Hot rolled steel plate

Abstract

This hot-rolled steel sheet has a desired chemical composition, wherein: a metal structure comprises, by area%, 10-30% ferrite, 40-85% bainite, 5-30% retained austenite, not more than 5% fresh martensite, and not more than 5% pearlite; the average particle diameter of the ferrite is not more than 5.00 μm; the difference between the average nanoindentation hardness of the ferrite and the average nanoindentation hardness of the bainite is not more than 1,000 MPa; and tensile strength is not less than 980 MPa.

Description

[Technical field]

[0001] The present invention relates to a hot-rolled steel sheet. This application claims priority based on Japanese Patent Application No. 2021-002859, filed on January 12, 2021, the contents of which are incorporated herein by reference. [Background technology]

[0002] From the viewpoint of protecting the global environment, efforts are being made to reduce the weight of automobile bodies in order to improve fuel efficiency. In order to further reduce the weight of automobile bodies, it is necessary to increase the strength of the steel sheets used in automobile bodies. However, in general, increasing the strength of steel sheets reduces their formability.

[0003] One method for improving the formability of steel sheets is to include retained austenite in the metal structure of the steel sheet. However, when retained austenite is included in the metal structure of the steel sheet, although the ductility is improved, the hole expandability and bendability may be reduced. When performing bending, hole expanding, and burring, not only excellent ductility but also excellent hole expandability and bendability are required.

[0004] Patent Document 1 discloses a hot-rolled steel sheet having excellent local deformability and excellent ductility with little orientation dependency of formability, and a manufacturing method thereof. The present inventors have found that it is necessary to further improve the strength, ductility, hole expandability, and bendability of the hot-rolled steel sheet described in Patent Document 1. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent No. 5533729 Summary of the Invention [Problem to be solved by the invention]

[0006] An object of the present invention is to provide a hot-rolled steel sheet having excellent strength, ductility, hole expandability and bendability. [Means for solving the problem]

[0007] In view of the above-mentioned problems, the present inventors have conducted extensive research into the chemical composition and metal structure of hot-rolled steel sheet and the relationship between the chemical composition and metal structure and the mechanical properties thereof, and have obtained the following findings (a) to (d) and completed the present invention.

[0008] (a) In order to obtain excellent strength, it is necessary to include a desired amount of bainite in the metal structure and a desired amount of Ti to precipitate Ti carbide in ferrite and increase the strength of the ferrite. (b) In order to obtain excellent ductility, it is necessary to include a desired amount of ferrite and retained austenite in the metal structure. However, the inclusion of ferrite and retained austenite reduces the hole expandability and bendability of the hot-rolled steel sheet. (c) By controlling the average grain size of ferrite within a desired range, the strength can be further improved, and the hole expandability and bendability can be improved. (d) By reducing the difference in hardness between ferrite and bainite, the hole expandability and bendability can be further improved.

[0009] The gist of the present invention, which has been made based on the above findings, is as follows. (1) A hot-rolled steel sheet according to one aspect of the present invention has a chemical composition, in mass%, C: 0.100~0.350%, Si: 0.01 to 3.00%, Mn: 1.00-4.00%, Sol.Al: 0.001-2.000%, Si+sol.Al:1.00% or more, Ti: 0.010~0.380%, P: 0.100% or less, S: 0.0300% or less, N: 0.1000% or less, O: 0.0100% or less, Nb: 0 to 0.100%, V: 0 to 0.500%, Cu: 0-2.00%, Cr: 0-2.00%, Mo: 0-1.00%, Ni: 0-2.00%, B: 0~0.0100%, Ca: 0 to 0.0200%, Mg: 0 to 0.0200%, REM: 0~0.1000%, Bi: 0 to 0.020%, One or more of Zr, Co, Zn and W: 0 to 1.00% in total, and Sn: 0 to 0.050% Tief represented by the following formula (a) is 0.010 to 0.300%, the balance being Fe and impurities, The metal structure is, in area%, Ferrite: 10-30%, Bainite: 40-85%, Retained austenite: 5 to 30%, Fresh martensite: 5% or less, and Perlite: 5% or less, The average grain size of the ferrite is 5.00 μm or less, The difference between the average nanoindentation hardness of the ferrite and the average nanoindentation hardness of the bainite is 1000 MPa or less, The tensile strength is 980MPa or more. Tief=Ti-48 / 14×N-48 / 32×S…(a) In the above formula (a), each element symbol indicates the content in mass %. (2) The hot-rolled steel sheet according to the above (1) has a chemical composition, in mass%, Nb: 0.005 to 0.100%, V: 0.005~0.500%, Cu: 0.01-2.00%, Cr: 0.01-2.00%, Mo: 0.01 to 1.00%, Ni: 0.02 to 2.00%, B: 0.0001 to 0.0100%, Ca: 0.0005~0.0200%, Mg: 0.0005~0.0200%, REM: 0.0005 to 0.1000%, and Bi: 0.0005 to 0.020% The resin may contain one or more selected from the group consisting of: Effect of the Invention

[0010] According to the above-described aspects of the present invention, it is possible to provide a hot-rolled steel sheet having excellent strength, ductility, hole expandability and bendability. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] The chemical composition and metal structure of the hot-rolled steel sheet according to this embodiment will be described in more detail below. However, the present invention is not limited to the configuration disclosed in this embodiment, and various modifications are possible without departing from the spirit of the present invention.

[0012] In the following, the numerical ranges described with "~" include the lower and upper limits. Numerical values ​​indicated as "less than" or "more than" are not included in the numerical range. In the following description, percentages related to the chemical composition of the steel sheet are mass% unless otherwise specified.

