CONSUMER PRODUCT COMPOSITIONS WITH PERFUME ENCAPSULATIONS

MX431837BActive Publication Date: 2026-02-25PROCTER & GAMBLE CO
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Patent Information

Application Number
MX2021010686
Authority / Receiving Office
MX · MX
Patent Type
Patents
Current Assignee / Owner
Priority Date
2019-05-08
Filing Date
2021-09-03
Publication Date
2026-02-25
Estimated Expiration
2040-03-05

AI Technical Summary

Technical Problem

Existing perfume encapsulation technologies face instability issues due to certain perfume compounds forming carboxylic acids, leading to leakage and poor performance, especially when using surfactants, which limits the use of desirable ingredients like aldehydes and esters.

Method used

Employing a core-shell encapsulation system with a polymeric shell made of acrylate materials, specifically designed to encapsulate perfumes with an acid number greater than 5.0 mg KOH/g, which reduces leakage and maintains stability even in the presence of surfactants.

Benefits of technology

The acrylate-based encapsulation system provides low leakage and improved stability for perfumes with high acid values, ensuring effective perfume deposition and duration in consumer products, particularly in surfactant-containing formulations.

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Abstract

Consumer product composition including encapsulants, the encapsulants having a core including perfume characterized by an acid value greater than 5.0 mg KOH / g of perfume, the encapsulants also including a coating including a (meth)acrylate material; methods for preparing and using such compositions.
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Description

