High strength steel sheet and method for manufacturing the same

Abstract

A high strength steel sheet having 1180 MPa or higher tensile strength and a method for manufacturing the same are disclosed. The high strength steel sheet has a specific chemical composition and is such that in a region at ¼ sheet thickness, the area fraction of martensite is 80% or more, the volume fraction of retained austenite is 3% or more and 15% or less, the area fraction of the total of ferrite and bainitic ferrite is 10% or less, the average grain size of prior austenite is 20 μm or less, and the average of the proportions of packets having the largest area in prior austenite grains is 70% by area or less of the prior austenite grain.

Description

CROSS REFERENCE TO RELATED APPLICATIONS

[0001] This is the U.S. National Phase application of PCT / JP2023 / 002916 filed Jan. 30, 2023, which claims priority to Japanese Patent Application No. 2022-049758 filed Mar. 25, 2022, the disclosures of these applications being incorporated herein by reference in their entireties for all purposes.FIELD OF THE INVENTION

[0002] The present invention relates to a high strength steel sheet excellent in tensile strength, bendability, flatness in the width direction, and working embrittlement resistance, and to a method for manufacturing the same. The high strength steel sheet according to aspects of the present invention may be suitably used as structural members, such as automobile parts.BACKGROUND OF THE INVENTION

[0003] Steel sheets for automobiles are being increased in strength in order to reduce CO2 emissions by weight reduction of vehicles and to enhance crashworthiness by weight reduction of automobile bodies at the same time, with introduction of new laws and regulations one after another. To increase the strength of automobile bodies, high strength steel sheets having a tensile strength (TS) of 1180 MPa or higher grade are increasingly applied to principal structural parts of automobiles.

[0004] High strength steel sheets used in automobiles requires excellent bendability. From the point of view of formability, steel sheets with high bendability are suitably used as, for example, bumpers and the like that have a portion bent by roll forming.

[0005] From the point of view of the performance of parts, high strength steel sheets used in automobiles require high working embrittlement resistance. For example, high strength steel sheets applied to automobile frame parts, such as bumpers, are suitably those that excel in working embrittlement resistance and are not embrittled upon being press-formed.

[0006] Furthermore, high strength steel sheets used in automobiles require high flatness. Patent Literature 1 describes that warpage of a steel sheet causes operational troubles in forming lines and adversely affects the dimensional accuracy of products. The present inventors carried out extensive studies and have found that the dimensional accuracy of products is affected not only by the warpage of steel sheets but also by the flatness in the width direction that is evaluated as steepness. For example, the steepness in the width direction is suitably 0.02 or less in order to achieve excellent dimensional accuracy.

[0007] To meet the above demands, for example, Patent Literature 2 provides a high strength steel sheet having a tensile strength of 1100 MPa or more and being excellent in YR, surface quality, and weldability, and a method for manufacturing the same. However, the technique described in Patent Literature 2 does not take into consideration flatness in the width direction or working embrittlement resistance.

[0008] Patent Literature 3 provides a hot-dip galvanized steel sheet with excellent press formability and low-temperature toughness that has a tensile strength of 980 MPa or more, and a method for manufacturing the same. While the steel sheet of Patent Literature 3 is improved in embrittlement at low temperatures, the technique does not take into consideration the working embrittlement of the steel sheet, bendability, or flatness in the width direction.

[0009] Patent Literature 4 provides a high strength steel sheet having a tensile strength of 1320 MPa or more and being excellent in workability and bendability, and a method for manufacturing the same. However, the technique described in Patent Literature 4 does not take into consideration flatness in the width direction or working embrittlement resistance.PATENT LITERATUREPTL 1: Japanese Patent No. 4947176

[0011] PTL 2: Japanese Patent No. 6525114

[0012] PTL 3: Japanese Patent No. 6777272

[0013] PTL 4: Japanese Patent No. 6338025Non Patent Literature

[0014] NPL 1: Journal of Smart Processing, 2013, Vol. 2, No. 3, pp. 110-118SUMMARY OF THE INVENTION

[0015] Aspects of the present invention have been developed in view of the circumstances discussed above. Objects of aspects of the present invention are therefore to provide a high strength steel sheet having 1180 MPa or higher TS and being excellent in bendability, flatness in the width direction, and working embrittlement resistance; and to provide a method for manufacturing the same.

[0016] The present inventors carried out extensive studies directed to solving the problems described above and have consequently found the following facts.(1) 1180 MPa or higher TS can be realized by limiting the area fraction of martensite to 80% or more and the area fraction of the total of ferrite and bainitic ferrite to 10% or less.(2) Excellent bendability can be realized by limiting the volume fraction of retained austenite to 3% or more.(3) Excellent flatness in the width direction can be achieved by limiting the proportion of a packet having the largest area in a prior austenite grain to 70% by area or less on average. (4) Excellent working embrittlement resistance can be realized by limiting the volume fraction of retained austenite to 15% or less, the proportion of a packet having the largest area in a prior austenite grain to 70% by area or less on average, and the average prior austenite grain size to 20 μm or less.

[0017] Aspects of the present invention have been made based on the above findings. Specifically, a summary of configurations of aspects of the present invention is as follows.[1] A high strength steel sheet having a chemical composition including, in mass %, C: 0.030% or more and 0.500% or less, Si: 0.50% or more and 2.50% or less, Mn: 1.50% or more and 5.00% or less, P: 0.100% or less, S: 0.0200% or less, Al: 1.000% or less, N: 0.0100% or less, and O: 0.0100% or less, a balance being Fe and incidental impurities, the high strength steel sheet being such that in a region at ¼ sheet thickness, an area fraction of martensite is 80% or more, a volume fraction of retained austenite is 3% or more and 15% or less, an area fraction of a total of ferrite and bainitic ferrite is 10% or less, an average grain size of prior austenite is 20 μm or less, and an average of proportions of packets having the largest area in prior austenite grains is 70% by area or less of the prior austenite grain.[2] The high strength steel sheet according to [1], wherein the chemical composition further includes at least one element selected from, in mass %, Ti: 0.200% or less, Nb: 0.200% or less, V: 0.200% or less, Ta: 0.10% or less, W: 0.10% or less, B: 0.0100% or less, Cr: 1.00% or less, Mo: 1.00% or less, Co: 0.010% or less, Ni: 1.00% or less, Cu: 1.00% or less, Sn: 0.200% or less, Sb: 0.200% or less, Ca: 0.0100% or less, Mg: 0.0100% or less, REM: 0.0100% or less, Zr: 0.100% or less, Te: 0.100% or less, Hf: 0.10% or less, and Bi: 0.200% or less.[3] The high strength steel sheet according to [1] or [2], which has a coated layer on a surface of the steel sheet.[4] A method for manufacturing the high strength steel sheet according to [1] or [2], the method including providing a cold rolled steel sheet produced by subjecting a steel having the chemical composition to hot rolling, pickling, and cold rolling; annealing the steel sheet by heating at an annealing temperature of 750° C. or above and 950° C. or below for a holding time at the annealing temperature of 10 seconds or more and 1000 seconds or less; bending and unbending the steel sheet 1 to 15 times in total with a roll having a radius of 800 mm or less during the annealing; cooling the steel sheet at an average cooling rate of 20° C. / s or more in a temperature range from 700° C. to 600° C. and at an average cooling rate of 20° C. / s or more in a temperature range from 499° C. to Ms; bending and unbending the steel sheet in the temperature range from 499° C. to Ms, 1 to 15 times in total with a roll having a radius of 800 mm or less; cooling the steel sheet at an average cooling rate of 150° C. / s or less in a temperature range from Ms to a cooling stop temperature Ta; applying a tension to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta while controlling the tension to 5 MPa or more and 100 MPa or less, the cooling stop temperature Ta being 100° C. or above and (Ms−80° C.) or below where Ms is martensite start temperature (° C.) defined by formula (1); and tempering the steel sheet at a tempering temperature of Ta or above and 450° C. or below for a holding time at the tempering temperature of 10 seconds or more and 1000 seconds or less,Ms=519-474×[%⁢ C]-30.4×[%⁢ Mn]-12.1×[%⁢ Cr]-7.5×[%⁢ Mo]-17.7×[%⁢ Ni](1)wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.[5] The method for manufacturing the high strength steel sheet according to [4], further including performing a coating treatment.According to aspects of the present invention, a high strength steel sheet can be obtained that has 1180 MPa or higher TS and excels in bendability, flatness in the width direction, and working embrittlement resistance. Furthermore, for example, the high strength steel sheet according to aspects of the present invention may be applied to automobile structural members to reduce the weight of automobile bodies and thereby to enhance fuel efficiency. Thus, aspects of the present invention are highly valuable in industry.BRIEF DESCRIPTION OF THE DRAWINGSFIG. 1 is a set of views illustrating a structure of a packet having the largest area in a prior austenite grain according to aspects of the present invention, and how the proportion of the packet is calculated.

[0020] FIG. 2 is a set of views illustrating the concept of the steepness A in the width direction of a steel sheet according to aspects of the present invention, and how the steepness is calculated.DETAILED DESCRIPTION OF EMBODIMENTS OF THE INVENTION

[0021] Embodiments of the present invention will be described below.

