next, the properties of the photosensitive resin composition will be described. The photosensitive resin composition may be, for example, in a liquid state. The photosensitive resin composition is preferably a dry film resist. The dry film resist is obtained by applying the photosensitive resin composition onto a base film using a roll coater, a die coater, a knife coater, a bar coater, a gravure coater, or the like, and then drying in a drying oven set at, for example, 45°C to 100°C to remove a predetermined amount of solvent. In addition, a cover film or the like may be appropriately laminated on the resist. Specific examples of the base film and cover film that serve as the substrate of the resist include films of polyester, polypropylene, polyethylene, TAC, polyimide, and the like. These films may be release-treated with a silicone-based release treatment agent or a non-silicone-based release treatment agent.

[0037] 1, the package 105 will be described. The package 105 is formed by flip-chip connecting a semiconductor element 121 to the element mounting surface of the substrate 101 via bumps 123. In the package 105, the semiconductor element 121 and the bumps 123 are sealed with a sealing material 107.

[0038] Specific examples of package 105 include QFP (Quad Flat Package), SOP (Small Outline Package), BGA (Ball Grid Array), CSP (Chip Size Package), QFN (Quad Flat Non-leaded Package), SON (Small Outline Non-leaded Package), LF-BGA (Lead Flame BGA), SiP (System In Package), and LGA (Land Grid Allay).

[0039] Next, a description will be given of the sealing material 107. The sealing material 107 is a cured product of a sealing resin composition. In Fig. 1, the sealing material 107 is provided over the entire element mounting surface of the substrate 101, and seals the hollow package 103 and the package 105.

[0040] (Sealing resin composition) In this embodiment, the encapsulating resin composition is used to encapsulate the substrate 109, the partition wall 113, and the top plate 115 of the hollow package 103, and contains the following components (A) and (B). (A) An epoxy resin containing one or more kinds selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule. (B) Inorganic filler

[0041] (Component (A)) The epoxy resin of component (A) includes one or more types selected from the group consisting of epoxy resins containing two epoxy groups in the molecule and epoxy resins containing three or more epoxy groups in the molecule. From the viewpoint of improving the filling characteristics of the encapsulating resin composition and the molding resistance of the hollow package, component (A) preferably contains one or more types selected from the group consisting of biphenylaralkyl-type epoxy resins; triphenylmethane-type epoxy resins; biphenyl-type epoxy resins; and bisphenol-type epoxy resins such as bisphenol A-type epoxy resins, bisphenol F-type epoxy resins, and tetramethylbisphenol F-type epoxy resins, and more preferably contains one or more types selected from the group consisting of biphenylaralkyl-type epoxy resins, bisphenol A-type epoxy resins, and bisphenol A-type epoxy resins.

[0042] From the viewpoint of obtaining suitable fluidity during molding and improving filling property and moldability, the content of component (A) in the encapsulating resin composition is preferably 2 mass% or more, more preferably 3 mass% or more, and even more preferably 4 mass% or more, when the entire encapsulating resin composition is taken as 100 mass%. From the viewpoint of improving the molding resistance of the hollow package 103, the content of component (A) in the encapsulating resin composition is preferably 40 mass% or less, more preferably 30 mass% or less, even more preferably 15 mass% or less, and even more preferably 10 mass% or less, when the entire encapsulating resin composition is 100 mass%.

[0043] (Component (B)) As the inorganic filler of component (B), those generally used in encapsulating resin compositions can be used. Specific examples of inorganic fillers include silica such as fused silica and crystalline silica; alumina; talc; titanium oxide; silicon nitride; and aluminum nitride. These inorganic fillers may be used alone or in combination of two or more. Among these, from the viewpoint of excellent versatility, it is preferable that the inorganic filler contains silica, and it is more preferable to use fused silica.

[0044] Regarding the size of the inorganic filler, from the viewpoint of increasing the fluidity of the encapsulating resin composition and filling the encapsulating resin composition between the element 111 such as a semiconductor element and the substrate without generating voids, the content of the undersize fraction when passed through a sieve with an opening of 20 μm is preferably 80 mass% or more, more preferably 90 mass% or more, and even more preferably 100 mass% relative to the entire inorganic filler. There is no upper limit to the content of the undersize fraction when passed through the sieve with an opening of 20 μm, and it is 100 mass% or less.

