Hot-rolled steel sheet for non-oriented electrical steel sheet, manufacturing method for hot-rolled steel sheet for non-oriented electrical steel sheet, and manufacturing method for non-oriented electrical steel sheet

Abstract

This hot-pressed steel sheet for a non-oriented electromagnetic steel sheet contains Si, Mn, Al, Ti, Nb, V and Zr in prescribed amounts as the chemical composition, and, viewed in a cut section parallel to the rolling direction and the plate thickness direction, AlN with a circle equivalent diameter of 10-200 nm is present in, and at the boundaries, of ferrite particles, and the number density of the aforementioned AlN present in the particles and at the particle boundaries is set to 8.0 / μm2 of the observation area, and the number density of the aforementioned AlN present at the particle boundaries is set to less than or equal to 40 / μm2 of the observation area.

Description

[Technical field]

[0001] The present invention relates to a hot-rolled steel sheet for a non-oriented electrical steel sheet that can improve magnetic properties, a manufacturing method for a hot-rolled steel sheet for a non-oriented electrical steel sheet, and a manufacturing method for a non-oriented electrical steel sheet. [Background technology]

[0002] Non-oriented electrical steel sheets are mainly used as iron core materials for rotating machines, etc. In recent years, there has been an increasing demand for higher efficiency in equipment, even in fields where low-grade non-oriented electrical steel sheets have been used. Therefore, even low-grade non-oriented electrical steel sheets are required to increase magnetic flux density and reduce iron loss while keeping costs down.

[0003] Furthermore, in recent years, the increasing use of inverter control in rotating machines has created a demand for improved iron loss at high frequencies, which means that even low-grade non-oriented electrical steel sheets are required to reduce iron loss at high frequencies.

[0004] Low-grade non-oriented electrical steel sheets generally have a low silicon content and chemical composition that causes α-γ transformation (ferrite-austenite transformation) during the manufacturing process. To date, methods have been proposed for improving the magnetic properties of such low-grade non-oriented electrical steel sheets by omitting the hot-rolled sheet annealing.

[0005] For example, Patent Document 1 proposes a method of completing hot rolling at or above the Ar3 transformation point and slowly cooling the temperature range from the Ar3 transformation point to the Ar1 transformation point at a rate of 5°C / sec or less. However, it is difficult to achieve this cooling rate in an industrial manufacturing process.

[0006] Patent Document 2 proposes a method of adding Sn to steel and controlling the hot rolling finishing temperature according to the Sn concentration to obtain a high magnetic flux density. However, this method limits the Si concentration to 0.4% or less, which is insufficient for obtaining a low iron loss.

[0007] Patent Document 3 proposes a steel sheet that has high magnetic flux density and excellent grain growth during stress relief annealing by limiting the heating temperature and finishing temperature during hot rolling. However, this method does not have a process such as autogenous annealing to replace hot-rolled sheet annealing, so it is not possible to obtain high magnetic flux density.

[0008] Patent Document 4 proposes a method of increasing magnetic flux density by controlling the chemical components of steel and hot rolling conditions. In Patent Document 4, to address the problem of AlN finely precipitating at α grain boundaries during γ→α transformation and inhibiting grain growth during self-annealing of the hot-rolled sheet, the finish rolling temperature is controlled to 800°C to (Ar1+20°C) and the coiling temperature is controlled to 780°C or higher. However, this method does not solve the fundamental problem of AlN precipitating during γ→α transformation. [Prior art documents] [Patent documents]

[0009] [Patent Document 1] Japanese Patent Publication No. 06-192731 [Patent Document 2] Japanese Patent Application Publication No. 2006-241554 [Patent Document 3] Japanese Patent Application Publication No. 2007-217744 [Patent Document 4] International Publication No. 2013 / 069754 Summary of the Invention [Problem to be solved by the invention]

[0010] As described above, low-grade non-oriented electrical steel sheets generally have chemical components that cause α-γ transformation during the manufacturing process. For such low-grade non-oriented electrical steel sheets, conventional techniques have attempted to improve the magnetic properties by subjecting the sheets to self-annealing after hot rolling instead of hot-rolled sheet annealing. However, as described above, the conventional techniques have not been able to fully satisfy the magnetic properties. In particular, the improvement of iron loss at high frequencies has not been sufficient.

[0011] The present invention has been made in view of the above circumstances. An object of the present invention is to provide a hot-rolled steel sheet for a non-oriented electrical steel sheet, which is excellent in iron loss characteristics at high frequencies in addition to general magnetic properties, a manufacturing method for the hot-rolled steel sheet for a non-oriented electrical steel sheet, and a manufacturing method for the non-oriented electrical steel sheet. [Means for solving the problem]

[0012] The gist of the present invention is as follows.

