steel plate

Abstract

The steel sheet according to the present disclosure comprises, by mass%, 0.50 to 0.90% C, 0.01 to 0.50% Si, 0.20 to 1.30% Mn, 0.100% or less P, 0.100% or less S, 0.100% or less Al, 0.01 to 1.20% Cr, 0.0150% or less N, and the balance being Fe and impurities, the total area ratio of ferrite and cementite particles being 95% or more, the average grain size of ferrite being 5.0 to 20.0 μm, and the Cr concentration [Cr] in the cementite particles being 0.01 to 0.90%. θ is less than 2.00%, and the Mo concentration [Mo] θ is 1.00% or less, the average particle size of the cementite particles is 1.50 μm or less, and the spheroidization rate of the cementite particles is 75 to less than 85%.

Description

[Technical Field]

[0001] The present disclosure relates to a steel sheet, and more particularly to a steel sheet that can be used as a material for machine parts, such as automobile parts. [Background technology]

[0002] Steel plates with a C content of 0.15% or more are used as materials for machine parts, such as automobile parts. The method for manufacturing these machine parts using steel plates as raw materials is as follows: The steel plate is cold-worked to form it into the shape of the machine part. The cold-worked steel plate is then quenched and tempered. High-strength machine parts are manufactured through the above manufacturing process. In order to obtain high strength in the machine parts after quenching, the steel plate is required to have excellent hardenability when quenched during the manufacturing process of machine parts made from steel plate. Furthermore, the steel plate is cold-worked before quenching. Therefore, the steel plate is required to have not only the above-mentioned excellent hardenability but also excellent cold workability.

[0003] Patent Documents 1 and 2 propose steel sheets that have excellent hardenability during quenching and excellent cold workability when used as materials for machine parts.

[0004] The steel sheet disclosed in Patent Document 1 contains, by mass%, C: 0.20 to 0.40%, Si: 0.10% or less, Mn: 0.50% or less, P: 0.03% or less, S: 0.010% or less, sol.Al: 0.10% or less, N: 0.0050% or less, and B: 0.0005 to 0.0050%, and further contains one or more of Sb, Sn, Bi, Ge, Te, and Se in a total amount of 0.002 to 0.030%, with the balance being Fe and unavoidable impurities. In this steel sheet, the proportion of solute B in the B content is 70% or more. Furthermore, the microstructure is composed of ferrite and cementite. Furthermore, the cementite density in the ferrite grains is 0.08 particles / μm 2 The following is the description: Patent Document 1 describes that total elongation can be increased by keeping the cementite density in ferrite grains low.

[0005] The steel sheet disclosed in Patent Document 2 contains, by mass%, C: 0.10% to 0.33%, Si: 0.01% to 0.50%, Mn: 0.40% to 1.25%, P: 0.03% to 0.01%, S: 0.01% to 0.10%, N: 0.01% to 0.50%, and Cr: 0.50% to 1.50%, with the balance being Fe and unavoidable impurities, and has a microstructure containing ferrite and carbides. The volume fraction of the ferrite and carbides in the entire microstructure is 90% or more, and the volume fraction of pro-eutectoid ferrite in the entire microstructure is 20% to 80%. The Mn concentration in the carbides is 0.10% by mass or more and 0.50% by mass or less, and the ratio of the number of carbides with a particle size of 1 μm or more to the total number of carbides is 30% to 60%. Patent Document 2 describes that by reducing the Mn concentration in the carbides, the carbides become more easily dissolved during quenching, resulting in improved hardenability. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] International Publication No. 2015 / 146173 [Patent Document 2] International Publication No. 2020 / 175665 Summary of the Invention [Problem to be solved by the invention]

[0007] Among mechanical parts, springs, washers, etc., require high strength. To increase strength, further improvement in the hardenability of the steel plate used as the material is required. C in steel plate is an effective element for improving the hardenability of steel plate. Therefore, steel plate with an increased C content of 0.50% or more is used for these mechanical parts. Even in such steel plate with a high C content, not only hardenability but also cold workability is required.

[0008] An object of the present disclosure is to provide a steel sheet having excellent hardenability and excellent cold workability. [Means for solving the problem]

[0009] The steel sheet according to the present disclosure has the following configuration.

[0010] A steel plate, The chemical composition is in mass%: C: 0.50~0.90%, Si: 0.01 to 0.50%, Mn: 0.20 to 1.30% P: 0.100% or less, S: 0.100% or less, Al: 0.100% or less, Cr: 0.01 to 1.20%, N: 0.0150% or less, Mo: 0 to 0.500%, Ni: 0 to 1.000%, B: 0~0.0100%, V: 0 to 0.500%, Nb: 0 to 0.500%, Ti: 0 to 0.150%, and The balance is composed of Fe and impurities. In the microstructure, the total area ratio of ferrite and cementite particles is 95% or more, The average particle size of the ferrite is 5.0 to 20.0 μm, Cr concentration in mass% in the cementite particles [Cr] θ is less than 2.00%, and the Mo concentration in mass% in the cementite particles [Mo] θ is 1.00% or less, The average particle size of the cementite particles is 1.50 μm or less, When the cementite particles having an aspect ratio of 3.0 or less are defined as spherical cementite particles, a spheroidization rate, which is the ratio of the total number of the spherical cementite particles to the total number of the cementite particles, is 75 to less than 85%. steel plate. [Effects of the Invention]

[0011] The steel sheet according to the present disclosure has excellent hardenability and excellent cold workability. DETAILED DESCRIPTION OF THE INVENTION

[0012] The present inventors have conducted research into steel sheets having excellent hardenability and excellent cold workability, and as a result, have made the following findings.

[0013] The present inventors first investigated a steel sheet having excellent hardenability and excellent cold workability from the viewpoint of chemical composition, and concluded that a chemical composition consisting of, in mass%, C: 0.50 to 0.90%, Si: 0.01 to 0.50%, Mn: 0.20 to 1.30%, P: 0.100% or less, S: 0.100% or less, Al: 0.100% or less, Cr: 0.01 to 1.20%, N: 0.0150% or less, Mo: 0 to 0.500%, Ni: 0 to 1.000%, B: 0 to 0.0100%, V: 0 to 0.500%, Nb: 0 to 0.500%, Ti: 0 to 0.150%, and the balance: Fe and impurities would enable both improved hardenability and improved cold workability. Therefore, the present inventors further investigated means for improving both hardenability and cold workability of a steel sheet having the above-mentioned chemical composition from the viewpoint of microstructure.

[0014] The present inventors first investigated means for improving the hardenability of the microstructure of a steel sheet. The microstructure of a steel sheet having the above-mentioned chemical composition is substantially composed of ferrite and cementite particles. In order to improve the hardenability of a steel sheet during quenching in a process for manufacturing a mechanical part using the steel sheet as a raw material, it is preferable that the cementite particles in the steel sheet are easily dissolved during quenching. In order to improve the solid solubility of the cementite particles during quenching, it is preferable that the particle size of the cementite particles is small. In the case of a steel sheet having the above-mentioned chemical composition, it is effective to make the average particle size of the cementite particles 1.50 μm or less.

[0015] Furthermore, as a result of investigations by the present inventors, it was found that the Mn concentration in cementite particles does not affect the solid solution of cementite particles during quenching. On the other hand, the present inventors found that the Cr and Mo concentrations in cementite particles significantly affect the solid solution of cementite particles during quenching. Specifically, if the Cr and Mo concentrations in cementite particles are high, the cementite particles are less likely to be solid-dissolved during quenching.

[0016] Based on the above findings, further investigation was carried out. As a result, the inventors found that the Cr concentration in cementite particles [Cr] θ is less than 2.00%, and the Mo concentration [Mo] θ It has been found that if the content of C is 1.00% or less, cementite particles are easily dissolved during quenching, and the hardenability of the steel sheet is improved.

