Flame-resistant polymer compositions and articles made therefrom - Patents.com

Abstract

Disclosed is a halogen-free, flame-resistant polymer composition. The polymer composition contains a thermoplastic polymer, such as polybutylene terephthalate. The thermoplastic polymer is combined with a flame retardant, including a phosphinate, a phosphite, and a nitrogen-containing synergist. Additionally, the composition may contain a fluoropolymer and an organometallic compatibilizer. The flame-resistant composition exhibits excellent flame retardancy, even when the thermoplastic polymer is present in an amount greater than 60% by weight.

Description

[Technical field]

[0001]

[0001] This application claims priority to U.S. Provisional Patent Application No. 62 / 868,061, filed June 28, 2019, which is incorporated herein by reference. [Background technology]

[0002]

[0002] Engineering thermoplastic and elastomeric materials are often used in many different applications to produce molded parts and products. For example, polyester polymers and polyester elastomers are used to produce all kinds of different types of molded articles, such as injection molded articles, blow molded articles, and the like. For example, polyester polymers can be formulated to be chemically resistant, to have excellent strength properties, and, when formulating compositions containing polyester elastomers, to be flexible. Particularly advantageously, polyester polymers can be melt processed due to their thermoplastic nature. Additionally, polyester polymers can be recycled and reprocessed.

[0003]

[0003] One problem faced by those skilled in the art when producing molded parts and products from thermoplastic polymers is the ability to make the article flame resistant. Although an almost endless variety of flame retardants are commercially marketed and sold, selecting the right flame retardant for a particular thermoplastic polymer composition can be difficult and unpredictable. Furthermore, many available flame retardants contain halogen compounds, such as bromine compounds, which can produce harsh chemical fumes during manufacturing.

[0004]

[0004] In view of the above, various halogen-free flame retardants have been developed and tested. In particular, a wide variety of phosphorus compounds have been used as flame retardants in thermoplastic polymer compositions. However, to meet certain requirements, phosphorus compounds are typically combined with many other various adjuvants, such as other polymers and fillers. However, phosphorus-based flame retardant packages tend to seriously and adversely affect the physical properties of the polymer, including the ability to melt process the polymer. Furthermore, many flame retardant packages do not provide satisfactory flame retardancy for many applications.

[0005] In view of the above, there is currently a need for non-halogen flame retardant compositions that can be used with thermoplastic polymers. There is also a need for flame retardant compositions for thermoplastic polymers that maintain various polymer properties, such as maintaining flowability. Summary of the Invention

[0006]

[0006] Generally, the present disclosure is directed to a polymer composition that includes a thermoplastic polymer in combination with a flame retardant composition. The components of the flame retardant composition are carefully selected to produce a polymer composition with improved flame resistance. For example, the polymer composition may exhibit a V-0 rating at a thickness of 0.4 mm when tested according to Underwriters Laboratories Test 94. Additionally, the components of the flame retardant composition are also selected to maintain various physical properties of the polymer composition.

[0007]

[0007] In one embodiment, for example, the present disclosure is directed to a flame-resistant polymer composition containing a thermoplastic polymer. The thermoplastic polymer can typically be present in the polymer composition in an amount greater than about 40% by weight, such as greater than about 60% by weight, greater than about 65% by weight, greater than about 70% by weight, greater than about 75% by weight, etc. Any suitable thermoplastic polymer, such as polyolefin, polyamide, and polyester polymers, may be used in the polymer composition of the present disclosure. However, the flame retardant composition of the present disclosure is particularly well suited for blending with polyester polymers, such as polybutylene terephthalate.

[0008]

[0008] According to the present disclosure, a thermoplastic polymer is combined with a flame retardant composition comprising a combination of a metal phosphinate, a metal phosphite and a nitrogen-containing synergist. The metal phosphite may, for example, comprise aluminum phosphite of the formula: Al2(HPO3)3. Meanwhile, the metal phosphinate may be a dialkyl phosphinate, such as aluminum diethylphosphinate. The nitrogen-containing synergist may comprise melamine, such as melamine cyanurate. In one embodiment, the metal phosphinate is present in the polymer composition in an amount of about 5% to about 30% by weight, such as about 10% to about 25% by weight, such as about 12% to about 19% by weight, etc. The metal phosphite can typically be present in the polymer composition in an amount of about 0.5% to about 9% by weight, such as about 1% to about 7% by weight, such as about 2% to about 5% by weight, etc. On the other hand, the nitrogen-containing synergist may typically be present in the polymer composition in an amount of about 0.01% to about 7% by weight, such as about 0.3% to about 4% by weight, about 0.5% to about 2.3% by weight, and the like.

[0009]

[0009] The flame-resistant polymer composition may further contain polytetrafluoroethylene. The polytetrafluoroethylene may be present in the polymer composition in an amount of, for example, about 0.1% to about 5% by weight.

[0010] The flame-resistant polymer composition may also contain an organometallic compatibilizer. The organometallic compatibilizer may be, for example, a titanate. One example of a titanate that may be used is titanium(IV) 2-propanolate, tris(dioctyl)phosphato-O. The organometallic compatibilizer may be present in the polymer composition in an amount typically between about 0.05% and about 2.5% by weight. The flame-resistant polymer composition may also contain a carboxylic acid ester. For example, the ester may be formed by reacting montanic acid with a polyfunctional alcohol. The polyfunctional alcohol may be ethylene glycol or glycerin. The carboxylic acid ester may be present in the polymer composition in an amount typically between about 0.05% and about 8% by weight. In one aspect, the flame-resistant polymer composition may be formulated to be free of metal oxides, metal hydroxides, metal borates, and metal stannates. In the past, these components were typically used as flame retardant adjuvants and were taught to be necessary in many formulations. However, it has been found that omitting one or more of the above components results in a polymer composition having superior physical properties, including flowability.

[0011] For example, the flame-resistant polymer composition of the present disclosure has a flame retardant strength of at least 4 cm when tested at 250° C. with a load of 2.16 kg. 3 / 10 minutes, for example, about 5 cm 3 / More than 10 minutes, about 10cm 3 The flame resistant polymer compositions of the present disclosure may have melt flow rates of 275°C or greater, such as 275°C or greater, and may have melt flow rates of 275°C or greater, such as 275°C or greater, such as greater than 100°C or greater. In the past, the addition of phosphorus-based flame retardant packages to thermoplastic polymers tended to significantly adversely affect the flow properties of the polymer. Thus, in the past, melt flow rates were tested at 275°C to allow the melt flow index to be measured. However, the flame resistant polymer compositions of the present disclosure may be formulated and exhibit sufficient flow properties at lower temperatures, such as 250°C.

[0012]

[0012] Other features and aspects of the disclosure are described in more detail below. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013]

[0013] Those skilled in the art should appreciate that this discussion is merely a description of exemplary embodiments and is not intended to limit the broader aspects of the present disclosure.