[0013] (1) A hot-rolled steel sheet for non-oriented electrical steel sheet according to one aspect of the present invention is Chemical composition, by mass%, C: 0.005% or less, Si: 0.10-1.50%, Mn: 0.10-0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010~0.0030%, V: 0.0010~0.0030%, Zr: 0.0010~0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0 to 0.20% with the remainder being Fe and impurities, When viewed from a cross section parallel to the rolling direction and plate thickness direction, AlN with a circle equivalent diameter of 10 to 200 nm exists within and at the grain boundaries of ferrite grains. The density of the AlN particles present within the grains and at the grain boundaries is 8.0 particles / μm 2 below and The density of the AlN particles present at the grain boundary is 40 particles / μm 2 below and When the hot-rolled steel sheet is cold-rolled without annealing, and then annealed at 800°C or higher and Ac1 point or lower, and then the iron loss W15 / 50 and iron loss W10 / 200 are measured, the iron loss W15 / 50 is less than 5.2 W / kg, and the iron loss W10 / 200 is less than 18.0 W / kg. It is. (2) In the hot-rolled steel sheet for non-oriented electrical steel sheet described in (1) above, Chemical composition, by mass%, Sn: 0.02-0.20%, Sb: 0.02 to 0.20% may contain at least one of the above. (3) A method for producing a hot-rolled steel sheet for non-oriented electrical steel sheet according to one aspect of the present invention is a method for producing a hot-rolled steel sheet for non-oriented electrical steel sheet according to the above (1) or (2), Chemical composition, by mass%, C: 0.005% or less, Si: 0.10-1.50%, Mn: 0.10-0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010~0.0030%, V: 0.0010~0.0030%, Zr: 0.0010~0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0 to 0.20% and the balance being Fe and impurities, to a temperature range of 1050°C to 1180°C, The heated slab is roughly rolled, The rough rolled material after the rough rolling is held in a temperature range of 850 ° C. or higher and Ar1 point or lower, The rough rolled material after the holding is reheated to a temperature range of more than Ar1 point and less than Ac1 point, The rough rolled material immediately after heating is finish-rolled under the condition that the end temperature of the finish rolling is 800 ° C. or more and Ar1 point or less, The finish-rolled material after the finish rolling may be coiled at a temperature in the range of 750°C to 850°C. (4) A method for producing a non-oriented electrical steel sheet according to one aspect of the present invention is a method for producing a non-oriented electrical steel sheet using the hot-rolled steel sheet for non-oriented electrical steel sheet according to (1) or (2) above, The hot-rolled steel sheet for non-oriented electrical steel sheet is cold-rolled without hot-rolled sheet annealing, The cold-rolled material after the cold rolling may be finish-annealed at 800° C. or higher and Ac1 point or lower. Effect of the Invention

[0014] According to the above aspects of the present invention, it is possible to provide a hot-rolled steel sheet for a non-oriented electrical steel sheet, which has excellent iron loss characteristics at high frequencies in addition to general magnetic properties, a manufacturing method for a hot-rolled steel sheet for a non-oriented electrical steel sheet, and a manufacturing method for a non-oriented electrical steel sheet. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0015] A preferred embodiment of the present invention will be described in detail below. However, the present invention is not limited to the configuration disclosed in this embodiment, and various modifications are possible without departing from the spirit of the present invention. In addition, the numerical ranges described below include lower and upper limits. Numerical values ​​indicated as "more than" or "less than" are not included in the numerical range. In addition, unless otherwise specified, "%" regarding the content of each element means "mass %".

[0016] In the hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment, the chemical components and the production conditions are controlled in a composite and inseparable manner to control the morphology of AlN contained in the hot-rolled steel sheet.

[0017] For example, in the case of a non-oriented electrical steel sheet that has a chemical composition that causes α-γ transformation during the manufacturing process and is manufactured by performing self-annealing after hot rolling instead of hot-rolled sheet annealing, it is preferable to grow crystal grains sufficiently during the self-annealing after hot rolling or during finish annealing in order to improve the magnetic properties.

[0018] However, AlN contained in the hot-rolled steel sheet pins grain boundary migration and inhibits the growth of crystal grains, so it is preferable that the heat-rolled steel sheet contains as little AlN as possible.

[0019] For example, the above-mentioned Patent Document 4 attempts to reduce the amount of AlN contained in the steel sheet. It is true that the technology disclosed in Patent Document 4 may be able to reduce the amount of AlN contained in the steel sheet to some extent. However, the technology disclosed in Patent Document 4 cannot fundamentally suppress the precipitation of AlN during the γ→α transformation, and a significant amount of AlN precipitated, particularly at the grain boundaries of ferrite (α) grains. As a result, the crystal grains could not grow sufficiently during self-annealing after hot rolling or during finish annealing.

[0020] In this embodiment, the chemical composition and the manufacturing conditions are controlled in a composite and inseparable manner to reduce the number of AlN particles present within and at the grain boundaries of the α phase, and in particular to reduce the number of AlN particles present at the grain boundaries of the α phase. As a result, the crystal grains can grow sufficiently during the self-annealing and finish annealing after hot rolling, making it possible to obtain a non-oriented electrical steel sheet that has excellent iron loss characteristics at high frequencies in addition to general magnetic properties.

[0021] In addition, Patent Document 4 refers to the AlN number density in the steel sheet after finish annealing. However, since it is presumed that AlN precipitated in the hot rolling process undergoes Ostwald ripening during finish annealing and the AlN number density decreases, it cannot necessarily be compared with the AlN number density in the hot-rolled steel sheet in this embodiment. Furthermore, since the steel sheet crystal structure after hot rolling is processed and deformed in the subsequent cold rolling and recrystallized and grows in grains in finish annealing, the ferrite grain boundaries after hot rolling and the ferrite grain boundaries after finish annealing do not necessarily coincide with each other.

