Method for handling flake-like material, and method for producing articles using flake-like material.

Abstract

To provide a new method for operating a flaky substance.SOLUTION: The present invention relates to a method of operating a flaky substance comprises (2) a step of grounding and pressing a first probe whose tip is covered by a first resin film on a flaky substance which is allowed to stand on a substrate in order to pick up the flaky substance, (3) a step of grounding and pressing a second probe whose tip is covered by a second resin film on a surface opposite to the first probe of the flaky substance picked up by the first probe, and (4) a step of separating the first probe from the second probe to deliver the flaky substance picked up by the first probe to the second probe. In the method, (i) a thickness ratio (thickness B / thickness A) of a thickness B of the second resin film to a thickness A of the first resin film when not pressed is less than 1.SELECTED DRAWING: Figure 2

Description

Technical Field

[0001] The present invention relates to a method for manipulating flaky substances, typically two-dimensional substances such as graphene and hexagonal boron nitride, and a method for producing an article using the flaky substance using the manipulation method.

Background Art

[0003] When producing an article using a flaky substance, it may be necessary to invert the flaky substance. To invert the flaky substance, it is convenient to exchange the picked-up flaky substance between probes. <^ And, in order to exchange the flaky substance between probes, (1) The probe on the delivery side must securely hold the flaky substance until the probe on the receiving side is grounded and pressed against the opposite surface of the flaky substance from the probe on the delivery side of the picked-up flaky substance (the probe on the delivery side does not unintentionally release the flaky substance from after pickup until delivery), and <00^00015>(2) When separating both probes and delivering the flaky substance, the probe on the delivery side must securely release the flaky substance, and the probe on the receiving side must securely hold the flaky substance (during delivery, the probe on the delivery side does not unintentionally continue to hold the flaky substance, and after delivery, the probe on the receiving side does not unintentionally release the flaky substance). is necessary. However, it has been difficult to satisfy the requirements (1) and (2) above.

Prior Art Documents

[0004] [Patent Document 1] Special Publication No. 2016-508891 [Non-patent literature]

[0005] [Non-Patent Document 1] Momoko Onodera et al., 2020 Japanese Journal of Applied Physics 59, 010101(2020) [Non-Patent Document 2] Yusai Wakafuji et al., Nano Letters 2020, 20, pp.2486-2492 [Overview of the Initiative] [Problems that the invention aims to solve]

[0006] The object of this invention is to provide a novel method for handling flake-like materials. [Means for solving the problem]

[0007] As a result of diligent research, the inventors have found that the above problem can be solved by using resin films of different thicknesses as covers for the tip of the handing probe and the tip of the receiving probe.

[0008] In other words, the embodiments of the present invention are as follows. [1]. A method for handling flake-like substances, (1) A first probe whose tip is covered with a first resin film, and A step of preparing a second probe whose tip is covered with a second resin film; (2) A step of placing the first probe, whose tip is covered with the first resin film, on the flake-like material that is stationary on the substrate, and pressing it to pick up the flake-like material; (3) A step of grounding and pressing the second probe, whose tip is covered with the second resin film, onto the surface of the flake-like material picked up by the first probe in step (2) above, opposite to the first probe; and, (4) The process includes separating the first probe and the second probe, thereby transferring the flake-like substance picked up by the first probe to the second probe. Here, (i) the thickness ratio (thickness B / thickness A) of the thickness of the second resin film when not pressed is less than 1. The above procedure. [2]. The operating method described in [1] above, wherein the thickness ratio (thickness B / thickness A) is 0.8 or less. [3]. The method of operation described in [1] or [2] above, wherein the flake-like substance is a two-dimensional substance. [4]. The operating method described in any one of the above [1] to [3], wherein both the first resin film and the second resin film are polyvinyl chloride resin films. [5]. The material of the tip of the first probe and the tip of the second probe is a silicone resin. The method of operation according to any one of the above [1] to [4], wherein the flake-like substance is graphene or hexagonal boron nitride. [6]. The above-mentioned first resin film is formed from a polyvinyl chloride resin containing (Aa) 100 parts by mass of polyvinyl chloride resin and (Ab) α parts by mass of plasticizer. The above-mentioned second resin film is formed from a polyvinyl chloride resin containing (Ba) 100 parts by mass of polyvinyl chloride resin and (Bb) β parts by mass of plasticizer. The operation method according to any one of [1] to [5] above, where α > β. [7]. A method for producing an article containing a flaky substance, The production method includes operating the flaky substance using the operation method according to any one of [1] to [6] above.

Effect of the Invention

[0009] The operation method of the flaky substance of the present invention has two requirements for smoothly exchanging the flaky substance between probes: (1) The probe on the delivering side must securely hold the flaky substance until the probe on the receiving side is grounded and pressed against the opposite surface of the delivering side of the picked-up flaky substance (from after the pickup until the delivery, the probe on the delivering side does not unintentionally release the flaky substance), and (2) When separating both probes and delivering the flaky substance, the probe on the delivering side must securely release the flaky substance, and the probe on the receiving side must securely hold the flaky substance (during the delivery, the probe on the delivering side does not unintentionally continue to hold the flaky substance, and after the delivery, the probe on the receiving side does not unintentionally release the flaky substance) can be satisfied. That is, by using the operation method of the flaky substance of the present invention, the exchange of the flaky substance between probes can be surely performed. Therefore, the operation method of the flaky substance of the present invention is very useful when attempting to industrially produce articles containing flaky substances, typically two-dimensional substances such as graphene and hexagonal boron nitride, with good productivity.

Brief Description of the Drawings

[0010] [Figure 1]FIG. 1 is a conceptual diagram showing a probe whose tip is covered with a resin film in a preferred embodiment of the method for manipulating flaky substances of the present invention. [Figure 2] FIG. 2 is a conceptual diagram showing the operation procedures of steps (2) to (4) in a preferred embodiment of the method for manipulating flaky substances of the present invention. [Figure 3-1] FIG. 3-1 is a conceptual diagram showing the operation procedure (first half) of Example 4. [Figure 3-2] FIG. 3-2 is a conceptual diagram showing the operation procedure (second half) of Example 4.

BEST MODE FOR CARRYING OUT THE INVENTION

[0011] In this specification, the term "resin" is used as a term that includes a resin mixture containing two or more resins and a resin composition containing components other than resins.

[0012] In this specification, the term "film" is used interchangeably or replaceably with "sheet". In this specification, the terms "film" and "sheet" are used for those that can be industrially wound into a roll. The term "plate" is used for those that cannot be industrially wound into a roll. Unless otherwise specified, "film" and "sheet" have a uniform thickness throughout. Also in this specification, laminating one layer on top of another layer in order includes both directly laminating those layers and laminating with one or more other layers such as an anchor coat interposed between those layers.