[0013] chemical composition The chemical composition of the hot-rolled steel sheet according to this embodiment includes, in mass%, C: 0.100 to 0.350%, Si: 0.01 to 3.00%, Mn: 1.00 to 4.00%, sol.Al: 0.001 to 2.000%, Si + sol.Al: 1.00% or more, Ti: 0.010 to 0.380%, P: 0.100% or less, S: 0.0300% or less, N: 0.1000% or less, O: 0.0100% or less, and the balance: Fe and impurities. Each element will be described in detail below.

[0014] C: 0.100~0.350% C is an element necessary for obtaining a desired strength. If the C content is less than 0.100%, it is difficult to obtain a desired strength. Therefore, the C content is set to 0.100% or more. The C content is preferably 0.120% or more, and more preferably 0.150% or more. On the other hand, if the C content exceeds 0.350%, the transformation rate becomes slow, which makes it easier for MA (a mixed phase of martensite and retained austenite) to form, making it difficult to obtain excellent hole expandability and bendability. Therefore, the C content is set to 0.350% or less. The C content is preferably 0.330% or less, 0.310% or less, 0.300% or less, or 0.280% or less.

[0015] Silicon: 0.01 to 3.00% Si has the effect of delaying the precipitation of cementite. This effect can increase the amount of austenite remaining untransformed, i.e., the area ratio of the retained austenite. In addition, the strength can be increased by maintaining a large amount of solid-solution C in the hard phase and preventing the cementite from coarsening. In addition, Si itself has the effect of increasing the strength of the hot-rolled steel sheet by solid-solution strengthening. In addition, Si has the effect of making the steel sound by deoxidization (suppressing the occurrence of defects such as blowholes in the steel). If the Si content is less than 0.01%, the above-mentioned effect cannot be obtained. Therefore, the Si content is set to 0.01% or more. The Si content is preferably 0.50% or more, 1.00% or more, 1.20% or more, or 1.50% or more. On the other hand, if the Si content exceeds 3.00%, the precipitation of cementite is significantly delayed and the amount of retained austenite becomes excessive, which is undesirable. In addition, the surface properties and chemical conversion treatability of the hot-rolled steel sheet, as well as the ductility and weldability, are significantly deteriorated, and the A 3 The transformation point rises significantly. This makes it difficult to perform stable hot rolling. Therefore, the Si content is set to 3.00% or less. The Si content is preferably set to 2.70% or less, more preferably 2.50% or less.

[0016] Mn: 1.00-4.00% Mn has the effect of suppressing ferrite transformation and increasing the strength of the hot-rolled steel sheet. If the Mn content is less than 1.00%, the desired strength cannot be obtained. Therefore, the Mn content is set to 1.00% or more. The Mn content is preferably 1.50% or more, 1.80% or more, 2.00% or more, or 2.40% or more. On the other hand, if the Mn content exceeds 4.00%, the ductility, hole expandability and bendability of the hot-rolled steel sheet deteriorate. Therefore, the Mn content is set to 4.00% or less. The Mn content is preferably 3.70% or less, 3.50% or less, 3.30% or less, or 3.00% or less.

[0017] Sol.Al: 0.001-2.000% Sol.Al, like Si, has the effect of deoxidizing steel to improve the soundness of the steel sheet and inhibiting the precipitation of cementite from austenite, thereby promoting the formation of retained austenite. If the sol.Al content is less than 0.001%, the above-mentioned effect cannot be obtained. Therefore, the sol.Al content is set to 0.001% or more. The sol.Al content is preferably 0.010% or more. On the other hand, if the sol.Al content exceeds 2.000%, the above effects are saturated and it is economically undesirable. 3 The transformation point rises significantly, making it difficult to perform stable hot rolling. Therefore, the sol.Al content is set to 2.000% or less. The sol.Al content is preferably set to 1.500% or less, and more preferably set to 1.300% or less. In the present embodiment, sol. Al means acid-soluble Al, and indicates solute Al that is present in the steel in a solid solution state.

[0018] Si+sol.Al:1.00% or more Both Si and sol.Al have the effect of delaying the precipitation of cementite, and this effect can increase the amount of austenite remaining untransformed, i.e., the area ratio of retained austenite. If the total content of Si and sol.Al is less than 1.00%, the above effect cannot be obtained. Therefore, the total content of Si and sol.Al is set to 1.00% or more, preferably 1.20% or more, 1.50% or more. The total content of Si and sol. Al may be 5.00% or less, 3.00% or less, or 2.60% or less. In addition, the Si in "Si+sol.Al" indicates the Si content in mass%, and the sol.Al indicates the sol.Al content in mass%.

[0019] Ti: 0.010~0.380% Ti precipitates in steel as carbides or nitrides (mainly Ti carbides), refines the metal structure through the pinning effect, and further increases the strength of ferrite through precipitation strengthening. As a result, the hardness difference between ferrite and bainite can be reduced. If the Ti content is less than 0.010%, this effect cannot be obtained. Therefore, the Ti content is set to 0.010% or more. Preferably, it is 0.050% or more, 0.070% or more, 0.090% or more, or 0.120% or more. On the other hand, if the Ti content exceeds 0.380%, the above effect saturates. Therefore, the Ti content is set to 0.380% or less, preferably 0.350% or less, 0.320% or less, or 0.300% or less.

[0020] P:0.100% or less P is an element generally contained in steel as an impurity, but has the effect of increasing the strength of hot-rolled steel sheets by solid solution strengthening. Therefore, P may be intentionally contained. However, P is an element that easily segregates, and if the P content exceeds 0.100%, the decrease in ductility due to grain boundary segregation becomes significant. Therefore, the P content is set to 0.100% or less. The P content is preferably 0.030% or less. There is no need to specify a lower limit for the P content, but from the viewpoint of refining costs, it is preferably set to 0.001%.