[0022] First, appropriate ranges of the chemical composition of the high strength steel sheet and the reasons why the chemical composition is thus limited will be described. In the following description, “%” indicating the contents of constituent elements of steel means “mass %” unless otherwise specified.[C: 0.030% or More and 0.500% or Less]

[0023] Carbon is one of the important basic components of steel. Particularly in accordance with aspects of the present invention, carbon is an important element that affects the amount of martensite and the total amount of ferrite and bainitic ferrite. When the C content is less than 0.030%, the amount of martensite is lowered and the total amount of ferrite and bainitic ferrite is increased, with the result that realizing 1180 MPa or higher TS is difficult. When, on the other hand, the C content is more than 0.500%, martensite becomes brittle to cause deterioration in working embrittlement resistance. Thus, the C content is limited to 0.030% or more and 0.500% or less. The lower limit of the C content is preferably 0.050% or more. The upper limit of the C content is preferably 0.400% or less. The lower limit of the C content is more preferably 0.100% or more. The upper limit of the C content is more preferably 0.350% or less.[Si: 0.50% or More and 2.50% or Less]

[0024] Silicon is one of the important basic components of steel and is an important element that affects TS and the amount of retained austenite. When the Si content is less than 0.50%, the strength of martensite decreases to make it difficult to achieve 1180 MPa or higher TS. When, on the other hand, the Si content is more than 2.50%, the amount of retained austenite is increased excessively to cause deterioration in working embrittlement resistance. Thus, the Si content is limited to 0.50% or more and 2.50% or less. The lower limit of the Si content is preferably 0.55% or more. The upper limit of the Si content is preferably 2.00% or less. The lower limit of the Si content is more preferably 0.60% or more. The upper limit of the Si content is more preferably 1.80% or less.[Mn: 1.50% or More and 5.00% or Less]

[0025] Manganese is one of the important basic components of steel and is an important element that affects the amount of martensite and the total amount of ferrite and bainitic ferrite. When the Mn content is less than 1.50%, the amount of martensite is lowered and the total amount of ferrite and bainitic ferrite is increased, with the result that realizing 1180 MPa or higher TS is difficult. When, on the other hand, the Mn content is more than 5.00%, martensite becomes brittle to cause deterioration in working embrittlement resistance. Thus, the Mn content is limited to 1.50% or more and 5.00% or less. The lower limit of the Mn content is preferably 2.00% or more. The upper limit of the Mn content is preferably 4.50% or less. The lower limit of the Mn content is more preferably 2.20% or more. The upper limit of the Mn content is more preferably 4.00% or less.[P: 0.100% or Less]

[0026] Phosphorus is segregated at prior austenite grain boundaries and makes the grain boundaries brittle, thereby lowering the ultimate deformability of steel sheets and causing deterioration in working embrittlement resistance. Thus, the P content needs to be 0.100% or less. The lower limit of the P content is not particularly specified. In view of the fact that phosphorus is a solid solution strengthening element and can increase the strength of steel sheets, the lower limit is preferably 0.001% or more. For the reasons above, the P content is limited to 0.100% or less. The lower limit of the P content is preferably 0.001% or more. The upper limit of the P content is preferably 0.070% or less.[S: 0.0200% or Less]

[0027] Sulfur forms sulfides and lowers the ultimate deformability of steel sheets to cause deterioration in working embrittlement resistance. Thus, the S content needs to be 0.0200% or less. The lower limit of the S content is not particularly specified but is preferably 0.0001% or more due to production technique limitations. For the reasons above, the S content is limited to 0.0200% or less. The lower limit of the S content is preferably 0.0001% or more. The upper limit of the S content is preferably 0.0050% or less.[Al: 1.000% or Less]

[0028] Aluminum forms the oxide and lowers the ultimate deformability of steel sheets to cause deterioration in working embrittlement resistance. Thus, the Al content needs to be 1.000% or less. The lower limit of the Al content is not particularly specified. In view of the fact that aluminum suppresses the occurrence of carbides during continuous annealing and promotes the formation of retained austenite, the Al content is preferably 0.001% or more. For the reasons above, the Al content is limited to 1.000% or less. The lower limit of the Al content is preferably 0.001% or more. The upper limit of the Al content is preferably 0.500% or less.[N: 0.0100% or Less]

[0029] Nitrogen forms nitrides and lowers the ultimate deformability of steel sheets to cause deterioration in working embrittlement resistance. Thus, the N content needs to be 0.0100% or less. The lower limit of the N content is not particularly specified, but the N content is preferably 0.0001% or more due to production technique limitations. For the reasons above, the N content is limited to 0.0100% or less. The lower limit of the N content is preferably 0.0001% or more. The upper limit of the N content is preferably 0.0050% or less.[O: 0.0100% or Less]

[0030] Oxygen forms oxides and lowers the ultimate deformability of steel sheets to cause deterioration in working embrittlement resistance. Thus, the O content needs to be 0.0100% or less. The lower limit of the O content is not particularly specified but the O content is preferably 0.0001% or more due to production technique limitations. For the reasons above, the O content is limited to 0.0100% or less. The lower limit of the O content is preferably 0.0001% or more. The upper limit of the O content is preferably 0.0050% or less.

[0031] The chemical composition of the high strength steel sheet according to an embodiment of the present invention includes the components described above, and the balance is Fe and incidental impurities. Here, the incidental impurities include Zn, Pb, As, Ge, Sr, and Cs. A total of 0.100% or less of these impurities is acceptable.

[0032] In addition to the components in the proportions described above, the high strength steel sheet according to aspects of the present invention may further include at least one element selected from, in mass %, Ti: 0.200% or less, Nb: 0.200% or less, V: 0.200% or less, Ta: 0.10% or less, W: 0.10% or less, B: 0.0100% or less, Cr: 1.00% or less, Mo: 1.00% or less, Ni: 1.00% or less, Co: 0.010% or less, Cu: 1.00% or less, Sn: 0.200% or less, Sb: 0.200% or less, Ca: 0.0100% or less, Mg: 0.0100% or less, REM: 0.0100% or less, Zr: 0.100% or less, Te: 0.100% or less, Hf: 0.10% or less, and Bi: 0.200% or less. These elements may be contained singly or in combination.

[0033] When the contents of Ti, Nb, and V are each 0.200% or less, coarse precipitates and inclusions will not occur in large amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the contents of Ti, Nb, and V are each preferably 0.200% or less. The lower limits of the contents of Ti, Nb, and V are not particularly specified. These elements form fine carbides, nitrides, or carbonitrides during hot rolling or continuous annealing to increase the strength of steel sheets. In view of this fact, the contents of Ti, Nb, and V are each more preferably 0.001% or more. When titanium, niobium, and vanadium are added, the contents thereof are each limited to 0.200% or less for the reasons above. The lower limits of the contents of Ti, Nb, and V, when added, are each more preferably 0.001% or more. The upper limits of the contents of Ti, Nb, and V, when added, are each more preferably 0.100% or less.

[0034] When the contents of Ta and W are each 0.10% or less, coarse precipitates and inclusions will not occur in large amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the contents of Ta and W are each preferably 0.10% or less. The lower limits of the contents of Ta and W are not particularly specified. These elements form fine carbides, nitrides, or carbonitrides during hot rolling or continuous annealing to increase the strength of steel sheets. In view of this fact, the contents of Ta and W are each more preferably 0.01% or more. When tantalum and tungsten are added, the contents thereof are each limited to 0.10% or less for the reasons above. The lower limits of the contents of Ta and W, when added, are each more preferably 0.01% or more. The upper limits of the contents of Ta and W, when added, are each more preferably 0.08% or less.

[0035] When the B content is 0.0100% or less, inner cracks that lower the ultimate deformability of steel sheets will not form during casting or hot rolling and thus there will be no deterioration in working embrittlement resistance. Thus, the B content is preferably 0.0100% or less. The lower limit of the B content is not particularly specified. The B content is more preferably 0.0003% or more in view of the fact that this element is segregated at austenite grain boundaries during annealing and enhances hardenability. When boron is added, the content thereof is limited to 0.0100% or less for the reasons above. The lower limit of the content of B, when added, is more preferably 0.0003% or more. The upper limit of the content of B, when added, is more preferably 0.0080% or less.

[0036] When the contents of Cr, Mo, and Ni are each 1.00% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the contents of Cr, Mo, and Ni are each preferably 1.00% or less. The lower limits of the contents of Cr, Mo, and Ni are not particularly specified. In view of the fact that these elements enhance hardenability, the contents of Cr, Mo, and Ni are each more preferably 0.01% or more. When chromium, molybdenum, and nickel are added, the contents thereof are each limited to 1.00% or less for the reasons above. The lower limits of the contents of Cr, Mo, and Ni, when added, are each more preferably 0.01% or more. The upper limits of the contents of Cr, Mo, and Ni, when added, are each more preferably 0.80% or less.

[0037] When the Co content is 0.010% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the Co content is preferably 0.010% or less. The lower limit of the Co content is not particularly specified. In view of the fact that this element enhances hardenability, the Co content is more preferably 0.001% or more. When cobalt is added, the content thereof is limited to 0.010% or less for the reasons above. The lower limit of the content of Co, when added, is more preferably 0.001% or more. The upper limit of the content of Co, when added, is more preferably 0.008% or less.

[0038] When the Cu content is 1.00% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the Cu content is preferably 1.00% or less. The lower limit of the Cu content is not particularly specified. In view of the fact that this element enhances hardenability, the Cu content is preferably 0.01% or more. When copper is added, the content thereof is limited to 1.00% or less for the reasons above. The lower limit of the content of Cu, when added, is more preferably 0.01% or more. The upper limit of the content of Cu, when added, is more preferably 0.80% or less.