[0013] In this specification, the term "or more" related to a numerical range is used to mean a certain numerical value or more than a certain numerical value. For example, 20% or more means 20% or more than 20%. The term "or less" related to a numerical range is used to mean a certain numerical value or less than a certain numerical value. For example, 20% or less means 20% or less than 20%. The "~" symbol, which indicates a numerical range, is used to mean a certain number, a number greater than a certain number but less than another certain number, or another certain number. Here, the other certain number is a number greater than a certain number. For example, 10~90% means 10%, greater than 10% but less than 90%, or 90%. Furthermore, the upper and lower limits of the numerical range can be arbitrarily combined, and embodiments with such arbitrary combinations can be inferred. For example, from descriptions relating to the numerical range of a certain characteristic, such as "usually 10% or more, preferably 20% or more. On the other hand, usually 40% or less, preferably 30% or less," or "usually 10-40%, preferably 20-30%," it can be inferred that the numerical range of that characteristic in one embodiment is 10-40%, 20-30%, 10-30%, or 20-40%.

[0014] Except in the examples, or unless otherwise specified, all numerical values ​​used in this specification and in the claims should be understood to be modified by the term "about". Without attempting to limit the application of the doctrine of equivalents to the claims, each numerical value should be interpreted in light of significant figures and by applying ordinary rounding methods.

[0015] In this specification, terms used to specify shapes or geometric conditions, such as parallel, orthogonal, and perpendicular, shall include not only their strict meanings but also substantially equivalent conditions.

[0016] In this specification, the term "two-dimensional material" is used not only in its strict sense (material with a thickness of one to several atoms), but also to include laminates in which two to several dozen layers of two-dimensional material in its strict sense are stacked.

[0017] The method for handling the flake-like substance of the present invention is as follows: (1) A first probe whose tip is covered with a first resin film, and A step of preparing a second probe whose tip is covered with a second resin film; (2) A step of placing the first probe, whose tip is covered with the first resin film, on the flake-like material that is stationary on the substrate, and pressing it to pick up the flake-like material; (3) A step of grounding and pressing the second probe, whose tip is covered with the second resin film, onto the side of the flake-like material picked up by the first probe in step (2) above, opposite to the first probe; and, (4) The process includes separating the first probe and the second probe, thereby transferring the flake-like substance picked up by the first probe to the second probe. Herein, (i) the thickness ratio (thickness B / thickness A) of the thickness B of the second resin film and the thickness A of the first resin film is less than 1, which is the operation method described above. The following describes each step.

[0018] Process (1) Step (1) is the step of preparing a first probe whose tip is covered with a first resin film, and a second probe whose tip is covered with a second resin film.

[0019] In step (1), the resin films to be used as the first and second resin films are cut to an appropriate size, and then placed and attached so as to cover the tips of the probes to be used as the first and second probes. The size of the cut resin film is not particularly limited, as long as the tips of the probes, that is, the parts that may come into contact with the flake-like material during pickup and delivery of the material, are completely covered. The method of attachment can be appropriately selected from the viewpoint of preventing the resin film from peeling off or falling off the probe during operation.

[0020] The method for performing the above-mentioned attachment is not particularly limited, but examples include the following: A method for self-adhering the above resin film to the tip of the above probe, A method of interposing an adhesive / glue between the above-mentioned resin film and the tip of the above-mentioned probe. A method of attaching the resin film to the tip of the probe, and then fixing the end of the resin film to the base of the probe or the like using a jig or adhesive tape, and Methods such as these combinations. When performing the above-mentioned attachment, the resin film and / or the probe may be preheated to an appropriate temperature as desired. This preheating temperature varies depending on the material used and is not particularly limited, but may be, for example, 40°C to 200°C. Before performing the above attachment, the surface of the resin film and / or the surface of the tip of the probe may be washed with an appropriate solvent such as isopropanol, ethanol, or acetone.

[0021] We will now describe the probes used as the first and second probes. Figure 1 is a conceptual diagram showing a preferred embodiment of a probe whose tip is covered with a resin film. This preferred embodiment of the probe includes a metal base 1, a glass intermediate member 2 positioned thereon, and a dome-shaped tip 3 made of polydimethylsiloxane positioned thereon. The base 1 has a perforation 4 in the center, and the flake-like material to be manipulated can be observed through the perforation 4 via the probe in the direction of the arrow shown in the figure. The resin film 5 is self-adhesive to the tip portion 3 of the probe, and the end of the resin film 5 is further fixed to the intermediate member 2 of the probe using adhesive tape (not shown).

[0022] The shape and material of the resin film and probe shown in Figure 1 should be understood as one preferred example, and the present invention is not limited thereto. This also applies to the subsequent drawings. For example, the shape and material of the base 1 are not particularly limited, as long as it stably holds the intermediate member 2 and allows it to be freely manipulated; it may be made of a hard resin instead of metal. Also, the shape and material of the intermediate member 2 are not particularly limited, as long as it has an area greater than or equal to the flat surface of the tip 3 and can stably hold it; it may be made of transparent resin instead of glass.

[0023] The shape of the probe tip can be appropriately selected from the viewpoint of preventing gaps from forming between the probe tip and the resin film when the tip is covered with the resin film. Preferably, the probe tip has a curved surface at least near its top. Furthermore, preferably, at least a portion of the probe tip, preferably the entire circumference of the outer edge of the bottom, is flat so as to maintain close contact with the intermediate member that supports the tip. Alternatively, the probe tip may have a flat surface on both its top and the bottom opposite it. The tip of the probe is preferably dome-shaped, from the viewpoint of preventing gaps from forming between the probe tip and the resin film when the tip is covered with the resin film. The term "dome shape" as used in this specification refers to a shape having an outer surface composed of a curved surface almost entirely, preferably an outer surface that does not contain any acute angles of 90 degrees or less. For example, the dome shape may be a shape that forms at least part of a substantially hemisphere or a substantially semi-ellipsoid. The radius of curvature of the tip of the dome shape is not particularly limited, but for example, it may usually be 100 μm or more and 10 cm or less, or 200 μm or more and 5 cm or less, or 300 μm or more and 1 cm or less, or 400 μm or more and 0.5 cm or less.

[0024] The material of the tip of the probe can be appropriately selected from the viewpoint of temperature in each step of the present invention, pressure in step (3), and transparency. The material of the probe tip may preferably be a silicone-based resin such as polydimethylsiloxane, polydiethylsiloxane, polymethylphenylsiloxane, and polydiphenylsiloxane, as well as modified versions thereof.

