Bundling protection tape

Abstract

Provided is a binding protective tape that has an excellent balance between flexibility and protective performance, and also has excellent tape storage stability. The present invention provides a binding protective tape having a substrate and an adhesive layer formed on one side of the substrate, wherein the substrate is composed of a resin composition containing a polyvinyl chloride resin, a plasticizer, a filler, and a slidability imparting agent, and the content of the slidability imparting agent in the resin composition is 1-10 parts by mass with respect to 100 parts by mass of the polyvinyl chloride resin.

Description

[Technical Field]

[0001] The present invention relates to a bundling and protection tape that can be suitably used for bundling and protecting high-voltage cables in electric vehicles and hybrid vehicles, automotive wire harnesses, and the like. [Background technology]

[0002] For the purposes of bundling and protecting automotive wire harnesses, polyvinyl chloride bundling protection tapes, which have a substrate made of polyvinyl chloride resin and a pressure-sensitive adhesive applied to one side thereof, are used because they have moderate flexibility and extensibility, and are excellent in flame retardancy, mechanical strength, heat deformation resistance, electrical insulation, and moldability, and are also relatively inexpensive (Patent Documents 1 and 2).It is also known that the cuttability and abrasion resistance of polyvinyl chloride bundling protection tapes can be improved by arranging hard wires that are harder than polyvinyl chloride resin in a predetermined cutting direction and embedding them in the substrate (Patent Document 3). [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 8-259909 [Patent Document 2] Japanese Patent Application Laid-Open No. 2012-184369 [Patent Document 3] Patent Publication No. 9-71031 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present invention is to provide a bundling and protective tape that has an excellent balance between flexibility and protective performance and also has excellent storage stability. [Means for solving the problem]

[0005] As a result of investigations by the present inventors, it has been found that in a binding protection tape having a substrate and an adhesive layer formed on one side of the substrate, by incorporating a polyvinyl chloride resin, a plasticizer, a filler, and a sliding property imparting agent in the substrate, and by setting the content of the sliding property imparting agent to 1 to 10 parts by mass per 100 parts by mass of the polyvinyl chloride resin, a binding protection tape can be obtained that has an excellent balance of flexibility and protective performance and also has excellent storage stability. That is, the present invention provides: [1] A binding and protection tape having a substrate and a pressure-sensitive adhesive layer formed on one side of the substrate, the substrate is made of a resin composition containing a polyvinyl chloride resin, a plasticizer, a filler, and a sliding property imparting agent; the content of the sliding property imparting agent in the resin composition is 1 to 10 parts by mass relative to 100 parts by mass of the polyvinyl chloride resin; Binding protection tape. [2] The substrate is fixed to a sample stage using Nitto Denko No. 5000NS double-sided tape, and the coefficient of dynamic friction of the substrate surface is measured using an R contactor based on ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec., and is 0.06 to 0.26. [1] The bundling protection tape described in [1]. [3] The bundling protection tape is fixed to a sample stage via the pressure-sensitive adhesive layer, and the dynamic friction coefficient of the back surface of the substrate of the bundling protection tape is measured using an R contactor based on ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec., and is 0.13 to 0.60. [1] The bundling protection tape described in [1]. [4] The binding and protection tape according to any one of [1] to [3], wherein the sliding property imparting agent is any one selected from the group consisting of linear polyorganosiloxane, crosslinked polyorganosiloxane, silica, talc, glass fiber, and fluororesin. [5] The binding protection tape according to any one of [1] to [4], wherein the agent for imparting sliding properties is a linear polydimethylsiloxane. [6] The linear polydimethylsiloxane has a kinematic viscosity of 2,000,000 mm at 25°C. 2 The bundling protection tape according to [4], wherein the bundling protection tape is / s or more. [7] The binding protection tape according to any one of [1] to [6], wherein the content of the plasticizer in the resin composition is 38 to 60 parts by mass per 100 parts by mass of the polyvinyl chloride resin. [8] The binding protection tape according to any one of [1] to [7], wherein the content of the filler in the resin composition is 10 to 60 parts by mass per 100 parts by mass of the polyvinyl chloride resin. [9] The binding protection tape according to any one of [1] to [8], wherein the thickness of the substrate is 180 to 330 μm.

[10] The binding protection tape according to any one of [1] to [9], wherein the tensile modulus of elasticity converted into thickness of the substrate is 5 to 9 N / mm. Regarding. [Effects of the Invention]

[0006] According to the present invention, it is possible to provide a bundling and protective tape that has an excellent balance between flexibility and protective performance, and further has excellent storage stability of the tape. DETAILED DESCRIPTION OF THE INVENTION

[0007] <Terminology> In the present specification, for example, the expression "A to B" means A or more and B or less.