[0021] S: 0.0300% or less S is an element contained in steel as an impurity, and forms sulfide-based inclusions in steel, reducing the ductility of the hot-rolled steel sheet. If the S content exceeds 0.0300%, the ductility of the hot-rolled steel sheet is significantly reduced. Therefore, the S content is set to 0.0300% or less. The S content is preferably 0.0050% or less. There is no need to specify a lower limit for the S content, but from the viewpoint of refining costs, it is preferably set to 0.0001%.

[0022] N: 0.1000% or less N is an element contained in steel as an impurity, and has the effect of reducing the ductility of a hot-rolled steel sheet. If the N content exceeds 0.1000%, the ductility of the hot-rolled steel sheet is significantly reduced. Therefore, the N content is set to 0.1000% or less. The N content is preferably 0.0800% or less, 0.0700% or less. There is no need to specify a lower limit for the N content, but in order to promote the precipitation of carbonitrides, the N content is preferably 0.0010% or more, and more preferably 0.0020% or more.

[0023] O: 0.0100% or less If the steel contains a large amount of O, it forms coarse oxides that become the starting points of fracture, causing brittle fracture and hydrogen-induced cracking. Therefore, the O content is set to 0.0100% or less. The O content is preferably set to 0.0080% or less, and more preferably 0.0050% or less. In order to disperse a large number of fine oxides during deoxidation of molten steel, the O content may be set to 0.0005% or more, or 0.0010% or more.

[0024] Tief: 0.010~0.300% Tief represented by the following formula (a) is an index related to the formation of Ti carbide. Ti nitrides and Ti sulfides are formed at a higher temperature than Ti carbide. Therefore, when the steel contains a large amount of N and S, Ti carbide cannot be formed sufficiently. If Tief is less than 0.010%, the amount of Ti carbide precipitated is small, so that the effect of improving the strength of ferrite by Ti carbide cannot be obtained. As a result, the hardness difference between ferrite and bainite cannot be reduced. Therefore, Tief is set to 0.010% or more. Preferably, it is 0.050% or more, 0.100% or more. On the other hand, if Tief exceeds 0.300%, the above effects are saturated and this is not economically preferable. Therefore, Tief is set to 0.300% or less, preferably 0.270% or less, more preferably 0.250% or less.

[0025] Tief=Ti-48 / 14×N-48 / 32×S…(a) In the above formula (a), each element symbol indicates the content in mass %.

[0026] The balance of the chemical composition of the hot-rolled steel sheet according to this embodiment is composed of Fe and impurities. In this embodiment, the impurities are ores, scraps, or impurities that are mixed in from the manufacturing environment, etc. It is an element means that it is acceptable within a range that does not adversely affect the hot-rolled steel sheet according to this embodiment.

[0027] In addition to the above elements, the hot-rolled steel sheet according to this embodiment may contain the following elements as optional elements. When the optional elements are not contained, the lower limit of the content is 0%. Each optional element will be described in detail below.

[0028] Nb: 0.005~0.100% and V: 0.005~0.500% Since both Nb and V precipitate in steel as carbides or nitrides and have the effect of refining the metal structure by the pinning effect, one or more of these elements may be contained. In order to obtain the above-mentioned effect more reliably, it is preferable that the Nb content is 0.005% or more, or the V content is 0.005% or more. However, even if these elements are contained in excess, the above-mentioned effects become saturated and it is not economically preferable. Therefore, the Nb content is set to 0.100% or less, and the V content is set to 0.500% or less.

[0029] Cu: 0.01-2.00%, Cr: 0.01-2.00%, Mo: 0.01-1.00%, Ni: 0.02-2.00% and B: 0.0001-0.0100% Cu, Cr, Mo, Ni and B all have the effect of improving the hardenability of the hot-rolled steel sheet. In addition, Cr and Ni have the effect of stabilizing the retained austenite, and Cu and Mo have the effect of precipitating carbides in the steel to increase the strength of the hot-rolled steel sheet. Furthermore, when Cu is contained, Ni has the effect of effectively suppressing grain boundary cracking of the slab caused by Cu. Therefore, one or more of these elements may be contained.

[0030] Cu has the effect of increasing the hardenability of the steel sheet and the effect of increasing the strength of the hot-rolled steel sheet by precipitating in the steel as carbides at low temperatures. In order to obtain the above effects more reliably, the Cu content is preferably 0.01% or more. However, if the Cu content exceeds 2.00%, grain boundary cracking may occur in the slab, so the Cu content is set to 2.00% or less.

[0031] As described above, Cr has the effect of increasing the hardenability of the steel sheet and the effect of stabilizing the retained austenite. In order to more reliably obtain the effects of these actions, it is preferable that the Cr content be 0.01% or more. However, if the Cr content exceeds 2.00%, the chemical conversion treatability of the hot-rolled steel sheet is significantly reduced, and therefore the Cr content is set to 2.00% or less.

[0032] As described above, Mo has the effect of increasing the hardenability of the steel sheet and the effect of increasing the strength by precipitating carbides in the steel. In order to more reliably obtain the effects of the above-mentioned actions, it is preferable that the Mo content be 0.01% or more. However, even if the Mo content exceeds 1.00%, the above-mentioned effects are saturated and it is not economically preferable. Therefore, the Mo content is set to 1.00% or less.