[0025] The first probe and the second probe may be substantially identical (substantially identical in material and shape), or they may be made of different materials and have different shapes. It is preferable that the first probe and the second probe be substantially identical (substantially identical in material and shape) in order to reduce the number of factors influencing the transfer of the flake-like material from the first probe to the second probe in step (4), thereby improving the predictability of the operation results and ensuring reliable transfer. The first probe and the second probe may be completely identical in material and shape. Furthermore, the first probe and the second probe may have completely identical dome shapes in material and shape.

[0026] The following describes the resin films used as the first and second resin films. The resin film can be appropriately selected from among the types of flake-like substances described above, with respect to the ability to carry out each step of the present invention without any problems.

[0027] Examples of the above-mentioned resin films include polyvinyl chloride resins, acrylic resins such as polymethyl methacrylate, polyethyl methacrylate, methyl methacrylate / ethyl acrylate copolymers, and vinylcyclohexane / (meth)methyl acrylate copolymers, polyolefin resins such as polyethylene, polypropylene, and poly-4-methylpentene-1, polycarbonate resins such as 2,2-bis(4-hydroxyphenyl)propane carbonate and polypropylene carbonate, polyester resins such as polyethylene terephthalate, cyclic hydrocarbon resins such as ethylene / norbornene copolymers, cellulose ester resins such as triacetylcellulose, poly(meth)acrylimide resins, polyamide resins, polyarylate resins, polymer-type urethane acrylate resins, and polyimide resins. These films include unoriented films, uniaxially oriented films, and biaxially oriented films. They also include laminated films, which consist of two or more layers of one or more of these films.

[0028] When the flake-like substance is a two-dimensional material, the resin film is preferably made of polyvinyl chloride resin, polycarbonate resin such as 2,2-bis(4-hydroxyphenyl)propane carbonate and polypropylene carbonate, or acrylic resin such as polymethyl methacrylate, polyethyl methacrylate and methyl methacrylate / ethyl acrylate copolymer, with polyvinyl chloride resin being more preferred.

[0029] The first resin film and the second resin film may be films made of the same resin, or they may be films made of different resins.

[0030] The first resin film may preferably be a polyvinyl chloride resin film. The second resin film may preferably be a polyvinyl chloride resin film. The first resin film and the second resin film may both preferably be polyvinyl chloride resin films.

[0031] The thickness of the above-mentioned resin film can be appropriately selected from the viewpoint of productivity during film formation and ease of handling when manipulating the flake-like material. The thickness of the above resin film may be typically 0.5 to 300 μm, preferably 1 to 200 μm, and more preferably 5 to 150 μm, from the viewpoint of productivity during film formation and ease of handling when manipulating the flake-like material.

[0032] Examples of polyvinyl chloride resins constituting the above-mentioned polyvinyl chloride resin film include polyvinyl chloride (polyvinyl chloride homopolymer); vinyl chloride-vinyl acetate copolymer, vinyl chloride-(meth)acrylic acid copolymer, vinyl chloride-methyl (meth)acrylate copolymer, vinyl chloride-(meth)acrylate copolymer, vinyl chloride-ethyl (meth)acrylate copolymer, vinyl chloride-maleic acid ester copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer, vinyl chloride-styrene copolymer, vinyl chloride-isobutylene copolymer, vinyl chloride-vinylidene chloride copolymer, vinyl chloride-styrene-maleic anhydride terpolymer, vinyl chloride-styrene-acrylonitrile terpolymer, vinyl chloride-butadiene copolymer, vinyl chloride-isoprene copolymer, vinyl chloride-chlorinated propylene copolymer, vinyl chloride-vinylidene chloride-vinyl acetate terpolymer, vinyl chloride-acrylonitrile copolymer, and vinyl chloride-various vinyl ether copolymers, as well as chlorinated products thereof such as post-chlorinated polyvinyl chloride. As an alternative embodiment, chlorinated polyolefins, such as chlorinated polyethylene, which have a chemical structure similar to that of polyvinyl chloride, may be used. Among these, polyvinyl chloride (a homopolymer of vinyl chloride) is preferred. As the polyvinyl chloride resins mentioned above, one or a mixture of two or more of these can be used.

[0033] The polyvinyl chloride resin described above may further contain other resins commonly used in polyvinyl chloride resin compositions. The proportion of the other resins is not particularly limited as long as it does not contradict the purpose of the present invention. The proportion of the other resins may be typically 0 to 40% by mass, preferably 0 to 20% by mass.

[0034] Examples of the other resins mentioned above include ethylene-vinyl acetate copolymer; ethylene-(meth)acrylic acid copolymer; ethylene-(meth)acrylate alkyl ester copolymers such as ethylene-(meth)acrylate methyl copolymer; acrylic resins such as polymethyl methacrylate; and core-shell rubbers such as methacrylate ester-styrene / butadiene rubber graft copolymer and methacrylate ester / acrylic acid ester rubber graft copolymer. As the other resins mentioned above, one or more of these can be used.

[0035] From the viewpoint of enabling each step of the present invention to be carried out in a relatively low temperature range, and from the viewpoint of processability when forming a film, it is preferable that the above polyvinyl chloride resin further contains a plasticizer that is commonly used in polyvinyl chloride resin compositions.

[0036] Examples of the plasticizers mentioned above include phthalate ester plasticizers, trimellitic acid ester plasticizers, pyromellitic acid ester plasticizers, adipic acid ester plasticizers, itaconic acid ester plasticizers, citrate ester plasticizers, cyclohexanedicarboxylate plasticizers, and epoxy plasticizers.

[0037] Other examples of the above plasticizers include polyester-based plasticizers that use polyhydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, 1,5-hexanediol, 1,6-hexanediol, and neopentyl glycol, and polyhydric carboxylic acids such as oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, trimellitic acid, pimelic acid, suberic acid, maleic acid, azelaic acid, sebacic acid, fumaric acid, phthalic acid, isophthalic acid, and terephthalic acid, and optionally use monohydric alcohols and monocarboxylic acids as stoppers.

[0038] Examples of the phthalate ester plasticizers mentioned above include dibutyl phthalate, butylhexyl phthalate, diheptyl phthalate, di(2-ethylhexyl) phthalate, diisononyl phthalate, diisodecyl phthalate, diundecyl phthalate, ditridecyl phthalate, dilauryl phthalate, dicyclohexyl phthalate, and dioctyl terephthalate.

[0039] Examples of the trimellitic acid ester plasticizers mentioned above include tri(2-ethylhexyl) trimellitate, tri(n-octyl) trimellitate, and tri(isononyl) trimellitate.

