Sterilizing combinations, mixtures and compositions, and their uses

Abstract

To provide fungicides and combinations of fungicides that are safer, have better performance, are effective over long periods of time, require lower dosages, are easier to use, and cost less, and also provide a method for treating a plant or a locus of the plant against fungal infection.SOLUTION: The present invention provides fungicidal combination comprising: (i) a predetermined amount of a compound of Formula I and (ii) a predetermined amount of at least one fungicide (A) selected from the group consisting of fluindapyr, pydiflumetofen, mefentrifluconazole, and fenpicoxamid.SELECTED DRAWING: None

Description

Technical Field

[0001] This application claims the benefit of U.S. Provisional Patent Application No. 62 / 877,180, filed Jul. 22, 2019, the entire contents of which are incorporated herein by reference. and its entire content is incorporated herein by reference.

[0002] Throughout this application, various publications are referenced. The entire disclosure of these documents is incorporated herein by reference to more fully describe the state of the art to which this invention pertains.

[0003] The present disclosure relates to a combination comprising (i) a predetermined amount of a compound of Formula I and (ii) a predetermined amount of at least one fungicide (A) selected from the group consisting of flindapyr, pydiflumetofen, mefentrifluconazole, inpyrfluxam, isofetamid, and a Qi inhibitor. The present disclosure also relates to a composition comprising the combination described herein and a method of using the combination described herein. ndapyr), pydiflumetofen, mefentrifluconazole, inpyrfluxam, isofetamid ), and at least one fungicide (A) selected from the group consisting of a Qi inhibitor. ), and at least one fungicide (A) selected from the group consisting of a Qi inhibitor. composition, and a method of using the combination described herein.

Background Art

[0004] Fungicides are compounds of natural or synthetic origin that act to protect plants from damage caused by fungi. Current agricultural practices rely heavily on the use of fungicides. In fact, some crops cannot be grown successfully without the use of fungicides. The use of fungicides allows growers to increase yields and improve the quality of their crops, thereby increasing the value of the crops. In most situations, the increase in the value of the crops is at least three times the cost of using the fungicides. Current agricultural practices rely heavily on the use of fungicides. In fact, some crops cannot be grown successfully without the use of fungicides. The use of fungicides allows growers to increase yields and improve the quality of their crops, thereby increasing the value of the crops. In most situations, the increase in the value of the crops is at least three times the cost of using the fungicides.​​

[0005] 5-Fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine- 2(1H)-ones are the pathogens of wheat leaf blight, including but not limited to Zymoseptoria tri. Including fungi of the tici (SEPTTR) class, ascomycetes, and basidiomycetes, economically important crops. It is a compound that helps control various pathogens that have adverse effects.

[0006] 5-Fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine- 2(1H)-one has both preventive and therapeutic effects.

[0007] Use of N3-substituted-N1-sulfonyl-5-fluoropyrimidinone derivatives as bactericides The use is described in U.S. Patent No. 8,263603, issued on September 11, 2012. The full contents thereof are incorporated herein by reference. 5-Fluoro-4-imino-3-meth The method for preparing ru-1-tosyl-3,4-dihydropyrimidine-2(1H)-one is as follows: U.S. Patent No. 9850215 issued on December 26, 2007 and issued on December 12, 2017 This is described in U.S. Patent No. 9840476, and the entire contents of each are referred to by the present. It will be used as reference in the detailed document.

[0008] U.S. Patent No. 8263603 also relates to N3-substitution for the control or prevention of fungal invasion. -N1-sulfonyl-5-fluoropyrimidinone derivatives and botanically acceptable carriers This document describes a disinfectant composition containing the materials, as well as a method of using it.

[0009] 5-fluoro-4-imino-3- (alkyl / substituted alkyl)-1-(arylsulfonyl)-3,4-dihydropyrimidium The use of n-2(1H)-on is described in U.S. Patent Application Publication No. 2018, published on January 4, 2018. This was stated in specification no. / 0000082.

[0010] 5-Fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine- A synergistic mixture containing 2(1H)-one and at least one bactericidal sterol biosynthesis inhibitor The joint publication is U.S. Patent No. 9,526,245 issued on December 27, 2016 and 2 It was described in U.S. Patent No. 10,045,533, issued on August 14, 2018.

[0011] 5-Fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine- A synergistic combination containing 2(1H)-one and at least one succinate dehydrogenase inhibitor The mixture is described in U.S. Patent No. 9,532,570 issued on January 3, 2017 and 20 It was described in U.S. Patent No. 10,045,534, issued on August 14, 2018.

[0012] Many fungicides are not effective in all situations, and repeated use of a single fungicide is not recommended. This often leads to the development of resistance to related fungicides. Therefore, it is safer to use It offers superior performance, is effective over a long period, requires a lower dosage, and is easy to use. Therefore, research is being conducted to manufacture low-cost fungicides and fungicide combinations. Yes, they are.

[0013] A synergistic combination including a mixture containing the compound of formula I and at least one additional fungicide. The purpose of this disclosure is to provide products, compositions, and mixtures. It is a further object of the present disclosure to provide for the use of these synergistic combinations. Summary of the Invention

[0014] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0015]

Chemical formula

[0016] The present invention also provides a mixture comprising the combination described herein.

[0017] The present invention also provides a composition comprising the combination described herein.

[0018] The present invention also provides a method for treating a plant or a location where a plant is present against fungal infection, comprising (i) a predetermined amount of a compound of formula I,

[0019]

Chemical formula

[0020] (ii) a predetermined amount of at least one fungicide (A) selected from the group consisting of fluindapyr, pydiflumetofen, mefentrifluconazole, impyrfluxam, isofetamid, and a QoI inhibitor ​​​Selected from the group consisting of npyrfluxam, isofetamide, and Qi inhibitors. at least one type of fungicide (A) Apply and thereby treat the plant or the area where the plant is located against fungal infection. We also provide methods that include this.

[0021] The present invention also relates to a method for treating a plant or a location where a plant is present against fungal infection. Then, an effective amount of any one of the combinations, mixtures, or compositions described herein, To apply to plants or the places where plants exist, thereby changing the plants or the places where plants exist We also provide methods that include treatment for fungal infections.

[0022] The present invention also provides a method for controlling plant diseases caused by plant pathogenic fungi, A plant or the location where the plant is present in an effective amount of the combination, mixture or composition described herein. The method also includes contacting the plant with one of the substances to control the plant disease. To provide.

[0023] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, as specified herein. Any one of the combinations, mixtures, or compositions described above is used on plants, seeds, seedlings, and / Alternatively, apply it to the area where the plant is present, thereby treating fungal infestation of the plant, seeds, or seedlings. The invention also provides methods that include placing or preventing the disease.

[0024] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, as specified herein. Any one of the combinations, mixtures, or compositions described above is used on plants, seeds, seedlings, and / Alternatively, apply it to the area where the plant is present to control fungal invasion of the plant, seeds, or seedlings. We also provide methods that include controlling the situation.

[0025] The present invention also relates to treating plants, seeds, or seedlings to produce plants resistant to fungal invasion. A method comprising using any one of the combinations, mixtures, or compositions described herein. Plants, seeds adapted to produce the said plants, seedlings adapted to produce the said plants , or applied to the location where the plant exists, thereby creating a plant resistant to fungal invasion. We also provide methods that include production.

[0026] The present invention also provides a method for protecting plants from fungal invasion, and the combination described herein , one of the mixture or composition is placed in the plant, the location where the plant is located, and This is applied to seeds or seedlings adapted to produce the aforementioned plants, thereby enabling the plants The method also provides protection from fungal invasion.

[0027] The present invention also provides plants resistant to fungal invasion and adapted for producing such plants. The seeds, seedlings adapted to produce the plant, or the location where the plant exists are Treatment with any one of the combinations, mixtures, or compositions described herein Yes, they are.

[0028] The present invention also relates to plant seeds adapted to produce plants resistant to fungal invasion or Seedlings are also provided, and plant seeds or seedlings are provided in combinations, mixtures or compositions as described herein. It is treated with one of the following methods.

[0029] The present invention also provides a method for controlling fungal invasion of plants, and the combination described herein , one of the mixture or composition, the place where the plant is located, the plant, roots, leaves, seeds Apply to the area where the fungus is present and / or where you want to prevent its invasion. Therefore, we also provide a method that includes controlling fungal invasion of plants.

[0030] The present invention relates to a method for controlling fungal diseases of plants and / or soil, as described herein. One of the combinations, mixtures, or compositions is used in soil, plants, roots, leaves, seeds, and fungi. Apply to the location where it is present and / or where you want to prevent intrusion, thereby protecting the plants The invention also provides methods for controlling fungal diseases in soil.

[0031] The present invention also provides a method for controlling plant diseases caused by plant pathogenic fungi, (i) A predetermined amount of a compound of formula I,

[0032] [ka] Furthermore (ii) A prescribed amount of fluindapyr, pydiflumetfen ofen), mefentrifluconazole, impulfluxam (i Selected from the group consisting of npyrfluxam, isofetamide, and Qi inhibitors. at least one type of fungicide (A) The invention also provides a method that involves contacting the plant with a plant to control plant diseases.

[0033] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, (i) A predetermined amount of the compound of formula I,

[0034] [ka] Furthermore (ii) A prescribed amount of fluindapyr, pydiflumetfen ofen), mefentrifluconazole, impulfluxam (i Selected from the group consisting of npyrfluxam, isofetamide, and Qi inhibitors. at least one type of fungicide (A) Methods are also proposed that include applying [a specific method] to control fungal invasion of plants, seeds, or seedlings. To provide.

[0035] The present invention also relates to a method for protecting plants, seeds, or seedlings from fungal invasion, and the present invention relates to a method for protecting plants, seeds , in the place where seedlings and / or plants are present, (i) a predetermined amount of the compound of formula I,

[0036] [ka] Furthermore (ii) A prescribed amount of fluindapyr, pydiflumetfen ofen), mefentrifluconazole, impulfluxam (i Selected from the group consisting of npyrfluxam, isofetamide, and Qi inhibitors. at least one type of fungicide (A) Methods are also proposed that include applying a solution to protect plants, seeds, or seedlings from fungal infections. To provide.

[0037] This invention also provides a method for treating plants or the locations where plants exist against fungal infections. The specification also provides the use of any one of the combinations, mixtures, or compositions described herein.

[0038] The present invention can also be used to treat plants or the locations where plants exist against fungal infections. The Specified Specified also provides any one of the combinations, mixtures, or compositions described herein. [Brief explanation of the drawing]

[0039] [Figure 1] This is a comparison of the area under the disease progression curve (AUDPC) obtained from infection of the first leaf of the wheat seedling cultivar Alixan with the wheat pathogen (Zymoseptoria tritici) strain Mg Tri-R6 at 21 and 28 dpi intensities, after treatment with an untreated control, and with 5 or 10 g ai / ha of the compound of formula I, 0.39 g ai / ha of mefentrifluconazole, a mixture of 0.39 g ai / ha of mefentrifluconazole and 5 g ai / ha of the compound of formula I, or a mixture of 0.39 g ai / ha of mefentrifluconazole and 10 g ai / ha of the compound of formula I. Values ​​followed by the same letter are not significantly different according to the Newman-Coils test (p<0.05). [Figure 2] This is a comparison of the area under the disease progression curve (AUDPC) obtained from infection of the first leaf of the wheat seedling cultivar Alixan with the wheat pathogen (Zymoseptoria tritici) strain Mg Tri-R6 at 21 and 28 dpi intensities, after treatment with an untreated control, and with 5 or 10 g ai / ha of the compound of formula I, 0.39 g ai / ha of fenpicoxamide, a mixture of 0.39 g ai / ha of fenpicoxamide and 5 g ai / ha of the compound of formula I, or a mixture of 0.39 g ai / ha of fenpicoxamide and 10 g ai / ha of the compound of formula I. Values ​​followed by the same letter are not significantly different according to the Newman-Coils test (p<0.05). [Figure 3]This is a comparison of the area under the disease progression curve (AUDPC) obtained from infection of the first leaf of the wheat seedling cultivar Alixan with the wheat pathogen (Zymoseptoria tritici) strain Mg Tri-R6 at 21 and 28 dpi intensities, after treatment with an untreated control, and with 5 or 10 g ai / ha of the compound of formula I, 0.39 g ai / ha of fluindapyr, a mixture of 0.39 g ai / ha of fluindapyr and 5 g ai / ha of the compound of formula I, or a mixture of 0.39 g ai / ha of fluindapyr and 10 g ai / ha of the compound of formula I. Values ​​followed by the same letter are not significantly different according to the Newman-Coils test (p<0.05). [Figure 4] Wheat pathogen (Zymoseptoria tritici) strain Mg at 21 and 28 dpi intensities on the first leaf of wheat seedling cultivar Alixan, compared to an untreated control, and after treatment with 5 or 10 g ai / ha of formula I compound, 0.00032 g ai / ha, 0.0016 g ai / ha and 0.006 g ai / ha of pydiflumetofen, a mixture of 0.00032 g ai / ha of pydiflumetofen and 5 g ai / ha of formula I compound, or a mixture of 0.0016 g ai / ha of pydiflumetofen and 5 g ai / ha of formula I compound. This is a comparison of the area under the disease progression curve (AUDPC) obtained from infections caused by Tri-R6. Values ​​with the same letter following each other are not significantly different according to the Newman-Coirs trial (p<0.05). [Modes for carrying out the invention]

[0040] definition Unless otherwise defined, all technical and scientific terms used herein are: This has meanings that are generally understood by those skilled in the art to which this subject belongs.

[0041] In this specification, the term "compound of formula I" includes, but is not limited to, all of its solid forms. Although not always the case, examples include amorphous, crystalline, solvates, or hydrates. The compound of formula I The crystal morphology is described in PCT International Patent Application Publication No. 2019 / 038583, published on February 28, 2019. The full contents of the brochure are disclosed and incorporated herein by reference. The compound of formula I also includes its salts and optical isomers.

[0042] In this specification, the term "combination" means simultaneous or concurrent (cont (Emporaneous) refers to an assembly of pesticides applied by either method. ru.

[0043] In this specification, the term “simultaneous” means, when used in relation to the application of pesticides, when the pesticides are in a mixture. This means, for example, that it is applied in a tank mix. In simultaneous application, the combination is a mixture. The pesticides that may be used or combined before application are in separate containers. It is possible.

[0044] In this specification, the term "concurrent period" is used in relation to the application of pesticides, when used in connection with the application of individual pesticides This may occur simultaneously with the action of another pesticide or pre-mixture, or with the action of either pesticide alone at the same dose. Compared to each other, an additive, or more additive, or synergistic effect is achieved. This means that they are applied separately, with enough time to allow for their application to be completed.

[0045] In this specification, the term “mixture” means any combination of any physical form, but not limited to these. This refers to, for example, blends, solutions, suspensions, dispersions, emulsions, alloys, etc.

[0046] In this specification, the term "tank mix" refers to the mixture used during or before spraying. Add one or more components of the combination, mixture, or composition of the above into a spray tank. It means to mix.

[0047] In this specification, the term “composition” means at least one combination of an agriculturally acceptable carrier This invention includes combinations or mixtures of the present invention.

[0048] In this specification, the term "effective" refers to the amount of active ingredients, combinations, mixtures, or compositions. When used in combination, apply to plants, plant propagation material, soil, or the area where plants are present. When used to achieve agriculturally beneficial levels of control over fungi, pathogens, and / or diseases This refers to the amount of a substance, combination, mixture, or composition.

[0049] In this specification, the term “bactericidally effective amount” refers to a commercially recommended amount for use in controlling fungi. This refers to the amount of the active component being used. The commercially recommended amount of each active component is large. In certain cases, the amount specified for use in commercially available preparations is indicated on the label attached to the commercially available preparation. It can be found. The commercially recommended dosage of commercially available formulations depends on the plant species and how well controlled it is It can vary depending on factors such as the type of fungus that may be involved.

[0050] In this specification, the term "effective" means that a plant or the place where a plant exists is resistant to fungal infection. When used in relation to a treatment method, the method significantly promotes the normal growth and development of the plant. To provide an agriculturally beneficial level of treatment without hindering it.

[0051] In this specification, the term "treating a plant or a location where a plant exists against fungal infection" is used. This includes, but is not limited to, plants or the places where plants exist that are susceptible to fungal infection. To protect and / or control fungal infections of plants or the places where plants exist. These are some examples.

[0052] In this specification, the term "protecting plants or the locations where plants exist from fungal infections" is used. This includes, but is not limited to, plants or the places where plants exist that are susceptible to fungal invasion. To protect, to protect plants or the places where plants exist from fungal diseases, and / or This could include preventing fungal infections in plants or the places where plants live.

[0053] In this specification, the term "controlling fungal infections of plants or the locations where plants exist" is defined as follows: , but not limited to, controlling fungal diseases that infect plants or the places where plants exist. To control plant or soil diseases caused by plant pathogenic fungi, Controlling fungal invasion of objects or plants in a place where plants or plants exist To reduce fungal infections in the area and / or those caused by plant pathogenic fungi This includes treating diseases of plants or soil.

[0054] In this specification, the term "to protect a plant or the place where a plant resides from fungal invasion" is used. "More effective" means, but is not limited to, protection against fungal invasion after application. This includes extending the duration of protection and the period of protection against fungal invasion.

[0055] In this specification, the term "more effective in controlling fungal diseases" is not limited to these. However, the effectiveness of fungal disease control increases, and in order to reach a predetermined level of fungal control... One benefit is reducing the time required.

[0056] In this specification, the term "application for protective purposes" refers to fungal infections of plants or the places where plants exist. This means the application of one or more fungicides to prevent infection, and the fungicide combination, mixture, or composition is sensitive. It is applied before infection occurs, before any symptoms appear, or when the disease is mild. The severity of the disease is based on factors related to disease development, such as spore concentration and certain environmental conditions. It can be evaluated and appreciated.

[0057] In this specification, the term "therapeutic application" refers to fungal infections of plants or the places where plants exist. This means the application of one or more fungicides to control the reaction, and the fungicide combination, mixture, or composition is sensitive. It is applied after infection or after symptoms appear.

[0058] In this specification, the term “agriculturally permissible carrier” means a composition for agricultural or horticultural use. This refers to a carrier known and permitted in the relevant art for the formation of an object.