CONSUMER PRODUCT COMPOSITIONS WITH PERFUME ENCAPSULATIONS FIELD OF INVENTION This description relates to consumer product compositions that include perfume encapsulations, where the perfume is characterized by a particular acidity index. Related methods for preparing and using such compositions are also described. BACKGROUND OF THE INVENTION Perfumes are often desirable ingredients in consumer products such as laundry detergent, fabric softener, and hair care products like shampoo and conditioner. A fragrance can enhance the aesthetic appeal of the product itself or the surface (e.g., fabric or hair) treated with it. To improve the deposit and / or longevity of the perfume, a perfume delivery system can be used. Core-shell encapsulation, where the perfume is encapsulated by a polymer shell, is a technology commonly used in consumer products. The shell material can be selected from any number of polymers or blends thereof. When the shell is broken, the perfume is released. However, the presence of certain perfume compounds within the capsule core can lead to capsule instability. For example, patent no. WO2017 / 148504 describes how certain perfume compounds, such as those containing aldehyde, acetal, and / or ester functional groups, can form carboxylic acids in the presence of atmospheric oxygen and / or through hydrolysis. It is believed that the resulting acids can impair the capsule wall quality and may result in perfume leakage. To address this issue, patent no. WO2017 / 148504 describes how selecting certain fragrance compositions, specifically those characterized by an acid value of no more than 5 mg KOH / g immediately before encapsulation (preferably determined according to DIN EN ISO 660:2009-10), can improve capsule performance. To obtain fragrance compositions or perfume blends with acidity levels no higher than 5 mg KOH / g, the formulator may need to limit the amount of certain ingredients, such as those containing aldehydes, acetals, and / or esters. However, these ingredients may be desirable to provide a specific fragrance experience for the consumer. It would be desirable to provide perfume encapsulants and related consumer products that provide acceptable freshness benefits and / or low encapsulation leakage without unduly limiting the formulator to certain perfume formulations. BRIEF DESCRIPTION OF THE INVENTION This description relates to compositions of consumer products that include perfume encapsulations; the perfume is characterized by a particular acidity index and the encapsulation cover includes an acrylate material. For example, the present description relates to a consumer product composition that includes encapsulants, the encapsulants having a core and a shell surrounding the core, the core including a perfume, the perfume being characterized by an acid value greater than 5.0 mg KOH / g immediately before encapsulation, as determined by the acid value determination method described herein, and the shell having a polymeric material, the polymeric material including an acrylate polymer; and a consumer product adjuvant. This description also relates to a method for treating a surface or article with consumer product compositions according to this description, wherein the method includes bringing the surface or article into contact with the consumer product composition, optionally in the presence of water. BRIEF DESCRIPTION OF THE FIGURES The figures in this description are illustrative in nature and are not intended to be limiting. Figure 1 shows a graph of the retention of encapsulated perfume after storage in a detergent product. DETAILED DESCRIPTION OF THE INVENTION This description relates to certain core-shell encapsulations containing perfumes with relatively high acid values, as well as to compositions and processes related to such encapsulations. It has been found that the selection of particular shell materials, specifically acrylate materials, can result in perfume encapsulations that exhibit surprisingly low leakage, even when containing perfumes characterized by, for example, an acid value greater than 5.0 mg KOH / g. Surprisingly, insufficient surfactant stability in fragrance capsules has been found to be associated with the presence of aldehyde fragrances or fragrances with ester groups. Aldehydes have a tendency to form carboxylic acids in the presence of atmospheric oxygen; esters (and correspondingly also lactones) can be saponified and thus also form carboxyl groups. Without theoretical limitations, it is believed that for radical capsule formation, and especially if part of this radical capsule formation is achieved through polymerization from the oil phase, as in polyacrylate-based capsules, the sensitivity to perfume materials, such as aldehydes and esters, which can be prone to transformation into acidic materials that are typically charged, is lower compared to capsules formed by other formation mechanisms, such as coacervate formation, condensation reaction mechanisms, and / or interfacial polymerization. This lower sensitivity is thought to stem from the fact that the acids formed can more readily interfere with the other capsule formation mechanisms due to their explicit charge as acids and, therefore, can interact with the chemical species intended to form the capsule wall. Since encapsulated perfumes having an acid value greater than 5.0 mg KOH / g have been reported to leach out and / or provide poor performance in compositions comprising surfactant (such as hair shampoo, liquid detergent, or fabric softener), the encapsulants of the present description, which tend to have relatively low leakage rates, may be particularly preferred in compositions containing surfactant and / or conditioning agents, or when used in applications comprising such materials in an aqueous environment, such as during washing or other treatment operations, e.g., in a washing machine, shower, or bathtub. The encapsulations, compositions, and processes described herein are further detailed below. As used herein, when the articles "a" and "one" are used in a claim, they should be understood to mean one or more of the items claimed or described. As used herein, the terms "include," "includes," and "which includes" are not limiting. The compositions described herein may comprise, consist essentially of, or consist of the components described herein. The term "substantially free of" may be used in this description. This means that the material indicated is present in a minimal amount and is not deliberately added to the composition to form part of it, or is preferably not present at analytically detectable levels. This includes compositions in which the material indicated is present only as an impurity in one of the other deliberately included materials. The material indicated may, in any case, be present at a level of less than 1%, or less than 0.1%, or less than 0.01%, or even 0%, by weight of the composition. As used in this description, consumer product means products or devices for baby care, personal care, fabric and home care, family care, feminine care, health care, snacks, and / or beverages intended for use or consumption in the form in which they are sold and not intended for subsequent commercial manufacture or modification. Such products include, but are not limited to, diapers, bibs, wipes; products and / or methods relating to the treatment of hair (of humans, dogs, and / or cats), including products for bleaching, coloring, dyeing, conditioning, shampooing, and styling; deodorants and antiperspirants; grooming products; cosmetics; and skin care, including the application of creams, lotions, and other topical products for consumer use.and shaving products, products and / or methods relating to the treatment of fabrics, hard surfaces and any other surface included within the field of fabric and home care, including: environmental care, car care, dishwashing, fabric conditioning (including fabric softeners), laundry detergents, laundry care and / or rinse additives, hard surface cleaning and / or treatment and other cleaners for institutional or consumer use; products and / or methods relating to toilet paper, facial wipes, tissues and / or paper towels; tampons, feminine hygiene products; products and / or methods relating to oral care including toothpaste, dental gels, mouthwash, denture adhesives, teeth whitening products;over-the-counter health care products including cough and cold medicines, pain relievers, prescription pharmaceuticals, pet health and nutrition, and water purification. As used in the present description, the term cleaning composition includes, unless otherwise indicated, all-purpose or high-performance washing agents in granular or powder form, especially cleaning detergents; liquid, multi-purpose gel or paste cleaning agents, especially liquid types designated as high-performance; liquid detergents for delicate fabrics; hand dishwashing agents or low-performance dishwashing agents, especially those of the high-foaming type; automatic dishwashing agents, including the various types in tablet, granule, liquid form and rinse aid for institutional and domestic use;Liquid cleaning and disinfecting agents, including antibacterial handwashing agents, cleaning bars, mouthwashes, denture cleaners, toothpaste, car or carpet shampoos, bathroom cleaning products; shampoos and hair conditioners; shower gels and bath foams, and metal cleaners; as well as cleaning aids, such as bleaching additives and types of stain removers in bar or pretreatment form, substrate-loaded products, such as dryer sheets, dry and wet pads and cloths, non-woven fabric substrates, and sponges; as well as sprays and vaporizers. MA / a / ZUZl / UlUOÜO As used herein, the phrase "fabric care composition" includes compositions and formulations designed for the treatment of fabrics. Such compositions include, but are not limited to, laundry compositions and detergents, fabric softening compositions, fabric enhancing compositions, fabric renewing compositions, laundry pre-wash, laundry pre-treatment, laundry additives, aerosol products, dry cleaning agent or composition, laundry rinse additive, wash additive, post-rinse fabric treatment, ironing aid, unit-dose formulation, delayed-release formulation, detergent contained in or within a porous substrate or nonwoven fabric, and other suitable forms that may be apparent to a person skilled in the art in view of the teachings of the present invention.The compositions can be used as a pre-wash treatment, a post-wash treatment, or they could be added during the wash or rinse cycle of the washing operation. Unless otherwise stated, all component or composition levels refer to the active portion of that component or composition and exclude impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions. All temperatures in this description are expressed in degrees Celsius (°C), unless otherwise specified. Unless otherwise specified, all measurements described herein are made at 20°C and under atmospheric pressure. In all formulations described herein, all percentages are by weight of the total composition, unless otherwise specified. All ratios are by weight, unless otherwise specified. Each maximum numerical limit given in this specification shall be understood to include all lower numerical limits, as if the lower numerical limits were explicitly stated herein. All minimum numerical limits stated in this specification shall include all higher numerical limits, as if the higher numerical limits were expressly stated herein. Any numerical range given throughout this specification includes any lower numerical range that lies within that broader numerical range, as if the lower numerical range were expressly stated herein. Composition of consumer product This description relates to consumer product compositions. The compositions may include encapsulated components, as described in more detail below. The composition may be a consumer product. The consumer product may be useful as a product or device for baby care, beauty care, fabric and home care, family care, feminine care, or health care. The composition may be a beauty care composition, a fabric care composition, a home care composition, or combinations thereof. The composition may be a beauty care composition, such as a hair treatment product (including shampoo and / or conditioner), a skin care product (including a cream, lotion or other product applied topically for consumer use), a shaving care product (including a lotion, shaving foam or pre- or post-shave treatment), a personal hygiene product (including a liquid body soap, a liquid hand soap and / or a bar soap), a deodorant and / or antiperspirant or mixtures thereof. The composition may be a fabric treatment composition, such as a laundry detergent composition (including a high-performance washing detergent), a fabric conditioning composition (including a fabric softener and / or fabric enhancer composition), a laundry and rinse additive, a fabric pretreatment composition, a fabric renewing composition, or a mixture of these. The composition may be a composition for home care, such as for environmental care, car care, dishwashing, cleaning and / or treatment of hard surfaces, and other cleaning for consumer or institutional use. The composition may be in any suitable form. It may be a liquid, granular, single-compartment pouch, multi-compartment pouch, soluble sheet, lozenge or globule, fibrous article, tablet, bar, flake, dryer sheet, or a mixture thereof. The composition may be selected from a liquid, solid, or combination thereof. Preferably, the composition is a liquid. The liquid may be encapsulated by a water-soluble film to form a unit-dose article, such as a pouch. The composition may be in the form of a liquid. The liquid composition may include from approximately 30%, or approximately 40%, or approximately 50%, to approximately 99%, or approximately 95%, or approximately 90%, or approximately 75%, or approximately 70%, or approximately 60%, by weight of the composition, water. The liquid composition may be a liquid laundry detergent, a liquid fabric conditioner, a liquid dish soap, a hair shampoo, a hair conditioner, or a mixture thereof. Preferably, the liquid composition is selected from a liquid laundry detergent, a liquid fabric improver, or combinations thereof. The liquid may be packaged in an aerosol can or other roll-on bottle. The composition may be in the form of a solid. The solid composition may be a powder or granular composition. Such compositions may be agglomerated or spray-dried. Such a composition may include a plurality of granules or particles, at least some of which may contain different compositions. The composition may be a powdered or granular cleaning composition, which may include a bleaching agent. The composition may be in the form of a globule or tablet, which may be pelletized from a molten liquid. The composition may be an extruded product. The composition may be in the form of a unit-dose article, such as a tablet, pouch, sheet, or fibrous article. Such pouches typically include a water-soluble film, such as a water-soluble polyvinyl alcohol film, that at least partially encapsulates the composition. Suitable films are available from MonoSol, LLC (Indiana, USA). The composition may be encapsulated in a single-compartment or multi-compartment pouch. A multi-compartment pouch may have at least two, at least three, or at least four compartments. A multi-compartment pouch may include compartments that are side-by-side and / or overlapping. The composition contained in the pouch or in compartments thereof may be liquid, solid (such as powders), or combinations thereof.The composition contained in the bag may have relatively low amounts of water, for example, less than approximately 20%, or less than approximately 15%, or less than approximately 12%, or less than approximately 10%, or less than approximately 8%, by weight of the detergent composition, of water. The composition may have a viscosity of 1 to 1500 centipoises (1-1500 mPa*s), preferably 100 to 1000 centipoises (100-1000 mPa*s), or more preferably 200 to 500 centipoises (200-500 mPa*s) at 20 s and 21 °C. Compositions having such viscosities are convenient to use without being too thick or too thin. Encapsulated This description relates to encapsulated components. The consumer product compositions described herein comprise encapsulated components. Since more than one encapsulated component is typically present, the compositions may be described as comprising a plurality or population of encapsulated components. The composition may comprise from approximately 0.05% to approximately 20%, from approximately 0.05% to approximately 10%, from approximately 0.1% to approximately 5%, or from approximately 0.2% to approximately 2%, by weight of the composition, of encapsulants. The composition may comprise a sufficient quantity of encapsulants to provide from approximately 0.05% to approximately 10%, or from approximately 0.1% to approximately 5%, or from approximately 0.1% to approximately 2%, by weight of the composition, of perfume to the composition. When described herein, the quantity or weight percentage of the encapsulants refers to the sum of the shell material and the core material. The encapsulants can have an average size weighted by encapsulation volume of approximately 0.5 microns to approximately 100 microns, or even 10 to 100 microns, preferably from approximately 1 micron to approximately 60 microns, or even from 10 microns to 50 microns, or even from 20 microns to 45 microns, or even from 20 microns to 60 microns. Core The encapsulated products described herein may comprise a core. The core may be surrounded by a shell. The core may comprise a perfume. The perfume may comprise a single perfume raw material or a mixture of perfume raw materials. The term perfume raw material (or PRM), as used herein, refers to compounds with a molecular weight of at least approximately 100 g / mol that are useful for imparting an