[0017] The present inventors have further investigated means for improving the cold workability of the microstructure of a steel sheet. In order to improve the cold workability of a steel sheet, it is effective to increase the spheroidization rate of cementite particles and to increase the average grain size of ferrite. Therefore, in the steel sheet of this embodiment, the spheroidization rate of cementite particles is set to less than 75 to 85%, and the average grain size of ferrite is set to 5.0 μm or more. Note that the smaller the average grain size of ferrite, the larger the ferrite grain boundary area in the steel sheet. Therefore, due to grain boundary diffusion, the dissolution of cementite particles becomes faster during quenching. Therefore, the average grain size of ferrite is set to 20.0 μm or less.

[0018] The steel sheet according to this embodiment, which was completed based on the above findings, has the following configuration.

[0019] [1] A steel plate, The chemical composition is in mass%: C: 0.50~0.90%, Si: 0.01 to 0.50%, Mn: 0.20 to 1.30% P: 0.100% or less, S: 0.100% or less, Al: 0.100% or less, Cr: 0.01 to 1.20%, N: 0.0150% or less, Mo: 0 to 0.500%, Ni: 0 to 1.000%, B: 0~0.0100%, V: 0 to 0.500%, Nb: 0 to 0.500%, Ti: 0 to 0.150%, and The balance is composed of Fe and impurities. In the microstructure, the total area ratio of ferrite and cementite particles is 95% or more, The average particle size of the ferrite is 5.0 to 20.0 μm, Cr concentration in mass% in the cementite particles [Cr] θ is less than 2.00%, and the Mo concentration in mass% in the cementite particles [Mo] θ is 1.00% or less, The average particle size of the cementite particles is 1.50 μm or less, When the cementite particles having an aspect ratio of 3.0 or less are defined as spherical cementite particles, a spheroidization rate, which is the ratio of the total number of the spherical cementite particles to the total number of the cementite particles, is 75 to less than 85%. steel plate.

[0020] [2] [1] The steel plate according to The chemical composition is Mo: 0.001 to 0.500%, Ni: 0.001 to 1.000%, B: 0.0001~0.0100%, V: 0.001 to 0.500%, Nb: 0.001 to 0.500%, and Ti: 0.001 to 0.150%, Contains one or more elements selected from the group consisting of steel plate.

[0021] The steel sheet of this embodiment will be described in detail below. Note that "%" relating to elements means mass % unless otherwise specified.

[0022] [Features of the steel sheet according to this embodiment] The steel sheet of this embodiment satisfies the following features 1 to 6. (Feature 1) The chemical composition, in mass%, is C: 0.50-0.90%, Si: 0.01-0.50%, Mn: 0.20-1.30%, P: 0.100% or less, S: 0.100% or less, Al: 0.100% or less, Cr: 0.01-1.20%, N: 0.0150% or less, Mo: 0-0.500%, Ni: 0-1.000%, B: 0-0.0100%, V: 0-0.500%, Nb: 0-0.500%, Ti: 0-0.150%, and the balance: Fe and impurities. (Feature 2) In the microstructure, the total area ratio of ferrite and cementite particles is 95% or more. (Feature 3) The average grain size of ferrite is 5.0 to 20.0 μm. (Feature 4) Cr concentration in cementite particles by mass% [Cr] θ is less than 2.00%, and the Mo concentration in mass% in the cementite particles [Mo] θ is 1.00% or less. (Feature 5) The average particle size of cementite particles is 1.50 μm or less. (Feature 6) When cementite particles having an aspect ratio of 3.0 or less are defined as spherical cementite particles, the spheroidization rate, which is the ratio of the total number of spherical cementite particles to the total number of cementite particles, is 75 to less than 85%. Features 1 to 6 will be explained below.

[0023] [(Feature 1) Chemical composition] The chemical composition of the steel sheet of this embodiment contains the following elements.

[0024] C: 0.50 to 0.90% Carbon (C) improves the hardenability of steel sheet. As a result, when a mechanical component is manufactured using the steel sheet as a raw material and hardened, the mechanical component has increased strength. If the C content is less than 0.50%, the above effect cannot be sufficiently obtained even if the contents of other elements are within the ranges of this embodiment. On the other hand, if the C content exceeds 0.90%, the cold workability of the steel sheet will be reduced even if the contents of other elements are within the ranges of this embodiment. Therefore, the C content is 0.50 to 0.90%. The lower limit of the C content is preferably 0.52%, more preferably 0.55%, and even more preferably 0.60%. The upper limit of the C content is preferably 0.88%, more preferably 0.85%, and even more preferably 0.80%.

[0025] Si: 0.01 to 0.50% Silicon (Si) deoxidizes steel during the steelmaking process of steel sheet production. Furthermore, Si enhances the temper softening resistance of steel sheet when tempering is performed in a process for manufacturing machine parts using the steel sheet as a raw material. If the Si content is less than 0.01%, the above effects cannot be sufficiently obtained even if the contents of other elements are within the ranges of this embodiment. On the other hand, if the Si content exceeds 0.50%, the strength of the steel sheet becomes excessively high due to solid solution strengthening, and therefore the cold workability of the steel sheet deteriorates even if the contents of other elements are within the ranges of this embodiment. Therefore, the Si content is 0.01 to 0.50%. The lower limit of the Si content is preferably 0.02%, more preferably 0.05%, and even more preferably 0.10%. The upper limit of the Si content is preferably 0.48%, more preferably 0.44%, and even more preferably 0.40%.

[0026] Mn: 0.20 to 1.30% Manganese (Mn) improves the hardenability of steel sheets. As a result, when a mechanical component is manufactured using the steel sheet as a raw material and hardened, the mechanical component has increased strength. If the Mn content is less than 0.20%, the above effect cannot be sufficiently obtained even if the contents of other elements are within the ranges of this embodiment. On the other hand, if the Mn content exceeds 1.30%, the strength of the steel sheet becomes excessively high due to solid solution strengthening, and therefore the cold workability of the steel sheet deteriorates even if the contents of other elements are within the ranges of this embodiment. Therefore, the Mn content is 0.20 to 1.30%. The lower limit of the Mn content is preferably 0.25%, more preferably 0.30%, and even more preferably 0.35%. The upper limit of the Mn content is preferably 1.25%, more preferably 1.20%, and even more preferably 1.15%.

[0027] P:0.100% or less Phosphorus (P) is an impurity. If the P content exceeds 0.100%, the toughness of the steel sheet will decrease even if the contents of other elements are within the ranges of this embodiment. Therefore, the P content is 0.100% or less. The P content is preferably as low as possible. However, an extreme reduction in the P content significantly increases production costs. Therefore, in consideration of industrial production, the lower limit of the P content is preferably more than 0%, more preferably 0.001%, even more preferably 0.003%, and even more preferably 0.005%. The upper limit of the P content is preferably 0.090%, more preferably 0.080%, and even more preferably 0.050%.

[0028] S: 0.100% or less Sulfur (S) is an impurity. If the S content exceeds 0.100%, S forms excessively large amounts of sulfides. Therefore, even if the contents of other elements are within the ranges of this embodiment, the cold workability of the steel sheet is reduced. Therefore, the S content is 0.100% or less. The S content is preferably as low as possible. However, an extreme reduction in the S content significantly increases production costs. Therefore, in consideration of industrial production, the lower limit of the S content is preferably more than 0%, more preferably 0.001%, even more preferably 0.003%, and even more preferably 0.005%. The upper limit of the S content is preferably 0.090%, more preferably 0.080%, and even more preferably 0.050%.

[0029] Al: 0.100% or less Aluminum (Al) is an impurity. Al combines with N to form AlN. AlN refines austenite grains during heating in the quenching process in the process of manufacturing mechanical parts using steel sheet as a raw material. Refinement of austenite grains reduces the hardenability of the steel sheet. Therefore, if the Al content exceeds 0.100%, austenite grains are excessively refined during heating in the quenching process even if the contents of other elements are within the ranges of this embodiment. As a result, the hardenability of the steel sheet is significantly reduced. Therefore, the Al content is 0.100% or less. The Al content is preferably as low as possible. However, an extreme reduction in the Al content significantly increases production costs. Therefore, in consideration of industrial production, the lower limit of the Al content is preferably more than 0%, more preferably 0.001%, even more preferably 0.005%, and even more preferably 0.010%. The upper limit of the Al content is preferably 0.090%, more preferably 0.080%, even more preferably 0.070%, and still more preferably 0.050%. In the chemical composition of the steel sheet of this embodiment, the Al content means the acid-soluble Al (sol. Al) content.