[0059] In this specification, the term "adjuvant" refers to an ingredient that is not an active ingredient in itself, but is used in conjunction with other ingredients. Any substance intended to enhance or strengthen the effectiveness of a fungicide in a juvant Broadly defined, adjuvants are spreading agents, penetrating agents, compatibilizers, and drift retarders. It can be understood that this includes

[0060] In this specification, the term "agriculturally acceptable inactive additive" means that it is not an active ingredient in itself. However, any substance may be added to the composition, such as a binder, surfactant, synergist, or buffer. It is defined as an acidifying agent, antioxidant, antifoaming agent, and thickening agent.

[0061] In this specification, the term "plant" refers to the entire plant, or plant organs (e.g., leaves, stems, twigs, roots, trunks). This includes references to plant cells and plant reproductive materials (such as large branches, buds, and fruits).

[0062] In this specification, the term "plant" refers to field crops (soybeans, maize, wheat, rice, etc.), vegetables. References to agricultural products, including vegetables (potatoes, cabbage, etc.) and fruits (peaches, etc.) include.

[0063] In this specification, the term "propagation material" refers to seeds and spores, etc. All reproductive parts of a plant, seedlings, as well as bulbs, corms, tubers, rhizomes, roots, stems, and basal shoots. It should be understood that these exhibit growth structures such as shoots, creeping stems, and buds.

[0064] In this specification, the term "location" refers not only to areas where fungal infection may already be present, but also to areas where fungal infection may be present. This includes areas where dyeing has not yet been demonstrated and areas under cultivation. Location is not limited to these areas. Examples of suitable growing media include soil and other plant growing media.

[0065] In this specification, the term "ha" refers to a hectare.

[0066] In this specification, the term “excipient” refers to a significant substance such as a surfactant, solvent, or adjuvant. This refers to any chemical substance that does not possess insecticidal activity. One or more excipients are disclosed herein. It can be added to any combination, mixture, or composition.

[0067] In this specification, the term "stabilized surfactant" refers to a liquid combination or mixture containing a compound of formula I. When added to a substance or composition, the physical and / or chemical stability of the compound of formula I. Defined as any surfactant that improves [something]. In some embodiments, stabilizing surfactant The agent is effective in inhibiting crystal growth.

[0068] The terms “one (a)” or “one (an)” are not specifically defined herein. This includes both singular and plural forms. Therefore, the terms "one (a)" and "one (an)" are used. ) or “at least one” may be used interchangeably in this application.

[0069] Throughout this application, the description of various embodiments uses the term "comprising". Although it is used, in some specific circumstances the embodiment becomes essentially from (consisting The phrases "essentially of" or "consisting of" are used to describe the situation. Those skilled in the art will understand that this is possible.

[0070] The term "approximately" in this specification specifically includes ±10% of the values ​​shown within the range. Furthermore, both ends of the entire scope covering the same component or characteristic in this specification are inclusive of both ends. They can be combined independently and include all intermediate points and ranges.

[0071] If a parameter range is provided, all integers within that range and their first decimal place The number of decimal places is also as if the number of integers and their first decimal place were clearly stated herein. As provided by the present invention, for example, "5g / ha~120g / ha ” is 5.0g / ha, 5.1g / ha, 5.2g / ha, 5.3g / ha, 5.4g / Includes up to 120g / ha from hectares, etc.

[0072] All publications, patents, and patent applications described herein are as if they were each Whether individual publications, patents, or patent applications are specifically and individually invoked by reference. To the same extent as indicated above, the entirety of these references is incorporated herein by reference.

[0073] The following examples illustrate the implementation of the subject matter in some embodiments, but the scope of the subject matter is limited. It should not be interpreted as restrictive, in the spirit and scope of the attached claims. Given that the specification and examples described herein constitute part of the present invention, other embodiments may be considered part of the present invention. This is obvious to the user. This specification, including the examples, does not limit the scope and spirit of the invention. It is intended to be illustrative only.

[0074] Aspects and embodiments of the present invention are described herein.

[0075] Sterilizing combinations, mixtures, and compositions The present invention relates to (i) a predetermined amount of a compound of formula I,

[0076] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from We provide a sterilization combination containing the following.

[0077] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0078] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from We provide a synergistic sterilization combination containing [the specified ingredient].

[0079] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0080] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, The combination is used in the treatment of plants or the locations where plants are present against fungal infections, with each fungicide being used. It is more effective than when applied alone in the same amount. We provide a combination of sterilization products.

[0081] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0082] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, When the predetermined amount of the compound of formula I and the predetermined amount of the disinfectant (A) are applied together, In the treatment of plants or areas where plants are present for fungal infections, each fungicide is used individually in equal amounts. It is more effective than when applied. We provide a combination of sterilization products.

[0083] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0084] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, The amount of compound I used determines the bactericidal effect of the compound I when used alone. Less than the effective amount, and / or The amount of disinfectant (A) used, and the amount of disinfectant (A) used when disinfectant (A) is used alone. Less than the effective amount We provide a combination of sterilization products.

[0085] In some embodiments, the combination is synergistic.

[0086] In some embodiments, the combination is a mixture. In some embodiments, the mixture is stored in a tank. It is a mix. In some embodiments, the mixture is synergistic.

[0087] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0088] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from We provide a sterilization combination containing the following.

[0089] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0090] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from We provide a synergistic sterilization combination containing [the specified ingredient].

[0091] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0092] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, The mixture is used in the treatment of plants or the locations where plants are present against fungal infections, with each fungicide being It is more effective than when applied alone in the same amount. We provide a mixture of fungicides.

[0093] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0094] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, When a predetermined amount of compound I and a predetermined amount of fungicide (A) are applied together, fungal infection In the treatment of plants or the places where plants are present, each fungicide is applied individually in equal amounts. It is more effective than the case where We provide a mixture of fungicides.

[0095] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0096] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A sterilization combination including, The amount of compound I used determines the bactericidal effect of the compound I when used alone. Less than the effective amount, and / or The amount of disinfectant (A) used, and the amount of disinfectant (A) used when disinfectant (A) is used alone. Less than the effective amount We provide a mixture of fungicides.

[0097] The present invention also includes sterilization comprising any one of the combinations or mixtures disclosed herein. We also provide formulations.

[0098] In this specification, the compound of formula I is defined as 5-fluoro-4-imino-3-methyl-1-tosyl It is -3,4-dihydropyrimidine-2(1H)-one and has the following structure:

[0099] [ka]

[0100] In this specification, fluindapyr is defined as 3-(difluoromethyl)-N-( 7-Fluoro-2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl The generic name for )-1-methyl-1H-pyrazole-4-carboxamide is the following structure. To possess:

[0101] [ka]

[0102] Fluindapyr is a succinate dehydrogenase inhibitor (SDHI). ru.

[0103] In this specification, pydiflumetofen is defined as 3-(difluoromethyl) -N-methoxy-1-methyl-N-[(2S)-1-(2,4,6-trichlorophenyl The generic name for )propan-2-yl]-1H-pyrazole-4-carboxamide is as follows: It has the following structure:

[0104] [ka]

[0105] Pydiflumetofen is a succinate dehydrogenase inhibitor (SDH). I) It is a fungicide used on soybeans, grains, vegetables, corn, peanuts, and melons (curcubit s), potatoes, fruit trees (top fruit), grapes, melons, and yams, udon Powdery mildew (Uncinula necator), Septoria leaf spot ), Cercospora leaf spot, Alternaria leaf spot, scab ( Venturia inaequalis, and grey mold It is used to protect against gray mold (Botrytis cinerea).

[0106] In this specification, mefentrifluconazole is defined as 2-[4- (4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1,2,4 -Triazole-1-yl)propan-2-ol is the generic name and has the following structure. :

[0107] [ka]

[0108] Mefentrifluconazole is a sterol biosynthesis inhibitor. Demethylation inhibitors are fungicides used for grains against wheat leaf blight fungus (Septoria tritici). It is used in contrast to.

[0109] In this specification, fenpicoxamide is (3S, 6S, 7R, 8R) -8-benzyl-3-{3-[(isobutyryloxy)methoxy]-4-methoxypyridyl n-2-carboxamide}-6-methyl-4,9-dioxo-1,5-dioxonane-7 -Il-isobutyrate is the common name and has the following structure:

[0110] [ka]

[0111] Fenpicoxamide is a Qi inhibitor fungicide that targets wheat pathogens (Zy). It is used for *Moseptoria tritici*.

[0112] In this specification, inpyrfluxam is defined as 3-(difluoromethyl)- N-[(R)-2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl ]-1-methyl-1H-pyrazole-4-carboxamide is the generic name, and has the following structure To possess:

[0113] [ka]

[0114] Inpyrfluxam is a succinate dehydrogenase inhibitor (SDHI). )

[0115] In this specification, isofetamide is defined as N-[1,1-dimethyl-2-(4 -Isopropoxy-o-tolyl)-2-oxoethyl]-3-methylthiophene-2-ca The generic name for ruboxamide is the following structure:

[0116] [ka]

[0117] Isofetamid is a succinate dehydrogenase inhibitor (SDHI). ru.

[0118] In some embodiments, the compounds of formula I may be amorphous, crystalline, or solvent-based, but are not limited to these. This refers to any solid form, including dihydrates or hydrates. The crystalline form of the compound of formula I is shown in the reference. The entire content of this document is referenced in PCT International Application Publication No. 2, published on February 28, 2019. It is listed in issue 019 / 038583.

[0119] In some embodiments, the fungicide (A) is fluindapyru.

[0120] In some embodiments, the bactericide (A) is pidflumetofen.

[0121] In some embodiments, the bactericide (A) is mefentrifluconazole.

[0122] In some embodiments, the bactericide (A) is isofetamide.

[0123] In some embodiments, the fungicide (A) is impulfluxam.

[0124] In some embodiments, the bactericide (A) is a Qi inhibitor.

[0125] In some embodiments, the Qi inhibitor is cyazoimidazole. In some embodiments, Cyazoimidazole is cyazofamide.

[0126] In some embodiments, the Qi inhibitor is sulfamoyltriazole. In this context, sulfamoyltriazole is amisulbrom.

[0127] In some embodiments, the Qi inhibitor is a picocolinamide. Phosphate amide is fenpicoxamide.

[0128] In some embodiments, a compound of formula I in a combination, mixture, or composition and a bactericide (A) The weight ratio is 400:1 to 1:100. In some embodiments, combinations and mixtures are used. Alternatively, the weight ratio of the compound of formula I to the bactericide (A) in the composition is 200:1 to 1:100. Yes. In some embodiments, a compound of formula I in a combination, mixture, or composition and a bactericide ( The weight ratio with A) is 50:1 to 1:50. In some embodiments, combinations and mixtures are used. Alternatively, the weight ratio of the compound of formula I to the bactericide (A) in the composition is 10:1 to 1:10. In some embodiments, a compound of formula I in a combination, mixture, or composition and a bactericide (A) The weight ratio is 5:1 to 1:5. In some embodiments, combinations, mixtures or combinations are used. The weight ratio of the compound of formula I to the fungicide (A) in the product is 2:1 to 1:2. In terms of form, the weight ratio of the compound of formula I to the bactericide (A) in a combination, mixture, or composition is The ratio is 5:1 to 30:1. In some embodiments, the formula in the combination, mixture or composition is used. The weight ratio of compound I to fungicide (A) is 10:1 to 30:1. In some embodiments, The weight ratio of the compound of formula I to the bactericide (A) in the combination, mixture, or composition is 25 The ratio is 1 to 12.5. In some embodiments, the formula in the combination, mixture or composition is 1. The weight ratio of compound I to bactericide (A) is 25:1. In some embodiments, combination The weight ratio of the compound of formula I to the bactericide (A) in a substance, mixture, or composition is 12.5:1. Yes. In some embodiments, a compound of formula I in a combination, mixture, or composition and a bactericide ( The weight ratio with A) is 1:1.

[0129] In some embodiments, the combination, mixture, or composition is synergistic. In terms of form, it may be a combination, mixture, or composition, or a plant or organism present against a fungal infection. It has a synergistic effect on the treatment of the place where it is performed. In some embodiments, a combination, mixture, or combination The product has a synergistic therapeutic effect. In some embodiments, it is a combination, mixture, or composition. The objects have a synergistic protective effect.

[0130] In some embodiments of the combinations, mixtures, or compositions described herein, the bactericidal effect In protective and / or therapeutic applications, it is synergistic with SEPTTR. The weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 200:1 to 1:200. ru.

[0131] In some embodiments of the combinations, mixtures, or compositions described herein, the bactericidal effect In protective and / or therapeutic applications, it is synergistic with SEPTTR. The weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 100:1 to 1:100. ru.

[0132] In some embodiments of the combinations, mixtures, or compositions described herein, the bactericidal effect In protective and / or therapeutic applications, it is synergistic with SEPTTR. The weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 50:1 to 1:50.

[0133] In some embodiments of the combinations, mixtures, or compositions described herein, the bactericidal effect In protective and / or therapeutic applications, it is synergistic with SEPTTR. The weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 10:1 to 1:10.

[0134] In some embodiments of the combinations, mixtures, or compositions described herein, the bactericidal effect In protective and / or therapeutic applications, it is synergistic with SEPTTR. Furthermore, the weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 5:1 to 1:1.

[0135] In some embodiments, SEPTTR is the wheat pathogen (Zymoseptoria tritici).

[0136] In some embodiments, the bactericidal effect of compound I is synergistic in protective applications. The weight ratio of the fungicide (A) is in the range of approximately 400:1 to 1:400. In this state, the bactericidal effect is synergistic in applications for protective purposes, and the compound of formula I and the bactericide (A) The weight ratio is in the range of approximately 200:1 to 1:200. In some embodiments, the bactericidal effect The weight ratio of the compound of formula I to the fungicide (A) is such that the effect is synergistic in protective applications. The ratio is within the range of approximately 100:1 to 1:100. In some embodiments, the sterilization effect is for protective purposes. The weight ratio of the compound of formula I to the fungicide (A), which is synergistic in application, is approximately 50:1 to 1 : is within the range of 50. In some embodiments, the bactericidal effect is in the application of the bactericide for protective purposes. The weight ratio of the compound of formula I that is synergistic with (A) is in the range of approximately 10:1 to 1:10. In some embodiments, the bactericidal effect is synergistic in applications for protective purposes, and the compound of formula I The weight ratio with fungicide (A) is in the range of approximately 5:1 to 1:5. In some embodiments, The weight ratio of compound I to bactericide (A) in which the bactericidal effect is synergistic in protective applications. The ratio is within the range of approximately 2:1 to 1:2. In some embodiments, the bactericidal effect is applied for protective purposes. The weight ratio of the compound of formula I to the fungicide (A), which is synergistic in this case, is approximately 25:1. In some embodiments, the bactericidal effect is synergistic in applications for protective purposes, and the compound of formula I The weight ratio of the disinfectant (A) is approximately 12.5:1. In some embodiments, the bactericidal effect is maintained. The weight ratio of compound I to fungicide (A), which is synergistic in protective applications, is approximately 1: It is 1.

[0137] In some embodiments, the bactericidal effect of compound I is synergistic in therapeutic applications. The weight ratio of the fungicide (A) is in the range of approximately 400:1 to 1:400. In this state, the bactericidal effect is synergistic in therapeutic applications of the compound of formula I and the bactericide (A). The weight ratio is in the range of approximately 200:1 to 1:200. In some embodiments, the bactericidal effect The weight ratio of the compound of formula I to the bactericide (A) that is synergistic in therapeutic application is: The ratio is within the range of approximately 100:1 to 1:100. In some embodiments, the bactericidal effect is for therapeutic purposes. The weight ratio of the compound of formula I to the fungicide (A), which is synergistic in application, is approximately 50:1 to 1 It is within the range of :50. In some embodiments, the bactericidal effect is synergistic in therapeutic applications. The weight ratio of the compound of formula I to the fungicide (A) is in the range of approximately 10:1 to 1:10. In some embodiments, the bactericidal effect of the compound of formula I is synergistic in therapeutic applications. The weight ratio of the substance to the disinfectant (A) is in the range of approximately 5:1 to 1:5. In some embodiments, The compound of formula I and the bactericide (A) exhibits a synergistic bactericidal effect when applied for therapeutic purposes. The ratio is in the range of approximately 2:1 to 1:2. In some embodiments, the bactericidal effect is for therapeutic purposes. The weight ratio of the compound of formula I to the fungicide (A), which is synergistic in application, is approximately 25:1. In some embodiments, the bactericidal effect of the compound of formula I is synergistic in therapeutic applications. The weight ratio of the substance to the disinfectant (A) is approximately 12.5:1. In some embodiments, the disinfectant effect The weight ratio of the compound of formula I to the bactericide (A), which is synergistic in therapeutic applications, is approximately The ratio is 1:1.

[0138] In some embodiments, the combination, mixture, or composition further comprises at least one pesticidal agent ..

[0139] In some embodiments, the combination, mixture, or composition comprises at least one stabilizing surfactant. In some embodiments, the combination, mixture, or composition comprises at least two stabilizing surfactants. In some embodiments, the combination, mixture, or composition comprises two stabilizing surfactants. In some embodiments, the combination, mixture, or comp osition comprises a stabilizing system

[0140] In some embodiments, one of the stabilizing surfactants is a nonionic stabilizing surfactant . In some embodiments, the nonionic stabilizing surfactant is selected from the group consisting of polymers, esters of alkoxylated diethylethanolamine, polyalkylene oxide alcohol ethers, and alcohols

[0141] In some embodiments, the polymer is a block polymer of a random polymer. Some embodiments, the polymer is a triblock polymer. In some embodiments, the tri block polymer is an ABA block polymer. In some embodiments, the polymer has a low HLB (hydrophilic-lipophilic balance) value, preferably an HLB value of 5. Some embodiments, the polymer is Atlox™ 4912 (manufactured and sold by Croda) .

[0142] In some embodiments, the ester of alkoxylated amine is Atlox™ 491 5 alkoxylated diethylethanolamine, diethylethanolamine monotrimellate Tor, or Altox (trademark) 4915 (manufactured and sold by Croda) is.