odor, fragrance, essence, or aroma, either alone or with other perfume raw materials. Typical PRMs include, but are not limited to, alcohols, ketones, aldehydes, esters, ethers, nitrites, and alkenes, such as terpenes. A list of common PRMs can be found in several reference sources, for example, Perfume and Flavor Chemicals, Vols. I and II; Steffen Arctander Allured Pub. Co. (1994) and Perfumes: Art, Science and Technology, Miller, P.M. and Lamparsky, D., Blackie Academic and Professional (1994). Perfumes with a specific fragrance composition (PMR) can be characterized by their boiling points (BP) measured at standard pressure (760 mm Hg) and their octanol / water partition coefficient (P), which can be described in terms of logP, determined according to the test method below. Based on these characteristics, PMRs can be categorized as Quadrant I, Quadrant II, Quadrant III, or Quadrant IV perfumes, as described in more detail below. A perfume with a variety of PMRs from different quadrants may be desirable, for example, to provide fragrance benefits at different points of contact during normal use. Perfume raw materials may comprise a perfume raw material selected from the group consisting of perfume raw materials having a boiling point (BP) below approximately 250 °C and a ClogP below approximately 3, perfume raw materials having a BP above approximately 250 °C and a ClogP below approximately 3, perfume raw materials having a BP above approximately 250 °C and a ClogP below approximately 3, perfume raw materials having a BP below approximately 250 °C and a ClogP above approximately 3, and mixtures thereof. Perfume raw materials having a boiling point (BP) below approximately 250 °C and a ClogP below approximately 3 are known as Quadrant I perfume raw materials. Quadrant I perfume raw materials are preferably limited to less than 30% of the perfume composition.Perfume raw materials having a boiling point (BP) greater than approximately 250°C and a ClogP greater than approximately 3 are known as Quadrant IV perfume raw materials; perfume raw materials having a BP greater than approximately 250°C and a ClogP less than approximately 3 are known as Quadrant II perfume raw materials; and perfume raw materials having a BP less than approximately 250°C and a ClogP greater than approximately 3 are known as Quadrant III perfume raw materials. The appropriate Quadrant I, II, III, and IV perfume raw materials are described in U.S. Patent No. 6,869,923 B1. The perfume at the core of the encapsulated components may comprise perfume raw materials capable of forming an acid. For example, aldehydes (and, correspondingly, acetals) tend to form carboxylic acids in the presence of atmospheric oxygen; esters (and, correspondingly, lactones) can saponify, thereby forming carboxyl groups. Despite the formulation challenges associated with these acid-forming materials, they remain desirable for product formulation due to the pleasing aesthetic they can provide. The perfume core can be characterized by an acidity index. The acidity index is effectively a measurement of the amount of free carboxylic acids present in the perfume before encapsulation. The perfume can be characterized by an acidity index greater than 5.0 mg / KOH immediately before encapsulation, determined by the acidity index determination method provided in the test methods section below. The perfume can be characterized by an acidity index greater than 5.25, or greater than 5.50, or greater than 5.75, or greater than 6.0 mg / KOH immediately before encapsulation. The perfume can be characterized by an acidity index of approximately 5.0 to approximately 25, or of approximately 5.0 to approximately 20, or of approximately 5.0.5 to approximately 20, or from approximately 6 to approximately 20, or from approximately 8 to approximately 20, or from approximately 10 to approximately 20, or from approximately 12 to approximately 20, or from approximately 15 to approximately 20 mg / KOH immediately before encapsulation. Perfume raw materials capable of forming an acid may include materials comprising aldehyde, acetal, ester, and / or lactone entities. The perfume herein described may comprise from approximately 30% to approximately 75%, or from approximately 35% to approximately 70%, or from approximately 40% to approximately 60%, by weight of the total perfume in the core immediately after encapsulation formation, of perfume raw materials comprising aldehyde entities, acetal entities, ester entities, lactone entities, or mixtures thereof. The encapsulated perfume described herein may comprise aldehyde compounds, ester compounds, or mixtures thereof. The perfume described herein may comprise from approximately 30% to approximately 75%, or from approximately 35% to approximately 70%, or from approximately 40% to approximately 60%, by weight of the total perfume in the core immediately after encapsulation formation, of aldehyde compounds, ester compounds, or mixtures thereof. The perfume described herein may comprise from approximately 2% to approximately 30%, or from approximately 3% to approximately 25%, or from approximately 4% to approximately 20%, or from approximately 4% to approximately 15%, by weight of the total perfume in the core immediately after encapsulation formation, of aldehyde compounds.The perfume of the present description may comprise from approximately 10% to approximately 60%, or from approximately 20% to approximately 50%, or from approximately 30% to approximately 50%, by weight of the total perfume in the core immediately after encapsulation formation, of ester compounds. Perfume raw materials capable of forming an acid may include aliphatic aldehydes and / or their acetals; cycloaliphatic aldehydes; aromatic and / or araliphatic aldehydes; aliphatic, aromatic or araliphatic esters; lactones; or mixtures thereof. Aliphatic aldehydes and their acetals may include: hexanal; heptanal; octanal; nonanal; decanal; undecanal; dodecanal; tridecanal; 2-methyloctanal; 2-methylnonanal; (F)-2-hexenal; (Z)-4-heptenal; 2,6-dimethyl-5-heptenal; 10-undecadienal; (F)-4-decenal; 2-dodecenal; 2,6,10-trimethyl-5,9-undecadienal; heptanal diethyl; 1,ldimethoxy-2,2,5-trimethyl-4-hexene; citronellyloxyacetaldehyde; or mixtures thereof. Cycloaliphatic aldehydes may include: 2,4-dimethyl-3-d-chlorohexene carbaldehyde; 2-methyl-4-(2,2,6-trimethylcyclohexene-1-1)-2-butenoyl; 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene carbaldehyde; 4-(4-methyl-3-penten-1-yl)-3-cyclohexene carbaldehyde; or mixtures of these. Aromatic and araliphatic aldehydes may include: benzaldehyde; phenylacetaldehyde; 3-phenylpropanal; hydratropaaldehyde; 4-methylbenzaldehyde; 4-methylphenylacetaldehyde; 3-(4-ethylphenyl)-2,2-dimethylpropanal; 2-methyl-3-(4-isopropylphenyl)propanal; 2-methyl-3-(4-tert-butylphenyl)propanal; 3-(4-tert-butylphenyl)propanal; cinnamic aldehyde; α-butylzinc aldehyde; α-amyl cinnamic aldehyde; α-hexyl cinnamic aldehyde; 3-methyl-5-phenylpentanal; 4-methoxybenzaldehyde; 4-hydroxy-3-methoxybenzaldehyde; 4-hydroxy-3-ethoxybenzaldehyde; 3,4-methylenedioxybenzaldehyde; 3,4-dimethoxybenzaldehyde; 2-methyl-3-(4-methoxyphenyl) propanal; 2-methyl-3-(4-methylenedioxyphenyl) propanal; or mixtures thereof. Esters of aliphatic carboxylic acids may include: (ε) and (Z)-3-hexenylformate; ethyl acetoacetate; isoamyl; hexyl acetate; 3,5,5-trimethylhexyl acetate; 3-methyl-2-butenyl acetate; (E)-2-hexenyl acetate; (E)- and (Z)-3-hexenyl acetate; octyl acetate; 3-octyl acetate; l-octene-3-yl acetate; ethyl butyrate; butyl butyrate; isoamyl; hexyl butyrate; (£)- and (Z)-3-hexenyl isobutyrate; hexyl crotonate; ethyl isovalerate; ethyl 2-methylpentanoate; ethyl hexanoate; allyl hexanoate; ethyl heptanoate; allyl heptanoate; ethyl octanoate; ethyl (f, Z)-2,4-decadienoate; methyl-2-octinate; methyl-2-noninate; allyl-2-isoamyloxyacetate; methyl 3,7-dimethyl-2,6-octadienoate; or mixtures thereof. Esters of cyclic alcohols may include: 2-tert-butylcyclohexyl acetate; 4-tert-butylcyclohexyl acetate; 2-tert-pentylcyclohexyl acetate; 4-tert-pentylcyclohexyl acetate; decahydro-2-naphthyl acetate; 3-pentyltetrahydro-2H-pyran-4-yl acetate; decahydro-2,5,5,8a-tetramethyl-2-naphthyl acetate; 4,7-methane-3a, 4,5,6,7,7a-hexahydro-5- or -6-indenyl acetate; 4,7-methane-3a, 4,5,6,7,7a-hexahydro-5- or -6-indenylpropionate; 4,7-methane-3a, 4,5,6,7,7a-hexahydro-5- or -6-indenyl isobutyrate; 4,7-methaneoctahydro-5- or -6-indenyl acetate; or mixtures thereof. Esters of araliphatic alcohols and aliphatic carboxylic acids may include benzyl acetate; benzylpropionate; benzyl isobutyrate; benzylisovalerate; 2-phenylethyl acetate; 2-phenylethyl propionate; 2-phenylethylisobutyrate; 2-phenylethylisovalerate; 1-phenylethyl acetate; α-trichloromethylbenzyl acetate; α,α-dimethylphenylethyl acetate; α,α-dimethylphenylethyl butyrate; cinnamyl; 2-phenoxyethyl isobutyrate; 4-methoxybenzyl acetate; or mixtures thereof. Cycloaliphatic carboxylic acid esters may include: allyl-3-cyclohexyl propionate; allylcyclohexyl oxyacetate; methyl dihydrojasmonate; methyl jasmonate; methyl 2-hexyl-3-oxocyclopentanecarboxylate; ethyl 2-ethyl-6,6-dimethyl-2-cyclohexenecarboxylate; ethyl 2,3,6,6-tetramethyl-2-cyclohexenecarboxylate; ethyl-2-methyl-1,3-dioxolan-2-acetate; or mixtures thereof. Esters of aromatic and araliphatic carboxylic acids may include: methyl benzoate; ethyl benzoate; hexyl benzoate; benzyl benzoate; methyl phenylacetate; ethyl phenylacetate; geranylphenyl acetate; phenylethyl phenylacetate; methyl cinnamate; ethyl cinnamate; benzyl cinnamate; phenylethyl cinnamate; cinnamyl cinnamate; allyl phenoxyacetate; methyl salicylate; isoamyl salicylate; hexyl salicylate; cyclohexyl salicylate; cis-3-hexenyl salicylate; benzyl; phenylethyl salicylate; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; ethyl 3-phenylglycidate; 3-methyl-3-phenyl ethyl glycidate; or mixtures thereof. It is known that not all aldehydes are equally prone to oxidation into acids, just as it is known that not all esters have the same probability of transforming into acids. Therefore, perfume blends that may superficially contain similar amounts of aldehydes and / or esters can be characterized by different acidity levels, depending on the specific aldehydes and / or esters present in each perfume blend. For example, the probability of oxidation of a compound can be related to the compound's ionization potential. Without being restricted by theory, it is generally believed that the lower the compound's ionization potential, the greater the probability of oxidation occurring. The core perfume may include perfume raw materials characterized by relatively low ionization potentials, for example, equal to or less than approximately 8.5, or equal to or less than approximately 8.0, or equal to or less than approximately 7.5. The core perfume may include a certain minimum of such perfume raw materials, such as at least approximately 10%, or at least approximately 20%, or at least approximately 30%, or at least approximately 40%, or at least approximately 50%, by weight of the core perfume.Higher quantities of such materials can provide higher acidity levels for the perfume, and the encapsulants of the present description are believed to be particularly suitable for encapsulating such perfumes. Certain asters may also be more likely to hydrolyze under certain conditions than others. Those asters that are more likely to undergo acid hydrolysis can lead to greater carboxylic acid formation and, therefore, higher acidity levels. Furthermore, without intending to be restricted by theory, it is believed that asters that are more likely to undergo basic hydrolysis may contribute to encapsulation leakage, since the salts formed after hydrolysis can enter an aqueous phase and are more likely to leave the encapsulation core. Differences in ionization potentials and / or hydrolysis rates can be affected by the structure of the perfume raw material. For example, steric hindrance near an ester entity can result in lower than expected hydrolysis rates. As mentioned previously, certain aldehydes are believed to be more susceptible to oxidation than others. The core perfume may comprise one or more of the following aldehyde perfume raw materials, which are believed to be relatively prone to oxidation to acids: 2,6-dimethyl-octanal; 2,2,5-trimethyl-4-hexenal; scentenal; 2-phenyl-3-(2-furyl)prop-2-enal; (l)-citronellal; tetrahydrogeraniol; 2-ethoxybenzaldehyde; 5-methylfurfural; calypsone; d-xylose; 3-(2-furanyl)-2-methyl-2-propenal; 3,5,5-trimethylhexanal; canthoxal; 2,4,5-trimethoxybenzaldehyde; 4-hydroxy-3-methoxycinnamaldehyde; 2,4,6-trimethoxybenzaldehyde; 3,4,5-Trimethoxybenzaldehyde; 2,3,4-Trimethoxybenzaldehyde; (d)-Citronellal; Lyral; Methyl octyl acetaldehyde; Octanal; 3,7-Dimethyl-; Adoxal; Citronellyl oxyacetaldehyde; cis-3-Hexenyloxyacetaldehyde; Methoxymelonal; n-Hexanal; Pentyl vanillin; o-Methoxycinnamaldehyde; o-Anisaldehyde; Octanal; Nonalaldehyde; 2,6,10-Trimethylundecanal; Citronellal; Melonal; Hydroxycitronellal;prenal; metilnonylacetaldehyde; valeraldehyde; capraldehído; panisaldehyde; heptaldehyde; ethyl vainillin; vainillin; heliotropina; helional; veratraldehyde; methoxycitronelal; 7-ethoxy-3,7-dimetiloctanal; 4-ethoxybenzaldehído; vainillin isobutyrate; vainillin acetate; ethyl vainillin acetate; l-met¡l-4-(4-met¡l-3-penten-l-¡lo)-3-clohexeno-lcarboxaldehyde; 8-undecenal; trans,trans,-2,4-nonadienal; beta-sinensal; 6-cyclopentylidene hexanal; preciclemona B; tangerinal; 2-thiophenocarboxaldehyde; 9-decenal; trans-2,cis-6nonadienal; acalea; 4-terc-butylbenzaldehído; trans-2-methyl-2-octenal; citral; 3-methyl-5-phenyl-pentanal; 2-decenal; trans-2-decenal; alpha,4-dimethyl bencenopropanal; cis-5-octenal; cis-7-decen-lal; cis-4-decen-l-al; 2-trans-6-cis-dodecadienal; 2-trans-4-trans-dodecadienal; 3-cyclohexeno-lpropanal; 2- nonen-l-al; 2-undecenal; 2,4-decadienal, (E,E)-; 2,4-undecadienal, (E,E)-; isohexenil ciclohexenil carboxaldehído; trans-2-nonen-l-al; 3-nonilacroleina;2,6-nonadienal; lilial; 2-trans-6-trans-nonadienal; alpha-sinensal; bourgeonal; 2-tridecenal; p-butylphenyl acetaldehyde; (Z)-3-dodecenal; m-methylbenzaldehyde; mefloral; trans-4-decen-l-al; silvial; 2-hexen-l-al; 2,4-nonadienal; floralozone; C-11 aldehyde; cis-3-hexenal; myristaldehyde; cinnamic aldehyde; p-tolualdehyde; undecanal; 10-undecenal; lauralaldehyde; trans-2-hexenal; geranial; 5-methyl-2-thiophenocarboxaldehyde; phenylacetaldehyde; alpha-amylcinnamaldehyde; floral super; hexyl cinnamic aldehyde; alpha-methyl cinnamaldehyde; benzaldehyde; or mixtures thereof. Preferably, the core perfume may comprise one or more of the following aldehyde perfume raw materials, as such PRMs are particularly desirable from an aesthetic point of view: scentenal; adoxal; ocatanal; nonalaldehyde; melonal; methylnonylacetaldehyde; p-anisaldehyde; ethyl vanillin; vanillin; heliotropin; lilial; C-11 aldehyde; undecanal; 10-undecenal; lauralaldehyde; or mixtures thereof. Similarly, certain esters are believed to be more prone to transformation into acids than others. The core perfume may comprise one or more of the following perfume ester raw materials, which are believed to be relatively prone to transformation into acids: quincester; serenolide; nirvanolide; acetarolle; alpinofix; aladinate; methyl laitone; firascone; 1-methylbuten-1-ol, 1-acetate; (Z)-3-heptene-1-yl acetate; 3-hydroxy-4,5-dimethyl-2(5H)-furanone; isoamyl undecylenate; verdox HC; pivarose Q; citryl acetate; (E)-5-tangerinol; (Z)-5-tangerinol; miraldyl acetate; geranyl phenylacetate; bergaptene; isopimpinelin; parsol MCX; ethyl beta-safranate; nopyl acetate; calixol; methyl octalactone; isopulegill acetate; ethyl tiglate; vanoris; acetoxymethyl-isolongifolene (isomers); l-oxaspiro[2.5]octane-2-carboxylic acid, 5,5,7-trimethyl-ethyl ester; 3,6-dimethyl-3-octanyl acetate; cis-3-hexenyl-cis-3-hexenoate; cis-3-hexenyl lactate; sclareolid;hexarosa; cis-iso-ambretolide; frutinate; ethyl gamma-safranate; amyl cinamate; isoambretolide; bornyl isobutyrate; cyprisate; anapear; montaverdi; vertosin; isobornyl isobutyrate; Ci cyprisate; cyclobutanate; cis-3-hexenyl butyrate; geranyl tiglate; trans-hedione; isoamyl acetate; givescona; ci doga Iba nato; verdural B extra; alpha-safranate of ethyl; jasmal; estyral acetate; nonalactone; trans-ambretolide; furfuryl heptanoate; furfuryl hexanoate; alpha-amylcinamyl acetate; carvyl acetate; ethyl isobutanoate; citronelil isobutyrate; furfuryl octanoate; Octyl 2-furoate; cedar acetate; isoamyl acetoacetate; cis-3-hexenyl benzoate; phenylethyl benzoate; hexenilo tiglato; citrus; gamma-undecalactona (racial); (S)-gama-undecalactona; (R)-gamma-undecalactona; phenyl benzoate; geranyl benzoate; isobutyl salicylate; isoamyl salicylate; greenx; 2-acetoxy-3-butanone; geranyl caprylate;(+)-D-menthyl acetate; prenyl benzoate; 7-methoxycoumarin; cis-3-hexenyl 2-methyl butyrate; cis-3-hexenyl trans-2-hexenoate; ethyl valerate; n-pentyl butyrate; ethyl 3-hydroxybutyrate; flor acetate; hexilene neopentanoate; decyl propionate; phenethyl tiglate; 2-phenyl(2)propenyl-l ester; methyl cyclopentylidene acetate; isononyl acetate; p-cresyl crotonate; octahydrocoumarin; methyl trans-2,cis-4-decadienoate; 3,3,5-trimethylcyclohexyl acetate; vanilla hexyl; cis-3-hexenyl levulinate; dimethyl anthranilate; methyl 2-methylbutyrate; butyl salicylate; isomentyl acetate; dihydrocarveol acetate; tetrahydrolinalyl acetate; dimethyl octanyl acetate; methyl cis-4-octenoate; hexahydro-S^S-trimethyl / ^Sa-ethane-SaH-lbenzopyran-2(3 H)-one; cyclohexylethyl acetate; alpha-acetoxystyrene; p-methylbenzyl acetate; heptyl propionate; gamma-dodecalactone; nenium isobutyrate; geranyl isobutyrate; hexyl isobutyrate; methyl geranium; or mixtures of these.Preferably, the core perfume may comprise one or more of the following perfume ester raw materials, as such PRMs are particularly desirable from an aesthetic point of view: methyl laitone; verdox HC; ethyl beta-safranate; hexarose; cyclobutanate; cyclogalbanate; ethyl