The invention relates to a dangerous goods transport vehicle dynamic monitoring method and an early warning device. The method comprises the following steps: (1) arranging the early warning device which comprises a collision, rollover and temperature and pressure early warning module, an early warning arithmetic and a threshold value; (2) acquiring the acceleration, the dip angle, the temperature/pressure and image signals of a goods wagon; (3) carrying out calculation on each signal and comparing the signal with the preset threshold value and sending out a corresponding alarm command; (4) displaying alarm information and sending the alarm information to a remote monitoring center through a global position system/general packet radio system (GPS/GPRS); (5) after the alarm is completed, returning to the step (2); and (6) carrying out real-time monitoring on a goods state and the alarm information by a driver through displaying. The corresponding early warning device comprises the GPS/GPRS, cameras, a card reader, a triaxial acceleration sensor, a display screen, an artificial alarm, a buzzing alarm, a temperature/pressure sensor, a dip angle sensor, a secure digital (SD) card storage and an electronic control unit which comprises a microprocessor. The collision, rollover and temperature and pressure early warning module is arranged in the microprocessor. The invention can be used for carrying out real-time monitoring on collision, rollover and temperature and pressure, thereby being beneficial to driving safety and rescue operation.