[0008] The following describes in detail the embodiments of the present invention. The present invention is not limited to these, and various modifications are possible without departing from the spirit of the invention. The various features shown in the following embodiments can be combined with each other. Furthermore, each feature can be an invention independently.

[0009] <Structure of bundling protection tape> The binding protection tape according to one embodiment of the present invention comprises a substrate and a pressure-sensitive adhesive layer formed on one side of the substrate. Each component will be described in detail below.

[0010] <Base material> A substrate according to one embodiment of the present invention is composed of a resin composition containing a polyvinyl chloride resin, a plasticizer, a filler, and a sliding property-imparting agent, in which the content of the sliding property-imparting agent is 1 to 10 parts by mass per 100 parts by mass of the polyvinyl chloride resin.

[0011] <Polyvinyl chloride resin> In one embodiment of the present invention, the polyvinyl chloride resin preferably has an average degree of polymerization of 1000 to 1500, and two or more polyvinyl chloride resins with different average degrees of polymerization may be used. If the average degree of polymerization is less than 1000, the entanglement of polymer chains may be insufficient, making it difficult to obtain sufficient strength (abrasion resistance). If the average degree of polymerization is higher than 1500, gelation may be difficult, which may result in poor film formability.

[0012] <Plasticizer> The plasticizer used in one embodiment of the present invention is not particularly limited as long as it can impart flexibility to the substrate. Examples include trimellitic acid esters, adipate esters, phthalate esters, epoxy-based plasticizers, isophthalate esters, terephthalate esters, and phosphate-based plasticizers. Phthalate esters are preferred from the viewpoints of their plasticizing effect on polyvinyl chloride resins and minimal bleed-out. These plasticizers may be used alone or in combination of two or more.

[0013] <Phthalate esters> Examples of phthalate ester plasticizers in one embodiment of the present invention include DINP (diisononyl phthalate), DHP (diheptyl phthalate), DOP (di-2-ethylhexyl phthalate), n-DOP (di-n-octyl phthalate), and diisodecyl phthalate (DIDP). From the viewpoints of plasticizing effect on polyvinyl chloride resin, less bleed-out, and less impact on the human body, diesters of phthalic acid and alcohols having 9 to 10 carbon atoms, such as DINP (diisononyl phthalate) and diisodecyl phthalate (DIDP), are preferred. These plasticizers may be used alone or in combination of two or more.

[0014] In one embodiment of the present invention, the content of the plasticizer is preferably 38 to 60 parts by mass, more preferably 40 to 50 parts by mass, per 100 parts by mass of polyvinyl chloride resin. Specifically, for example, 38, 40, 42, 43, 44, 45, 46, 48, 50, 55, or 60 parts by mass is preferred, and may be within a range between any two of the values ​​exemplified here. By using 38 parts by mass or more of the plasticizer, the flexibility of the substrate is improved, and for example, the conformability when wrapped around an electric wire or the like is improved, thereby reducing the occurrence of lifting in the bundling protection tape. By using 60 parts by mass or less of the plasticizer, the abrasion resistance of the substrate is improved, resulting in good protection performance. When a plasticizer is used in combination, the content of the plasticizer means the total amount of the plasticizer used in combination.

[0015] <Filler> The filler in one embodiment of the present invention is not particularly limited as long as it can increase the amount of the base material and improve hardness. For example, inorganic fillers are preferred from the viewpoint of achieving both reinforcing effect and flexibility.

[0016] <Inorganic filler> Examples of inorganic fillers in one embodiment of the present invention include calcium carbonate, aluminum hydroxide, magnesium hydroxide, zirconium hydroxide, calcium hydroxide, potassium hydroxide, barium hydroxide, triphenyl phosphite, ammonium polyphosphate, polyphosphate amide, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, molybdenum oxide, guanidine phosphate, hydrotalcite, smectite, zinc borate, anhydrous zinc borate, zinc metaborate, barium metaborate, antimony oxide, antimony pentoxide, red phosphorus, alumina, boehmite, bentonite, sodium silicate, calcium silicate, calcium sulfate, magnesium carbonate, and carbon black. From the viewpoint of achieving both reinforcing effect and flexibility, calcium carbonate and carbon black are preferred. These fillers may be used alone or in combination of two or more.

[0017] In one embodiment of the present invention, the content of the filler is preferably 10 to 60 parts by mass, more preferably 20 to 40 parts by mass, per 100 parts by mass of polyvinyl chloride resin. Specifically, the content is, for example, 10, 15, 20, 25, 30, 35, 40, 45, 50, or 60 parts by mass, and may be within a range between any two of the values ​​exemplified here. By using 10 parts by mass or more of the filler, the abrasion resistance of the substrate is improved, resulting in good protective performance. By using 60 parts by mass or less of the filler, the flexibility of the substrate is improved, and the improved conformability when wrapped around, for example, an electric wire can be improved, thereby reducing the occurrence of lifting in the bundling protection tape. When a filler is used in combination, the content of the filler means the total amount of the fillers used in combination.