[0045] The content of the inorganic filler in the encapsulating resin composition is preferably 50 mass % or more, more preferably 70 mass % or more, and even more preferably 80 mass % or more, when the entire encapsulating resin composition is taken as 100 mass %, from the viewpoint of improving the low moisture absorption and low thermal expansion properties of the encapsulating material formed using the encapsulating resin composition and more effectively improving the moisture resistance reliability and reflow resistance of the obtained semiconductor device. In addition, from the viewpoint of more effectively improving the fluidity and filling property during molding of the encapsulating resin composition, the total content of the inorganic filler in the encapsulating resin composition is preferably 95 mass % or less, more preferably 93 mass % or less, and even more preferably 90 mass % or less, when the entire encapsulating resin composition is taken as 100 mass %.

[0046] In the present embodiment, the encapsulating resin composition may contain components other than the epoxy resin and the inorganic filler. For example, the encapsulating resin composition may further include a curing agent.

[0047] (hardening agent) The curing agents can be roughly divided into three types, for example, polyaddition type curing agents, catalyst type curing agents, and condensation type curing agents, and one or more of these can be used.

[0048] Examples of the polyaddition type curing agent include aliphatic polyamines such as diethylenetriamine (DETA), triethylenetetramine (TETA), and metaxylylenediamine (MXDA), aromatic polyamines such as diaminodiphenylmethane (DDM), m-phenylenediamine (MPDA), and diaminodiphenylsulfone (DDS), as well as polyamine compounds including dicyandiamide (DICY) and organic acid dihydrazides; alicyclic acid anhydrides such as hexahydrophthalic anhydride (HHPA), methyltetrahydrophthalic anhydride (MTHPA), and aromatic acid anhydrides such as trimellitic anhydride (TMA), pyromellitic anhydride (PMDA), and benzophenonetetracarboxylic acid (BTDA); phenolic resin curing agents such as novolac-type phenolic resins and polyvinylphenol; polymercaptan compounds such as polysulfide, thioester, and thioether; isocyanate compounds such as isocyanate prepolymers and blocked isocyanates; and organic acids such as carboxylic acid-containing polyester resins.

[0049] Examples of catalyst-type curing agents include tertiary amine compounds such as benzyldimethylamine (BDMA) and 2,4,6-trisdimethylaminomethylphenol (DMP-30); imidazole compounds such as 2-methylimidazole and 2-ethyl-4-methylimidazole (EMI24); BF 3 Lewis acids such as complexes.

[0050] Condensation type curing agents include, for example, phenol resins; urea resins such as methylol group-containing urea resins; and melamine resins such as methylol group-containing melamine resins.

[0051] Among these, phenolic resin curing agents are preferred from the viewpoint of improving the balance of flame resistance, moisture resistance, electrical properties, curability, storage stability, etc. As the phenolic resin curing agent, any monomer, oligomer, or polymer having two or more phenolic hydroxyl groups in one molecule can be used, and the molecular weight and molecular structure thereof are not limited.

[0052] Examples of phenolic resin curing agents used in the curing agent include biphenyl aralkyl type phenolic resins; novolac type phenolic resins such as phenol novolac resins, cresol novolac resins, and bisphenol novolac; polyvinylphenol; multifunctional phenolic resins such as phenol-hydroxybenzaldehyde resins, triphenylmethane type phenolic resins, and modified triphenylmethane type phenolic resins such as triphenylmethane type phenolic resins modified with formaldehyde; modified phenolic resins such as terpene modified phenolic resins and dicyclopentadiene modified phenolic resins; aralkyl type phenolic resins such as phenol aralkyl resins having a phenylene skeleton and / or biphenylene skeleton, and naphthol aralkyl resins having a phenylene skeleton and / or biphenylene skeleton; bisphenol compounds such as bisphenol A and bisphenol F, and the like. These may be used alone or in combination of two or more. Among these, from the viewpoint of improving heat resistance and filling property, it is more preferable to use multifunctional phenolic resins such as phenol-hydroxybenzaldehyde resins. From the same viewpoint, it is also preferable to use one or more resins selected from the group consisting of biphenylaralkyl-based phenolic resins and triphenylmethane-type phenolic resins.