[0143] In some embodiments, the alkoxylated fatty alcohol is Genapol X080 ( manufactured and sold by Clariant), Genapol X050 (Cl ariant), tridecyl alcohol polyglycol ether, Rhodasurf LA30 (manufactured and sold by Solvay ), Aerosol OT-SE or Aerosol OT-100 (Solvay ), Rhodacal 70 / B (manufactured and sold by Solvay ), Arlatone TV (manufactured and sold by Croda ), Alkamuls A (manufactured and sold by Solvay ), or Alkamuls BR (manufactured and sold by Solvay). is.

[0144] In some embodiments, the alcohol has a short carbon chain of C1 - C6. In some embodiments the alcohol has a long carbon chain of C7 - C20.

[0145] In some embodiments, the nonionic stabilizing surfactant is a nonionic derivative of polyalkylene oxide poly reel ether.

[0146] In some embodiments, one of the stabilizing surfactants is an ionic surfactant. In some embodiments, the ionic stabilizing surfactant is an anionic stabilizing surfactant. The anionic stabilizing surfactant is a compound having anionic groups such as phosphonates and sulfonates This refers to [a specific type of ionic surfactant]. An example of an ionic surfactant that can be used is Aerosol® OT-SE. Sodium dioctyl sulfosuccinate, manufactured and sold by Solvay, is used as a product. It is Mu.

[0147] In some embodiments, the anionic stabilizing surfactant is polyalkylene oxide polyaryl It is an anionic derivative of an ether.

[0148] In some embodiments, the combination, mixture, or composition contains at least one nonionic compound, mixture, or composition. It contains a property-stabilizing surfactant and at least one anionic-stabilizing surfactant. In the application form, the stabilization system consists of at least one nonionic stabilizing surfactant and at least It also contains one type of anionic stabilizing surfactant.

[0149] In some embodiments, nonionic stabilizing surfactants and anionic stabilizing surfactants are used. The combination, mixture, or composition containing the product is an SC composition. In some embodiments, non-io Combinations, mixtures, or The composition is an SE composition.

[0150] In some embodiments, one of the stabilizing surfactants is polyalkylene oxide polyaryl It is a derivative of the ether. In some embodiments, it is a polyalkylene oxide polyaryl. Ether derivatives are nonionic derivatives of polyalkylene oxide polyaryl ethers. In some embodiments, polyalkylene oxide polyaryl ether surfactants are used. The derivatives are anionic derivatives of polyalkylene oxide polyaryl ethers.

[0151] In some embodiments, the combination, mixture, or composition comprises at least two stabilizing surfactants. In some embodiments, the two stabilizing surfactants comprise two derivatives of polyalkylene oxide polyaryl ether. In some embodiments, the two stabilizing surfactants comprise a nonionic derivative of polyalkylene oxide polyaryl ether and an anionic derivative of polyalkylene oxide polyaryl ether.

[0152] In some embodiments, the nonionic derivative of polyalkylene oxide polyaryl ether is a compound having an aryl group substituted with at least two aromatic groups.

[0153] In some embodiments, the nonionic derivative of polyalkylene oxide polyaryl ether has the following structure:

[0154]

Chemical formula

[0155] In some embodiments, the nonionic derivative of polyalkylene oxide polyaryl ether has the following structure:

[0156]

Chemical formula

[0157] In some embodiments, the anionic derivative of polyalkylene oxide polyaryl ether is a compound having an aryl group substituted with at least two aromatic groups.

[0158] In some embodiments, the anionic derivative of polyalkylene oxide polyaryl ether The anionic group is phosphate (PO4), phosphonate (PO3), sulfonate (S It has an anionic group selected from O3 and sulfate (SO4).

[0159] Polyalkylene oxides include, but are not limited to, polyethylene oxide groups, poly This may include propylene oxide, polybutylene oxide, and any combination thereof. In some embodiments, the polyalkylene oxide group is polyethylene oxide. In this embodiment, the polyalkylene oxide group is polypropylene oxide.

[0160] Polyalkylene oxides include, but are not limited to, copolymers and homogeneous polymers. Copolymers may include, but are not limited to, random polymers and block polymers. It may contain a polyalkylene polymer. In some embodiments, the polyalkylene oxide group is dibro It is a triblock copolymer. In some embodiments, the polyalkylene oxide group is triblock. It is a copolymer.

[0161] In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide dostyrylphenyl ether. In some embodiments, polyalkylene oxide Side polyaryl ethers are polyalkylene oxide benzylphenyl ethers. In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide bisphenyl ether. In some embodiments, polyalkylene oxide Polyaryl ethers are polyalkylene oxide tristyrylphenyl ethers. In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide distylylphenyl ether. In some embodiments, polyalkylene Hxidodistyrylphenyl ether is polyoxyethylene distyrylphenyl ether That is the case.

[0162] In some embodiments, polyalkylene oxide polyaryl ethers are anion-stabilized. These are surfactants. Anionic stabilized surfactants include phosphonates and sulfonates. This refers to compounds that have an anionic group.

[0163] In some embodiments, the salt contains a cation. In some embodiments, the cation is sodium From um, potassium, ammonium, calcium, magnesium, and combinations thereof. Selected from the group.

[0164] In some embodiments, anionic derivatives of polyalkylene oxide polyaryl ethers The structure is as follows:

[0165] [ka] It has.

[0166] In some embodiments, anionic derivatives of polyalkylene oxide polyaryl ethers It is tristyrylphenol ethoxylate phosphate ester.

[0167] In some embodiments, polyalkylene oxide polyaryl ether is tristyryl It is a phenol ethoxylate phosphate ester. Preferably, tristyrylphenol Ethoxylate phosphate esters are manufactured and sold by Solvay. oprophor(registered trademark)3D33.

[0168] In some embodiments, the polyalkylene oxide polyaryl ether has 54EO This is 2,4,6-tri-(1-phenylethyl)phenol polyglycol ether. Preferably, 2,4,6-tri-(1-phenylethyl)pheno having 54EO. Polyglycol ether is manufactured and sold by Clariant. This is mulsogen(registered trademark) TS540.

[0169] In some embodiments, polyalkylene oxide polyaryl ethers are ethoxylated. It is tristyrylphenol. Preferably, ethoxylated tristyrylphenol is Soprophor® TS / 5, manufactured and sold by Solvay. The answer is 4.

[0170] In some embodiments, the salt is sodium, potassium, ammonium, calcium, magnesium It contains cations selected from the group consisting of nesium and combinations thereof.

[0171] Polyalkylene oxide polyaryl ether surfactants are not limited to these, but It may also contain polyphenylethylphenol and tristyrylphenol.

[0172] Polyalkylene oxide polyaryl ether surfactants are not limited to these, but Including uncapped surfactants, trailing capped surfactants, or combinations thereof That's good too.

[0173] In some embodiments, a combination, mixture, or composition of two or more stabilized surfactants is used. It contains two stabilizing surfactants, nonionic polyalkylene oxide polyaryl ester. With methyl surfactants and anionic polyalkylene oxide polyaryl ether surfactants Yes. In some embodiments, the nonionic surfactant is tristyrylphenol ethoxyle In some embodiments, the anionic surfactant is tristyrylphenol ethoxyphosphate. It is a silate phosphate ether.

[0174] In some embodiments, the combination, mixture, or composition is tristyrylphenol. Includes toxylates and tristyrylphenol ethoxylate phosphate ethers. .

[0175] In some embodiments, nonionic polyalkylene oxide polyaryl ethers are aromatic It is a compound having an ether group substituted with at least two groups, including a fragrant ring.

[0176] In some embodiments, the polyalkylene oxide group is polyoxyethylene. In some embodiments, the polyalkylene oxide group is polyoxypropylene. In this state, the polyalkylene oxide group is a block copolymer of polyoxyethylene. In some embodiments, the polyalkylene oxide group blocks the polyoxypropylene. It is a copolymer.

[0177] Polyalkylene oxides include, but are not limited to, polyethoxylated groups, polypropylene The material may contain propylene glycol groups, polybutoxylated groups, and any combination thereof.

[0178] Polyalkylene oxides include, but are not limited to, copolymers and homogeneous polymers. It may include.

[0179] Copolymers include, but are not limited to, random polymers and block polymers. It may be included.

[0180] In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide tristyrylphenyl ether. In some embodiments, polyalkylene Oxidotristyrylphenyl ether is polyoxyethylene tristyrylphenyl ether It is a methyl group. In some embodiments, polyalkylene oxide tristyrenephenyl ether Tel is polyoxyethylene polyoxypropylene ristyrylphenyl ether. .

[0181] In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide distylylphenyl ether. In some embodiments, polyalkylene Hxidodistyrylphenyl ether is polyoxyethylene distyrylphenyl ether That is the case.

[0182] In some embodiments, nonionic derivation of polyalkylene oxide polyaryl ethers The substance is tristyrylphenol ethoxylate phosphate ester.

[0183] In some embodiments, the stabilizing surfactant is tristyrylphenol polyethyleneglycon It is a derivative of coal ether.

[0184] In some embodiments, the stabilizing surfactant is tristyrylphenol polyethyleneglycon It is an anionic derivative of a coal ether.

[0185] In some embodiments, the stabilizing surfactant is tristyrylphenol polyethyleneglycon It is a nonionic derivative of coal ether.

[0186] In some embodiments, the combination, mixture, or composition contains two stabilizing surfactants. Furthermore, the two types of stabilizing surfactants are Sopropphor 3D33 and Sopropphor It is r TS / 54 (TSP54).

[0187] In some embodiments, the combination, mixture, or composition contains two stabilizing surfactants. Both stabilizing surfactants are derivatives of polyalkylene oxide polyaryl ethers. In some embodiments, the combination, mixture, or composition consists of two stabilizing interfaces. It contains a stabilizing agent, and the stabilizing surfactant is a non-polyalkylene oxide polyaryl ether. It is an ionic derivative, and the stabilizing surfactant is polyalkylene oxide polyaryl ether It is an anionic derivative of ru.

[0188] In some embodiments, the combination, mixture, or composition contains at least two stabilizing interfaces. The surfactant is included, and at least one stabilizing surfactant is polyalkylene oxide polyary It is a nonionic derivative of ether, and at least one stabilizing surfactant is polyalkyl It is an anionic derivative of a ylene oxide polyaryl ether.

[0189] In some embodiments, the combination, mixture, or composition contains two stabilizing surfactants. Furthermore, one stabilizing surfactant is a nonionic induced polyalkylene oxide polyaryl ether. It is a conductor, and the stabilizing surfactant is polyalkylene oxide polyaryl ether. It is an ON derivative.

[0190] In some embodiments, the stabilizing surfactant is Soprophor 3D33.

[0191] In some embodiments, the stabilizing surfactant is tristyrylphenol ethoxylate rin. It is an acid ester.

[0192] In some embodiments, polyalkylene oxide polyaryl ether is Solvay This is a Soprophor 3D33 manufactured by the company.

[0193] In some embodiments, polyalkylene oxide polyaryl ether is Claria This is an Emulsogen TS540 manufactured by NT Corporation.

[0194] In some embodiments, polyalkylene oxide polyaryl ether is Solvay This is a Soprophor TS / 54 manufactured by the company.

[0195] In some embodiments, the cation-containing salt is sodium, potassium, ammonium, and ka It is selected from the group consisting of calcium, magnesium, and combinations thereof.

[0196] Polyaryls include, but are not limited to, polyphenylethylphenol and triglycerides. It may refer to styrylphenol.

[0197] Polyalkylene oxide polyaryl ether surfactants are uncapped surfactants. This refers to a rear-end capped surfactant or a combination thereof.

[0198] In some embodiments, the surfactant combination is a nonionic polyalkylene oxide poly Aryl ether surfactants and anionic polyalkylene oxide polyaryl ethers It includes a mixture with a surfactant. In some embodiments, the nonionic surfactant is tristil It is a triphenol ethoxylate. In some embodiments, the anionic surfactant is tri It is a styrylphenol ethoxylate phosphate ether.

[0199] In some embodiments, the surfactant combination is tristyrylphenol ethoxylate and includes tristyrylphenol ethoxylate phosphate ether.

[0200] In some embodiments, nonionic polyalkylene oxide polyaryl ethers are aromatic It is a compound having an ether group substituted with at least two groups, including a fragrant ring.

[0201] In some embodiments, the polyalkylene oxide group is polyoxyethylene. In some embodiments, the polyalkylene oxide group is polyoxypropylene. In this state, the polyalkylene oxide group is a block copolymer of polyoxyethylene. In some embodiments, the polyalkylene oxide group blocks the polyoxypropylene. It is a copolymer.

[0202] Polyalkylene oxides include, but are not limited to, polyethoxylated groups, polypropylene The material may contain propylene glycol groups, polybutoxylated groups, and any combination thereof.

[0203] Polyalkylene oxides include, but are not limited to, copolymers and homogeneous polymers. It may include.

[0204] Copolymers include, but are not limited to, random polymers and block polymers. It may be included.

[0205] In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide tristyrylphenyl ether. In some embodiments, polyalkylene Oxidotristyrylphenyl ether is polyoxyethylene tristyrylphenyl ether It is a methyl group. In some embodiments, polyalkylene oxide tristyrenephenyl ether Tel is polyoxyethylene polyoxypropylene ristyrylphenyl ether. .

[0206] In some embodiments, polyalkylene oxide polyaryl ether is polyalkylene It is an oxide distylylphenyl ether. In some embodiments, polyalkylene Hxidodistyrylphenyl ether is polyoxyethylene distyrylphenyl ether That is the case.

[0207] In some embodiments, nonionic derivation of polyalkylene oxide polyaryl ethers The substance is tristyrylphenol ethoxylate phosphate ester.

[0208] In some embodiments, the stabilizing surfactant is Emulsogen TS540.

[0209] In some embodiments, the nonionic derivative of the surfactant is Emulsogen TS5 It is 40.

[0210] In some embodiments, the stabilizing surfactant is Soprophor TS / 54.

[0211] In some embodiments, nonionic derivation of polyalkylene oxide polyaryl ethers The body is Soprophor TS / 54.

[0212] In some embodiments, the stabilizing surfactant is tristyrylphenol polyethyleneglycon It is an anionic derivative of a coal ether.

[0213] In some embodiments, the stabilizing surfactant is tristyrylphenol polyethyleneglycon It is a nonionic derivative of coal ether.

[0214] In some embodiments, the combination, mixture, or composition includes a stabilizing system.

[0215] In some embodiments, a compound of formula I and a polyalkylene oxide polyaryl ether The weight ratio with the nonionic derivative is 25:1 to 10:1. In some embodiments, Formula I The weight ratio of the compound to the anionic derivative of polyalkylene oxide polyaryl ether is The ratio is 25:1 to 10:1.

[0216] In some embodiments, the combination, mixture, or composition is a botanically acceptable aji. It also includes uvant.

[0217] In some embodiments, botanically acceptable adjuvants are (i) Polyalkylene oxide alkyl ether, (ii) Siloxane polyalkylene oxide copolymer, (iii) Fatty acid esters, (iv) vinylpyrrolidone and its derivatives, (v) Glycosamines It is selected from the group consisting of the following.

[0218] In some embodiments, the polyalkylene oxide alkyl ether is a polyalkoxyl It is a chemical alcohol.

[0219] In some embodiments, the alkyl in polyalkylene oxide alkyl ether is used to It is not limited to, but includes carbohydrate chains containing C1-C26.

[0220] In some embodiments, the alcohol of the polyalkoxylated alcohol is not limited to this. It does not contain any carbohydrate chains, but it does contain carbohydrate chains C1-C26.

[0221] In some embodiments, the alkyl of the polyalkylene oxide alkyl ether is these This includes, but is not limited to, short and long carbohydrate chains.

[0222] Carbohydrate chains are not limited to these, but include saturated chains, unsaturated chains, branched chains, and unbranched chains. It is possible to point to it.

[0223] In some embodiments, the short chain refers to C1-C8. In some embodiments, the long chain refers to C9-C8. It refers to 26.

[0224] In some embodiments, polyalkylene oxides are, but are not limited to, polyethyl Polyethylene oxide, polypropylene oxide, polybutylene oxide, or combinations thereof. It refers to.

[0225] In some embodiments, polyalkylene oxides are copolymers, but are not limited to polyalkylene oxides. It includes. Copolymers include blocks such as polyethylene oxide-polypropylene oxide. Copolymers, and / or random copolymers such as ethylene oxide-propylene oxide This refers to a rimer. In some embodiments, the polyalkylene oxide block copolymer is a di It is a block copolymer. In some embodiments, it is a polyalkylene oxide block copolymer. Remer is a triblock copolymer.

[0226] In some embodiments, the triblock copolymer is polyethylene oxide / polypropylene It is a ylene oxide / polyethylene oxide.

[0227] In some embodiments, the polyalkylene oxide alkyl ether has an alkyl trailing cap. It is pped. In some embodiments, alkyl is, but is not limited to, short carbonation Includes monocellular and long carbohydrate chains. Carbohydrate chains are not limited to these, but include saturated and non-saturated chains. This can refer to saturated chains, branched chains, and unbranched chains. In some embodiments, short chains refer to C1-C8. vinegar.

[0228] In some embodiments, the polyalkylene oxide alkyl ether is isotridecyl It is glycol polyglycol ether.

[0229] In some embodiments, the polyalkylene oxide alkyl ether is C16-C18 It is an ethanol ethoxylate propoxylate ether.

[0230] In some embodiments, C16-C18 alcohol ethoxylate propoxylate Tel is manufactured and sold by Akzo Nobel Agrochemicals. It is Ethylan 995. In some embodiments, C16-C18 alcohols. Ethoxylate propoxylate ethers are manufactured and sold by BASF. This is Agnique(registered trademark) BP420.

[0231] In some embodiments, the polyalkylene oxide alkyl ether is ethoxylate It is a propyl alcohol.

[0232] In some embodiments, ethoxylated propoxylate alcohols are produced by Croda. The Synperonic 13 / 9 is manufactured and sold by [company name missing]. In some embodiments, Ethoxylate propoxylate alcohol is manufactured and sold by Croda. This is the Atplus PFA.

[0233] In some embodiments, the polyalkylene oxide alkyl ether is isotridecyl It is glycol polyglycol ether.