alpha-safranate; jasmal; styralyl acetate; nonalactone; gamma-undecalactone (racemic); verdox; flor acetate; or mixtures thereof. The core fragrance may contain a blend of perfume raw materials. This core fragrance may comprise at least three, four, five, six, seven, eight, nine, or at least ten perfume raw materials. A blend of perfume raw materials may provide a more complex and desirable aesthetic and / or improved performance or longevity of the fragrance, for example, across a variety of contact points. The core perfume may comprise fewer than approximately fifty, or fewer than approximately forty, or fewer than approximately thirty, or fewer than approximately twenty-five, or fewer than approximately twenty perfume raw materials. Limiting the number of perfume raw materials in a perfume may be desirable as a way to reduce or limit the complexity and / or cost of the formulation. The perfume may comprise at least one, or at least two, or at least three perfume raw materials that do not form acids. The perfume may comprise at least one, or at least two, or at least three perfume raw materials that do not comprise an aldehyde, acetal, ester, and / or lactone entity. The perfume may comprise at least one perfume raw material of natural origin. Such components may be desirable for sustainability / environmental reasons. Perfume raw materials of natural origin may include natural extracts or essences, which may contain a mixture of natural perfume raw materials. Such natural extracts or essences may include orange oil, lemon oil, rose extract, lavender, musk, patchouli, balsamic essence, sandalwood oil, pine oil, cedarwood, and similar ingredients. The core of the encapsulated components described herein may comprise a partitioning modifier. The core may comprise, in addition to the encapsulated benefit agent, greater than 0% to approximately 80%, preferably greater than 0% to approximately 50%, more preferably greater than 0% to approximately 30%, and most preferably greater than 0% to approximately 20%, based on the total weight of the core, of a partitioning modifier. The partition modifier may comprise a material selected from the group consisting of vegetable oil, modified vegetable oil, mono-, di-, and triesters of C4-C24 fatty acids, isopropyl myristate, dodecanephenone, lauryl laurate, methyl behenate, methyl laurate, methyl palmitate, methyl stearate, and mixtures thereof. The partition modifier may preferably comprise or consist of isopropyl myristate. The modified vegetable oil may be esterified and / or brominated. The modified vegetable oil may preferably comprise castor oil and / or soybean oil. U.S. Patent Application Publication No. 20110268802, incorporated herein by reference, describes other partition modifiers that may be useful in the encapsulated beneficiation agents described herein. Deck The encapsulated components may include a cover. The cover may partially or completely surround the core. The shell may comprise a polymeric material. The polymeric material may comprise a (meth)acrylate material. As described above, perfumes with an acid value greater than 5.0 mg KOH / g have been found to perform remarkably well when encapsulated in a shell comprising an acrylate material. The polymeric material of the shell may be formed, at least in part, by a radical polymerization process. The acrylate material of the cover may include a (meth)acrylate material selected from the group consisting of a polyacrylate, a polyethylene glycol acrylate, a polyurethane acrylate, an epoxy acrylate, a polymethacrylate, a polyethylene glycol methacrylate, a polyurethane methacrylate, an epoxy methacrylate, and mixtures thereof. As used in this description, reference to the term (meth)acrylate or (meth)acrylic shall be understood to refer to both the acrylate and methacrylate versions of the specified monomer, oligomer, and / or prepolymer. For example, allyl (meth)acrylate indicates that both allyl methacrylate and allyl acrylate are possible; similarly, reference to alkyl esters of (meth)acrylic acid indicates that both acrylic acid alkyl esters and methacrylic acid alkyl esters are possible; similarly, poly(meth)acrylate indicates that both polyacrylate and polymethacrylate are possible. Poly(meth)acrylate materials intended to cover a broad spectrum of polymeric materials include, for example, polyester poly(meth)acrylates, urethane poly(meth)acrylates and polyurethane (especially those prepared by reacting a hydroxyalkyl(meth)acrylate with a polyisocyanate or a urethane polyisocyanate),methyl cyanoacrylate, ethyl cyanoacrylate, diethylene glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, allyl (meth)acrylate, glycidyl (meth)acrylate, functional silicones of (meth)acrylate, di-, tri- and tetraethylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, di(pentamethylene glycol di(meth)acrylate, ethylene di(meth)acrylate, neopentyl glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, ethoxylated bisphenol A di(meth)acrylates, bisphenol A di(meth)acrylates, diglycerol di(meth)acrylate, dichloroacrylate of tetraethylene glycol, 1,3-butanediol di(meth)acrylate, neopentyl di(meth)acrylate, trimethylolpropane tri(meth)acrylate, polyethylene glycol di(meth)acrylate, and dipropylene glycol di(meth)acrylate, and various polyfunctional (meth)acrylates. In addition, monofunctional acrylates can be used favorably, i.e.,Those that contain only one acrylate group. Typical monoacrylates include 2-ethylhexyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, cyanoethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, p-dimethylaminoethyl (meth)acrylate, lauryl (meth)acrylate, cyclohexyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, chlorobenzyl (meth)acrylate, aminoalkyl(meth)acrylate, various alkyl(meth)acrylates, and glycidyl (meth)acrylate. Mixtures of (meth)acrylates or their derivatives may also be used, as well as combinations of one or more monomers, oligomers and / or prepolymers of (meth)acrylate or its derivatives with other copolymerizable monomers, including acrylonitriles and methacrylonitriles. The main material of said cover may comprise polyacrylate. The cover material may include from approximately 25% to approximately 100%, or from approximately 50% to approximately 100%, or from approximately 65% ​​to approximately 100%, by weight of the cover material, of a polyacrylate polymer. The polyacrylate may include a crosslinked polyacrylate polymer. The (meth)acrylate material of the encapsulants may include a polymer derived from a material comprising one or more polyfunctional acrylate entities. The polyfunctional acrylate entity may be selected from the group consisting of trifunctional acrylate, tetrafunctional acrylate, pentafunctional acrylate, hexafunctional acrylate, heptafunctional acrylate, and mixtures thereof. The polyfunctional acrylate entity is preferably hexafunctional acrylate. The coating material may include a polyacrylate comprising an entity selected from the group consisting of an acrylate entity, a methacrylate entity, an amine acrylate entity, an amine methacrylate entity, a carboxylic acid acrylate entity, a carboxylic acid methacrylate entity, and combinations thereof, preferably an amine methacrylate or carboxylic acid acrylate entity. The (meth)acrylate material may include a material comprising one or more multifunctional acrylate and / or multifunctional methacrylate entities. The ratio of material comprising one or more multifunctional acrylate entities to material comprising one or more methacrylate entities may be from approximately 999:1 to approximately 6:4, preferably from approximately 99:1 to approximately 8:1, and more preferably from approximately 99:1 to approximately 8.5:1. Examples of multifunctional acrylates include commercial materials from Sartomer Inc., such as CN975 (a hexafunctional aromatic urethane acrylate), CN9006 (a hexafunctional aliphatic urethane acrylate), CN296, CN293, CN2295 (a hexafunctional acrylate polyester oligomer or acrylated polyester), CN2282, CN294E, CN299 (a tetrafunctional acrylate polyester oligomer or acrylated polyester), SR494, SR295, SR255 (a tetrafunctional acrylate oligomer), SR9009, SR9011 (a trifunctional methacrylate oligomer), SR929 (a polyester urethane acrylate oligomer), SR9053 (a trifunctional acid ester acrylate oligomer), CN989, CN9301 (an aliphatic urethane acrylate), SR350, SR353 (a trifunctional acrylate oligomer), SR9012 (a trifunctional acrylate ester), and / or SR368 (a tris(2hydroxyethyl)isocyanurate triacrylate).The acrylate material can be derived from a monomer selected from a hexafunctional acrylate, a triacrylate, or mixtures thereof, preferably a hexafunctional aromatic acrylate, an isocyanurate triacrylate, or mixtures thereof, most preferably a hexafunctional aromatic urethane acrylate, a tris(2-hydroxyethyl)isocyanurate triacrylate, or mixtures thereof, as such materials have been found to be useful for making robust capsules. The encapsulation, based on the total weight of the encapsulated product, may comprise from approximately 0.1% to approximately 40%, preferably from approximately 0.5% to approximately 40%, and more preferably 0.8% to 5%, of an emulsifier. Emulsifiers may be useful as processing aids during the formation of the encapsulated products. The emulsifier may be embedded in and / or located on the coating.The emulsifier can be selected from the group consisting of polyvinyl alcohol, carboxylated or partially hydrolyzed polyvinyl alcohol, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, salts or esters of stearic acid, lecithin, organosulfonic acid, 2-acrylamido-2-alkylsulfonic acid, styrene sulfonic acid, polyvinylpyrrolidone, copolymers of vinylpyrrolidone, polyacrylic acid, polymethacrylic acid; copolymers of acrylic acid and methacrylic acid, and water-soluble surfactant polymers that reduce the surface tension of water. The emulsifier preferably comprises polyvinyl alcohol. Preferably, the polyvinyl alcohol has at least one of the following properties, or a mixture thereof: (i) a degree of hydrolysis of 70% to 99%, preferably 75% to 98%, more preferably 80% to 96%, more preferably 82% to 96%, most preferably 86% to 94%; and / or (ii) a viscosity of 2 mPa·s to 150 mPa·s, preferably 3 mPa·s to 70 mPa·s, more preferably 4 mPa·s to 60 mPa·s, even more preferably 5 mPa·s to 55 mPa·s in a 4% aqueous solution at 20 °C; Suitable polyvinyl alcohol materials can be selected from Selvol 540 PVA (Sekisui Specialty Chemicals, Dallas, TX), Mowiol 18-88 = Poval 18-88, Mowiol 3-83, Mowiol 4-98 = Poval 4-98 (Kuraray), Poval KL-506 = Poval 6-77 KL (Kuraray), Poval R-1130 = Poval 25-98 R (Kuraray), Gohsenx K-434 (Nippon Gohsei). The encapsulants described herein may include a coating. The shell may comprise the coating; for example, the coating may be on an outer surface of the shell. The encapsulants may be manufactured and subsequently coated with a coating material. The coating may be useful as a deposition aid. Non-limiting examples of coating materials include, but are not limited to, materials selected from the group consisting of poly(meth)acrylate, poly(ethylene maleic anhydride), polyamine, wax, polyvinylpyrrolidone, polyvinylpyrrolidone copolymers, polyvinylpyrrolidone ethyl acrylate, polyvinylpyrrolidone vinyl acrylate, polyvinylpyrrolidone methacrylate, polyvinylpyrrolidone / vinyl acetate, polyvinyl acetal, polyvinyl butyral, polysiloxane, polypropylene, maleic anhydride, maleic anhydride derivatives, copolymers of maleic anhydride derivatives, polyvinyl alcohol,Butadiene styrene latex, gelatin, gum arabic, carboxymethylcellulose, carboxymethyl hydroxyethylcellulose, hydroxyethylcellulose, other modified celluloses, sodium alginate, chitosan, casein, pectin, modified starch, polyvinyl acetal, polyvinyl butyral, polyvinyl methyl ether / maleic anhydride, polyvinylpyrrolidone and its copolymers, poly(trimethylvinylpyrrolidone / methacrylamidopropyl ammonium chloride), polyvinylpyrrolidone / vinyl acetate, polyvinylpyrrolidone / dimethylaminoethyl methacrylate, polyvinyl amines, polyvinyl formamides, polyallyl amines and copolymers of polyvinyl amines, polyvinyl formamides, and polyallyl amines and mixtures thereof. The coating material may be a cationic polymer. The lining material may include chitosan. The compositions may comprise encapsulations according to the present description wherein at least 75% of the encapsulants have an encapsulation cover thickness of approximately 10 nm to approximately 350 nm, approximately 20 nm to approximately 200 nm, or 25 nm to approximately 180 nm, as determined by the encapsulation cover thickness test method described herein. Consumer product adjuvants The consumer product compositions of this composition may include a consumer product adjuvant. The consumer product adjuvant may provide a benefit in the intended end use of a composition, or it may be a processing aid and / or stability aid. Consumer product adjuvant materials may include: surfactants, conditioning agents, deposition aids, rheology modifiers or structuring agents, bleaching systems, stabilizers, additives, chelating agents, dye transfer inhibitors, dispersants, enzymes and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil extraction / anti-redeposition agents, brighteners, foam suppressants, silicones, toning agents, dyes MA / a / ZUZl / UlUOÜO aesthetic, perfumes and additional perfume delivery systems, structural elasticizing agents, carriers, hydrotropes, processing aids, structuring agents, anti-caking agents, coatings, formaldehyde scrubbers and / or pigments. Depending on the intended form, the formulation and / or end-use compositions described herein may or may not contain one or more of the following auxiliary materials: bleaching activators, surfactants, additives, chelating agents, dye transfer inhibitors, dispersants, enzymes and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil extraction / anti-redeposition agents, brighteners, foam suppressants, dyes, additional perfumes and perfume delivery systems, structural elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids, structuring agents, anti-caking agents, coatings, formaldehyde scrubbers and / or pigments. The precise nature of these additional components and their incorporation levels will depend on the physical form of the composition and the nature of the operation for which it will be used. However, when one or more adjuvants are present, they may be present as detailed below. The following is a non-exhaustive list of suitable additional adjuvants. Surfactants The compositions described herein may include surfactants. Surfactants can be useful in providing, for example, cleaning benefits. The compositions may comprise a surfactant system, which may contain one or more surfactants. The compositions described herein may include from approximately 1% to approximately 70%, or from approximately 2% to approximately 60%, or from approximately 5% to approximately 50%, by weight of the composition, of a surfactant system. Liquid compositions may include from approximately 5% to approximately 40%, by weight of the composition, of a surfactant system. Compact formulations, including compact liquids, gels, and / or compositions suitable for a unit-dose form, may include from approximately 25% to approximately 70%, or from approximately 30% to approximately 50%, by weight of the composition, of a surfactant system. The surfactant system may include anionic surfactant, nonionic surfactant, zwitterionic surfactant, cationic surfactant, amphoteric surfactant, or combinations thereof. The surfactant system may include linear alkylbenzene sulfonate, alkyl ethoxylated sulfate, alkyl sulfate, nonionic surfactant such as ethoxylated alcohol, amine oxide, or mixtures thereof. Surfactants may be derived, at least in part, from natural sources, such as naturally occurring raw material alcohols. Suitable anionic surfactants may include any conventional anionic surfactant. This may include a sulfate detergent surfactant, e.g., alkoxylated and / or non-alkoxylated alkyl sulfate materials, and / or sulfonic detergent surfactants, e.g., alkylbenzene sulfonates. Anionic surfactants may be linear, branched, or combinations thereof. Preferred surfactants include linear alkylbenzene sulfonate (LAS), alkyl ethoxylated sulfate (AES), alkyl sulfates (AS), or mixtures thereof.Other suitable anionic surfactants include branched modified alkylbenzene sulfonates (MLAS), methyl ester sulfonates (MES), sodium lauryl sulfate (SLS), sodium lauryl ether sulfate (SLES), and / or alkyl ethoxylated carboxylates (AEC). Anionic surfactants may be present as acids, salts, or mixtures thereof. Anionic surfactants can be partially or completely neutralized, for example, by an alkali metal (e.g., sodium) or an amine (e.g., monoethanolamine). The surfactant system may include a nonionic surfactant. Suitable nonionic surfactants include alkoxylated fatty alcohols, such as ethoxylated fatty alcohols. Other suitable anionic surfactants include alkoxylated alkylphenols, alkylphenol condenses, medium-chain branched alcohols, medium-chain branched alkyl alkoxylates, alkylpolysaccharides (e.g., alkylpolyglycosides), polyhydroxy fatty acid amides, ether-terminated poly(oxyalkylated) alcohol surfactants, and mixtures thereof. The alkoxylate units may be ethyleneoxyl units, propylenoxyl units, or mixtures thereof. Nonionic surfactants may be linear, branched (e.g., medium-chain branched), or a combination thereof.Specific nonionic surfactants may include alcohols that have an average of approximately 12 to approximately 16 carbons, and an average of approximately 3 to approximately 9 ethoxy groups, such as C12-C14 nonionic surfactant EO7. Zwitterionic surfactants may include any conventional zwitterionic surfactant, such as betaines, including alkyldimethyl betaine and cocodimethyl amidopropyl betaine, Cs to cis amine oxides (e.g., C12 to cis) (e.g., C12-14 dimethylamine oxide), and / or sulfo- and hydroxy betaines, such as