[0014] In general, the present disclosure is directed to halogen-free flame-resistant polymer compositions. The polymer compositions made according to the present disclosure not only exhibit superior flammability ratings when tested according to Underwriters Laboratories tests, but also have superior mechanical properties, including polymer processing properties. The flame retardant compositions combined with thermoplastic polymers according to the present disclosure include selected components that are found to work synergistically together. The flame retardant compositions can also be formulated such that various flame retardant adjuvants used in the past can be omitted without compromising the flame resistance of the polymer composition. In fact, it has been found that the omission of certain components maintains various physical properties of the composition, such as the melt flow properties of the composition.

[0014]

[0015] Generally, the flame-resistant polymer composition of the present disclosure contains a suitable thermoplastic polymer, such as polybutylene terephthalate, in combination with a flame retardant composition that contains a metal phosphinate, a metal phosphite and a nitrogen-containing synergist.In addition, the composition can contain a fluoropolymer, such as polytetrafluoroethylene.The flame-resistant polymer composition can also contain an organometallic compatibilizer.It is believed that the organometallic compatibilizer can not only improve the flame resistance of the composition, but also dramatically and unexpectedly improve the flowability of the polymer composition when heated.

[0015]

[0016] The flame-resistant polymer composition of the present disclosure may also be formulated without various flame retardant adjuvants that have been used in the past. For example, the flame-resistant polymer composition of the present disclosure may be formulated without metal oxides, metal hydroxides, metal borates, and / or metal stannates. For example, the flame-resistant polymer composition of the present disclosure may be formulated in one embodiment without magnesium oxide, calcium oxide, aluminum oxide, zinc oxide, manganese oxide, tin oxide, aluminum hydroxide, boehmite, dihydrotalcite, hydrocalumite, magnesium hydroxide, calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, zinc borate, zinc basic silicate, or zinc stannate. In the past, it was believed that one of the above components was necessary in certain applications to obtain a lower flammability rating. However, the above fillers may interfere with various physical properties of the polymer composition.

[0016]

[0017] As mentioned above, the polymer composition usually contains a thermoplastic polymer. Generally, any suitable thermoplastic polymer may be used. The thermoplastic polymer may be, for example, a polyamide, a polyolefin such as an ethylene polymer or a propylene polymer, a polyester polymer, a polycarbonate polymer, etc. However, the flame retardant composition of the present disclosure is particularly well suited for use with a polyester polymer.

[0017]

[0018] Suitable polyesters for use herein are derived from aliphatic or cycloaliphatic diols containing from 2 to about 10 carbon atoms, or mixtures thereof, and aromatic dicarboxylic acids, i.e., polyalkylene terephthalates.

[0018]

[0019] Polyesters derived from cycloaliphatic diols and aromatic dicarboxylic acids are prepared, for example, by condensing either the cis or trans isomer of 1,4-cyclohexanedimethanol (or mixtures thereof) with an aromatic dicarboxylic acid.

[0019]

[0020] Examples of aromatic dicarboxylic acids include isophthalic or terephthalic acid, 1,2-di(p-carboxyphenyl)ethane, 4,4'-dicarboxydiphenyl ether, and the like, and mixtures thereof. All of these acids contain at least one aromatic nucleus. Fused rings may also be present, such as in 1,4- or 1,5- or 2,6-naphthalene-dicarboxylic acids. In one embodiment, the dicarboxylic acid is terephthalic acid, or a mixture of terephthalic and isophthalic acids.

[0020]

[0021] Polyesters that may be used in the polymeric composition include, for example, polyethylene terephthalate, polybutylene terephthalate, mixtures thereof, and copolymers thereof.

[0021]

[0022] The thermoplastic polymer, such as polybutylene terephthalate polymer, is present in the polymer composition in an amount sufficient to form a continuous phase. For example, the thermoplastic polymer may be present in the polymer composition in an amount of at least about 40% by weight, such as at least about 60% by weight, at least about 65% by weight, at least about 70% by weight, at least about 75% by weight, at least about 80% by weight, etc. The thermoplastic polymer is usually present in an amount less than about 97% by weight.

[0022]

[0023] According to the present disclosure, at least one thermoplastic polymer as described above is combined with a flame retardant composition according to the present disclosure, the flame retardant composition comprising a metal phosphinate, a metal phosphite and a nitrogen-containing synergist.

[0023]

[0024] The metal phosphinate may be, for example, a dialkylphosphinate and / or a diphosphinate. The metal phosphinate may have one of the following chemical structures:

[0024] [ka]

[0025] (In the formula, R1 , R 2 are the same or different and each is a linear or branched C1-C6 alkyl; R 3 is a linear or branched C1-C 10 -Alkylene, C6~C 10 -Arylene, C7~C 20 -Alkyl arylene, or C7-C 20 -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and / or a protonated nitrogen base; m is 1-4; n is 1-4; x is 1-4). In one embodiment, the metal phosphinate is a dialkyl metal phosphinate, such as aluminum diethyl phosphinate. The metal phosphinate can be present in the polymer composition in an amount typically greater than about 5% by weight, such as greater than about 10% by weight, greater than about 15% by weight, greater than about 20% by weight, and typically less than about 25% by weight, such as less than about 22% by weight, less than about 19% by weight, less than about 17% by weight, less than about 14% by weight, and the like. In one embodiment, the metal phosphinate is present in the polymer composition in an amount between about 12% by weight and about 19% by weight.

[0026]

[0026] The metal phosphite present in the polymer composition can be any suitable metal phosphite made from any of the metals (M) set forth above. In one aspect, the metal phosphite is aluminum phosphite. Aluminum phosphite can have the chemical structure: Al2(HPO3)3. Other forms of aluminum phosphite can also be present in the polymer composition. Such other forms include basic aluminum phosphite, aluminum phosphite tetrahydrate, and the like. In yet another embodiment, aluminum phosphite can have the formula: Al(H2PO3)3.

[0027]

[0027] It is believed that the metal phosphites act synergistically with the metal phosphites in improving the flame resistance of the polymer composition, especially when the polymer composition contains polybutylene terephthalate. The weight ratio between the metal phosphites and the metal phosphites can usually be about 10:8 to about 30:1, for example, about 10:1 to about 20:1, about 14:1 to about 18:1, etc. In one embodiment, the metal phosphites can be present in the polymer composition in an amount of more than about 0.5% by weight, for example, more than about 1% by weight, more than about 1.5% by weight, more than about 2% by weight, etc., and usually less than about 10% by weight, for example, less than about 7% by weight, less than about 5% by weight, less than about 3% by weight, etc.