[0030] Cr: 0.01 to 1.20% Chromium (Cr) improves the hardenability of steel sheets. As a result, when a mechanical part is manufactured using the steel sheet as a raw material and hardened, the mechanical part is strengthened. If the Cr content is less than 0.01%, the above effect cannot be sufficiently obtained even if the contents of other elements are within the ranges of this embodiment. On the other hand, if the Cr content exceeds 1.20%, the Cr concentration in the cementite grains [Cr] θ As a result, cementite particles do not dissolve sufficiently during heating in the quenching process in the manufacturing process of mechanical parts using the steel sheet as a raw material. In this case, the hardenability of the steel sheet is actually reduced. As a result, mechanical parts manufactured using the steel sheet as a raw material do not have sufficient strength. Therefore, the Cr content is 0.01 to 1.20%. The lower limit of the Cr content is preferably 0.02%, more preferably 0.03%, and even more preferably 0.05%. The upper limit of the Cr content is preferably 1.15%, more preferably 1.10%, even more preferably 1.00%, even more preferably 0.70%, and even more preferably 0.50%.

[0031] N: 0.0150% or less Nitrogen (N) is an impurity. N combines with Al to form AlN. AlN refines austenite grains during heating in the quenching process in the manufacturing process of mechanical components using steel sheet as a raw material. Refinement of austenite grains reduces the hardenability of the steel sheet. Therefore, if the N content exceeds 0.0150%, austenite grains are excessively refined during heating in the quenching process even if the contents of other elements are within the ranges of this embodiment. As a result, the hardenability of the steel sheet is significantly reduced. Therefore, the N content is 0.0150% or less. The N content is preferably as low as possible. However, an extreme reduction in the N content significantly increases production costs. Therefore, in consideration of industrial production, the lower limit of the N content is preferably more than 0%, more preferably 0.0001%, even more preferably 0.0005%, even more preferably 0.0010%, even more preferably 0.0015%, and even more preferably 0.0018%. The upper limit of the N content is preferably 0.0140%, more preferably 0.0130%, even more preferably 0.0120%, and still more preferably 0.0100%.

[0032] The balance of the chemical composition of the steel sheet according to this embodiment is Fe and impurities. Here, the impurities in the chemical composition refer to substances that are mixed in from raw materials such as ore and scrap, or the manufacturing environment, during industrial production of the steel sheet, and are acceptable within a range that does not adversely affect the steel sheet according to this embodiment.

[0033] The impurities may include the following elements in the amounts listed below. Cu:0~0.15%, W:0~0.15%, Ta:0~0.15%, Sn:0~0.050%, Sb:0~0.050%, Co:0~0.050%, As:0~0. 050%, Mg: 0~0.050%, Y: 0~0.050%, Zr: 0~0.050%, La: 0~0.050%, Ce: 0~0.050%, Ca: 0~0.050%.

[0034] [Optional Elements] The chemical composition of the steel sheet of this embodiment further includes: Mo: 0 to 0.500%, Ni: 0 to 1.000%, B: 0~0.0100%, V: 0 to 0.500%, Nb: 0 to 0.500%, and Ti: 0 to 0.150% It may contain one or more elements selected from the group consisting of: These optional elements will be explained below.

[0035] [Group 1: Mo, Ni and B] The chemical composition of the steel sheet according to this embodiment may further contain, in place of a portion of Fe, one or more elements selected from the group consisting of Mo, Ni, and B. These elements are all optional elements and may not be contained. When contained, Mo, Ni, and B improve the hardenability of the steel sheet.

[0036] Mo: 0 to 0.500% Molybdenum (Mo) is an optional element and may not be contained, that is, the Mo content may be 0%. When Mo is contained, that is, when the Mo content is more than 0%, Mo improves the hardenability of the steel sheet. As a result, when quenching is performed in a process for manufacturing a mechanical part using the steel sheet as a raw material, the strength of the mechanical part is increased. Furthermore, when tempering is performed in a process for manufacturing a mechanical part using the steel sheet as a raw material, Mo improves the temper softening resistance of the steel sheet. Even if even a small amount of Mo is contained, the above effects can be obtained to some extent. However, if the Mo content exceeds 0.500%, the Mo concentration in the cementite grains [Mo] θ As a result, cementite particles do not dissolve sufficiently during heating in the quenching process in the manufacturing process of mechanical parts using the steel sheet as a raw material. In this case, the hardenability of the steel sheet is actually reduced. As a result, mechanical parts manufactured using the steel sheet as a raw material do not have sufficient strength. Therefore, the Mo content is 0 to 0.500%. The lower limit of the Mo content is preferably 0.001%, more preferably 0.003%, even more preferably 0.005%, even more preferably 0.010%, even more preferably 0.015%, even more preferably 0.020%, and even more preferably 0.025%. The upper limit of the Mo content is preferably 0.450%, more preferably 0.400%, even more preferably 0.350%, and still more preferably 0.300%.

[0037] Ni: 0 to 1.000% Nickel (Ni) is an optional element and may not be contained, that is, the Ni content may be 0%. When Ni is contained, that is, when the Ni content is more than 0%, Ni improves the hardenability of the steel sheet. As a result, when hardening is performed in a process for manufacturing a mechanical part using the steel sheet as a raw material, the strength of the mechanical part is increased. Furthermore, when tempering is performed in a process for manufacturing a mechanical part using the steel sheet as a raw material, Ni improves the temper softening resistance of the steel sheet. Even if even a small amount of Ni is contained, the above effects can be obtained to some extent. However, if the Ni content exceeds 1.000%, the strength of the steel sheet becomes excessively high even if the contents of other elements are within the ranges of this embodiment, and therefore the cold workability of the steel sheet deteriorates. Therefore, the Ni content is 0 to 1.000%. The lower limit of the Ni content is preferably 0.001%, more preferably 0.005%, even more preferably 0.007%, even more preferably 0.010%, even more preferably 0.050%, even more preferably 0.080%, and even more preferably 0.100%. The upper limit of the Ni content is preferably 0.950%, more preferably 0.900%, even more preferably 0.800%, even more preferably 0.700%, and even more preferably 0.600%.

[0038] B: 0 to 0.0100% Boron (B) is an optional element and may not be contained, that is, the B content may be 0%. When B is contained, that is, when the B content is more than 0%, B improves the hardenability of the steel sheet. As a result, when hardening is performed in a process for manufacturing a mechanical part using the steel sheet as a raw material, the strength of the mechanical part is increased. Even if even a small amount of B is contained, the above effect can be obtained to some extent. However, if the B content exceeds 0.0100%, even if the contents of other elements are within the ranges of this embodiment, B compounds are formed. In this case, the effect of improving hardenability cannot be sufficiently obtained. Furthermore, the cold workability of the steel sheet is deteriorated. Therefore, the B content is 0 to 0.0100%. The lower limit of the B content is preferably 0.0001%, more preferably 0.0003%, and even more preferably 0.0005%. The upper limit of the B content is preferably 0.0090%, more preferably 0.0080%, even more preferably 0.0070%, even more preferably 0.0060%, and even more preferably 0.0050%.

[0039] [Group 2: V, Nb, and Ti] The chemical composition of the steel sheet according to this embodiment may further contain, in place of a portion of Fe, one or more elements selected from the group consisting of V, Nb, and Ti. All of these elements are optional and may not be contained. When contained, V, Nb, and Ti form carbides. These carbides suppress the coarsening of austenite grains during heating in the quenching process in the process of manufacturing mechanical components using the steel sheet as a raw material. This improves the toughness of the mechanical components.