[0022] The hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment is Chemical composition, by mass%, C: 0.005% or less, Si: 0.10-1.50%, Mn: 0.10-0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010~0.0030%, V: 0.0010~0.0030%, Zr: 0.0010~0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0 to 0.20% with the remainder being Fe and impurities, When viewed from a cross section parallel to the rolling direction and plate thickness direction, AlN with a circle equivalent diameter of 10 to 200 nm exists within and at the grain boundaries of ferrite grains. The density of the AlN particles present within the grains and at the grain boundaries was 8.0 particles / μm 2 is less than or equal to The density of the AlN particles present at the grain boundaries is 40 particles / μm 2 The following is the result.

[0023] <Chemical composition of hot-rolled steel sheet> First, with regard to the hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment, the reasons for limiting the chemical components of the steel will be described.

[0024] In this embodiment, the heat-rolled steel sheet contains, as its chemical components, basic elements, optional elements as necessary, and the balance being Fe and impurities.

[0025] C: 0.005% or less C is a harmful element that deteriorates core loss and causes magnetic aging. The C content is 0.005% or less. The C content is preferably 0.003% or less. The lower the C content, the more preferable it is, and the lower limit may be 0%. However, in consideration of industrial productivity, the C content may be more than 0%, and may be 0.0015% or more, 0.0020% or more, or 0.0025% or more.

[0026] Silicon: 0.10 to 1.50% Silicon is an element that increases the resistivity of steel and reduces iron loss. Therefore, the lower limit of the silicon content is set to 0.10%. On the other hand, excessive addition of silicon reduces magnetic flux density. Therefore, the upper limit of the silicon content is set to 1.50%. Preferably, the lower limit of the silicon content may be 0.50% and the upper limit of the silicon content may be 1.20%.

[0027] Mn: 0.10 to 0.60% Mn increases the resistivity of steel and also coarsens sulfides to render them harmless. Therefore, the lower limit of Mn content is set to 0.10%. On the other hand, excessive addition of Mn embrittles steel and leads to increased costs. Therefore, the upper limit of Mn content is set to 0.60%.

[0028] P:0.100% or less P can increase the hardness of steel sheet, but it also leads to embrittlement of steel. The P content is set to 0.100% or less. The P content is preferably 0.08%. The lower the P content, the more preferable it is, and the lower limit may be 0%. However, in consideration of industrial productivity, the P content may be 0.001% or more.

[0029] Al: 0.20-1.00% Al is a deoxidizing element, and at the same time, it is an element that increases resistivity, raises the α-γ transformation point, and generates AlN. Therefore, the lower limit of the Al content is set to 0.20%. On the other hand, excessive addition of Al causes a decrease in magnetic flux density and a decrease in workability. Therefore, the upper limit of the Al content is set to 1.00%. The upper limit of the Al content is preferably 0.80%.

[0030] Ti: 0.0010~0.0030% Ti is an element that forms nitrides, but unlike AlN, it precipitates sufficiently as a nitride even in the γ phase. In this embodiment, Ti is important as a nitride forming element to suppress fine precipitation of AlN at the α grain boundary during γ→α transformation. Therefore, the lower limit of the Ti content is set to 0.0010%. On the other hand, excessive addition forms carbides and deteriorates grain growth during finish annealing. Therefore, the upper limit of the Ti content is set to 0.0030%.

[0031] Nb: 0.0010~0.0030% Nb is an element that forms nitrides, but unlike AlN, it precipitates sufficiently as a nitride even in the γ phase. In this embodiment, Nb is important as a nitride forming element to suppress fine precipitation of AlN at the α grain boundary during γ→α transformation. Therefore, the lower limit of the Nb content is set to 0.0010%. On the other hand, excessive addition forms carbides and deteriorates grain growth during finish annealing. Therefore, the upper limit of the Nb content is set to 0.0030%.

[0032] V: 0.0010~0.0030% V is an element that forms nitrides, but unlike AlN, it sufficiently precipitates as a nitride even in the γ phase. In this embodiment, V is important as a nitride forming element to suppress fine precipitation of AlN at the α grain boundary during γ→α transformation. Therefore, the lower limit of the V content is set to 0.0010%. On the other hand, excessive addition forms carbides and deteriorates grain growth during finish annealing. Therefore, the upper limit of the V content is set to 0.0030%.

[0033] Zr: 0.0010~0.0030% Zr is an element that forms nitrides, but unlike AlN, it can fully precipitate as a nitride even in the gamma phase. Zr is important as a nitride-forming element to suppress the fine precipitation of AlN at the alpha grain boundaries during the Zr gamma → alpha transformation. Therefore, the lower limit of the Zr content is set to 0.0010%. On the other hand, excessive addition forms carbides and impairs grain growth during finish annealing. Therefore, the upper limit of the Zr content is set to 0.0030%.

[0034] N: 0.0030% or less N is an element that produces AlN and is unfavorable for grain growth. In this embodiment, the N content is set to 0.0030% or less as the allowable upper limit for rendering N harmless. The lower the N content, the more preferable it is, and the lower limit may be 0%. However, in consideration of industrial productivity, the N content may be 0.0001% or more. For example, when the N content is 0.0001% or more, AlN is likely to be produced and grain growth is likely to be hindered.

[0035] Sn: 0 to 0.20% Sb: 0 to 0.20% Sn and Sb improve the texture after cold rolling recrystallization and increase the magnetic flux density. Therefore, Sn and Sb may be contained as necessary. For example, the lower limit of the Sn content and Sb content is preferably 0.02%, and more preferably 0.03%. On the other hand, excessive addition of Sn and Sb embrittles the steel. Therefore, the upper limit of the Sn content and Sb content is set to 0.20%. The upper limit of the Sn content and Sb content is preferably 0.10%.