[0028] The nitrogen-containing synergist present in combination with the metal phosphinate and metal phosphite can include melamine. For example, the nitrogen-containing synergist can include melamine cyanurate. Other melamine compounds that can be used include melamine polyphosphate, dimelamine polyphosphate, melem polyphosphate, melam polyphosphate, melon polyphosphate, and the like. Other nitrogen-containing synergists that can be used include benzoguanamine, tris(hydroxyethyl)isocyanurate, allantoin, glycoluril, guanidine, or mixtures thereof. Usually, only a small amount of the nitrogen-containing synergist needs to be present in the polymer composition. For example, the nitrogen-containing synergist can be present in the polymer composition in an amount less than about 4% by weight, for example, less than about 3.4% by weight, less than about 2.3% by weight, less than about 1.8% by weight, less than about 1.5% by weight, and usually more than about 0.1% by weight, for example, more than about 0.3% by weight, more than about 0.8% by weight, more than about 1.1% by weight, and the like.

[0029] In addition to the thermoplastic polymer and flame retardant compositions described above, the polymer compositions of the present disclosure may contain polytetrafluoroethylene and / or an organometallic compatibilizer.

[0030]

[0030] For example, the flame-resistant polymer composition of the present disclosure can contain a fluoropolymer such as polytetrafluoroethylene powder. For example, the polytetrafluoroethylene particles can have an average particle size of less than about 15 μm, such as less than about 12 μm, less than about 10 μm, less than about 8 μm, etc. The average particle size of the polytetrafluoroethylene particles is usually greater than about 0.5 μm, such as greater than about 1 μm, greater than about 2 μm, greater than about 3 μm, greater than about 4 μm, greater than about 5 μm, etc. The average particle size can be measured according to ISO test 13321.

[0031] In one embodiment, the polytetrafluoroethylene particles can have a relatively low molecular weight. The polytetrafluoroethylene polymer can have a density of about 300 g / l to about 450 g / l, such as about 325 g / l to about 375 g / l, when tested according to ASTM test D4895. The polytetrafluoroethylene particles can have a density of about 5 m when tested according to test DIN66132. 2 / g ~ approx. 15m 2 / g, for example, about 8m 2 / g ~ approx. 12m 2 The polytetrafluoroethylene polymer may have a specific surface area of ​​less than about 3 g / 10 min, such as less than about 2 g / 10 min, when tested according to ISO test 1133 at 372° C. under a load of 10 kg.

[0032]

[0032] The polytetrafluoroethylene particles can be present in the polymer composition in an amount greater than about 0.1% by weight, such as greater than about 0.2% by weight, greater than about 0.3% by weight, greater than about 0.4% by weight, etc. The polytetrafluoroethylene polymer is typically present in the polymer composition in an amount less than about 5% by weight, such as less than about 4% by weight, less than about 3% by weight, less than about 2% by weight, etc.

[0033]

[0033] The above-mentioned fluoropolymers can provide a wide variety of benefits and advantages when present in the polymer composition. For example, the fluoropolymers can improve various physical properties of the molded articles made from the polymer composition. In addition, the fluoropolymers can facilitate the melt processing of the polymer composition. The fluoropolymers can also have flame resistance. For example, the fluoropolymers can maintain the polymer composition as a coherent mass when exposed to an open flame and can prevent droplets of molten polymer material from separating from the polymer composition during flame testing.

[0034]

[0034] The polymer composition may also contain an organometallic compatibilizer. It has been found that the organometallic compatibilizer unexpectedly and dramatically improves the flowability of the polymer composition during polymer processing. In addition, the organometallic compatibilizer may provide various other benefits and advantages. For example, the organometallic compatibilizer may provide corrosion resistance, increase the acid resistance of the polymer composition, and improve the long-term aging resistance of the polymer composition. In addition, the organometallic compatibilizer may function as an intumescent flame retardant in certain applications.

[0035]

[0035] The organometallic compatibilizer may include monoalkoxy titanates. Other organometallic compounds that may be used include zirconates and aluminates. Specific examples of titanates that may be incorporated into the polymer composition include titanium(IV) 2-propanolato, trisisooctadecanoato-O; titanium(IV) bis 2-methyl-2-propenoato-O, isooctadecanoato-O 2-propanolato; titanium(IV) 2-propanolato, tris(dodecyl)benzenesulfanato-O; titanium(IV) 2-propanolato, tris(dioctyl)phosphato-O; titanium(IV), tris(2-methyl)-2-propenoato-O, methoxydiglycolylato; titanium(IV) 2-propanolato, tris(dioctyl)pyrophosphato-O; titanium(IV), tris(2-propenoato-O), methoxydiglycolylato-O; titanium(IV) 2-propanolato, tris(3,6-diaza)hexanolate, and mixtures thereof.

[0036]

[0036] When present in the polymer composition, the organometallic compatibilizer may be included in an amount that is typically greater than about 0.05 wt%, such as greater than about 0.1 wt%, greater than about 0.2 wt%, greater than about 0.4 wt%, etc., and typically less than about 2.8 wt%, such as less than about 2.5 wt%, less than about 2.2 wt%, less than about 1.8 wt%, less than about 1.6 wt%, less than about 1.2 wt%, etc.

[0037] The thermoplastic polymer composition of the present invention may also include a lubricant, constituting from about 0.01% to about 2%, in some embodiments from about 0.1% to about 1%, and in some embodiments from about 0.2% to about 0.5% by weight of the polymer composition. The lubricant may be formed from a fatty acid salt derived from a fatty acid having a chain length of 22 to 38 carbon atoms, in some embodiments from 24 to 36 carbon atoms. Examples of such fatty acids may include long chain aliphatic fatty acids such as montanic acid (octacosanoic acid), arachidic acid (arachic acid, icosanic acid, icosanoic acid, n-icosanoic acid), tetracosanoic acid (lignoceric acid), behenic acid (docosanoic acid), hexacosanoic acid (cerotic acid), melissic acid (triacontanoic acid), erucic acid, cetooleic acid, brassidic acid, selacholeic acid, nervonic acid, and the like. For example, montanic acid has an aliphatic carbon chain of 28 atoms, and arachidic acid has an aliphatic carbon chain of 20 atoms. Due to the long carbon chain provided by the fatty acids, the lubricant has high heat resistance and low volatility. This allows the lubricant to maintain its function during the formation of the desired article to reduce internal and external friction, thereby reducing material degradation caused by mechanical / chemical effects.

[0038]

[0038] The fatty acid salts may be formed by saponifying the fatty acid wax to neutralize excess carboxylic acid and form a metal salt. Saponification may be carried out with a metal hydroxide, such as an alkali metal hydroxide (e.g., sodium hydroxide) or an alkaline earth metal hydroxide (e.g., calcium hydroxide). The resulting fatty acid salts typically contain an alkali metal (e.g., sodium, potassium, lithium, etc.) or an alkaline earth metal (e.g., calcium, magnesium, etc.). Such fatty acid salts will generally have an acid number (ASTM D 1386) of about 20 mg KOH / g or less, in some embodiments about 18 mg KOH / g or less, and in some embodiments about 1 to about 15 mg KOH / g. Particularly suitable fatty acid salts for use in the present invention are C 28 ~C 32The montanic acid salts are derived from crude montan wax containing linear, unbranched monocarboxylic acids having chain lengths in the range of 0.01 to 0.05, and preferably 0.01 to 0.05. Such montanic acid salts are commercially available from Clariant GmbH under the names Licomont® CaV102 (calcium salt of long-chain linear montanic acid) and Licomont® NaV101 (sodium salt of long-chain linear montanic acid).