[0018] <Sliding agent> The sliding property imparting agent in one embodiment of the present invention is not particularly limited as long as it can impart sliding property to the substrate. Examples include polyorganosiloxane, silica, talc, glass fiber, fluororesin, boron nitride, molybdenum disulfide, and ultra-high molecular weight polyethylene resin. From the viewpoint of achieving both sliding property and flexibility, polyorganosiloxane is preferred. Examples of polyorganosiloxane include linear polyorganosiloxane and crosslinked polyorganosiloxane. These agents for imparting sliding properties may be used alone or in combination of two or more. From the viewpoints of sliding properties and preventing plate-out (a phenomenon in which part of the resin composition separates and adheres to the molding machine), the agents for imparting sliding properties are preferably uniformly dispersed in the resin composition.

[0019] <Polyorganosiloxane> <Polyorganosiloxane structure> The polyorganosiloxane in one embodiment of the present invention is not particularly limited as long as it has a polyorganosiloxane structure. The polyorganosiloxane structure is a polymer having a -Si-O- repeating unit in the main chain and an organic group in the side chain. Examples of the repeating unit include those represented by the following structural formula:

[0020] [ka]

[0021] In the formula, R1 and R2 are each independently an organic group selected from an alkyl group, a polyoxyalkylene group, a fluorine-containing group, and a chlorophenyl group. From the viewpoint of sliding properties, an alkyl group is preferred. Examples of the alkyl group include a methyl group and an ethyl group from the viewpoint of sliding properties. These polyorganosiloxane structures may be used alone or in combination of two or more.

[0022] <Linear polyorganosiloxane> The polyorganosiloxane in one embodiment of the present invention may be a linear polyorganosiloxane in which the siloxane bonds of the main chain are linearly bonded. Examples of linear polyorganosiloxanes include linear polydimethylsiloxane, linear polymethylphenylsiloxane, and linear polymethylhydrogensiloxane. From the viewpoint of sliding properties, linear polydimethylsiloxane is preferred. These other linear polyorganosiloxanes may be used alone or in combination of two or more.

[0023] <Kinematic viscosity of linear polyorganosiloxane> In one embodiment of the present invention, the linear polyorganosiloxane has a kinematic viscosity at 25 ° C. of 2 million mm 2 / s or more is preferable, and 5 million mm 2 The upper limit of the kinematic viscosity is not particularly limited, but from the viewpoint of ease of handling and dispersibility, it is preferably 50 million mm 2 Specifically, for example, 2 million, 5 million, 15 million, 20 million, 25 million, 30 million, 40 million, or 50 million mm 2 / s, and may be within a range between any two of the values ​​exemplified here. 2 By setting the viscosity at 1 / s or more, the abrasion resistance of the substrate is improved, good protective performance is obtained, and the storage stability of the tape is also improved.

[0024] In one embodiment of the present invention, the kinematic viscosity of the linear polyorganosiloxane at 25° C. is a value measured, for example, with a kinematic viscometer. The kinematic viscosity of the linear polyorganosiloxane can be controlled by adjusting the molecular weight. When a linear polyorganosiloxane is used in combination, the kinematic viscosity at 25°C of the linear polyorganosiloxane means the average kinematic viscosity of the linear polyorganosiloxane used in combination.

[0025] <Crosslinked polyorganosiloxane> In one embodiment of the present invention, the polyorganosiloxane may have a structure in which a linear polyorganosiloxane is crosslinked or a structure in which siloxane bonds are crosslinked in a three-dimensional network from the viewpoint of storage stability. From the viewpoint of sliding properties, a polyorganosiloxane in which a linear polyorganosiloxane is crosslinked is preferred. These crosslinked polyorganosiloxanes may be used alone or in combination of two or more.

[0026] The sliding property imparting agent in one embodiment of the present invention may be silica, talc, glass fiber, fluororesin, or the like.

[0027] <Content of agent for imparting sliding properties> In one embodiment of the present invention, the content of the sliding property-imparting agent is 1 to 10 parts by mass, more preferably 3 to 7 parts by mass, per 100 parts by mass of polyvinyl chloride resin. Specifically, the content is, for example, 1, 2, 4, 6, 8, or 10 parts by mass, and may be within a range between any two of the values ​​exemplified here. By setting the content of the sliding property-imparting agent to 1 part by mass or more, the abrasion resistance of the substrate is improved, and good protective performance is obtained. By setting the content of the sliding property-imparting agent to 10 parts by mass or less, the storage stability of the tape is improved. When a sliding property imparting agent is used in combination, the content of the sliding property imparting agent means the total amount of the sliding property imparting agents used in combination.