[0036] The above-mentioned effects can be obtained by containing at least one of Sn and Sb, and therefore it is preferable that the alloy contains at least one of Sn: 0.02 to 0.20% or Sb: 0.02 to 0.20% by mass as a chemical component.

[0037] The chemical components of the hot-rolled steel sheet according to the present embodiment described above correspond to the chemical components that cause α-γ transformation during the manufacturing process.

[0038] In the present embodiment, impurities may be contained as chemical components. The term "impurities" refers to elements that do not impair the effects of the present embodiment even if contained, and refers to elements that are mixed in from raw materials such as ores and scraps, or from the manufacturing environment, when industrially manufacturing steel sheets. The upper limit of the total content of impurities may be, for example, 5%.

[0039] The above chemical components may be measured by a general analysis method for steel. For example, the chemical components may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Specifically, a 35 mm square test piece taken from the steel plate is measured under conditions based on a calibration curve prepared in advance using a measuring device such as Shimadzu ICPS-8100, to identify the chemical components. C may be measured using a combustion-infrared absorption method, and N may be measured using an inert gas fusion-thermal conductivity method.

[0040] A slab is formed by casting molten steel adjusted so that the hot-rolled steel sheet has the above-described composition. The method for casting the slab is not particularly limited. In research and development, even if a steel ingot is formed in a vacuum melting furnace or the like, the same effect as when a slab is formed can be confirmed for the above-described composition.

[0041] <AlN contained in hot-rolled steel sheets> Regarding the hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment, the reason for limiting the amount of AlN contained in the hot-rolled steel sheet will be described.

[0042] As described above, in this embodiment, the chemical components and the manufacturing conditions are controlled in a composite and inseparable manner to control the form of AlN contained in the hot-rolled steel sheet. In particular, in this embodiment, precipitation of AlN at the grain boundaries of α grains is suppressed.

[0043] In the hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment, when viewed in a cross section parallel to the rolling direction and the sheet thickness direction, AlN having a circle equivalent diameter of 10 to 200 nm is present within and at the grain boundaries of ferrite grains (α grains), The number density of AlN particles present within the grains and at the grain boundaries (total number density) was 8.0 particles / μm 2 is less than or equal to The number density of AlN particles at the grain boundaries (number density at the grain boundaries) is 40 particles / μm 2 The following is the result.

[0044] In this embodiment, AlN having a size that has the greatest effect on grain growth is controlled to have a circle equivalent diameter of 10 to 200 nm. In the hot-rolled steel sheet for non-oriented electrical steel sheet according to this embodiment, AlN having the above size is contained within and at the grain boundaries of α grains.

[0045] The density of AlN particles of the above size present within and on the grain boundaries of α grains was 8.0 particles / μm 2 If the grain size exceeds 100%, the crystal grain growth during self-annealing and final annealing becomes insufficient. As a result, the magnetic flux density and core loss characteristics of the non-oriented electrical steel sheet decrease. The number density of AlN particles of the above size present within and on the grain boundaries of α grains is 8.0 particles / μm2 relative to the observation area. 2 On the other hand, the number density of AlN particles of the above sizes present within and on the grain boundaries of α grains is preferably as low as possible, with the lower limit being 0 particles / μm 2 However, this number density may be 0 pieces / μm 2 In practice, it is difficult to achieve this, and industrially, the density of AlN particles of the above size present within and on the grain boundaries of α grains is set to 0.1 particles / μm2 relative to the observation area. 2 It can be more than that.

[0046] Furthermore, in order to improve the iron loss characteristics at high frequencies, it is not sufficient to simply control the number density (total number density) of AlN of the above size present within and at the grain boundaries of α grains; it is preferable to control the number density (number density at the grain boundaries) of AlN of the above size present at the grain boundaries of α grains.

[0047] The density of AlN particles of the above size present at the grain boundaries of α grains is 40 particles / μm 2 If the grain size exceeds 100%, the grain growth during self-annealing and final annealing becomes insufficient. As a result, the core loss characteristics at high frequencies of the non-oriented electrical steel sheet deteriorate. The number density of AlN particles of the above size present at the grain boundaries of α grains is 40 particles / μm2 relative to the grain boundary area. 2 The density of the particles is 35 particles / μm 2On the other hand, the number density of AlN particles of the above size present in the grain boundaries of α grains is preferably as small as possible, and the lower limit is 0 particles / μm with respect to the grain boundary area. 2 However, this number density may be 0 pieces / μm 2 In practice, it is difficult to achieve this, and industrially, the density of AlN particles of the above size present at the grain boundaries of α grains is set to 0.5 particles / μm2 relative to the grain boundary area. 2 It can be more than that.

[0048] The AlN contained in the hot-rolled steel sheet may be identified using TEM-EDS (Transmission Electron Microscope-Energy Dispersive X-ray Spectroscopy). For example, a thin film sample may be taken from the hot-rolled steel sheet, with a cross section parallel to the rolling direction and the sheet thickness direction as the observation surface, and precipitates with an atomic ratio of Al to N of approximately 1:1 may be identified in the observation field based on the observation and quantitative analysis results using TEM-EDS. The diameter of the identified AlN when its area is converted into a circle is defined as the circle equivalent diameter. AlN with a circle equivalent diameter of 10 to 200 nm present in the observation field (observation area) may be identified, and the number density of AlN present within and at the grain boundaries of α grains (total number density) and the number density of AlN present at the grain boundaries of α grains (number density at grain boundaries) may be obtained. For example, the observation field may be at least 10 μm×10 μm in size. The number of AlN particles present at a grain boundary is defined as the number of AlN particles present within a distance of 0.2 μm from the grain boundary into each grain on either side of the grain boundary, and the grain boundary area is defined as the total distance of the grain boundaries in the image obtained by TEM-EDS observation multiplied by 0.4 μm. Note that, in order to derive the circle equivalent diameter, the image obtained by TEM-EDS observation may be read by a scanner or the like and analyzed using commercially available image analysis software.