[0039] Optionally, fatty acid esters may be used as lubricants. The fatty acid esters may be obtained by oxidative bleaching of crude natural waxes, followed by esterification of the fatty acids with alcohols. The alcohols typically have 1 to 4 hydroxyl groups and 2 to 20 carbon atoms. When the alcohols are polyfunctional (e.g., 2 to 4 hydroxyl groups), those with 2 to 8 carbon atoms are particularly desirable. Particularly suitable polyfunctional alcohols include dihydric alcohols (e.g., ethylene glycol, propylene glycol, butylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, and 1,4-cyclohexanediol), trihydric alcohols (e.g., glycerol and trimethylolpropane), tetrahydric alcohols (e.g., pentaerythritol and erythritol), and the like. Aromatic alcohols such as o-, m-, and p-tolylcarbinol, chlorobenzyl alcohol, bromobenzyl alcohol, 2,4-dimethylbenzyl alcohol, 3,5-dimethylbenzyl alcohol, 2,3,5-cumobenzyl alcohol, 3,4,5-trimethylbenzyl alcohol, p-cuminyl alcohol, 1,2-phthalyl alcohol, 1,3-bis(hydroxymethyl)benzene, 1,4-bis(hydroxymethyl)benzene, pseudocumenyl glycol, mesitylene glycol, and mesitylene glycerol may also be suitable. Particularly suitable fatty acid esters for use in the present invention are derived from Montan acid wax. Licowax® OP (Clariant) contains, for example, Montan acid partially esterified with butylene glycol and partially saponified with calcium hydroxide. Licowax® OP therefore contains a mixture of Montan acid esters and calcium Montanate. Other Montan acid esters that may be used include Licowax® E, Licowax® OP, and Licolub® WE4 (all from Clariant), which are Montan acid esters obtained, for example, as a secondary product from the oxidative refining of raw Montan wax.Licowax® E and Licolub® WE4 contain montanic acid esterified with ethylene glycol or glycerin.

[0040] Other known waxes may also be used in the lubricant. For example, amide waxes formed by the reaction of fatty acids with monoamines or diamines having 2 to 18, especially 2 to 8, carbon atoms (e.g., ethylenediamine) may be used. For example, ethylenebisamide waxes formed by the amidation reaction of ethylenediamine with fatty acids may be used. The fatty acids may be C 12 ~C 30 For example, stearic acid (C 18 Ethylene bisstearamide waxes can be formed from N,N'-(ethylene bis) 12-hydroxystearamide, ...

[0041]

[0041] The polymer composition may also contain at least one stabilizer. The stabilizers may include antioxidants, light stabilizers such as UV stabilizers, heat stabilizers, and the like.

[0042] Sterically hindered phenolic antioxidants may be used in the composition. Examples of such phenolic antioxidants include, for example, calcium bis(ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate) (Irganox® 1425); terephthalic acid, 1,4-dithio-,S,S-bis(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) ester (Cyanox® 1729); triethylene glycol bis(3-tert-butyl-4-hydroxy-5-methylhydrocinnamate); hexamethylene bis(3,5-di- tert-Butyl-4-hydroxyhydrocinnamate (Irganox® 259); 1,2-bis(3,5,di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazide (Irganox® 1024); 4,4'-di-tert-octyldiphenamine (Naugalube® 438R); Phosphonic acid, (3,5-di-tert-butyl-4-hydroxybenzyl)-, dioctadecyl ester (Irganox® 1093); 1,3,5-trimethyl-2,4, 6-Tris(3',5'-di-tert-butyl-4'hydroxybenzyl)benzene (Irganox® 1330); 2,4-bis(octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine (Irganox® 565); isooctyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (Irganox® 1135); octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (Irganox® 1135); lopionate) (Irganox® 1076); 3,7-bis(1,1,3,3-tetramethylbutyl)-10H-phenothiazine (Irganox® LO3); 2,2'-methylenebis(4-methyl-6-tert-butylphenol) monoacrylate (Irganox® 3052); 2-tert-butyl-6-[1-(3-tert-butyl-2-hydroxy-5-methylphenyl)ethyl]-4-methylphenyl acrylate (Sumilizer® TM4039);2-[1-(2-hydroxy-3,5-di-tert-pentylphenyl)ethyl]-4,6-di-tert-pentylphenyl acrylate (Sumilizer® GS); 1,3-dihydro-2H-benzimidazole (Sumilizer® MB); 2-methyl-4,6-bis[(octylthio)methyl]phenol (Irganox® 1520); N,N'-trimethylenebis-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionamide (Irganox® 1520); anox® 1019); 4-n-octadecyloxy-2,6-diphenylphenol (Irganox® 1063); 2,2'-ethylidenebis[4,6-di-tert-butylphenol] (Irganox® 129); N-N'-hexamethylenebis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide) (Irganox® 1098); diethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphone phosphate (Irganox® 1222); 4,4'-di-tert-octyldiphenylamine (Irganox® 5057); N-phenyl-1-napthalenamine (Irganox® L05); tris[2-tert-butyl-4-(3-tert-butyl-4-hydroxy-6-methylphenylthio)-5-methylphenyl]phosphite (Hostanox® OSP1); dinonyldithiocarbamic acid (dinonydithiocarbamic acid zinc rbamate (Hostanox® VP-ZNCS1); 3,9-bis[1,1-dimethyl-2-[(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane (Sumilizer® AG80); pentaerythrityl tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] (Irganox® 1010);Ethylene-bis(oxyethylene)bis[3-(5-tert-butyl-4-hydroxy-m-tolyl)-propionate (Irganox® 245); 3,5-di-tert-butyl-4-hydroxytoluene (Lowinox BHT, Chemtura);

[0042]

[0043] Some examples of sterically hindered phenolic antioxidants suitable for use in the present compositions are the triazine antioxidants having the general formula:

[0043] [ka]

[0044] wherein each R is independently a phenolic group, which may be attached to the triazine ring via a C1-C5 alkyl or ester substituent. Preferably, each R is one of the following formulas (I) to (III):

[0045] [ka]

[0046] Commercially available examples of such triazine antioxidants may be obtained from American Cyanamid under the designation Cyanox® 1790 (wherein each R group is represented by Formula III), and from Ciba Specialty Chemicals under the designations Irganox® 3114 (wherein each R group is represented by Formula I) and Irganox® 3125 (wherein each R group is represented by Formula II).

[0047] The sterically hindered phenolic antioxidant may comprise from about 0.01% to about 3%, in some embodiments from about 0.05% to about 1%, and in some embodiments from about 0.05% to about 0.3% by weight of the total stabilized polymer composition. In one embodiment, for example, the antioxidant comprises pentaerythrityl tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate.