[0053] In the present embodiment, the content of the curing agent in the encapsulating resin composition is preferably 1 mass % or more, more preferably 2 mass % or more, and even more preferably 3 mass % or more, when the entire encapsulating resin composition is taken as 100 mass %, from the viewpoint of realizing excellent fluidity during molding and improving filling property and moldability. In addition, in a semiconductor device using a cured product of the encapsulating resin composition as an encapsulant, from the viewpoint of improving moisture resistance reliability and reflow resistance, the content of the curing agent in the encapsulating resin composition is preferably 25 mass % or less, more preferably 15 mass % or less, and even more preferably 10 mass % or less, when the entire encapsulating resin composition is taken as 100 mass %.

[0054] The encapsulating resin composition may contain components other than the above-mentioned components. For example, one or more of various additives such as a coupling agent, a curing accelerator, a fluidity imparting agent, a release agent, an ion scavenger, a low stress component, a flame retardant, a colorant, and an antioxidant may be appropriately blended. Of these, the coupling agent can include one or more types selected from known coupling agents such as aminosilanes such as epoxysilane, mercaptosilane, secondary aminosilane, various silane compounds such as alkylsilane, ureidosilane, vinylsilane, and methacrylsilane, titanium compounds, aluminum chelates, and aluminum / zirconium compounds. The curing accelerator may contain one or more of phosphorus atom-containing compounds such as organic phosphines, tetra-substituted phosphonium compounds, phosphobetaine compounds, adducts of phosphine compounds and quinone compounds, and adducts of phosphonium compounds and silane compounds; and nitrogen atom-containing compounds such as amidines and tertiary amines, exemplified by 1,8-diazabicyclo[5.4.0]undecene-7, benzyldimethylamine, and 2-methylimidazole, and quaternary salts of the above amidines and amines. Among these, it is more preferable to contain a phosphorus atom-containing compound from the viewpoint of improving the curability. In addition, it is more preferable to contain a compound having latency, such as a tetra-substituted phosphonium compound, a phosphobetaine compound, an adduct of a phosphine compound and a quinone compound, or an adduct of a phosphonium compound and a silane compound, from the viewpoint of improving the balance between moldability and curability. A specific example of the fluidity imparting agent is 2,3-dihydroxynaphthalene. The release agent may contain one or more types selected from natural waxes such as carnauba wax, synthetic waxes such as Montan acid ester wax, higher fatty acids such as zinc stearate and metal salts thereof, and paraffin. A specific example of the ion scavenger is hydrotalcite. Specific examples of low stress components include silicone oil and silicone rubber. Specific examples of flame retardants include aluminum hydroxide, magnesium hydroxide, zinc borate, zinc molybdate, and phosphazene. Specific examples of colorants include carbon black and red iron oxide. Specific examples of the antioxidant include hindered phenol compounds, hindered amine compounds, and thioether compounds.

[0055] The glass transition temperature (Tg) of the cured product of the encapsulating resin composition is preferably 100° C. or higher, more preferably 110° C. or higher, and even more preferably 120° C. or higher, from the viewpoint of improving the heat resistance of the cured product. There is no upper limit to the Tg of the cured product, but from the viewpoint of improving the toughness of the cured product, it is preferably 200° C. or lower, more preferably 180° C. or lower, and even more preferably 160° C. or lower. Here, the glass transition temperature of the cured product is measured using a Thermal Mechanical Analysis (TMA) device (TMA100, manufactured by Seiko Instruments Inc.) under conditions of a measurement temperature range of 0° C. to 320° C. and a temperature rise rate of 5° C. / min.

[0056] In the present embodiment, the shape of the encapsulating resin composition is preferably a tablet or granular shape. Specific examples of the granular encapsulating resin composition include those in the form of powder or granule. Here, the encapsulating resin composition being in the form of powder or granule means that the encapsulating resin composition is in the form of either powder or granule.