[0040] V: 0 to 0.500% Vanadium (V) is an optional element and may not be contained, that is, the V content may be 0%. When V is contained, that is, when the V content is more than 0%, V forms carbides and suppresses the coarsening of austenite grains during heating in the quenching process in the process of manufacturing mechanical parts using the steel plate as a raw material. As a result, the toughness of the mechanical parts is improved. Even if even a small amount of V is contained, the above effect can be obtained to some extent. However, if the V content exceeds 0.500%, V forms excessive carbides to precipitation strengthen the steel sheet, and therefore the cold workability of the steel sheet deteriorates even if the contents of other elements are within the ranges of this embodiment. Therefore, the V content is 0 to 0.500%. The lower limit of the V content is preferably 0.001%, more preferably 0.003%, and even more preferably 0.005%. The upper limit of the V content is preferably 0.480%, more preferably 0.450%, and even more preferably 0.400%.

[0041] Nb: 0 to 0.500% Niobium (Nb) is an optional element and may not be contained, that is, the Nb content may be 0%. When Nb is contained, that is, when the Nb content is more than 0%, Nb forms carbides and suppresses the coarsening of austenite grains during heating in the quenching process in the process of manufacturing mechanical parts using steel sheet as a raw material. This improves the toughness of the mechanical parts. Nb also bonds with N and suppresses the formation of nitrides by solute B. This improves the hardenability of the steel sheet due to solute B. Even if even a small amount of Nb is contained, the above effects can be obtained to some extent. However, if the Nb content exceeds 0.500%, Nb forms excessive carbides and precipitation strengthens the steel sheet, which reduces the cold workability of the steel sheet even if the contents of other elements are within the ranges of this embodiment. Therefore, the Nb content is 0 to 0.500%. The lower limit of the Nb content is preferably 0.001%, more preferably 0.003%, and even more preferably 0.005%. The upper limit of the Nb content is preferably 0.480%, more preferably 0.450%, even more preferably 0.400%, even more preferably 0.350%, and even more preferably 0.300%.

[0042] Ti: 0 to 0.150% Titanium (Ti) is an optional element and may not be contained, that is, the Ti content may be 0%. When Ti is contained, that is, when the Ti content is more than 0%, Ti forms carbides and suppresses the coarsening of austenite grains during heating in the quenching process in the manufacturing process of mechanical parts using steel sheet as a raw material. This improves the toughness of the mechanical parts. Ti also bonds with N and suppresses the formation of nitrides by solute B. This improves the hardenability of the steel sheet due to the solute B. Even if even a small amount of Ti is contained, the above effects can be obtained to some extent. However, if the Ti content exceeds 0.150%, Ti forms excessive carbides and precipitation strengthens the steel sheet, which reduces the cold workability of the steel sheet even if the contents of other elements are within the ranges of this embodiment. Therefore, the Ti content is 0 to 0.150%. The lower limit of the Ti content is preferably 0.001%, more preferably 0.003%, and even more preferably 0.005%. The upper limit of the Ti content is preferably 0.145%, more preferably 0.130%, even more preferably 0.120%, even more preferably 0.100%, and still more preferably 0.080%.

[0043] [(Feature 2) Microstructure] In the microstructure of the steel sheet of this embodiment, the total area ratio of ferrite and cementite particles is 95% or more, that is, the microstructure of the steel sheet of this embodiment is substantially composed of ferrite and cementite particles.

[0044] In the microstructure, the structure other than ferrite and cementite particles is, for example, one or more types selected from the group consisting of precipitates other than cementite particles, inclusions, bainite, martensite, and pearlite.

[0045] Preferably, the total area ratio of ferrite and cementite particles in the microstructure is 96% or more, more preferably 97% or more, even more preferably 98% or more, and even more preferably 99% or more. The microstructure may be a structure consisting of ferrite and cementite particles.

[0046] If the total area ratio of ferrite and cementite particles is 95% or more, sufficient hardenability and sufficient cold workability can be obtained, provided that Feature 1 and Features 3 to 6 are satisfied.

[0047] [Method for measuring the total area ratio of ferrite and cementite particles in a microstructure] The total area ratio of ferrite and cementite particles in the microstructure can be measured by the following method. A test piece measuring 15 mm in the rolling direction (L direction) of the steel plate, 10 mm in the width direction, and plate thickness is taken from the center of the steel plate width. Here, the rolling direction can be identified by observing the roll marks formed on the surface of the steel plate. Roll marks are thin lines formed on the surface of the steel plate along the direction of the rolling rolls when rolling is performed. In this case, the direction in which the roll marks extend is identified as the rolling direction.

[0048] The cross section of the test piece surface parallel to the rolling direction (the surface of 15 mm x plate thickness in the rolling direction) is defined as the observation surface. The observation surface of the test piece is mirror-polished. The mirror-polished observation surface is etched using 3% nitric acid alcohol (nital etchant). Secondary electron images of five randomly selected observation fields on the etched observation surface are observed using a scanning electron microscope (SEM) at 1000x magnification. Each observation field is a rectangle of 100 μm x 120 μm.

[0049] In the observation field, ferrite and cementite particles exhibit contrast and morphology that differ from other structures (bainite, martensite, pearlite, precipitates other than cementite particles, inclusions, etc.). Specifically, when the observation surface is etched with a nital etching solution, areas with high granular brightness can be identified as cementite particles. Areas with lamellar structures can be identified as pearlite. Areas with a brightness lower than pearlite and where no substructure is observed can be identified as ferrite. Areas with a brightness higher than ferrite and lower than pearlite and where a substructure is observed can be identified as bainite and martensite. Therefore, ferrite and cementite particles can be identified within the observation field based on contrast and morphology.

[0050] The total area ratio (%) of ferrite and cementite particles is calculated based on the total area of ​​ferrite and the total area of ​​cementite particles in the five observation fields and the total area of ​​the five observation fields.

[0051] [(Feature 3) Average grain size of ferrite] Furthermore, in the steel sheet of this embodiment, the average grain size of ferrite is 5.0 to 20.0 μm. If the average grain size of ferrite is less than 5.0 μm, the cold workability of the steel sheet is reduced. On the other hand, if the average grain size of ferrite is more than 20.0 μm, the grain boundary area is reduced, and the effect of promoting the dissolution of cementite particles by grain boundary diffusion cannot be obtained. In this case, sufficient hardenability cannot be obtained in the hardening process when manufacturing mechanical parts using the steel sheet as a raw material. As a result, the strength of the mechanical parts manufactured using the steel sheet as a raw material is reduced. Therefore, the average grain size of ferrite is 5.0 to 20.0 μm.

[0052] The lower limit of the average grain size of ferrite is preferably 5.2 μm, more preferably 5.5 μm, even more preferably 5.7 μm, even more preferably 6.0 μm, and even more preferably 6.5 μm. The upper limit of the average grain size of ferrite is preferably 19.5 μm, more preferably 19.0 μm, even more preferably 18.5 μm, and even more preferably 18.0 μm.

[0053] [Method for measuring the average grain size of ferrite] The average grain size of ferrite can be measured by the following method. A test piece measuring 15 mm in the rolling direction of the steel plate, 10 mm in the width direction, and thickness is taken from the center of the steel plate width. The cross section of the test piece surface parallel to the rolling direction (15 mm in the rolling direction × thickness surface) is defined as the observation surface. The observation surface of the test piece is mirror-polished. The mirror-polished observation surface is etched using a 5% nital etching solution. The average ferrite grain size of the etched observation surface is determined using the following method. The ferrite grain size number is determined by the intercept method in accordance with JIS G 0551:2020. The magnification of the optical microscope is selected so that the number of ferrite grains cut by a single line is at least 10 in one field of view. After selecting the magnification, the cut lengths are determined for five fields of view. The ferrite grain size number is calculated from the arithmetic mean of the cut lengths of the five fields of view. The average ferrite grain size number (μm) is calculated from the obtained grain size number.