[0033] As described above, Ni has the effect of increasing the hardenability of the steel sheet. In addition, when Cu is contained, Ni has the effect of effectively suppressing grain boundary cracking of the slab caused by Cu. In order to obtain the above-mentioned effect more reliably, it is preferable that the Ni content is 0.02% or more. Since Ni is an expensive element, it is economically undesirable to include a large amount of it, and therefore the Ni content is set to 2.00% or less.

[0034] As described above, B has the effect of enhancing the hardenability of a steel sheet. To more reliably obtain this effect, the B content is preferably 0.0001% or more. However, if the B content exceeds 0.0100%, the ductility of the hot-rolled steel sheet is significantly reduced, so the B content is set to 0.0100% or less.

[0035] Ca: 0.0005~0.0200%, Mg: 0.0005~0.0200%, REM: 0.0005~0.1000% and Bi: 0.0005~0.020% Ca, Mg and REM all have the effect of controlling the shape of inclusions to a preferred shape, thereby improving the formability of the hot-rolled steel sheet. Bi also has the effect of refining the solidification structure, thereby improving the formability of the hot-rolled steel sheet. Therefore, one or more of these elements may be contained. In order to obtain the effect of the above action more reliably, it is preferable that any one or more of Ca, Mg, REM and Bi is 0.0005% or more. However, if the Ca content or Mg content exceeds 0.0200%, or if the REM content exceeds 0.1000%, inclusions are excessively generated in the steel, which may actually reduce the ductility of the hot-rolled steel sheet. Also, even if the Bi content exceeds 0.020%, the effect of the above action is saturated, which is not economically preferable. Therefore, the Ca content and Mg content are 0.0200% or less, the REM content is 0.1000% or less, and the Bi content is 0.020% or less. The Bi content is preferably 0.010% or less.

[0036] Here, REM refers to a total of 17 elements consisting of Sc, Y and lanthanides, and the content of the above REM refers to the total content of these elements. In the case of lanthanides, they are added industrially in the form of misch metals.

[0037] One or more of Zr, Co, Zn and W: 0 to 1.00% in total, and Sn: 0 to 0.050% The inventors have confirmed that the effect of the hot-rolled steel sheet according to the present embodiment is not impaired even if the total content of Zr, Co, Zn, and W is 1.00% or less. Therefore, one or more of Zr, Co, Zn, and W may be contained in a total content of 1.00% or less. Furthermore, the inventors have confirmed that the effect of the hot-rolled steel sheet according to this embodiment is not impaired even if a small amount of Sn is added. However, since defects may occur during hot rolling, the Sn content is set to 0.050% or less.

[0038] The chemical composition of the above-mentioned hot-rolled steel sheet may be measured by a general analytical method. For example, it may be measured by using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Sol. Al may be measured by ICP-AES using the filtrate after thermally decomposing the sample with acid. C and S may be measured by the combustion-infrared absorption method, N by the inert gas fusion-thermal conductivity method, and O by the inert gas fusion-non-dispersive infrared absorption method.

[0039] Metal structure of hot-rolled steel sheet Next, the metal structure of the hot-rolled steel sheet according to this embodiment will be described. In the hot-rolled steel sheet according to this embodiment, the metal structure is composed, by area percentage, of ferrite: 10-30%, bainite: 40-85%, retained austenite: 5-30%, fresh martensite: 5% or less, and pearlite: 5% or less, the average grain size of the ferrite is 5.00 μm or less, and the difference between the average nanoindentation hardness of the ferrite and the average nanoindentation hardness of the bainite is 1000 MPa or less.

[0040] In this embodiment, the metal structure at a 1 / 4 depth position of the sheet thickness from the surface (a region from 1 / 8 depth of the sheet thickness from the surface to 3 / 8 depth of the sheet thickness from the surface) in the sheet thickness cross section parallel to the rolling direction is specified because the metal structure at this position shows a typical metal structure of a hot-rolled steel sheet.

[0041] Ferrite: 10~30% Ferrite is a structure that is inferior in strength but improves the ductility of the hot-rolled steel sheet. If the area ratio of ferrite is less than 10%, the desired ductility cannot be obtained. Therefore, the area ratio of ferrite is set to 10% or more. Preferably, it is 12% or more, 15% or more. On the other hand, if the area ratio of ferrite exceeds 30%, the desired strength cannot be obtained, so the area ratio of ferrite is set to 30% or less, preferably 27% or less, more preferably 25% or less.

[0042] Bainite: 40~85% Bainite is a structure that improves the strength and ductility of a hot-rolled steel sheet. If the area ratio of bainite is less than 40%, the desired strength and ductility cannot be obtained. Therefore, the area ratio of bainite is set to 40% or more. Preferably, it is 50% or more, 55% or more, or 60% or more. On the other hand, if the area fraction of bainite exceeds 85%, the desired ductility cannot be obtained, so the area fraction of bainite is set to 85% or less, preferably 82% or less, and more preferably 80% or less.

[0043] Retained austenite: 5~30% Retained austenite is a structure that improves the ductility of a hot-rolled steel sheet. If the area ratio of retained austenite is less than 5%, the desired ductility cannot be obtained. Therefore, the area ratio of retained austenite is set to 5% or more. Preferably, the area ratio is 7% or more, 10% or more, 12% or more, 13% or more, 14% or more, or 15% or more. On the other hand, if the area ratio of the retained austenite exceeds 30%, the desired strength cannot be obtained. Therefore, the area ratio of the retained austenite is set to 30% or less, preferably 25% or less, more preferably 23% or less.

[0044] Fresh martensite: 5% or less Fresh martensite is a hard structure, which contributes to improving the strength of hot-rolled steel sheets. However, fresh martensite is also a structure with poor ductility. If the area ratio of fresh martensite exceeds 5%, the desired ductility cannot be obtained. Therefore, the area ratio of fresh martensite is set to 5% or less. Preferably, it is 4% or less, 3% or less, or 2% or less. The area ratio of fresh martensite may be 0%.