[0048]

[0046] To inhibit degradation of the polyester composition and thus extend its durability, hindered amine light stabilizers ("HALS") may be used in the composition. Suitable HALS compounds may be derived from substituted piperidines, such as alkyl-substituted piperidyl, piperidinyl, piperazinone, and alkoxypiperidinyl compounds. For example, the hindered amine may be derived from a 2,2,6,6-tetraalkylpiperidinyl. Regardless of the compound from which it is derived, the hindered amine is typically an oligomeric or polymeric compound having a number average molecular weight of about 1,000 or more, in some embodiments from about 1000 to about 20,000, in some embodiments from about 1500 to about 15,000, and in some embodiments from about 2000 to about 5000. Such compounds typically contain at least one 2,2,6,6-tetraalkylpiperidinyl group (e.g., 1 to 4) per polymer repeat unit.

[0049]

[0047] Without being limited by theory, it is believed that high molecular weight hindered amines are relatively heat resistant and therefore capable of inhibiting light degradation even after exposure to extrusion conditions. One particularly suitable high molecular weight hindered amine has the following general structure:

[0050] [ka]

[0051] (In the formula, p is 4 to 30, in some embodiments, 4 to 20, and in some embodiments, 4 to 10.) This oligomeric compound is commercially available from Clariant under the name Hostavin® N30 and has a number average molecular weight of 1200.

[0052] Another suitable high molecular weight hindered amine has the following structure:

[0053] [ka]

[0054] (In the formula, n is 1 to 4, and R 30 are independently hydrogen or CH3) Such an oligomeric compound is available from Adeka Palmarole SAS (a joint venture of Adeka Corp. and Palmarole Group) under the trade name ADK STAB® LA-63 (R 30 is CH3) and ADK STAB (registered trademark) LA-68 (R 30 It is sold commercially under the name ethylenediaminetetraacetate (hydrogen).

[0055] Other examples of suitable high molecular weight hindered amines include, for example, N-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-piperidinol and oligomers of succinic acid (Ciba Specialty Tinuvin® 622, MW=4000, from Great Lakes Chemicals; oligomer of cyanuric acid and N,N-di(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine; poly((6-morpholine-S-triazine-2,4-diyl)(2,2,6,6-tetramethyl-4-piperidinyl)-iminohexamethylene-(2,2,6,6-tetramethyl-4-piperidinyl)-imino) (Cyasorb® UV3346, MW=1600, from Cytec); polymethylpropyl-3-oxy-[4(2,2,6,6-tetramethyl)-piperidinylysiloxane] (Great Lakes Uvasil® 299, MW=1100-2500, manufactured by Chemical Co., Ltd.; copolymer of α-methylstyrene-N-(2,2,6,6-tetramethyl-4-piperidinyl)maleimide and N-stearylmaleimide; 2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diethanoltetramethyl-polymer with 1,2,3,4-butanetetracarboxylic acid.

[0056] In addition to the polymeric hindered amines, low molecular weight hindered amines may also be used in the composition. Such hindered amines are typically monomeric in nature and have a molecular weight of up to about 1000, in some embodiments from about 155 to about 800, and in some embodiments from about 300 to about 800.

[0057] Specific examples of such low molecular weight hindered amines include, for example, bis-(2,2,6,6-tetramethyl-4-piperidyl)sebacate (Tinuvin® 770, MW=481, manufactured by Ciba Specialty Chemicals); bis-(1,2,2,6,6-pentamethyl-4-piperidinyl)-(3,5-di-tert-butyl-4-hydroxybenzyl)butyl-propanedioate; bis-(1,2,2,6,6-pentamethyl-4-piperidinyl)sebacate; 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro- (4,5)-Decane-2,4-dione, butanedioic acid, bis-(2,2,6,6-tetramethyl-4-piperidinyl) ester;Tetrakis-(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate;7-Oxa-3,20-diazadispiro(5.1.11.2)heneicosane-20-propionic acid, 2,2,4,4-tetramethyl-21-oxo, dodecyl ester;N -(2,2,6,6-tetramethyl-4-piperidinyl)-N'-amino-oxamide;ot-amyl-o-(1,2,2,6,6-pentamethyl-4-piperidinyl)-monoperoxy-carbonate;β-Alanine, N-(2,2,6,6-tetramethyl-4-piperidinyl), dodecyl ester;Ethanediamide, N-(1-acetyl-2,2,6,6-tetramethylpiperidinyl)-N'-dodecyl;3-Dodecyl 3-Dodecyl-1-(1,2,2,6,6-tetramethyl-4-piperidinyl)-pyrrolidine-2,5-dione; 3-Dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidinyl)-pyrrolidine-2,5-dione; 3-Dodecyl-1-(1-acetyl,2,2,6,6-tetramethyl-4-piperidinyl)-pyrrolidine-2,5-dione, (Sanduvar® 3058 from Clariant, MW=448.7); 4-benzoyloxy-2,2,6,6-tetramethylpiperidine; 1-[2-(3,5-di-tert-butyl-4-hydroxyphenylpropionyloxy)ethyl]-4-(3,5-di-tert-butyl-4-hydroxylphenylpropionyloxy)-2,2,6,6-tetramethyl-piperidine; 2-methyl-2-(2”,2”,6”,6”-tetramethyl-4”-piperidinylamino)-N-(2',2',6',6'-tetra-methyl-4'-piperidinyl)propionylamide; 1,2-bis-(3,3,5,5-tetramethyl-2-oxo-piberazinyl)ethane; 4-oleoyloxy-2,2,6,6-tetramethylpiperidine; and combinations thereof. Other suitable low molecular weight hindered amines are described in U.S. Patent No. 5,679,733 to Malik et al.

[0058]

[0052] The hindered amines may be used alone or in combination in any amount to achieve the desired properties, but typically comprise from about 0.01% to about 4% by weight of the polymer composition.

[0059]

[0053] UV absorbers, such as benzotriazoles or benzopheones, may be used in the composition to absorb UV energy.Suitable benzotriazoles include, for example, 2-(2-hydroxyphenyl)benzotriazoles, such as 2-(2-hydroxy-5-methylphenyl)benzotriazole; 2-(2-hydroxy-5-tert-octylphenyl)benzotriazole (Cyasorb® UV5411 from Cytec); 2-(2-hydroxy-3,5-di-tert-butylphenyl)-5-chlorobenzo-triazole; 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole; 2- (2-Hydroxy-3,5-dicumylphenyl)benzotriazole;2,2'-Methylenebis(4-tert-octyl-6-benzo-triazolylphenol);2-(2-hydroxy-3-tert-butyl-5-carboxyphenyl)benzotriazole polyethylene glycol esters;2-[2-hydroxy-3-(2-acryloyloxyethyl)-5-methylphenyl]-benzotriazole;2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]benzotriazole;2-[2-hydroxy-3-(2-hydroxyethyl)-5-tert-butylphenyl]benzotriazole 2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole;2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole;2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole;2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole;2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole;2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole 2-[2-hydroxy-3-tert-butyl-5-(3-methacryloyloxypropyl)phenyl]-5-chlorobenzotriazole; 2-[2-hydroxy-4-(2-methacryloyloxymethyl)phenyl]benzotriazole; 2-[2-hydroxy-4-(3-methacryloyloxy-2-hydroxypropyl)phenyl]benzotriazole; 2-[2-hydroxy-4-(3-methacryloyloxypropyl)phenyl]benzotriazole; and combinations thereof.