[0054] (Feature 4) Cr concentration in cementite particles [Cr] θ and Mo concentration [Mo] θ About In the steel sheet of this embodiment, the Cr concentration [Cr] in mass% in cementite particles θ is less than 2.00%, and the Mo concentration in mass% in the cementite particles [Mo] θ is 1.00% or less.

[0055] Cr concentration in cementite particles of steel plate [Cr] θ and Mo concentration [Mo] θIf the hardness is too high, cementite particles do not dissolve sufficiently during heating in the quenching step in the process of manufacturing mechanical parts using the steel sheet as a raw material. In this case, the hardenability of the steel sheet is reduced. As a result, mechanical parts manufactured using the steel sheet as a raw material do not have sufficient strength.

[0056] Cr concentration in cementite particles of steel plate [Cr] θ is less than 2.00%, and the Mo concentration in the cementite grains [Mo] θ When is 1.00% or less, the Cr concentration in the cementite grains [Cr] θ and Mo concentration [Mo] θ Therefore, during heating in the above-mentioned quenching step, cementite particles are sufficiently dissolved, and the hardenability of the steel sheet is improved.

[0057] Cr concentration in cementite particles [Cr] θ The upper limit of the content of Cr is preferably 1.90%, more preferably 1.80%, and even more preferably 1.70%. Mo concentration in cementite particles [Mo] θ The upper limit of the Si content is preferably 0.90%, more preferably 0.80%, and even more preferably 0.70%.

[0058] Cr concentration in cementite particles [Cr] θ The lower limit of Cr concentration [Cr] is not particularly limited. θ The most preferable lower limit of is 0%, but there may be cases where 0.01% or more, or 0.10% or more remains. Mo concentration in cementite particles [Mo] θ There is no particular lower limit for Mo concentration [Mo]. θ The most preferable lower limit of is 0%, but there may be cases where 0.01% or more, or 0.03% or more remains.

[0059] [Cr concentration in cementite particles [Cr] θ and Mo concentration [Mo] θ Measurement method] Cr concentration in cementite particles [Cr] θand Mo concentration [Mo] θ can be measured in the following way: A test piece measuring 10 mm x 10 mm x plate thickness is taken from the center of the steel plate width.

[0060] The test piece is subjected to constant current electrolysis using a 10% AA-based solution (a solution containing 10% by volume of acetylacetone and a methanol solution containing 1% by mass of tetramethylammonium chloride).

[0061] Specifically, the above-mentioned 10% AA-based solution is prepared. Then, using the 10% AA-based solution, a current density of 20 mA / cm is applied at room temperature. 2 The test piece is held at this temperature and subjected to constant current electrolysis. After constant current electrolysis, the test piece is removed from the 10% AA solution. The removed test piece is immersed in an alcohol solution. The test piece immersed in the alcohol solution is subjected to ultrasonic cleaning.

[0062] The 10% AA solution used in the constant current electrolysis and the alcohol solution used in the subsequent ultrasonic cleaning are suction filtered through a filter with a mesh size of 0.2 μm to extract the residue.

[0063] The extracted residue is subjected to chemical elemental analysis. Specifically, the residue is dissolved in acid to obtain a solution. The solution is subjected to chemical elemental analysis using inductively coupled plasma optical emission spectroscopy (ICP-OES) to obtain the Cr mass and Mo mass in the residue. Based on the obtained Cr mass, Mo mass, and total mass of the residue, the Cr concentration (mass%) and Mo concentration (mass%) in the residue are calculated.

[0064] The obtained residue is substantially composed of cementite particles. In other words, the amount of particles other than cementite particles (inclusions and other precipitates other than cementite particles) in the residue is negligibly small. Therefore, the Cr and Mo concentrations in the residue are calculated as the Cr concentration in the cementite particles [Cr] θ and Mo concentration [Mo] θ It is considered to be.

[0065] [(Feature 5) Average particle size of cementite particles] In the steel sheet of this embodiment, the average particle size of the cementite particles is 1.50 μm or less. As described above, if the cementite particles are large, they will not dissolve sufficiently during heating in the quenching step in the process of manufacturing mechanical components using the steel sheet as a raw material. In this case, the hardenability of the steel sheet will be reduced. As a result, mechanical components manufactured using the steel sheet as a raw material will not have sufficient strength.

[0066] If the average particle size of the cementite particles is 1.50 μm or less, the cementite particles are sufficiently small, and therefore, when heated in the above-mentioned quenching step, the cementite particles dissolve sufficiently, improving the hardenability of the steel sheet.

[0067] The upper limit of the average particle size of the cementite particles is preferably 1.45 μm, more preferably 1.40 μm, even more preferably 1.35 μm, and still more preferably 1.30 μm. To improve hardenability, a smaller average particle size of cementite particles is preferable. However, if the average particle size of cementite particles is too small, the hardness of the steel sheet becomes too high. In this case, the cold workability of the steel sheet deteriorates. Therefore, the lower limit of the average particle size of cementite particles is preferably 0.05 μm, more preferably 0.10 μm, even more preferably 0.15 μm, and even more preferably 0.20 μm.

[0068] [Method for measuring the average particle size of cementite particles] The average particle size of the cementite particles can be determined by the following method. A test piece measuring 15 mm in the rolling direction of the steel plate, 10 mm in the width direction, and thickness is taken from the center of the steel plate. The cross section of the surface of the test piece parallel to the rolling direction (the surface of 15 mm in the rolling direction and thickness) is defined as the observation surface.

[0069] The observation surface is etched using picral solution. Secondary electron images are taken at five arbitrary observation fields located at a depth of 1 / 4 of the plate thickness from the surface of the etched observation surface. Specifically, a scanning electron microscope (SEM) is used to observe the five observation fields at a magnification of 2000x, and the above-mentioned secondary electron images are taken. Each observation field is a rectangle of 50 μm x 60 μm.

[0070] In each secondary electron image, cementite particles are identified based on the contrast. The area of ​​each identified cementite particle is calculated, and the circle-equivalent diameter of each cementite particle is calculated based on the area. The calculated circle-equivalent diameter is used as the particle diameter of the cementite particle. The particle diameter is calculated using well-known image processing software. The arithmetic mean value of the particle diameters of the cementite particles obtained in the five observation fields is defined as the average particle diameter (μm) of the cementite particles.

[0071] [(Feature 6) Spheroidization rate] In the steel sheet of this embodiment, among the plurality of cementite particles, cementite particles having an aspect ratio of 3.0 or less are defined as spherical cementite particles, and the spheroidization ratio, which is the ratio of the total number of spherical cementite particles to the total number of the plurality of cementite particles, is 75 to less than 85%.

[0072] If the spheroidization rate is less than 75%, sufficient cold workability cannot be obtained in the steel sheet even if Features 1 to 5 are satisfied. Therefore, the spheroidization rate is 75% or more.

[0073] A higher spheroidization rate is preferable. However, if the spheroidization rate is excessively high, the solubility of cementite during quenching decreases. The dissolution of cementite proceeds through the solid solution and diffusion of elements from the interface between the cementite and the matrix. Therefore, the more spherical the cementite is, the smaller the interface area between the cementite and the matrix becomes. In this case, the solubility of cementite decreases. Therefore, the upper limit of the spheroidization rate is preferably less than 85%, more preferably 84%, and even more preferably 83%.

[0074] [Method for measuring spheroidization rate] The spheroidization rate can be measured by the following method. The aspect ratio is determined for each of the multiple cementite particles identified in the five observation fields using the above-mentioned [Method for Measuring the Average Particle Diameter of Cementite Particles]. Specifically, the maximum distance obtained when the outline of the cementite particle is sandwiched between two parallel line segments is defined as the major axis. Furthermore, the distance between the two line segments when the outline of the cementite particle is sandwiched between two line segments parallel to the major axis (i.e., the width in the direction perpendicular to the major axis) is defined as the minor axis.