[0234] In some embodiments, isotridecyl alcohol polyglycol ether is Clar This is Genapol X80, manufactured and sold by Iant. In this context, isotridecyl alcohol polyglycol ether is manufactured by BASF. It is Trycol (registered trademark) and is sold commercially.

[0235] In some embodiments, the polyalkylene oxide alkyl ether provides surface tension to the composition. This is effective in reducing surface tension and improving the diffusion of the compound of formula I on plant leaves. This reduction leads to a reduction in drift from the leaves.

[0236] In some embodiments, the siloxane polyalkylene oxide copolymer is an organically modified to This refers to siloxane.

[0237] In some embodiments, the siloxane polyalkylene oxide copolymer is Evonik This is Break Thru S233 manufactured by the company. In some embodiments, siloxane polya Lukilen oxide copolymer is Silwett 077 manufactured by Momentive. ru.

[0238] In some embodiments, siloxane polyalkylene oxide copolymer is a combination, mixture It is effective in reducing the surface tension of mixtures or compositions. Silicone surfactants are effective in reducing surface tension. Reduced surface tension and rapid spreading of combinations, mixtures, or compositions across the entire lipophilic surface. It was found to be an effective auxiliary agent for powdered medicine.

[0239] In some embodiments, fatty acid esters are, but are not limited to, alkyl fatty acids. It may also contain esters and vegetable oils.

[0240] In some embodiments, the alkyl ester comprises a carbohydrate chain containing C10-C20.

[0241] In some embodiments, the alkyl group includes, but is not limited to, a short carbohydrate chain.

[0242] Carbohydrate chains are not limited to these, but include saturated chains, unsaturated chains, branched chains, and unbranched chains. It is possible to point to it.

[0243] In some embodiments, the short chain refers to C1-C8. Ester is Rhodaphac PA / 23 (ethoxylated lipids) manufactured by Solvay. (phosphate ester of ethanol) or Alkamuls VO / 200 manufactured by Solvay 3 (ethoxylated (18EO) fatty acid).

[0244] In some embodiments, the adjuvant is ethoxylated tridecyl alcohol or poly It is oxyethylene(9) isotridecanol.

[0245] In some embodiments, vegetable oil is, but is not limited to, vegetable oil. This includes derivatives thereof.

[0246] In some embodiments, vegetable oils are not limited to these, but may include seed oil, coconut oil, rapeseed oil, and hi Contains malt oil, soybean oil, palm oil, and corn oil.

[0247] In some embodiments, the vegetable oil derivative is an alkyl ester, polyalkylene oxide It refers to.

[0248] Polyalkylene oxides include polyethylene oxide, polypropylene oxide, and polypropylene oxide. This refers to ethylene oxides and combinations thereof.

[0249] In some embodiments, vegetable oils and their derivatives are not limited to these, but include rapeseed oil. It contains chylated esters and coconut fatty acid esters of polyglycerol ethers.

[0250] In some embodiments, the adjuvant is a methylated seed oil with a polyglycerol ester. It is a mixture.

[0251] In some embodiments, methylated rapeseed oil is manufactured and sold by BASF. This is the Agnique ME 18 RDF.

[0252] In some embodiments, the polyalkylene oxide derivative of vegetable oil is polyglycerol. It is a coconut fatty acid ester.

[0253] In some embodiments, the coconut fatty acid ester of polyglycerol ether is Clari This is Synergen GL5, manufactured and sold by Ant.

[0254] In some embodiments, fatty acid esters are used for better and more effective penetration of compounds of formula I. This softens the surface properties of the leaves.

[0255] In some embodiments, the vinylpyrrolidone derivative is vinylpyrrolidone and vinyl acetate ( It is a block copolymer of VP / VA.

[0256] In some embodiments, a block copolymer of vinylpyrrolidone and vinyl acetate is, This is the Sokalan VA64P, manufactured and sold by Hland.

[0257] In some embodiments, a block copolymer of vinylpyrrolidone and vinyl acetate is, This is the Agrimer VA6, manufactured and sold by Hland.

[0258] In some embodiments, vinylpyrrolidone (PVP) and its derivatives have adhesive properties and To improve retention properties (e.g., rain resistance), the adhesion of the compound of formula I to leaves is enhanced. It is effective for that purpose.

[0259] Sugar-type surfactants are not limited to these, but include sorbitan esters, sucrose esters, It may also contain alkyl polyglycosides and fatty acid glucamides.

[0260] In some embodiments, the sugar-type surfactant is an alkyl or fatty acid glucamide derivative. ru.

[0261] In some embodiments, the sugar-type surfactant is an alkylglucamide.

[0262] In some embodiments, the fatty acid glucamide is a C8 / C10 fatty acid glucose amide. ru.

[0263] In some embodiments, the C8 / C10 fatty acid glucose amide is manufactured by Glariant. This is Synergen GA.

[0264] In some embodiments, the sugar-type surfactant is sorbitan and its derivatives.

[0265] In some embodiments, the sorbitan derivative is a polyethylene oxide derivative and a fat. It is an acid ester.

[0266] In some embodiments, sorbitan is a di or tri fatty acid ester. Morphologically, sorbitan derivatives are polyethylene containing 20 to 80 ethylene oxide groups. It is an oxide derivative.

[0267] In some embodiments, the derivative of sorbitan is Tween 80.

[0268] In some embodiments, sugar-type surfactants improve the penetration of compounds of formula I through the leaf surface. It affects the surface of the leaves in order to do so.

[0269] Some embodiments include combinations, mixtures, or compositions, or multi-adjuvant systems. Hmm. A multi-adjuvant system refers to a blend or any combination of adjuvants.

[0270] In some embodiments, a combination, mixture, or composition, or at least two types of ajuba Includes. In some embodiments, the combination, mixture, or composition includes at least three types. Includes adjuvants.

[0271] In some embodiments, the adjuvant blend may include, but is not limited to, alkyl This includes combinations of fatty acid esters and fatty alcohol alkoxylates.

[0272] In some embodiments, alkyl fatty acid esters and fatty alcohol alkoxylates The combination is Synergen SOC, manufactured and sold by Clariant. That is the case.

[0273] In some embodiments, alkyl fatty acid esters and fatty alcohol alkoxylates The combination is FOP manufactured and sold by Clariant.

[0274] In some embodiments, the blend of adjuvants may include, but is not limited to, vegetable oils. This includes combinations of and / or derivatives thereof with sugar-type surfactants.

[0275] In some embodiments, the combination, mixture, or composition includes a pH adjuster.

[0276] In some embodiments, pH adjusters include, but are not limited to, buffers, bases and / Alternatively, it may contain an acidifying agent.

[0277] In some embodiments, the pH adjuster is an acid. In some embodiments, the pH adjuster is a base. That is the case.

[0278] In some embodiments, the pH adjuster comprises at least one base and at least one acid. It is a mixture.

[0279] In some embodiments, the pH adjuster is a buffering agent.

[0280] A buffering agent refers to a combination of acid and base. Acids are not limited to these, but include organic acids and This includes inorganic acids. Bases include, but are not limited to, organic and inorganic bases.

[0281] Organic acids are not limited to these, but include citric acid, formic acid, acetic acid, propionic acid, and dairy products. Examples include acids, oxalic acid, lactic acid, malic acid, and benzoic acid.

[0282] Inorganic acids include, but are not limited to, hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, and boric acid. It can be listed.

[0283] Organic bases include, but are not limited to, primary and secondary amines, pyridines, Examples include imidazoles and any combination thereof.

[0284] In some embodiments, the pH adjuster is potassium hydrogen phosphate.

[0285] In some embodiments, the pH adjusters are disodium monohydrogen phosphate and potassium hydrogen phosphate. This is the combination.

[0286] The present invention relates to a composition comprising any one of the combinations or mixtures disclosed herein. provide.

[0287] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0288] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from The present invention provides a bactericidal composition containing the following:

[0289] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0290] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from The present invention provides a synergistic bactericidal composition containing [a specific compound / component].

[0291] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0292] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A bactericidal composition containing, In the treatment of plants or places where plants are present for fungal infections, each fungicide is It is more effective than when applied alone in the same amount. A bactericidal composition is provided.

[0293] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0294] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A bactericidal composition containing, When a predetermined amount of compound I and a predetermined amount of fungicide (A) are applied together, fungal infection In the treatment of plants or the places where plants are present, each fungicide is applied individually in equal amounts. It is more effective than the case where A bactericidal composition is provided.

[0295] The present invention relates to (i) a predetermined amount of a compound of formula I,

[0296] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from A bactericidal composition containing, The amount of compound I used determines the bactericidal effect of compound I when used alone. Less than the effective amount, and / or The amount of disinfectant (A) used is the amount of disinfectant (A) used alone. Less than the effective amount A bactericidal composition is provided.

[0297] In some embodiments, the composition contains about 0.1 wt of the compound of formula I based on the total weight of the composition. Amount % to 90% by weight, preferably about 0.1% to 20% by weight based on the total weight of the composition. It includes amounts within the range.

[0298] In some embodiments, the composition contains a bactericide (A) based on the total weight of the composition at about 0.1 wt. Amount % to 90% by weight, preferably about 0.1% to 20% by weight based on the total weight of the composition. It includes amounts within the range.

[0299] In some embodiments, the amount of compound I in the composition is about 0 based on the total weight of the composition. .1% by weight, 0.5% by weight, 1% by weight, 1.5% by weight, 2% by weight, 2.5% by weight, 3% by weight %, 3.5% by weight, 4% by weight, 4.5% by weight or 5% by weight to approximately 90% by weight, 93% by weight The weights can be up to %, 95%, 98%, or 99%.

[0300] In some embodiments, the amount of bactericide (A) in the composition is about 0 based on the total weight of the composition. .1% by weight, 0.5% by weight, 1% by weight, 1.5% by weight, 2% by weight, 2.5% by weight, 3% by weight %, 3.5% by weight, 4% by weight, 4.5% by weight or 5% by weight to approximately 90% by weight, 93% by weight The weights can be up to %, 95%, 98%, or 99%.

[0301] In some embodiments, the amount of compound I in the composition is about 0 based on the total weight of the composition. .1% by weight, 0.5% by weight, 1% by weight, 1.5% by weight, 2% by weight, 2.5% by weight, 3% by weight %, 3.5% by weight, 4% by weight, 4.5% by weight, 5% by weight, 10% by weight, 15% by weight, 20 Weight%, 25% by weight, 30% by weight, 35% by weight, 40% by weight, 45% by weight, 50% by weight, 55% by weight, 60% by weight, 65% by weight, 70% by weight, 75% by weight, 80% by weight, 85% by weight This is %, 90% by weight, or 95% by weight.

[0302] In some embodiments, the amount of bactericide (A) in the composition is about 0 based on the total weight of the composition. .1% by weight, 0.5% by weight, 1% by weight, 1.5% by weight, 2% by weight, 2.5% by weight, 3% by weight %, 3.5% by weight, 4% by weight, 4.5% by weight, 5% by weight, 10% by weight, 15% by weight, 20 Weight%, 25% by weight, 30% by weight, 35% by weight, 40% by weight, 45% by weight, 50% by weight, 55% by weight, 60% by weight, 65% by weight, 70% by weight, 75% by weight, 80% by weight, 85% by weight This is %, 90% by weight, or 95% by weight.

[0303] In some embodiments, the weight ratio of the compound of formula I to the bactericide (A) in the composition is about 400 The ratio is within the range of 1 to 1:100. In some embodiments, the compound of formula I in the composition and sterilization The weight ratio of agent (A) is in the range of approximately 200:1 to 1:100. In some embodiments, The weight ratio of the compound of formula I to the bactericide (A) in the composition is approximately 50:1 to 1:50. In some embodiments, the weight ratio of the compound of formula I to the bactericide (A) in the composition is about 200: The ratio is within the range of 1 to 1:100. In some embodiments, the compound of formula I in the composition is a bactericide. The weight ratio with (A) is in the range of approximately 10:1 to 1:10. In some embodiments, the composition The weight ratio of the compound of formula I in the substance to the disinfectant (A) is in the range of approximately 5:1 to 1:5. In one embodiment, the weight ratio of the compound of formula I to the bactericide (A) in the composition is approximately 2:1 to 1 It is within the range of :2.

[0304] In some embodiments, the weight ratio of the compound of formula I to the bactericide (A) in the composition is 5:1~ The ratio is 30:1. In some embodiments, the weight of the compound of formula I in the composition is equal to the weight of the bactericide (A). The ratio is 10:1 to 30:1. In some embodiments, the compound of formula I in the composition and sterilization The weight ratio of agent (A) is 25:1 to 12.5:1. In some embodiments, the composition The weight ratio of the compound of formula I to the fungicide (A) is 25:1. In some embodiments, The weight ratio of the compound of formula I to the fungicide (A) in the product is 12.5:1. (Partial implementation) In this state, the weight ratio of the compound of formula I to the disinfectant (A) in the composition is 1:1.

[0305] In some embodiments, the composition further comprises a botanically acceptable carrier.

[0306] In some embodiments, the composition further comprises a botanically acceptable adjuvant.

[0307] In some embodiments, the composition further comprises at least one insecticide.

[0308] In some embodiments, the composition is formulated by diluting it with water before application.

[0309] In some embodiments, the composition is a concentrated formulation, and application It can be dispersed in water or another liquid. In some embodiments, the composition is dusty or The granules are then applied without further processing. The product is conventional in the field of pesticide technology, but the synergistic effect of the composition makes it novel and It can be prepared according to important procedures.

[0310] The compositions applied in most cases are aqueous suspensions or emulsions. Water-soluble, water-suspending, or emulsifying formulations are usually solids known as wettable powders, and This is a liquid, typically known as an emulsion, aqueous suspension, or concentrated suspension. This disclosure is, The whole vehicle used in formulation for delivering the synergistic composition and its bactericide To use it.

[0311] A wettable powder that can be compressed to form a water-dispersible granule is It comprises a close mixture of a synergistic composition, a carrier, and an agrochemically acceptable surfactant. The concentration of the disclosed composition in the preparation is typically about 10% by weight, based on the total weight of the preparation. The amount is approximately 90% by weight, more preferably about 25% to about 75% by weight. The synergistic composition can be mixed with any fine solid.

[0312] To make it easy to understand, any material to which the disclosed composition may be added They may be used, however, the antifungal activity of these synergistic mixtures or compositions The condition is that the desired usefulness is produced without significant interference.

[0313] How to use The present invention relates to a method for treating a plant or a location where a plant is present against fungal infection, (i) A predetermined amount of compound of formula I,

[0314] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Apply to the plant or the place where the plant is located, thereby the plant or the place where the plant is located The present invention provides a method for treating fungal infections.

[0315] The present invention relates to a method for treating a plant or a location where a plant is present against fungal infection, (i) A predetermined amount of compound of formula I,

[0316] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Apply to the plant or the place where the plant is located, thereby the plant or the place where the plant is located This includes treating fungal infections, In the treatment of plants or areas where plants are present for fungal infections, each fungicide is used individually in equal amounts. It is more effective than when applied. Provide a method.

[0317] The present invention relates to a method for treating a plant or a location where a plant is present against fungal infection, (i) A predetermined amount of compound of formula I,

[0318] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Apply to the plant or the place where the plant is located, thereby the plant or the place where the plant is located This includes treating fungal infections, When a specified amount of compound I and a specified amount of fungicide (A) are applied together, fungal infection In the treatment of plants or the places where plants are present, each fungicide is applied individually in equal amounts. It is more effective than the case where Provide a method.

[0319] The present invention relates to a method for treating a plant or a location where a plant is present against fungal infection, (i) A predetermined amount of compound of formula I,

[0320] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Apply to the plant or the place where the plant is located, thereby the plant or the place where the plant is located This includes treating fungal infections, The amount of compound I used determines the bactericidal effect of compound I when used alone. Less than the effective amount, and / or The amount of disinfectant (A) used is the amount of disinfectant (A) used alone. Less than the effective amount Provide a method.

[0321] The present invention also relates to a method for treating a plant or a location where a plant is present against fungal infection. and an effective amount of any one of the combinations, mixtures, or compositions disclosed herein Apply this to the plant or the place where the plant is located, thereby the place where the plant or the place where the plant is located The present invention also provides a method that includes treating the area for fungal infection.

[0322] In some embodiments, the method involves treating a plant or the location where the plant is present for fungal infection. In this case, it is more effective than when each fungicide is applied individually in the same amount.

[0323] In some embodiments, a predetermined amount of the compound of formula I and a predetermined amount of the fungicide (A) are used together. When used, each fungicide is used in the treatment of plants or the area where plants are present against fungal infections. It is more effective when the drug is applied alone in the same amount.

[0324] In some embodiments, the amount of compound I used is when compound I is used alone. The amount of the compound of formula I is less than the effective bactericidal amount. In some embodiments, the amount of bactericide (A) used is The amount is less than the effective bactericidal amount of bactericide (A) when bactericide (A) is used alone.

[0325] In some embodiments, the method controls fungal infections of plants or the locations where plants exist. It is effective for this purpose.

[0326] In some embodiments, controlling fungal infections is done on plants or in the locations where plants exist. This includes controlling fungal diseases that infect. In some embodiments, this includes controlling fungal infections. This includes controlling plant or soil diseases caused by plant pathogenic fungi. In some embodiments, controlling fungal infections can affect plants or the locations where plants reside. This includes controlling fungal invasion. In some embodiments, controlling fungal infection is This includes reducing fungal infections in plants or the locations where plants reside. In some embodiments, this includes reducing fungal infections in plants or the locations where plants reside. Controlling fungal infections is essential for preventing plant or soil diseases caused by plant pathogenic fungi. This includes treating the body's energy.

[0327] In some embodiments, the method protects the plant or the location where the plant resides from fungal infection. It is effective for that purpose.

[0328] In some embodiments, the purpose is to protect plants or the locations where plants reside from fungal infections. This includes protecting plants or the areas where plants reside from fungal invasion. Morphologically, protecting plants or the places where plants exist from fungal infections is important for the plants themselves. This includes protecting the area where the plants are located from fungal diseases. In some embodiments, the plants also Protecting the area where plants are present from fungal infections is important for protecting the plants or the area where plants are present. This includes preventing fungal infections in the area.