[0060] Representative benzophenone light stabilizers include, in turn, 2-hydroxy-4-dodecyloxybenzophenone; 2,4-dihydroxybenzophenone; 2-(4-benzoyl-3-hydroxyphenoxy)ethyl acrylate (Cyasorb® UV209 from Cytec); 2-hydroxy-4-n-octyloxy)benzophenone (Cyasorb® 531 from Cytec); 2,2'-dihydroxy-4-(octyloxy)benzophenone (Cyasorb® UV314 from Cytec); hexadecyl-3,5-bis-tert-butyl 4,4'-dimethoxy-2,2'-dihydroxybenzoate (Cyasorb® UV2908 from Cytec); 2,2'-thiobis(4-tert-octylphenolato)-n-butylamine nickel(II) (Cyasorb® UV1084 from Cytec); 3,5-di-tert-butyl-4-hydroxybenzoic acid, (2,4-di-tert-butylphenyl) ester (Cyasorb® 712 from Cytec); 4,4'-dimethoxy-2,2'-dihydroxybenzophenone (Cyasorb® UV12 from Cytec); and combinations thereof.

[0061]

[0055] When used, the UV absorber may comprise from about 0.01% to about 4% by weight of the total polymer composition. In one embodiment, the polymer composition may contain a blend of stabilizers that provide UV resistance and color stability. The combination of stabilizers allows for the production of products with bright and fluorescent colors. Furthermore, brightly colored products may be produced that do not fade significantly over time. In one embodiment, for example, the polymer composition may contain a combination of a benzotriazole light stabilizer and a hindered amine light stabilizer, such as an oligomeric hindered amine.

[0062] Organophosphorus compounds may be used in the compositions which function as secondary antioxidants that decompose peroxides and hydroperoxides into stable non-radical products. Trivalent organophosphorus compounds (e.g., phosphites or phosphonites) are particularly useful in the stabilization systems of the present invention. In certain embodiments of the present invention, monophosphite compounds (i.e., only one phosphorus atom per molecule) may be used. Preferred monophosphites have a C1-C aryl group in at least one of the aryloxide groups. 10Aryl monophosphites containing alkyl substituents. These substituents can be linear (as in the case of a nonyl substituent) or branched (as in the isopropyl or tertiary butyl substituents). Non-limiting examples of suitable aryl monophosphites (or monophosphonites) may include triphenyl phosphite; diphenyl alkyl phosphites; phenyl dialkyl phosphites; tris(nonylphenyl) phosphite (Weston™ 399, available from GE Specialty Chemicals); tris(2,4-di-tert-butylphenyl) phosphite (Irgafos® 168, available from Ciba Specialty Chemicals Corp.); bis(2,4-di-tert-butyl-6-methylphenyl)ethyl phosphite (Irgafos® 38, available from Ciba Specialty Chemicals Corp.); and 2,2′,2″-nitrilo[triethyltris(3,3′5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl) phosphate (Irgafos® 12, available from Ciba Specialty Chemicals Corp.).Aryl diphosphites or diphosphonites (i.e., containing at least two phosphorus atoms per phosphite molecule) may also be used in the stabilization system, such as distearyl pentaerythritol diphosphite, diisodecyl pentaerythritol diphosphite, bis(2,4 di-tert-butylphenyl) pentaerythritol diphosphite (Irgafos 126, available from Ciba); bis(2,6-di-tert-butyl-4-methylpenyl) pentaerythritol diphosphite; Included may be mentioned are bis(2,4-di-tert-butyl-6-methylphenyl)pentaerythritol diphosphite, bis(2,4,6-tri-tert-butylphenyl)pentaerythritol diphosphite, tetrakis(2,4-di-tert-butylphenyl)4,4'-biphenylene diphosphonite (Sandostab™ P-EPQ, available from Clariant), and bis(2,4-dicumylphenyl)pentaerythritol diphosphite (Doverphos® S-9228).

[0063]

[0058] The organophosphorus compound may comprise from about 0.01% to about 2% by weight, in some embodiments from about 0.05% to about 1% by weight, and in some embodiments, from about 0.1% to about 0.5% by weight of the polymer composition.

[0064] In addition to those mentioned above, secondary amines may also be used in the composition. The secondary amines may be aromatic in nature, such as, for example, N-phenylnaphthylamines (e.g., Naugard® PAN from Uniroyal Chemical); diphenylamines, such as 4,4'-bis(dimethylbenzyl)-diphenylamine (e.g., Naugard® 445 from Uniroyal Chemical); p-phenylenediamines (e.g., Wingstay® 300 from Goodyear); quinolones, and the like. Particularly suitable secondary amines are oligomeric or polymeric amines, such as homo- or copolymeric polyamides. Examples of such polyamides may include nylon 3 (poly-β-alanine), nylon 6, nylon 10, nylon 11, nylon 12, nylon 6 / 6, nylon 6 / 9, nylon 6 / 10, nylon 6 / 11, nylon 6 / 12, polyesteramides, polyamideimides, polyacrylamides, and the like. In one particular embodiment, the amine is a polyamide terpolymer having a melting point in the range of 120° C. to 220° C. Suitable terpolymers may be of the nylon family selected from the group consisting of nylon 6, nylon 6 / 6, nylon 6 / 9, nylon 6 / 10, and nylon 6 / 12, and may include nylon 6-66-69, nylon 6-66-610, and nylon 6-66-612. One example of such a nylon terpolymer is a terpolymer of nylon 6-66-610, available commercially from Du Pont de Nemours under the name Elvamide® 8063R.

[0065]

[0060] The secondary amine may comprise from about 0.01% to about 2% by weight of the total polymer composition. In addition to the above components, the polymer composition may contain various other components. Colorants that may be used include any desired inorganic pigments, such as titanium dioxide, ultramarine, cobalt blue, and other organic pigments and dyes, such as phthalocyanines, anthraquinones, and the like. Other colorants include carbon black or various other polymer-soluble dyes. Colorants can typically be present in the composition in an amount of up to about 2% by weight.

[0066]

[0062] The polymer composition may also contain reinforcing fibers in addition to the thermoplastic polymer matrix. Reinforcing fibers that may be advantageously used are mineral fibers such as glass fibers, polymer fibers, in particular organic high-modulus fibers such as aramid fibers, or metal fibers such as steel fibers, or carbon fibers, or natural fibers, fibers from renewable sources.

[0067]

[0063] These fibres may be in modified or unmodified form, for example sized or chemically treated to improve adhesion to plastics. Glass fibres are particularly preferred.