[0040] Examples of the above-mentioned adipate ester plasticizers include bis(2-ethylhexyl) adipate, dioctyl adipate, diisononyl adipate, and diisodecyl adipate.

[0041] Examples of the epoxy plasticizers mentioned above include epoxidized soybean oil, epoxidized linseed oil, epoxidized fatty acid octyl esters, and epoxidized fatty acid alkyl esters.

[0042] Other examples of the above-mentioned plasticizers include trimellitic acid-based plasticizers, cyclohexane dicarboxylate-based plasticizers, tetrahydrophthalate diester-based plasticizers, glycerin ester-based plasticizers, epoxyhexahydrophthalate diester-based plasticizers, isosorbide diester-based plasticizers, phosphate-based plasticizers, azelaic acid-based plasticizers, sebaciic acid-based plasticizers, stearic acid-based plasticizers, citric acid-based plasticizers, pyromellitic acid-based plasticizers, biphenyltetracarboxylic acid-based plasticizers, and chlorine-based plasticizers.

[0043] As the plasticizers mentioned above, one or a mixture of two or more of these can be used.

[0044] The amount of the plasticizer used (when used) is preferably 10 parts by mass or more, more preferably 20 parts by mass or more, and even more preferably 30 parts by mass or more, with the total of the polyvinyl chloride resin and the other resins being 100 parts by mass, from the viewpoint of reliably obtaining the effect of using the plasticizer. On the other hand, the amount of plasticizer blended may be 120 parts by mass or less, preferably 80 parts by mass or less, and more preferably 60 parts by mass or less, from the viewpoint of suppressing problems such as plasticizer bleed-out, with the total of the polyvinyl chloride resin and the other resins being 100 parts by mass.

[0045] The above polyvinyl chloride resin may further contain chlorine scavengers such as hydrotalcite compounds, zeolite compounds, and metal soaps, and / or antioxidants such as phosphorus-based, phenol-based, and sulfur-based agents, from the viewpoint of processing stability when forming a film. The amount of the chlorine scavenger and / or the antioxidant (the total amount of both) used (when used) is preferably 0.1 to 10 parts by mass, more preferably 0.5 to 3 parts by mass, based on a total of 100 parts by mass of the polyvinyl chloride resin and the other resin.

[0046] The polyvinyl chloride resin described above may or may not contain substances commonly used in polyvinyl chloride resin compositions, to the extent that it does not contradict the objectives of the present invention. Optional components that may be included in the above polyvinyl chloride resin include, for example, light stabilizers such as hindered amines, ultraviolet absorbers such as benzotriazoles and benzophenones, β-diketone compounds, perchlorates, polyhydric alcohols, pigments, lubricants, crosslinking agents, antistatic agents, antifogging agents, plate-out inhibitors, surface treatment agents, flame retardants, fillers, fluorescent agents, antifungal agents, disinfectants, metal deactivators, mold release agents, and processing aids. The amount of these optional components may be 20 parts by mass or less, or 0 to 10 parts by mass, when the total amount of polyvinyl chloride resin and the other resins mentioned above is 100 parts by mass.

[0047] The method for producing a polyvinyl chloride resin film using the above-mentioned polyvinyl chloride resin can be appropriately selected considering the desired thickness and the properties of the polyvinyl chloride resin. Examples of the above-mentioned film-forming methods include the T-die extrusion method, the calender roll rolling method, and the solvent casting method.

[0048] The thickness of the above polyvinyl chloride resin film can be appropriately selected from the viewpoint of productivity during film formation and ease of handling when manipulating the flake-like material. The thickness of the above polyvinyl chloride resin film may be typically 0.5 to 300 μm, preferably 1 to 200 μm, and more preferably 5 to 150 μm, from the viewpoint of productivity during film formation and ease of handling when manipulating the flake-like material.

[0049] Process (2) Step (2) is a step of picking up flake-like material using a first probe whose tip is covered with a first resin film.

[0050] In step (2), the first probe, whose tip is covered with the first resin film, is brought into contact with the flake-like material that is resting on the substrate, and is pressed to pick up the flake-like material. The first resin film must cover the tip of the first probe to such an extent that it covers at least the portion that the flake-like substance comes into contact with when the first probe is grounded and pressed to pick up the flake-like substance. The first resin film may typically cover at least 30% of the surface area of ​​the protrusion, including the vicinity of the top of the tip of the first probe, and preferably at least 50% of the surface area of ​​the protrusion.

[0051] In step (2), it is preferable to control the temperature of the flake-like material to an appropriate level (heating or cooling) before it is picked up. The temperature of the flake-like material can be controlled, for example, by heating or cooling the substrate or the base on which the substrate is installed. The temperature to be controlled for the flake-like material can be appropriately determined from the viewpoint of reliably picking up the flake-like material, taking into consideration the material of the flake-like material, the thickness of the first resin film, and other factors. The temperature to be controlled for the above-mentioned flake-like material is usually determined by conducting preliminary experiments. The reference example in the examples described later is a typical example of a preliminary experiment.

[0052] In step (2), if desired, the first resin film and the first probe may be controlled to an appropriate temperature (heated or cooled) before contacting and pressing the flake-like substance. The temperature of the first resin film and the first probe can be controlled, for example, by heating or cooling the base of the first probe (1 in Figure 1). The control temperature of the flake-like substance and / or the first resin film and the first probe in step (2) is not particularly limited, but may be typically 40 to 150°C, preferably 45 to 110°C, and more preferably 50 to 100°C.

[0053] In step (2), the force applied when the first probe, whose tip is covered with the first resin film, is brought into contact with the flake-like substance resting on the substrate, can be appropriately determined taking into account the material and thickness of the first resin film, the type of flake-like substance, and the mechanical strength of the first probe. In step (2), the first probe, whose tip is covered with the first resin film, is brought into contact with the flake-like substance that is stationary on the substrate, and the force applied when pressing it may be typically 0.0005 to 5 N, preferably 0.001 to 1 N, and more preferably 0.01 to 0.1 N.