[0329] In some embodiments, the method involves an effective amount of the combination, mixture, and disclosed herein. This includes applying any one of the compositions to plant propagation material. Some embodiments The method involves using an effective amount of any of the combinations, mixtures, or compositions disclosed herein. This includes applying any one of the following to plant seeds and / or seedlings.

[0330] In some embodiments, the method involves the combination, mixture, or composition disclosed herein. This includes the application of any one of the following protective purposes. In some embodiments, the method is as follows: The therapeutic application of any one of the combinations, mixtures, or compositions disclosed herein include.

[0331] In some embodiments, the method includes the application of the compound of formula I and the bactericide (A) for protective purposes. In some embodiments, the method applies the compound of formula I and the bactericide (A) for therapeutic purposes. include.

[0332] In some embodiments, fungal invasion is prevented from occurring in plants, seeds, or seedlings. It is controlled by [the following]. In some embodiments, fungal invasion is controlled by fungi in plants, seeds, or seedlings. It is controlled by treating the invasiveness.

[0333] The present invention also relates to a method for controlling plant diseases caused by plant pathogenic fungi. The plant, plant propagation material, or location of the plant is disclosed in an effective amount herein. This includes contacting the plant with one of the possible combinations to control the plant disease. We will also provide the method.

[0334] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, as specified herein. Any one of the disclosed combinations is a plant, seedling, seedling, and / or the location where the plant is located. It is applied to and thereby treats or prevents fungal infestations of plants, seeds, or seedlings. We will also provide methods for doing so.

[0335] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, as specified herein. Any one of the disclosed compositions or mixtures can be used to treat plants, seeds, seedlings, and / or It is applied to the area where plants are present, thereby controlling fungal invasion of plants, seeds, or seedlings. We also provide methods that include this.

[0336] The present invention also relates to treating plants, seeds, or seedlings to produce plants resistant to fungal invasion. A method comprising using any one of the compositions or mixtures disclosed herein to a plant Seeds adapted to produce plants, seedlings adapted to produce plants, or plants The method involves applying it to the location where the substance exists, thereby producing plants that are resistant to fungal invasion. We also provide methods for including this.

[0337] The present invention also relates to a method for protecting plants from fungal invasion, comprising the composition disclosed herein. Any one of the substances or mixtures is a plant, a place where a plant exists, or a place that produces a plant. It is applied to seeds or seedlings that have been adapted to protect the plants from fungal invasion. We also provide methods that include doing so.

[0338] The present invention also provides plants that are resistant to fungal invasion and adapted to produce plants. The location where seeds, seedlings adapted to produce plants, or plants exist is described herein. It is treated with one of the compositions or mixtures shown.

[0339] The present invention also relates to plant seeds adapted to produce plants resistant to fungal invasion or Seedlings are also provided, and plant seeds or seedlings are provided in the composition or mixture disclosed herein. It is treated by one of the following methods.

[0340] The present invention also relates to a method for controlling fungal invasion of plants, comprising the compositions described herein. Or, one of the mixtures, in the soil, plants, roots, leaves, seeds, or places where fungi are present. Apply to areas where you want to prevent intrusion and / or fungal invasion of plants. It also provides methods that include control.

[0341] The present invention also relates to a method for controlling fungal infections of plants and / or soil, as specified herein. Any one of the compositions or mixtures described above is used in soil, plants, roots, leaves, seeds, and fungi. Apply to the location where it exists and / or where you want to prevent its intrusion, thereby planting The invention also provides methods for controlling fungal infections of materials and / or soil.

[0342] The present invention also provides a method for controlling plant diseases caused by plant pathogenic fungi, (i) A predetermined amount of a compound of formula I,

[0343] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from The invention also provides a method that involves contacting the plant with a plant to control plant diseases.

[0344] In some embodiments, plant diseases are controlled by protecting plants from plant diseases. In some embodiments, plant diseases are controlled by treating them.

[0345] The present invention also relates to a method for controlling fungal invasion of plants, seeds, or seedlings, (i) A predetermined amount of the compound of formula I,

[0346] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Methods are also proposed that include applying [a specific method] to control fungal invasion of plants, seeds, or seedlings. To provide.

[0347] In some embodiments, fungal invasion is prevented from occurring in plants, seeds, or seedlings. It is controlled by [the following]. In some embodiments, fungal invasion is controlled by fungi in plants, seeds, or seedlings. It is controlled by treating the invasiveness.

[0348] The present invention also relates to a method for protecting plants, seeds, or seedlings from fungal invasion, and the present invention relates to a method for protecting plants, seeds , in the place where seedlings and / or plants are present, (i) a predetermined amount of the compound of formula I,

[0349] [ka] (ii) a prescribed amount of fluindapyr, pydiflumetofen flumetofen, mefentrifluconazole, impulflux A group consisting of inpyrfluxam, isofetamide, and Qi inhibitors. At least one fungicide (A) selected from Methods are also proposed that include applying a solution to protect plants, seeds, or seedlings from fungal infections. To provide.

[0350] In some embodiments, the method includes the application of the compound of formula I and the bactericide (A) for protective purposes. In some embodiments, the method applies the compound of formula I and the bactericide (A) for therapeutic purposes. include.

[0351] In some embodiments, the method involves the compound of formula I and a fungicide in the presence of a fungal pathogen infection. This includes applying A). In some embodiments, the method is applied before symptoms of fungal disease appear. The method includes applying a compound of formula I and a bactericide (A). In some embodiments, the method is This includes applying the compound of formula I and a fungicide (A) when the disease is mild.

[0352] In some embodiments, the method involves the compound of formula I and a fungicide in the presence of a fungal pathogen infection. This includes applying A). In some embodiments, the method is applied after symptoms of a fungal disease have appeared. This includes applying the compound of formula I and the fungicide (A).

[0353] In some embodiments, the method is effective in reducing leaf necrosis. Leaf necrosis is reduced by at least 10%. In some embodiments, leaf necrosis is less It is reduced by at least 25%. In some embodiments, leaf necrosis is reduced by at least 50%. In some embodiments, leaf necrosis is reduced by at least 75%.

[0354] In some embodiments, the effectiveness of the method is less due to the application of the compound of formula I and the fungicide (A). At the very least, it will be evaluated after one week. In some embodiments, the effectiveness of the method is determined by the compound of formula I. The evaluation is performed at least two weeks after the application of the fungicide (A). In some embodiments, The effectiveness of the method was evaluated at least three weeks after the application of the compound of formula I and the fungicide (A). In some embodiments, the effectiveness of the method depends on the application of the compound of formula I and the fungicide (A). It will be evaluated at least four weeks later.

[0355] In some embodiments, the compound of formula I and the fungicide (A) are applied simultaneously.

[0356] In some embodiments, the compound of formula I and the fungicide (A) are applied simultaneously.

[0357] In some embodiments, the compound of formula I and the fungicide (A) are applied sequentially.

[0358] In some embodiments, the compound of formula I and the fungicide (A) are applied separately.

[0359] In some embodiments, the compound of formula I and the fungicide (A) are applied together.

[0360] In some embodiments, the compound of formula I and the fungicide (A) are combined as a tank mix. This applies to the following. In some embodiments, the compound of formula I and the bactericide (A) are used in a single composition and It is then formulated. In some embodiments, the compound of formula I and the bactericide (A) are two separate They are formulated as various compositions.

[0361] In some embodiments, the compound of formula I and the bactericide (A) are in combination as disclosed herein. It is applied in the form of any one of the following: a compound, a mixture, or a composition.

[0362] In some embodiments, the compound of formula I and the fungicide (A) are applied to a part of a plant, adjacent to the plant. The area, the soil in contact with the plant, the soil adjacent to the plant, any surface adjacent to the plant, the plant This applies to any surface, seeds, and / or equipment used in agriculture that are in contact with it. In one embodiment, the compound of formula I and the fungicide (A) are used in the location where the plant is present and close to the plant. This applies to areas of contact, areas where fungi are present, or areas in close proximity to fungi. In terms of form, the compound of formula I and the fungicide (A) are applied to soil in which plants grow. In this embodiment, the compound of formula I and the fungicide (A) are suitable for the soil in which plants are to be grown. It is used.

[0363] In some embodiments, the compound of formula I and the fungicide (A) are applied at the time of sowing.

[0364] In some embodiments, the compound of formula I and the fungicide (A) are suitable 1 to 60 days after sowing. It is used.

[0365] In some embodiments, the compound of formula I and the fungicide (A) are suitable 1 to 9 months after sowing. It is used.

[0366] In some embodiments, the compound of formula I and the fungicide (A) are applied once during the growth stage. It can be done.

[0367] In some embodiments, the compound of formula I and the fungicide (A) are used at least once during the growth stage. It is applied multiple times.

[0368] In some embodiments, the compound of formula I and the fungicide (A) are applied two or more times during the growth stage. It will be done.

[0369] In some embodiments, the compound of formula I and the fungicide (A) are applied as soil application. In some embodiments, the compound of formula I and the fungicide (A) are applied as foliar applications.

[0370] In some embodiments, the compound of formula I is applied in amounts ranging from 1 g / ha to 500 g / ha. In some embodiments, the compound of formula I is applied in amounts ranging from 5 g / ha to 120 g / ha. In some embodiments, the compound of formula I is applied in amounts ranging from 1 g / ha to 100 g / ha. In some embodiments, the compound of formula I is applied in amounts ranging from 1 g / ha to 75 g / ha. In some embodiments, the compound of formula I is applied in amounts ranging from 1 g / ha to 50 g / ha. In some embodiments, the compound of formula I is applied in amounts of 1 g / ha to 25 g / ha. In the embodiment, the compound of formula I is applied in amounts of 1 g / ha to 15 g / ha. In the embodiment, the compound of formula I is applied in amounts of 2 g / ha to 13 g / ha. In terms of application methods, the compound of formula I is applied in amounts of 5 g / ha to 10 g / ha.

[0371] In some embodiments, the compound of formula I is applied in an amount of about 5 g / ha. In this configuration, the compound of formula I is applied in an amount of approximately 6.25 g / ha. In some embodiments, The compound of formula I is applied in an amount of approximately 10 g / ha. In some embodiments, the compound of formula I is applied. This is applied in an amount of approximately 12.5 g / ha. In some embodiments, the compound of formula I is approximately 7 It is applied at a rate of 5 g / ha. In some embodiments, the compound of formula I is applied at approximately 100 g / ha. It is applied in the amount of [amount]. In some embodiments, the compound of formula I is applied in the amount of about 125 g / ha. In some embodiments, the compound of formula I is applied in an amount of about 150 g / ha. In some embodiments, the compound of formula I is applied in an amount of about 300 g / ha. In this scenario, the compound of formula I is applied in an amount of approximately 500 g / ha.

[0372] In some embodiments, the fungicide (A) is administered in amounts from 0.0001 g / ha to 500 g / ha. Applicable. In some embodiments, the fungicide (A) is 0.1 g / ha to 100 g / ha It is applied by quantity. In some embodiments, the fungicide (A) is 0.1 g / ha to 75 g / ha It is applied in the following amounts. In some embodiments, the fungicide (A) is 0.1 g / ha to 50 g / h It is applied in an amount of a. In some embodiments, the fungicide (A) is 0.1 g / ha to 25 g / It is applied in amounts of ha. In some embodiments, the fungicide (A) is 0.1 g / ha to 10 g It is applied in amounts of / ha. In some embodiments, the fungicide (A) is 0.1g / ha to 5g It is applied in amounts of / ha. In some embodiments, the fungicide (A) is 0.1g / ha~0. It is applied at a rate of 7 g / ha. In some embodiments, the fungicide (A) is 0.0001 g / It is applied at a quantity of ha~0.01 g / ha. In some embodiments, the fungicide (A) is 0. It is applied in amounts of 0.003 g / ha to 0.008 g / ha. In some embodiments, it is used as a fungicide. (A) is applied in amounts of 0.1 g / ha to 150 g / ha. In some embodiments, The fungicide (A) is applied in amounts of 0.1 g / ha to 1 g / ha.

[0373] In some embodiments, the fungicide (A) is applied in an amount of approximately 0.0003 g / ha. In some embodiments, the fungicide (A) is applied in an amount of approximately 0.001 g / ha. In the application method, the fungicide (A) is applied at an amount of approximately 0.002 g / ha. (Some embodiments) Then, the fungicide (A) is applied in an amount of approximately 0.008 g / ha. In some embodiments, The fungicide (A) is applied in an amount of approximately 0.4 g / ha. In some embodiments, the fungicide (A ) is applied in an amount of approximately 6.25 g / ha. In some embodiments, the fungicide (A) is approximately It is applied at a rate of 10 g / ha. In some embodiments, the fungicide (A) is approximately 12.5 g / It is applied in amounts of hectares (ha). In some embodiments, the fungicide (A) is applied in amounts of about 75 g / ha. It is used. In some embodiments, the fungicide (A) is applied in an amount of about 100 g / ha. In some embodiments, the fungicide (A) is applied in an amount of approximately 125 g / ha. In its morphology, the fungicide (A) is applied in an amount of approximately 150 g / ha. In some embodiments, The fungicide (A) is applied in an amount of approximately 300 g / ha. In some embodiments, the fungicide (A This applies to an amount of approximately 500g / ha.

[0374] In some embodiments, fluindapyr is administered at concentrations of 5 g / ha to 150 g / ha. It is applied in the amount of . In some embodiments, fluindapyr is 0.1 g / It is applied at a rate of 150g / ha. In some embodiments, fluid apyr) is applied in amounts of 0.1 g / ha to 1 g / ha. In some embodiments, a sieve Fluindapyr is administered at a dose of approximately 0.4 g / ha.

[0375] In some embodiments, pydiflumetofen is administered at a dose of 0.0001 g / h. It is applied in amounts of a~150g / ha. In some embodiments, pidiflumetofen (pydi Flumetofen is applicable in amounts of 0.0001 g / ha to 0.01 g / ha. In terms of application methods, pydiflumetofen is administered at a rate of approximately 0.0003 g / ha. Applicable. In some embodiments, pydiflumetofen is about 0.0 It is applied at a rate of 0.1 g / ha. In some embodiments, pydiflumetofen is used. (ofen) is applied in an amount of approximately 0.002 g / ha. In some embodiments, pidiflumeth Pydiflumetofen is applied at a rate of approximately 0.008 g / ha.

[0376] In some embodiments, mefentrifluconazole is 5 g Applied at a rate of 150g / ha. In some embodiments, mefentri fruccona Mefentrifluconazole is applied in amounts ranging from 0.1 g / ha to 150 g / ha. In some embodiments, mefentrifluconazole is 0. It is applied in amounts of 1 g / ha to 1 g / ha. In some embodiments, mefentri fluconate Mefentrifluconazole is applied at a dose of approximately 0.4 g / ha.

[0377] In some embodiments, inpyrfluxam is administered at a dose of 5 g / ha to 150 g. It is applied in amounts of / ha. In some embodiments, impyrfluxam is used This applies to amounts ranging from 0.1 g / ha to 150 g / ha.

[0378] In some embodiments, isofetamide is present in concentrations of 5 g / ha to 150 g / ha. It is applied in the amount of . In some embodiments, isofetamide is 0.1 g / This applies to amounts of 150g / ha or more.

[0379] In some embodiments, the Qi inhibitor is applied in amounts ranging from 5 g / ha to 150 g / ha. In some embodiments, the Qi inhibitor is applied in amounts ranging from 0.1 g / ha to 150 g / ha. In some embodiments, the Qi inhibitor is applied in amounts of 0.1 g / ha to 1 g / ha. In some embodiments, the Qi inhibitor is applied at an amount of approximately 0.4 g / ha.

[0380] In some embodiments, fenpicoxamide is administered at 5 g / ha to 150 g It is applied in amounts of / ha. In some embodiments, fenpicoxamide is It is applied in amounts from 0.1 g / ha to 150 g / ha. In some embodiments, fenpico Fenpicoxamid is applied at doses of 0.1 g / ha to 1 g / ha. In terms of application methods, fenpicoxamid is applied at a rate of approximately 0.4 g / ha. ru.

[0381] Compounds of formula I and bactericide (A) are combinations, mixtures or compositions disclosed herein. When applied in the form of a substance, the ratio to which the combination, mixture and / or composition is applied is , the specific type of fungus to be controlled, the degree of control required, and the timing of application and It depends on the method. Generally, the combinations, mixtures, or compositions disclosed herein are The application rate will be between approximately 1 gram per hectare (g / ha) and approximately 2600 g / ha. It is possible.

[0382] The combinations, mixtures, or compositions disclosed herein are approximately 4 based on the total amount of active ingredients. It can be applied at a ratio between 0 g / ha and approximately 600 g / ha.

[0383] In some embodiments, the amount of compound I is in the range of 1 g / ha to 500 g / ha. A compound, mixture, or composition is applied. In some embodiments, the amount of compound I is 5 This applies to combinations, mixtures, or compositions in the range of g / ha to 120 g / ha. In the embodiment, the amount of compound I is in the range of 1 g / ha to 100 g / ha. A substance, mixture, or composition is applied. In some embodiments, the amount of compound of formula I is 1 g / This applies to combinations, mixtures, or compositions in the range of ha~75g / ha. In terms of application methods, combinations and mixtures in which the amount of compound I is in the range of 1 g / ha to 50 g / ha are used. A substance or composition is applied. In some embodiments, the amount of compound of formula I is 1 g / ha to 2 Combinations, mixtures, or compositions in the range of 5 g / ha are applicable. This refers to combinations, mixtures, or The composition is applied. In some embodiments, the amount of compound I is 2 g / ha to 13 g / h. A combination, mixture, or composition within the range of a is applicable. In some embodiments, formula I A combination, mixture, or composition in which the amount of the compound is in the range of 5 g / ha to 10 g / ha It applies.