[0045] Perlite: 5% or less If the area ratio of pearlite is too high, the desired amount of retained austenite cannot be obtained. Therefore, the area ratio of pearlite is set to 5% or less. Preferably, the area ratio is 4% or less, 3% or less, or 2% or less. The area ratio of pearlite may be 0%.

[0046] Of the above-mentioned structures, the area ratio of the structures other than the retained austenite is measured by the following method. A test piece is taken from the hot-rolled steel sheet so that the metal structure can be observed at a depth of 1 / 4 of the sheet thickness from the surface (a region from 1 / 8 of the sheet thickness from the surface to 3 / 8 of the sheet thickness from the surface) in the sheet thickness cross section parallel to the rolling direction. Next, the sheet thickness cross section is polished, and the polished surface is etched with nital, and an optical microscope and a scanning electron microscope (SEM) are used to observe the structure of an area of ​​30 μm × 30 μm. At least three areas are observed. Image analysis is performed on the structure photograph obtained by this structure observation to obtain the area ratios of ferrite, pearlite, and bainite. After that, Lepera etching is performed on the same observation position, and then the structure is observed using an optical microscope and a scanning electron microscope, and image analysis is performed on the obtained structure photograph to obtain the area ratio of fresh martensite.

[0047] In the above-mentioned structure observation, each structure is identified by the following method. Fresh martensite has a high dislocation density and has a substructure such as blocks and packets within the grains, so it can be distinguished from other metal structures using electron channeling contrast images taken with a scanning electron microscope.

[0048] Bainite is defined as a structure that is a collection of lath-shaped crystal grains and does not contain Fe-based carbides with a major axis of 20 nm or more within the structure, and is not fresh martensite, or a structure that contains Fe-based carbides with a major axis of 20 nm or more within the structure and has a single variant, i.e., the Fe-based carbides are elongated in the same direction. Here, Fe-based carbides elongated in the same direction are defined as those whose elongation directions differ by within 5°.

[0049] A structure consisting of massive crystal grains that does not contain substructures such as laths within the structure is considered to be ferrite. A structure in which plate-like ferrite and Fe-based carbides are layered is considered to be pearlite.

[0050] The area ratio of retained austenite is measured by the following method. In this embodiment, the area ratio of the retained austenite is measured by X-ray diffraction. First, in the thickness section of the hot-rolled steel sheet parallel to the rolling direction, at a depth of 1 / 4 of the thickness from the surface (a region from 1 / 8 of the thickness from the surface to 3 / 8 of the thickness from the surface), the integrated intensity of a total of six peaks, α(110), α(200), α(211), γ(111), γ(200), and γ(220), is obtained using Co-Kα radiation, and the area ratio of the retained austenite is calculated using the intensity averaging method.

[0051] Average grain size of ferrite: 5.00μm or less The size of ferrite has a significant effect on the strength, hole expandability and bendability of the hot-rolled steel sheet. If the average grain size of ferrite exceeds 5.00 μm, the strength, hole expandability and / or bendability of the hot-rolled steel sheet cannot be improved. Therefore, the average grain size of ferrite is set to 5.00 μm or less. Preferably, it is 4.00 μm or less, 3.50 μm or less, or 3.00 μm or less. Although there is no particular lower limit, the average grain size of ferrite may be 0.50 μm or more, or 1.00 μm or more.

[0052] The average grain size of ferrite is measured by the following method. The average grain size of ferrite is obtained by carrying out the following measurements on the same area as the area observed by the optical microscope and scanning electron microscope described above. The plate cross section is polished using silicon carbide paper of #600 to #1500, and then finished to a mirror surface using a diluted solution such as alcohol or a liquid in which diamond powder of grain size 1 to 6 μm is dispersed in pure water. Next, the strain introduced into the surface layer of the sample is removed by electrolytic polishing. At any position in the longitudinal direction of the sample cross section, a region of 50 μm in length and from 1 / 8 of the plate thickness depth from the surface to 3 / 8 of the plate thickness depth from the surface is measured by electron backscatter diffraction at a measurement interval of 0.1 μm to obtain crystal orientation information. For the measurement, an EBSD device consisting of a thermal field emission scanning electron microscope (JEOL JSM-7001F) and an EBSD detector (TSL DVC5 type detector) is used. At this time, the degree of vacuum in the EBSD device is 9.6 × 10 -5 The irradiation current level is 13, and the electron beam irradiation level is 62.

[0053] The obtained crystal orientation data group was analyzed using analysis software (TSL OIM Analysis), and interfaces with an orientation difference of 15° or more were defined as crystal grain boundaries. The crystal grain size was calculated as a circle equivalent diameter from the area of ​​the region surrounded by the crystal grain boundary. Among these, for the crystal grains identified as ferrite using the optical microscope and scanning electron microscope (SEM) mentioned above, the median diameter (D 50 ) to calculate the average grain size.

[0054] Difference between the average nanoindentation hardness of ferrite and that of bainite: 1000 MPa or less If the difference between the average nanoindentation hardness of ferrite and the average nanoindentation hardness of bainite exceeds 1000 MPa, the hole expandability and / or bendability cannot be improved. Therefore, the difference between the average nanoindentation hardness of ferrite and the average nanoindentation hardness of bainite is set to 1000 MPa or less. Preferably, it is 950 MPa or less, 900 MPa or less, or 850 MPa or less. Although the lower limit is not particularly defined, the difference between the average nanoindentation hardness of ferrite and the average nanoindentation hardness of bainite may be 500 MPa or more, 600 MPa or more, or 700 MPa or more.