[0028] <Other additives> Furthermore, the resin composition of the present embodiment may contain other additives such as colorants, stabilizers, antioxidants, ultraviolet absorbers, and lubricants, as needed, within the scope of not impairing the effects of the present invention.

[0029] <Base material thickness> The substrate thickness of the bundling protection tape in this embodiment varies depending on the intended use and application, but is preferably 180 to 330 μm, more preferably 180 to 250 μm. Specifically, the thickness may be, for example, 180, 185, 190, 195, 200, 205, 210, 220, 250, 280, 300, or 330 μm, and may be within a range between any two of the values ​​exemplified here. By setting the substrate thickness to 180 μm or more, the abrasion resistance of the substrate is improved, resulting in good protective performance. By setting the substrate thickness to 330 μm or less, the flexibility of the substrate is improved, and the improved conformability when wrapped around, for example, an electric wire can be improved, thereby reducing the occurrence of lifting in the bundling protection tape.

[0030] <Substrate structure> The structure of the substrate of the binding protection tape in this embodiment is preferably a single layer structure from the viewpoint of simplifying the manufacturing process and manufacturing equipment.

[0031] <Method of manufacturing the substrate> The resin composition for producing the substrate according to this embodiment can be obtained by melt-kneading polyvinyl chloride resin, plasticizer, filler, and sliding agent, as well as, if necessary, heat stabilizers, light absorbers, pigments, and other additives. The melt-kneading method is not particularly limited, but various mixers and kneaders equipped with heating devices, such as twin-screw extruders, continuous and batch kneaders, rolls, and Banbury mixers, can be used. The resin composition is mixed to uniformly disperse, and the resulting mixture is molded into the substrate using conventional molding methods such as the calendaring method, T-die method, and inflation method. A calendar molding machine is preferred for productivity, color change, and shape uniformity. The roll arrangement method used in calendar molding can be, for example, a known type, such as L-type, reverse L-type, or Z-type. The roll temperature is typically set to 150 to 200°C, preferably 155 to 190°C.

[0032] <Dynamic friction coefficient of substrate surface> In one embodiment of the present invention, when the substrate is fixed to a measurement stage with Nitto Denko Corporation's No. 5000NS double-sided tape, the coefficient of kinetic friction of the substrate surface, measured using an R contactor based on ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec, is preferably 0.06 to 0.26, more preferably 0.10 to 0.25. Specifically, the coefficient of kinetic friction is, for example, 0.06, 0.08, 0.10, 0.12, 0.14, 0.16, 0.18, 0.20, 0.22, 0.24, or 0.26, and may be within a range between any two of the values ​​exemplified here. By ensuring that the coefficient of kinetic friction of the substrate surface is 0.06 or higher, the flexibility of the bundling protection tape is improved, and the improved followability when wrapped around, for example, an electric wire can be improved, thereby reducing the occurrence of lifting of the bundling protection tape. By making the coefficient of dynamic friction of the substrate surface 0.26 or less, the abrasion resistance of the bundling protection tape is improved, and good protection performance is obtained.

[0033] The dynamic friction coefficient of the substrate surface can be controlled by adjusting the type and content of the sliding property imparting agent contained in the resin composition used to produce the substrate.

[0034] <Measurement of the dynamic friction coefficient of the substrate surface> The dynamic friction coefficient of the substrate surface of the substrate according to this embodiment can be measured, for example, using an automatic friction and wear analyzer TS-501 manufactured by Kyowa Interface Science Co., Ltd. according to the following procedure. The substrate sample is cut to a width of 50 mm and a length of 100 mm, and fixed to the sample stage using double-sided tape (Nitto Denko Corporation No. 5000NS). An R contact based on ASTM D1894 is placed on the back of the bonded substrate sample, and the dynamic friction coefficient is measured under conditions of a load of 200 g and a test speed of 2.5 mm / sec (room temperature 23°C, humidity 50% RH).

[0035] <Tensile modulus converted into thickness of substrate> For the substrate according to this embodiment, the tensile modulus of elasticity, calculated as the thickness of the substrate, is preferably 5 to 9 N / mm, and more preferably 6 to 9 N / mm. Specifically, it is, for example, 5, 6, 7, 8, or 9 N / mm, and may be within a range between any two of the values ​​exemplified here. By setting the tensile modulus of elasticity, calculated as the thickness of the substrate, to 5 N / mm or more, a good balance with the protective performance of the substrate can be achieved. By setting the tensile modulus of elasticity, calculated as the thickness of the substrate, to 9 N / mm or less, the flexibility of the substrate is improved, and the improved conformability when the binding protection tape is wound around, for example, an electric wire can be improved, thereby reducing the occurrence of lifting of the binding protection tape. The tensile modulus of elasticity converted into thickness of the substrate can be controlled by adjusting the type and content of the sliding property imparting agent contained in the resin composition used to produce the substrate.