N-alkyl-N,N-dimethylamine-1-propane sulfonate where the alkyl group may be Cs to cis, or C10 to C14. The zwitterionic surfactant may include amine oxide. Depending on the formulation and / or intended end use, the composition may be substantially free of certain surfactants. For example, liquid fabric enhancer compositions, such as fabric softeners, may be substantially free of anionic surfactant, as surfactants can interact negatively with cationic ingredients. Active conditioning The compositions described herein may include a conditioning agent. Compositions containing conditioning agents may provide benefits such as smoothness, wrinkle reduction, anti-static properties, conditioning, elasticity enhancement, color improvement, and / or improved appearance. Conditioning agents may be present at a level of approximately 1% to approximately 99% by weight of the oral composition. The composition may include approximately 1%, or approximately 2%, or approximately 3%, to approximately 99%, or to approximately 75%, or to approximately 50%, or to approximately 40%, or to approximately 35%, or to approximately 30%, or to approximately 25%, to approximately 20%, or to approximately 15%, or to approximately 10%, by weight of the composition, of conditioning agent. The composition may include approximately 5% to approximately 30%, by weight of the composition, of conditioning agent. Suitable fabric conditioning agents for the compositions described herein may include quaternary ammonium ester compounds, silicones, non-ester quaternary ammonium compounds, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, polysaccharides, fatty acids, softening or conditioning oils, polymeric latex, or combinations thereof. The composition may include a quaternary ammonium ester compound, a silicone, or combinations thereof, preferably a combination. The total combined amount of quaternary ammonium ester compound and silicone may be approximately 5% to approximately 70%, or approximately 6% to approximately 50%, or approximately 7% to approximately 40%, or approximately 10% to approximately 30%, or approximately 15% to approximately 25% of arabinose and ethylene carbonate combined, by weight of the composition. The composition may include a quaternary ammonium ester compound and silicone in a weight ratio of approximately 1:10 to approximately 10:1, or approximately 1:5 to approximately 5:1, or approximately 1:3 to approximately 3:1, or approximately 1:2 to approximately 2:1, or approximately 1:1.5 to approximately 1.5:1, or approximately 1:1. The composition may contain mixtures of different types of conditioning agents. The compositions described herein may contain a certain conditioning agent but are substantially free of others. For example, the composition may be free of quaternary ammonium ester compounds, silicones, or both. The composition may comprise quaternary ammonium ester compounds but is substantially free of silicone. The composition may comprise silicone but is substantially free of quaternary ammonium ester compounds. Warehouse Assistant The compositions described herein may include a deposition aid. Deposition aids may facilitate the deposition of encapsulants, conditioning agents, perfumes, or combinations thereof, thereby enhancing the performance benefits of the compositions and / or enabling more efficient formulation of such beneficial agents. The composition may comprise, by weight of the composition, from 0.0001% to 3%, preferably from 0.0005% to 2%, more preferably from 0.001% to 1%, or from approximately 0.01% to approximately 0.5%, or from approximately 0.05% to approximately 0.3%, of a deposition aid. The deposition aid may be a cationic or amphoteric polymer, preferably a cationic polymer. Generally, cationic polymers and their manufacturing methods are well-known in the literature. Suitable cationic polymers may include quaternary ammonium polymers known as Polyquaternium polymers, as designated by the International Nomenclature of Cosmetic Ingredients, such as Polyquaternium-6 (poly(diethyldimethylammonium chloride)), Polyquaternium-7 (acrylamide-diethyldimethylammonium chloride copolymer), Polyquaternium-10 (quaternized hydroxyethylcellulose), Polyquaternium-22 (acrylic acid-diethyldimethylammonium chloride copolymer), and the like. The deposition auxiliary may be selected from the group consisting of polyvinylformamide, partially hydroxylated polyvinylformamide, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinyl alcohol, polyacrylates, and combinations thereof. The cationic polymer may comprise a cationic acrylate. Deposit aids can be added concomitantly with encapsulants (at the same time as, e.g., encapsulated benefit agents) or directly / independently in the fabric treatment composition. The weighted average molecular weight of the polymer can be 500 to 5,000,000, 1,000 to 2,000,000, or 2,500 to 1,500,000 daltons, as determined by size exclusion chromatography related to polyethylene oxide standards using refractive index (RI) detection. The weighted average molecular weight of the cationic polymer can be 5,000 to 37,500 daltons. Rheology modifier / structuring agent The compositions described herein may contain a rheology modifier and / or a structuring agent. Rheology modifiers may be used to thicken or thin liquid compositions to a desired viscosity. Structuring agents may be used to facilitate phase stability and / or to suspend or inhibit particle aggregation in the liquid composition, such as encapsulated particles as described herein. Suitable rheology modifiers and / or structuring agents may include non-polymeric crystalline hydroxyl functional structuring agents (including those based on hydrogenated castor oil), polymeric structuring agents, cellulosic fibers (e.g., microfibrillated cellulose, which may be of bacterial, fungal or vegetable origin, including wood), diamido gelling agents, or combinations thereof. Polymer structuring agents can be of natural or synthetic origin. Natural polymer structuring agents may include hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylcellulose, polysaccharide derivatives, and mixtures thereof. Polysaccharide derivatives may include pectin, alginate, arabinogalactan (gum arabic), carrageenan, gellan gum, xanthan gum, guar gum, and mixtures thereof. Synthetic polymer structuring agents may include polycarboxylates, polyacrylates, hydrophobically modified ethoxylated urethanes, hydrophobically modified nonionic polyols, and mixtures thereof. Polycarboxylate polymers may include polyacrylate, polymethacrylate, or mixtures thereof. Polyacrylates may comprise a copolymer of an unsaturated mono- or dicarbonic acid and a C1-C30 alkyl ester of (meth)acrylic acid. These copolymers are distributed by Noveon Inc.under the trade name Carbopol Aqua 30®. Another suitable structuring agent is sold under the trade name Rheovis CDE, available from BASF. Encapsulated and raw material compositions of these This description also relates to encapsulants and their raw material compositions. The encapsulants described herein, which may have a core and a shell surrounding the core, were described in more detail above. The encapsulants described herein may be prepared according to any known method using suitable starting materials. For example, the encapsulants may be prepared by a process comprising heating, in one or more heating stages, an emulsion, the emulsion being produced by emulsifying the combination of: (a) a first composition formed by combining a first oil and a second oil, said first oil comprising a perfume, an initiator, and a partition modifier, preferably a partition modifier comprising a material selected from the group consisting of vegetable oil (preferably comprising castor oil and / or soybean oil), modified vegetable oil (preferably esterified and / or brominated), propan-2-yl tetradecanoate (i.e., isopropyl myristate), and mixtures thereof; preferably the partition modifier comprising propan-2-yl tetradecanoate;said second oil comprises (i) an oil-soluble aminoalkyl acylate and / or methacrylate monomer; (ii) a carboxyalkyl acrylate monomer and / or oligomer; (iii) a material selected from the group consisting of a multifunctional acrylate monomer, multifunctional methacrylate monomer, multifunctional methacrylate oligomer, and mixtures thereof; (iv) a perfume; and (b) a second composition comprising water, a pH regulator, an emulsifier, preferably an anionic emulsifier, said emulsifier preferably comprising polyvinyl alcohol, and optionally an initiator. In the process described, the heating stage comprises heating the emulsion from approximately 1 hour to approximately 20 hours, preferably from approximately 2 hours to approximately 15 hours, with greater preference from approximately 4 hours to approximately 10 hours, with maximum preference from approximately 5 hours to approximately 7 hours, and / or heating sufficiently to transfer from approximately 500 joules / kg to approximately 5000 joules / kg, or from approximately 1000 joules / kg to approximately 4500 joules / kg, or from approximately 2900 joules / kg to approximately 4000 joules / kg to the emulsion. The emulsion can be characterized by, prior to said heating stage, a volume-weighted average encapsulation size of approximately 0.5 microns to approximately 100 microns, preferably from approximately 1 micron to approximately 60 microns, more preferably from approximately 10 microns to approximately 25 microns or from approximately 0.5 microns to approximately 10 microns. The weight ratio of the first composition to the second composition can be from approximately 1:9 to approximately 1:1, preferably from approximately 3:7 to approximately 4:6. The weight ratio of the first oil to the second oil can be from approximately 99:1 to approximately 1:99, preferably 9:1 to approximately 1:9, most preferably 6:4 to approximately 8:2. This description also relates to raw material compositions comprising the encapsulated components as described herein. These raw material compositions, which may be convenient for storage and / or transport, may be combined with other adjuvant ingredients to form a consumer product composition. The raw material composition may be a suspension or an agglomerate. Suspensions may include from approximately 1% to approximately 75%, from approximately 5% to approximately 60%, from approximately 20% to approximately 60%, or from approximately 30% to approximately 60%, by weight of the suspension, of encapsulants. Suspensions may comprise from approximately 25% to approximately 99%, from approximately 40% to approximately 95%, from approximately 40% to approximately 80%, or from approximately 40% to approximately 70%, by weight of the composition, of water. The suspension may comprise a processing aid, which may be selected from the group consisting of water, added inhibitor materials (such as divalent salts), particle suspension polymers, solvents (polar and / or non-polar), and mixtures thereof. Examples of added inhibitor materials may include salts that can have a charge-protecting effect around the particle, such as magnesium chloride, calcium chloride, magnesium bromide, magnesium sulfate, and mixtures of these. Examples of particle suspension polymers include polymers such as xanthan gum, carrageenan gum, guar gum, shellac, alginates, chitosan; cellulosic materials such as carboxymethylcellulose, hydroxypropyl methylcellulose, cationicly charged cellulosic materials; polyacrylic acid; polyvinyl alcohol; hydrogenated castor oil; ethylene glycol distearate; and mixtures thereof. Examples of solvents (which, as used in the present description, are not intended to include water) include polar solvents including, but not limited to, ethylene glycol, propylene glycol, polyethylene glycol, glycerol and non-polar solvents including, but not limited to, mineral oil, silicone oils, hydrocarbon paraffin oils and mixtures thereof. The suspensions may further comprise a deposition aid, such as a polymer selected from the group comprising: polysaccharides, in one aspect, cationicly modified starch and / or cationicly modified guar; polysiloxanes; polydiallyl dimethylammonium halides; copolymers of polydiallyl dimethylammonium chloride and polyvinylpyrrolidone; a composition comprising polyethylene glycol and polyvinylpyrrolidone; acrylamides; imidazoles; imidazolinium halides; polyvinylamine; copolymers of polyvinylamine and N-vinylformamide; polyvinylformamide; polyvinyl alcohol; boric acid-crosslinked polyvinyl alcohol; polyacrylic acid; crosslinked polymers of silicone and polyglycerol ether; polyacrylic acids, polyacrylates, copolymers of polyvinylamine and polyvinyl alcohol, oligomers of amines, in one aspect, a diethylenetriamine, ethylenediamine, bis(3-aminopropyl)piperazine, N,NB¡s-(3-aminopropyl)methylamine, tris(2-aminoethyl)amine and mixtures thereof;polyethyleneimine, a derivatized polyethyleneimine, such as an ethoxylated polyethyleneimine; a polymeric compound comprising at least two entities selected from entities consisting of a carboxylic acid entity, an amine entity, a hydroxyl entity, and a nitrile entity in a backbone of polybutadiene, polyisoprene, polybutadiene / styrene, polybutadiene / acrylonitrile, carboxyl-terminated polybutadiene / acrylonitrile, or combinations thereof; preformed coacervates of anionic surfactants combined with cationic polymers; polyamines and mixtures thereof. The raw material composition may be an agglomerate comprising the encapsulants and a second material. The second material may comprise a material such as silicas, citric acid, sodium carbonate, sodium sulfate, sodium chloride, and binders such as sodium silicates, modified celluloses, polyethylene glycols, polyacrylates, polyacrylic acids, zeolites, and mixtures thereof. One or more perfumes that are different from the perfume or perfumes contained in the core of the encapsulated products may be used outside the core-shell encapsulated products. Method for developing a consumer product This description relates to processes for preparing any of the compositions described herein. The process for preparing a composition, which may be a consumer product composition, may include the step of combining an encapsulant as described herein with a consumer product adjuvant material as described herein. Encapsulants may be combined with one or more consumer product adjuvants when the encapsulants are in one or more forms, including a suspension form, a pure encapsulation form, and a spray-dried encapsulation form. The encapsulants may be combined with the consumer product adjuvants by methods including mixing and / or spraying. The compositions described herein may be formulated in any suitable form and prepared by any process chosen by the formulator. The encapsulants and adjuvant materials may be combined in a batch process, a circulating loop process, and / or an in-line blending process. Suitable equipment for use in the processes described herein may include continuously stirred tank reactors, homogenizers, turbine agitators, recirculating pumps, paddle mixers, grate mixers, ribbon mixers, vertical shaft granulators, and drum mixers, both in batch and, where available, in continuous process configurations, spray dryers, and extruders. The composition can be encapsulated in water-soluble films according to known methods to form a unit-dose article. The composition can be placed in an aerosol or other spray container according to known methods. Method for using a consumer product This description also relates to methods for using a consumer product. For example, this description relates to methods for treating a surface or article with a composition according to this description. Such methods may provide cleaning, conditioning, and / or refreshing benefits. Suitable surfaces or items may include fabrics (including clothing, towels, or linens), hard surfaces (such as tile, porcelain, linoleum, or wood floors), tableware, hair, skin, or mixtures thereof. The method may include a step of contacting a surface or article with a composition of the herein description. The composition may be in pure form or diluted in a liquor, for example, a washing or rinsing liquor. The composition may be diluted in water before, during, or after contacting the surface or article. The surface or article may optionally be washed and / or rinsed before and / or after the contact step. The composition may be sprayed into the air and / or directly onto a surface or article. The method for treating and / or cleaning a surface or article may include the steps of: (a) optionally washing, rinsing and / or drying the surface or article; (b) contacting the surface or article with a composition as described herein, optionally in the presence of water; (c) optionally washing and / or rinsing the surface or article; and (d) optionally drying by passive drying and / or by an active drying method, such as a laundry dryer. For the purposes of the present invention, washing includes, but is not limited to, scrubbing and mechanical agitation. The fabric may comprise, in general, any fabric that can be washed or treated under normal consumer use conditions. The liquors comprising the described compositions can have a pH of approximately 3 to approximately 11.5. When diluted, such compositions are typically used in concentrations of approximately 500 ppm to approximately 15,000 ppm in solution. When the washing solvent is water, the temperature typically ranges from approximately 5 °C to approximately 90 °C, and when the site involves fabric, the water-to-fabric ratio is typically from approximately 1:1 to approximately 30:1. This description also relates to a surface or article treated with a composition as described herein. The surface or article treated with a composition according to this description may include encapsulations according to this description, for example, in or on a surface after treatment. Combinations The following numbered paragraphs describe specific combinations from the