[0055] The average nanoindentation hardness of ferrite and the average nanoindentation hardness of bainite are measured by the following method. In the field of view where the area ratio of the metal structure was measured, the area determined to be ferrite is subjected to hardness measurement by the nanoindentation method. The Martens hardness of ferrite is measured at at least 20 points and the average value is calculated to obtain the average nanoindentation hardness of ferrite. The same operation is performed on bainite to obtain the average nanoindentation hardness of bainite. The measurement is performed using a TriboScope / TriboIndenter manufactured by Hysitron, with a measurement load of 1 mN.

[0056] Mechanical properties The hot-rolled steel sheet according to the present embodiment has a tensile (maximum) strength of 980 MPa or more. By making the tensile strength 980 MPa or more, it is possible to contribute to weight reduction of the vehicle body. More preferably, the tensile strength is 1180 MPa or more. There is no particular need to limit the upper limit, but it may be 1470 MPa. The product of tensile strength and uniform elongation (TS × uEl), which is an index of ductility, may be 8260 MPa·% or more. The hole expansion ratio, which is an index of hole expandability, may be 45% or more. The maximum bending angle, which is an indicator of bendability, may be 60° or more.

[0057] The tensile strength TS and uniform elongation uEl are measured in accordance with JIS Z 2241: 2011 using a No. 5 test piece of JIS Z 2241: 2011. The tensile test piece is taken from a quarter part from the end in the sheet width direction, with the direction perpendicular to the rolling direction as the longitudinal direction.

[0058] The hole expansion ratio λ is measured in accordance with JIS Z 2256: 2020. The hole expansion test piece may be taken from a 1 / 4 portion from the end in the sheet width direction of the hot-rolled steel sheet.

[0059] The maximum bending angle α is evaluated based on the VDA standard (VDA238-100) specified by the German Association of the Automotive Industry. The displacement at the maximum load obtained in the bending test is converted to an angle using the VDA standard to determine the maximum bending angle α.

[0060] Plate Thickness The thickness of the hot-rolled steel sheet according to this embodiment is not particularly limited, but may be 0.5 to 8.0 mm. By making the thickness of the hot-rolled steel sheet 0.5 mm or more, it is easy to ensure the rolling completion temperature and the rolling load can be reduced, and hot rolling can be easily performed. Therefore, the thickness of the hot-rolled steel sheet according to this embodiment may be 0.5 mm or more. It is preferably 1.2 mm or more, 1.4 mm or more. Moreover, by making the thickness 8.0 mm or less, it is easy to make the metal structure fine, and the above-mentioned metal structure can be easily ensured. Therefore, the thickness may be 8.0 mm or less. It is preferably 6.0 mm or less.

[0061] Plating layer The hot-rolled steel sheet according to the present embodiment having the above-mentioned chemical composition and metal structure may be provided with a plating layer on the surface for the purpose of improving corrosion resistance, etc., to form a surface-treated steel sheet. The plating layer may be an electroplating layer or a hot-dip plating layer. Examples of the electroplating layer include electrogalvanizing and electrogalvanizing Zn-Ni alloy plating. Examples of the hot-dip plating layer include hot-dip galvanizing, alloyed hot-dip galvanizing, hot-dip aluminum plating, hot-dip Zn-Al alloy plating, hot-dip Zn-Al-Mg alloy plating, and hot-dip Zn-Al-Mg-Si alloy plating. The coating weight is not particularly limited and may be the same as in the past. In addition, it is also possible to further improve the corrosion resistance by performing an appropriate chemical conversion treatment (for example, application of a silicate-based chromium-free chemical conversion treatment liquid and drying) after plating.

[0062] Manufacturing conditions In a preferred manufacturing method of the hot-rolled steel sheet according to this embodiment, the following steps (1) to (7) are carried out in order. Note that the temperature of the slab and the temperature of the steel sheet in this embodiment refer to the surface temperature of the slab and the surface temperature of the steel sheet. In this embodiment, the temperature of the hot-rolled steel sheet is measured with a contact or non-contact thermometer if it is at the end in the width direction of the sheet. If it is other than the end in the width direction of the hot-rolled steel sheet, it is measured with a thermocouple or calculated by heat transfer analysis.

[0063] (1) A slab is heated to a temperature range of T0° C. or more represented by the following formula (1), and is held in that temperature range for 6000 seconds or more, and then rough rolling is performed. (2) After rough rolling is completed, finish rolling is carried out within 150 seconds. (3) The cumulative reduction in the temperature range from T1 (°C) to T1+30°C is more than 30%, the cumulative reduction in the finish rolling is 90% or more, and the final reduction in the finish rolling is 15% or more. T1 (°C) is expressed by the following formula (2). (4) Cooling is started within 1.0 second after the completion of finish rolling, and cooled to a temperature range of 600 to 700°C at an average cooling rate of 20°C / s or more. (5) After air cooling in the temperature range of 600 to 700°C for 1.0 to 3.0 seconds, the material is cooled at an average cooling rate of 40°C / s or more. (6) Winding is performed in the temperature range of T2 (℃) to 500℃. (7) The average cooling rate to the temperature range below 150°C is 15 to 40°C / h.

[0064] T0(℃)=7000 / {2.75-log(Ti×C)}-273 …(1) T1(℃)=850+10×(C+N)×Mn+350×Nb+250×Ti+40×B+10×Cr+100×Mo+100×V …(2) T2(℃)=591-474×C-33×Mn-17×Ni-17×Cr-21×Mo…(3) In the above formulas (1) to (3), the element symbols indicate the content of each element in mass %, and 0 is substituted when the element is not contained.