[0039] When the Sn content is 0.200% or less, inner cracks that lower the ultimate deformability of steel sheets will not form during casting or hot rolling and thus there will be no deterioration in working embrittlement resistance. Thus, the Sn content is preferably 0.200% or less. The lower limit of the Sn content is not particularly specified. The Sn content is more preferably 0.001% or more in view of the fact that tin enhances hardenability (in general, is an element that enhances corrosion resistance). When tin is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Sn, when added, is more preferably 0.001% or more. The upper limit of the content of Sn, when added, is more preferably 0.100% or less.

[0040] When the Sb content is 0.200% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the Sb content is preferably 0.200% or less. The lower limit of the Sb content is not particularly specified. In view of the fact that this element enables control of the thickness of surface layer softening and the strength, the Sb content is more preferably 0.001% or more. When antimony is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Sb, when added, is more preferably 0.001% or more. The upper limit of the content of Sb, when added, is more preferably 0.100% or less.

[0041] When the contents of Ca, Mg, and REM are each 0.0100% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the contents of Ca, Mg, and REM are each preferably 0.0100% or less. The lower limits of the contents of Ca, Mg, and REM are not particularly specified. In view of the fact that these elements change the shapes of nitrides and sulfides into spheroidal and enhance the ultimate deformability of steel sheets, the contents of Ca, Mg, and REM are each more preferably 0.0005% or more. When calcium, magnesium, and rare earth metal(s) are added, the contents thereof are each limited to 0.0100% or less for the reasons above. The lower limits of the contents of Ca, Mg, and REM, when added, are each more preferably 0.0005% or more. The upper limits of the contents of Ca, Mg, and REM, when added, are each more preferably 0.0050% or less.

[0042] When the contents of Zr and Te are each 0.100% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the contents of Zr and Te are each preferably 0.100% or less. The lower limits of the contents of Zr and Te are not particularly specified. In view of the fact that these elements change the shapes of nitrides and sulfides into spheroidal and enhance the ultimate deformability of steel sheets, the contents of Zr and Te are each more preferably 0.001% or more. When zirconium and tellurium are added, the contents thereof are each limited to 0.100% or less for the reasons above. The lower limits of the contents of Zr and Te, when added, are each more preferably 0.001% or more. The upper limits of the contents of Zr and Te, when added, are each more preferably 0.080% or less.

[0043] When the Hf content is 0.10% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the Hf content is preferably 0.10% or less. The lower limit of the Hf content is not particularly specified. In view of the fact that this element changes the shapes of nitrides and sulfides into spheroidal and enhances the ultimate deformability of steel sheets, the Hf content is more preferably 0.01% or more. When hafnium is added, the content thereof is limited to 0.10% or less for the reasons above. The lower limit of the content of Hf, when added, is more preferably 0.01% or more. The upper limit of the content of Hf, when added, is more preferably 0.08% or less.

[0044] When the Bi content is 0.200% or less, coarse precipitates and inclusions will not occur in increased amounts and thus will not cause lowering of the ultimate deformability of steel sheets; hence there will be no deterioration in working embrittlement resistance. Thus, the Bi content is preferably 0.200% or less. The lower limit of the Bi content is not particularly specified. In view of the fact that this element reduces the occurrence of segregation, the Bi content is more preferably 0.001% or more. When bismuth is added, the content thereof is limited to 0.200% or less for the reasons above. The lower limit of the content of Bi, when added, is more preferably 0.001% or more. The upper limit of the content of Bi, when added, is more preferably 0.100% or less.

[0045] When the content of any of Ti, Nb, V, Ta, W, B, Cr, Mo, Ni, Co, Cu, Sn, Sb, Ca, Mg, REM, Zr, Te, Hf, and Bi is below the preferred lower limit, the element does not impair the advantageous effects according to aspects of the present invention and is regarded as an incidental impurity.

[0046] Next, the steel microstructure of the high strength steel sheet according to aspects of the present invention will be described.[Area Fraction of Martensite: 80% or More]

[0047] This configuration is a very important requirement that constitutes an aspect of the present invention. 1180 MPa or higher TS can be achieved when the area fraction of martensite is 80% or more. Thus, the area fraction of martensite is limited to 80% or more. The area fraction is preferably 82% or more, and more preferably 84% or more.[Volume Fraction of Retained Austenite: 3% or More and 15% or Less]

[0048] This configuration is a very important requirement that constitutes an aspect of the present invention. When the volume fraction of retained austenite is less than 3%, it is difficult to realize excellent bendability because the anti-cracking effect of retained austenite cannot be obtained at the time of bending. When the amount of retained austenite is more than 15%, retained austenite is excessively transformed into hard martensite at the time of working and the steel sheet is lowered in ultimate deformability and will not attain excellent working embrittlement resistance. Thus, the amount of retained austenite is limited to 3% or more and 15% or less. The lower limit of the amount of retained austenite is preferably 5% or more. The upper limit of the amount of retained austenite is preferably 14% or less. The lower limit of the amount of retained austenite is more preferably 7% or more. The upper limit of the amount of retained austenite is more preferably 13% or less.

[0049] Here, retained austenite is measured as follows. The steel sheet is polished to expose a face 0.1 mm below ¼ sheet thickness and is thereafter further chemically polished to expose a face 0.1 mm below the face exposed above. The face is analyzed with an X-ray diffractometer using CoKα radiation to determine the integral intensity ratios of the diffraction peaks of {200}, {220}, and {311}planes of fcc iron and {200}, {211}, and {220}planes of bcc iron. Nine integral intensity ratios thus obtained are averaged to determine retained austenite.[Area Fraction of the Total of Ferrite and Bainitic Ferrite: 10% or Less]

[0050] This configuration is a very important requirement that constitutes an aspect of the present invention. When the total amount of ferrite and bainitic ferrite is more than 10%, it is difficult to achieve 1180 MPa or higher TS. Thus, the total amount of ferrite and bainitic ferrite is limited to 10% or less. The total amount is preferably 8% or less, and more preferably 5% or less. The lower limit of the total amount of ferrite and bainitic ferrite is not particularly limited. The total amount may be 0%.

[0051] Here, the total amount of ferrite and bainitic ferrite is measured as follows. A longitudinal cross section of the steel sheet is polished and is etched with 3 vol % Nital. A portion at ¼ sheet thickness (a location corresponding to ¼ of the sheet thickness in the depth direction from the steel sheet surface) is observed using SEM in 10 fields of view at a magnification of ×2000. In the microstructure images, ferrite and bainitic ferrite are recessed structures having a flat interior and containing no inner carbides. The values thus obtained are averaged to determine the total amount of ferrite and bainitic ferrite.

[0052] The amount of martensite is measured as follows. The amount of martensite can be determined by measuring the amounts of retained austenite, ferrite, and bainitic ferrite based on the methods described above, and subtracting the total thereof from 100%. Thus, the amount of martensite in accordance with aspects of the present invention includes both quenched martensite and tempered martensite. Because the volume fraction of retained austenite is almost equal to the area fraction, the amount is subtracted as such from 100% together with the amounts of ferrite and bainitic ferrite expressed in area fraction.[Average Grain Size of Prior Austenite: 20 μm or Less]

[0053] This configuration is a very important requirement that constitutes an aspect of the present invention. Reducing the average grain size of prior austenite can suppress crack propagation and thereby enhances the working embrittlement resistance of steel sheets. In order to obtain these effects, the average grain size of prior austenite needs to be 20 μm or less. The lower limit of the average grain size of prior austenite is not particularly specified but is preferably 2 μm or more due to production technique limitations. For the reasons above, the average grain size of prior austenite is limited to 20 μm or less. The average grain size is preferably 2 μm or more. The average grain size is preferably 15 μm or less. The average grain size is more preferably 3 μm or more. The average grain size is more preferably 10 μm or less.

[0054] Here, the average grain size of prior austenite is measured as follows. A longitudinal cross section of the steel sheet is polished and is etched with, for example, a mixed solution of picric acid and ferric chloride to expose prior austenite grain boundaries. Portions at ¼ sheet thickness (locations corresponding to ¼ of the sheet thickness in the depth direction from the steel sheet surface) are photographed with an optical microscope each in 3 to 10 fields of view at a magnification of ×400. Twenty straight lines including 10 vertical lines and 10 horizontal lines are drawn at regular intervals on the image data obtained, and the grain size is determined by a linear intercept method.[Average of the Proportions of Packets Having the Largest Area in Prior Austenite Grains: 70% by Area or Less]

[0055] This configuration is a very important requirement that constitutes an aspect of the present invention. The proportion of a packet having the largest area in a prior austenite grain affects the flatness in the width direction and the working embrittlement resistance. As illustrated in FIG. 1, a prior austenite grain contains up to four kinds of packets distinguished by crystal habit plane formed by transformation. The packet having the largest area in a prior austenite grain is the packet that occupies the largest area among such packets.

[0056] The proportion of one packet in a prior austenite grain is determined by dividing the area of the packet of interest by the area of the whole prior austenite grain.

[0057] As a result of extensive studies, the present inventors have found that strain among the packets is reduced and the flatness in the width direction is improved by lowering the proportion of a packet having the largest area in a prior austenite grain. The present inventors have also found that lowering the proportion of a packet having the largest area in a prior austenite grain leads to a fine microstructure and suppresses crack propagation, thereby enhancing the working embrittlement resistance of the steel sheet. Thus, the average of the proportions of packets having the largest area in prior austenite grains is limited to 70% or less. The average proportion is preferably 60% or less. The lower limit of the average proportion of packets having the largest area in prior austenite grains is not particularly limited. The grains contain up to four kinds of packets. When four packets are evenly distributed, the proportion of a packet having the largest area in the prior austenite grain is 25%. Thus, the lower limit of the average proportion of packets having the largest area in prior austenite grains is preferably 25% or more. However, the lower limit of the average proportion is not necessarily limited thereto.