description. These combinations are illustrative and not intended to be exhaustive. A. A consumer product composition comprising: encapsulants; the encapsulants comprising a core and a shell surrounding the core, the core comprising a perfume, the perfume being characterized by an acid value greater than 5.0 mg KOH / g immediately prior to encapsulation, as determined by the acid value determination method described herein, and the shell comprising a polymeric material, the polymeric material comprising a (meth)acrylate material; and a consumer product adjuvant. B. A consumer product composition according to paragraph A, wherein the perfume is characterized by an acidity index greater than approximately 5.25, or ML / a / ZUZ l / U 1 uooo greater than approximately 5.50, or greater than approximately 5.75, or greater than approximately 6.0 mg / KOH immediately before encapsulation. C. A consumer product composition according to either paragraph A or B, wherein the perfume comprises from approximately 30% to approximately 75%, or from approximately 35% to approximately 70%, or from approximately 40% to approximately 60%, by weight of the total perfume in the core immediately after encapsulation formation, of aldehyde compounds, ester compounds, or mixtures thereof. D. A consumer product composition according to any of paragraphs AC, wherein the perfume comprises a material selected from the group consisting of aliphatic aldehydes and / or their acetals; cycloaliphatic aldehydes; aromatic and / or araliphatic aldehydes; aliphatic, aromatic or araliphatic esters; lactones; or mixtures thereof. E. A consumer product composition according to any of paragraphs AD, wherein the core further comprises a partition modifier, preferably a partition modifier selected from the group consisting of vegetable oil, modified vegetable oil, mono, di, and triesters of C4-C24 fatty acids, isopropyl myristate, dodecanephenone, lauryl laurate, methyl behenate, methyl laurate, methyl palmitate, methyl stearate, and mixtures thereof, most preferably isopropyl myristate. F. A consumer product composition according to any of paragraphs AE, wherein the polymeric material of the coating is formed, at least in part, by a radical polymerization process. G. A consumer product composition according to any of paragraphs AF, wherein the (meth)acrylate material is selected from the group consisting of a polyacrylate, a polyethylene glycol acrylate, a polyurethane acrylate, an epoxy acrylate, a polymethacrylate, a polyethylene glycol methacrylate, a polyurethane methacrylate, an epoxy methacrylate, and mixtures thereof. H. A consumer product composition according to any of paragraphs AG, wherein the (meth)acrylate material is derived from a material comprising one or more multifunctional acrylate entities, preferably wherein the multifunctional acrylate entity is selected from the group consisting of trifunctional acrylate, tetrafunctional acrylate, pentafunctional acrylate, hexafunctional acrylate, heptafunctional acrylate, and mixtures thereof. I. A consumer product composition according to any of paragraphs AH, wherein the (meth)acrylate material is derived from a monomer selected from a hexafunctional acrylate, a triacrylate or mixtures thereof, preferably a hexafunctional aromatic acrylate, an isocyanurate triacrylate or mixtures thereof, more preferably a hexafunctional aromatic urethane acrylate, a tris(2-hydroxyethyl)isocyanurate triacrylate, or mixtures thereof. J. A consumer product composition in accordance with any of paragraphs AI, wherein the encapsulants are characterized by a volume-weighted average diameter of approximately 10 to approximately 100 microns. K. A consumer product composition according to any of paragraphs AJ, wherein the consumer product adjuvant comprises a material selected from the group consisting of surfactants, conditioning agents, deposition aids, rheology modifiers or structuring agents, bleaching systems, stabilizers, additives, chelating agents, dye transfer inhibitors, dispersants, enzymes and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil extraction / anti-redeposition agents, brighteners, foam suppressants, silicones, toning agents, aesthetic dyes, perfumes and additional perfume delivery systems, structural elasticizing agents, carriers, hydrotropes, processing aids, anti-caking agents, coatings, formaldehyde scrubbers, pigments, and mixtures thereof. L. A consumer product composition according to any of paragraphs AK, wherein the consumer product adjuvant comprises a surfactant, preferably the surfactant is selected from anionic surfactant, nonionic surfactant, zwitterionic surfactant, cationic surfactant, amphoteric surfactant, and combinations thereof, most preferably comprising anionic surfactant. M. A consumer product composition according to any of paragraphs AL, wherein the consumer product adjuvant comprises a conditioning active, preferably a conditioning active selected from a quaternary ammonium ester compound, a silicone, or a combination thereof. N. A consumer product composition according to any of paragraphs AM, wherein the consumer product composition is in the form of a liquid composition, a granular composition, a single-compartment pouch, a multi-compartment pouch, a soluble sheet, a lozenge or globule, a fibrous article, a tablet, a bar, a flake, a dryer sheet, or a mixture thereof, preferably a liquid composition. O. A consumer product composition in accordance with any of paragraphs AN, wherein the consumer product composition is encapsulated in a water-soluble film. P. A consumer product composition according to any of paragraphs A0, wherein the consumer product composition is a laundry detergent composition, a fabric conditioning composition, a laundry additive, a fabric pretreatment composition, a fabric renewing composition, a dishwashing composition, a hard surface cleaning composition, an air care composition, a car care composition, a hair treatment product, a skin care product, a shaving care product, a personal cleansing product, a deodorant product, an antiperspirant product, or mixtures thereof. Q. A consumer product composition according to any of paragraphs AP, wherein the perfume comprises one or more aldehyde perfume raw materials selected from the group consisting of: 2,6-dimethyloctanal; 2,2,5-trimethyl-4-hexenal; scentenal; 2-phenyl-3-(2-furyl)prop-2-enal; (I)citronellal; tetrahydrogeraniol; 2-ethoxybenzaldehyde; 5-methylfurfural; calypsone; xylose; 3-(2-furanyl)-2-methyl-2-propenal; 3,5,5-trimethylhexanal; canthoxal; 2,4,5-trimethoxybenzaldehyde; 4-hydroxy-3-methoxycinnamaldehyde; 2,4,6-trimethoxybenzaldehyde; 3,4,5-trimethoxybenzaldehyde; 2,3,4-trimethoxybenzaldehyde; (d)-citronellal; liral; methyl octyl acetaldehyde; Octanal; 3,7-dimethyl-; adoxal; citronellol oxyacetaldehyde; cis-3-hexenyl oxyacetaldehyde; methoxymelonal; n-hexanal; pentyl vanillin; o-methoxycinnamaldehyde; o-anisaldehyde; octanal; nonalaldehyde; 2,6,10-trimethylundecanal; citronellal; melonal; hydroxycitronellal; prenal; methylnonylacetaldehyde; valeraldehyde; capraldehyde; p-anisaldehyde;heptaldehído; ethyl vanillin; vaillin; heliotropin; helional; veratraldehído; metoxicitronelal; 7ethoxy-3,7-dimethyloctanal; 4-etoxibenzaldehído; vanillin isobutyrate; vanillin acetate; ethyl vanillin acetate; 1-methyl-4-(4-methyl-3-penten-1-yl)-3cyclohexeno-1-carboxaldehyde; 8-undecenal; trans,trans,-2,4-nonadienal; betasinensal; hexanal de 6-cyclopentylidene; preciclemona B; tangerine; 2thiophenocarboxaldehído; 9-decenal; trans-2,cis-6-nonadienal; acalea; 4-tertbutylbenzaldehído; trans-2-methyl-2-octenal; citral; 3-methyl-5-phenyl-pentanal; 2; ΜΛ / a / ZUZ l / U 1 uooo decenal; trans-2-decenal; alpha,4-dimethyl bencenopropanal; ds-5-octenal; cis-7decen-l-al; cis-4-decen-l-al; 2-trans-6-cis-dodecadienal; 2-trans-4-transdodecadienal; 3-cyclohexeno-l-propanal; 2- nonen-l-al; 2-undecenal; 2,4decadienal, (E,E)-; 2,4-undecadienal, (E,E)-; isohexenil ciclohexenil carboxaldehído; trans-2-nonen-l-al; 3-nonylcrolein; 2,6-nonadienal; lilial; 2trans-6-trans-nonadienal; alpha-sinensal; bourgeonal; 2-tridecenal; pt-butyl phenyl acetaldehyde; (Z)-3-dodecenal; m-methylbenzaldehído; mefloral; trans-4-decen-lal; silvial; 2-hexen-l-al; 2,4-nonadienal; floral zone; aldehyde C-ll; cis-3-hexenal; miristaldehído; Chinese aldehyde; p-tolualdehyde; Undecanal; 10-undecenal; lauraldehído; trans-2-hexenal; Geranial; 5-methyl-2-t¡ophenocarboxaldehyde; phenylacetaldehydo; alpha-amylcinamaldehído; floral super; Aldehido hexil cinámico; alpha-methyl cinamaldehído; benzaldehído; or mixes of these; preferably if selected: scentenal; adoxal; ocatanal;nonaldehído; melonal; metilnonilacetaldehído; p-anisaldehído; etil vainillina; vainillina; heliotropina; lilial; aldehido C-ll; Undecanal; 10-undecenal; lauraldehído; o mezclas de estos.; R. A consumer product composition according to any of paragraphs AQ, wherein the perfume comprises one or more perfume ester raw materials selected from the group consisting of: quinester; serenolide; nirvanolide; acetarolle; alpinofix; aladinate; methyl laitone; firascone; 1-methylbuten-1-acetate; (Z)-3-heptene-l-yl acetate; 3-hydroxy-4,5-dimethyl-2(5H)-furanone; isoamyl undecylenate; verdox HC; pivarose Q; citryl acetate; (E)-5-tangerinol; (Z)-5-tangerinol; miraldyl acetate; geranyl phenylacetate; bergaptene; isopimpinelin; parsol MCX; ethyl beta-safranate; nopyl acetate; calixol; methyl octalactone; isopulegill acetate; ethyl tiglate; vanoris; acetoxymethyl-isolongifolene (isomers); l-oxaspiro[2.5]octane-2-carboxylic acid, 5,5,7-trimethyl-ethyl ester; 3,6-dimethyl-3-octanyl acetate; cis-3-hexenyl-cis-3-hexenoate; cis-3-hexenyl lactate; sclareolide; hexarose; cis-iso-ambretolide; frutinat; ethyl gamma-safranate;amyl cinamate; isoambretolide; bornyl isobutyrate; cyprisate; anapear; montaverdi; vertosin; isobornyl isobutyrate; cyprisate C¡; cyclobutanate; ds-3-hexenyl butyrate; geranyl tiglate; transhedione; isoamyl acetate; givescone; cyclogalbanate; verdural B extra; ethyl alphasafranate; jasmal; estyral acetate; nonalactone; trans-ambretolide; furfuryl heptanoate; furfuryl hexanoate; alpha-amylcinamyl acetate; carvyl acetate; ethyl isobutanoate; citronyl isobutyrate; furfuryl octanoate; octyl 2-furoate; cedar acetate; isoamyl acetoacetate; cis-3-hexenyl benzoate; phenylethyl benzoate; hexenyl tiglate; citrus; gammaundecalactone (racemic); (S)-gama-undecalactone; (R)-gamma-undecalactone; phenyl benzoate; geranyl benzoate; isobutyl salicylate; isoamyl salicylate; verdox; 2-acetoxy-3-butanone; geranyl caprylate; (+)-Dmenthyl acetate; prenyl benzoate; 7-methoxycoumarin;cis-3-hexenyl-2-methyl butyrate; cis-3-hexenyl trans-2-hexenoate; ethyl valerate; n-pentyl butyrate; ethyl 3-hydroxybutyrate; fluorine acetate; hexyl neopentanoate; decyl propionate; phenethyl tiglate; 2-phenyl-1(2)propenyl-1 ester; methyl cyclopentylidene acetate; isononyl acetate; p-cresyl crotonate; octahydrocoumarin; trans-2,cis-4-methyl decadienoate; 3,3,5-trimethylcyclohexyl acetate; hexyl vanillate; cis-3-hexenyl levulinate; dimethyl anthranilate; methyl 2-methylbutyrate; butyl salicylate; isomentyl acetate; dihydrocarveol acetate; tetrahydrolinalyl acetate; dimethyl octanyl acetate; methyl cs-4-octenoate; hexahydro3,5,5-trimethyl-3,8a-ethane-8aH-l-benzopyran-2(3 H)-one; cyclohexylethyl acetate; alpha-acetoxystyrene; p-methylbenzyl acetate; heptyl propionate; gammadodecalactone; neryl isobutyrate; geranyl isobutyrate; hexyl isobutyrate; methyl geranium; or mixtures of these;preferably methyl laitone; verdox HC; ethyl beta-safranate; hexarose; cyclobutanate; cyclogalbanate; ethyl alpha-safranate; jasmal; styralyl acetate; nonalactone; gamma-undecalactone (racemic); verdox; fluor acetate; or mixtures thereof. S. A method for treating a surface or article with the consumer product composition in accordance with any of paragraphs AR, the method comprising the step of bringing the surface or article into contact with the consumer product composition, optionally in the presence of water. Testing methods Extraction of encapsulated finished products. Except where otherwise specified in this description, the preferred method for isolating encapsulates from finished products is based on the fact that the density of most such encapsulates differs from that of water. The finished product is mixed with water to dilute and / or release the encapsulates. The diluted product suspension is centrifuged to accelerate the separation of the encapsulates. These encapsulates tend to float or sink in the dilute dispersion / solution of the finished product. Using a pipette or spatula, the upper and lower layers of this suspension are removed, and further rounds of dilution and centrifugation are performed to separate and enrich the encapsulates. The encapsulates are observed using an optical microscope equipped with cross-polarization or differential interference contrast (DIC) filters at a total magnification of 100x to 400x.Microscopic observations provide an initial indication of the presence, size, quality, and aggregation of the encapsulated particles. The following procedure is performed to extract the encapsulated components from the finished liquid fabric enhancer product: 1. Three aliquots of approximately 20 ml of a liquid fabric enhancer are placed into three separate 50 ml centrifuge tubes and each aliquot is diluted 1:1 with DI water (e.g., 20 ml of fabric enhancer + 20 ml of DI water), each aliquot is thoroughly mixed and each aliquot is centrifuged for 30 minutes at approximately 10,000 x g. 2. After centrifuging according to step 1, the bottom layer of water (about 10 ml) is discarded in each 50 ml centrifuge tube; then, 10 ml of DI water is added to each 50 ml centrifuge tube. 3. For each aliquot, the centrifugation process is repeated, the bottom layer of water is removed, and then 10 ml of DI water is added to each 50 ml centrifuge tube two more times. 4. The top layer is removed with a spatula or pipette, and 5. This top layer is transferred to a 1.8 ml centrifuge tube and centrifuged for 5 minutes at approximately 20,000 x g. 6. The top layer is removed with a spatula and transferred into a new 1.8 ml centrifuge tube and DI water is added until the tube is completely filled; it is then centrifuged for 5 minutes at approximately 20,000 x g. 7. Remove the bottom layer with a fine pipette and add DI water until the tube is completely filled and centrifuge for 5 minutes at approximately 20,000 x g. 8. Step 7 is repeated 5 more times (6 times in total). If both an upper and a lower layer of enriched capsules appear in step 1 described above, then proceed immediately to step 3 (i.e., skip step 2) and continue with steps 4 through 8. Once these steps are completed, the lower layer from the 50 ml centrifuge tube in step 1 is removed using a spatula and / or pipette. The lower layer is transferred to a 1.8 ml centrifuge tube and centrifuged for 5 minutes at approximately 20,000 x g. The lower layer is then removed into a new tube, and DI water is added until the tube is completely full; it is then centrifuged for 5 minutes at approximately 20,000 x g. The upper layer (water) is removed, and DI water is added again until the tube is full. This process is repeated 5 more times (6 times in total). The enriched encapsulation and the isolated upper and lower layers are recombined together. If the fabric enhancer is white or it is difficult to distinguish the enriched encapsulation layers, add 4 drops of dye (such as Liquitint Blue JH, 5% premix from Milliken & Company, Spartanburg, South Carolina, USA) to the Step 1 centrifuge tube and continue with isolation as described. For the extraction of encapsulates from solid finished products that readily disperse in water, mix 11 g of water with 20 g of the finished product (e.g., detergent foams, films, gels, and granules; or water-soluble polymers; soap flakes and bars; and other readily water-soluble matrices such as salts, sugars, clays, and starches). When extracting encapsulates from finished products that do not readily disperse in water, such as waxes, dryer sheets, dryer bars, and greasy materials, it may be necessary to add detergents, gently stir and / or heat the product, and dilute it to release the encapsulates from the matrix. The use of organic solvents or drying of the encapsulates should be avoided during the extraction steps, as these actions can damage the encapsulates during this phase. For the extraction of encapsulates from liquid finished products that are not fabric softeners or fabric enhancers (e.g., liquid laundry detergents, liquid dishwashing detergents, liquid hand soaps, lotions, shampoos, conditioners, and hair dyes), 20 ml of the finished product are mixed with 20 ml of dilute water. If necessary, NaCl (e.g., 100–200 g of NaCl) can be added to the dilute suspension to increase the solution density and facilitate the floating of the encapsulates to the top of the layer. If the product is white, making it difficult to distinguish the layers of encapsulates formed during centrifugation, a water-soluble dye can be added to the diluent to provide visual contrast. The water and product mixture undergo sequential centrifugation series, which involves removing the top and bottom layers, resuspending these layers in fresh diluent, followed by further centrifugation, isolation, and resuspension. Each centrifugation series is performed in 1.5 to 50 ml tubes, using centrifugal forces up to 20,000 xg, for periods of 5 to 30 minutes. Typically, at least six centrifugation series are required to sufficiently extract and clean the encapsulated material for testing. For example, the first centrifugation series might be performed in 50 ml tubes, centrifuged at 10,000 xg for 30 minutes, followed by five more centrifugation series, where the top and bottom layer material is resuspended separately in fresh diluent in 1.8 ml tubes and centrifuged at 20,000 xg for 5 minutes per series. If microscopic encapsulants are observed in both the upper and lower layers, the