[0065] Slab temperature and holding time when subjected to hot rolling The slab to be subjected to hot rolling may be a slab obtained by continuous casting or a slab obtained by casting and blooming. If necessary, it may be a slab that has been subjected to hot working or cold working. In order to fully dissolve Ti carbide, it is preferable that the slab to be subjected to hot rolling is heated to a temperature range of T0 (℃) or more and held at this temperature range for 6000 seconds or more. If Ti carbide cannot be fully dissolved, it may not be possible to precipitate a sufficient amount of Ti carbide in ferrite, and it may not be possible to reduce the hardness difference between ferrite and bainite.

[0066] The hot rolling is preferably performed using a reverse mill or a tandem mill as multi-pass rolling. From the viewpoint of industrial productivity, it is more preferable to perform hot rolling using a tandem mill for at least the final several stages.

[0067] Rough rolling After holding the material in the temperature range of T0 (° C.) or higher for 6000 seconds or more, rough rolling is performed. The conditions for rough rolling are not particularly limited, and the material may be roughly rolled in the usual manner.

[0068] Finish rolling After completion of rough rolling, it is preferable to perform finish rolling within 150 seconds. That is, it is preferable to perform the first pass of finish rolling within 150 seconds after completion of the final pass of rough rolling. By performing finish rolling within 150 seconds after completion of rough rolling, a sufficient amount of Ti carbide can be precipitated in ferrite without excessive precipitation of Ti carbide in retained austenite in the secondary cooling described below. As a result, the hardness difference between ferrite and bainite can be reduced.

[0069] In addition, it is preferable that the cumulative reduction rate of the finish rolling in the temperature range of T1 (°C) to T1+30°C is more than 30%, the cumulative reduction rate of the finish rolling is 90% or more, and the final reduction rate of the finish rolling is 15% or more. By performing the finish rolling under such conditions, a desired amount of ferrite can be obtained. In addition, it is preferable that the finish rolling completion temperature is 830°C or more.

[0070] The cumulative reduction in the temperature range of T1 (℃) to T1+30℃ is the thickness at the entrance of the rolling process before the first pass in this temperature range. 0 The exit thickness after the final pass in this temperature range is t 1 Then, (t 0 -t 1 ) / t 0 It can be expressed as ×100(%). The cumulative reduction rate of the finishing roll is the thickness at the entrance before the first pass of the finishing roll. i The outlet thickness after the final pass of the finishing rolling is t f Then, (t i -t f ) / t i It can be expressed as ×100(%). The final reduction rate of the finishing rolling is the thickness at the entrance before the final pass of the finishing rolling. 2 The outlet thickness after the final pass of the finishing rolling is t 3 Then, (t 2 -t 3 ) / t 2 It can be expressed as ×100(%).

[0071] Primary cooling after finishing rolling After the completion of the finish rolling, it is preferable to start cooling within 1.0 second and cool to a temperature range of 600 to 700°C at an average cooling rate of 20°C / s or more. In other words, it is preferable to start cooling at an average cooling rate of 20°C / s or more within 1.0 second after the completion of the finish rolling and perform this cooling to a temperature range of 600 to 700°C. By performing the primary cooling within 1.0 second after the completion of the finish rolling, it is possible to preferably control the average grain size of ferrite. In addition, by performing the primary cooling to a temperature range of 600 to 700°C, it is possible to reduce the hardness difference between ferrite and bainite.

[0072] In this embodiment, the average cooling rate is a value obtained by dividing the temperature difference between the start and end of cooling by the elapsed time from the start to the end of cooling.

[0073] Intermediate and secondary cooling After cooling to a temperature range of 600 to 700°C, air cooling is performed in this temperature range for 1.0 to 3.0 seconds, and then cooling is performed at an average cooling rate of 40°C / s or more. Air cooling here refers to cooling at an average cooling rate of 10°C / s or less. Unless heat is input from the outside using a heating device or the like, the cooling rate in air cooling is about 3°C / s even for a plate thickness of about half an inch. By performing secondary cooling under these conditions, a desired amount of ferrite and residual austenite can be obtained, and a sufficient amount of Ti carbide can be precipitated in the ferrite. As a result, the hardness difference between ferrite and bainite can be reduced. Cooling at an average cooling rate of 40° C. / s or more is preferably performed to a temperature range of T2 (° C.) to 500° C. so that the sheet can be wound at the winding temperature described below. In other words, the cooling stop temperature at an average cooling rate of 40° C. / s or more is preferably set to a temperature range of T2 (° C.) to 500° C.

[0074] Winding The coiling temperature is preferably in the temperature range of T2 (°C) to 500°C. By coiling in this temperature range, it is possible to suppress the excessive precipitation of fresh martensite and obtain a desired amount of bainite. If the coiling temperature exceeds 500°C, the formation of cementite associated with bainite transformation is promoted, and the desired amount of retained austenite may not be obtained. If the coiling temperature is less than T2 (°C), tempered martensite may be formed.

[0075] Tertiary cooling after winding After coiling, the average cooling rate to a temperature range of 150°C or less is preferably 15 to 40°C / h. By carrying out tertiary cooling under such conditions, carbon can be concentrated in the retained austenite, and the retained austenite can be stabilized. As a result, a desired amount of retained austenite can be obtained. The average cooling rate is more preferably 20°C / h or more. Also, the average cooling rate is more preferably less than 30°C / h. The average cooling rate after winding may be controlled by using a heat insulating cover, an edge mask, mist cooling, or the like. EXAMPLES

[0076] Next, the effect of one embodiment of the present invention will be described in more detail with reference to an example, but the conditions in the example are merely an example of conditions adopted to confirm the feasibility and effect of the present invention, and the present invention is not limited to this example of conditions. Various conditions may be adopted in the present invention as long as they do not deviate from the gist of the present invention and the object of the present invention is achieved.