[0075] The aspect ratio (= major axis / minor axis) of each cementite particle is calculated based on the obtained major axis and minor axis. Of all cementite particles in the five observation fields, cementite particles with an aspect ratio of 3.0 or less are identified as "spheroidal cementite particles." The ratio of the total number of spherical cementite particles to the total number of multiple cementite particles is defined as the spheroidization rate (%).

[0076] [Effects of the steel sheet according to this embodiment] The steel sheet of this embodiment, which satisfies the above-mentioned Features 1 to 6, exhibits sufficient hardenability during quenching in the process of manufacturing mechanical components using the steel sheet as a raw material. Furthermore, the steel sheet of this embodiment exhibits sufficient cold workability.

[0077] [About hardenability] In the steel sheet of this embodiment, the fact that sufficient hardenability is obtained means the following evaluation.

[0078] [Hardenability evaluation method] (A c1 transformation point measurement) A test piece is taken from the center of the sheet width of the steel sheet of this embodiment. The thermal expansion coefficient during heating is measured using a Formaster testing machine. From the obtained thermal expansion coefficient, A c1 Find the transformation point.

[0079] (Maximum hardness measurement) A plate-shaped test piece is taken from the center of the steel plate width, measuring 15 mm in the rolling direction (L direction) of the steel plate, 30 mm in the plate width direction (W direction), and the plate thickness. The plate test specimen is heated to 1000°C for 20 minutes in a salt bath. The plate test specimen is then removed from the salt bath and immersed in water in a water tank for quenching. After quenching, the plate test specimen is cut into two equal parts in the W direction. The cut surfaces are mirror-polished. Vickers hardness tests in accordance with JIS Z2244:2009 are performed at three arbitrary points in the center of the plate thickness direction (T direction) of the polished cut surfaces. The test force is 98N. The arithmetic mean of the obtained Vickers hardness values ​​is defined as the maximum quenched hardness HD0 (HV).

[0080] (Hardenability evaluation) A plate-shaped test piece is taken from the center of the steel plate width, measuring 15 mm in the rolling direction (L direction) of the steel plate, 30 mm in the plate width direction (W direction), and the plate thickness. The plate-shaped test piece was heated by electrical current at 400°C / sec. c1 The specimen is heated to +150°C. After heating, the plate-shaped test piece is immersed in water in a water tank and quenched. After quenching, the plate-shaped test piece is cut into two equal parts in the W direction. The cut surfaces are mirror-polished. Vickers hardness tests are performed in accordance with JIS Z2244:2009 at three arbitrary points in the center of the plate thickness direction (T direction) of the polished cut surfaces. The test force is 98N. The arithmetic mean value of the obtained Vickers hardness is defined as the quenched hardness HD1 (HV). When the obtained hardness HD1 is 95% or more of the maximum hardness HD0, the steel plate is determined to have sufficient hardenability.

[0081] [Cold workability] In the steel sheet of this embodiment, the cold workability can be evaluated, for example, by the following method.

[0082] [Cold workability evaluation method] A JIS No. 5 plate test piece, as specified in JIS Z2241:2011, is taken from the center of the steel plate width. A V-notch is formed in the longitudinal center of the parallel part of the plate test piece so that the depth direction of the V-notch is parallel to the width direction of the parallel part. The V-notch opening angle is 45° and the V-notch depth is 2 mm. The gauge length, including the V-notch, is 10 mm. The longitudinal direction of the plate test piece is the rolling direction (L direction) of the steel plate.

[0083] A fracture elongation test is carried out using a plate-shaped test piece at room temperature in the atmosphere. The butt elongation after fracture is measured, and the obtained butt elongation (%) is defined as the notch elongation (%). The steel plate of this embodiment has a larger notch elongation than a steel plate that does not satisfy any of Features 1 to 6. For example, when the plate-shaped test piece has a thickness of 2 mm, the steel plate of this embodiment has a notch elongation of 3.0% or more, and is −33 × C content (%) of the steel plate + 30.0% or more.

[0084] [Steel plate applications] The steel sheet of this embodiment is suitable as a material for mechanical parts, such as automobile parts. Examples of mechanical parts include automobile springs and washers. The steel sheet of this embodiment may also be used for applications other than mechanical parts that require excellent hardenability and excellent cold workability.

[0085] [Steel plate manufacturing method] An example of a method for manufacturing the steel sheet of this embodiment will be described. The method for manufacturing the steel sheet described below is one example for manufacturing the steel sheet of this embodiment. Therefore, the steel sheet having the above-described configuration may be manufactured by a manufacturing method other than the manufacturing method described below. However, the manufacturing method described below is a preferred example of the method for manufacturing the steel sheet of this embodiment.

[0086] An example of the method for manufacturing the steel sheet according to this embodiment includes the following steps. (Process 1) Material preparation process (Process 2) Hot rolling process (Process 3) Cold rolling process (Process 4) Cold-rolled sheet annealing process In this embodiment, the annealing step is not performed after the hot rolling step and before the cold rolling step.

[0087] The main production conditions in the above steps 1 to 4 are as follows. (Condition 1) Coiling temperature CT in process 2: 400 to 650°C (Condition 2) Cold rolling rate CR in process 3: over 15 to 35% (Condition 3) Annealing temperature T1 in step 4: 600 to 720°C (Condition 4) Holding time t1 in step 4: more than 16 to 50 hours

[0088] Each step will be described below.

[0089] [(Process 1) Material preparation process] In the material preparation step, a material satisfying Feature 1 is prepared. The material is produced, for example, by the following method. Molten steel is produced, the content of each element in the chemical composition of which falls within the range of this embodiment. The molten steel is used to produce a material (slab or ingot) by a casting method. For example, the molten steel is used to produce a slab by a well-known continuous casting method. Alternatively, the molten steel is used to produce an ingot by a well-known ingot-making method.

[0090] [(Process 2) Hot rolling process] In the hot rolling process, hot rolling is performed on a prepared material (slab or ingot) to produce a hot-rolled steel sheet. The hot rolling process includes a rough rolling process in which the material is rough-rolled to produce a rough bar (intermediate steel sheet), and a finish rolling process in which the rough bar is finish-rolled to produce a hot-rolled steel sheet.

[0091] In the rough rolling step, a material (slab or ingot) is heated in a heating furnace. The heated material is rolled using a rough rolling mill to produce a rough bar. The heating temperature of the material in the rough rolling step is, for example, 1100 to 1300°C. The time the material is left in the heating furnace is 30 minutes or more, preferably 60 minutes or more. The upper limit of the time is not particularly limited, but is, for example, 300 minutes.

[0092] In the finish rolling process, the rough bar is further rolled (finish rolling) using a finish rolling mill to produce a hot-rolled steel sheet. The finish rolling mill includes a plurality of stands arranged in a row. Each stand is equipped with a pair of work rolls. The surface temperature of the steel sheet at the outlet of the stand that lastly reduces the steel sheet among the plurality of stands in the finish rolling mill is defined as the finish rolling temperature (°C). In this embodiment, the finish rolling temperature is 830 to 950°C. Furthermore, the reduction rate of the last stand that reduces the steel sheet among the plurality of stands arranged in a row in the finish rolling mill is defined as the final pass reduction rate (%). In this embodiment, the final pass reduction rate is 5 to 30%. The hot-rolled steel sheet after finish rolling is wound up into a coil. The coiling temperature CT will be described later. The coiled hot-rolled steel sheet is cooled to room temperature.

[0093] [(Process 3) Cold rolling process] In the cold rolling process, cold rolling is performed on the hot-rolled steel sheet after the hot rolling process. The cold rolling is performed using a cold rolling mill. The cold rolling mill is, for example, a reverse rolling mill consisting of one rolling stand, and the rolling stand includes a pair of work rolls.

[0094] In the cold rolling process, cold rolling is performed using the above-mentioned reverse rolling mill to produce a cold-rolled steel sheet. The cold rolling reduction ratio CR in the cold rolling process will be described later.