[0049] <Method of manufacturing hot-rolled steel sheets> Next, a method for producing a hot-rolled steel sheet for use as a non-oriented electrical steel sheet according to this embodiment will be described.

[0050] The manufacturing method of the hot-rolled steel sheet for non-oriented electrical steel sheet according to the present embodiment is the manufacturing method of the above-mentioned hot-rolled steel sheet, Chemical composition, by mass%, C: 0.005% or less, Si: 0.10-1.50%, Mn: 0.10-0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010~0.0030%, V: 0.0010~0.0030%, Zr: 0.0010~0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0 to 0.20% and the balance being Fe and impurities, to a temperature range of 1050°C to 1180°C, The heated slab is roughly rolled, The rough-rolled material after the rough rolling is held at a temperature range of 850°C or higher and Ar1 point or lower, The rough rolled material after the above-mentioned holding is reheated to a temperature range of more than Ar1 point and less than Ac1 point, The rough rolled material immediately after heating is finish-rolled under the condition that the end temperature of the finish rolling is 800°C or higher and Ar1 point or lower, The finish-rolled material after the above-mentioned finish rolling is coiled at a temperature in the range of 750°C to 850°C.

[0051] In this embodiment, the coil is self-annealed after the finish rolling of the hot rolling, aiming to improve the magnetic properties of the non-oriented electrical steel sheet. For example, in this embodiment, during hot rolling, the slab heating temperature is set to 1050°C to 1180°C, rough rolling is performed, the rough rolled material is held at 850 to Ar1 point, the rough rolled material after holding is heated to above Ar1 point and below Ac1 point, finish rolling is performed, and the finish rolled material is coiled at 750°C to 850°C. These manufacturing conditions can preferably suppress the precipitation of AlN at the grain boundaries of the α phase. As a result, crystal grains grow preferably during self-annealing and finish annealing, and excellent core loss and magnetic flux density can be obtained as a non-oriented electrical steel sheet.

[0052] The chemical composition of the slab is the same as that of the hot-rolled steel sheet described above. In the production of non-oriented electrical steel sheets, the chemical composition hardly changes during the process from the slab to the hot-rolled steel sheet. The chemical composition of the slab described above corresponds to the chemical composition in which the α-γ transformation occurs during the production process.

[0053] The slab heating temperature is set to 1180°C or less to prevent the precipitates from resolving and forming fine precipitates, and to prevent deterioration of iron loss. However, if the slab heating temperature is too low, the deformation resistance increases and the load of hot rolling increases, so the temperature is set to 1050°C or more. The lower limit of the slab heating temperature is preferably 1080°C. The upper limit of the slab heating temperature is preferably 1150°C, and more preferably 1130°C.

[0054] The conditions for the rough rolling are not particularly limited, and known rough rolling conditions may be applied.

[0055] The rough rolled material after rough rolling is kept at or below the Ar1 point to transform into the α phase. The Ar1 point is the temperature at which transformation to the α phase ends during cooling. The rough rolled material immediately after rough rolling has a two-phase structure of the α phase and the γ phase. In this embodiment, since Ti, Nb, V, and Zr are essential chemical components, nitrides of Ti, Nb, V, and Zr are generated in the γ phase, the number of AlN present in the steel is reduced, and the content of solute N in the steel is reduced. However, some N remains in a state of being dissolved in the steel. Therefore, the rough rolled material after rough rolling is kept at or below the Ar1 point to transform the steel structure into a single-phase structure of the α phase with low N solubility. As a result, a large amount of N dissolved in the steel precipitates as nitrides (e.g., AlN). By applying such a heat cycle to suppress the amount of solute N, it is possible to suppress the precipitation of a large amount of nitrides after finish rolling.

[0056] As a result of the study by the present inventors, it was found that AlN precipitated after rough rolling and before finish rolling is unlikely to become AlN present at the grain boundary of the α phase. Although the detailed reason is unclear at present, even if AlN precipitates at the grain boundary after rough rolling and before finish rolling, it is considered that the location of AlN (grain boundary or grain interior) changes due to dynamic and static structural changes caused by finish rolling. Therefore, it is considered that the number of AlN present at the grain boundary of the α phase will eventually decrease. That is, in this embodiment, it is important to precipitate a large amount of N that was dissolved in the steel after rough rolling and before finish rolling as nitrides (e.g., AlN), and not to re-dissolve this nitride after finish rolling. For example, if nitrides are re-dissolved after finish rolling, it is considered that N that was re-dissolved in the steel will preferentially precipitate as AlN at the grain boundary of the α phase during the cooling process after finish rolling.

[0057] For the above reasons, the rough-rolled material after rough rolling is kept at the Ar1 point or lower. On the other hand, if the holding temperature is too low, nitrides are difficult to precipitate and grow. Therefore, the rough-rolled material after rough rolling is kept at 850°C or higher.