[0068]

[0064] To protect the glass fibers and to make them smooth, as well as to improve adhesion between the fibers and the matrix material, the glass fibers are sized. The sizing agent usually contains silanes, film formers, lubricants, wetting agents, adhesives, optionally antistatic agents and plasticizers, emulsifiers, and optionally further additives.

[0069] Specific examples of silanes are aminosilanes, such as 3-trimethoxysilylpropylamine, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-(3-trimethoxysilanylpropyl)ethane-1,2-diamine, 3-(2-aminoethyl-amino)propyltrimethoxysilane, N-[3-(trimethoxysilyl)propyl]-1,2-ethane-diamine.

[0070]

[0066] Film-forming agents are, for example, polyvinyl acetates, polyesters and polyurethanes. Polyurethane-based sizes may be advantageously used.

[0067] The reinforcing fibers may be compounded into the polymer matrix, for example in an extruder or kneader.

[0071]

[0068] According to one embodiment, the molding composition of the present disclosure comprises at least one reinforcing fiber, which is a mineral fiber, preferably a glass fiber, more preferably a coated or impregnated glass fiber. Glass fibers suitable for the molding composition of the present disclosure are commercially available, for example, Johns Manville, ThermoFlow® Chopped Strand 753, OCV Chopped Strand 408A, Nippon Electric Glass (NEG) Chopped Strand T-651.

[0072]

[0069] The diameter of the fibers may vary depending on the particular fiber used and whether the fibers are in chopped or continuous form. For example, the fibers may have a diameter of about 5 μm to about 100 μm, such as about 5 μm to about 50 μm, about 5 μm to about 15 μm, etc. The length of the fibers may vary depending on the particular application. For example, the fibers may have a length of more than about 100 μm, such as more than about 200 μm, more than about 300 μm, more than about 350 μm, etc. The length of the fibers may typically be less than about 1,000 μm, such as less than about 800 μm, less than about 600 μm, less than about 500 μm, etc. When incorporated into a polymer composition and formed into an article, the length of the fibers may decrease. For example, the average fiber length in the final product may be about 100 μm to about 400 μm, such as about 100 μm to about 300 μm.

[0073]

[0070] Typically, the reinforcing fibers are optionally present in the polymer composition in an amount sufficient to increase the tensile strength of the composition. For example, the reinforcing fibers can be present in the polymer composition in an amount greater than about 2 wt%, e.g., greater than about 5 wt%, greater than about 10 wt%, greater than about 15 wt%, greater than about 20 wt%, etc. The reinforcing fibers are typically present in an amount less than about 55 wt%, e.g., less than about 50 wt%, less than about 45 wt%, less than about 40 wt%, less than about 35 wt%, less than about 30 wt%, etc.

[0074] The compositions of the present disclosure may be compounded and formed into polymeric articles using any technique known in the art. For example, the respective compositions may be vigorously mixed to form a substantially homogenous blend. The blend may be melt kneaded at an elevated temperature, such as a temperature above the melting point but below the decomposition temperature of the polymers utilized in the polymeric composition. Alternatively, the respective compositions may be melted and mixed simultaneously in a conventional single or twin screw extruder. Preferably, the melt mixing is carried out at a temperature ranging from 150 to 300°C, such as, for example, 200 to 280°C, 220 to 270°C, or 240 to 260°C. However, such processing should be carried out for each composition at the desired temperature to minimize any polymer degradation.

[0075] After extrusion, the composition may be formed into pellets. The pellets may be molded into polymer articles by techniques known in the art, such as injection molding, thermoforming, blow molding, rotational molding, etc. In accordance with the present disclosure, the polymer articles exhibit excellent tribological behavior and mechanical properties. As a result, the polymer articles may be used in several applications where low wear and excellent slip properties are desired.

[0076] In addition to physical properties, polymer compositions according to the present disclosure can have excellent flame resistance. For example, when tested in a vertical burn test according to Underwriters Laboratories Test 94, test plaques made according to the present disclosure can have a UL-94 rating of V-0 when tested at a thickness of 0.8 mm, and even at a thickness of 0.4 mm.

[0077]

[0074] Of particular advantage, flame resistant polymer compositions having excellent flowability can be formulated according to the present disclosure. For example, when tested according to ISO test 1133 at a temperature of 250°C and a load of 2.16 kg, the entire polymer composition can be formed to a thickness of about 3 cm. 3 / More than 10 minutes, for example, about 4 cm 3 / More than 10 minutes, about 5cm 3 / Over 10 minutes, approx. 6cm 3 / More than 10 minutes, about 7cm 3 / More than 10 minutes, about 8cm 3 / More than 10 minutes, about 9cm 3 / More than 10 minutes, about 10cm 3 The melt flow rate can be greater than about 50 cm / 10 min. 3 / less than 10 minutes.

[0078] The polymer composition of the present disclosure can also have excellent mechanical properties when tested according to ISO test number 527. For example, the polymer composition can have a strength of about 3,400 N / mm 2 Over 5,000N / mm 2 The tensile yield strength is typically about 40 N / mm 2 For example, about 43N / mm 2 Ultra-high and usually around 70N / mm 2 The tensile strength may be less than about 40 N / mm 2 For example, about 43N / mm 2 Ultra-high and usually around 70N / mm 2 The elongation at break can be greater than about 4%, such as greater than about 5%, and typically less than about 25%.

[0079]

[0076] The present disclosure can be better understood with reference to the following examples. EXAMPLES

[0080] Various polymer compositions were formulated according to the present disclosure and tested for various properties. The following results were obtained:

[0081] [Table 1]

[0082] The titanate coupling agent used in Samples Nos. 4 and 5 was titanium(IV) 2-propanolato, tris(dioctyl)phosphato-O. As noted above, Samples Nos. 3-5 had a V-0 rating even at a thickness of 0.4 mm. Additionally, the samples containing the titanate coupling agent exhibited dramatically superior melt flow properties.