[0054] The above-mentioned flake-like substance is not particularly limited other than having a flake-like shape. Examples of the flake-like material mentioned above include two-dimensional materials and aggregates of two-dimensional materials that have a flake-like shape. In a typical embodiment, the flake-like material may be a two-dimensional material. The above two-dimensional material is not particularly limited, but examples include the following: Single-atom layer materials (materials with a thickness of one atom) such as graphene, graphene oxide, and hexagonal boron nitride; Monolayers (substances with a thickness of 2 to several atoms) such as molybdenum disulfide (MoS2) and niobium diselenide (NbSe2); Transition metal chalcogenides and transition metal dichalcogenides, which contain a transition metal and one or more chalcogenous elements (e.g., sulfur, selenium, and tellurium); Perovskite-type compounds formed in a two-dimensional layered structure (e.g., calcium titanate (CaTiO3), strontium titanate (SrTiO3), and barium titanate (BaTiO3)); Furthermore, laminates in which one or more of these types are stacked in 2 to tens of layers, for example, graphite in which multiple layers of graphene are stacked. The planar size of the above-mentioned flake-like material is not particularly limited, other than being pickable by the first probe. For example, it may be 1 μm to 3 cm at its longest point, or 2 μm to 1 cm at its longest point, or 5 μm to 5 mm at its longest point, or 10 μm to 3 mm at its longest point.

[0055] The above-mentioned substrates are not particularly limited, but examples include silicon substrates (Si substrates), substrates with a silicon dioxide film formed on the surface of a silicon substrate (SiO2 / Si substrates), silicon carbide substrates (SiC substrates), and inorganic glass substrates such as soda-lime glass, borosilicate glass, and quartz glass.

[0056] In a preferred additional embodiment of this process, a stack of flake-like material (typically a two-dimensional material) can also be picked up. This additional embodiment may include (i) touching and pressing a first probe, whose tip is covered with a first resin film, to a first flake-like material that is stationary on a substrate to pick up the first flake-like material; (ii) touching and pressing a second flake-like material (stationary on a substrate) to the side of the first flake-like material opposite to the first probe to pick it up from the substrate, thereby picking up a two-layer laminate of the flake-like material; and (iii) optionally, further repeating operation (ii) one or more times to pick up a laminate of three or more layers of the flake-like material. Temperature control, pressure control, etc., in this additional embodiment may be the same as those described above. This embodiment makes it possible to pick up not only single-layer flake-like material (typically two-dimensional material), but also flake-like material in the form of a multi-layered laminate. Furthermore, by transferring this to a second probe and then placing it on another substrate, it is possible to successfully obtain a laminate of inverted flake-like material. Here, the second flake-like substance may have an area less than or equal to the area of ​​the first flake-like substance in plan view (for example, an area less than approximately 100%, approximately 95%, approximately 90%, approximately 85%, or approximately 80% of the area of ​​the first flake-like substance in plan view). Conversely, the first flake-like substance may have an area less than or equal to the area of ​​the second flake-like substance in plan view (for example, an area less than approximately 100%, approximately 95%, approximately 90%, approximately 85%, or approximately 80% of the area of ​​the second flake-like substance in plan view). Alternatively, the area of ​​the first flake-like substance and the second flake-like substance in plan view may be the same. The relative size of the area of ​​the first and second flake-like materials in plan view can be similarly applied to the relative size of the area of ​​adjacent flake-like materials in plan view when obtaining a laminate of three or more layers of flake-like materials.

[0057] Process (3) Step (3) is a step in which a second probe, whose tip is covered with a second resin film, is placed on the side of the flake-like substance picked up by the first probe in step (2) that is opposite to the first probe, and pressed down. The second resin film must cover the tip of the second probe to the extent that it covers at least the portion that the flake-like material is in contact with when the second probe is grounded and pressed against the surface of the flake-like material opposite to the flake-like material. The second resin film may typically cover at least 30% of the surface area of ​​the protrusion, including the vicinity of the top of the tip of the second probe, and preferably at least 50% of the surface area of ​​the protrusion.

[0058] In step (3), when the first resin film is in contact with one side of the flake-like material and the second resin film is in contact with the other side, it is preferable to control the temperatures of the flake-like material, the first resin film, and the second resin film to appropriate temperatures. The control temperatures for the flake-like substance, the first resin film, and the second resin film in step (3) can be appropriately determined taking into account the material and thickness of the first resin film, the material and thickness of the second resin film, and the type of flake-like substance. The control temperature in step (3) is not particularly limited, but is usually 50 to 200°C, preferably 70 to 120°C, and more preferably 80 to 110°C. The control temperature in step (3) may preferably be 70 to 120°C, more preferably 80 to 110°C, when using polyvinyl chloride resin films of substantially the same material as the first resin film and the second resin film, the thickness of the polyvinyl chloride resin film is 5 to 150 μm, and the flake material is a two-dimensional material.

[0059] In step (3), the force applied when the second probe, whose tip is covered with a second resin film, is placed on the side of the flake-like substance picked up by the first probe in step (2) that is opposite to the first probe, can be appropriately determined taking into account the material and thickness of the first resin film, the material and thickness of the second resin film, the type of flake-like substance, and the mechanical strength of the first and second probes. In step (3), the second probe, whose tip is covered with a second resin film, is placed on the side of the flake-like substance picked up by the first probe in step (2) that is opposite to the first probe, and the force applied when pressing it is usually 0.0005 to 5 N, preferably 0.001 to 1 N, and more preferably 0.01 to 0.1 N.

[0060] Process (4) Step (4) is a step in which the flake-like substance picked up by the first probe is transferred to the second probe by separating the first probe from the second probe.

[0061] From the viewpoint of stably transferring the flake-like substance from the first probe to the second probe in step (4), the thickness ratio (thickness B / thickness A) of the thickness of the second resin film and the thickness of the first resin film when no pressure is applied (i) is usually less than 1, preferably 0.8 or less, more preferably 0.7 or less, and even more preferably 0.6 or less. The thickness of each resin film here is measured under normal temperature and pressure (25°C, 1 atm) and without pressure applied.

[0062] According to the inventors' research, even if the materials of the first resin film and the second resin film are significantly different, if the thickness of these resin films is the same, it is not easy to satisfy requirement (2) above (when separating the two probes and transferring the flake-like substance, the transferring probe must reliably release the flake-like substance, and the receiving probe must reliably hold the flake-like substance; that is, during the transfer, the transferring probe must not unintentionally continue to hold the flake-like substance, nor release it unintentionally).

[0063] However, it is remarkable that by setting the thickness ratio (thickness B / thickness A) of the thickness B of the second resin film to the thickness A of the first resin film to (i) above to normally less than 1, preferably 0.8 or less, more preferably 0.7 or less, and even more preferably 0.6 or less, the above requirement (2) can be easily satisfied, and the picked-up flake-like material can be reliably exchanged between probes.