[0036] <Measurement of tensile modulus converted into substrate thickness> The tensile modulus of elasticity of the substrate according to this embodiment, converted into thickness, can be obtained from the value of the tensile modulus of elasticity by the following procedure. A 19 mm wide, 200 mm long binding tape test piece is clamped and fixed in the chuck of a tensile tester with a chuck distance of 100 mm. The test piece is pulled at a speed of 300 mm / min in an environment of room temperature 23°C and relative humidity 50% RH, and the tensile stress and strain are measured. The ratio of tensile stress to strain between 0.01 and 0.05% strain is calculated by linear regression and the value is taken as the tensile modulus. The product of the tensile modulus thus obtained and the total thickness of the tape (unit: mm) is defined as the tensile modulus converted into thickness.

[0037] <Adhesive layer> The adhesive of the adhesive layer of the bundling protection tape according to this embodiment is preferably a rubber-based adhesive, and may be either a solvent-based or emulsion-based adhesive. The rubber-based adhesive preferably contains one or more rubbers selected from natural rubber or synthetic rubber and a tackifier resin, and more preferably a mixture of natural rubber, synthetic rubber, and tackifier resin. The mixing ratio of the tackifier resin is preferably 50 to 150 parts by mass of tackifier resin per 100 parts by mass of the rubber component of the mixture containing natural rubber and synthetic rubber.

[0038] Examples of the natural rubber and synthetic rubber include natural rubber-methyl methacrylate copolymer latex, styrene-butadiene copolymer, acrylonitrile-butadiene copolymer, methyl methacrylate-butadiene copolymer, etc. These may be used alone or in combination of two or more.

[0039] The tackifying resin can be selected in consideration of the softening point, compatibility with each component, etc. Examples include emulsions of terpene resin, rosin resin, hydrogenated rosin resin, coumarone-indene resin, styrene-based resin, aliphatic petroleum resin, alicyclic petroleum resin, terpene-phenol resin, xylene-based resin, and other aliphatic hydrocarbon resins or aromatic hydrocarbon resins. These may be used alone or in combination of two or more.

[0040] The rubber-based adhesive can be freely selected from solvent-based and emulsion-based adhesives, but emulsion-based adhesives that generate less VOC are preferred.

[0041] <Primer layer>

[0042] Furthermore, if necessary, the binding protection tape of this embodiment may have a primer layer between the substrate and the adhesive layer for the purpose of improving adhesion between the substrate and the adhesive layer, within a range that does not impair the effects of the present invention. In this case, as described below, the thickness of the primer layer is usually 0.1 to 1 μm, more preferably 0.3 to 0.5 μm, and it is preferable that the thickness of the primer layer is smaller than the thickness of the substrate.

[0043] The primer for forming the primer layer is preferably one containing 25 to 300 parts by mass of an acrylonitrile-butadiene copolymer with 100 parts by mass of a graft polymer obtained by graft polymerizing methyl methacrylate onto natural rubber.

[0044] The graft polymer used in the primer, obtained by graft polymerizing methyl methacrylate onto natural rubber, is preferably obtained by graft polymerizing 70 to 50% by mass of natural rubber with 30 to 50% by mass of methyl methacrylate. If the proportion of methyl methacrylate in the graft polymer is less than 30% by mass, the adhesion between the methyl methacrylate and the film substrate may be poor, resulting in interlayer delamination of the bundling protection tape. Furthermore, if the proportion of methyl methacrylate is more than 50% by mass, the primer itself may harden and be unable to follow the deformation of the film substrate, resulting in interlayer delamination of the bundling protection tape.

[0045] The acrylonitrile-butadiene copolymers used in the primer include medium nitrile types (25 to 30% by mass of acrylonitrile, 75 to 70% by mass of butadiene), medium-high nitrile types (31 to 35% by mass of acrylonitrile, 69 to 65% by mass of butadiene), high nitrile types (36 to 43% by mass of acrylonitrile, 64 to 57% by mass of butadiene), etc. These may be used alone or in combination of two or more types.

[0046] <Method of manufacturing the bundling protection tape> The bundling protection tape according to this embodiment can be produced, for example, by coating one side of a substrate with a primer, thoroughly removing the solvent in a drying oven, and then coating with a pressure-sensitive adhesive. Similarly to the primer, the solvent is thoroughly removed in a drying oven, and then the pressure-sensitive adhesive is coated again to obtain a bundling protection tape. The primer coating method can be a gravure coating method, a spray coating method, a kiss roll coating method, a bar coating method, or a knife coating method. The pressure-sensitive adhesive coating method can be a comma coating method, a lip die coating method, a gravure coating method, a roll coating method, or a slot die coating method. The thickness of the primer layer is typically 0.1 to 1 μm, more preferably 0.3 to 0.5 μm. The thickness of the pressure-sensitive adhesive layer varies depending on the intended use and application, but is typically 5 to 50 μm, more preferably 10 to 30 μm.