[0057] Next, a method for producing the encapsulating resin composition will be described. In the present embodiment, the encapsulating resin composition can be obtained, for example, by mixing the above-mentioned components by a known means, melt-kneading the mixture with a kneader such as a roll, a kneader, or an extruder, cooling the mixture, and then pulverizing the mixture. The degree of dispersion, flowability, and the like of the obtained encapsulating resin composition may be appropriately adjusted.

[0058] In this embodiment, by using the photosensitive resin composition and the encapsulating resin composition having the above-described configurations and setting the sizes of the partition 113 and the top plate 115 to predetermined sizes, the hollow portion 117 in the hollow package 103 is stably maintained and a structure 100 having excellent filling properties for narrow gaps such as between multiple bumps 123 can be obtained.

[0059] 1 shows an example in which hollow package 103 and package 105 are mounted on substrate 101, but in this embodiment, the structure may be one in which only hollow packages are mounted, or one in which hollow packages are mixed with elements that do not have hollow portions. When the structure includes multiple packages, the multiple packages may be separated into individual packages in a later process.

[0060] Next, a description will be given of a method for manufacturing the hollow package 103 and the structure 100 including the hollow package 103. In this embodiment, the method for manufacturing the hollow package 103 includes the following steps 1 and 2. (Step 1) A step of forming a partition wall 113 and a top plate 115 made of at least one kind of organic material on a substrate 109 to provide one or more closed hollow spaces 117. (Step 2) A step of compressing and molding the sealing resin composition of the present embodiment described above at a low pressure of 0.1 MPa or more and less than 5.0 MPa to resin-seal the substrate 109, the partition wall 113, and the top plate 115. Hereinafter, a more specific description will be given with reference to Figures 2(a) to 2(d), which are cross-sectional views showing the manufacturing process of the structure 100.

[0061] First, as shown in FIG. 2( a ), an element 111 is mounted on a substrate 109 . 2(b), a partition 113 that surrounds the outer periphery of the element 111 is formed at a distance from the element 111 on the element mounting surface of the substrate 109, and a top plate 115 that covers the upper part of the partition 113 is formed on the partition 113, and a hollow portion 117 is provided. However, as described later with reference to FIGS. 3(a) to 3(e), in some cases, the element 111 may be mounted after the partition is formed, and the top plate 115 may be formed last.

[0062] The partition walls 113 and the top plate 115 having a predetermined planar shape can be formed, for example, using the above-mentioned photosensitive resin composition and the method described in WO 2012 / 008472. Specifically, when a liquid photosensitive resin composition is used, the photosensitive resin composition is applied to a thickness of, for example, 0.1 μm to 1000 μm on the substrate 109 on which the elements 111 are provided, for example, using a spin coater or the like, and the solvent is removed by heat treatment, for example, at 60° C. to 130° C. for 5 minutes to 60 minutes to form a photosensitive resin composition layer. Thereafter, a mask having a pattern corresponding to the planar shape of the partition wall 113 is placed on the substrate, and ultraviolet rays are irradiated, followed by heat treatment, for example, at 50° C. to 130° C. for 1 minute to 50 minutes. Thereafter, the unexposed portions are developed using a developer, for example, at 15° C. to 50° C. for 1 minute to 180 minutes to form a pattern. This is then heated at a temperature of, for example, 130° C. to 200° C. to obtain a permanent protective film. As the developer, for example, an organic solvent such as γ-butyrolactone, triethylene glycol dimethyl ether, or propylene glycol monomethyl ether acetate, or a mixture of these organic solvents with water, can be used. For development, a paddle-type, spray-type, or shower-type developing device can be used, and ultrasonic irradiation can be used as appropriate.

[0063] Furthermore, when using a dry film resist, for example, the cover film is removed, and the resist is transferred to the substrate 109 using a hand roll, a laminator, or the like at a temperature of, for example, 30°C or more and 100°C or less and a pressure of 0.05 MPa or more and 2 MPa or less, and then exposed, post-exposure baked, developed, and heated in the same manner as in the case of a liquid photosensitive resin composition. After the partition walls 113 are formed, the top plate 115 can be formed in accordance with the method for using the above-mentioned dry film resist. By using a film-like photosensitive resin composition (dry film resist), the steps of applying to the substrate 109 and drying can be omitted, so that the manufacturing process of the partition wall 113 and the top plate 115 can be simplified.