[0058] The cooling rate for cooling the rough rolled material after rough rolling to a temperature range of 850°C or higher and Ar1 point or lower is not particularly limited. However, after rough rolling is completed, it is preferable to cool the rough rolled material to a temperature range of 850°C or higher and Ar1 point or lower at an average cooling rate of 0.1 to 2°C / sec. If the average cooling rate is less than 0.1°C / sec, the production efficiency is poor, and if it exceeds 2°C / sec, nitrides may be difficult to precipitate or grow.

[0059] The rough rolled material held in the temperature range of 850°C to Ar1 is reheated to a temperature range of more than Ar1 and less than Ac1. As described above, Ar1 is the temperature at which transformation to the α phase ends when cooled. Ac1 is the temperature at which transformation to the γ phase begins when heated. The rough rolled material held in the temperature range of 850°C to Ar1 is transformed into a single-phase structure of the α phase, but the finish rolling temperature and coiling temperature are too low at this temperature. Therefore, the finish rolling temperature and coiling temperature are increased, and the rough rolled material after the above holding is reheated in order to increase the self-annealing effect when wound into a coil. If the reheating temperature exceeds Ac1, transformation from the α phase to the γ phase occurs, N redissolves in the steel, and the redissolved N precipitates as nitrides (e.g., AlN) during the cooling process after finish rolling. In particular, it precipitates in large amounts at the grain boundaries of the α phase, and as a result, it inhibits grain growth during self-annealing and finish annealing. Therefore, the reheating temperature is set to Ac1 point or lower. On the other hand, in order to obtain a sufficient self-annealing effect by increasing the finish rolling temperature and coiling temperature, the reheating temperature is set to above Ar1 point. Note that any number of heating degrees may be used within this temperature range. In addition, there are no particular limitations on the method or system of reheating, and induction heating or the like may be used. Note that the temperatures of Ar1 and Ac1 may be determined experimentally.

[0060] The rough rolled material reheated to a temperature range of more than Ar1 point and less than Ac1 point is finish-rolled. The end temperature of the finish rolling is 800°C or more and less than Ar1 point. As described above, Ar1 point is the temperature at which transformation to α phase is completed during cooling. If the end temperature of the finish rolling is lower than 800°C, a sufficient coiling temperature cannot be secured. Therefore, the end temperature of the finish rolling is 800°C or more. On the other hand, if the end temperature of the finish rolling exceeds Ar1 point, some γ phase remains as a steel structure in the finish rolled material, and γ→α transformation occurs during coiling after finish rolling, and N that was solid-solved in the γ phase precipitates at the grain boundaries of the α phase, which inhibits grain growth during self-annealing and finish annealing. Therefore, the end temperature of the finish rolling is Ar1 point or less.

[0061] The coiling temperature of the finish rolled material is 750°C or higher and 850°C or lower. If the coiling temperature is lower than 750°C, the crystal grains do not grow sufficiently by self-annealing. Therefore, the coiling temperature is set to 750°C or higher. On the other hand, if the coiling temperature exceeds 850°C, the surface scale (surface oxide) of the finish rolled material becomes excessive, which deteriorates the descaling property during pickling. Therefore, the coiling temperature is set to 850°C or lower.

[0062] In the hot-rolled steel sheet manufactured under the above-mentioned manufacturing conditions, the number of AlN present within and at the grain boundaries of the α phase is small, and the number of AlN present at the grain boundaries of the α phase is particularly small. As a result, the crystal grains can grow sufficiently during the self-annealing and finish annealing after hot rolling, making it possible to obtain a non-oriented electrical steel sheet that has excellent iron loss characteristics at high frequencies in addition to general magnetic properties.

[0063] <Manufacturing method of non-oriented electrical steel sheet> Next, a method for manufacturing the non-oriented electrical steel sheet according to this embodiment will be described.

[0064] The manufacturing method of the non-oriented electrical steel sheet according to the present embodiment is a manufacturing method of the non-oriented electrical steel sheet using the above-mentioned hot-rolled steel sheet, The hot-rolled steel sheet manufactured under the above-mentioned manufacturing conditions is cold-rolled without hot-rolled sheet annealing, The cold-rolled material after the above cold rolling is finish-annealed at 800° C. or higher and Ac1 point or lower.

[0065] The hot-rolled steel sheet manufactured under the above-mentioned manufacturing conditions is pickled, cold-rolled, and finish-annealed. The cold-rolling conditions are not particularly limited. Known cold-rolling conditions may be used.

[0066] The final annealing temperature is 800°C or higher and Ac1 point or lower. If the final annealing temperature is lower than 800°C, unrecrystallized structure remains and the magnetic properties deteriorate. Therefore, the final annealing temperature is 800°C or higher. On the other hand, if the final annealing temperature exceeds the Ac1 point, α→γ transformation occurs and the magnetic properties deteriorate. Therefore, the final annealing temperature is set to Ac1 point or lower.

[0067] The final annealing time is preferably 10 seconds or more and 600 seconds or less. If the final annealing time is within the above range, the crystal grains can be grown sufficiently.

[0068] The non-oriented electrical steel sheet manufactured under the above-mentioned manufacturing conditions has excellent core loss characteristics at high frequencies in addition to general magnetic properties.