[0095] In this embodiment, the hot-rolled steel sheet after the hot-rolling process is subjected to the cold-rolling process without being subjected to an annealing treatment. In other words, the hot-rolled sheet annealing process is not performed after the hot-rolling process but before the cold-rolling process. In this manufacturing method, strain is accumulated in the steel sheet during the hot-rolling process and the cold-rolling process, and the annealing process is performed after the cold-rolling process. As a result, ferrite grains of an appropriate size, cementite grains of an appropriate size, and a Cr concentration [Cr] in the cementite grains are obtained. θ and Mo concentration [Mo] θ The following is obtained.

[0096] [(Process 4) Cold-rolled sheet annealing process] In the cold-rolled sheet annealing process, the cold-rolled steel sheet after the cold rolling process is annealed. In the annealing process, the annealing temperature T1 and the holding time t1 at the annealing temperature T1 are adjusted to adjust the degree of ferrite recrystallization and cementite particle precipitation.

[0097] [Conditions 1 to 4] In the above-described steps 1 to 4, the following conditions 1 to 4 are satisfied. (Condition 1) Coiling temperature CT in process 2: 400 to 650°C (Condition 2) Cold rolling rate CR in process 3: over 15 to 35% (Condition 3) Annealing temperature T1 in step 4: 600 to 720°C (Condition 4) Holding time t1 in step 4: more than 16 to 50 hours Each condition will be explained below.

[0098] [(Condition 1) Coiling temperature CT] In the hot rolling process, the coiling temperature CT affects the spheroidization rate of cementite particles and the Cr concentration in the cementite particles [Cr]. θ , Mo concentration [Mo] θ If the coiling temperature CT is 650°C or less, the cementite particles formed in the hot-rolled steel sheet are distributed sufficiently uniformly. Furthermore, the strain imparted by the hot-rolled steel sheet is properly maintained. In this case, the spheroidization rate of the cementite particles is increased by performing an annealing process after the cold rolling process. Furthermore, the concentration of Cr and Mo in the formed cementite particles can be suppressed, and the Cr concentration [Cr] in the cementite particles can be reduced. θ is less than 2.00%, and the Mo concentration [Mo] θ Therefore, the coiling temperature CT is preferably set to 650°C or less.

[0099] On the other hand, there is no particular limitation on the lower limit of the coiling temperature CT, but due to equipment restrictions, the lower limit of the coiling temperature CT is preferably 400°C.

[0100] If the coiling temperature CT is 400 to 650°C, a steel sheet satisfying Features 1 to 6 can be produced, provided that other conditions are met.

[0101] [(Condition 2) Cold rolling rate CR] In the cold rolling process, the cold reduction ratio CR is defined by the following formula: Cold rolling ratio CR (%) = (1 - (thickness of cold-rolled steel sheet after cold rolling process / thickness of hot-rolled steel sheet before cold rolling process)) × 100

[0102] If the cold rolling rate CR is 15% or less, the strain introduced into the steel sheet is insufficient. In this case, the spheroidization of cementite particles is not sufficiently promoted in the subsequent annealing process, resulting in a spheroidization rate of less than 75%. On the other hand, if the cold rolling rate CR exceeds 35%, the spheroidization rate will be 85% or more.

[0103] If the cold rolling rate CR is more than 15% and less than 35%, the spheroidization rate will be 75% to less than 85%, and a steel sheet satisfying Features 1 to 6 can be manufactured, provided that other conditions are met.

[0104] [(Condition 3) Annealing temperature T1] In the cold-rolled sheet annealing process, the annealing temperature T1 adjusts the spheroidization rate of cementite particles in the steel sheet. If the annealing temperature T1 is less than 600°C, the spheroidization of cementite particles will be insufficient, and the spheroidization rate of cementite particles will be less than 75%.

[0105] On the other hand, if the annealing temperature T1 exceeds 720°C, the annealing temperature is too high. In this case, the spheroidization of cementite becomes insufficient, and the spheroidization rate of cementite particles becomes less than 75%. In this case, other structures such as pearlite other than ferrite and cementite particles are excessively precipitated, and the total area ratio of ferrite and cementite particles decreases.

[0106] If the annealing temperature T1 is 600 to 720°C, a steel sheet satisfying Features 1 to 6 can be produced, provided that other conditions are met.

[0107] [(Condition 4) Holding time t1 at annealing temperature T1] In the cold-rolled sheet annealing process, the holding time t1 at the annealing temperature T1 affects the spheroidization rate of cementite, similar to the annealing temperature T1. Specifically, if the holding time t1 is 16 hours or less, the cementite particles are not sufficiently spheroidized.

[0108] On the other hand, if the holding time t1 exceeds 50 hours, the holding time is too long, and in this case, the spheroidization rate of cementite particles becomes 85% or more.

[0109] If the holding time t1 is more than 16 hours and up to 50 hours, a steel sheet satisfying Features 1 to 6 can be produced, provided that other conditions are met.

[0110] Through the above manufacturing process, a steel sheet satisfying Features 1 to 6 can be manufactured.

[0111] The effects of the steel sheet of this embodiment will be described in more detail below using examples. The conditions in the following examples are one example of conditions adopted to confirm the feasibility and effects of the steel sheet of this embodiment. Therefore, the steel sheet of this embodiment is not limited to this one example of conditions. [Example]

[0112] Steel sheets having the chemical compositions shown in Tables 1-1 and 1-2 were manufactured.

[0113] [Table 1-1]

[0114] [Table 1-2]

[0115] Specifically, molten steel was continuously cast to produce a slab. The slab was then subjected to a hot rolling process. Specifically, the slab was heated at 1100 to 1250°C for 240 minutes. The heated slab was rolled in a roughing mill to produce a rough bar. The rough bar was then rolled in a finishing mill to produce a hot-rolled steel sheet. The finish rolling temperature for each test number was 830 to 950°C. The reduction ratio of the final pass was 5 to 30%. The hot-rolled steel sheet after finish rolling was wound up and formed into a coil. The coiled hot-rolled steel sheet was allowed to cool to room temperature. The coiling temperature CT in the hot rolling process for each test number was as shown in Table 2.

[0116] [Table 2]

[0117] For test numbers 1 to 45, the hot-rolled steel sheets after the hot rolling process were subjected to a cold rolling process without being subjected to a hot-rolled sheet annealing process. The cold rolling reduction ratios CR in the cold rolling process were as shown in Table 2. The cold-rolled steel sheets after the cold rolling were subjected to a cold-rolled sheet annealing process. The annealing temperature T1 and holding time t1 were as shown in Table 2. In the cold-rolled sheet annealing process, the steel sheets were furnace-cooled after the holding time t1 had elapsed. For test number 46, the hot-rolled sheet annealing process was performed after the hot rolling process and before the cold rolling process. The annealing temperature and the holding time at the annealing temperature were as shown in Table 2. Steel sheets were produced by the above-mentioned production process.

[0118] [Evaluation test] The following tests were carried out on the manufactured steel plates with each test number. (Test 1) Total area ratio measurement test for ferrite and cementite particles (Test 2) Ferrite average grain size measurement test (Test 3) Cr concentration in cementite particles [Cr] θ and Mo concentration [Mo] θ Measurement test (Test 4) Average particle size measurement test for cementite particles (Test 5) Measurement test of the spheroidization rate of cementite particles (Test 6) Hardenability evaluation test (Test 7) ​​Cold workability evaluation test Tests 1 to 7 will be explained below.

[0119] [(Test 1) Total Area Ratio Measurement Test of Ferrite and Cementite Particles] The total area ratio of ferrite and cementite particles was determined for each test number based on the method described in the above-mentioned [Method for measuring the total area ratio of ferrite and cementite particles in a microstructure]. As a result, as shown in Table 3, the total area ratios of ferrite and cementite particles for all test numbers other than test number 43 were 95% or more.

[0120] [Table 3]

[0121] [(Test 2) Ferrite average grain size measurement test] The average grain size of ferrite in the steel sheets of each test number was determined based on the method described in [Method for measuring the average grain size of ferrite] above. The results are shown in Table 3.