[0064] After the top plate 115 is formed, bumps 119 such as solder bumps are formed at predetermined positions on the upper surface of the top plate 115, that is, on the back surface of the surface to be bonded to the partition wall 113 (FIG. 2(b)).

[0065] Figures 2(a) and 2(b) show an example in which multiple elements 111 are mounted on a substrate 109. In this case, as shown in Figure 2(c), the substrate 109 is diced into individual elements 111 to obtain multiple packages.

[0066] Next, the individual packages are flip-chip connected to predetermined positions on the substrate 101 via bumps 119. In manufacturing the structure 100, a semiconductor element 121 is also flip-chip connected to predetermined positions on the substrate 101 via bumps 123 (FIG. 2(d)).

[0067] Thereafter, the element mounting surface of the substrate 101 is sealed with the sealing resin composition of this embodiment to form the sealing material 107. At this time, from the viewpoint of improving the molding resistance of the hollow package 103 and improving the filling ability into narrow gaps such as between the bumps 123, the sealing material 107 is preferably formed by compression molding. From a similar viewpoint, the molding pressure in compression molding is preferably 0.1 MPa or more, more preferably 0.5 MPa or more, and also preferably less than 5.0 MPa, more preferably 3.0 MPa or less, even more preferably 2.0 MPa or less, and even more preferably 1.0 MPa or less.

[0068] Through the above steps, a structure 100 including a hollow package 103 and a package 105 can be obtained. In this embodiment, by performing low-pressure molding by a compression molding method using an encapsulating resin composition containing components (A) and (B), it is possible to provide excellent molding resistance for the hollow portion 117 provided in the hollow package 103, and also to provide excellent filling characteristics for the gaps between the bumps 123 in the package 105, even when the bumps 123 are arranged at a narrow pitch.

[0069] In the above, after the elements 111 are mounted on the substrate 109, the partition walls 113 and the top plate 115 are formed, but the order of forming the components may be different. For example, Figures 3(a) to 3(e) are cross-sectional views showing other manufacturing steps of the structure 110.

[0070] 3(a) to 3(e), first, partitions 113 are formed at predetermined positions on substrate 109 (FIG. 3(a)). Then, element 111 is mounted on substrate 109 so that its periphery is surrounded by partitions 113 (FIG. 3(b)). Next, a top plate 115 is formed on the partition wall 113 to cover the upper portion of the partition wall 113, and a hollow portion 117 is provided (FIG. 3(c)). Each of these steps can be carried out, for example, in accordance with the steps described above with reference to Figures 2(a) and 2(b).

[0071] 2(b) and 2(c), bumps 119 such as solder bumps are formed (FIG. 3(c)), and the substrate 109 is divided into individual elements 111 to obtain a plurality of packages (FIG. 3(d)). Then, the divided packages are flip-chip connected to predetermined positions on the substrate 101 (FIG. 3(e)), in accordance with the process shown in FIG. 2(d).

[0072] The above steps also provide the structure 100 including the hollow package 103 and the package 105, and provide the same effects as those described above.