[0058] Here, the average proportion of packets having the largest area in prior austenite grains is measured as follows. First, a test specimen for microstructure observation is sampled from the cold rolled steel sheet. Next, the sampled test specimen is polished by vibration polishing with colloidal silica to expose a cross section in the rolling direction (a longitudinal cross section) for use as observation surface. The observation surface is specular. Next, electron backscatter diffraction (EBSD) measurement is performed with respect to a portion at ¼ sheet thickness (a location corresponding to ¼ of the sheet thickness in the depth direction from the steel sheet surface) to obtain local crystal orientation data. Here, the SEM magnification is ×1000, the step size is 0.2 μm, the measured region is 80 μm square, and the WD is 15 mm. The local orientation data obtained is analyzed with OIM Analysis 7 (OIM), and a map (a CP map) that shows close-packed plane groups (CP groups) with different colors is created using the method described in Non Patent Literature 1. In accordance with aspects of the present invention, a packet is defined as a region or regions belonging to the same CP group. From the CP map obtained, the area of the packet having the largest area is determined and is divided by the area of the whole prior austenite grain to give the proportion of the packet having the largest area in the prior austenite grain. This analysis is performed with respect to 10 or more adjacent prior austenite grains, and the results are averaged to give the average proportion of packets having the largest area in prior austenite grains.

[0059] Next, a manufacturing method according to aspects of the present invention will be described.

[0060] In accordance with aspects of the present invention, a steel material (a steel slab) may be obtained by any known steelmaking method without limitation, such as a converter or an electric arc furnace. To prevent macro-segregation, the steel slab (the slab) is preferably produced by a continuous casting method.

[0061] In accordance with aspects of the present invention, the slab heating temperature, the slab soaking holding time, and the coiling temperature in hot rolling are not particularly limited. For example, the steel slab may be hot rolled in such a manner that the slab is heated and is then rolled, that the slab is subjected to hot direct rolling after continuous casting without being heated, or that the slab is subjected to a short heat treatment after continuous casting and is then rolled. The slab heating temperature, the slab soaking holding time, the finish rolling temperature, and the coiling temperature in hot rolling are not particularly limited. The lower limit of the slab heating temperature is preferably 1100° C. or above. The upper limit of the slab heating temperature is preferably 1300° C. or below. The lower limit of the slab soaking holding time is preferably 30 minutes or more. The upper limit of the slab soaking holding time is preferably 250 minutes or less. The lower limit of the finish rolling temperature is preferably Ar3 transformation temperature or above. Furthermore, the lower limit of the coiling temperature is preferably 350° C. or above. The upper limit of the coiling temperature is preferably 650° C. or below.

[0062] The hot rolled steel sheet thus produced is pickled. Pickling can remove oxides on the steel sheet surface and is thus important to ensure good chemical convertibility and a high quality of coating in the final high strength steel sheet. Pickling may be performed at a time or several. The hot rolled sheet that has been pickled may be cold rolled directly or may be subjected to heat treatment before cold rolling.

[0063] The rolling reduction in cold rolling and the sheet thickness after rolling are not particularly limited. The lower limit of the rolling reduction is preferably 30% or more. The upper limit of the rolling reduction is preferably 80% or less. The advantageous effects according to aspects of the present invention may be obtained without any limitations on the number of rolling passes and the rolling reduction in each pass.

[0064] The cold rolled steel sheet obtained as described above is annealed. Annealing conditions are as follows.[Annealing Temperature: 750° C. or Above and 950° C. or Below]

[0065] When the annealing temperature is below 750° C., the amount of martensite is lowered and the total amount of ferrite and bainitic ferrite is increased, with the result that realizing 1180 MPa or higher TS is difficult. When, on the other hand, the annealing temperature is above 950° C., prior austenite grains are excessively increased in size and the prior austenite grain size exceeds 20 μm to give rise to a decrease in working embrittlement resistance. Thus, the annealing temperature is limited to 750° C. or above and 950° C. or below. The lower limit of the annealing temperature is preferably 800° C. or above. The upper limit of the annealing temperature is preferably 900° C. or below.[Holding Time During Annealing at the Annealing Temperature: 10 Seconds or More and 1000 Seconds or Less]

[0066] When the holding time at the annealing temperature is less than 10 seconds, the amount of martensite is lowered and the total amount of ferrite and bainitic ferrite is increased, with the result that realizing 1180 MPa or higher TS is difficult. When, on the other hand, the holding time at the annealing temperature is more than 1000 seconds, prior austenite grains are excessively increased in size to cause a decrease in working embrittlement resistance. Thus, the holding time at the annealing temperature is limited to 10 seconds or more and 1000 seconds or less. The lower limit of the holding time at the annealing temperature is preferably 50 seconds or more. The upper limit of the holding time at the annealing temperature is preferably 500 seconds or less.[During the Annealing, the Steel Sheet is Bent and Unbent 1 to 15 Times in Total with a Roll Having a Radius of 800 mm or Less.]

[0067] As a result of extensive studies, the present inventors have found that bending and unbending of the steel sheet during annealing affects the proportion of a packet having the largest area in a prior austenite grain. When the steel sheet being annealed is not subjected to bending and unbending with a roll having a radius of 800 mm or less, the amount of nucleation sites for martensite transformation is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, the steel sheet being annealed is subjected to bending and unbending 16 times or more with a roll having a radius of 800 mm or less, the steel sheet is deteriorated in ultimate deformability and also in working embrittlement resistance. Thus, in the annealing, the total count of bending and unbending with a roll having a radius of 800 mm or less is limited to 1 or more and 15 or less. The radius of the roll is preferably 600 mm or less. The lower limit of the total count of bending and unbending is preferably 3 or more. The upper limit of the total count of bending and unbending is preferably 10 or less. The lower limit of the radius of the roll is not necessarily limited but is preferably 50 mm or more.

[0068] Incidentally, “bending and unbending” is a treatment that bends the steel sheet with a roll in one direction according to a known technique and unbends the steel sheet in the opposite direction to cancel the bend. Bending and unbending are not counted in pairs. That is, each bending is counted one and each unbending is counted one.[Average Cooling Rate in the Temperature Range from 700° C. to 600° C.: 20° C. / s or More]

[0069] As a result of extensive studies, the present inventors have found that the average cooling rate in the temperature range from 700° C. to 600° C. affects the proportion of a packet having the largest area in a prior austenite grain. When the average cooling rate in the temperature range from 700° C. to 600° C. is less than 20° C. / s, the effects imparted by bending and unbending of the steel sheet during annealing are lowered and the amount of nucleation sites for martensite transformation is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. Thus, the average cooling rate from 700° C. to 600° C. is limited to 20° C. / s or more and is preferably 30° C. / s or more. The upper limit is not necessarily limited but is preferably 100° C. / s or less.[Average Cooling Rate in the Temperature Range from 499° C. to Ms: 20° C. / s or More]

[0070] The average cooling rate in the temperature range from 499° C. to Ms affects the total area fraction of ferrite and bainitic ferrite. When the average cooling rate in the temperature range from 499° C. to Ms is less than 20° C. / s, the total amount of ferrite and bainitic ferrite is increased to make it difficult to realize 1180 MPa or higher TS. Thus, the average cooling rate in the temperature range from 499° C. to Ms is limited to 20° C. / s or more. The average cooling rate is preferably 25° C. / s or more. The upper limit is not necessarily limited but is preferably 100° C. / s or less.

[0071] The martensite start temperature Ms (° C.) is defined by the following formula (1):Ms=519-474×[%⁢ C]-30.4×[%⁢ Mn]-12.1×[%⁢ Cr]-7.5×[%⁢ Mo]-17.7×[%⁢ Ni](1)wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.[The Steel Sheet in the Temperature Range from 499° C. to Ms is Bent and Unbent 1 to 15 Times in Total with a Roll Having a Radius of 800 mm or Less.]As a result of extensive studies, the present inventors have found that bending and unbending of the steel sheet in the temperature range from 499° C. to Ms affects the proportion of a packet having the largest area in a prior austenite grain. When the steel sheet in the temperature ranges from 499° C. to Ms is not subjected to bending and unbending with a roll having a radius of 800 mm or less, the amount of martensite nucleation sites is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, the steel sheet in the temperature ranges from 499° C. to Ms is subjected to bending and unbending 16 times or more with a roll having a radius of 800 mm or less, the steel sheet is deteriorated in ultimate deformability and also in working embrittlement resistance. Thus, the total count of bending and unbending in the temperature range from 499° C. to Ms with a roll having a radius of 800 mm or less is limited to 1 or more and 15 or less. The radius of the roll is preferably 600 mm or less. The lower limit of the total count of bending and unbending is preferably 3 or more. The upper limit of the total count of bending and unbending is preferably 10 or less. The lower limit of the radius of the roll is not necessarily limited but is preferably 50 mm or more.[Average Cooling Rate in the Temperature Range from Ms to Cooling Stop Temperature Ta: 150° C. / s or Less]As a result of extensive studies, the present inventors have found that the average cooling rate in the temperature range from Ms to the cooling stop temperature Ta affects the proportion of a packet having the largest area in a prior austenite grain. When the average cooling rate in the temperature range from Ms to the cooling stop temperature Ta is more than 150° C. / s, the martensite transformation rate is so fast that a packet grows fast easily. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. Thus, the average cooling rate in the temperature range from Ms to the cooling stop temperature Ta is limited to 150° C. / s or less. The average cooling rate is preferably 120° C. / s or less. The lower limit is not necessarily limited but is preferably 5° C. / s or more.[Tension Applied to the Steel Sheet in the Temperature Range from Ms to the Cooling Stop Temperature Ta: 5 MPa or More and 100 MPa or Less]As a result of extensive studies, the present inventors have found that the application of tension to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta affects the proportion of a packet having the largest area in a prior austenite grain. When the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta is less than 5 MPa, the amount of martensite nucleation sites is reduced. Consequently, the average proportion of packets having the largest area in prior austenite grains exceeds 70%, and the flatness in the width direction and also the working embrittlement resistance are deteriorated. When, on the other hand, more than 100 MPa tension is applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta, the ultimate deformability of the steel sheet is lowered and the working embrittlement resistance is deteriorated. Thus, the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta is limited to 5 MPa or more and 100 MPa or less. The lower limit of the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta is preferably 6 MPa or more. The upper limit of the tension applied to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta is preferably 50 MPa or less. The tension is applied in a usual manner. As an example, the tension may be applied by controlling the roll speeds of the rolls in the furnace.