[0047] <Dynamic friction coefficient on the backside of the bundling protection tape substrate> In another embodiment of the present invention, when the bundling protection tape is fixed to a measurement stage via the pressure-sensitive adhesive layer, the kinetic friction coefficient of the back surface of the bundling protection tape substrate, as measured using an R contactor according to ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec, is preferably 0.13 to 0.60, more preferably 0.23 to 0.58. Specifically, for example, 0.13, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, or 0.60 is preferred, and may be within a range between any two of the values ​​exemplified here. By ensuring that the kinetic friction coefficient of the back surface of the bundling protection tape substrate is 0.13 or higher, the flexibility of the bundling protection tape is improved, and the improved followability when wrapped around, for example, an electric wire can be improved, thereby reducing the occurrence of lifting of the bundling protection tape. By setting the dynamic friction coefficient of the back surface of the bundling protection tape substrate to 0.60 or less, the abrasion resistance of the bundling protection tape is improved, and good protective performance is obtained. The back surface of the substrate of the bundling and protection tape refers to the surface of the substrate of the bundling and protection tape opposite to the surface on which the pressure-sensitive adhesive layer is formed.

[0048] For example, when the thickness of the substrate is the same, the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape tends to increase as the kinetic friction coefficient of the substrate surface increases. Therefore, the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape can be controlled by adjusting the kinetic friction coefficient of the substrate surface within the above-mentioned range. When a bundling protection tape is formed by providing a pressure-sensitive adhesive layer on the substrate, the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape tends to be higher than the kinetic friction coefficient of the substrate surface. However, due to the above-mentioned relationship, the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape can be controlled within a desired range by adjusting the kinetic friction coefficient of the substrate surface within a predetermined range. Furthermore, as the thickness of the substrate increases, the effect of providing a pressure-sensitive adhesive layer on the change in the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape tends to decrease. Therefore, even when the thickness of the substrate is large, the kinetic friction coefficient of the back surface of the substrate of the bundling protection tape can be controlled by adjusting the kinetic friction coefficient of the substrate surface within the above-mentioned range.

[0049] <Measurement of the dynamic friction coefficient on the back surface of the bundling protection tape substrate> The dynamic friction coefficient of the back surface of the substrate of the bundling protection tape according to this embodiment can be measured, for example, using an automatic friction and wear analyzer TS-501 manufactured by Kyowa Interface Science Co., Ltd. according to the following procedure. A bundling protection tape sample is cut to a width of 50 mm and a length of 100 mm, and fixed to a sample stage via the adhesive layer of the bundling protection tape sample. An R contact based on ASTM D1894 is placed on the back of the bonded protective tape sample, and the dynamic friction coefficient is measured under conditions of a load of 200 g and a test speed of 2.5 mm / sec (room temperature 23°C, humidity 50% RH).

[0050] <Applications of bundling protection tape> The bundling and protection tape according to this embodiment is suitably used, for example, as a bundling and protection tape for bundling high-voltage cables and wire harnesses in electric vehicles and hybrid vehicles. [Example]

[0051] The present invention will be described in more detail below with reference to examples, but these examples are merely illustrative and are not intended to limit the scope of the present invention.

[0052] <Preparation of substrate> <Materials used> (1) Polyvinyl chloride resin Vinyl chloride homopolymer, average degree of polymerization 1000: Product name "TH-1000", manufactured by Taiyo Vinyl Corporation (2) Sliding agent Linear polydimethylsiloxane (kinematic viscosity at 25°C: 25 million mm 2 / s): Product name: "GENIOPLAST GUM", manufactured by Asahi Kasei Wacker Silicone Co., Ltd. Linear polydimethylsiloxane (kinematic viscosity at 25°C: 2 million mm 2 / s): Product name "DMF100-200M", manufactured by Tomita Matex Co., Ltd. Linear polydimethylsiloxane (kinematic viscosity 1 million mm at 25°C) 2 / s): Product name "AK1000000", manufactured by Asahi Kasei Wacker Silicone Co., Ltd. Cross-linked polydimethylsiloxane (polyorganosiloxane in which linear polyorganosiloxane is cross-linked): Product name "KMP-597", manufactured by Shin-Etsu Chemical Co., Ltd. Silica: Product name "HDK H-18", manufactured by Wacker Asahi Kasei Silicone Co., Ltd. Talc: Product name "High Micron HE5", manufactured by Takehara Chemical Industry Co., Ltd. Glass fiber: Product name: "Milled Fiber EPH80M-10A", manufactured by Nippon Electric Glass Co., Ltd. Fluoropolymer: Product name: "Dyneon PTFE Micropowder TF9207Z" manufactured by 3M (3) Plasticizer Phthalate ester plasticizer, diisononyl phthalate: product name "DINP", manufactured by J-Plus Corporation (4) Filler Calcium carbonate: Product name: "Calcise (registered trademark) P", manufactured by Konoshima Chemical Co., Ltd.