[0077] Steels having the chemical compositions shown in Tables 1 and 2 were melted and continuously cast into slabs with thicknesses of 240 to 300 mm. Hot-rolled steel sheets were obtained from the resulting slabs under the manufacturing conditions shown in Tables 3 and 4. Before hot rolling, the slabs were heated to the slab heating temperature shown in Table 3 and held for 6000 seconds or more. For Production No. 10 in Table 4, after the primary cooling, air cooling was performed in a temperature range of 530°C or less for the air cooling time shown in Table 4, and for Production No. 11, after the primary cooling, air cooling was performed in a temperature range of more than 700°C and 723°C or less for the air cooling time shown in Table 4. In all examples, tertiary cooling was performed to a temperature range of 150°C or less.

[0078] The area ratio of each structure, the average grain size of ferrite, the difference between the average nanoindentation hardness of ferrite and the average nanoindentation hardness of bainite, the tensile strength TS, the uniform elongation uEl, the hole expansion ratio λ, and the maximum bending angle α were measured for the obtained hot-rolled steel sheet by the above-mentioned method. Note that the total elongation El (the fracture elongation as defined in JIS Z 2241:2011) was obtained by the tensile test in which the tensile strength TS and the uniform elongation uEl were measured. The obtained measurement results are shown in Table 5. In addition to the structures shown in Table 5, Production No. 15 had 40 area % of tempered martensite (a structure that cannot be identified as any other structure by the above-mentioned structure observation method).

[0079] Evaluation criteria When the tensile strength TS was 980 MPa or more, it was judged to have excellent strength and to pass the test, whereas when the tensile strength TS was less than 980 MPa, it was judged to have poor strength and to fail the test.

[0080] When the product of tensile strength TS and uniform elongation uEl (TS × uEl) was 8260 MPa % or more, the specimen was deemed to have excellent ductility and passed the test. On the other hand, when TS × uEl was less than 8260 MPa %, the specimen was deemed to have poor ductility and failed the test.

[0081] When the hole expanding ratio λ was 45% or more, it was judged as having excellent hole expandability and thus passed, whereas when the hole expanding ratio λ was less than 45%, it was judged as not having excellent hole expandability and thus failed.

[0082] When the maximum bending angle was 60° or more, it was judged as having excellent bendability and passing the test, whereas when the maximum bending angle was less than 60°, it was judged as not having excellent bendability and failing the test.

[0083] [Table 1]

[0084] [Table 2]

[0085] [Table 3]

[0086] [Table 4]

[0087] [Table 5]

[0088] [Table 6]

[0089] As can be seen from Table 6, in the examples of the present invention, hot-rolled steel sheets having excellent strength, ductility, hole expandability and bendability were obtained. On the other hand, the comparative examples, whose chemical compositions and / or metal structures were not within the ranges specified by the present invention, were inferior in one or more of the above properties. In Production No. 15, the amount of bainite was insufficient, and tempered martensite was formed, resulting in poor ductility. In Production No. 16, the amount of fresh martensite was large, resulting in a large overall difference in hardness between structures, resulting in poor hole expandability and bendability. [Industrial Applicability]

[0090] According to the above-described aspects of the present invention, it is possible to provide a hot-rolled steel sheet having excellent strength, ductility, hole expandability and bendability.

Claims

1. The chemical composition, in mass%, is C: 0.100-0.350%, Si: 0.01-3.00%, Mn: 1.00-4.00%, sol. Al: 0.001 to 2.000%, Si+sol. Al: 1.00% or more, Ti: 0.010 to 0.380%, P: 0.100% or less, S: 0.0300% or less, N: 0.1000% or less, O: 0.0100% or less, Nb: 0 to 0.100%, V: 0 to 0.500%, Cu: 0-2.00%, Cr: 0-2.00%, Mo: 0-1.00%, Ni: 0-2.00%, B: 0 to 0.0100%, Ca: 0-0.0200%, Mg: 0 to 0.0200%, REM: 0-0.1000%, Bi: 0 to 0.020%, One or more of Zr, Co, Zn, and W: 0 to 1.00% in total; and Sn: 0 to 0.050%; Tief represented by the following formula (a) is 0.010 to 0.300%, The balance is Fe and impurities, The metal structure is, in area percent, Ferrite: 10-30%, Bainite: 40-85%, Retained austenite: 5 to 30%, Fresh martensite: 5% or less, and Perlite: 5% or less, The average grain size of the ferrite is 5.00 μm or less, The difference between the average nanoindentation hardness of the ferrite and the average nanoindentation hardness of the bainite is 1000 MPa or less; A hot-rolled steel sheet having a tensile strength of 980 MPa or more. Tief=Ti-48 / 14×N-48 / 32×S…(a) In the above formula (a), each element symbol indicates the content in mass %.

2. The chemical composition, in mass%, Nb: 0.005-0.100%, V: 0.005-0.500%, Cu: 0.01-2.00%, Cr: 0.01-2.00%, Mo: 0.01-1.00%, Ni: 0.02-2.00%, B: 0.0001 to 0.0100%, Ca: 0.0005-0.0200%, Mg: 0.0005-0.0200%, REM: 0.0005 to 0.1000%, and Bi: 0.0005-0.020% The hot-rolled steel sheet according to claim 1, further comprising one or more selected from the group consisting of:

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