[0083]

[0080] These and other modifications and variations of the present invention are set forth in the appended claims. It will be understood that the present invention can be practiced by those skilled in the art without departing from the spirit and scope of the present invention, which is more particularly described in the following sections. It should be understood that the various modifications and variations of the present invention may be interchanged in various ways. Moreover, those skilled in the art will appreciate that the foregoing description is merely illustrative and is not intended to limit the invention as further described in such appended claims. The claims as filed are set forth below. [Claim 1] 1. A flame-resistant polymer composition comprising: a thermoplastic polymer present in the polymer composition in an amount greater than about 60% by weight; a flame retardant composition contained in the polymer composition, the flame retardant composition comprising a combination of a metal phosphinate, a metal phosphite, and a nitrogen-containing synergist; and Polytetrafluoroethylene 1. A flame-resistant polymer composition comprising: [Claim 2] 10. The flame-resistant polymer composition of claim 1, wherein the metal phosphite comprises aluminum phosphite. [Claim 3] 3. The flame-resistant polymer composition of claim 2, wherein the aluminum phosphite has the chemical formula: Al2(HPO3)3. [Claim 4] 4. The flame-resistant polymer composition according to claim 1, wherein the metal phosphinate comprises a dialkyl phosphinate. [Claim 5] 5. The flame-resistant polymer composition according to claim 1, wherein the metal phosphinate comprises aluminum diethylphosphinate. [Claim 6] 6. The flame resistant polymer composition of claim 1, wherein the nitrogen-containing synergist comprises melamine cyanurate. [Claim 7] 7. The flame-resistant polymer composition of claim 1, wherein the metal phosphinate is present in the composition in an amount of about 10% to about 25% by weight, the metal phosphite is present in the polymer composition in an amount of about 1% to about 7% by weight, and the nitrogen-containing synergist is present in the polymer composition in an amount of about 0.3% to about 4% by weight. [Claim 8] 8. The flame resistant polymer composition according to claim 1, wherein the polytetrafluoroethylene is present in the polymer composition in an amount of about 0.1% to about 5% by weight. [Claim 9] 9. The flame resistant polymer composition of claim 1, wherein the thermoplastic polymer comprises a polyester polymer. [Claim 10] 10. The flame-resistant polymer composition of claim 1, wherein the thermoplastic polymer comprises a polybutylene terephthalate polymer. [Claim 11] 11. The flame-resistant polymer composition according to claim 1, wherein the polymer composition further comprises an organometallic compatibilizer. [Claim 12] 12. The flame-resistant polymer composition of claim 11, wherein the organometallic compatibilizer comprises a titanate. [Claim 13] 12. The flame-resistant polymer composition of claim 11, wherein the organometallic compatibilizer comprises titanium(IV) 2-propanolato, tris(dioctyl)phosphato-O. [Claim 14] 14. The flame-resistant polymer composition according to claim 11, wherein the organometallic compatibilizer is present in the polymer composition in an amount of about 0.05% to about 2.5% by weight. [Claim 15] 15. The flame resistant polymer composition according to claim 1, wherein the polymer composition further comprises a carboxylic acid ester. [Claim 16] 16. The flame resistant polymer composition of claim 15, wherein the carboxylic acid ester comprises the reaction product of Montanic acid and a polyfunctional alcohol. [Claim 17] 17. The flame-resistant polymer composition according to any one of claims 1 to 16, wherein the polymer composition is free of metal oxides, metal hydroxides, metal borates, and metal stannates. [Claim 18] The polymer composition has a melting point of at least 4 cm when tested at a temperature of 250° C. and a load of 2.16 kg. 3 / 10 minutes, e.g., at least about 5 cm 3 / 10 minutes, e.g., at least about 6 cm 3 18. The flame resistant polymer composition according to claim 1, having a melt flow rate of 1 / 10 min. [Claim 19] 19. The flame resistant polymer composition of any one of claims 1 to 18, wherein when tested by a vertical burn test according to Underwriters Laboratories Test 94, the polymer composition has a rating of V-0 when tested at a thickness of 0.4 mm. [Claim 20] 20. The flame-resistant polymer composition of claim 1, wherein the metal phosphinate is present in the composition in an amount of about 5% to about 30% by weight, the metal phosphite is present in the polymer composition in an amount of about 0.5% to about 9% by weight, and the nitrogen-containing synergist is present in the polymer composition in an amount of about 0.01% to about 7% by weight.

Claims

1. 1. A flame-resistant polymer composition comprising: a thermoplastic polymer comprising a polybutylene terephthalate polymer present in said polymer composition in an amount greater than 60 wt%; A flame retardant composition contained in the polymer composition, the flame retardant composition comprising a combination of a metal phosphinate, a metal phosphite, and a nitrogen-containing synergist; and Polytetrafluoroethylene Including, Does not contain glass fibers exhibiting a breaking elongation of greater than 4% when tested according to ISO test number 527; The flame-resistant polymer composition.

2. 10. The flame-resistant polymer composition of claim 1, wherein the metal phosphite comprises aluminum phosphite.

3. The aluminum phosphite has the chemical formula: Al ２ (H.P.O. ３ ) ３ 3. The flame resistant polymer composition of claim 2, having

4. 4. The flame-resistant polymer composition of claim 1, wherein the metal phosphinate comprises a dialkyl phosphinate.

5. 5. The flame-resistant polymer composition of claim 1, wherein the metal phosphinate comprises aluminum diethylphosphinate.

6. 6. The flame resistant polymer composition of claim 1, wherein the nitrogen-containing synergist comprises melamine cyanurate.

7. A flame-resistant polymer composition described in any one of claims 1 to 6, wherein the metal phosphinate is present in the polymer composition in an amount of 5 wt% to 30 wt%, the metal phosphite is present in the polymer composition in an amount of 0.5 wt% to 9 wt%, and the nitrogen-containing synergist is present in the polymer composition in an amount of 0.01 wt% to 7 wt%.

8. The flame resistant polymer composition according to any one of claims 1 to 7, wherein the polytetrafluoroethylene is present in the polymer composition in an amount of from 0.1% to 5% by weight.

9. 9. The flame resistant polymer composition according to any one of claims 1 to 8, wherein the polymer composition further comprises an organometallic compatibilizer.

10. 10. The flame-resistant polymer composition of claim 9, wherein the organometallic compatibilizer comprises a titanate.

11. 10. The flame-resistant polymer composition of claim 9, wherein the organometallic compatibilizer comprises titanium(IV) 2-propanolato, tris(dioctyl)phosphato-O.

12. The flame resistant polymer composition according to any one of claims 9 to 11, wherein the organometallic compatibilizer is present in the polymer composition in an amount of from 0.05% to 2.5% by weight.

13. The flame resistant polymer composition according to any one of claims 1 to 12, wherein the polymer composition further comprises a carboxylic acid ester.

14. 14. The flame resistant polymer composition of claim 13, wherein the carboxylic acid ester comprises the reaction product of Montanic acid and a polyfunctional alcohol.

15. 15. The flame resistant polymer composition of any one of claims 1 to 14, wherein the polymer composition is free of metal oxides, metal hydroxides, metal borates, and metal stannates.

16. The polymer composition has a thickness of at least 4 cm when tested at a temperature of 250° C. and a load of 2.16 kg. ３ 16. The flame resistant polymer composition of claim 1 having a melt flow rate of 1 / 10 min.

17. 17. The flame resistant polymer composition according to any one of claims 1 to 16, wherein when tested by the Vertical Burn Test according to Underwriters Laboratories Test 94, the polymer composition has a rating of V-0 when tested at a thickness of 0.4 mm.

18. The metal phosphinate is present in the polymer composition in an amount of 10% to 25% by weight. wherein said metal phosphite is present in said polymer composition in an amount from 1 wt % to 7 wt %, and said nitrogen-containing synergist is present in said polymer composition in an amount from 0.3 wt % to 4 wt %.

18. A flame resistant polymer composition according to any one of claims 1 to 17.

Images