[0075] While the bending and unbending process increases the number of nucleation sites that are martensite start sites, the tension application process produces different effects by promoting martensite transformation itself.[Cooling Stop Temperature Ta: 100° C. or Above and (Ms−80° C.) or Below]

[0076] When the cooling stop temperature Ta is below 100° C., the amount of retained austenite decreases and bendability is lowered. When, on the other hand, the cooling stop temperature Ta is above (Ms−80° C.), the amount of retained austenite is excessively increased and the prior austenite grain size is excessively enlarged to cause deterioration in working embrittlement resistance. Thus, the cooling stop temperature Ta is limited to 100° C. or above and (Ms−80° C.) or below. The lower limit of the cooling stop temperature Ta is preferably 120° C. or above. The upper limit of the cooling stop temperature Ta is preferably (Ms−100° C.) or below.[Tempering Temperature: Ta or Above and 450° C. or Below]

[0077] After the cooling is stopped at the cooling stop temperature Ta, the steel sheet is held at the temperature or is reheated and held at a temperature of 450° C. or below to stabilize retained austenite. When the tempering temperature is below Ta, retained austenite cannot be obtained as desired and consequently bendability is lowered. When the tempering temperature is above 450° C., martensite is excessively tempered to make it difficult to achieve 1180 MPa or higher TS. Thus, the tempering temperature is limited to Ta or above and 450° C. or below. The lower limit of the tempering temperature is preferably (Ta+10° C.) or above. The upper limit of the tempering temperature is preferably 420° C. or below.[Holding Time at the Tempering Temperature: 10 Seconds or More and 1000 Seconds or Less]

[0078] When the holding time at the tempering temperature is less than 10 seconds, austenite stabilization is insufficient and retained austenite cannot be obtained as desired. Consequently, bendability is lowered. When the holding time at the tempering temperature is more than 1000 seconds, martensite is excessively tempered to make it difficult to achieve 1180 MPa or higher TS. Thus, the holding time at the tempering temperature is limited to 10 seconds or more and 1000 seconds or less. The lower limit of the holding time at the tempering temperature is preferably 50 seconds or more. The upper limit of the holding time at the tempering temperature is preferably 800 seconds or less.

[0079] Post-temper cooling is not particularly limited and the steel sheet may be cooled to a desired temperature in an appropriate manner. Incidentally, the desired temperature is preferably about room temperature.

[0080] Furthermore, the high strength steel sheet described above may be worked under conditions where the amount of equivalent plastic strain is 0.10% or more and 5.00% or less. The working may be followed by reheating at 100° C. or above and 400° C. or below.

[0081] When the high strength steel sheet is a product that is traded, the steel sheet is usually traded after being cooled to room temperature.

[0082] The high strength steel sheet may be subjected to coating treatment during annealing or after annealing.

[0083] For example, the coating treatment during annealing may be hot-dip galvanizing treatment performed when the annealed steel sheet is being cooled or has been cooled from 700° C. to 600° C. at an average cooling rate of 20° C. / s or more. The hot-dip galvanizing treatment may be followed by alloying. For example, the coating treatment after annealing may be Zn-Ni electrical alloy coating treatment or pure Zn electroplated coating treatment performed after tempering. A coated layer may be formed by electroplated coating, or hot-dip zinc-aluminum-magnesium alloy coating may be applied. While the coating treatment has been described above focusing on zinc coating, the types of coating metals, such as Zn coating and Al coating, are not particularly limited. Other conditions in the manufacturing method are not particularly limited. From the point of view of productivity, the series of treatments including annealing, hot-dip galvanizing, and alloying treatment of the coated zinc layer is preferably performed on hot-dip galvanizing line CGL (continuous galvanizing line). To control the coating weight of the coated layer, the hot-dip galvanizing treatment may be followed by wiping. Conditions for operations, such as coating, other than those conditions described above may be determined in accordance with the usual hot-dip galvanizing technique.

[0084] After the coating treatment after annealing, the steel sheet may be worked again under conditions where the amount of equivalent plastic strain is 0.10% or more and 5.00% or less. The working may be followed by reheating at 100° C. or above and 400° C. or below.Examples

[0085] Steels having a chemical composition described in Table 1 and 2, with the balance being Fe and incidental impurities, were smelted in a converter and were continuously cast into slabs. Next, the slabs obtained were heated, hot rolled, pickled, cold rolled, and subjected to annealing treatment described in Table 3 and 4. High strength cold rolled steel sheets having a sheet thickness of 0.6 to 2.2 mm were thus obtained. During annealing, the steel sheet was subjected to bending and unbending with a roll having a radius of 300 mm. In the temperature range from 499° C. to Ms, the steel sheet was subjected to bending and unbending with a roll having a radius of 300 mm. Incidentally, some of the steel sheets were subjected to coating treatment during or after annealing.