[0053] Polyvinyl chloride resin, a sliding property imparting agent, a plasticizer, and a filler were melt-kneaded in a Banbury mixer in the formulations shown in Tables 1 and 2 so as to be uniformly dispersed, and then a substrate of a predetermined thickness was produced in a calendar molding machine at a roll temperature of 165°C.

[0054] <Preparation of bundling protection tape> <Materials used> (1) Base material The substrate prepared by the above process (2) Undercoat layer A mixture emulsion of graft polymer latex, which is made by graft polymerizing methyl methacrylate onto natural rubber, and acrylonitrile butadiene copolymer emulsion: Product name KT4612A, manufactured by E-Tech Co., Ltd. (3) Adhesive layer A mixture of 60 parts by mass (solids) of natural rubber latex (manufactured by Resitex Co., Ltd., product name: HA LATEX), 40 parts by mass (solids) of graft polymer latex (manufactured by Resitex Co., Ltd., product name: MG-40S) in which natural rubber is graft polymerized with methyl methacrylate, and 135 parts by mass (solids) of a petroleum resin emulsion tackifier (manufactured by Arakawa Chemical Industries, Ltd., product name: AP-1100-NT).

[0055] A primer was applied to one side of the substrate using the gravure method, and the solvent was thoroughly removed in a drying oven. The adhesive was then applied using the comma method, and the solvent was thoroughly removed in the same manner as for the primer. The resulting bond protection tape had a dried thickness of 0.3 μm for the primer layer and 20 μm for the adhesive layer.

[0056] <Physical properties of the substrate and bundling protection tape> The physical properties of the substrate and bundling protection tape were measured and evaluated under the measurement conditions shown below. The results are shown in Tables 1 and 2. In the tables, PVC stands for polyvinyl chloride resin, DINP stands for diisononyl phthalate, PDMS stands for polydimethylsiloxane, and PTFE stands for polytetrafluoroethylene.

[0057] <Dynamic friction coefficient of substrate surface> Measurement was carried out using an automatic friction and wear analyzer TS-501 manufactured by Kyowa Interface Science Co., Ltd. according to the following procedure. The substrate sample was cut to a width of 50 mm and a length of 100 mm and fixed to the sample stage using double-sided tape (Nitto Denko Corporation, No. 5000NS). An R contact based on ASTM D1894 was placed on the back of the bonded substrate sample, and the dynamic friction coefficient was measured under conditions of a load of 200 g and a test speed of 2.5 mm / sec (room temperature 23°C, humidity 50% RH).

[0058] <Dynamic friction coefficient of bundling protection tape> Measurement was carried out using an automatic friction and wear analyzer TS-501 manufactured by Kyowa Interface Science Co., Ltd. according to the following procedure. The bundling protection tape sample was cut to a width of 50 mm and a length of 100 mm, and was attached and fixed to the sample stage via the adhesive layer. An R contact based on ASTM D1894 was placed on the back of the bonded protective tape sample, and the dynamic friction coefficient was measured under conditions of a load of 200 g and a test speed of 2.5 mm / sec (room temperature 23°C, humidity 50% RH).

[0059] <Tensile modulus / Tensile modulus converted into thickness> A 19 mm wide, 200 mm long binding tape test piece was clamped and fixed in the chucks of a tensile tester with a chuck distance of 100 mm. The test piece was pulled at a speed of 300 mm / min in an environment of room temperature 23°C and relative humidity 50% RH, and the tensile stress and strain were measured. The ratio of tensile stress to strain between 0.01 and 0.05% strain was calculated by linear regression and used as the tensile modulus. The product of the tensile modulus and the total thickness of the tape (unit: mm) was taken as the tensile modulus converted into thickness.

[0060] <Hardness> The durometer A hardness of the substrate samples stacked to a thickness of 6 mm or more was measured using an Asker rubber hardness tester Type A (type A indenter based on ASTM D2240) manufactured by Kobunshi Keiki Co., Ltd. (room temperature 23°C, humidity 50% RH).