[0073] The present invention has been described above based on the embodiments, but the present invention is not limited to the above embodiments, and the configuration can be changed without departing from the gist of the present invention. Below, examples of reference forms are given. 1. A substrate; one or more elements selected from the group consisting of semiconductor elements, MEMS, and electronic components mounted on the substrate; a partition wall provided on an upper portion of the substrate so as to surround an outer periphery of the element; a top plate provided in contact with an upper surface of the partition wall and covering an upper portion of the element; Equipped with a hollow package having one or more closed hollow portions covered with the substrate, the partition wall, and the top plate, the substrate, the partition wall, and the top plate being sealed with a cured product of an encapsulating resin composition, the top plate and the partition wall are both made of an organic material, The thickness of the top plate is 10 μm or more and 50 μm or less, The thickness of the partition wall is 5 μm or more and 30 μm or less, and the width of the partition wall is 5 μm or more and 200 μm or less, the maximum width of the hollow portion in a cross section perpendicular to the element mounting surface of the substrate is 60 μm or more and 1000 μm or less; The encapsulating resin composition comprises: (A) an epoxy resin containing one or more selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule; and (B) Inorganic filler Including, hollow package. 2. The hollow package according to claim 1, wherein the organic material is a photosensitive dry film resist. 3. The hollow package according to 2., wherein the organic material is a negative photosensitive dry film resist. 4. The hollow package according to 3., wherein the organic material is a negative photosensitive dry film resist containing a photoacid generator and an epoxy resin. 5. The hollow package described in any one of 1. to 4., wherein the component (A) contains one or more resins selected from the group consisting of biphenyl aralkyl type epoxy resins, triphenylmethane type epoxy resins, biphenyl type epoxy resins and bisphenol type epoxy resins. 6. Steps 1 and 2 below: (Step 1) A step of forming a partition wall and a top plate made of at least one kind of organic material on a substrate to provide one or more closed hollow portions. (Step 2) A step of compressing and molding the encapsulating resin composition at a low pressure of 0.1 MPa or more and less than 5.0 MPa to resin-encapsulate the substrate, the partition wall, and the top plate. A method for manufacturing a hollow package, comprising: the step 1 includes a step of mounting one or more elements selected from the group consisting of a semiconductor element, a MEMS, and an electronic component on the substrate so that the element is disposed in the hollow portion; The encapsulating resin composition comprises: (A) an epoxy resin containing one or more selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule, and (B) Inorganic filler A method for manufacturing a hollow package, comprising: 7. The method for producing a hollow package according to 6., wherein the organic material is a photosensitive dry film resist. 8. The method for producing a hollow package according to 7., wherein the organic material is a negative photosensitive dry film resist. 9. The method for producing a hollow package according to 8., wherein the organic material is a negative photosensitive dry film resist containing a photoacid generator and an epoxy resin. 10. A method for producing a hollow package described in any one of 6. to 9., wherein the component (A) contains one or more types selected from the group consisting of biphenyl aralkyl type epoxy resins, triphenylmethane type epoxy resins, biphenyl type epoxy resins and bisphenol type epoxy resins. EXAMPLES

[0074] Hereinafter, the present embodiment will be described in detail with reference to examples. However, the present embodiment is not limited to the description of these examples.

[0075] Example 1 An encapsulating resin composition was prepared according to the formulation shown in Table 1, and a device was encapsulated with the cured product of the resulting composition, and the filling characteristics and molding resistance of the hollow portion were evaluated. First, the raw material components of the encapsulating resin composition used in the following examples will be shown. (Epoxy resin) Epoxy resin 1: A mixed resin of a biphenylene skeleton-containing phenol aralkyl type epoxy resin (manufactured by Nippon Kayaku Co., Ltd., NC3000L) and a bisphenol A type epoxy resin (manufactured by Javan Epoxy Resins Co., Ltd., jER (registered trademark) YL6810) Epoxy resin 2: phenol aralkyl type epoxy resin containing a biphenylene skeleton (manufactured by Nippon Kayaku Co., Ltd., NC3000L) (hardening agent) Hardener 1: Phenol aralkyl resin containing biphenylene skeleton (MEH-7851SS, manufactured by Meiwa Kasei Co., Ltd.) (catalyst) Catalyst 1: Tetraphenylphosphonium bis(naphthalene-2,3-dioxy)phenylsilicate and tetraphenylphosphonium-4,4'-sulfonyldiphenolate (Inorganic filler) Inorganic filler 1: Fused spherical silica (Micron Corporation, TS-6021) Fraction passing through a sieve with 20 μm openings: 100% by mass

[0076] (Preparation of Encapsulating Resin Composition) Based on the formulation shown in Table 1, the raw materials were kneaded using a twin-screw kneading extruder at 110° C. for 7 minutes. The kneaded product thus obtained was degassed, cooled, and then pulverized using a pulverizer to obtain a granular encapsulating resin composition.