[0384] In some embodiments, the amount of compound I is about 5 g / ha in combinations, mixtures or The composition is applied. In some embodiments, the amount of compound I is about 6.25 g / ha. A combination, mixture, or composition is applied. In some embodiments, the amount of the compound of formula I A combination, mixture, or composition with approximately 10 g / ha is applied. In some embodiments This applies to combinations, mixtures, or compositions in which the amount of compound I is approximately 12.5 g / ha. In some embodiments, the amount of compound of formula I is about 75 g / ha in the combination, mixture. A substance or composition is applied. In some embodiments, the amount of compound of formula I is about 100 g / h A combination, mixture, or composition of formula a is applied. In some embodiments, a compound of formula I The combination, mixture, or composition in which the amount of the substance is approximately 125 g / ha is applicable. In terms of application, the amount of compound I is approximately 150 g / ha in a combination, mixture, or composition. The following applies. In some embodiments, the amount of compound of formula I is about 300 g / ha. A substance, mixture, or composition is applied. In some embodiments, the amount of compound of formula I is about 50 A combination, mixture, or composition with a concentration of 0 g / ha is applicable.

[0385] In some embodiments, the amount of fungicide (A) is in the range of 1 g / ha to 500 g / ha. A mixture, blend, or composition may be applied.

[0386] In some embodiments, the amount of fungicide (A) is in the range of 0.1 g / ha to 100 g / ha. A combination, mixture, or composition is applied. In some embodiments, the amount of the fungicide (A) The combination, mixture, or composition in the range of 0.1 g / ha to 75 g / ha is applicable. In some embodiments, the amount of fungicide (A) is in the range of 0.1 g / ha to 50 g / ha. A combination, mixture, or composition is applied. In some embodiments, the amount of the fungicide (A) This applies to combinations, mixtures, or compositions in the range of 0.1 g / ha to 25 g / ha. In some embodiments, the amount of fungicide (A) is in the range of 0.1 g / ha to 10 g / ha. A combination, mixture, or composition is applied. In some embodiments, the amount of the fungicide (A) This applies to combinations, mixtures, or compositions in the range of 0.1 g / ha to 5 g / ha. In some embodiments, the amount of fungicide (A) is in the range of 0.1 g / ha to 0.7 g / ha. A combination, mixture, or composition is applied.

[0387] In some embodiments, the amount of fungicide (A) is approximately 0.4 g / ha in combinations, mixtures, etc. Or the composition is applied. In some embodiments, the amount of fungicide (A) is about 6.25 g / ha A combination, mixture, or composition is applied. In some embodiments, a fungicide (A) A combination, mixture, or composition in which the amount is approximately 10 g / ha is applicable. Some implementations In this state, a combination, mixture, or composition in which the amount of fungicide (A) is approximately 12.5 g / ha Applicable. In some embodiments, the amount of compound I is about 75 g / ha in the combination. A mixture or composition is applied. In some embodiments, the amount of fungicide (A) is about 100 g A combination, mixture, or composition of / ha is applied. In some embodiments, a fungicide is used. A combination, mixture, or composition in which the amount of (A) is approximately 125 g / ha is applicable. In this embodiment, the amount of fungicide (A) is approximately 150 g / ha in the combination, mixture or combination The product is applied. In some embodiments, the amount of fungicide (A) is about 300 g / ha. A mixture, blend, or composition is applied. In some embodiments, the amount of fungicide (A) is approximately A combination, mixture, or composition with a concentration of 500 g / ha is applied.

[0388] The combinations, mixtures, and compositions disclosed herein are effective against a variety of fungal pathogens and It can be applied to control and / or prevent related diseases. In this embodiment, the fungal pathogen is Mycosphaerella graminicola, the wheat leaf blight fungus. Leaf blight fungus (Septoria tritici), wheat rust fungus (Puccinia triticina), wheat yellow sap Puccinia striiformis f. sp. tritici, Venturia inaequal is), corn smut fungus (Ustilago maydis), powdery mildew fungus (Uncinula necator) , Rhynchosporium secalis, Magnaporche grisea ), Asian soybean rust fungus (Phakopsora pachyrhizi), wheat rot fungus (Leptosphaer) (Ia nodorum), wheat powdery mildew fungus (Blumeria graminis f. sp. tritici), barley Powdery mildew fungus (Blumeria graminis f. sp. hordei), cucurbit powdery mildew fungus (Erysiphe cich). oracearum), cucurbit anthracnose fungus (Glomerella lagenarium), sugar beet brown spot fungus (Cercosporum (Alternaria beticola), tomato ring spot disease fungus (Alternaria solani), reticulosis fungus (Pyrenophora teres) ), Ramularia genus, Peronospora spp. species, gray mold fungus (Botrytis cinereal), and the banana black sigatoka pathogen (Mycosphaerella fijiensis) It is one of them.

[0389] In some embodiments, the fungal pathogen belongs to the genus Septoria. In terms of application, the fungal pathogen is the wheat pathogen (Zymoseptoria tritici) (SEPTTR). In some embodiments, the fungal pathogen is of the genus Rhynhosporium. Yes. In some embodiments, the fungal pathogen belongs to the genus Pyrenophora. In some embodiments, the fungal pathogen is Microduchium majus. In some embodiments, the fungal pathogen belongs to the genus Sclerotinia. In this embodiment, the fungal pathogen is Cercosporea beticola, the fungus that causes brown spot disease in sugar beets.

[0390] In some embodiments, the fungal disease is called Leaf Blotch of Wheat (wheat leaf blight). Mycosphaerella graminicola (a type of fungus), anamorph, and Zymoseptoria trifolia (a type of wheat pathogen). Puccinia tritici)), Wheat Brown Rust (Wheat Red Rust) na)), Stripe Rust (wheat yellow rust fungus (Puccinia striiformis f. sp. t) ritici)), Apple Scab (Scab of Apple) (Apple Scab Fungus (Venturia inaequalis) ), corn blister disease (corn smut fungus (Ust Ilago maydis), Grapevine Powdery Mildew (Powdery Mildew of Grapevine) (Uncinula necator), Barley scald (Barley scald fungus (Rhyn)) Chosporium secalis), Blast of Rice (rice blast fungus (Magnaporc) soybean rust (Phakopso) ra pachyrhizi), Glume Blotch of Wheat (Glume Blotch of Wheat fungus (Leptospermum erythrorhizon)) Osphaeria nodorum, also known as powdery mildew of wheat. Barley powdery mildew (Powdered barley fungus: Blumeria graminis f. sp. tritici), Barley powdery mildew fungus (Blumeria graminis f. sp. hordei), Powdery mildew of cucurbits (Erysiphe ci) choracearum), Anthracnose of Cucurbits (Glo merella lagenarium)), Leaf Spot of Beet (C Ercospora beticola, also known as early blight of tomato (tomato ring spot disease fungus). (Alternaria solani), Net Blotch of Barley (Pyrrhus solani) Enophora teres), Downy Mildew of vegetables (a species of the genus Enophora) (Peronospora spp.), Downy Mildew of Brassicas (Commelina communis) Species of the genus Peronospora (Peronospora spp.), Downy Mildew of Cucurbits (Ts) Species of the genus Peronospora (Peronospora spp.), Gray Mold of Grape (gray) (Botrytis cinereal), Gray Mold of Vegetables Gray mold (Botrytis cinereal) and banana black sigatoka disease (Banana Black Sigatoka disease) It is one of the Toka (banana black cigatoka pathogens (Mycosphaerella fijiensis)) bacteria.

[0391] In some embodiments, plant or soil diseases include leaf spot, tea rust, yellow rust, and powdery mildew. Diseases, downy mildew, gray mold, Asian soybean rust, and black sedge It is one of the Toka diseases.

[0392] In some embodiments, the plant is a crop. The methods of the present invention are not limited to these, Monocotyledonous plants such as sugarcane, cereals, rice, maize (corn), and / or biscuits. Dicotyledonous crops such as sugar beets or fodder beets; fruits (pears, drupes, etc.) Or soft fruits, such as apples, pears, plums, peaches, almonds, cherries, Strawberries, raspberries, or blackberries; legumes (beans, lentils, etc.); Soybeans, etc.); oily plants (rapeseed, mustard, poppy, olive, sunflower, yam). Castor oil plants, cocoa beans, or peanuts, etc.; cucumber plants (mallow, cucumber) Lily or melon, etc.; fiber plants (cotton, flax, hemp, or jute, etc.); citrus fruits (Oranges, lemons, grapefruits, or mandarins, etc.); vegetables (hore Greens, lettuce, cabbage, carrots, tomatoes, potatoes, cucurbits, or paprika Mosquitoes, etc.; Lauraceae family (avocado, cinnamon, or camphor, etc.); tobacco; nuts Coffee; tea; climbing plants; hops; durian; bananas; natural rubber plants; and ornamental plants It can be used on any crop, including plants (flowers, shrubs, broad-leaved trees, or evergreen trees, such as conifers). It is possible.

[0393] In some embodiments, the plant is a monocotyledonous plant, more preferably a cereal. Specific Embodiments In this particular embodiment, the cereal is wheat. In another specific embodiment, the cereal is rye wheat. In one particular embodiment, the cereal is rye. In another specific embodiment, the cereal is oats. In further embodiments, the cereal is barley. In another specific embodiment, the cereal is In another embodiment, the crop is rice. In yet another embodiment, In yet another embodiment, the crop is corn.

[0394] In another embodiment, the crop is a dicotyledonous plant.

[0395] In one embodiment, the crop is rapeseed.

[0396] The combinations, mixtures, or compositions disclosed herein are, in their entirety, referred to in this application. The referenced U.S. Patent Application Publication No. 2018-0000082 (published January 4, 2018) It can also be used as a seed treatment to prevent or control the plant pathogenic fungi described above. .

[0397] In some embodiments, the present invention includes at least one combination, mixture, or composition of the present invention. Further includes additional insecticides. In some embodiments, the insecticide is a fungicide, herbicide, or insecticide. It is a pesticide, a mite exterminator, or nematode anthelmintic.

[0398] In some embodiments, the present invention includes at least one combination, mixture, or composition of the present invention. It also contains a disinfectant.

[0399] In some embodiments, the bactericide is a bactericidal sterol biosynthesis inhibitor.

[0400] In some embodiments, the sterol biosynthesis inhibitor is prothioconazole, epoxyconazole Zole, cyproconazole, mycrobutanil, prochloraz, metconazole, dipheno Conazole, Tebuconazole, Tetraconazole, Fenbuconazole, Propiconazole Fluquinconazole, flucilazole, flutriafole, and fenpropimol It is selected from the group consisting of F.

[0401] In some embodiments, the sterol biosynthesis inhibitor is prothioconazole, epoxyconazole Zol, metconazole, difenoconazole, propiconazole, prochloraz, teto Laconazole, Tebuconazole, Fenpropimorph, Fenpropidine, Ipconazole L, triticonazole, spiroxamine, fenhexamide, and fenpyrazamine Selected from the following group.

[0402] In some embodiments, the sterol biosynthesis inhibitor is prothioconazole. In the application form, the sterol biosynthesis inhibitor is epoxyconazole. In some embodiments, The sterol biosynthesis inhibitor is cyproconazole. In some embodiments, sterol The biosynthesis inhibitor is mycrobutanil. In some embodiments, the sterol biosynthesis inhibitor is The inhibitor is metconazole. In some embodiments, the sterol biosynthesis inhibitor is difenoconazole. It is a sterol. In some embodiments, the sterol biosynthesis inhibitor is propiconazole. In some embodiments, the sterol biosynthesis inhibitor is prochloraz. In some embodiments, the sterol biosynthesis inhibitor is tetraconazole. The sterol biosynthesis inhibitor is tebuconazole. In some embodiments, a sterol biosynthesis inhibitor is used. It is fluquinconazole. In some embodiments, the sterol biosynthesis inhibitor is fluquinconazole. It is a zole. In some embodiments, the sterol biosynthesis inhibitor is flutriahole. In some embodiments, the sterol biosynthesis inhibitor is fenpropimorph. In the application form, the sterol biosynthesis inhibitor is fenpropidine. In some embodiments, The sterol biosynthesis inhibitor is ipconazole. In some embodiments, sterol biosynthesis The sterol biosynthesis inhibitor is triticonazole. In some embodiments, the sterol biosynthesis inhibitor is It is pyroxamine. In some embodiments, the sterol biosynthesis inhibitor is fenhexamide. In some embodiments, the sterol biosynthesis inhibitor is fenpyrazamine. In this embodiment, the sterol biosynthesis inhibitor is fenbuconazole.

[0403] In some embodiments, the bactericide is a succinate dehydrogenase inhibitor.

[0404] In some embodiments, succinate dehydrogenase inhibitors include benzovinyl flupirin, pe Nthiopyrad, isopyrazam, fluxapiroxad, boscalid, fluopyram, bixa The group is selected from fen and penflufen.

[0405] In some embodiments, the succinate dehydrogenase inhibitor is benzovindiflupyr. In some embodiments, the succinate dehydrogenase inhibitor is penthiopyrad. In some embodiments, the succinate dehydrogenase inhibitor is isopyrazam. In some embodiments, the succinate dehydrogenase inhibitor is fluxapyroxade. In this case, the succinate dehydrogenase inhibitor is boscalid. In some embodiments, succinate The citrate dehydrogenase inhibitor is fluopyram. In some embodiments, succinate dehydrogenase inhibitors are used. The dragenase inhibitor is bixafen. In some embodiments, dehydrogenase succinate is used. The enzyme inhibitor is penflufen.

[0406] In some embodiments, the fungicide is a strobilurin-based fungicide.

[0407] In some embodiments, the strobilurin-based fungicide is azoxystrobin, pyracloth Robin, picoxystrobin, fluoxastrobin, trifloxystrobin, creso Selected from the group consisting of ximemethyl, dimoxystrobin, and orysastrobin. .

[0408] In some embodiments, the strobilurin fungicide is azoxystrobin. In terms of application methods, the strobilurin-based fungicide is pyraclostrobin. In some embodiments, The strobilurin-based fungicide is picoxystrobin. In some embodiments, strobil The strobilurin-based fungicide is fluoxastrobin. In some embodiments, strobilurin-based The fungicide is trifloxystrobin. In some embodiments, a strobilurin-based fungicide is used. It is kresoxime methyl. In some embodiments, the strobilurin-based fungicide is dimoxy It is strobin. In some embodiments, strobilurin-based fungicides are used with orysastrobin. be.

[0409] In some embodiments, the bactericide is a bactericidal multipoint inhibitor.

[0410] In some embodiments, the bactericidal multipoint inhibitor is mancozeb, chlorothalonil, forpet T, captan, methylam, maneb, propineb, copper hydroxide, copper octanoate, oxysalt Copper oxide, copper sulfate, copper sulfate (tribase), mancopper, copper oxide, bis(3-phenylsulfate) Chilates) copper, zinc copper chromate, cuprous oxide, copper hydrazinium sulfate, and cuprobum Selected from the group consisting of (cuprobam).

[0411] In some embodiments, the bactericidal multipoint inhibitor is mancozeb. In some embodiments, The fungicidal multipoint inhibitor is chlorothalonil. In some embodiments, the bactericidal multipoint inhibitor is fo It is lupet. In some embodiments, the bactericidal multipoint inhibitor is captan. In the application method, the bactericidal multipoint inhibitor is methilam. In some embodiments, bactericidal multipoint inhibitor The agent is maneb. In some embodiments, the bactericidal multi-point inhibitor is propineb. In this embodiment, the bactericidal multipoint inhibitor is copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, Copper sulfate (tribase), mancopper, oxine copper, bis(3-phenylsalicylate) copper, These are zinc copper chromate, cuprous oxide, copper hydrazinium sulfate, or cuprobum.

[0412] In some embodiments, the combination, mixture, or composition further comprises an insecticide.