[0122] [(Test 3) Cr concentration in cementite particles [Cr] θ and Mo concentration [Mo] θ Measurement test The above [Cr concentration in cementite particles [Cr] θ and Mo concentration [Mo] θ Based on the method described in [Measurement method for Cr in cementite particles], the Cr concentration [Cr] of the steel plate of each test number θ and Mo concentration [Mo] θ The obtained Cr concentration [Cr] θ , and Mo concentration [Mo] θ is shown in Table 3.

[0123] [(Test 4) Average particle size measurement test for cementite particles] The average particle size of cementite particles in the steel sheet of each test number was determined based on the method described above in [Method for measuring the average particle size of cementite particles]. The obtained average particle sizes of cementite particles are shown in Table 3.

[0124] [(Test 5) Measurement test of the spheroidization rate of cementite particles] The spheroidization ratio of cementite particles of the steel plate of each test number was determined based on the method described above in [Method for measuring spheroidization ratio]. The obtained spheroidization ratios are shown in Table 3.

[0125] [(Test 6) Hardenability Evaluation Test] The hardenability of the steel sheets with each test number was evaluated after hardening based on the method described in the "Hardenability Evaluation Method" above. The "hardenability lower limit" in Table 3 indicates the maximum hardenability HD0 × 0.95. If the hardenability HD1 was equal to or greater than the hardenability lower limit, it was determined that sufficient hardenability was obtained (shown as "E (Excellent)" in the "Hardenability Evaluation" column in Table 3). On the other hand, if the hardenability HD1 was less than the hardenability lower limit, it was determined that sufficient hardenability was not obtained (shown as "NA (Not Allowed)" in the "Hardenability Evaluation" column in Table 3). Furthermore, if the hardenability HD1 was less than 600 HV, it was determined that the part strength was insufficient.

[0126] [(Test 7) ​​Cold workability evaluation test] The cold workability of the steel sheets of each test number was evaluated based on the method described in the "Cold workability evaluation method" above. The thickness of the plate-shaped test specimens was 2 mm. The notch elongations obtained are shown in Table 3. If the notch elongation obtained was 3.0% or more and equal to or greater than the notch elongation target (-33 × C content (%) of the steel sheet + 30.0%), the steel sheet was judged to have sufficient cold workability (shown as "E (Excellent)" in "Cold workability evaluation" in Table 3). On the other hand, if the notch elongation obtained was less than 3.0% or less than the notch elongation target (-33 × C content (%) of the steel sheet + 30.0%), the steel sheet was judged to have insufficient cold workability (shown as "NA (Not Allowed)" in "Cold workability evaluation" in Table 3).

[0127] [Evaluation results] With reference to Table 1-1, Table 1-2, Table 2, and Table 3, test numbers 1 to 32 had appropriate chemical compositions and satisfied manufacturing conditions 1 to 4. Therefore, the steel sheets of these test numbers satisfied features 1 to 6. As a result, sufficient hardenability and sufficient cold workability were obtained.

[0128] On the other hand, in test number 33, the C content was too high, and as a result, the notch elongation was less than 3.0%, and sufficient cold workability was not obtained.

[0129] In test number 34, the Si content was too high, and as a result, the notch elongation was less than the target notch elongation, and sufficient cold workability was not obtained.

[0130] In test number 35, the Mn content was too low, and therefore sufficient hardenability was not obtained.

[0131] In test number 36, the Mn content was too high, and as a result, the notch elongation was less than 3.0%, and sufficient cold workability was not obtained.

[0132] In test number 37, the Cr content was too high. Therefore, the Cr concentration in mass% in the cementite particles [Cr] θ The content of Cr was 2.00% or more. Therefore, sufficient hardenability was not obtained. As a result, the hardness after quenching (HD1) was less than 600 HV, and it was determined that sufficient part strength could not be achieved.

[0133] On the other hand, in test number 38, the Mo content was too high. Therefore, the Mo concentration in mass% in the cementite particles [Mo] θ exceeded 1.00%, and therefore sufficient hardenability could not be obtained.

[0134] In test number 39, although the chemical composition was appropriate, the coiling temperature CT was too high. Therefore, the spheroidization rate of the cementite particles was too low. As a result, sufficient cold workability was not obtained. Furthermore, the Cr concentration in the cementite particles [Cr] θ is 2.00% or more, and the Mo concentration [Mo]θ As a result, sufficient hardenability was not obtained.

[0135] In test number 40, although the chemical composition was appropriate, the cold rolling rate (CR) was too low. Therefore, the spheroidization rate of the cementite particles was too low. As a result, the notch elongation was below the target, and sufficient cold workability was not obtained.

[0136] In test number 41, although the chemical composition was appropriate, the cold rolling rate CR was too high, which resulted in a high spheroidization rate, and as a result, insufficient hardenability was obtained.

[0137] In Test No. 42, although the chemical composition was appropriate, the annealing temperature T1 in the cold-rolled sheet annealing process was too low. As a result, the spheroidization rate of cementite particles was low at less than 75%. As a result, the notch elongation was below the target, and sufficient cold workability was not obtained.

[0138] In test number 43, although the chemical composition was appropriate, the annealing temperature T1 in the cold-rolled sheet annealing process was too high. As a result, pearlite precipitated, and the total area ratio of ferrite and cementite particles was less than 95%. Furthermore, the spheroidization rate of the cementite particles was low. As a result, sufficient cold workability was not obtained.

[0139] In test number 44, although the chemical composition was appropriate, the holding time t1 in the cold-rolled sheet annealing process was too short. As a result, the spheroidization rate of cementite particles was too low, at less than 75%, and as a result, sufficient cold workability was not obtained.

[0140] In test number 45, although the chemical composition was appropriate, the holding time t1 in the cold-rolled sheet annealing process was too long. As a result, the spheroidization rate of cementite particles was too high. As a result, sufficient hardenability was not obtained.

[0141] In test number 46, annealing was performed after the hot rolling process but before the cold rolling process. Therefore, the spheroidization rate of the cementite particles was too high. Furthermore, the Cr concentration [Cr] in the cementite particles θ was too high, resulting in insufficient hardenability.

[0142] The embodiments of the present disclosure have been described above. However, the above-described embodiments are merely examples for implementing the present disclosure. Therefore, the present disclosure is not limited to the above-described embodiments, and can be implemented by appropriately modifying the above-described embodiments within the scope of the present disclosure.

Claims

1. A steel plate, The chemical composition is in mass %: C: 0.50-0.90%, Si: 0.01 to 0.50%, Mn: 0.20-1.30%, P: 0.100% or less, S: 0.100% or less, Al: 0.100% or less, Cr: 0.01-1.20%, N: 0.0150% or less, Mo: 0-0.500%, Ni: 0-1.000%, B: 0 to 0.0100%, V: 0 to 0.500%, Nb: 0 to 0.500%, Ti: 0 to 0.150%, and The balance is composed of Fe and impurities, In the microstructure, the total area ratio of ferrite and cementite particles is 95% or more, The average particle size of the ferrite is 5.0 to 20.0 μm, Cr concentration in mass% in the cementite particles [Cr] θ is less than 2.00%, and the Mo concentration in mass% in the cementite particles [Mo] θ is 1.00% or less, The average particle size of the cementite particles is 1.50 μm or less, When the cementite particles having an aspect ratio of 3.0 or less are defined as spherical cementite particles, a spheroidization rate, which is the ratio of the total number of the spherical cementite particles to the total number of the cementite particles, is 75 to less than 85%. steel plate.

2. The steel sheet according to claim 1, The chemical composition is Mo: 0.001 to 0.500%, Ni: 0.001 to 1.000%, B: 0.0001 to 0.0100%, V: 0.001-0.500%, Nb: 0.001 to 0.500%, and Ti: 0.001 to 0.150%, Contains one or more elements selected from the group consisting of steel plate.

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