[0077] (Physical Properties of the Encapsulating Resin Composition) (Tg) The obtained encapsulating resin composition was compression molded in a mold using a compression molding machine (TOWA PMC1040) under the conditions of a mold temperature of 175°C, molding pressure of 9.8 MPa, and curing time of 300 seconds to obtain a cured product. The cured product had a length of 10 mm, a width of 4 mm, and a thickness of 4 mm. The obtained cured product was then post-cured at 175°C for 4 hours, and then measured using a thermomechanical analyzer (Seiko Electronics Industries, Inc., TMA100) under conditions of a measurement temperature range of 0°C to 320°C and a heating rate of 5°C / min, to calculate Tg.

[0078] (evaluation) (Filling characteristics) On a substrate (printed wiring board with a copper circuit), a semiconductor element having a thickness of 100 μm and a size of 5 mm×5 mm was flip-chip connected with a bump. The bump material was Cu, the bump height was 50 μm, the bump diameter was 90 μm, and the pitch between the bumps was 90 μm. Six of the above semiconductor elements were bonded onto one substrate, and the substrate was fixed to the upper mold by a substrate fixing means so that the surface on which the semiconductor elements were mounted faced downward. Next, a resin granule made of an encapsulating resin composition was supplied into the lower mold cavity, and then the cavity was decompressed and the panel was molded by a compression molding machine (manufactured by TOWA Corporation) to obtain a molded product. The molding conditions at this time were a mold temperature of 150° C. or 175° C., a molding pressure of 1.0 MPa or 2.0 MPa, and a curing time of 300 seconds. The obtained molded product was not divided into individual pieces, but was evaluated as it is using a microscope manufactured by Keyence Corp. The six semiconductor elements were checked for the presence or absence of filling defects such as unfilled areas and voids in the areas between the bumps, and the number of elements with filling defects out of the six elements was taken as the filling defect occurrence rate (%).

[0079] [Table 1]

[0080] As can be seen from Table 1, the encapsulating resin composition obtained in Example 1 was excellent in filling narrow gaps.

[0081] (Molding resistance of hollow parts) A structure having a hollow portion was sealed with the sealing resin composition of Example 1, and the moldability of the hollow portion was evaluated.

[0082] As the negative photosensitive dry film resist, SU-8 3000CF DFR series (product name, manufactured by Nippon Kayaku Co., Ltd., dry film resists containing epoxy resin, photoacid generator, etc., with thicknesses of 20 μm (3020CF), 30 μm (3030CF), and 45 μm (3045CF)) were used.

[0083] The structure having a hollow portion was formed by the following procedure. That is, the cover film of the negative photosensitive dry film resist was peeled off on a silicon wafer, and the laminate was performed a predetermined number of times at a roll temperature of 70°C, an air pressure of 0.2 MPa, and a speed of 0.5 m / min to obtain a photosensitive resin composition layer of a predetermined thickness. This photosensitive resin composition layer was subjected to pattern exposure (soft contact, i-line) using an i-line exposure device (mask aligner: manufactured by Ushio Inc.). After that, the layer was baked after exposure for 4 minutes at 95°C using a hot plate, and developed for 5 minutes at 23°C using propylene glycol monomethyl ether acetate (PGMEA) by an immersion method to obtain a hardened resin pattern on the wafer. Then, the layer was hard baked at 180°C for 60 minutes using a hot air convection oven. The obtained resin pattern had a shape in which line-shaped resins of a predetermined height and width were arranged in parallel at a predetermined interval, and this was used as a partition wall. Next, the cover film of the photosensitive dry film resist was peeled off, and the wafer on which the partition walls were formed was laminated a predetermined number of times at a roll temperature of 40° C., an air pressure of 0.1 MPa, and a speed of 1.0 m / min to obtain a photosensitive resin composition layer of a predetermined thickness. Then, pattern exposure, post-exposure baking, development treatment, and hard baking were performed in accordance with the method for forming the partition walls to form a resin pattern of a predetermined width and thickness covering the upper portion between adjacent partition walls, which was used as a top plate. The sizes of the partitions and top plate are shown below. Partition thickness (gap height): 20μm Distance between partition walls (width of gap): 10 to 500 μm (created every 10 μm) Width of partition wall: 30μm Thickness of top plate: 20μm, 30μm or 45μm Width of top plate: The sum of the widths of both partition walls (60μm) added to the spacing between the partition walls. 70~560μm