[0413] In some embodiments, the insecticide is 2-(thiocyanatomethylthio)-benzothiazo Lu, 2-phenylphenol, 8-hydroxyquinoline sulfate, ametoctrazine, amiso Rubrom, antimycin, Ampelomyces quisqualis, azacona Zole, azoxystrobin, Bacillus subtilis, Bacillus subtilis strain QST713, Benalaxyl, Benomyl, Bentiavaricarb Isopropyl, Benzylaminobenzenes BABS salt, bicarbonate, biphenyl, bismelthiazole, biternol Bixafen, Blastsaidin S, Borax, Bordeaux mixture, Boscalid, Bromconazole Calcium, bupirimate, calcium polysulfide, captafor, captan, carbendazim Carboxine, carpropamide, carvone, chlazafenone, chlorone Coniothyrium min Itans), copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, copper sulfate (tribase), copper oxide Copper monocoque, cyazofamide, cyflufenamide, cymoxanil, cyproconazole, cyprodi Nyl, dazomet, debacarb, diammonium ethylenebis(dithiocarbamate), Diclofluanide, dichlorophene, diclocimet, diclomedin, dichlorane, die Tofencarb, difenoconazole, diphenzocort ion, diflumetrim, dime Tomorph, Dimoxystrobin, Diniconazole, Diniconazole M, Dinovton, Di Nocap, diphenylamine, dithianone, dodemorph, dodemorph acetate, dozin, dozin Free base, edifenphos, enestrobin, enestrobrin, epoxyconazole , etaboxam, ethoxyquin, etridiazole, famoxadone, fenamidon, Fenalimol, fenbuconazole, fenflam, fenhexamide, phenoxanil Fenpiclonil, fenpropidine, fenpropimorph, fenpyrazamine, fe Thin, triphenyltin acetate, triphenyltin hydroxide, felbam, ferrimzon, Fluazinam, fludioxonil, flumorph, fluopicolide, fluopyram, fluo Luimide, fluoxastrobin, fluquinconazole, flucilazole, flusulfa Mido, fluthianil, fluthranil, flutriol, fluxapiroxad, folpe Formaldehyde, fosetyl, fosetyl-aluminum, fuberidazole, flara Xyl, Flamethopyr, Guazatin, Guazatin Acetate, GY-81, Hexachloroben Zen, hexaconazole, himexazole, imazalil, imazalil sulfate, imibencone Nazol, iminoctadine, iminoctadine triacetate, iminoctadine albesylate, Iodocarb, ipconazole, ipfenpyrazolone, iprobenphos, Iprodione, iprovalicarb, isoprothiolane, isopyrazam, isothianil, Sugamicin, Kasugamycin hydrochloride monohydrate, Kresoxim methyl, Laminarin, Man Copper, mancozeb, mandipropamide, maneb, mephenoxamin, mepanipyrim Mepronil, Meptyldinocap, Mercuric Chloride, Mercury Oxide, Mercurous Chloride, Metalaxy Metam, Metamammonium, Metampotassium, Metamsodium Metconazole, metasulfocarb, methyl iodide, methyl isothiocyanate, methyl Metminostrobin, Metraphenone, Mildiomycin, Microbutanil, Nabam Nitrotar isopropyl, Nualimol, Octylinone, Offrace, Oleic acid (fat) Acid, Orysastrobin, Oxadixyl, Oxygen Copper, Oxpoconazole Fumarate Oxycarboxyne, pefurazoate, penconazole, pencyclon, penflufe Pentachlorophenol, pentachlorophenyl laurate, penthiopyrad, acetic acid Phenylmercury, phosphonic acid, phthalide, picoxystrobin, polyoxin B, polyox Syn, polyoxin-D (polyoxorim), potassium bicarbonate, potassium hydroxyquinoline sulfate Um, probenazole, prochloraz, procymidone, propamocarb, propamocarb Hydrochloride, propiconazole, propineb, proquinazide, prothioconazole, pyracol Strobin, pyrametostrobin, pyroxystrobin, pyrazophos, pyrizencarb Pyributicarb, Pyriphenox, Pyrimethanil, Pyriophenone, Pyrroquilon, K Nocramin, quinoxyfen, quintozen, Japanese knotweed extract (Reynoutria sachaline) Nsis extract, sedaxane, silthiofamm, simeconazole, sodium 2-phenotype Luphenoxide, sodium bicarbonate, sodium pentachlorophenoxide, spiroxane Min, sulfur, SYP-Z048, tar oil, tebuconazole, tebufloxin, technazen Tetraconazole, thiabendazole, tifluzamide, thiophanate-methyl, thyram , thiadinyl, tolclophosmethyl, tollylfluanide, triadimephon, triadimeno Triazoxide, tricyclazole, tridemorph, trifloxystrobin, Riflumiso, triforine, triticonazole, validamycin, valifenarate, Valifenal, vinclozoline, zineb, ziram, zoxamide, Candida oleofib Candida oleophila, Fusarium oxysporum, Glycine Gliocladium spp., Phlebiopsis gigantea Streptomyces griseoviridis, Trichoderma spp., (RS)-N-(3,5-dichlorophenyl)- 2-(methoxymethyl)succinimide, 1,2-dichloropropane, 1,3-dichloro -1,1,3,3-tetrafluoroacetone hydrate, 1-chloro-2,4-dinitronaph Talene, 1-chloro-2-nitropropane, 2-(2-heptadecyl-2-imidazoline) -1-yl)ethanol, 2,3-dihydro-5-phenyl-1,4-dithiine, 1,1 ,4,4-tetraoxide, 2-methoxyethylmercury acetate, 2-methoxyethylmercury chloride , 2-methoxyethylmercury silicate, 3-(4-chlorophenyl)-5-methylrhodanine, 4-(2-nitropropa-1-enyl)phenylthiocyanate, ampropylphos, a Nirazine, Ajichiram, Polybarium sulfide, Bayer 32394, Benodanil, Benki Knox, Bentalon, Benzamacryl, Benzamacryl-isobutyl, Benzamorph , Binapacril, Bis(methylmercury) sulfate, Bis(tributyltin) oxide, Butiobe Cadmium calcium copper zinc chromate sulfate (cadmium calcium copper zinc (inc chromate sulfate), carbamorph, CECA, cloventiazone, chloraniform Tan, chlorphenazole, chlorquinox, crimbazole, bis(3-phenylalanine) Copper lysate, zinc copper chromate, cufraneb, copper hydrazinium sulfate, cuprobum, cyclamate Laflamid, cypendazole, cyproflam, decafentin, diclozol, diclozoline Diclobutrazol, Dimethylmol, Dinoctone, Dinosulfone, Dinoterbone, Di Pyrithione, ditalimphos, dodjicin, dorazoxolone, EBP, ESBP, etaconazole Fluorine, etem, ethilim, phenaminosulf, phenapanyl, fenitropan, fluoto Limazole, Flucarbanil, Fluconazole, Fluconazole-cis, Flumecyclo Kus, flofanate, glyodine, griseofulvin, halacrinate, Hercules3944, hexylthiophos, ICIA0858, isopamphos, i Sobarezion, Mebenil, Mecarbinzide, Metazoxolone, Metofloxamin, Methyl water Silver dicyandiamide, metosulfovax, milneb, mucochloran anhydride, micro Zoline, N-3,5-dichlorophenylsuccinimide, N-3-nitrophenylitaco N-imide, natamycin, N-ethyl mercurio-4-toluenesulfonanilide, nitrate Kelvis (dimethyldithiocarbamate), OCH, phenylmercury dimethyldithiocarbamate Mate, phenylmercury nitrate, phosdifen, prothiocarb, prothiocarb hydrochloride, Pyracarboride, pyridinitrile, pyroxycyclol, pyroxiflu, quinacetol, sulfuric acid Kinasetol, quinazamide, quinconazole, ravenzazole, salicylanilide, SS F-109, sultropene, tecolam, thiadifluor, thyiophene, thiochlorfe Nhim, thiophanate, thioquinox, thioximide, triamiphos, trialimol , triazbutyl, triclamide, urbasid, zarilamide, and any combination thereof Selected from the group consisting of "se".

[0414] In some embodiments, the insecticide is an insecticide. In some embodiments, the insecticide is a mite It is a pesticide. In some embodiments, the insecticide is a nematicide. In some embodiments, Insecticides are herbicides.

[0415] Examples of insecticides and acaricides include, but are not limited to, abamectin (ab amectin, pyriproxyfen, acetamiprid, bifenthrin, cyfluthrin, pi Pymetrozine, novaluron, ethiprole Examples include fipronil and lambda-cyhalothrin.

[0416] Examples of nematicides, though not limited to this, include fluensulfone. It can be listed.

[0417] Applying this combination, mixture, or composition to fungi or the locations where they are present is not permitted. Yes, it is possible. Applications include conventional ground sprayers and granule applicators. This can be done by using cators and by other customary means known to those skilled in the art. Cut.

[0418] Each embodiment disclosed herein is applicable to each other disclosed embodiment. It is intended to be used as such. Therefore, all combinations of the various elements described herein are intended to be used as such. It is within the scope of the invention. In addition, the elements listed in the combined embodiments are as described herein. It can be used in compounds, compositions, methods, and embodiments of use, and vice versa. .

[0419] Calculation of synergistic effects Whenever the combined effect of a combination of active ingredients is greater than the sum of the effects of its individual components, a synergistic effect occurs. A specific effect exists.

[0420] In the field of agriculture, the term "synergy" originated in the journal Weeds, 1967, 15, pp. 20-22. The title displayed is "Calculation of the synergistic and antagonistic responses of the As defined by Colby SR in the article "rbicide combinations" This is often understood. The expected effects of a given combination of two active components are as follows: It can be calculated as follows:

[0421]

number

[0422] Although this subject is shown and described with reference to its preferred embodiments, many alternatives Alternatives, changes, and modifications may be made without exceeding the spirit and scope of the work. This will be understood by those skilled in the art. Therefore, the spirit and broad scope of the attached claims are It is intended to encompass all such alternatives, changes, and modifications.

[0423] All publications, patents, and patent applications described herein are as if they were each Individual publications, patents, or patent applications are specifically and individually incorporated herein by reference. To the same extent that they are shown to be incorporated herein by reference, It will be done.

[0424] The following examples illustrate the implementation of the subject matter in some embodiments, but the scope of the subject matter is limited. It should not be construed as limiting. Other embodiments are described in the specification and examples. This will be understood by those skilled in the art through consideration. This specification, including examples, is within the scope of the subject matter. It is intended to be considered illustrative only, without limiting its scope or spirit.

[0425] Experiment Section material and method The compound of formula I is described in International Publication No. 2015 / 103144 and the same publication No. 201 It can be prepared as described in pamphlet No. 5 / 103142. Pydiflumetofen (ADEPYDIN®, Synge nta)-Tween 0.05% of 80 Fluindapyr-Tween 0.05% Mefentrifluconazole-Tween 0.05 in 80 % Fenpicoxamide-Tween 80: 0.05% Inpyrfluxam-Tween 0.05% of 80 Isofetamid-Tween 80 contains 0.05%

[0426] Compounds of formula I, and fluindapyr, pydiflumetof en), mefentrifluconazole, fenpicoxamide (fen picoxamid, impyrfluxam, and isofetamide A mixture of fungicides selected from the group consisting of the following is used in BBCH 12 growth stages. Treat winter wheat plants, cultivated variety Alixan (Limagrain).

[0427] The compound of formula I and the fungicide (A) were used in different ratios and weight ratios in a handheld sprayer. Depending on the instrument, calibrate to 2 bar and apply. Regarding the test conditions, 3 of the six wheat plants... Use a pot (iteration) 1 time.

[0428] Cut the first leaf fragment and transfer it to a petri dish containing the adapted agar (one petri dish) (Six leaf fragments per unit). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. Inoculate with a calibrated spore suspension.

[0429] After vaccination, place the petri dish in an artificial climate chamber (20°C during the day / 17°C at night - 16 hours of light / 8 Cultivate under controlled conditions (day length during dark periods, relative humidity). Disease evaluation is based on the length of necrotic leaf fragments. The procedure is performed at 21 days (dpi) and 28 dpi after vaccination by measuring the saturation. Then, The intensity of infection is determined by the percentage of the total length of the leaf fragment.

[0430] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, Calculate the effectiveness. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method is applied to each time interval.

[0431] The bactericidal effect is determined from the AUDPC value and expressed as a percentage of the untreated control.

[0432] [Example 1] Synergistic effect of a mixture of the compound of formula I and mefentrifluconazole test The compounds of formula I and mefentrifluconazole are listed in the table below. The spraying was carried out according to step 1.

[0433] [Table 1]

[0434] I have the compound of formula I and mefentrifluconazole on hand. The sprayer is calibrated to 2 bar to deliver an equivalent volume of 200 L / ha and applied. The treatment was applied by spraying. Each treatment group used three replicates (pots) of six wheat plants.

[0435] The first leaf fragment was cut and transferred to a petri dish containing adapted agar (one petri (Six leaf fragments per plate). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. The calibrated spore suspension was inoculated.

[0436] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The plants were cultured in an artificial climate chamber with controlled day length and relative humidity. Disease evaluation was performed on leaf fragments. By measuring the length of necrotic tissue, the procedure was performed at 21 days (dpi) and 28 dpi after vaccination. Next, the intensity of infection was determined as a percentage of the total length of the leaf fragments.

[0437] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, The effectiveness was calculated. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method was applied to each time interval.

[0438] The bactericidal effect was determined from the AUDPC value and expressed as a percentage of the untreated control.

[0439] The results are shown in Table 2 and Figure 1.

[0440] [Table 2]

[0441] [Example 2] Synergistic test of a mixture of the compound of formula I and fenpicoxamide. The compound of formula I and fenpicoxamide are prepared according to Table 3 below. I used it.

[0442] [Table 3]

[0443] The compound of formula I and fenpicoxamide were dispensed using a handheld sprayer. Each was calibrated to 2 bar to deliver an equivalent volume of 200 L / ha and applied. Three replicates (in pots) of wheat plants were used for each treatment group.

[0444] The first leaf fragment was cut and transferred to a petri dish containing adapted agar (one petri (Six leaf fragments per plate). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. The calibrated spore suspension was inoculated.

[0445] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The plants were cultured in an artificial climate chamber with controlled day length and relative humidity. Disease evaluation was performed on leaf fragments. By measuring the length of necrotic tissue, the procedure was performed at 21 days (dpi) and 28 dpi after vaccination. Next, the intensity of infection was determined as a percentage of the total length of the leaf fragments.

[0446] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, The effectiveness was calculated. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method was applied to each time interval.

[0447] The bactericidal effect was determined from the AUDPC value and expressed as a percentage of the untreated control.

[0448] The results are shown in Table 4 and Figure 2.

[0449] [Table 4]

[0450] [Example 3] Synergistic test of a mixture of compound I and fluindapyr The compound of formula I and fluindapyr were applied according to Table 5 below. .

[0451] [Table 5]

[0452] The compound of formula I and fluindapyr were sprayed using a handheld sprayer for 20 minutes. It was calibrated to 2 bar and applied to deliver an equivalent volume of 0 L / ha. Each of the six combs Three replicates (in pots) of the plant were used for each treatment group.

[0453] The first leaf fragment was cut and transferred to a petri dish containing adapted agar (one petri (Six leaf fragments per plate). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. The calibrated spore suspension was inoculated.

[0454] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The plants were cultured in an artificial climate chamber with controlled day length and relative humidity. Disease evaluation was performed on leaf fragments. By measuring the length of necrotic tissue, the procedure was performed at 21 days (dpi) and 28 dpi after vaccination. Next, the intensity of infection was determined as a percentage of the total length of the leaf fragments.

[0455] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, The effectiveness was calculated. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method was applied to each time interval.

[0456] The bactericidal effect was determined from the AUDPC value and expressed as a percentage of the untreated control.

[0457] The results are shown in Table 6 and Figure 3.

[0458] [Table 6]

[0459] [Example 4] Synergistic test of a mixture of compound I and pydiflumetofen BBCH 12 Winter wheat plants in growth stage, cultivar Alixan (Limagr ain) is a compound of formula I and several ratios of pydiflumetofen. The mixture is calibrated to 2 bar to deliver an equivalent volume of 200 L / ha. Treatment was performed using a type 2 sprayer. Compound I was applied at a concentration of 5 g ai / ha. Metofen (pydiflumetofen) in concentrations of 0.00032-0.0016 and 0.008 g Applied to .i. / ha. Each of the 6 wheat plants was tested in 3 replicates (pots). Used in the set of conditions.

[0460] After treatment, the wheat plants were dried at room temperature for 1 hour, and then subjected to a temperature of 24°C during the day and 18°C ​​at night. In an artificial climate chamber with a day length of 16 hours of light / 8 hours of dark and a relative humidity of 65% The culture was performed. A fragment of the first leaf was cut and transferred to a petri dish containing adapted agar (1 Six leaf fragments per petri dish. The fragments contain the wheat pathogen (Z. tritici) strain Mg Tr Calibrated i-R6 spore suspension was inoculated.

[0461] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The cells were cultured in an artificial climate chamber with controlled day length and relative humidity.

[0462] Disease assessment is performed by measuring the length of necrotic leaf fragments 21 days (dpi) after inoculation. The scans were performed at 28 dpi. Then, the intensity of infection was determined as a percentage of the total length of the leaf fragment. did.

[0463] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, The effectiveness was calculated. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method was applied to each time interval.

[0464] The bactericidal effect was determined from the AUDPC value and expressed as a percentage of the untreated control.

[0465] The results are shown in Table 7 and Figure 4.

[0466] [Table 7]

[0467] [Example 5] Synergistic test of a mixture of compound I and inpyrfluxam BBCH 12 Winter wheat plants in growth stage, cultivar Alixan (Limagr ain) is a compound of formula I and several ratios of inpyrfluxam The mixture was calibrated to 2 bar to deliver an equivalent volume of 200 L / ha. Treatment is performed using a sprayer. Each of the six wheat plants was tested in three replicates (pots). Used for conditional groups.

[0468] Cut the first leaf fragment and transfer it to a petri dish containing the adapted agar (one petri dish) (Six leaf fragments per unit). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. Inoculate with a calibrated spore suspension.

[0469] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The plants are cultured in an artificial climate chamber with controlled day length and relative humidity. Disease evaluation is performed on leaf fragments. By measuring the length of necrotic tissue, the procedure was performed at 21 days (dpi) and 28 dpi after vaccination. Next, the intensity of infection is determined as a percentage of the total length of the leaf fragment.

[0470] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, Calculate the effectiveness. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method is applied to each time interval.

[0471] The bactericidal effect is determined from the AUDPC value and expressed as a percentage of the untreated control.

[0472] The result was a mixture of the compound of formula I and inpyrfluxam, obtained by two methods. This shows a synergistic effect against the wheat pathogen (Z. tritici) strain Mg Tri-R6. vinegar.

[0473] [Example 6] Synergistic test of a mixture of compound I and isofetamide. BBCH 12 Winter wheat plants in growth stage, cultivar Alixan (Limagr Mix a) with the compound of formula I and isofetamide in several ratios. A handheld sprayer calibrated to 2 bar to deliver an equivalent volume of 200 L / ha using a compound. Treatment was performed according to the machine. Each condition group was tested with 3 replicates (pots) of 6 wheat plants. It is used for this purpose.

[0474] Cut the first leaf fragment and transfer it to a petri dish containing the adapted agar (one petri dish) (Six leaf fragments per unit). The fragments contain the wheat pathogen (Z. tritici) strain Mg Tri-R6. Inoculate with a calibrated spore suspension.

[0475] After vaccination, the petri dish should be kept at a temperature of 20°C during the day and 17°C at night, with a 16-hour light period and an 8-hour dark period. The plants are cultured in an artificial climate chamber with controlled day length and relative humidity. Disease evaluation is performed on leaf fragments. By measuring the length of necrotic tissue, the procedure was performed at 21 days (dpi) and 28 dpi after vaccination. Next, the intensity of infection is determined as a percentage of the total length of the leaf fragment.

[0476] Based on the area under the disease progression curve (AUDPC), which is a quantitative measure of disease severity over time, Calculate the effectiveness. This is the most commonly used method to estimate AUDPC. This involves multiplying the average disease intensity between adjacent points in time by the corresponding time interval. The trapezoidal method is applied to each time interval.

[0477] The bactericidal effect is determined from the AUDPC value and expressed as a percentage of the untreated control.

[0478] The result was that a mixture of the compound of formula I and isofetamide was obtained using two methods. This study demonstrates a synergistic effect against the Mg Tri-R6 strain of the pathogenic bacterium Z. tritici.