[0086] The high strength cold rolled steel sheets obtained as described above were used as test steels. Tensile characteristics, bendability, flatness in the width direction, and working embrittlement resistance were evaluated in accordance with the following test methods.TABLE 1Chemical composition (mass %)SteelsCSiMnPSNOAlTiBNbCuOthersA0.2421.022.690.0060.00120.0020.0060.034INV. EX.B0.2461.312.670.0050.00050.0030.0020.030INV. EX.C0.2481.352.660.0080.00130.0070.0020.055INV. EX.D0.2491.402.840.0060.00090.0060.0060.015INV. EX.E0.2361.002.860.0120.00090.0020.0040.036INV. EX.F0.0341.1912.480.0150.00120.0050.0040.031INV. EX.G0.0251.192.610.0120.00090.0040.0020.036COMP. EX.H0.4661.232.500.0130.00120.0060.0060.034INV. EX.I0.5041.342.430.0070.00140.0010.0030.028COMP. EX.J0.2680.742.810.0060.00080.0030.0020.028INV. EX.K0.2260.412.590.0120.00140.0040.0060.031COMP. EX.L0.2352.362.840.0090.00120.0040.0020.034INV. EX.M0.2402.582.870.0090.00090.0010.0050.051COMP. EX.N0.2411.031.570.0120.00110.0030.0060.055INV. EX.O0.2461.341.410.0110.00140.0020.0070.018COMP. EX.P0.2291.324.750.0070.00100.0050.0010.014INV. EX.Q0.2231.325.160.0070.00080.0020.0040.031COMP. EX.R0.2241.082.750.0970.00120.0040.0070.017INV. EX.S0.2251.392.540.1090.00110.0050.0010.050COMP. EX.T0.2301.052.430.0100.01950.0020.0030.015INV. EX.U0.2391.292.420.0070.02040.0030.0060.044COMP. EX.V0.2461.182.630.0110.00110.0050.0030.924INV. EX.W0.2651.152.740.0060.00070.0070.0071.049COMP. EX.X0.2611.212.590.0090.0010 0.00900.0050.033INV. EX.Y0.2521.362.730.0100.0007 0.01100.0050.049COMP. EX.Z0.2381.092.650.0120.00130.004 0.00900.019INV. EX.AA0.2631.212.700.0090.00080.002 0.01100.058COMP. EX.AB0.2451.112.440.0070.00110.0060.0030.045INV. EX.AC0.2521.082.710.0150.00120.0070.0040.0280.003INV. EX.AD0.2381.252.710.0130.00120.0040.0040.0520.195INV. EX.AE0.2271.042.750.0090.00130.0020.0060.0410.212COMP. EX.AF0.2591.162.520.0070.00140.0050.0040.0580.0003INV. EX.AG0.2491.292.650.0110.00150.0050.0020.0540.0072INV. EX.AH0.2291.182.770.0130.00140.0010.0050.0270.0105COMP. EX.AI0.2521.322.450.0130.00050.0030.0050.0520.003INV. EX.AJ0.2511.022.870.0130.00110.0030.0020.0370.182INV. EX.AK0.2321.302.530.0130.00130.0050.0050.0200.213COMP. EX.AL0.2251.232.420.0080.00050.0050.0030.0450.02INV. EX.AM0.2421.082.780.0100.00090.0020.0040.0410.92INV. EX.Underlines indicate being outside the range of the present invention.TABLE 2Chemical composition (mass %)SteelsCSiMnPSNOAlTiBNbCuOthersAN0.2571.322.530.0100.00150.0020.0030.0321.12COMP. EX.AO0.2511.072.820.0060.00140.0050.0030.012V: 0.024INV. EX.AP0.2551.262.730.0090.00110.0020.0040.035Ta: 0.06INV. EX.AQ0.2261.222.470.0130.00140.0070.0060.044W: 0.07INV. EX.AR0.2401.282.650.0090.00080.0060.0040.044Cr: 0.17INV. EX.AS0.2481.252.700.0100.00060.0040.0060.023Mo: 0.54INV. EX.AT0.2291.092.800.0110.00090.0030.0010.043Co: 0.008INV. EX.AU0.2451.192.790.0070.00140.0050.0050.042Ni: 0.75INV. EX.AV0.2281.312.570.0110.00130.0040.0030.049Sn: 0.019INV. EX.AW0.2681.152.670.0060.00130.0030.0020.012Sb: 0.056INV. EX.AX0.2421.162.750.0140.00100.0020.0030.012Ca: 0.0024INV. EX.AY0.2401.102.770.0140.00060.0030.0050.011Mg: 0.0090INV. EX.AZ0.2341.182.900.0080.00120.0020.0020.052Zr: 0.064INV. EX.BA0.2331.382.750.0120.00070.0050.0050.032Te: 0.075INV. EX.BB0.2681.022.540.0060.00130.0040.0020.042Hf: 0.04INV. EX.BC0.2301.282.780.0110.00140.0040.0040.052REM: 0.0079INV. EX.BD0.2271.172.600.0110.00080.0040.0050.055Bi: 0.164INV. EX.BE0.2271.172.610.0140.00140.0070.0070.021Zn: 0.037INV. EX.BF0.2351.332.820.0080.00110.0010.0010.021Pb: 0.086INV. EX.BG0.2391.262.820.0120.00120.0030.0020.013As: 0.035INV. EX.BH0.2481.302.610.0100.00060.0060.0070.055Ge: 0.032INV. EX.BI0.2211.182.860.0120.00080.0020.0030.040Sr: 0.050INV. EX.BJ0.2401.142.450.0100.00080.0020.0050.026Cs: 0.012INV. EX.BK0.2621.152.570.0110.00090.0060.0050.011INV. EX.BL0.2401.342.880.0070.00060.0060.0020.055INV. EX.BM0.2201.362.740.0110.00110.0040.0030.043INV. EX.BN0.2421.392.720.0090.00070.0020.0060.016INV. EX.BO0.2241.022.660.0110.00060.0070.0040.052INV. EX.Underlines indicate being outside the range of the present invention.TABLE 3AverageAverageCount ofCount ofcoolingcoolingbending andHoldingbending andrate inrate inunbending intime atunbendingtemperaturetemperaturetemperatureAnnealingannealingduringrange ofrange ofrange oftemp.temp.annealing700-600° C.499° C.-Ms499° C.-MsMs(Ms-80)Nos.Steels(° C.)(s)(times)(° C. / s)(° C. / s)(times)(° C.)(° C.)1A861 5610 686433232432B77712510 667333212413B77713510 516933212414B74416810 783833212415B946 7710 576433212416B95219510 664933212417B863 3010 773933212418B871 310 717633212419B87583710 7654332124110B8761008 10 6760332124111B87510716958332124112B870 7306480332124113B88014815 5355332124114B877 6415 7834332124115B880 8333853332124116B86019731253332124117B870 8037270332124118B87312637636332124119B86614036422332124120B86916935516332124121B861 7237271332124122B86611135534332124123B86218037949132124124B86819836664032124125B863 623634815 32124126B8731843737215 32124127B87419137272332124128B86915035043332124129B87910335662332124130B87817637978332124131B869 8137061332124132B87915137467332124133B87913437056332124134B87810210 7970332124135B872 8810 7662332124136B87812810 5762332124137B868 9510 5930332124138B86011510 5663332124139B86618710 6753332124140B86812510 5364332124141B87613310 5064332124142B86512010 5737332124143B86514110 506410 32124144B8611343546410 32124145B8771533724710 32124146B874 823777310 32124147B8681383653410 32124148B8781013675410 32124149C866 703533310 32124150D877 853544110 31523551E87012536962332024052F86211937068342734753G869 7036438342834854H87212535951322214255I865 8237753320612656J872112359573307227AverageTensioncoolingapplied torate insteel sheet inHoldingCoolingtemperaturetemperaturetime atstop temp.range ofrange ofTemperingtemperingSheetTaMs-TaMs-Tatemp.temp.thicknessNos.(° C.)(° C. / s)(MPa)(° C.)(s)(mm)Type*120815173392471.4CRINV. EX.219014122972991.4CRINV. EX.318717162942081.4CRINV. EX.417718122782141.4CRCOMP. EX.518913132611901.4CRINV. EX.618213123292451.4CRCOMP. EX.718718113221911.4CRINV. EX.818513 83491161.4CRCOMP. EX.918415112801011.4CRINV. EX.1019613143252381.4CRCOMP. EX.1118418102612061.4CRINV. EX.1220013183032701.4CRCOMP. EX.1318914163322671.4CRINV. EX.1418513142922421.4CRINV. EX.1518619182591171.4CRINV. EX.1617410173452941.4CRCOMP. EX.1717117163092691.4CRINV. EX.1819416173472371.4CRINV. EX.1919314183202981.4CRINV. EX.2018211153352121.4CRCOMP. EX.2117595133052111.4CRINV. EX.2217919151792711.4CRINV. EX.2320317143081361.4CRINV. EX.2417715183022491.4CRCOMP. EX.2519311133141771.4CRINV. EX.2617312162801091.4CRINV. EX.2710520153491341.4CRINV. EX.28 9719123412121.4CRCOMP. EX.2924015173432211.4CRINV. EX.3024415133322841.4CRCOMP. EX.3119917122731371.4CRINV. EX.3218619173361531.4CRINV. EX.33175135 112842531.4CRINV. EX.34191154 143372211.4CRCOMP. EX.3520917 63361661.4CRINV. EX.3617420 22761641.4CRCOMP. EX.3719714903472511.4CRINV. EX.3820016923251761.4CRINV. EX.3920518112052651.4CRINV. EX.4017519151751401.4CRINV. EX.4120013134352371.4CRINV. EX.4218519 84441731.4CRINV. EX.431871815312 271.4CRINV. EX.441921315269 61.4CRCOMP. EX.4519411142759361.4CRINV. EX.4621116103309951.4CRINV. EX.4718211102952541.4CRINV. EX.48196107 123381651.6CRINV. EX.4920697162801382.0CRINV. EX.5019612162642381.4CRINV. EX.5118213103102701.4CRINV. EX.5228811 93452361.4CRINV. EX.5329617 93251351.4CRCOMP. EX.5411012122571771.4CRINV. EX.5510513152832101.4CRCOMP. EX.5616417132651271.4CRINV. EX.Underlines indicate being outside the range of the present invention.*CR: cold rolled steel sheet (no coating), GI: hot-dip galvanized steel sheet (no alloying of zinc coating), GA: galvannealed steel sheet, EG: electrogalvanized steel sheetTABLE 4AverageAverageCount ofCount ofcoolingcoolingbending andHoldingbending andrate inrate inunbending intime atunbendingtemperaturetemperaturetemperatureAnnealingannealingduringrange ofrange ofrange oftemp.tempannealing700-600° C.499° C.-Ms499° C.-MsMs(Ms-80)Nos.Steels(° C.)(s)(times)(° C. / s)(° C. / s)(times)(° C.)(° C.)57K8686436637333325358L87616235373332124159M86779106765331823860N880118106632335727761O87187106472336028062P86899105643326618663Q86761105276325617664R87356106761332924965S87111435040333525566T8716035449333625667U87619536959333225268V8767237746332224269W87219537958331023070X86389371651031723771Y86870354611031723772Z877157366431032624673AA861186354731031223274AB862154374481032924975AC872154351581031723776AD865109359521032424477AE87292377711032824878AF87014736768332024079AG87211336953332024080AH871175106036332624681AI861183107264332524582AJ86178105470331323383AK86751105478333225284AL879195106531333925985AM877182107170332024086AN870192107147332024087AO799181105534331423488AP917153107874331523589AQ87019105140333725790AR879870105778332324391AS86018715230331523592AT869182155832332524593AU86811232250330522594AV87114836332333325395AW864181107123331123196AX862175106475332124197AY87451106435132124198AZ872561055711532024099BA86599351613325245100BB864166362403315235101BC8661801060393325245102BD8621591053743332252103BE866173369513332252104BF877158356333322242105BG8761401061383320240106BH8701901068523322242107BI8631751050753327247108BJ8771871058543331251109BK87719610693212317237110BL8781455783912318238111BM86792577573331251112BN8631291255373322242113BO8761811251433332252AverageTensioncoolingapplied torate insteel sheet inHoldingCoolingtemperaturetemperaturetime atstop temp.range ofrange ofTemperingtemperingSheetTaMs-TaMs-Tatemp.temp.thicknessNos.(° C.)(° C. / s)(MPa)(° C.)(s)(mm)Type*5720912162772901.4CRCOMP. EX.5820515173391791.4CRINV. EX.5919915102622691.4GACOMP. EX.602401693012921.4GAINV. EX.6122120102862071.4GACOMP. EX.621261892932841.4GAINV. EX.6314613172711941.4GACOMP. EX.6420217112591621.4CRINV. EX.6520513182932641.4CRCOMP. EX.6621114182541761.4GAINV. EX.6719314143022861.4GACOMP. EX.6818210103052061.4GIINV. EX.6916716153011321.4GACOMP. EX.7019519132651841.4GAINV. EX.711691983071351.4GACOMP. EX.7217613132591931.4GAINV. EX.7316718103072791.4GICOMP. EX.7419612123271741.4GAINV. EX.7519411143491851.4GAINV. EX.7621317163311801.4GAINV. EX.7720213123181121.4GACOMP. EX.7817413112581521.4GAINV. EX.7920317132671841.4GIINV. EX.8018217142871641.4GACOMP. EX.8118317123312341.4GAINV. EX.8220014182752431.4GAINV. EX.8320716112771661.4GACOMP. EX.8418918102732181.4CRINV. EX.8519520172611781.4CRINV. EX.8618913153462751.4GACOMP. EX.8718313162651581.4GAINV. EX.8816711123392751.4GAINV. EX.8921818162852321.4GAINV. EX.9018413103111811.4GAINV. EX.9120213142932981.4GAINV. EX.9220015163492981.4GAINV. EX.9318611152771411.5CRINV. EX.9421016173061751.6CRINV. EX.9519416103181721.2CRINV. EX.9620015152002841.1CRINV. EX.972091983352771.4CRINV. EX.9820315153171511.4CRINV. EX.9910916173391621.4CRINV. EX.10023114133292731.2CRINV. EX.10119817132912801.1CRINV. EX.102203149173372941.4CRINV. EX.1031901453071931.5CRINV. EX.10419715863161141.6CRINV. EX.10517213111721721.2CRINV. EX.10620113114371601.1CRINV. EX.1071971917311211.5CRINV. EX.10822117113259431.6CRINV. EX.10919611103022941.2EGINV. EX.11019015163171411.1GIINV. EX.1112021393331381.4EGINV. EX.11219594153021341.5GIINV. EX.113188103172671621.8GAINV. EX.Underlines indicate being outside the range of the present invention.*CR: cold rolled steel sheet (no coating), GI: hot-dip galvanized steel sheet (no alloying of zinc coating), GA: galvannealed steel sheet, EG: electrogalvanized steel sheet(Microstructure Observation)The amount of martensite, the amount of retained austenite, the total amount of ferrite and bainitic ferrite, and the average grain size of prior austenite were determined by the methods described hereinabove.(Proportion of Packets Having the Largest Area in Prior Austenite Grains)The average proportion of packets having the largest area in prior austenite grains was determined by the method described hereinabove.(Tensile Test)A JIS No. 5 test specimen (gauge length: 50 mm, parallel section width: 25 mm) was sampled so that the longitudinal direction of the test specimen would be perpendicular to the rolling direction. A tensile test was performed in accordance with JIS Z 2241 under conditions where the crosshead speed was 1.67×10−1 mm / sec. TS was thus measured. In accordance with aspects of the present invention, 1180 MPa or higher TS was determined to be acceptable.(Bendability)