[0064] As a result of diligent research, the inventors have found that the phase transition temperature from the rubber state to the molten state of a resin film (typically a polyvinyl chloride resin film) (measured by a compression probe in thermomechanical analysis (TMA)) shifts significantly to the lower temperature side as the thickness of the resin film increases, even if the material is the same. Although there is no intention to be bound by theory, when the thickness ratio (thickness B / thickness A) of the thickness of the second resin film to the thickness of the first resin film is usually less than 1 (i.e., when the thickness A of the first resin film is greater than the thickness B of the second resin film), in an embodiment in which both of these resin films are formed from the same material, the phase transition temperature of the first resin film shifts to a lower temperature side than the phase transition temperature of the second resin film. As a result, at a predetermined temperature, the phase states of the first resin film and the second resin film become at least partially different, and it is thought that such a state may contribute to the stable transfer of flake-like material from the first probe to the second probe. Thus, the optimal temperature for picking up / releasing flake-like material using a resin film is strongly related to the phase state of the resin film. Therefore, we believe that by appropriately controlling the thickness of each resin film, as well as the temperature of each resin film and the flake-like material in contact with it, the picked-up flake-like material can be reliably exchanged between probes using the operating method of the present invention.

[0065] In step (4), from the viewpoint of reliably transferring the flake-like substance from the first probe to the second probe, one preferred embodiment is to ensure that, when resin films of the same thickness are fabricated and compared, the temperature at which the resin film made using the material of the second resin film is suitable for picking up / releasing the flake-like substance is higher than the temperature at which the resin film made using the material of the first resin film is suitable for picking up / releasing the flake-like substance.

[0066] When using polyvinyl chloride resin films for both the first and second resin films, in step (4), from the viewpoint of reliably transferring the flake-like substance from the first probe to the second probe, the relationship between the amount of plasticizer α (parts by mass) in the polyvinyl chloride resin film used as the first resin film and the amount of plasticizer β (parts by mass) in the polyvinyl chloride resin film used as the second resin film may be normally α≧β, preferably α>β, more preferably α≧(β+20), and even more preferably α≧(β+50). Here, the amount of polyvinyl chloride resin blended in the polyvinyl chloride resin film (in embodiments including the above-mentioned other resins, the total amount of polyvinyl chloride resin and the other resins blended) is set to 100 parts by mass.

[0067] Articles produced using the method for producing articles of the present invention are articles made of flake-like material. Examples of such articles include transparent electrodes, touch panels, light-emitting electrochemical cells, transistors, integrated circuits, semiconductors, non-volatile memory, solar cells, energy storage devices, gas sensors, infrared sensors, ultraviolet light-emitting devices, heat-conducting devices, insulating devices, and superconducting devices. [Examples]

[0068] The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

[0069] Examples of polyvinyl chloride resin film manufacturing (α1) A polyvinyl chloride resin composition consisting of 100 parts by mass of a polyvinyl chloride homopolymer with a degree of polymerization of 1000 and 40 parts by mass of di(2-ethylhexyl) phthalate was dissolved in a solvent (cyclohexane) to obtain a polyvinyl chloride resin composition solution. This solution was then applied to the surface of an inorganic glass plate using an applicator and dried to obtain a polyvinyl chloride resin film (α1) with a thickness of 5 μm. At this time, the concentration of the polyvinyl chloride resin composition solution and the applicator were appropriately changed / adjusted so that the thickness of the obtained polyvinyl chloride resin film was 5 μm.

[0070] (α2) A polyvinyl chloride resin film (α2) was obtained in the same manner as in (α1) above, except that the thickness of the resulting polyvinyl chloride resin film was set to 15 μm.

[0071] (α3) A polyvinyl chloride resin film (α3) was obtained in the same manner as in (α1) above, except that the thickness of the resulting polyvinyl chloride resin film was set to 50 μm.

[0072] (α4) A polyvinyl chloride resin film (α4) was obtained in the same manner as in (α1) above, except that the thickness of the resulting polyvinyl chloride resin film was set to 100 μm.

[0073] (α5) A polyvinyl chloride resin film (α5) was obtained in the same manner as in (α1) above, except that the thickness of the resulting polyvinyl chloride resin film was set to 150 μm.

[0074] (β1) A polyvinyl chloride resin composition consisting of 100 parts by mass of a polyvinyl chloride homopolymer with a degree of polymerization of 1000 and 120 parts by mass of di(2-ethylhexyl) phthalate was dissolved in a solvent (cyclohexane) to obtain a polyvinyl chloride resin composition solution. This solution was then applied to the surface of an inorganic glass plate using an applicator and dried to obtain a polyvinyl chloride resin film (β1) with a thickness of 1 μm. At this time, the concentration of the polyvinyl chloride resin composition solution and the applicator were appropriately changed / adjusted so that the thickness of the obtained polyvinyl chloride resin film was 1 μm.

[0075] (β2) A polyvinyl chloride resin film (β2) was obtained in the same manner as in (β1) above, except that the amount of di(2-ethylhexyl) phthalate was changed to 80 parts by mass.

[0076] (β3) A polyvinyl chloride resin film (β3) was obtained in the same manner as in (β1) above, except that the amount of di(2-ethylhexyl) phthalate was changed to 40 parts by mass.

[0077] (β4) A polyvinyl chloride resin film (β4) was obtained in the same manner as in (β1) above, except that di(2-ethylhexyl) phthalate was not included.

[0078] Example 1-1 Two identical probes were prepared and used. The probe has the configuration shown in the conceptual diagram in Figure 1. It has a metal base, a glass intermediate member, and a dome-shaped tip (a hemispherical shape with a diameter of 1.5 mm) made of polydimethylsiloxane on top of that. The base also has a perforation in the center, which allows observation of the flake-like substance being manipulated through the probe. For the first resin film, a polyvinyl chloride-based resin film (α4) with a thickness of 100 μm obtained in the production of the polyvinyl chloride-based resin film described above was used. For the second resin film, a polyvinyl chloride-based resin film (α2) with a thickness of 15 μm obtained in the production of the polyvinyl chloride-based resin film described above was used.

[0079] For ease of understanding, please refer to Figure 2 in the following explanation. (1) A first resin film 6, cut to an appropriate size (4 mm x 4 mm), was placed over the tip 7 of the first probe (one of the two probes prepared) so as to cover more than half of the surface area of ​​the protrusion at the tip, and allowed to self-adhere. The end of the first resin film was then fixed to the intermediate member of the first probe using adhesive tape. Similarly, a second resin film 8 was placed over the tip 9 of the second probe (the other of the two probes prepared) so as to cover more than half of the surface area of ​​the protrusion at the tip, and allowed to self-adhere. The end of the second resin film 8 was then fixed to the intermediate member of the second probe using adhesive tape (not shown). Thus, a first probe with its tip 7 covered by a first resin film 6 and a second probe with its tip 9 covered by a second resin film 8 were prepared.