[0084] The wafer on which the structure consisting of the top plate and the partition wall was formed was placed in a compression molding machine (manufactured by TOWA Corporation), and a sample was obtained by compression molding using the encapsulating resin composition of Example 1. The compression molding conditions were a mold temperature of 175°C, a molding pressure of 1.0 MPa, 2.0 MPa or 3.0 MPa, and a curing time of 120 seconds.

[0085] The moldability of the hollow portion was evaluated for the samples obtained in Example 1. That is, for each sample, the cross section of the hollow portion was observed with a scanning electron microscope, and the maximum cap displacement (δmax) of the top plate was measured based on the following, and samples with δmax of less than 5 μm were deemed to have passed. δmax = Height of top surface above bulkhead - Height of top surface at midpoint of bulkhead spacing

[0086] FIG. 4 is a diagram showing the relationship between the molding pressure (MPa) for each top plate thickness and the maximum top plate width (μm) at which δmax was acceptable. [Explanation of symbols]

[0087] 100 structures 101 Substrate 103 Hollow Package 105 Packages 107 Encapsulating materials 109 Board 111 elements 113 Bulkhead 115 Tabletop 117 Hollow part 119 Bump 121 Semiconductor elements 123 Bump

Claims

1. forming a partition wall and a top plate made of at least one kind of organic material on a substrate, thereby providing one or more closed hollow portions; A step of compressing and molding the encapsulating resin composition at a pressure of 0.1 MPa or more and less than 5.0 MPa to resin-encapsulate the substrate, the partition wall, and the top plate. A method for manufacturing a hollow package, comprising: one or more elements selected from the group consisting of a semiconductor element, a MEMS, and an electronic component are mounted on the substrate so as to be disposed in the hollow portion; The encapsulating resin composition comprises: (A) an epoxy resin containing one or more kinds selected from the group consisting of an epoxy resin containing two epoxy groups in the molecule and an epoxy resin containing three or more epoxy groups in the molecule; (B) an inorganic filler, and Phenolic resin hardener Including, the component (A) comprises one or more selected from the group consisting of biphenyl aralkyl type epoxy resins, triphenylmethane type epoxy resins, biphenyl type epoxy resins, and bisphenol type epoxy resins, the content of component (A) in the encapsulating resin composition is 2% by mass or more and 30% by mass or less with respect to the entire encapsulating resin composition, The content of the component (B) in the encapsulating resin composition is 50% by mass or more and 95% by mass or less with respect to the entire encapsulating resin composition, the glass transition temperature of the cured product of the encapsulating resin composition is 100° C. or higher and 200° C. or lower, as measured by a thermomechanical analyzer; the organic material constituting the top plate is a negative photosensitive dry film resist, the organic material constituting the partition wall is a photosensitive resin composition, The main component of the organic material is polyimide, polyamide, polybenzoxazole, maleimide, acrylate resin, phenolic resin or epoxy resin.

2. The method for producing a hollow package according to claim 1 , wherein the component (B) comprises silica.

3. The method for producing a hollow package according to claim 1 or 2, wherein the encapsulating resin composition further contains a phenolic resin curing agent.

4. The method for producing a hollow package according to claim 1 , wherein the encapsulating resin composition further contains a curing accelerator.

5. The thickness of the top plate is 10 μm or more and 50 μm or less, The thickness of the partition wall is 5 μm or more and 30 μm or less, and the width of the partition wall is 5 μm or more and 200 μm or less, The method for manufacturing a hollow package according to claim 1 , wherein the maximum width of the hollow portion in a cross section perpendicular to the element mounting surface of the substrate is 60 μm or more and 1000 μm or less.

6. A method for manufacturing a hollow package described in any one of claims 1 to 5, wherein the organic material constituting the partition is a negative photosensitive dry film resist.

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