[0069] The lower the iron loss of the non-oriented electrical steel sheet, the more preferable, for example, the iron loss W15 / 50 is preferably less than 5.2 W / kg, and the iron loss W10 / 200 is preferably less than 18.0 W / kg. Also, the higher the magnetic flux density of the non-oriented electrical steel sheet, the more preferable, for example, the magnetic flux density B50 is preferably 1.69 T or more, and the magnetic flux density B25 is preferably 1.62 T or more.

[0070] The magnetic properties of the magnetic steel sheet, such as the magnetic flux density, can be measured by a known method. For example, the magnetic properties of the magnetic steel sheet can be measured by using a method based on the Epstein test defined in JIS C2550:2011, or the Single Sheet Tester (SST) defined in JIS C2556:2015. In research and development, when a steel ingot is formed in a vacuum melting furnace or the like, it is difficult to take a test piece of the same size as that of the actual production. In this case, for example, a test piece with a width of 55 mm and a length of 55 mm may be taken and a measurement in accordance with the Single Sheet Magnetic Property Test Method may be performed. Furthermore, a correction coefficient may be multiplied to the obtained result so that a measurement value equivalent to that of the method based on the Epstein test is obtained. In this embodiment, the measurement is performed by a measurement method in accordance with the Single Sheet Magnetic Property Test Method. EXAMPLES

[0071] The effects of one embodiment of the present invention will be described in more detail with reference to the following examples, but the conditions in the examples are merely examples of conditions adopted to confirm the feasibility and effects of the present invention, and the present invention is not limited to these examples. Various conditions may be adopted in the present invention as long as they do not deviate from the gist of the present invention and the object of the present invention is achieved.

[0072] <Example 1> Slabs having the chemical compositions shown in Tables 1A and 1B were hot rolled to a thickness of 2.5 mm under the manufacturing conditions of the hot rolling codes shown in Tables 2A and 2B, and hot rolled steel sheets were coiled.

[0073] [Table 1A]

[0074] [Table 1B]

[0075] [Table 2A]

[0076] [Table 2B]

[0077] The chemical composition of the produced hot-rolled steel sheet was equivalent to that of the slab. A test piece was cut out from the center in the sheet width direction of the produced hot-rolled steel sheet, and a transmission electron microscope (TEM) sample was prepared so that a cross section parallel to the rolling direction and sheet thickness direction could be observed. A field of view of 10 μm × 10 μm was observed with the transmission electron microscope (TEM), and the number density of AlN with a circle equivalent diameter of 10 to 200 nm was calculated as described above. The results are shown in Tables 3A to 3C.

[0078] [Table 3A]

[0079] [Table 3B]

[0080] [Table 3C]

[0081] In addition, the hot-rolled steel sheets were pickled and then cold-rolled to 0.5 mm to obtain cold-rolled steel sheets, which were then finish-annealed under the conditions of the finish-annealing codes shown in Table 4 to obtain non-oriented electrical steel sheets.

[0082] [Table 4]

[0083] Test pieces of 55 mm square were cut out parallel to the rolling direction and sheet width direction from the non-oriented electrical steel sheets after final annealing, and the iron loss and magnetic flux density were measured using a measurement method in accordance with the single sheet magnetic property test method (JIS C 2556:2015), and the average values ​​in the L direction and C direction were calculated.

[0084] In addition to the conventional general evaluation index W15 / 50, we also measured W10 / 200, which is the iron loss when used at high frequencies. W15 / 50 is the iron loss obtained by exciting non-oriented electrical steel sheet to 1.5T at 50Hz, and W10 / 200 is the iron loss obtained by exciting non-oriented electrical steel sheet to 1.0T at 200Hz.

[0085] The magnetic flux densities measured were B50 and B25. Note that B50 is the magnetic flux density when a magnetic field of 5000 A / m at 50 Hz is applied to a non-oriented electrical steel sheet, and B25 is the magnetic flux density when a magnetic field of 2500 A / m at 50 Hz is applied to a non-oriented electrical steel sheet.

[0086] It was judged as passing when W15 / 50 was less than 5.2 W / kg, W10 / 200 was less than 18.0 W / kg, B50 was 1.69 T or more, and B25 was 1.62 T or more. The results are shown in Tables 3A to 3C.

[0087] As shown in Tables 3A to 3C, the examples of the present invention satisfied the chemical composition and AlN number density, and therefore had excellent magnetic properties. In contrast, as shown in Tables 3A to 3C, the comparative examples did not satisfy either the chemical composition or the AlN number density, and therefore did not have excellent manufacturability or magnetic properties.

[0088] In Comparative Examples No. d30 and No. d31, the contents of Ti, Nb, V and Zr in the slab components did not satisfy the preferred range, and the rough rolled material was not held in the temperature range of 850 ° C. or more and Ar1 point or less after rough rolling, and the rough rolled material was not reheated to a temperature range of more than Ar1 point and less than Ac1 point after rough rolling. In Comparative Examples No. d30 and No. d31, rolling was performed with care so that the steel sheet temperature did not decrease during rough rolling and finish rolling, so the finish rolling end temperature was 800 ° C. or more even without reheating after rough rolling. In Comparative Examples No. d30 and No. d31, the finish rolling end temperature was 800 ° C. or more, but holding and reheating after rough rolling were not performed, so the AlN number density of the hot-rolled steel sheet was not favorably controlled. As a result, in Comparative Examples No. d30 and No. d31, as non-oriented electrical steel sheets, they satisfied W15 / 50, but were not excellent in W10 / 200.