[0080] (2) Next, the two-dimensional material (hexagonal boron nitride) 10 (approximately 40 μm in length at its longest point) that was sitting on the SiO2 / Si substrate was heated to a temperature of 55°C, and then the first probe, whose tip 7 was covered with the first resin film 6 prepared in step (1), was pressed and picked up (upper side of Figure 2(a)).

[0081] (3) Next, the second probe (lower side of Figure 2(a)), whose tip 9 is covered with the second resin film 8 prepared in (1) above, is placed on the opposite side of the two-dimensional material (hexagonal boron nitride) 10 picked up by the first probe in (2) above, and pressed down (Figure 2(b)). At this time, heating was initiated from the second probe side, and the temperatures of the two-dimensional material (hexagonal boron nitride) 10, the first resin film 6, and the second resin film 8 were controlled to 95°C.

[0082] (4) Next, the first probe and the second probe were separated. The two-dimensional material (hexagonal boron nitride) 10 picked up by the first probe was transferred to the second probe (Figure 2(c)).

[0083] (5) Repeat steps (1) to (4) above 20 times. In all trials, it was visually confirmed that the two-dimensional material (hexagonal boron nitride) 10 picked up by the first probe was transferred to the second probe (transfer probability 100%).

[0084] Examples 1-2 to 1-18 A polyvinyl chloride resin film having the thickness shown in Table 1 obtained in the "Example of Manufacturing a Polyvinyl Chloride Resin Film" described above was used as the first resin film, and a polyvinyl chloride resin film having the thickness shown in Table 1 obtained in the "Example of Manufacturing a Polyvinyl Chloride Resin Film" described above was used as the second resin film. Except for setting the control temperature in step (3) to the temperature shown in Table 1, each step was carried out in the same manner as in Example 1-1, and a two-dimensional material delivery test was performed. The results (delivery probability) are shown in Table 1.

[0085] [Table 1]

[0086] From the results shown in Table 1, it was found that when the thickness ratio (thickness B / thickness A) of the second resin film thickness B to the first resin film thickness A was adjusted to less than 1 according to the present invention, a higher delivery probability was achieved compared to when no such adjustment was made.

[0087] Example 2 Except for using graphite in the form of flakes with a thickness of 50 nm (approximately 40 μm in length at its longest point) as the flake material, each step was carried out in the same manner as in Example 1-1, and a delivery test of the two-dimensional material was performed. The delivery probability was 100%.

[0088] Example 3 Except for using molybdenum disulfide (MoS2) with a flake-like shape and a thickness of 50 nm (approximately 40 μm in length at its longest point) as the flake material, each step was carried out in the same manner as in Example 1-1, and a delivery test of the two-dimensional material was performed. The delivery probability was 100%.

[0089] Example 4 Two identical probes were prepared and used. The probe has the configuration shown in the conceptual diagram in Figure 1. It has a metal base, a glass intermediate member, and a dome-shaped tip (a hemispherical shape with a diameter of 1.5 mm) made of polydimethylsiloxane on top of that. The base also has a perforation in the center, which allows observation of the flake-like substance being manipulated through the probe. For the first resin film, a polyvinyl chloride-based resin film (α4) with a thickness of 100 μm obtained in the production of the polyvinyl chloride-based resin film described above was used. For the second resin film, a polyvinyl chloride-based resin film (α2) with a thickness of 15 μm obtained in the production of the polyvinyl chloride-based resin film described above was used.

[0090] For ease of understanding, please refer to Figure 2 in the following explanation. (1) A first resin film 6, cut to an appropriate size (4 mm x 4 mm), was placed over the tip 7 of the first probe (one of the two probes prepared) so as to cover more than half of the surface area of ​​the protrusion at the tip, and allowed to self-adhere. The end of the first resin film was then fixed to the intermediate member of the first probe using adhesive tape. Similarly, a second resin film 8 was placed over the tip 9 of the second probe (the other of the two probes prepared) so as to cover more than half of the surface area of ​​the protrusion at the tip, and allowed to self-adhere. The end of the second resin film 8 was then fixed to the intermediate member of the second probe using adhesive tape (not shown). Thus, a first probe with its tip 7 covered by a first resin film 6 and a second probe with its tip 9 covered by a second resin film 8 were prepared.

[0091] (2) Next, the two-dimensional material (hexagonal boron nitride) 10 (approximately 40 μm in length at its longest point) that was sitting on the SiO2 / Si substrate was heated to a temperature of 55°C, and then picked up using the first probe, whose tip 7 was covered with the first resin film 6 prepared in step (1).

[0092] (2-2) Next, a two-dimensional material (hexagonal boron nitride) 11 (which is placed on the SiO2 / Si substrate 15) that is slightly smaller in area than the two-dimensional material (hexagonal boron nitride) 10 picked up in step (2) (i.e., its area is about 90% of the former) was heated to a temperature of 55°C, and then placed on the side of the two-dimensional material (hexagonal boron nitride) 10 opposite to the first probe (Figure 3-1(a)), and picked up from the SiO2 / Si substrate 15 (Figure 3-1(b)). The same process was repeated, and five sheets of two-dimensional material (hexagonal boron nitride) in sizes 10 to 14 (with decreasing area in that order) were stacked to form a mountain shape overall, and then picked up (Figure 3-1(c)).

[0093] (3) Next, the second probe, whose tip 9 is covered with the second resin film 8 prepared in step (1), was placed on the surface of the two-dimensional material (hexagonal boron nitride) 14 side of the laminate made of two-dimensional material (hexagonal boron nitride) 10 to 14 created in step (2-2), and pressed down (Figure 3-2(d)). At this time, heating was initiated from the second probe side, and the temperatures of the laminate consisting of 10-14 two-dimensional materials (hexagonal boron nitride), the first resin film 6, and the second resin film 8 were controlled to 100°C.

[0094] (4) Next, the first probe and the second probe were separated. The laminate consisting of 10-14 two-dimensional materials (hexagonal boron nitride) picked up by the first probe was then passed to the second probe (Figure 3-2(e)).

[0095] (5) Next, the second probe was inverted, and a laminate consisting of two-dimensional material (hexagonal boron nitride) 10-14 was placed on the surface of the SiO2 / Si substrate 15 heated to 150°C and pressed down.

[0096] (6) Next, the second probe was separated from the SiO2 / Si substrate 15. A laminate consisting of two-dimensional material (hexagonal boron nitride) 10-14 was placed on the surface of the SiO2 / Si substrate 15 such that the surface on the two-dimensional material (hexagonal boron nitride) 10 side was in contact with the surface of the SiO2 / Si substrate 15 (Figure 3-2(f)). In other words, a laminate consisting of 10-14 two-dimensional materials (hexagonal boron nitride) could be placed on the surface of the SiO2 / Si substrate 15 in an inverted state compared to its fabrication state.