encapsulants from these two layers are then recombined after the final centrifugation stage to create a single sample containing all the supply encapsulants extracted from that product. The extracted encapsulants should be analyzed as soon as possible, but can be stored as a suspension in DI water for up to 14 days prior to analysis. An expert in the technique will recognize that several different protocols can be developed for the extraction and isolation of encapsulants from finished products, and will recognize that such methods require validation by comparing the resulting measured values, as measured before and after the incorporation and extraction of the encapsulants from the finished product. Goo The viscosity of the finished liquid product is measured using a TA Instruments AR 550 rheometer / viscometer (New Castle, DE, USA), using parallel steel plates 40 mm in diameter and a gap size of 500 pm. The high shear viscosity at 20 s1 and the low shear viscosity at 0.05 s1 are obtained from a logarithmic sweep of shear rate from 0.1 s1 to 25 s1 for 3 minutes at 21 °C. Thickness of the encapsulation cover The thickness of the encapsulation coating was measured in nanometers on 50 encapsulants using freeze-fracture cryo-scanning electron microscopy (FF cryoSEM) at magnifications between 50,000x and 150,000x. Samples were prepared by flash-freezing small volumes of a suspension of the encapsulants or the finished product. Flash-freezing could be achieved by immersion in liquid ethane or through the use of a device such as a Leica Microsystems Model 706802 EM Pact high-pressure freezer (Leica Microsystems, Wetzlar, Germany). The frozen samples were fractured at -120 °C, then cooled below -160 °C and lightly coated by vacuum metallization with gold / palladium. These steps could be accomplished using cryo-preparation devices such as those from Gatan Inc. (Pleasanton, CA, USA).The frozen, fractured, and coated sample is then transferred at -170 °C or lower to a suitable cryoSEM microscope, such as the Hitachi S5200 SEM / STEM (Hitachi High Technologies, Tokyo, Japan). In the Hitachi S-5200, scanning is performed with an accelerating voltage of 3.0 kV and a tip emission current of 5 pA–20 μA. Images of the fractured wall of the cross-sectional view are obtained from 50 selected, size-neutral, beneficial supply encapsulates to create a representative sample of the encapsulate size distribution. The shell thickness of each of the 50 encapsulates is measured using calibrated microscope software by drawing a measurement line perpendicular to the outer surface of the encapsulation shell. The 50 independent shell thickness measurements are recorded and used to calculate the mean thickness and the percentage of encapsulates with a shell thickness within the claimed range. Perfume and perfume raw materials (PRM1 To determine the identity and quantify the weight of perfume, perfume ingredients, or perfume raw materials (PRM) encapsulated within the supply capsules of the beneficial agent, gas chromatography with flame ionization mass spectrometry (GC-MS / FID) detector is used. The appropriate equipment includes: an Agilent Technologies G1530A GC / FID; a Hewlett Packard 5973 mass selective device; and a 5% phenyl methylpolysiloxane J&W DB-5 column (30 m length x 0.25 mm internal diameter x 0.25 µm film thickness). Approximately 3 g of the finished product or suspension from the supply capsules is weighed and the weight recorded. The sample is then diluted with 30 mL of deionized water and filtered through a 5.0 µm pore size nitrocellulose membrane filter. The material captured in the filter is solubilized in 5 ml of ISTD solution (25.0 mg / L of tetradecane in anhydrous alcohol) and heated to 60 °C for 30 minutes. The cooled solution is filtered through a 0.45 µm pore size PTFE syringe filter and analyzed by GC-MS / FID. Three well-known essential oils are used as reference standards for comparison. Data analysis involves summing the total area measurements minus the ISTD area measurements and calculating an average response factor (RF) for the three standard perfumes. The response factor and total area measurements for the encapsulated perfumes in the product are then used, along with the sample weight, to determine the total weight percentage of each PRM in the encapsulated perfume. The PRMs are identified from the mass spectrometry peaks. Test method to determine loqP The logarithm of the octanol / water partition coefficient (logP) is calculated for each PRM in the perfume mixture being evaluated. The logP of an individual PRM is calculated using the Consensus LogP computational model, version 14.02 (Linux), available from Advanced Chemistry Development, Inc. (ACD / Labs) (Toronto, Canada), which is unitless. The ACD / Labs Consensus LogP computational model is part of the ACD / Labs suite of models. Average size weighted by encapsulation volume The capsule size is measured using an Accusizer 780A, manufactured by Particle Sizing Systems, Santa Barbara, CA. The instrument is calibrated from 0 to 300 μm using Duke capsule size standards. Samples for capsule size evaluation are prepared by diluting approximately 1 g of emulsion, if the volume-weighted average capsule size of the emulsion is to be determined, or 1 g of capsule suspension if the volume-weighted average capsule size of the finished capsule is to be determined, in approximately 5 g of deionized water, and then further diluting approximately 1 g of this solution in approximately 25 g of water. Add approximately 1 g of the most diluted sample to the Accusizer and start the test using the auto-dilution function. The Accusizer should read more than 9200 counts / second. If the count is less than 9200, add more sample. The Accusizer will dilute the test sample to 9200 counts / second and begin the evaluation. After 2 minutes of testing, the Accusizer will display the results, including the volume-weighted average size. The amplitude index can be calculated by determining the package size at which 95% of the cumulative package volume is exceeded (95% size), the package size at which 5% of the cumulative package volume is exceeded (5% size), and the volume-weighted average package size (50% size — 50% of package volume both above and below this size). Amplitude index (5) = ((95% size)-(5% size) / 50% size). Determination of the acidity index To determine the acidity index of a perfume material, the following method is followed, which is based on DIN EN ISO 660: 2009-10. In a 200 ml three-well cup, place approximately 5 g of the perfume to be tested; record the exact weight of the perfume. To the perfume sample, add 100 ml of a solvent mixture made from equal volumes of ethanol and diethyl ether (e.g., prepare a mixture of 500 ml of each). Add 0.3 ml of phenolphthalein solution (made from 1.0 g of phenolphthalein and 100 ml of ethanol). Add a stirring rod, place it on the shaker plate, and begin stirring the sample. A pH probe is added to the sample and the pH is allowed to stabilize. The sample solution is then neutralized by slowly adding potassium hydroxide (0.1 M KOH) via titration until the sample reaches a pH of 7. At this point, the initial volume of potassium hydroxide is recorded as the initial volume. Add 0.1 M potassium hydroxide until a single drop produces a pink color change that persists for at least 15 seconds. Record this volume of potassium hydroxide as the final volume. Determine the total volume of potassium hydroxide added by calculating the difference between the initial and final volumes (e.g., the volume of KOH solution added from when pH = 7 until the sample turns a persistent pink color). The acidity index (reported as mg of KOH / g of perfume) is determined using the following equation: .1*Concentration of KOH (M)*Volume of KOH (ml) Acidity index =-------------------------------------------------Sample weight (g) It should be noted that the 5 g sample of perfume is only a guideline; larger volumes may be useful for perfumes with relatively low acid values, and smaller volumes for perfumes with relatively high acid values. Depending on the result of the initial titration, the sample weight may be increased or decreased for a repeat test. Furthermore, although 0.1 M KOH is used in this procedure, higher molalities may be useful for perfumes with relatively high acid values. The following table can be used as a rough guide. Approximate acidity index of perfume (mg KOH / g of perfume) Weight of perfume sample (g) KOH concentration (M) 0 to 1 10 0.1 1 to 4 5 0.1 4 to 15 2.5 0.1 15 to 75 0.5 0.1 3.0 0.5 >75 0.2 0.1 1.0 0.5 Determining perfume leakage To determine perfume leakage, a liquid detergent with perfume encapsulates is prepared and stored (e.g., for one week at 35°C) and then compared to a reference sample of liquid detergent that has an equal level of total perfume (e.g., 1% by weight), although it is not encapsulated. To prepare the internal standard solution, 70 mg of tonalid is weighed, 20 ml of analytical grade hexane is added, and the mixture is stirred. 200 ml of this mixture is then added to 20 ml of analytical grade hexane and stirred to homogenize, forming the internal standard solution. To extract the perfume from the liquid phase of the test or reference sample, 2 grams of the detergent sample and 2 ml of the internal standard solution are placed in an extraction vessel. Free perfume is extracted from the detergent sample by gently inverting the extraction vessel by hand twenty times. A small amount of sodium sulfate is added to the extraction vessel. Layer separation should occur. To collect the gas chromatograph data, after layer separation, the hexane layer is immediately transferred to an autosampler bottle of the gas chromatograph and the bottle is capped. 1.5 µL of the sample is injected undivided into the injection port of the gas chromatograph. Gas chromatography-mass spectrometry analysis is performed (gas chromatographic separation on Durawax-4 [60 m, 0.32 mm ID, 0.25 pm film] 40 °C / 4 °C / min / 230 °C / 20 min). The perfume leakage from the encapsulated products is calculated based on the perfume raw material according to the following calculation: Perfume raw material area capacity x reference internal area of ​​standard solution x reference weight % perfume leakage =-----------------------------------------------------------* 100 standard solution internal area capacity x reference internal area of ​​perfume raw material x capacity weight The total leakage of a perfume is the sum of the perfume leakage from the capsules per individual PRM. To determine the perfume retention (e.g., percentage of perfume that remains in the encapsulation), the % of perfume leakage is subtracted from 100. Examples The examples provided below are for illustrative purposes and are not intended to be limiting. Example 1. Illustrative perfumes Perfumes according to the present description, as well as comparative perfumes (marked with comp.) are provided in Table 1. Table 1. Perfume % by weight of aldehydes % by weight of esters % by total weight of aldehydes + esters Acidity index (mg of KOH / g of perfume) 1A (comp.) 17.0 52.4 69.4 0.80 IB (comp.) 33.4 37.0 70.4 1.31 1C (comp.) 35.9 38.6 74.5 2.00 ID (comp.) 6.2 50.7 56.9 2.94* 1E (comp.) 12.7 47.7 60.4 3.53* 1F 10.8 34.1 44.9 5.94 1G 10.4 47.7 58.1 6.32 1H 4.7 45.4 50.1 7.32 11 13.0 36.5 49.5 16.49 average of two lots Example 2. Process for making encapsulated products The polyacrylate perfume capsules are prepared as follows: an oily first phase, consisting of 37.5 g of perfume, 0.2 g of tert-butylaminoethyl methacrylate and 0.2 g of beta hydroxyethyl acrylate, is mixed for approximately 1 hour before the addition of 18 g of CN975 (Sartomer, Exter, PA). The solution is mixed as required for the subsequent process. A second oil phase, consisting of 65 g of perfume oil, 84 g of isopropyl myristate, 1 g of 2,2'-azobis(2-methylbutyronitrile), and 0.8 g of 4,4'-azobis[4-cyanovaleric acid], is added to a lined steel reactor. The reactor is maintained at 35 °C, and the oil solution is mixed at 500 rpm using a 2-inch flat paddle mixer. A nitrogen blanket is applied to the reactor at a rate of 300 cc / min. The solution is heated to 70 °C in 45 minutes and held at 70 °C for 45 minutes before being cooled to 50 °C in 75 minutes. The first oil phase is added at 50 °C, and the combined oils are mixed for a further 10 minutes at 50 °C. An aqueous phase was prepared, containing 85 g of Selvol 540 polyvinyl alcohol (Sekisui Specialty Chemicals, Dallas, TX) at 5% solids, 268 g of water, 1.2 g of 4,4'-azobis[4-cyanovaleric acid] and 1.1 g of 21.5% NaOH, and was mixed until the 4,4'-azobis[5-cyanovaleric acid] was dissolved. Once the temperature of the oil phase has been reduced to 50 °C, mixing is stopped and the aqueous phase is added to the blended oils. High shear agitation is applied to produce an emulsion with the desired size characteristics (1900 rpm for 60 minutes). Then, the temperature is increased to 75°C in 30 minutes, maintained at 75°C for 4 hours, heated to 95°C in 30 minutes and maintained at 95°C for 6 hours. Example 3. Encapsulation Leakage To test for leakage, various perfumes are encapsulated in shells that include polyacrylate materials (including CN975 from Sartomer, Inc.), generally according to the encapsulation process described in Example 2. In addition to the perfumes provided below, the cores of the encapsulants comprise approximately 30% to approximately 45% of a partition modifier (i.e., isopropyl myristate). The encapsulants are added to a liquid detergent composition that is otherwise fragrance-free. The encapsulants are added at a level to provide a total of 1% fragrance by weight of the detergent composition. The formulation of the liquid detergent is provided below in Table 2. ML / a / ZUZ 1 / U1 uooo Table 2. Ingredient Level [% by weight of active ingredient] Alkyl ether sulfate 3.96 Dodecylbenzene sulfonic acid 9.15 Ethoxylated alcohol 3.83 Amine oxide 0.51 Fatty acid 1.73 Citric acid 2.79 Sodium salt of diethylenetriaminepentamethylenephosphonic acid 0.512 Calcium chloride 0.011 Sodium formate 0.034 Quaternized hexamethylenediamine ethoxysulfate 0.664 Polyethylene glycol vinyl acetate copolymer 1.27 Optical brightener 49 0.046 1,2-Benzisothiazolin-3-one and 2-Methyl-4-isothiazolin-3-one 0.005 Ethanol 0.42 1,2-Propanediol 1.259 Sodium cumene sulfonate 1.724 Monoethanolamine 0.24 NaOH 3.1 Hydrogenated castor oil structuring agent 0.3 Silicone emulsion 0.0025 Dye 0.0054 Perfume (encapsulated in test sample; not encapsulated in reference sample) 1.0 Water, minor components Equilibrium Liquid detergent samples are aged for one week at 35°C. After storage, the samples are analyzed for perfume leakage by hexane extraction, as detailed in the test methods section above. Leakage is measured against a reference sample containing 1% by weight of the reference sample of unencapsulated perfume of the same identity. The perfumes tested are some of those provided in Example 1, Table 1 above. Tests 1-5 show encapsulations comprising comparative perfumes, characterized by acid values ​​less than 5.0 mg KOH / g. Tests 6-9 show encapsulations comprising perfumes according to the present description, characterized by acid values ​​greater than 5.0 mg KOH / g. The results of perfume leakage are shown in Table 3. Figure 1 shows a graph of acidity indices versus perfume retention, measured as the percentage of perfume remaining in the encapsulated products. Table 3. Perfume Tests (from Table 1) Acidity Index (mg KOH / g) Perfume Leakage (%) Perfume Retention (% remaining in the encapsulation) 1 (comp.) 1A 0.8 10.67* 89.33* 2 (comp.) IB 1.31 9.79 90.21 3 (comp.) 1C 2.00 2.19 97.81 4 (comp.) ID 2.94 7.52 92.48 5 (comp.) 1E 3.53 3.78 96.22 6 1F 5.94 8.9* 91.10* 7 1G 6.32 7.66* 92.34* 8 1H 7.32 13.33 86.67 9 11 16.49 19.54 80.46 * Average of two samples ** Average of three samples According to the results in Table 3 and Figure 1, perfume encapsulations that include polyacrylate materials in the encapsulation cover show relatively little leakage after storage in a detergent product, even though the perfume is characterized by an acidity index greater than 5.0 mg KOH / g. Although tested under different temperatures and times, this trend contrasts with the trend described in patent no. WO2017 / 148504, which indicates that very little perfume is retained in a capsule when the perfume has an acidity index greater than 5 mg KOH / g of perfume. Without any theoretical limitations, it is believed that the selection of the encapsulated wall material (in this description, a polyacrylate material) contributes to the relative stability of the encapsulants described herein. The dimensions and values ​​described herein should not be understood as strictly limited to the exact numerical values ​​stated. Instead, unless otherwise specified, each such dimension shall mean the stated value and a functionally equivalent range encompassing that value. For example, a dimension described as 40 mm refers to approximately 40 mm. Each document mentioned in this description, including any cross-references to related patents or applications and any patent applications or patents to which this application claims priority or benefit, is hereby incorporated by reference in its entirety unless expressly excluded or limited otherwise. Mention of any document is not an admission that it constitutes prior art with respect to any invention described or claimed herein or that, alone or in any combination with any other reference(s), it teaches, suggests, or describes such invention.Furthermore, 10 to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to the term in this document shall prevail. Although particular embodiments of the present invention have been illustrated and described, it will be evident to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention. It has therefore been intended that the appended claims encompass all changes and modifications within the scope of this invention.