[0089] <Example 2> Slabs having the chemical compositions shown in Tables 1A and 1B were hot rolled to a thickness of 2.5 mm under the manufacturing conditions of the hot rolling codes shown in Tables 2A and 2B, and hot rolled steel sheets were coiled.

[0090] The chemical composition of the produced hot-rolled steel sheet was equivalent to that of the slab. A test piece was cut out from the center in the sheet width direction of the produced hot-rolled steel sheet, and a transmission electron microscope (TEM) sample was prepared so that a cross section parallel to the rolling direction and sheet thickness direction could be observed. A field of view of 10 μm × 10 μm was observed with the transmission electron microscope (TEM), and the number density of AlN with a circle equivalent diameter of 10 to 200 nm was calculated as described above. The results are shown in Table 5.

[0091] [Table 5]

[0092] In addition, the hot-rolled steel sheets were pickled and then cold-rolled to 0.5 mm to obtain cold-rolled steel sheets, which were then finish-annealed under the conditions of the finish-annealing codes shown in Table 4 to obtain non-oriented electrical steel sheets.

[0093] Test pieces of 55 mm square were cut out parallel to the rolling direction and sheet width direction from the non-oriented electrical steel sheets after final annealing, and the iron loss and magnetic flux density were measured using a measurement method in accordance with the single sheet magnetic property test method (JIS C 2556:2015), and the average values ​​in the L direction and C direction were calculated.

[0094] In addition to the conventional evaluation index of W15 / 50, the iron loss was also measured at W10 / 200, which is the iron loss when used at high frequencies. Magnetic flux density was measured at B50 and B25.

[0095] As in Example 1, the test piece was judged as acceptable when W15 / 50 was less than 5.2 W / kg, W10 / 200 was less than 18.0 W / kg, B50 was 1.69 T or more, and B25 was 1.62 T or more. The results are also shown in Table 5.

[0096] As shown in Table 5, the examples of the present invention satisfied the chemical composition and AlN number density, and therefore had excellent magnetic properties. [Industrial Applicability]

[0097] According to the above aspects of the present invention, it is possible to provide a hot-rolled steel sheet for a non-oriented electrical steel sheet, which is excellent in iron loss characteristics at high frequencies in addition to general magnetic properties, a manufacturing method for the hot-rolled steel sheet for a non-oriented electrical steel sheet, and a manufacturing method for the non-oriented electrical steel sheet, which are therefore highly industrially applicable.

Claims

1. A hot-rolled steel sheet for use in a non-oriented electrical steel sheet, Chemical composition, by mass%, C: 0.005% or less, Si: 0.10 to 1.50%, Mn: 0.10 to 0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010-0.0030%, V: 0.0010-0.0030%, Zr: 0.0010-0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0-0.20% with the remainder being Fe and impurities, When viewed from a cross section parallel to the rolling direction and the sheet thickness direction, AlN having a circle equivalent diameter of 10 to 200 nm is present within and at the grain boundaries of ferrite grains, The number density of the AlN particles present within the grains and at the grain boundaries is 8.0 particles / μm ２ is as follows: The density of the AlN particles present at the grain boundary is 40 particles / μm ２ is less than or equal to When the hot-rolled steel sheet is cold-rolled without annealing, and then annealed at 800° C. or higher and Ac1 point or lower, and then the iron loss W15 / 50 and iron loss W10 / 200 are measured, the iron loss W15 / 50 is less than 5.2 W / kg, and the iron loss W10 / 200 is less than 18.0 W / kg. A hot-rolled steel sheet for non-oriented electrical steel sheet, characterized in that

2. Chemical composition, by mass%, Sn: 0.02-0.20%, Sb: 0.02-0.20% Contains at least one of The hot-rolled steel sheet for non-oriented electrical steel sheet according to claim 1 .

3. A method for producing a hot-rolled steel sheet for non-oriented electrical steel sheet according to claim 1 or 2, Chemical composition, by mass%, C: 0.005% or less, Si: 0.10 to 1.50%, Mn: 0.10 to 0.60%, P: 0.100% or less, Al: 0.20-1.00%, Ti: 0.0010 to 0.0030%, Nb: 0.0010-0.0030%, V: 0.0010-0.0030%, Zr: 0.0010-0.0030%, N: 0.0030% or less, Sn: 0-0.20%, Sb: 0-0.20% and the balance being Fe and impurities, heating the slab to a temperature range of 1050° C. to 1180° C., The heated slab is roughly rolled, The rough rolled material after the rough rolling is held at a temperature range of 850 ° C. or higher and Ar1 point or lower, The roughly rolled material after the holding is reheated to a temperature range of more than Ar1 point and less than Ac1 point, The rough rolled material immediately after heating is finish-rolled under the condition that the end temperature of the finish rolling is 800 ° C. or more and Ar1 point or less, The finish-rolled material after the finish rolling is coiled at a temperature in the range of 750° C. to 850° C. The present invention relates to a method for producing a hot-rolled steel sheet for use as a non-oriented electrical steel sheet.

4. A method for producing a non-oriented electrical steel sheet using the hot-rolled steel sheet for non-oriented electrical steel sheet according to claim 1 or 2, The hot-rolled steel sheet for non-oriented electrical steel sheet is cold-rolled without hot-rolled sheet annealing, The cold-rolled material after the cold rolling is finish-annealed at 800° C. or higher and Ac1 point or lower. A method for producing a non-oriented electrical steel sheet comprising the steps of:

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