[0061] <Protection performance> The abrasion resistance was evaluated according to the following procedure. The test was conducted in accordance with ISO6722-1 (2001). The substrate sample was wrapped around a 10 mm diameter cylinder twice and secured with tape or the like. The sample surface was then abraded at a speed of 1500 mm / min using sandpaper made of fused alumina and 150 μm grit. The abrasion distance (mm) until a hole was created in the sample was measured (room temperature 23°C, humidity 50% RH). The abrasion distance (mm) until a hole was created in the sample was evaluated according to the following criteria. A substrate with an excellent abrasion distance evaluation has high abrasion resistance, and it is expected that a bundling protection tape manufactured using that substrate will achieve excellent protective performance. ◎: Wear distance is 1000mm or more ○: Wear distance is 800mm or more and less than 1000mm ×: Wear distance is less than 800 mm

[0062] <Flexibility> The wires were evaluated based on whether or not they floated when bound, according to the following procedure. A bundling protection tape sample was spirally wrapped around bundles of electric wires with diameters of 15 mm and 10 mm (half-wrapped) to bind them. When this bundled electric wire was wrapped around a mandrel with a diameter of 50 mm once, the presence or absence of lifting (gaps due to peeling) between the bundling protection tape sample and the electric wire bundle was confirmed. The lifting between the bundling protection tape sample and the electric wire bundle was evaluated according to the following criteria. ◎: No floating occurred with either 15mm or 10mm wire diameter ○: No floating with 15mm wire diameter, floating with 10mm wire diameter ×: Floating occurred for both 15mm and 10mm wire diameters

[0063] <Tape storage stability> The evaluation was carried out according to the following procedures and evaluation criteria. The substrate sample before heating was subjected to EDX analysis (energy dispersive X-ray analysis) to quantify the amount of Si in the substrate sample. The substrate sample was heated in an oven at 100°C for 168 hours. After removing the silicone precipitated on the surface of the substrate sample after heating, the substrate sample was subjected to EDX analysis to quantify the amount of Si in the substrate sample after heating. The Si reduction rate before and after heating was calculated and evaluated according to the following criteria. A substrate with an excellent storage stability evaluation has high storage stability, and therefore it can be expected that a bundling protection tape manufactured using this substrate will achieve excellent storage stability. ◎: Si reduction rate is less than 5% by mass ○: The reduction rate of Si is 5% or more by mass and less than 20% by mass ×: Si reduction rate is 20 mass% or more

[0064] [Table 1]

[0065] [Table 2]

[0066] From the results in Tables 1 and 2, it can be seen that the bundling protection tapes using the substrates according to the Examples and the bundling protection tapes according to the Examples have an excellent balance between flexibility and protective performance, and furthermore, since the storage stability of the substrates according to the Examples is excellent, it is expected that the bundling protection tapes using these substrates will have excellent storage stability. On the other hand, it can be seen that the bundling protection tapes using the substrates according to the Comparative Examples are inferior in one or more respects of the balance between flexibility and protective performance and the storage stability of the bundling protection tapes. [Industrial Applicability]

[0067] The bundling and protective tape of the present invention has an excellent balance between flexibility and protective performance, and further has excellent storage stability. The bundling and protective tape of the present invention can be suitably used for bundling and protecting high-voltage cables in electric vehicles and hybrid vehicles, automotive wire harnesses, etc., and has industrial applicability.

Claims

1. A binding and protection tape having a substrate and a pressure-sensitive adhesive layer formed on one side of the substrate, the substrate is made of a resin composition containing a polyvinyl chloride resin, a plasticizer, a filler, and a sliding property imparting agent; the content of the sliding property imparting agent in the resin composition is 1 to 10 parts by mass relative to 100 parts by mass of the polyvinyl chloride resin; The sliding property imparting agent is a linear polydimethylsiloxane. Binding protection tape.

2. The substrate is fixed to a sample stage using Nitto Denko Corporation's No. 5000NS double-sided tape, and the coefficient of dynamic friction of the substrate surface is measured using an R contactor based on ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec, and is 0.06 to 0.

26. The bundling and protection tape according to claim 1 .

3. The bundling protection tape is fixed to a sample stage via the pressure-sensitive adhesive layer, and the dynamic friction coefficient of the back surface of the substrate of the bundling protection tape is measured using an R contactor based on ASTM D1894 under conditions of a load of 200 g and a test speed of 2.5 mm / sec, and is 0.13 to 0.

60. The bundling and protection tape according to claim 1 .

4. The linear polydimethylsiloxane has a kinematic viscosity of 2,000,000 mm at 25°C. ２ The bundling protection tape according to any one of claims 1 to 3, wherein the bundling protection tape has a viscosity of 1 / s or more.

5. The binding protection tape according to any one of claims 1 to 3, wherein the content of the plasticizer in the resin composition is 38 to 60 parts by mass per 100 parts by mass of the polyvinyl chloride resin.

6. The binding protection tape according to any one of claims 1 to 3, wherein the content of the filler in the resin composition is 10 to 60 parts by mass per 100 parts by mass of the polyvinyl chloride resin.

7. The binding protection tape according to any one of claims 1 to 3, wherein the thickness of the substrate is 180 to 330 µm.

8. The binding protection tape according to any one of claims 1 to 3, wherein the tensile modulus of elasticity of the substrate converted into thickness is 5 to 9 N / mm.

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