Claims

1. A consumer product composition comprising: encapsulants, the encapsulants comprising a core and a shell surrounding the core, the core comprising a perfume, the perfume being characterized by an acid value greater than 5.0 mg KOH / g immediately before encapsulation, as determined by the acid value determination method described herein, and the shell comprising a polymeric material, the polymeric material comprising a (meth)acrylate material; and a consumer product adjuvant.

2. The consumer product composition according to claim 1, characterized in that the perfume is characterized by an acidity index greater than approximately 5.25, or greater than approximately 5.50, or greater than approximately 5.75, or greater than approximately 6.0 mg KOH / g immediately before encapsulation.

3. The consumer product composition according to claim 1 or 2, characterized in that the perfume comprises from approximately 30% to approximately 75%, or from approximately 35% to approximately 70%, or from approximately 40% to approximately 60%, by weight of the total perfume in the core immediately after encapsulation formation, of aldehyde compounds, ester compounds, or mixtures thereof.

4. The consumer product composition according to any preceding claim, characterized in that the perfume comprises a material selected from the group consisting of: aliphatic aldehydes and / or their acetals; cycloaliphatic aldehydes; aromatic and / or araliphatic aldehydes; aliphatic, aromatic, or araliphatic esters; lactones; or mixtures thereof.

5. The consumer product composition according to any preceding claim, characterized in that: the perfume comprises one or more aldehyde perfume raw materials selected from the group consisting of: 2,6-dimethyl-octanal; 2,2,5-trimethyl-4-hexenal; scentenal; 2-phenyl-3-(2-furyl)prop-2-enal; (l)-citronellal; tetrahydrogeraniol; 2-ethoxybenzaldehyde; 5-methylfurfural; calypsone; d-xylose; 3-(2-furanyl)-2-methyl-2-propenal; 3,5,5-trimethylhexanal; canthoxal; 2,4,5-trimethoxybenzaldehyde; 4-hydroxy-3-methoxycinnamaldehyde; 2,4,6-trimethoxybenzaldehyde; 3,4,5-trimethoxybenzaldehyde; 2,3,4-trimethoxybenzaldehyde; (d)-citronellal; liral; methyl octyl acetaldehyde; octanal, 3,7-dimethyl-; adoxal; citronellyloxyacetaldehyde; cis-3-hexenyloxyacetaldehyde; methoxymelonal; n-hexanal; pentyl vanillin; o-methoxycinmalaldehyde; o-anisaldehyde; octanal; nonalaldehyde; 2,6,10-trimethylundecanal; citronellal; melonal; hydroxycitronellal; prenal; methylnonylacetaldehyde; valeraldehyde; capraldehyde;p-anisaldehyde; heptaldehyde; ΜΛ / a / ZUZ l / U 1 uooo ethylvanillin; vanillin; heliotropin; helional; veratraldehyde; methoxycitronelal; 7-ethoxy¡-3,7dimethyloctanal; 4-ethoxybenzaldehyde; vanillin isobutyrate; vanillin acetate; vanillin ethyl acetate; l-methyl-4-(4-met¡l-3-penten-l-¡lo)-3-cyclohexene-l-carboxaldehyde; 8-decadal; trans,trans,-2,4-nonadienal; beta-senescent; 6-cyclopentylidene hexanal; preciclemona B; tangerine; 2-thiophenocarboxaldehyde; 9-decade; trans-2,cis-6-nonadienal; acalea; 4-tercbutylbenzaldehyde; trans-2-methyl-2-octenal; citral; 3-met¡l-5-phen¡ll-pentanal; 2-decade; trans-2decadal; alpha, 4-dimethyl benzenopropanal; cis-5-octenal; cis-7-decene-l-al; cis-4-decene-l-al; 2-trans6-cis-dodecadienal; 2-trans-4-trans-dodecadienal; 3-cyclohexene-l-propanal; 2- nonen-l-al; 2undecenial; 2,4-decadienal, (E,E)-; 2,4-dndecadienal, (E,E)-; isohexenyl cyclohexenyl carboxaldehyde; trans-2-nonen-l-al; 3-nonyl acrolein; 2,6-nonadiene; lilial;2-trans-6-trans-nonadienal; alpha-sinensal; bourgeonal; 2-tridecenal; p-butylphenyl acetaldehyde; (Z)-3-dodecenal; m-methylbenzaldehyde; mefloral; trans-4-decen-l-al; sylvial; 2-hexen-l-al; 2,4-nonadienal; floralozone; C-11 aldehyde; cis-3-hexenal; myristaldehyde; cinnamic aldehyde; p-tolualdehyde; undecanal; undecenal; lauralaldehyde; trans-2-hexenal; geranial; 5-methyl-2-thiophenocarboxaldehyde; phenylacetaldehyde; alpha-amylcinnamaldehyde; floral super; hexylcinnamic aldehyde; alpha-methylcinnamaldehyde; benzaldehyde; and mixtures thereof; preferably selected from: scentenal; adoxal; ocatanal; nonalaldehyde; melonal; methylnonylacetaldehyde; p-anisaldehyde; ethylvanillin; vanillin; heliotropin; lilial; C-II aldehyde; undecanal; 10-undecenal; lauralaldehyde; and mixtures thereof; and / or the perfume comprises one or more perfume ester raw materials selected from the group consisting of: quintester; serenolide; nirvanolide; acetarolle; alpinofix; aladinate; methyl laitone; firascone;1-methylbuten-l-ol, 1-acetate; (Z)-3-hepteno-l-yl acetate; 3-hydroxy-4,5-dimethyl-2(5H)-furanone; isoamyl undecylenate; verdox HC; pivarose Q; citrile acetate; (E)-5-tangerinol; (Z)-5-tangerinol; miraldyl acetate; geranyl phenylacetate; bergapten; isopimpineline; parsol MCX; ethyl beta-safranate; nopyl acetate; calixol; methyl octalactone; isopulegil acetate; ethyl tiglate; vanoris; acetoxymethylisolongifoleno (isomers); l-oxaspiro[2.5]octano-2-carboxylic acid, 5,5,7-trimethyl-, ethyl ester; 3,6-dimethyl-3-octan¡l acetate; cls-3-hexenyl-c¡s-3-hexenoate; ds-3-hexenyl lactate; clareolide; hexarose; cis-iso-ambretólide; frutinate; ethyl gamma-safranate; amyl cinamate; isoambretólide; bornyl isobutyrate; cyprisate; anapear; montaverdi; vertosine; isobornyl isobutyrate; c¡ cyprisate; cyclobutanate; cis-3-hexenyl butyrate; geranyl tiglate; trans-hedione; isoamyl acetate; givescona; cyclogalbanate; verdural B extra;alpha-ethyl safranate; jasmal; estiral acetate; nonalactone; trans-ambretolide; furfuryl heptanoate; furfuryl hexanoate; alpha-amylcinamyl acetate; carbyl acetate; ethyl isobutanoate; citronyl isobutyrate; furfuryl octanoate; octyl 2-furoate; cedar acetate; isoamyl acetoacetate; cis-3-hexenyl benzoate; phenylethyl benzoate; hexenyl tiglate; citrus; gamma-undecalactone (racemic); (S)-gama-undecalactone; (R)gamma-undecalactone; phenyl benzoate; geranyl benzoate; isobutyl salicylate; isoamyl salicylate; greenx; 2-acetoxy-3-butanone; geranyl caprylate; de (+)-D-menthyl acetate; prenyl benzoate; 7-methoxyumarin; cis-3-hexenyl 2-methyl butyrate; ds-3-hexenyl trans-2-hexenoate; ethyl valerate; n-pentyl butyrate; Ethyl 3-hydroxybutyrate; flower acetate; hexilo neopentanoate; decile propionate; phenethyl tiglate; 2-ί6ηϋ-1(2)ρΓορεηίΙ-1 éster; methyl cyclopentylideneacetate;isononyl acetate; p-cresyl crotonate; octahydrocoumarin; trans-2,cis-4-methyl decadienoate; 3,3,5-trimethylcyclohexyl acetate; hexyl vanillate; cis-3-hexenyl levulinate; dimethyl anthranilate; methyl 2-methylbutyrate; butyl salicylate; isomentyl acetate; dihydrocarveol acetate; tetrahydrolinalyl acetate; dimethyl octanyl acetate; ds-4-methyloctenoate; hexahydro-3,5,5-trimethyl-3,8-aethane-1H-1-benzopyran-2(3H)-one; cyclohexylethyl acetate; alpha-acetoxystyrene; p-methylbenzyl acetate; heptyl propionate; gamma-dodecalactone; neryl isobutyrate; geranyl isobutyrate; hexyl isobutyrate; methyl geranate; and mixtures thereof; preferably selected from methyl laitone; Verdox HC; ethyl beta-safranate; hexarose; cyclobutanate; cyclogalbanate; ethyl alpha-safranate; jasmal; styralyl acetate; nonalactone; gamma-undecalactone (racemic); Verdox; fluor acetate; and mixtures thereof.

6. The consumer product composition according to any of the preceding claims, characterized in that the core further comprises a partitioning modifier, preferably a partitioning modifier selected from the group consisting of vegetable oil, modified vegetable oil, mono, di, and triesters of C4-C24 fatty acids, isopropyl myristate, dodecanephenone, lauryl laurate, methyl behenate, methyl laurate, methyl palmitate, methyl stearate, and mixtures thereof, most preferably isopropyl myristate.

7. The consumer product composition according to any of the preceding claims, characterized in that the polymeric material of the coating is formed, at least in part, by a radical polymerization process.

8. The consumer product composition according to any preceding claim, characterized in that the (meth)acrylate material is selected from the group consisting of a polyacrylate, a polyethylene glycol acrylate, a polyurethane acrylate, an epoxy acrylate, a polymethacrylate, a polyethylene glycol methacrylate, a polyurethane methacrylate, an epoxy methacrylate, and mixtures thereof.

9. The consumer product composition according to any preceding claim, characterized in that the (meth)acrylate material is derived from a material comprising one or more multifunctional acrylate entities, preferably wherein the multifunctional acrylate entity is selected from the group consisting of trifunctional acrylate, tetrafunctional acrylate, pentafunctional acrylate, hexafunctional acrylate, heptafunctional acrylate, and mixtures thereof.

10. The consumer product composition according to any preceding claim, characterized in that the (meth)acrylate material is derived from a monomer selected from a hexafunctional acrylate, a triacrylate, or mixtures thereof, preferably a hexafunctional aromatic acrylate, an isocyanurate triacrylate, or mixtures thereof, more preferably a hexafunctional aromatic urethane acrylate, a tris(2-hydroxyethyl)isocyanurate triacrylate, or mixtures thereof.

11. The consumer product composition according to any of the preceding claims, characterized in that the encapsulants are characterized by a volume-weighted median diameter of approximately 10 to approximately 100 microns.

12. The consumer product composition according to any preceding claim, characterized in that the consumer product adjuvant comprises a material selected from the group consisting of surfactants, conditioning agents, deposition aids, rheology modifiers or structuring agents, bleaching systems, stabilizers, additives, chelating agents, dye transfer inhibitors, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil extraction / anti-redeposition agents, brighteners, foam suppressants, silicones, toning agents, aesthetic dyes, perfumes and additional perfume delivery systems, structural elasticizing agents, carriers, hydrotropes, processing aids, anti-caking agents, coatings, formaldehyde scrubbers, pigments, and mixtures thereof.

13. The consumer product composition according to any preceding claim, characterized in that the consumer product composition is in the form of a liquid composition, a granular composition, a single-compartment pouch, a multi-compartment pouch, a soluble sheet, a lozenge or globule, a fibrous article, a tablet, a bar, a flake, a dryer sheet, or a mixture thereof, preferably a liquid composition.

14. The consumer product composition according to any preceding claim, characterized in that the consumer product composition is a laundry detergent composition, a fabric conditioning composition, a laundry additive, a fabric pretreatment composition, a fabric renewing composition, a dishwashing composition, a hard surface cleaning composition, an air care composition, a car care composition, a hair treatment product, a skin care product, a shaving care product, a personal hygiene product, a deodorant product, an antiperspirant product, or mixtures thereof.

15. A method for treating a surface or article with a consumer product composition according to any preceding claim, the method comprising the step of bringing the surface or article into contact with the consumer product composition, optionally in the presence of water.