[0090] A 30 mm×100 mm bendability test specimen was sampled and was tested by a V-block method in accordance with JIS Z 2248 to measure the minimum bending radius R that did not cause cracking on the ridge portion of the bend. The bending direction was the longitudinal direction of the test specimen. The minimum bending radius (R) was divided by the sheet thickness (t) to determine the value R / t. Bendability was evaluated as excellent when R / t was 6.0 or less. Here, the presence or absence of cracking was determined by analyzing the ridge portion of the bend top with a digital microscope (RH-2000 manufactured by HIROX CO., LTD.) at ×40 magnification.(Flatness in the Width Direction)

[0091] The cold rolled steel sheets obtained as described above were analyzed to measure the flatness in the width direction. The measurement is illustrated in FIG. 2. Specifically, a sheet with a length of 500 mm in the rolling direction (coil width×500 mm L×sheet thickness) was cut out from the coil and was placed on a surface plate in such a manner that the warp at the ends would face upward. The height on the steel sheet was measured with a contact displacement meter by continuously moving the stylus over the width. Based on the results, the steepness as an index of the flatness of the steel sheet shape was measured as illustrated in FIG. 2. The flatness was rated as “x” when the steepness was more than 0.02, as “∘” when the steepness was more than 0.01 and 0.02 or less, and as “⊚” when the steepness was 0.01 or less. The steel sheet was evaluated as “excellent in the flatness in the width direction” when the steepness was 0.02 or less.(Working Embrittlement Resistance)

[0092] The working embrittlement resistance was evaluated by Charpy test. A Charpy test specimen was a 2 mm deep V-notched test piece that was a stack of steel sheets fastened together with bolts to eliminate any gaps between the steel sheets. The number of steel sheets that were stacked was controlled so that the thickness of the stack as the test piece would be closer to 10 mm. When, for example, the sheet thickness was 1.2 mm, eight sheets were stacked to give a 9.6 mm thick test piece. The sheets for stacking into the Charpy test specimen were sampled so that the width direction would be the longitudinal direction. As an index of the working embrittlement resistance, the ratio vE0% / vE10% of the absorbed impact energy at room temperature of the as-produced (unworked) steel sheet to that of the steel sheet after 10% rolling was measured. The working embrittlement resistance was rated as “x” when vE0% / vE10% was less than 0.6, as “∘” when vE0% / vE10% was 0.6 or more and less than 0.7, and as “⊚” when VE0% / vE10% was 0.7 or more. The Charpy test specimen was evaluated as “excellent in working embrittlement resistance” when vE0% / vE10% was 0.6 or more. Conditions other than those described above conformed to JIS Z 2242: 2018.

[0093] The results are described in Tables 5 to 7. As shown in Tables 5 to 7, INVENTIVE EXAMPLES achieved 1180 MPa or higher TS and excellent bendability, flatness in the width direction, and working embrittlement resistance. In contrast, COMPARATIVE EXAMPLES were unsatisfactory in one or more of TS, bendability, flatness in the width direction, and working embrittlement resistance.TABLE 5Averageproportion ofTotal ofpackets havingAverageSheetferrite andthe largestgrain sizeLimitingWorkingthick-Retainedbainiticarea in priorof priorbendingFlatnessembrit-nessMartensiteausteniteferriteaustenite grainsausteniteTSRin widthtlementNos.Steels(mm)(area %)(vol %)(area %)(area %)(μm)(MPa)(mm)R / tdirectionresistance1A1.48111 7561013855.53.9⊚⊚INV. EX.2B1.48594531115624.53.2⊚⊚INV. EX.3B1.481910 47 812144.53.2⊚⊚INV. EX.4B1.479813 591010045.53.9⊚⊚COMP. EX.5B1.48410 7591914105.53.9⊚◯INV. EX.6B1.48310 5492315144.53.2⊚XCOMP. EX.7B1.48010 10 531312004.53.2⊚⊚INV. EX.8B1.482513 491111025.53.9⊚⊚COMP. EX.9B1.48496591614584.53.2⊚◯INV. EX.10B1.48410 5532415155.03.6⊚XCOMP. EX.11B1.48685651415113.52.5◯◯INV. EX.12B1.48793911016094.02.9XXCOMP. EX.13B1.48595451415094.02.9⊚◯INV. EX.14B1.48111 849 813643.52.5⊚◯INV. EX.15B1.48311 764 814094.02.9◯◯INV. EX.16B1.48297901314072.01.4XXCOMP. EX.17B1.48410 5531415134.02.9⊚⊚INV. EX.18B1.48297571114054.53.2⊚⊚INV. EX.19B1.481810 541412016.54.6⊚⊚INV. EX.20B1.474917 491410477.05.0⊚⊚COMP. EX.21B1.48595581015145.53.9⊚⊚INV. EX.22B1.48595471015111.00.7⊚⊚INV. EX.23B1.48511 468 915547.05.0◯◯INV. EX.24B1.48212 7891014136.04.3XXCOMP. EX.25B1.48610 3601416106.04.3⊚◯INV. EX.26B1.48610 4501315596.54.6⊚◯INV. EX.27B1.49232461116648.05.7⊚⊚INV. EX.28B1.49523551316089.06.4⊚⊚COMP. EX.29B1.48414 3511116047.05.0⊚◯INV. EX.30B1.48116 3481516096.04.3⊚XCOMP. EX.31B1.48511 7541014155.03.6⊚⊚INV. EX.32B1.48884551015625.03.6⊚⊚INV. EX.33B1.48910 3701016075.03.6◯◯INV. EX.34B1.48912 2901516556.04.3XXCOMP. EX.35B1.48498681013585.03.6◯◯INV. EX.36B1.48610 381 916045.53.9XXCOMP. EX.37B1.4878558 815106.04.3⊚◯INV. EX.38B1.48810 3521316066.54.6⊚◯INV. EX.39B1.4828859 913565.03.6⊚⊚INV. EX.40B1.48412 549 915123.52.5⊚⊚INV. EX.41B1.48884531511996.04.3⊚⊚INV. EX.42B1.48412 6471212075.03.6⊚⊚INV. EX.43B1.48548601313608.05.7⊚⊚INV. EX.Underlines indicate being outside the range of the present invention.TABLE 6Averageproportion ofAverageTotal ofpackets havinggrainSheetferrite andthe largest areasize ofLimitingWorkingthick-Retainedbainiticin priorpriorbendingFlatnessembrit-nessMartensiteausteniteferriteaustenite grainsausteniteTSRin widthtlementNos.Steels(mm)(area %)(vol %)(area %)(area %)(μm)(MPa)(mm)R / tdirectionresistance44B1.495 22591216558.56.1⊚⊚COMP. EX.45B1.486 93551012076.04.3⊚⊚INV. EX.46B1.485 96581411956.54.6⊚⊚INV. EX.47B1.483117541514085.03.6⊚⊚INV. EX.48B1.686 8656914566.03.8⊚⊚INV. EX.49C2.090 92561016658.04.0⊚⊚INV. EX.50D1.485117471314406.04.3⊚⊚INV. EX.51E1.487 82581116276.04.3⊚⊚INV. EX.52F1.4811010 511211896.54.6⊚⊚INV. EX.53G1.483 512 471011035.03.6⊚⊚COMP. EX.54H1.485115591018036.04.3⊚◯INV. EX.55I1.483 86481419956.04.3⊚XCOMP. EX.56J1.482107471112114.02.9⊚⊚INV. EX.57K1.486 92581411756.04.3⊚⊚COMP. EX.58L1.484132471417115.03.6⊚◯INV. EX.59M1.482162461417493.02.1⊚XCOMP. EX.60N1.482109591511886.54.6⊚⊚INV. EX.61O1.472 919 561010117.05.0⊚⊚COMP. EX.62P1.48510546916026.04.3⊚◯INV. EX.63Q1.48810448916695.53.9⊚XCOMP. EX.64R1.482108521012843.02.1⊚◯INV. EX.65S1.488104461014910.50.4⊚XCOMP. EX.66T1.485123561515204.02.9⊚◯INV. EX.67U1.486 9449815253.02.1⊚XCOMP. EX.68V1.487113471116396.54.6⊚◯INV. EX.69W1.483 9857914665.53.9⊚XCOMP. EX.70X1.486114451515875.53.9⊚◯INV. EX.71Y1.483108601413824.02.9⊚XCOMP. EX.72Z1.485 84491315154.53.2⊚◯INV. EX.73AA1.48510754914605.53.9⊚XCOMP. EX.74AB1.487125581414795.03.6⊚⊚INV. EX.75AC1.486115501011935.53.9⊚⊚INV. EX.76AD1.485 85571014886.04.3⊚◯INV. EX.77AE1.486104521318796.04.3⊚XCOMP. EX.78AF1.485116561211976.04.3⊚⊚INV. EX.79AG1.485125491015146.04.3⊚◯INV. EX.80AH1.486112491318804.53.2⊚XCOMP. EX.81AI1.481127551412126.04.3⊚⊚INV. EX.82AJ1.489102471016685.03.6⊚◯INV. EX.83AK1.487 93571418925.03.6⊚XCOMP. EX.84AL1.480118581211954.53.2⊚⊚INV. EX.85AM1.487 95501114925.53.9⊚◯INV. EX.86AN1.488113511418515.53.9⊚XCOMP. EX.Underlines indicate being outside the range of the present invention.TABLE 7Averageproportion ofTotal ofpackets havingAverageSheetferrite andthe largest areagrain sizeLimitingWorkingthick-Retainedbainiticin priorof priorbendingFlatnessembrit-nessMartensiteausteniteferriteaustenite grainsausteniteTSRin widthtlementNos.Steels(mm)(area %)(vol %)(area %)(area %)(μm)(MPa)(mm)R / tdirectionresistance87AO1.4818955911944.02.9⊚⊚INV. EX.88AP1.486116541614935.53.9⊚◯INV. EX.89AQ1.48299541511955.53.9⊚⊚INV. EX.90AR1.48794541715415.03.6⊚◯INV. EX.91AS1.481107481314166.04.3◯◯INV. EX.92AT1.482118491213057.55.4⊚⊚INV. EX.93AU1.586103631416116.54.3◯◯INV. EX.94AV1.683127581013555.53.4⊚⊚INV. EX.95AW1.2811010461412024.03.3⊚⊚INV. EX.96AX1.188113531115944.03.6⊚⊚INV. EX.97AY1.482106631014385.03.6◯◯INV. EX.98AZ1.483106491314267.55.4⊚⊚INV. EX.99BA1.49045481114818.05.7⊚⊚INV. EX.100BB1.283134521116024.53.8⊚◯INV. EX.101BC1.18587471413745.04.5⊚⊚INV. EX.102BD1.485104701214843.02.1◯◯INV. EX.103BE1.58396691413847.04.7◯◯INV. EX.104BF1.687115521214838.55.3⊚⊚INV. EX.105BG1.285104471115415.54.6⊚⊚INV. EX.106BH1.18711355912174.03.6⊚⊚INV. EX.107BI1.58835461214368.55.7⊚⊚INV. EX.108BJ1.68198561112017.04.4⊚⊚INV. EX.109BK1.285114501515905.54.6⊚⊚INV. EX.110BL0.68682591116612.54.2⊚⊚INV. EX.111BM2.28485471214418.03.6⊚⊚INV. EX.112BN1.586124511015586.04.0⊚⊚INV. EX.113BO1.88893521315308.54.7⊚⊚INV. EX.Underlines indicate being outside the range of the present invention.