[0097] Reference example 1-1 A resin film (the above-mentioned polyvinyl chloride resin film (β1)) cut to an appropriate size (4 mm x 4 mm) was placed over the tip of the probe and self-adhered, and the ends of the resin film were further fixed to the intermediate member of the probe using adhesive tape. The probe has the configuration shown in the conceptual diagram in Figure 1. It has a glass intermediate member on a metal base, and a dome-shaped tip (a hemispherical shape with a diameter of 1.5 mm) made of polydimethylsiloxane on top of that. The base also has a perforation in the center, which allows the flake-like substance to be manipulated to be observed through the probe.

[0098] A probe, with its tip covered by a resin film, was placed on an SiO2 / Si substrate heated to a predetermined temperature. The probe was then pressed against the two-dimensional material, and the SiO2 / Si substrate and the probe were separated to attempt to pick up the two-dimensional material. This trial was repeated 20 times, and the probability of successful pickup was calculated.

[0099] A probe, whose tip is covered with a resin film, picked up a two-dimensional material (hexagonal boron nitride) (approximately 40 μm in length at its longest point). The side of the two-dimensional material opposite to the probe was placed on the surface of an SiO2 / Si substrate heated to a predetermined temperature, pressed down, and then the SiO2 / Si substrate and the probe were pulled apart to attempt to release the two-dimensional material. This trial was repeated 20 times, and the probability of successful release was determined.

[0100] Table 2 shows the results of the pickup and release probabilities from the above trials. In the table, HP indicates that there was a greater than 70% chance of picking it up. mp means that the probability of picking up the item was between 30% and 70%. HR means that the ball was released with a probability of over 70%. "MR" means that the probability of successful release was between 30% and 70%.

[0101] Reference examples 1-2~1-4 Except for using the resin film shown in Table 2 (i.e., varying the amount of plasticizer), the operation and pickup / release tests were performed in the same manner as in Reference Example 1-1. The results are shown in Table 2.

[0102] Reference examples 2-1~2-3 Except for using the resin film shown in Table 2 (i.e., varying the thickness of the resin film), the operation and pickup / release tests were performed in the same manner as in Reference Example 1-1. The results are shown in Table 2.

[0103] [Table 2]

[0104] The results shown in Table 2 indicate that when using polyvinyl chloride resin film as the resin film, increasing the amount of plasticizer slightly lowers the temperature at which the material can be picked up with high probability and the temperature at which it can be released with high probability. Furthermore, increasing the thickness of the resin film significantly lowers the temperature at which the material can be picked up with high probability and the temperature at which it can be released with high probability.

[0105] This patent application is based on the planned content of a scientific paper titled "All-dry flip-over stacking of 2D crystal flakes based on polymer-to-polymer transfer using polyvinyl chloride" (Momoko Onodera, et al.), which is scheduled to be submitted to and published in the academic journal (Japanese Journal of Applied Physics) after the filing of this patent application and before the application is published. As this paper has already been submitted to the academic journal and its content is complete at the time of filing this patent application, all contents of the said paper are incorporated into this specification by citation. Furthermore, all disclosures in the above-mentioned Non-Patent Documents 1 and 2 are also incorporated into this Specified Specification by reference. [Explanation of Symbols]

[0106] 1: Probe base 2: Intermediate component of the probe 3: Tip of the probe 4: The perforation in the center of the base 1 5: Resin film 6: First resin film 7: First probe 8: Second resin film 9: Second probe 10: Two-dimensional matter 11: A two-dimensional material with a slightly smaller area than 10 two-dimensional material. 12: A two-dimensional material with a slightly smaller area than two-dimensional material 11. 13: A two-dimensional material with a slightly smaller area than two-dimensional material 12. 14: A two-dimensional material with a slightly smaller area than two-dimensional material 13. 15: SiO2 / Si substrate

Claims

1. A method for handling flake-like substances, (1) A first probe whose tip is covered with a first resin film, and A step of preparing a second probe whose tip is covered with a second resin film; (2) A step of placing the first probe, whose tip is covered with the first resin film, on the flake-like material which is resting on the substrate, and pressing it to pick up the flake-like material; (3) The step of grounding and pressing the second probe, whose tip is covered with the second resin film, onto the surface of the flake-like material picked up by the first probe in the step of (2) above, on the side opposite to the first probe; and, (4) The process includes separating the first probe and the second probe, thereby transferring the flake-like substance picked up by the first probe to the second probe. Here, the first resin film and the second resin film are formed from the same material. (i) The thickness ratio (thickness B / thickness A) of the second resin film thickness B and the first resin film thickness A when not pressed is less than 1. The above procedure.

2. The operating method according to claim 1, wherein the above thickness ratio (thickness B / thickness A) is 0.8 or less.

3. The operating method according to claim 1, wherein both the first resin film and the second resin film are films formed from the same polyvinyl chloride resin.

4. A method for handling flake-like material, (1) A step of preparing a first probe whose tip is covered with a first resin film, and a second probe whose tip is covered with a second resin film; (2) A step of placing the first probe, whose tip is covered with the first resin film, on the flake-like material which is resting on the substrate, and pressing it to pick up the flake-like material; (3) The step of grounding and pressing the second probe, whose tip is covered with the second resin film, onto the surface of the flake-like material picked up by the first probe in the step of (2) above, on the side opposite to the first probe; and, (4) The process includes separating the first probe and the second probe, thereby transferring the flake-like substance picked up by the first probe to the second probe. The first resin film described above is formed from a polyvinyl chloride resin containing (A-a) 100 parts by mass of polyvinyl chloride resin and (A-b) α parts by mass of plasticizer. The second resin film described above is formed from a polyvinyl chloride resin containing (B-a) 100 parts by mass of polyvinyl chloride resin and (B-b) β parts by mass of plasticizer. Here, α > β, (i) The thickness ratio (thickness B / thickness A) of the second resin film thickness B and the first resin film thickness A when not pressed is less than 1. The above procedure.

5. The operating method according to claim 4, wherein α ≥ (β + 20).

6. The method of operation according to any one of claims 1 to 5, wherein the flake-like material is a two-dimensional material.

7. The material of the tip of the first probe and the tip of the second probe is a silicone resin, The method of operation according to any one of claims 1 to 5, wherein the flake-like substance is graphene or hexagonal boron nitride.

8. A method for producing an article containing a flake-like substance, The production method comprising manipulating the flake-like substance using the operating method described in any one of claims 1 to 5.

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