[0479] conclusion As shown, the combination of the compound of formula I with the fungicide (A) (where fungicide (A) is selected from the group consisting of fluindapyr, pydiflumetofen, mefentrifluconazole, fenpicoxamid, inpyrfluxam, and isofetamide) demonstrates a potent synergistic effect. The invention described in the original claims of this application is listed below. [1] (i) A predetermined amount of compound I and [ka] (ii) A prescribed amount of at least one bactericide (A) selected from the group consisting of fluindapyr, pydiflumetofen, mefentrifluconazole, inpyrfluxam, isofetamide, and Qi inhibitors. A combination of sterilization products, including those mentioned above. [2] a) The combination is more effective than when each fungicide is applied individually in the same amount in the treatment of a plant or a place where a plant is present against a fungal infection. b) When the specified amount of compound I and the specified amount of fungicide (A) are applied together, they are more effective in treating a plant or a place where a plant is present against a fungal infection than when each fungicide is applied alone in the same amount, and / or c) The amount of compound I used is less than the effective bactericidal amount of compound I when used alone, and / or the amount of bactericide (A) used is less than the effective bactericidal amount of bactericide (A) when used alone. [1] The combination described above. [3] The combination according to [1] or [2], wherein the Qi inhibitor is cyazoimidazole, sulfamoyltriazole, or picolinamide. [4] The combination according to [3], wherein the cyazoimidazole is cyazofamide, the sulfamoyltriazole is amisulfrom, or the picolineamide is fenpicoxamide. [5] A combination of any of the following [1] to [4], wherein the weight ratio of the compound of formula I to the fungicide (A) is approximately 400:1 to 1:400. [6] A combination of any of [1] to [5], wherein the weight ratio of the compound of formula I to the fungicide (A) is approximately 10:1 to 1:10. [7] A combination of any of the items in [1] to [6] that has a synergistic effect on treating plants or the locations where plants are present against fungal infections. [8] A combination of any of the [1] to [7] having a synergistic therapeutic effect and / or synergistic protective effect. [9] A combination according to any one of [1] to [8], further comprising at least one insecticide, at least one stabilizing surfactant, and / or at least one botanically acceptable adjuvant.

[10] A mixture containing any of the combinations described in [1] to [9].

[11] The mixture according to

[10] , wherein the mixture is a tank mix.

[12] A composition comprising any combination described in [1] to [9].

[13] a) The composition contains a compound of formula I in an amount ranging from about 0.1% to 90% by weight based on the total weight of the composition, and / or b) The composition contains the bactericide (A) in an amount ranging from about 0.1% to 90% by weight based on the total weight of the composition. The composition described in

[12] .

[14] The composition according to

[12] or

[13] , further comprising a botanically acceptable carrier.

[15] A method for treating a plant or a place where a plant is present against fungal infection, comprising (i) a predetermined amount of a compound of formula I,

change

[16] A method for treating a plant or a place where a plant is present against a fungal infection, comprising applying an effective amount of any combination, mixture or composition described in [1] to

[14] to the plant or the place where a plant is present, thereby treating the plant or the place where a plant is present against a fungal infection.

[17] a) The method is more effective than when each fungicide is applied individually in equal amounts in the treatment of a plant or a place where a plant is present against a fungal infection. b) When the predetermined amount of compound I and the predetermined amount of fungicide (A) are applied together, they are more effective in treating plants or places where plants are present against fungal infection than when each fungicide is applied individually in the same amount. c) The amount of compound I used is less than the effective bactericidal amount of compound I when used alone, and / or the amount of bactericide (A) used is less than the effective bactericidal amount of bactericide (A) when used alone. d) The method is effective in controlling fungal infections of the plant or the location where the plant is present, and / or e) The method is effective in protecting the plant or the location where the plant is present from fungal infection. The method described in

[15] or

[16] .

[18] a) Controlling fungal infections includes controlling fungal diseases that infect the plant or the place where the plant is located, controlling plant or soil diseases caused by plant pathogens, controlling fungal invasion of the plant or the place where the plant is located, reducing fungal infections of the plant or the place where the plant is located, and / or treating plant or soil diseases caused by plant pathogens. b) Protecting the plant or the location where the plant is present from fungal infection includes protecting the plant or the location where the plant is present from fungal invasion, protecting the plant or the location where the plant is present from fungal diseases, and / or preventing fungal infection of the plant or the location where the plant is present. The method described in

[17] .

[19] a) The compound of formula I and the fungicide (A) are applied to the plant's propagation material, b) The compound of formula I and the fungicide (A) are applied to the seeds and / or seedlings of the plant, c) The method includes the application of the compound of formula I and the bactericide (A) for the purpose of protection, d) The method includes the therapeutic application of the compound of formula I and the bactericide (A), e) When the compound of formula I and the fungicide (A) are applied simultaneously or at the same time, f) The compound of formula I and the fungicide (A) are applied separately or together. g) The method described above is effective in reducing leaf necrosis. h) The compound of formula I is applied in amounts of 1 g / ha to 500 g / ha, and / or i) The fungicide (A) is applied in amounts of 0.1 g / ha to 500 g / ha. The method described in any of

[15] to

[18] .

[20] The method according to any of

[15] to

[19] , wherein the compound of formula I is applied in an amount of 5 g / ha to 10 g / ha.

[21] a) Fluindapyr is administered in the range of 0.1 g / ha to 150 g / ha. b) Pydiflumetofen is applied in a range of 0.0001 g / ha to 150 g / ha. c) Mefentrifluconazole is administered in a range of 0.1 g / ha to 150 g / ha. d) A Qi inhibitor, preferably fenpicoxamide, is applied in a range of 0.1 g / ha to 150 g / ha. e) Inpyrfluxam is applied in the range of 0.1 g / ha to 150 g / ha, or f) Isofetamid is applied in a range of 0.1 g / ha to 150 g / ha. The method described in any of

[15] to

[20] .

[22] A method for controlling a plant disease caused by plant pathogenic fungi, comprising contacting a plant or a place where a plant is present with an effective amount of any combination, mixture or composition described in [1] to

[14] , thereby controlling the plant disease.

[23] A method for controlling fungal invasion of a plant, seed or seedling, comprising applying a combination, composition or mixture described in any of [1] to

[14] to the plant, seed, seedling and / or the location where the plant is present, thereby controlling fungal invasion of the plant, seed or seedling.

[24] A method for controlling fungal invasion of a plant, seed or seedling, comprising applying a combination, mixture or composition described in any of [1] to

[14] to the plant, seed, seedling and / or the location where the plant is present, thereby controlling fungal invasion of the plant, seed or seedling.

[25] A method for producing plants resistant to fungal invasion by treating plants, seeds or seedlings, comprising applying a combination, mixture or composition described in any of [1] to

[14] to the plant, a seed adapted to produce the plant, a seedling adapted to produce the plant, or the location where the plant is present, thereby producing plants resistant to fungal invasion.

[26] A method for protecting a plant from fungal invasion, comprising applying a combination, mixture, or composition described in any of [1] to

[14] to the plant, the location where the plant is located, or seeds or seedlings adapted to produce the plant, thereby protecting the plant from fungal invasion.

[27] A plant resistant to fungal invasion, wherein the seeds adapted to produce the plant, the seedlings adapted to produce the plant, or the location where the plant is located is treated with any combination, mixture or composition described in [1] to

[14] .

[28] Seeds or seedlings of plants adapted to produce plants resistant to fungal invasion, wherein the seeds or seedlings of the plants are treated with any combination, mixture or composition described in [1] to

[14] .

[29] A method for controlling fungal invasion of a plant, comprising applying a combination, mixture, or composition described in any of [1] to

[14] to soil, a plant, roots, leaves, seeds, a place where fungi are present, and / or a place where fungal invasion is to be prevented, thereby controlling fungal invasion of the plant.

[30] A method for controlling fungal diseases of plants and / or soil, comprising applying a combination, mixture or composition described in any of [1] to

[14] to soil, plants, roots, leaves, seeds, places where fungi are present and / or places where fungal invasion is to be prevented, thereby controlling fungal diseases of plants and / or soil.

[31] A method for controlling plant diseases caused by plant pathogenic fungi, comprising (i) a predetermined amount of a compound of formula I,

change

[32] A method for controlling fungal invasion of a plant, seed or seedling, comprising: (i) a predetermined amount of a compound of formula I,

change

[33] A method for protecting a plant, seed or seedling from fungal invasion, comprising: (i) a predetermined amount of a compound of formula I,

change

[34] Use of any combination, mixture or composition described in [1] to

[14] for treating a plant or a place where a plant is present against fungal infection.

[35] A combination, mixture, or composition described in any of [1] to

[14] used to treat a plant or a place where a plant is present against fungal infection.

Claims

1. (i) A compound of formula I, 【Chemistry 1】 (ii) Fluindapyr and Includes, The weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:270.

3. Sterilized combination.

2. The combination according to claim 1, wherein the combination is more effective in treating plants or places where plants are present against fungal infection than when each fungicide is applied individually in equal amounts.

3. The combination according to claim 1 or 2, wherein when the compound of formula I and the fluindapyrus are applied together, they are more effective in treating plants or places where plants are present against fungal infections than when each fungicide is applied individually in equal amounts.

4. The combination according to any one of claims 1 to 3, wherein the amount of compound of formula I used is less than the effective bactericidal amount of compound of formula I when compound of formula I is used alone, and / or the amount of fluindapil used is less than the effective bactericidal amount of fluindapil when fluindapil is used alone.

5. The combination according to any one of claims 1 to 4, wherein the weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:

10.

6. The combination according to any one of claims 1 to 5, wherein the weight ratio of the compound of formula I to flu-indapyrus is 10:1 to 1:

10.

7. A combination according to any one of claims 1 to 6, further comprising at least one insecticide, at least one stabilizing surfactant, and / or at least one botanically acceptable adjuvant.

8. A mixture comprising the combination described in any one of claims 1 to 7.

9. The mixture according to claim 8, wherein the mixture is a tank mix.

10. A composition comprising the combination described in any one of claims 1 to 7 and a botanically acceptable carrier.

11. The composition according to claim 10, wherein the composition contains a compound of formula I in an amount ranging from 0.1% by weight to 90% by weight based on the total weight of the composition.

12. The composition according to claim 10 or 11, wherein the composition contains flu-indapil in an amount ranging from 0.1% by weight to 90% by weight based on the total weight of the composition.

13. A method for treating a plant or a place where a plant is present against infection by the wheat pathogen (Z. tritici), wherein (i) a compound of formula I, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine-2(1H)-one 【Chemistry 2】 Furthermore (ii) Fluindapyr This includes applying the said plant or the place where the plant is located to treat the said plant or the place where the plant is located against infection by the wheat pathogen (Z. tritici), The weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:270.

3. method.

14. A method for treating a plant or a place where a plant is present against wheat pathogen (Z. tritici) infection, comprising applying an effective amount of the combination according to any one of claims 1 to 7, the mixture according to claim 8 or 9, or the composition according to any one of claims 10 to 12 to the plant or the place where a plant is present, thereby treating the plant or the place where a plant is present against wheat pathogen (Z. tritici) infection.

15. The method according to claim 13 or 14, wherein the method is more effective in treating a plant or a place where a plant is present against a wheat pathogen (Z. tritici) infection than when each fungicide is applied individually in equal amounts.

16. The method according to any one of claims 13 to 15, wherein when the compound of formula I and the fluindapyrus are applied together, they are more effective than when each fungicide is applied alone in the same amount in the treatment of a plant or a place where a plant is present against a wheat pathogen (Z. tritici) infection.

17. The method according to any one of claims 13 to 16, wherein the amount of compound of formula I used is less than the effective bactericidal amount of compound of formula I when compound of formula I is used alone, and / or the amount of fluindapil used is less than the effective bactericidal amount of fluindapil when fluindapil is used alone.

18. The method according to any one of claims 13 to 17, wherein the method is effective in controlling a wheat pathogen (Z. tritici) infection of the plant or the place where the plant is located.

19. The method according to any one of claims 13 to 18, wherein the method is effective in protecting the plant or the place in which the plant is located from infection with the wheat pathogen (Z. tritici).

20. The method according to any one of claims 15 to 19, wherein controlling a wheat pathogen (Z. tritici) infection includes controlling a wheat pathogen (Z. tritici) disease that infects the plant or the place where the plant is located, controlling a plant or soil disease caused by wheat pathogens (Z. tritici), controlling the invasion of wheat pathogens (Z. tritici) into the plant or the place where the plant is located, reducing a wheat pathogen (Z. tritici) infection in the plant or the place where the plant is located, and / or treating a plant or soil disease caused by wheat pathogens (Z. tritici).

21. The method according to any one of claims 15 to 20, wherein protecting the plant or the place where the plant is located from wheat pathogen (Z. tritici) infection includes protecting the plant or the place where the plant is located from wheat pathogen (Z. tritici) invasion, protecting the plant or the place where the plant is located from wheat pathogen (Z. tritici) disease, and / or preventing wheat pathogen (Z. tritici) infection of the plant or the place where the plant is located.

22. The method according to any one of claims 13 to 21, wherein the compound of formula I and flu-indapyrus are applied to the plant's reproductive material.

23. The method according to any one of claims 13 to 22, wherein the compound of formula I and fluindapyrus are applied to the seeds and / or seedlings of the plant.

24. The method according to any one of claims 13 to 23, wherein the method includes the application of the compound of formula I and flu-indapyrus for the purpose of protection.

25. The method according to any one of claims 13 to 24, wherein the method includes the therapeutic application of a compound of formula I and fluindapil.

26. The method according to any one of claims 13 to 25, wherein the compound of formula I and flu-indapyrus are applied simultaneously or concurrently.

27. ​​The method according to any one of claims 13 to 26, wherein the compound of formula I and flu-indapyrus are applied separately or together.

28. The method according to any one of claims 13 to 27, wherein the method is effective in reducing leaf necrosis.

29. The method according to any one of claims 13 to 28, wherein the compound of formula I is applied in an amount of 1 g / ha to 500 g / ha.

30. The method according to any one of claims 13 to 29, wherein flu-indapil is applied in an amount of 0.1 g / ha to 500 g / ha.

31. The method according to any one of claims 13 to 30, wherein the compound of formula I is applied in an amount of 5 g / ha to 10 g / ha.

32. The method according to any one of claims 13 to 31, wherein fluindapyr is applied in a range of 0.1 g / ha to 150 g / ha.

33. A method for controlling a plant disease caused by wheat pathogens (Z. tritici), comprising contacting a plant or a location where a plant is present with an effective amount of a combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12, thereby controlling the plant disease.

34. A method for controlling the invasion of wheat pathogen (Z. tritici) into a plant, seedling, or seedling, comprising applying the combination described in any one of claims 1 to 7, the mixture described in claim 8 or 9, or the composition described in any one of claims 10 to 12 to the plant, seedling, seedling, and / or the location where the plant is present, thereby controlling the invasion of wheat pathogen (Z. tritici) into the plant, seedling, or seedling.

35. A method for controlling the invasion of wheat pathogen (Z. tritici) into a plant, seedling, or seedling, comprising applying the combination described in any one of claims 1 to 7, the mixture described in claim 8 or 9, or the composition described in any one of claims 10 to 12 to the plant, seedling, seedling, and / or the location where the plant is present, thereby controlling the invasion of wheat pathogen (Z. tritici) into the plant, seedling, or seedling.

36. A method for producing plants resistant to the invasion of wheat pathogen (Z. tritici) by treating plants, seeds or seedlings, comprising applying a combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12 to the plants, seeds adapted to produce the plants, seedlings adapted to produce the plants, or the location where the plants are present, thereby producing plants resistant to the invasion of wheat pathogen (Z. tritici).

37. A method for protecting a plant from wheat pathogen (Z. tritici) invasion, comprising applying the combination described in any one of claims 1 to 7, the mixture described in claim 8 or 9, or the composition described in any one of claims 10 to 12 to the plant, the location where the plant is located, or seeds or seedlings adapted to produce the plant, thereby protecting the plant from wheat pathogen (Z. tritici) invasion.

38. A plant resistant to fungal invasion, wherein seeds adapted to produce the plant, seedlings adapted to produce the plant, or the location where the plant exists are treated with the combination described in any one of claims 1 to 7, the mixture described in claim 8 or 9, or the composition described in any one of claims 10 to 12.

39. Plant seeds or seedlings adapted to produce plants resistant to fungal invasion, wherein the plant seeds or seedlings are treated with the combination described in any one of claims 1 to 7, the mixture described in claim 8 or 9, or the composition described in any one of claims 10 to 12.

40. A method for controlling the invasion of wheat pathogen (Z. tritici) into plants, comprising applying a combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12 to soil, plants, roots, leaves, seeds, places where wheat pathogen (Z. tritici) is present, and / or places where the invasion of wheat pathogen (Z. tritici) is to be prevented, thereby controlling the invasion of wheat pathogen (Z. tritici) into the plants.

41. A method for controlling wheat pathogen (Z. tritici) disease in plants and / or soil, comprising applying a combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12 to soil, plants, roots, leaves, seeds, places where wheat pathogen (Z. tritici) is present, and / or places where the invasion of wheat pathogen (Z. tritici) is to be prevented, thereby controlling wheat pathogen (Z. tritici) disease in plants and / or soil.

42. A method for controlling plant diseases caused by wheat pathogens (Z. tritici), comprising: (i) a plant, plant reproductive material, or a place where a plant is present, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine-2(1H)-one, which is a compound of formula I. 【Transformation 3】 Furthermore (ii) Fluindapyr This includes bringing the plant into contact with the plant and thereby controlling the plant disease. The weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:270.

3. method.

43. A method for controlling the invasion of a wheat pathogen (Z. tritici) into a plant, seed, or seedling, comprising: (i) a compound of formula I, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine-2(1H)-one, 【Chemistry 4】 Furthermore (ii) Fluindapyr This includes applying the following to control the invasion of wheat pathogen (Z. tritici) into the plants, seeds, or seedlings: The weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:270.

3. method.

44. A method for protecting a plant, seed, or seedling from the invasion of the wheat pathogen (Z. tritici), comprising: (i) a compound of formula I, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidine-2(1H)-one, 【Transformation 5】 Furthermore (ii) Fluindapyr This includes applying the following to protect the plants, seeds, or seedlings from infection by the wheat pathogen (Z. tritici): The weight ratio of the compound of formula I to flu-indapyrus is 12.8:1 to 1:270.

3. method.

45. Use of a combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12 for treating a plant or a place where a plant is present against fungal infection.

46. A combination according to any one of claims 1 to 7, a mixture according to claim 8 or 9, or a composition according to any one of claims 10 to 12, used to treat a plant or a place where a plant is present against fungal infection.

Images