Claims

1. A high strength steel sheet having a chemical composition comprising, in mass %,C: 0.030% or more and 0.500% or less,Si: 0.50% or more and 2.50% or less,Mn: 1.50% or more and 5.00% or less,P: 0.100% or less,S: 0.0200% or less,Al: 1.000% or less,N: 0.0100% or less, andO: 0.0100% or less,a balance being Fe and incidental impurities,the high strength steel sheet being such that in a region at ¼ sheet thickness,an area fraction of martensite is 80% or more,a volume fraction of retained austenite is 3% or more and 15% or less,an area fraction of a total of ferrite and bainitic ferrite is 10% or less,an average grain size of prior austenite is 20 μm or less, andan average of proportions of packets having the largest area in prior austenite grains is 70% by area or less of the prior austenite grain.

2. The high strength steel sheet according to claim 1, wherein the chemical composition further comprises at least one element selected from, in mass %,Ti: 0.200% or less, Nb: 0.200% or less,V: 0.200% or less, Ta: 0.10% or less,W: 0.10% or less, B: 0.0100% or less,Cr: 1.00% or less, Mo: 1.00% or less,Co: 0.010% or less, Ni: 1.00% or less,Cu: 1.00% or less, Sn: 0.200% or less,Sb: 0.200% or less, Ca: 0.0100% or less,Mg: 0.0100% or less, REM: 0.0100% or less,Zr: 0.100% or less, Te: 0.100% or less,Hf: 0.10% or less, and Bi: 0.200% or less.

3. The high strength steel sheet according to claim 1, which has a coated layer on a surface of the steel sheet.

4. The high strength steel sheet according to claim 2, which has a coated layer on a surface of the steel sheet.

5. A method for manufacturing the high strength steel sheet according to claim 1, the method comprising:providing a cold rolled steel sheet produced by subjecting a steel having the chemical composition to hot rolling, pickling, and cold rolling;annealing the steel sheet by heating at an annealing temperature of 750° C. or above and 950° C. or below for a holding time at the annealing temperature of 10 seconds or more and 1000 seconds or less;bending and unbending the steel sheet 1 to 15 times in total with a roll having a radius of 800 mm or less during the annealing;cooling the steel sheet at an average cooling rate of 20° C. / s or more in a temperature range from 700° C. to 600° C. and at an average cooling rate of 20° C. / s or more in a temperature range from 499° C. to Ms;bending and unbending the steel sheet in the temperature range from 499° C. to Ms, 1 to 15 times in total with a roll having a radius of 800 mm or less;cooling the steel sheet at an average cooling rate of 150° C. / s or less in a temperature range from Ms to a cooling stop temperature Ta;applying a tension to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta while controlling the tension to 5 MPa or more and 100 MPa or less, the cooling stop temperature Ta being 100° C. or above and (Ms−80° C.) or below where Ms is martensite start temperature (° C.) defined by formula (1); andtempering the steel sheet at a tempering temperature of Ta or above and 450° C. or below for a holding time at the tempering temperature of 10 seconds or more and 1000 seconds or less,Ms=519-474×[%⁢ C]-30.4×[%⁢ Mn]-12.1×[%⁢ Cr]-7.5×[%⁢ Mo]-17.7×[%⁢ Ni](1)wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.

6. A method for manufacturing the high strength steel sheet according to claim 2, the method comprising:providing a cold rolled steel sheet produced by subjecting a steel having the chemical composition to hot rolling, pickling, and cold rolling;annealing the steel sheet by heating at an annealing temperature of 750° C. or above and 950° C. or below for a holding time at the annealing temperature of 10 seconds or more and 1000 seconds or less;bending and unbending the steel sheet 1 to 15 times in total with a roll having a radius of 800 mm or less during the annealing;cooling the steel sheet at an average cooling rate of 20° C. / s or more in a temperature range from 700° C. to 600° C. and at an average cooling rate of 20° C. / s or more in a temperature range from 499° C. to Ms;bending and unbending the steel sheet in the temperature range from 499° C. to Ms, 1 to 15 times in total with a roll having a radius of 800 mm or less;cooling the steel sheet at an average cooling rate of 150° C. / s or less in a temperature range from Ms to a cooling stop temperature Ta;applying a tension to the steel sheet in the temperature range from Ms to the cooling stop temperature Ta while controlling the tension to 5 MPa or more and 100 MPa or less,the cooling stop temperature Ta being 100° C. or above and (Ms−80° C.) or below where Ms is martensite start temperature (° C.) defined by formula (1); andtempering the steel sheet at a tempering temperature of Ta or above and 450° C. or below for a holding time at the tempering temperature of 10 seconds or more and 1000 seconds or less,Ms=519-474×[%⁢ C]-30.4×[%⁢ Mn]-12.1×[%⁢ Cr]-7.5×[%⁢ Mo]-17.7×[%⁢ Ni](1)wherein [% C], [% Mn], [% Cr], [% Mo], and [% Ni] indicate the contents (mass %) of C, Mn, Cr, Mo, and Ni, respectively, and are zero when the element is absent.

7. The method for manufacturing the high strength steel sheet according to claim 5, further comprising performing a coating treatment.

8. The method for manufacturing the high strength steel sheet according to claim 6, further comprising performing a coating treatment.

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